• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    In an apparatus for the separation of air by cryogenic distillation, the overhead gas of a mixing column is sent to the passages for warming a bottom reboiler of the low-pressure column of a double column fed with air to be distilled. This increases the production of oxygen in the bottom of the low-pressure column.
    公开号:US20010003909A1
    申请号:US09/725,462
    申请日:2000-11-30
    公开日:2001-06-21
    发明作者:Jean Brugerolle
    申请人:LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude；
    IPC主号:F25J3-04715
    专利说明:
    [0001] 1. Field of the invention [0001]
    [0002] The invention relates to a process and a plant for the separation of air by cryogenic distillation. In particular, it relates to a process for producing pure oxygen using a mixing column and, possibly, for producing argon using an argon column. [0002]
    [0003] 2. Description of Prior Art [0003]
    [0004] In EP-A-0229803, the mixing column is fed at the bottom with vaporized rich liquid coming from the head condenser of the argon column. [0004]
    [0005] EP-A-0269342 relates to the case in which the argon column is thermally coupled to a mixing column so that the overhead gas of the argon column warms the mixing column. [0005]
    [0006] U.S. Pat. No. 5,551,258 describes a process in which a mixing column is fed at the top with a liquid containing 55 vol % oxygen, the overhead gas of the mixing column then serving to warm the bottom condenser of the low-pressure column. [0006]
    [0007] One object of the present invention is to increase the amount of pure gaseous oxygen (containing more than 99.5 mol % oxygen) which can be produced by a double air separation column. [0007] SUMMARY OF THE INVENTION
    [0008] One object of the invention is an air separation plant for producing an oxygen-rich fluid by cryogenic distillation, comprising: [0008]
    [0009] a double column comprising at least one medium-pressure column and a low-pressure column which includes a reboiler for vaporizing the liquid in the bottom of the low-pressure column; [0009]
    [0010] a mixing column; [0010]
    [0011] means for sending cooled and compressed air to the medium-pressure column; [0011]
    [0012] means for sending an oxygen-enriched liquid from the medium-pressure column to an injection point of the low-pressure column and means for sending a nitrogen-enriched liquid from the medium-pressure column to the low-pressure column; [0012]
    [0013] means for sending gas to the bottom of the mixing column; [0013]
    [0014] means for sending a second oxygen-enriched liquid from the low-pressure column to the top of the mixing column, this second liquid being less volatile than the gas feeding the bottom of the mixing column; [0014]
    [0015] means for withdrawing an oxygen-rich fluid from the low-pressure column; [0015]
    [0016] means for sending at least one portion of a gas, possibly the overhead gas, from the mixing column to passages for warming the reboiler, [0016]
    [0017] characterized in that it includes means for withdrawing the second liquid from the low-pressure column at a level at least 5 theoretical trays below the injection point of the low-pressure column, or possibly at least 10 theoretical trays below the injection point of the low-pressure column and/or about a third of the way up the low pressure column. [0017]
    [0018] The apparatus may include an argon column or simply a vaporiser for vaporizing liquid from the bottom of the medium pressure column by heat exchange with a gas from the low pressure column. [0018]
    [0019] Preferably it comprises meand for withdrawing the second liquid at a level between the bottom of the low pressure column and the point of removal of the feed to the argon column or the point of removal of the gas sent from the low pressure column to the rich liquid vaporizer. [0019]
    [0020] In this case, the mixing column may be fed at the bottom with any gas more volatile than the liquid oxygen sent to the top of the column. [0020]
    [0021] Another object of the invention is an air separation plant for producing an oxygen-rich fluid and possibly an argon enriched fluid by cryogenic distillation, comprising: [0021]
    [0022] a double column comprising a medium-pressure column and a low-pressure column which includes a reboiler for vaporizing the liquid in the bottom of the low-pressure column; [0022]
    [0023] a condenser, possibly at the top of an argon column; [0023]
    [0024] a mixing column; [0024]
    [0025] means for sending cooled and compressed air at least to the medium-pressure column; [0025]
    [0026] means for sending a first oxygen-enriched liquid from the medium-pressure column to the condenser; [0026]
    [0027] means for withdrawing an argon-enriched gas from a first level of the low-pressure column and means for sending it to the condenser or to the argon column; [0027]
