• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:

    公开号:SU786850A3
    申请号:SU782640056
    申请日:1978-07-24
    公开日:1980-12-07
    发明作者:Зайто Юнихи；Кадаматсу Акио；Куме Тойохико；Тсубой Шинихи
    申请人:Нихон Токушу Нойяку Зейцо К.К. (Фирма)；
    IPC主号:
    专利说明:

    (54) INSECTICIDOACARICIDONEMATOCIDE COMPOSITION
    The invention relates to the field of agriculture, in particular to means for the destruction of pests. Insecticides are known — arbitrary thio- and dithiophosphoric acids and. However, when spraying them with water emulsions, some growth in wheat occurs. Known insecticidal composition,. containing phosphoric acid derivatives and filler | 2. The purpose of the invention is to enhance its activity. The goal is achieved by the fact that, as derivatives of phosphoric acid, 5 lots contain a compound of the formula P-0- (iH.-CY, (l) "2 Y where R is C -Co-alkyl; hLT f. -C-alC -C-alkyl or coxyl; hydrogen, halogenalkyl with 25 carbon atoms 1-8 or C-C-alkoxy; halogen;
    moreover, the content of the active principle in the agent is 0.1-95.0 wt.%. 30 va g with pg m M p
    where R ,, X, Y, and Hat have the indicated Compounds of formula (I) are obtained by the action of a) a common thrombolyne halide mule: p-Hal, (0) R and Rjj have the indicated value. On E, it is halogen, alcohol, or an alcoholate of the common Mula K-0-CH-5-Y, e X and Y have the indicated value, hydrogen or alkali metal, or b) the total piule thiophosphoryl halide. P-O-CH-O-Y, () meaning, with an alcohol or alcohol of the general formula M-O-RI, (v) (V) where M has the indicated meaning, c) a phosphite of the general formula “lO. P-O-CH-C-Y, (1) where R, X and Y have the indicated value, with a sulfenyl halide of the general formula R, j-HaC {VI I) where R and Hal have the indicated value. As the thiophosphoryl halide of the general formula (i), for example, o-methyl - $ - n-propylphosphoric chloride thioate, O-ethyl-5-n-propylphosphoric chloride thioate can be mentioned. O, 5-di-n-propilfosforhloridtioat, O-ethyl-5-n-butilfosforhloridtioat, O-ethyl-5-isobutyl fosforhloridtioat, O-ethyl-S-sec-Bu tilfosforhloridtioat, O-ethyl-5-Meto sietilfosforhloridtioat, O -ethyl-S-ethoxyethylphosphoric chloride, O-these -S-n-propoxyphosphoric chloride, 0-ethyl-5-isopropoxyethylphosphoric chloride, O-ethyl-S-n-butoxyethylphosphoric fortioride and the corresponding bromides. As alcohol or alcohol of the general formula (III), for example, 2,2,2-trifluoroethanol, 2,2, -trich ortho-ethanol, 1,1,1,3,3,3-hexafluoro-2-propanol, .1,1,1,3,3,3-hexachlor-2-propanol and 2-ethoxy-2,2,2 trifluoroethanol, as well as sodium or potassium salts of these alcohols. If O-methyl-5-n-propylphos forchloride thioate and 2,2,2-trifluoroethano are used as starting compounds, then the reaction according to option a) proceeds as follows: CHaO 9 P-Ci + BUT -HN CHjCH2 lH2 $ НlO o PO-dHj-CF + H CHjilMjCHj as the thiophosphoryl halide of the general formula {IV) can be mentioned, for example, O-2,2,2-trifluoroethyl-5-nPE pilosorphlorothioate, 0-2,2,2-trichloroethyl-5-n-propylphosphoric chloride, 0-1,1,1,3,3, 3-hexafluoro-2-propyl-3-n-propylphosphoric chloro-thioate O-1,1,1,3,3,3-hexachlor-2-propyl-5-n-propyl-phosphoro-chloro-thioate , O-2 / 2,2-trifluoroethyl-5-n-butylphosphoric chloride, 2.2-trichloroethyl-5- -buty phosphorchloridothioate, 0-1,1,1,1,3,3,3-hexafluoro-2-propyl-S-n-butylphosphoric chlorothioate, O-2,2,2-triftrretil-8-isobutylphosphoric thioate, 0-1, 1 , 1,3,3, 3-hexafluoro-2-propyl-S-sec-butylphosphoric chloride, O-2, 2,2-trifluoroethyl-5-sec-2, Butylphosphoric chloride, O-2,2,2-trifluoroethyl-5-2 -methoxyethylphosphoric thioate, 0-2,2,2-trifluoroethyl-5-2-ethoxyethylphosphoric thioate, O-2,2,2-trichloroethyl-5-2-ethoxyethylphosphoric thioate, 0-1,1,1,3,3,3-hexafluoro -2-propyl-5-2-ethoxyethylphosphoric chloride, O2, 2,2-trifluoroethyl-5- {2-n-propoxyethyl) -phosphoric chloride, 0-2,2,2-trifluoroethyl-5.