• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    The invention relates to copolyamide based hot melts for application to flat materials; in particular, padding fabrics, for outerwear such as woven, knitted or nonwoven fabrics. For coating outerwear padding fabrics, most often used: with copolyamides. The invention allows to increase the adhesion and strength when gluing textile materials due to the use in the composition of the hot melt consisting of a copolyamide and the target additive, which is used as behenic acid in an amount of 0.3-14.6 wt.%. Table 4. Table of designation refers to hot-melt adhesives based on copolymers for application to flat materials, in particular, cushioning fabrics, for outerwear such as woven, knitted or nonwoven fabrics. For coating over cushioning fabrics for outerwear, most often copolyamides, which have a low melting range. As a rule, hot melts are applied in the form of dots or in the form of pores on the engraving rollers. —In order to provide the required durability when cleaning and washing the adhesive joint between the gasket and top material, a minimum amount of hot melt is required, which, among other things, also depends on the raster location of the points, the gasket design, the gasket finish, the drying and sintering conditions and not the last of the kind and composition of the adhesive mass. Hot-melt glue affects the neck (quality by touch) of a joint by hot-sealing, the greater its quantity, so it is impossible to avoid a known increase in joint stiffness to a greater or lesser extent. The modern comfort of clothing requires more padding fabrics, the effect of increased rigidity which is as small as possible. The garment industry needs gaskets that only affect the shape retention and stabilization of the textile bond, but do not cause any compaction of the neck. The aim of the invention is to increase adhesion and strength when gluing textile materials. Example 1. Making a hot-melt powder applied proceeds as follows .4iffeel o ^ > & 00
    公开号:SU1715207A3
    申请号:SU843794618
    申请日:1984-10-01
    公开日:1992-02-23
    发明作者:Хефеле Йозеф
    申请人:Куфнер Текстильверке Гмбх (Фирма)；
    IPC主号:
    专利说明:

    100 wt.h. copolyamide 6 / 6-6 / 12 160 µm, melting point about 112 ° C, melting index 160 ° C about 25 g / 10 min and 2 wt.h. Behenic acid, finely ground, less than 20 microns, is pre-mixed in a high-speed mixer and then further mixed by sieving. The mixture is kept in a closed vessel for 24 hours at 90 ° C. After stirring, a further 100 parts by weight are added. copolyamide powder 6 / 6-6 / 12 and stirred again in a high-speed mixer. This final blend with a proportion of behenic acid of about 1% is used for powder coating in a powder spot method, for example, as follows.
    Engraved valiums with 16 mesh (depressions per inch) are used, on which hemispherical stamping (engraved) grooves are evenly spaced so that the midpoints of the hemispheres are respectively in the corners of equilateral triangles with a distance between the midpoints of the hemispheres of 1.6 mm. The immersion depth of the engraving tool is 0.31 mm and the diameter of the engraved stamp on the surface of the roller is 0.75 mm. Knitted fabric consisting of a loop-forming chain of 44 decitex polyamide complex yarns and 13 filament yarns, 24 warp threads per inch and weft yarn of viscose staple fiber N 20 of viscose staple fibers inserted into the knit loops 4.0 cm long and 1.7 decitex fiber thickness. The weft density is 120 weft threads per 10 cm. One weft thread is laid in each loop. The warp threads, which form the loops, pass in each case straight through 3 loops and then the next loop is shifted to the side by one looped row left or right. Knitted fabric before covering from the side of the base is combed, washed and non-shrinkingly finished.
    When comparing the bonding strength between cti / schonizirovanny poplinovy material for outerwear and carrier fabric, untreated copolybmide {$ spoliamidom, processed in our own with the invention, get the hpc shown in table. 1. A steel blade with a 0.2 mm thick blade is applied to the blade. T € MfTfp3typa engraving rollers composition tt C, temperature heated rollers KOS 240 C, coating speed 10 M / MWH. The conditions of fixation: the temperature of the upper plate, 165 ° C, the temperature of the lower plate, 100 ° C, pressure 300 Pa / cm, fixed for 15 s on siliconized poplin.
    As can be seen from the table, with the addition of 1% behenic acid with coating weight, KOTOpbfi is reduced from 17.3 to 13.4 g / m, practically the same bonding strength is achieved with only small deviations. The added amount of behenic acid in the case of powder spot coatings should be no higher than 2.5%, because the weight of the applied coating decreases due to the addition of behenic acid. This reduction is only desirable to a level at which it does not go below the minimum strength limit. Reducing the amount of coating applied gives the desired softer
    0 neck
    EXAMPLE 2 A printable raw paste, which, after drying and sintering, leaves on the printed flat material the corresponding invention of the mass of hot melt, consists, for example, and is able to spread pasty.