    [0028] means for sending an oxygen-enriched liquid from the medium-pressure column to at least one injection point of the low-pressure column and a nitrogen-enriched liquid from the medium-pressure column to the low-pressure column; [0028]
    [0029] means for vaporizing oxygen-enriched liquid in the condenser and means for sending at least one portion of the vapour and/or air to the bottom of the mixing column; [0029]
    [0030] means for sending a second oxygen-enriched liquid from the low-pressure column to the top of the mixing column, this second liquid being less volatile than the gas feeding the bottom of the mixing column; [0030]
    [0031] possibly means for withdrawing an argon-enriched fluid at the top of the argon column; [0031]
    [0032] means for withdrawing an oxygen-rich fluid from the low-pressure column and [0032]
    [0033] means for sending at least one portion of a gas, possibly the overhead gas, from the mixing column to passages for warming the reboiler. [0033]
    [0034] Preferbaly the apparatus comprises means for withdrawing the second liquid is withdrawn from the low-pressure column at a level at least 5 theoretical trays below the point of injection or the lowermost point of injection at a level (still more preferably at least 10 theoretical trays below the point of injection or the lowermost point of injection) and/or about a third of the way up the low-pressure column. [0034]
    [0035] According to other optional aspects: [0035]
    [0036] the overhead gas of the mixing column at least partially condenses in the reboiler and at least part of the condensate is sent to the low pressure column, preferbaly at a level above the first level; [0036]
    [0037] there are means for sending the liquid in the bottom of the argon column to the top of the mixing column; [0037]
    [0038] there are means for sending a bottom liquid and/or an intermediate liquid from the mixing column to the double column; [0038]
    [0039] there are at least 80, preferably at least 90, theoretical trays in the low-pressure column; [0039]
    [0040] there are means for sending air or a gas from the medium-pressure column to other passages for warming the reboiler; [0040]
    [0041] the apparatus includes a blowing turbine for sending air to the low pressure column or the mixing column; [0041]
    [0042] the apparatus comprises means for withdrawing gaseous nitrogen from the medium-pressure column as a product. [0042]
    [0043] Another object of the invention is a process for the separation of air by cryogenic distillation for producing oxygen with a double column comprising: [0043]
    [0044] a medium-pressure column; and [0044]
    [0045] a low-pressure column which includes a reboiler for vaporizing the liquid in the bottom of the low-pressure column, [0045]
    [0046] comprising the steps of: [0046]
    [0047] sending cooled and compressed air to the medium-pressure column; [0047]
    [0048] sending an oxygen-enriched liquid and a nitrogen-enriched liquid from the medium-pressure column to the low-pressure column; [0048]
    [0049] sending gas to the bottom of the mixing column; [0049]
    [0050] sending a second oxygen-enriched liquid from the low-pressure column to the top of the mixing column, this second liquid being less volatile than the gas feeding the bottom of the mixing column; [0050]
    [0051] withdrawing an oxygen-rich fluid from the low-pressure column; [0051]
    [0052] sending at least one portion of a gas, possibly the overhead gas, from the mixing column to passages for warming the reboiler, [0052]
    [0053] characterized in that the second liquid contains less than 5 mol % nitrogen and/or the gas sent from the mixing column to the warming passages contains less than 15 mol % nitrogen. [0053]
    [0054] Another object of the invention is a process for the separation of air by cryogenic distillation for producing oxygen and possibly argon with a double column comprising: [0054]
    [0055] a medium-pressure column; [0055]
    [0056] a low-pressure column which includes a reboiler for vaporizing the liquid in the bottom of the low-pressure column; and [0056]
    [0057] a condenser, optionally at the top of an argon column, and a mixing column, [0057]
    [0058] comprising the steps of: [0058]
    [0059] sending cooled and compressed air to at least the medium-pressure column; [0059]
    [0060] sending a first oxygen-enriched liquid from the medium-pressure column to the head condenser; [0060]
    [0061] withdrawing an argon-enriched gas from a first level of the low-pressure column and sending it to the condenser or the argon column; [0061]
    [0062] sending an oxygen enriched liquid and a nitrogen-enriched liquid from the medium-pressure column to the low-pressure column; [0062]
    [0063] at least partially vaporizing oxygen-enriched liquid in the condenser and sending at least one portion of the vapour and/or air to the bottom of the mixing column; [0063]
    [0064] sending a second oxygen-enriched liquid from the low-pressure column to the top of the mixing column, this second liquid being less volatile than the gas feeding the bottom of the mixing column; [0064]