-2-isopropoxyethylphos orhloridtioat, O-2,2,2-trichloroethyl-S-2-izopropoksietilfosforhloridtioat, 0-2,2,2-trifluoroethyl-5- (2-n-butoxyethyl) -fosforhloridtioat and the corresponding bromides. As alcohol or alcohol of the general formula (V), for example, methanol, ethanol and n-propanol and sodium or potassium salts of these alcohols can be mentioned. If O-2,2,2-trifluoroethyl-S-n-butylphosphoric chloride thioate and ethanol are used as starting compounds, then the reaction according to variant b) proceeds as follows: p-o-CngCH3 + CgIdOH1 ZH5 (; H2 1H2CH2 J2 "5M / P-O-Jnp-SG-f Hdl as a phosphite of the general formula (VI), for example, O-methyl-.-O-2,2,2-trifluoroethyl phosphite, O-methyl-O-2, 2, 2-trichloroethylphosphine, O-ethyl-O-1, 1,1,3,3, 3-hexafluoro-2-propyl phosphite, O-ethyl-0-1,1,1,3,3,3-hexachloro- 2-propylphosphite., O-ethyl-O-1-e hydroxy-2, 2,2-trifluoroethyl phosphite, O-n-propyl-O-2, 2,2-trifluoroethyl phosphite, O-ethyl-O-2, 2 , 2-trifluoroethylphosphite and 0-ethyl-O-2, 2,2-trichloroet ylfositelnuyu can be obtained by the interaction of the corresponding disulfide with chlorine, bromine, sulfuryl chloride or sulfuryl bromide. If O-methyl-O-2,2,2-trichloroethyl phosphite and 1-butanesulfenyl chloride are used as starting compounds, the reaction according to variant c) proceeds as follows; / P-OH + (H2 5H2 5I2 "H22C1 dCljCHjO" 2H, "J P-O-CH. CH, CH2C1G2; H2 $ Reactions a) -c) can be carried out in the presence of an acid binding agent, which For example, an alkali metal hydroxide, carbonate, bicarbonate, and alcoholate can be mentioned, as well as tertiary amines, for example, triethylamine, diethylane pin, or pyridine. . According to options a) and b), the desired product can be obtained in good yield and with high purity and without the use of an acid binding agent, provided that the tiophosphoryl halide of the total (II) or (I) be reacted with an alkali metal alcohol of the general formula (III ) or (V). Reactions a) to c) are preferably carried out in a solvent or diluent medium. Examples of such solvents or diluents are water and inert organic solution, such as aliphatic, alicyclic and aromatic hydrocarbons (which can be chlorinated), for example hexane, cyclohexane, petroleum ether, ligroin, benzene, toluene, xylene, chlorides methylene, chloroform, carbon tetrachloride, ethylene chloride, trichlorethylene and chlorobenzene; ethers, such as diethyl ether, methyl alkyl ether, diisopropyl ether, dibutyl ether, dioxane and tetrahydrofuran; ketones, such as acetone, methyl ethyl ketone, methyl isopropyl ketone and methyl isobutyl ketone; nitriles such as acetonitrile, propionitrile and acrylonitrile; alcohols, such as methanol, ethanol, isopropanol, tert-butanol and ethylene glycol; esters, such as ethyl acetate; acid amides, such as dimethylformamide and dimethylacetamide; sulfones and sulphoxides, such as dimethyl sulphoxide