    V mixture of the following components, wt.h: water 100; Behenic acid 11; ammonium alkali 10% polyacrylic acid ammonium solution 20 (pH 11); deoxidizer (for example, L- (2-hydroxyprogyl) amide benzenesulfonic acid 10; copolyamide powder from O to 80 μm 100: highly dispersed magnesium stearate 1; polystyrene oxide,
    5 Molecular weight 5x10 0.1: butanol 0.1.
    In the screen printing method, the paste thus prepared is applied to a knitted fabric from polyamide multifilament yarn 44/14 as a base and from yarn N 20 mz viscose staple fiber as weft material using an internal squeegee using a round mesh stencil with an 11 mesh raster. 20 g / m (dry weight) and dried
    5 and sintered at 135 ° C for 4 minutes. After sintering, a hot-melt hot melt is obtained, which contains about 10% behenic acid.
    Comparison with a paste coating such
    The same composition, which instead of behenic acid contains the same amount of stearic acid, is given in Table. 2, in which: adhesion values are given in p / 5 cm on various fabrics for the upper
    5 clothes. The ramming (fixing) was performed at a temperature of the upper plate of 165 ° C, the temperature of the bottom plate of the SO, the pressure of 300 Pa / cm, the fixing time of 15 s. The adhesion was measured 24 hours after fixation and additionally after
    one dry cleaning. In both types of hotmelt, the coating weight was the same.
    The same results are obtained on dried samples after the washing process at 40 ° C in a domestic washing machine.
    As you can see from the table. 2, directly in the case of fabrics for outerwear, which are particularly difficult to unclean, an increase in the adhesion strength is clearly expressed. Here the increase may be more than 50%.
    PRI me R 3. Mixed in a high-speed mixer, 100 mas. Hours, copolyamide 6 / 6-6 / 12 with a particle size of 0-160 µm, melting point from 112 ° C, melt index at 160 ° C from 25 g / 10 min, and 1 wt.h. part of behenic acid, finely milled to 20 microns. Then the mass is mixed by sieving.
    The resulting mixture was kept in a thermostat at 90 ° C for 24 h, then another 100 wt.h. copolyamide powder 6./6-6/12 and again mixed in a high-speed mixer. The obtained target composition with a content of behenic acid of 0.5% is used as a powder for coating in a powder spot method as in Example 1.
    PRI me R 4. The original paste consists of a free-flowing mixture of the following components, parts by weight: water 160; begen acid 15; ammonia 10% ammonium polyacrylate solution 20, pH 11; 6 / 6-6 / 12 copolyamide (powder 0-80 microns) 100; fine magnesium stearate 1; polyethylene oxide (mol. weight 5 -10) 0.1; butane ol 0,1.
    This paste is processed as in Example 2.
    Example 5. 100 wt.h. copolyamide powder 0-160 μm, obtained from compounds. nantov, mol: adipic acid 1.06; 1-amino-3-aminomethyl-3,5,5-trimethylcyclohexane 0.60; dodecamethylenediamine 0.20; 2,4,4-trimethylhexamethylenediamine 0.20; caprolactam 2.00; aminoundecanoic acid 4.00 and 0.6 wt.h. behenic acid, finely ground at 20 µm, is pre-mixed in a high-speed mixer and then further mixed by sieving. The mixture is carried out for 24 hours, annealed at 90 ° C. After the annealing process, another 100 parts by weight are added. copolyamide powder 0160 µm OF; the aforementioned components and mixed again in a high-speed mixer. The final mixture with a fraction of about 0.3% behenic acid is used.
    as in Example 1 for a point coating powder.
    EXAMPLE 6 Analogously to Example 5, a calcined mixture of 100 parts by weight was prepared. 5 copolyamide powder 0-160 μm, prepared from the following components, mol: adipic acid 0.70; azelaic acid 0.30; 1-amino-3-aminomethyl-3, 5,5-trimethylcyclohexane, 1.08;
    10 caprolactam 1.00; aminoundecanoic acid and finely ground behenic acid with a particle size of 20 μm in an amount of 1 wt.h. 5.00 After calcination (annealing), the next 100 wt.h. such a
    15 same copolymer powder. The final mixture has a proportion of behenic acid of 0.5% and is used analogously to example 1 for spot coating powder.
    Example 7. Analogously to example 5
    0 preparing a calcined mixture of 100 wt.h. copolyamide powder 0-160 μm, obtained from the following components, mol: azelaic acid 1.04; 1,3-bisaminomethylcyclohexane 0.30; 2-methylhexamethylenediamine
    5 0.30; 3,3-dimethylhexamethylenediamine 0.40; caprolactam 5,20 and 1 wt.h. of behenic acid finely ground to 20 microns, and after calcination (annealing), the next 100 wt.h. the same copolyamide powder. The final mixture has a proportion of behenic acid of 0.5% and is used analogously to example 1 for spot coating powder.