    [0065] possibly withdrawing an argon-enriched liquid from the top of the argon column; [0065]
    [0066] withdrawing an oxygen-rich fluid from the low-pressure column; [0066]
    [0067] sending at least one portion of a gas, possibly the overhead gas, from the mixing column to passages for warming the reboiler, [0067]
    [0068] characterized in that the second liquid contains less than 5 mol. % nitrogen and/or the gas sent from the mixing column to the warming passages contains less than 15 mol. % nitrogen. [0068]
    [0069] According to other optional aspects: [0069]
    [0070] the overhead gas of the mixing column at least partially condenses in the reboiler and the condensate is sent to the low pressure column, possibly at a level above the first level; [0070]
    [0071] at least part of the liquid in the bottom of the argon column is sent to the top of the mixing column; [0071]
    [0072] a bottom liquid and/or an intermediate liquid are sent from the mixing column to the double column; [0072]
    [0073] a gas from the medium-pressure column or air at least partially condenses in other passages for warming the reboiler; [0073]
    [0074] the overhead gas of the mixing column comprises 3 to 5 mol % nitrogen; [0074]
    [0075] the overhead gas of the mixing column comprises at least 93 mol. %, possibly at least 95 mol. % oxygen; [0075]
    [0076] the liquid sent to the top of the mixing column contains at least 98 mol % oxygen; [0076]
    [0077] the pressure of the mixing column is at between 0,5 and 1 bar above the pressure of the low pressure column. [0077]
    [0078] It will be understood that the overhead gas of the mixing column may be withdrawn from the top of the mixing column or at most five theoretical trays below the top of the mixing column. [0078] BRIEF DESCRIPTION OF THE DRAWINGS
    [0079] The invention will now be described in greater detail with reference to the figures which diagrammatically illustrate plants according to the invention. [0079] DESCRIPTION OR PREFERRED EMBODIMENTS
    [0080] The plant in FIG. 1 comprises a double column [0080] 1 comprising a medium-pressure column 3 and a low-pressure column 5 coupled together via a reboiler 7.
    [0081] The reboiler includes passages for vaporizing liquid and two independent series of warming passages for two different warming gases. [0081]
    [0082] The low-pressure column operates at between 1.4 and 2.7 bar and the medium-pressure column operates at between 5 and 8 bar. [0082]
    [0083] The argon column [0083] 9 is fed from a first level of the low-pressure column 5. There is also a mixing column 11 operating at a pressure between 1.9 and 3.7 bar.
    [0084] A stream of air [0084] 13 is sent to the column 3 and a stream of blown air 14 is sent to the column 5.
    [0085] A stream of liquid [0085] 15 containing 40 mol % oxygen is withdrawn from the bottom of the medium-pressure column 3; a portion 17 of this liquid feeds the low-pressure column 5 after expansion in a valve and a portion 19 of the liquid is expanded to between 1.7 and 2.2 bar absolute in a valve and sent to the head condenser 21 of the argon column 9 where it at least partially vaporizes. The vaporized liquid 23 is sent to the bottom of the mixing column.
    [0086] The overhead nitrogen of the low-pressure column at least partially condenses in the bottom reboiler [0086] 7 and the condensate is sent to the medium-pressure column and/or the low-pressure column.
    [0087] A gas stream [0087] 41 containing at least 80 mol % nitrogen is withdrawn as a product from the top of the medium-pressure column and constitutes 10 to 15% of the feed air.
    [0088] A stream of nitrogen-enriched liquid [0088] 25 containing less than 2 mol % oxygen is sent from the medium-pressure column to the top of the low-pressure column.
    [0089] A liquid stream [0089] 27 containing less than 5 mol % nitrogen is withdrawn from the bottom of the low-pressure column 5 below the point of withdrawal of the gas 26 intended for the argon column 9 and between 0 and 5 theoretical trays above the bottom of the column and is sent after pumping to between 1.9 and 3.7 bar to the top of the mixing column 11. Preferably, this stream 27 is mixed with the bottom liquid 29 of the argon column before being pumped and sent to the mixing column.
    [0090] A gas stream [0090] 31 containing at most 5 mol % nitrogen is sent from the top of the mixing column to the reboiler 7 where it condenses in passages separate from those in which the nitrogen of the medium-pressure column condenses so as to increase the reflux in the bottom of the low-pressure column. Instead of this nitrogen, air or another fluid less volatile than the medium-pressure nitrogen may possibly be condensed therein, provided that it condenses in another condenser of the system, normally above the reboiler. A portion of the stream 31 may serve as an oxygen-enriched product.