and dimethyl sulfone; organic bases, such as pyridine. The temperature of the reactions a) to c) can vary widely. Usually it is operated at a temperature from to the boiling point of the reaction mixture, preferably at a temperature from 0 to. Reactions can be carried out at atmospheric, elevated or reduced pressure. The proposed active principles are converted into conventional preparations, such as, for example, solutions, emulsions, suspensions, powders, pastes, foams, granules, aerosols, and microcapsules. They are prepared in a known manner, for example, by mixing the active principle with diluents, i.e. liquid, solid or liquefied gaseous diluents or fillers, if necessary with the use of surfactants, i.e. emulsifiers and / or dispersants and / or foaming agents. In the case of using water as a diluent, for example, organic solvents can be used as auxiliary. Aromatic hydrocarbons such as xylene, toluene, benzene or alkylnaphthalenes, chlorinated aromatic or aliphatic hydrocarbons, such as xPorbenzenes, ethylene chloride and methylene chloride, aliphatic hydrocarbons, such as are used as liquid diluents or fillers, in particular solvents. cyclohexane or paraffins, for example petroleum fractions, alcohols, such as butaiol or glycol, as well as their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, highly polar solvents, such as dimethylformamide and dimethyl sulfoxide, as well as water Liquefied gaseous diluents or fillers are understood to be liquids that are gaseous at normal temperature and at normal pressure, for example working gases, such as dichlorodifluoromethane or trichlorofluoromethane. As solid fillers, preferably crushed natural minerals, such as kaolin, alumina, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and crushed synthetic minerals, such as highly dispersed silicic acid, alumina and silicates, are used. As emulsifiers and foaming agents, nonionic and anionic emulsifiers can be mentioned, such as polyoxyethylene fatty acid esters, fatty polyoxyethylene fatty alcohol ethers, for example alkyl aryl glycol glycol ethers, alkyl sulfonates, aryl sulfonates, alkyl sulfates, and also the hydrolysates for the hydrolysates, alkyl sulfates, arylsulfonates, alkyl sulfates, as well as protein hydrolysates, alkyl sulfates, arylsulfonates, alkyl sulfates, as well as protein hydrolysates. , for example, lignin, spent sulphite liquor and methylcellulose. Preparations may also contain binders, such as carboxymethyl cellulose, and natural and synthetic polymers in the form of powder, granules or latexes, such as, for example, poly vinyl alcohol and polyvinyl acetate.
    Preparations may also contain inorganic or organic colorants, as well as micronutrient substances, such as, for example, salts of iron, arganese, boron, copper, cobalt, moibden, and zinc.
    The concentration of the active principle of the ready-to-use preparations can vary widely, preferably 0.005 to 10% by weight.
    The composition according to the measurement is applied in an amount of 0.03-10 kg / ha.
    Example 1. By grinding and mixing 15 parts by weight the current beginning, 80. weight.h. mixture (1: 5) diatomaceous earth with kaolin and 5 weight.h. a simple polyoxyethylene alkyl phenyl ether, a wettable powder is prepared which can be diluted with water to the desired concentration before being applied to insects, mites, nematodes and / or their biotope.