    Example Analogously to example 5
    5 preparing a calcined mixture of 100 wt.h. copolyamide powder 0-160 μm, prepared from the following components, mol: adipic acid 1.06; 1-amino-Zaminomethyl-3, 5,5-trimethylcyclohexane
    0 0.60; dodecamethylenediamine 0.20; 2,4,4-trimethylhexamethylenediamine 0.20; caprolactam 2.00; aminoundecanoic acid 4.00 and. 1.5 wt.h. behenic acid, finely divided to 20 microns, after calcination (from -
    5 gig) add the following 100 wt.h. the same copolyamide powder. The final blend has a 0.75% POWER of behenic acid and is used, as in Example 1, for spot coating with a powder.
    0П р and мер 9. Analogously to example 5
    preparing a calcined mixture of 100 wt.h. copolyamide powder 0-160 µm, obtained from the following components, g: dimerized fatty acid 4019.0,
    5 hexamethylenediamine 812.2; caprolactam 2415.6; laurinectam 4831.2; stearic acid 120.8 and 1.5 wt.h. of behenic acid, finely ground to 20 µm, after calcination (annealing), the next 100 wt. the same copolyamide powder. The final mixture has a proportion of behenic acid of 0.75% and is used analogously to example 1 for powder coating with a point method.
    PRI me R 10. The original paste consists of a flowing paste-like mixture of the following components, parts by weight: water 180, behenic acid 18; 10% ammonium alkaline solution of ammonium polyacrylate (pH 11) 20: copolyamide powder 0-80 μm, prepared from the components of example 5, 100; fine magnesium stearate 1; polyethylene oxide with mol. weight 5x10 0.1; butanol 0.1.
    The pasty mixture is processed analogously to example 2. The dry mass of this paste has a proportion of behenic acid of 14.6%.
    Example 11. The original paste consists of a fluid pasty mixture of the following components, parts by weight: water 150; Behenic acid 15; 10% ammonium alkali ammonium polyacrylate solution (pH 11) 20; copolyamide powder 0-80 μm, prepared from the components of example 6, 100; fine magnesium stearate 1; polyethylene oxide with mol. weight 5x10 0.1; butanol 0.1. This pasty mixture is processed analogously to example 2. The content of behenic acid in their dry weight is 12.7%.
    PRI me R 12. The original paste consists of a flowable paste-like mixture of the following components, parts by weight: water 150; Behenic acid 12; 10% ammonium alkaline solution of ammonium polyacrylate (pH 11) 20; copolyamide powder 0-80 microns prepared from the components of the example
    7, 100; fine magnesium stearate 1; polyethylene oxide with mol. weight 5x10® 0.1; butenol 0,1,
    The pasty mixture is processed analogously to example 2. The content of behenic acid in the dry weight is 10.40%.
    In tab. Tables 3 and 4 show the coating conditions. The fixing conditions are the same as in table. one.
    权利要求:
    Claims (1)
    [1]
    Invention Thermoglue for application to textile materials, including copolyamide and a modifying additive, is made in that, in order to increase adhesion and strength when gluing textile materials, it contains behenic acid in the amount of 0 ,, 6 May. % of the composition.
    Table
    类似技术:
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    同族专利:
    公开号 | 公开日
    PL143046B1|1988-01-30|
    DE3336417A1|1985-04-18|
    MX162911B|1991-07-08|
    US4602057A|1986-07-22|
    CN1004209B|1989-05-17|
    HU201793B|1990-12-28|
    DE3464633D1|1987-08-13|
    CN85101541A|1987-01-24|
    JPH0380828B2|1991-12-26|
    AT28212T|1987-07-15|
    EP0150262B1|1987-07-08|
    HUT36847A|1985-10-28|
    JPS6096677A|1985-05-30|
    EP0150262A1|1985-08-07|
    PL249887A1|1985-07-30|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    RU2455912C2|2003-12-20|2012-07-20|ЛлойдЛимитед|Body protection device and method of its production|CA1170118A|1980-07-08|1984-07-03|Gerald T. Downing|Lift-off element|
    JPS5782581A|1980-11-04|1982-05-24|Asahi Chemical Ind|Heat adhesive core cloth|
    US4452931A|1982-03-30|1984-06-05|Ube Industries, Ltd.|Flame-retardant polyamide resin composition|ES2078418T3|1991-12-17|1995-12-16|Kufner Textilwerke Gmbh|COATED SURFACE PRINT.|
    JPH0725307U|1994-09-14|1995-05-12|自動車電機工業株式会社|Actuator|
    CN109640976A|2016-08-22|2019-04-16|救急药品工业株式会社|Adhesive preparation|
    CN110982256B|2019-11-26|2021-10-26|金旸（厦门）新材料科技有限公司|Anti-yellowing high-thermal-conductivity nylon composite material and preparation method thereof|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    DE19833336417|DE3336417A1|1983-10-06|1983-10-06|HOT SEAL ADHESIVE FOR COATING SURFACES, ESPECIALLY INSERTS, AND METHOD FOR THE PRODUCTION THEREOF|
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