    [0091] Next, the liquid containing 5 mol % nitrogen is sent to the low-pressure column at a level above the point of withdrawal of the stream [0091] 26.
    [0092] An intermediate liquid [0092] 33 containing 80 mol % oxygen is sent from the mixing column to the low-pressure column 5.
    [0093] The bottom liquid [0093] 35 containing 65 mol % oxygen is sent from the mixing column to the low-pressure column 5.
    [0094] A stream [0094] 37 containing more than 99.5 mol % oxygen is withdrawn from the bottom of the low-pressure column 5 either in gaseous form or in liquid form.
    [0095] It may thus be seen that the low-pressure column is fed, going from the top downwards, with lean liquid [0095] 25 containing less than 1 mol % oxygen, with blowing air 14, the unvaporized rich liquid 45 from the head condenser of the argon column, the rich liquid 17, the liquid 35 from the bottom of the mixing column, the intermediate liquid 33 from the mixing column and the recondensed mixture 31 from the reboiler 7.
    [0096] In order to further improve the arrangement, several intermediate liquids could be sent from the mixing column to the low-pressure column. [0096]
    [0097] The low-pressure column contains at least 80 theoretical trays and preferably at least 90 theoretical trays. [0097]
    [0098] The plant in FIG. 2 differs from that in FIG. 1 in that the mixing column is fed at the bottom exclusively with a stream of air possibly coming from a turbine or a supercharger (these not being illustrated). The vapour from the condenser [0098] 21 of the argon column is sent to the low-pressure column just below the point of injection of the rich liquid 45.
    [0099] It would be conceivable to combine the concepts of FIGS. 1 and 2 and to feed the mixing column with air and with vaporized rich liquid at the same time. [0099]
    [0100] Obviously in the case of FIG. 2, the argon column may be omitted or reduced to a simple condenser fed by rich liquid and a gas from the low pressure column, for example having the composition of the feed to the argon column. [0100]
    [0101] As required, the argon column and/or the low-pressure column may be constructed in two sections in the manner described in EP-A-0628777. [0101]
    [0102] Likewise, the medium-pressure and low-pressure columns may be constructed side by side. [0102]
    [0103] These various staged feeds make it possible to obtain almost perfect low-pressure distillation. This allows the production of oxygen to be increased while maintaining, or even increasing, the production of argon when more than 10 to 15% of the air is withdrawn as medium-pressure nitrogen or 10 to 15% of the air is sent as blowing air. [0103]
    [0104] The refrigeration needed for the apparatus may be provided by a blowing turbine and/or a Claude turbine and/or a nitrogen turbine. The apparatus may produce liquids and/or gases. [0104]
    权利要求:
    Claims (29)
    [1" id="US-20010003909-A1-CLM-00001] 1. Air separation plant for producing an oxygen-rich fluid by cryogenic distillation, comprising:
    a double column comprising at least one medium-pressure column and a low-pressure column which includes a reboiler for vaporizing the liquid in the bottom of the low-pressure column;
    a mixing column;
    means for sending cooled and compressed air to at least the medium-pressure column;
    means for sending an oxygen-enriched liquid from the medium-pressure column to an injection point of the low-pressure column and a nitrogen-enriched liquid from the medium-pressure column to the low-pressure column;
    means for sending gas to the bottom of the mixing column;
    means for sending a second oxygen-enriched liquid from the low-pressure column to the top of the mixing column, this second liquid being less volatile than the gas feeding the bottom of the mixing column;
    means for withdrawing an oxygen-rich fluid from the low-pressure column;
    means for sending at least one portion of a gas, possibly the overhead gas, from the mixing column to passages for warming the reboiler,
    characterized in that the second liquid is withdrawn from the low-pressure column at a level at least 5 theoretical trays below the injection point of the low pressure column, or possibly at least 10 theoretical trays below the injection point of the low pressure column and/ or about a third of the way up the low-pressure column.
    [2" id="US-20010003909-A1-CLM-00002] 2. The plant of
    claim 1 comprising means for vaporizing at least part of a liquid withdrawn from the medium pressure column and means for sending at least part of the vaporized liquid to the bottom of the mixing column.
    [3" id="US-20010003909-A1-CLM-00003] 3. The plant of
    claim 2 wherein the means for vaporizing at least part of a liquid withdrawn from the medium pressure column are constituted by the top condenser of an argon column.