    Example 2. By grinding and mixing (parts by weight) 30 active agents, 30 xylene, 30 methylnaphtaglin and 10 polyoxyethylene alkylphenyl ether, an emulsifiable concentrate is prepared, which can be diluted with water to the desired concentration before application to insects, nematodes, and mites / or their biotope.
    Example 3. By fine grinding and mixing 0.1 parts by weight deist. beginning and 99.9 weight.h. Mixtures (1: 3) of talc with clay prepare a sprayed preparation that is sprayed onto insects, mites, nematodes and / or their biotope.
    Example 4. By fine grinding and mixing 1.5 parts by weight deistuing beginning, 0.5 weight.h. isopropyl hydrogen phosphate and 98 weight.h. Mixtures (1: 3) of talc with clay prepare a sprayed preparation that is sprayed onto insects, mites, nematodes and / or their biotope.
    For example 5. 10 weight.h. the current beginning is mixed with 10 weight.h. bentonite, 78 weight.h. a mixture of (1: 3) talc with clay and 2 parts by weight ligninsulfonate. 25 parts by weight are added to the mixture. water, thoroughly mixed, and then passed through an extrusion granulator to obtain granules of 350-700 µm in size, which are dried at 40-50 0. The granules thus obtained are applied to insects, mites, nematodes and / or their biotope.
    Example 6. 95 weight.h. powdered clay with a size of 0.2-2 mm served in a rotary mixer. After switching on the mixer, 5 parts by weight are sprayed onto the particles. solution of the active principle in an organic solvent.
    The resulting granules are dried at 40-50s and applied to insects, mites, nematodes and / or their biotope.
    Example 7. 0.1 weight.h. the current beginning is intensively mixed with 20 weight.h. a high boil of gold apiOMaic compounds and 79.9 parts by weight. kerosene. An oil preparation is obtained that is applied to insects, mites, nematodes, and / or their biotope.
    Example 8. 95 weight.h. Actually, they are mixed with 1 wt.h. polyethylene oxide and 4 weight.h. the aromatic oil fraction and the resulting preparation are applied to insects, mites, nematodes, and / or their biotope in an ultra-small volume.
    Tests according to examples 1-8 showed that the degree of killing at the concentration of activities of the leach (ml) 1000, 300, 100 and 10 is equal to 100%.
    Example 9 (control). Tested compounds
    MsO fl
    / p-o-dHdgHg
    "JjHsoJ Pti2H: $ 5 C2H40
    on the larvae of Spodoptera gitura, CapEo sobruchus chinensis, Nephotettix. cinct i.ceps, Musca domestica, Tetranychus teParius, Panonychus spp., 5 Acarus spp., B ateBBa, germanica,
    CuEex tgitaeniorhynchus, Meloidogyne i ncog n i ta ac g i i ta,
    Tests have shown that these compounds did not cause death or Q caused death, but at a concentration of 1000.
    Experimental data on the testing of compounds (I) showed that the composition according to the invention acts as an acaricide, nematocide, insecticide.
    权利要求:
    Claims (1)
    [1]
    1. Melnikov N.N. and Baskakov Yu.A.k. 45 b 9/36, 1974 (prototype).
    类似技术:
    公开号 | 公开日 | 专利标题
    Dixon1956|Elimination reaction of fluoroölefins with organolithium compounds
    SU786850A3|1980-12-07|Insecticidoacariocidonematocide composition
    EP0189960B1|1991-04-24|Novel insecticidal 1,3-thiazole derivatives
    CA1224480A|1987-07-21|Carbamate compounds, and their production and use
    GB842306A|1960-07-27|Thiophosphonic acid esters
    US4190653A|1980-02-26|Pesticidally active O-ethyl-S-N-propyl-O-2,2,2-trihaloethyl-phosphoro|thiolates
    GB753766A|1956-08-01|Improvements in or relating to carbamic acid esters
    GB947485A|1964-01-22|Improvements in or relating to heterocyclic amidophosphate compounds and combating noxious organisms thereby
    JPH0314567A|1991-01-23|Herbicidal benzylsulfonamides
    US2668841A|1954-02-09|O-ethyl o-| methanephosphonate
    CA1040642A|1978-10-17|Substituted oxirane compounds
    JP2003113168A|2003-04-18|Nematocidal trifluorobutene derivative
    US2437527A|1948-03-09|Insecticidal compositions from halocaprylphenoxyacetic acid
    US3360432A|1967-12-26|Chlorophenylcyclopropanecar-boxamide mite ovicides
    US3658873A|1972-04-25|Methylene-bis-|-4-phenylsulfonic acid esters
    SU547168A3|1977-02-15|Nematocide
    GB1081270A|1967-08-31|Dithiol-phosphoric acid esters
    GB900557A|1962-07-11|New mono-and di-thiophosphoric esters, and processes for their manufacture and compositions containing them
    US3859441A|1975-01-07|Anti-arthropodal cyclic dithioketals of glyoxyloyl halide 1-phenylhydrazones
    US4526609A|1985-07-02|Phenoxy phenoxy propionic hydrazides
    US2929834A|1960-03-22|Thiophosphoric acid esters and their production
    US3634557A|1972-01-11|Oxime thiophosphates
    US3719467A|1973-03-06|Herbicidal 3-|crotonamides
    CA1097373A|1981-03-10|Algicidal and fungicidal sulfones
    PL99605B1|1978-07-31|A WORMHOUSE
    同族专利:
    公开号 | 公开日
    IT7825985D0|1978-07-21|
    JPS5424829A|1979-02-24|
    DE2860061D1|1980-11-13|
    PT68318A|1978-08-01|
    BR7803517A|1979-03-20|
    PL114583B1|1981-02-28|
    IL55198D0|1978-09-29|
    ATA540178A|1980-05-15|
    ZA784182B|1979-07-25|
    EP0000528A1|1979-02-07|
    HU182737B|1984-03-28|
    PL114565B1|1981-02-28|
    OA06034A|1981-06-30|
    AT360276B|1980-12-29|
    US4189476A|1980-02-19|
    CS199738B2|1980-07-31|
    DD138878A5|1979-11-28|
    JPS6021159B2|1985-05-25|
    EG13377A|1982-09-30|
    DK328078A|1979-01-26|
    PL119038B1|1981-11-30|
    AU517310B2|1981-07-23|
    EP0000528B1|1980-07-23|
    AR220719A1|1980-11-28|
    CA1110650A|1981-10-13|
    TR19961A|1980-05-16|
    IT1099576B|1985-09-18|
    PL208574A1|1980-01-02|
    IL55198A|1982-12-31|
    ES471989A1|1979-10-01|
    ES479024A1|1979-07-01|
    AU3828578A|1980-01-31|
    ES479025A1|1979-07-01|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    US3184377A|1961-12-12|1965-05-18|Chemagro Corp|Method of killing nematodes with thiophosphates|
    DD107581A1|1973-05-02|1974-08-12|
    JPS5926634B2|1976-07-27|1984-06-29|Nihon Tokushu Noyaku Seizo Kk|JPS5788414A|1980-11-21|1982-06-02|Seiko Epson Corp|Alignment device|
    US4673664A|1985-10-07|1987-06-16|American Cyanamid Company|Shape for extruded catalyst support particles and catalysts|
    DE3910662A1|1989-04-03|1990-10-04|Bayer Ag|THIOPHOSPHORIC ACID FLUORALKYLESTER|
    DE4110972A1|1991-04-05|1992-10-08|Bayer Ag|O--S-ALKYL-THIOPHOSPHORACID ESTER, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE AS A PEST CONTROL|
    US6620362B1|2002-06-14|2003-09-16|Nan Ya Plastics Corporation|Method of manufacturing polyester fiber having improved light fastness|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    JP52088352A|JPS6021159B2|1977-07-25|1977-07-25|
    [返回顶部]