    [4" id="US-20010003909-A1-CLM-00004] 4. The plant of
    claim 2 wherein the means for vaporizing at least part of a liquid withdrawn from the medium pressure column are constituted by a condenser heated by a gas removed from the low pressure column.
    [5" id="US-20010003909-A1-CLM-00005] 5. Air separation plant for producing an oxygen-rich fluid and argon by cryogenic distillation, comprising:
    a double column comprising a medium-pressure column and a low-pressure column which includes a reboiler for vaporizing the liquid in the bottom of the low-pressure column;
    a condenser possibly at the top of an argon column;
    a mixing column;
    means for sending cooled and compressed air to the medium-pressure column;
    means for sending a first oxygen-enriched liquid from the medium-pressure column to the condenser;
    means for withdrawing an argon-enriched gas from a first level of the low-pressure column and means for sending it to the condenser or the argon column;
    means for sending an oxygen-enriched liquid and a nitrogen-enriched liquid from the medium-pressure column to the low-pressure column;
    means for at least partially vaporizing oxygen-enriched liquid in the head condenser and means for sending at least one portion of the vapour and/or air to the bottom of the mixing column;
    means for sending a second oxygen-enriched liquid from the low-pressure column to the top of the mixing column, this second liquid being less volatile than the gas feeding the bottom of the mixing column;
    optionally means for withdrawing an argon-enriched fluid at the top of the argon column;
    means for withdrawing an oxygen-rich fluid at the low-pressure column;
    means for sending at least one portion of a gas, possibly the overhead gas, from the mixing column to passages for warming the reboiler.
    [6" id="US-20010003909-A1-CLM-00006] 6. Plant according to one of claims 3, 4 or 5 comprising means for withdrawing the second liquid at a level below the point of withdrawal of the gas heating the condenser or feeding the argon column.
    [7" id="US-20010003909-A1-CLM-00007] 7. Plant according to
    claim 5 comprising means for withdrawing the second liquid at a level below the first level and bottom of the low pressure column.
    [8" id="US-20010003909-A1-CLM-00008] 8. Plant according to
    claim 3 ,
    5 , 6 or 7, in which the overhead gas of the mixing column at least partially condenses in the reboiler and the condensate is sent to a level above the first level.
    [9" id="US-20010003909-A1-CLM-00009] 9. Plant according to
    claim 3 ,
    5 , 6, 7 or 8, comprising means for sending at least one portion of the liquid in the bottom of the argon column to the top of the mixing column.
    [10" id="US-20010003909-A1-CLM-00010] 10. Plant according to one of the preceding claims, comprising means for sending a bottom liquid and/or an intermediate liquid from the mixing column to the double column.
    [11" id="US-20010003909-A1-CLM-00011] 11. Plant according to one of the preceding claims, comprising at least 80, preferably at least 90, theoretical trays in the low-pressure column.
    [12" id="US-20010003909-A1-CLM-00012] 12. Plant according to one of the preceding claims, comprising means for sending air, or a gas which contains more nitrogen than air does from the medium-pressure column to other passages for warming the reboiler.
    [13" id="US-20010003909-A1-CLM-00013] 13. Process for the separation of air by cryogenic distillation for producing oxygen with a double column comprising:
    a medium-pressure column; and
    a low-pressure column which includes a reboiler for vaporizing the liquid in the bottom of the low-pressure column,
    comprising the steps of:
    sending cooled and compressed air to the medium-pressure column;
    sending an oxygen-enriched liquid and a nitrogen-enriched liquid from the medium-pressure column to the low-pressure column;
    sending gas to the bottom of the mixing column;
    sending a second oxygen-enriched liquid from the low-pressure column to the top of the mixing column, this second liquid being less volatile than the gas feeding the bottom of the mixing column;
    withdrawing an oxygen-rich fluid from the low-pressure column;
    sending at least one portion of a gas, possibly the overhead gas, from the mixing column to passages for warming the reboiler,
    characterized in that the second liquid contains less than 5 mol % nitrogen and/or the gas sent from the mixing column to the warming passages contains less than 15 mol % nitrogen.
    [14" id="US-20010003909-A1-CLM-00014] 13. Process according to
    claim 12 in which the gas sent to the bottom of the mixing column is a vaporized liquid formed by removing oxygen enriched liquid from the medium pressure column and vaporising at least part of it.
    [15" id="US-20010003909-A1-CLM-00015] 14. Process of
    claim 13 wherein the liquid is vaporised in the top condenser of an argon column.
    [16" id="US-20010003909-A1-CLM-00016] 15. Process of
    claim 13 wherein the liquid is vaporised in a condenser heated by a gas from the low pressure column.
    [17" id="US-20010003909-A1-CLM-00017] 16. Process for the separation of air by cryogenic distillation for producing oxygen and optionally argon with a double column comprising:
    a medium-pressure column;
    a low-pressure column which includes a reboiler for vaporizing the liquid in the bottom of the low-pressure column; and
    a condenser, possibly at the top of an argon column, and a mixing column,
    comprising the steps of:
    sending cooled and compressed air to the medium-pressure column;
    sending a first oxygen-enriched liquid from the medium-pressure column to the head condenser;
    withdrawing an argon-enriched gas from a first level of the low-pressure column and sending it to the condenser or the argon column;
    sending an oxygen enriched liquid and a nitrogen-enriched liquid from the medium-pressure column to the low-pressure column;
    at least partially vaporizing oxygen-enriched liquid in the head condenser and sending at least one portion of the vapour and/or air to the bottom of the mixing column;
    sending a second oxygen-enriched liquid from the low-pressure column to the top of the mixing column, this second liquid being less volatile than the gas feeding the bottom of the mixing column;
    withdrawing an argon-enriched liquid from the top of the argon column;
    withdrawing an oxygen-rich fluid from the low-pressure column;
    sending at least one portion of a gas, possibly the overhead gas, from the mixing column to passages for warming the reboiler.
    [18" id="US-20010003909-A1-CLM-00018] 17. Process according to
    claim 16 wherein the second liquid contains less than 5 mol % nitrogen and/or the gas sent from the mixing column to the warming passages contains less than 15 mol % nitrogen.
    [19" id="US-20010003909-A1-CLM-00019] 18. Process according to one of
    claims 13 to
    17 wherein the overhead gas of the mixing column at least partially condenses in the reboiler and the condensate is sent to the low pressure column, possibly to a level above the first level.
    [20" id="US-20010003909-A1-CLM-00020] 19. Process according to
    claim 14 ,
    16 or 17, comprising the step of sending the liquid in the bottom of the argon column to the top of the mixing column.
    [21" id="US-20010003909-A1-CLM-00021] 20. Process according to one of
    claims 13 to
    19 , comprising the step of sending a bottom liquid and an intermediate liquid from the mixing column to the double column.
    [22" id="US-20010003909-A1-CLM-00022] 21. Process according to one of
    claims 13 to
    20 , in which a gas from the medium-pressure column or air at least partially condenses in other passages for warming the reboiler.
    [23" id="US-20010003909-A1-CLM-00023] 22. Process according to one of
    claims 13 to
    21 , in which the overhead gas of the mixing column (11) comprises 1 to 7 mol % nitrogen, preferably between 0.1 and 5 mol % nitrogen.
    [24" id="US-20010003909-A1-CLM-00024] 23. Process according to one of
    claims 13 to
    22 , in which the overhead gas of the mixing column comprises at least 93 mol %, possibly at least 95 mol % oxygen.
    [25" id="US-20010003909-A1-CLM-00025] 24. Process according to one of
    claims 13 to
    23 , in which the liquid sent to the top of the mixing column (11) contains at least 99 mol % oxygen.
    [26" id="US-20010003909-A1-CLM-00026] 25. Process according to one of
    claims 13 to
    24 , in which air is sent to a blowing turbine and thence to the low pressure column or the mixing column.
    [27" id="US-20010003909-A1-CLM-00027] 26. Process according to one of
    claims 13 to
    25 , in which gas is withdrawn as a product from the top of the medium-pressure column.
    [28" id="US-20010003909-A1-CLM-00028] 27. Process according to one of
    claims 13 to
    26 , in which the gas sent to the bottom of the mixing column is richer in oxygen than air.
    [29" id="US-20010003909-A1-CLM-00029] 28. Process according to one of
    claims 13 to
    27 wherein the mixing column operates at a pressure between 0.5 and 1 bar above the pressure of the low pressure column.
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    US6484534B2|2002-11-26|Process and plant for separating air by cryogenic distillation
    US6318120B1|2001-11-20|Cryogenic distillation system for air separation
    US6339938B1|2002-01-22|Apparatus and process for separating air by cryogenic distillation
    US6314757B1|2001-11-13|Cryogenic rectification system for processing atmospheric fluids
    同族专利:
    公开号 | 公开日
    JP2001194058A|2001-07-17|
    US6385996B2|2002-05-14|
    EP1106945B1|2005-06-01|
    EP1106945A1|2001-06-13|
    DE60020500D1|2005-07-07|
    FR2801963A1|2001-06-08|
    AT297001T|2005-06-15|
    FR2801963B1|2002-03-29|
    DE60020500T2|2006-03-23|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    FR2854232A1|2003-04-23|2004-10-29|Air Liquide|Air separation procedure to produce argon uses cryogenic distillation with additional liquid flow containing 18-30 mol percent oxygen fed to low pressure column|
    EP3557166A1|2018-04-19|2019-10-23|Linde Aktiengesellschaft|Method for the low-temperature decomposition of air and air separation plant|IT961138B|1971-02-01|1973-12-10|Air Liquide|PLANT FOR COMPRESSING A FLUID BY EXPANSION OF ANOTHER FLUID|
    FR2584803B1|1985-07-15|1991-10-18|Air Liquide|AIR DISTILLATION PROCESS AND INSTALLATION|
    FR2655137B1|1989-11-28|1992-10-16|Air Liquide|AIR DISTILLATION PROCESS AND INSTALLATION WITH ARGON PRODUCTION.|
    FR2680114B1|1991-08-07|1994-08-05|Lair Liquide|METHOD AND INSTALLATION FOR AIR DISTILLATION, AND APPLICATION TO THE GAS SUPPLY OF A STEEL.|
    DE69419675T2|1993-04-30|2000-04-06|Boc Group Plc|Air separation|
    US5379599A|1993-08-23|1995-01-10|The Boc Group, Inc.|Pumped liquid oxygen method and apparatus|
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    US5551258A|1994-12-15|1996-09-03|The Boc Group Plc|Air separation|
    FR2774159B1|1998-01-23|2000-03-17|Air Liquide|COMBINED INSTALLATION OF AN OVEN AND AN AIR DISTILLATION APPARATUS AND METHOD OF IMPLEMENTING IT|
    US5865041A|1998-05-01|1999-02-02|Air Products And Chemicals, Inc.|Distillation process using a mixing column to produce at least two oxygen-rich gaseous streams having different oxygen purities|
    GB9902101D0|1999-01-29|1999-03-24|Boc Group Plc|Separation of air|CN102620520B|2012-04-09|2014-09-17|开封黄河空分集团有限公司|Process for preparing pressure oxygen and pressure nitrogen as well as by-product liquid argon through air separation|
    CN103162512B|2013-01-27|2015-06-10|南京瑞柯徕姆环保科技有限公司|Air separation plant used for preparing oxygen and nitrogen in identical-pressure separation mode|
    JP5655104B2|2013-02-26|2015-01-14|大陽日酸株式会社|Air separation method and air separation device|
    法律状态:
    2001-05-17| AS| Assignment|Owner name: L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'E Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:BRUGEROLLE, JEAN RENAUD;REEL/FRAME:011809/0954 Effective date: 20001128 |
    2002-03-04| AS| Assignment|Owner name: L'AIR LIQUIDE SOCIETE ANONYME A DIRECTOIRE ET CONS Free format text: CHANGE OF NAME;ASSIGNOR:L'AIR LIQUIDE, SOCIETE ANONYME POUR LE E'TUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE;REEL/FRAME:012648/0034 Effective date: 20020118 |
    2005-10-17| FPAY| Fee payment|Year of fee payment: 4 |
    2009-12-21| REMI| Maintenance fee reminder mailed|
    2010-05-14| LAPS| Lapse for failure to pay maintenance fees|
    2010-06-14| STCH| Information on status: patent discontinuation|Free format text: PATENT EXPIRED DUE TO NONPAYMENT OF MAINTENANCE FEES UNDER 37 CFR 1.362 |
    2010-07-06| FP| Expired due to failure to pay maintenance fee|Effective date: 20100514 |
    优先权:
    申请号 | 申请日 | 专利标题
    FR9915208A|FR2801963B1|1999-12-02|1999-12-02|METHOD AND INSTALLATION FOR AIR SEPARATION BY CRYOGENIC DISTILLATION|
    FR9915208||1999-12-02||
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