• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    Concentrated emulsions, adaptable to use as pour point improvers, of (1) copolymers of ethylene and a vinyl ester of a C1-C24-carboxylic acid and/or (2) polyalkyl(meth)acrylic acid ester polymers in a liquid carrier medium which does not dissolve said polymers, said emulsions additionally containing, as an emulsifier, a graft- or block-copolymer of the formula A-Y, wherein A is a segment of a copolymer of ethylene and a vinyl ester of a C1-C24-carboxylic acid (corresponding to polymer P1) or of a polymer of esters of acrylic acid and/or methacrylic acid with a C1-C20-alkanol, wherein Y is at least one segment obtained by the polymerization of vinyl monomers which are predominantly esters of acrylic acid or methacrylic acid with a C1-C40-alkanol, and wherein the carrier medium is capable of dissolving segments Y; oils containing such emulsions as pour point improvers.
    公开号:SU1690546A3
    申请号:SU874202400
    申请日:1987-04-17
    公开日:1991-11-07
    发明作者:Мюллер Михаэль；Пенневисс Хорст；Гебхардт Юрген
    申请人:Рем Гмбх (Фирма)；
    IPC主号:
    专利说明:

    isobutylperoctate. In an atmosphere of carbon dioxide at 100 ° C, a mixture of 565 g of isodecyl methacrylate and 10.17 g of tert-butyl peroctoate is added over 3.5 hours. After 90 minutes from the end of the addition, the resulting 70% solution is diluted to 30% by adding 1468 g of dimethyl phthalate and 928 g of dibutyl phthalate. Then, an additional 2.4 g of tert-butyl peroctoate is added. The total polymerization time is 20 hours. A weakly viscous, viscous solution is obtained containing 30% by weight of the graft copolymer. The mass ratio of the mixture of methacrylic acid esters and ethylene copolymer with vinyl acetate is 1: 0.94.
    Getting additive
    228 g of the solution of the obtained graft copolymer, 191.6 g of copolymer of ethylene with vinyl acetate (28 wt.% Of vinyl acetate, mol.m., 20,000), 115.2 g of dimethyl phthalate and 115.2 g dibutyl phthalate and at 80 ° C in an atmosphere of carbon dioxide, the mixture is stirred at 200 rpm for 16 hours. A whitish-cloudy stable emulsion of the following composition is obtained, May. %: ethylene-vinyl acetate copolymer 29.5; grafted polymer 10.5; liquid carrier 60. Here, the weight ratio of said dialkyl phthalates is 1: 1, and the mass ratio of the solution of the graft copolymer, ethylene vinyl acetate copolymer and liquid carrier is 1: 0.84: 1.01.
    Particle size 0.5-2 microns; viscosity 570 mm2 / s at 50 ° C and 9000 mm2 / s at 20 ° C; solidification point -20 ° C.
    PRI mme R 2. Obtaining a graft copolymer.
    In a four-liter flask with a capacity of 2 liters, equipped with a stirrer, a reflux condenser, and an internal thermometer, 120 g of a copolymer of ethylene with vinyl acetate (28% by weight of vinyl acetate, mol.m. 20000) was dissolved in 400 g of iododecanol at 100 ° C. To this solution, 43.4 g of isodecyl methacrylate, 14.5 g of 2-hydroxyethyl methacrylate and 1.6 g of tert-butyl peroctoate are added. In an atmosphere of carbon dioxide at 90 ° C, a mixture of 316.7 g of isodecyl methacrylate, 105.5 g of 2-hydroxyethyl methacrylate and 2.53 g of tert-butyl peroctoate is added over 3.5 hours. 2 hours after the end of the addition, an additional 0.96 g of tert-butyl peroctoate is added. The total duration of limerization is 20 hours. A cloudy, viscous solution is obtained containing 60% by weight of the graft copolymer. The mass ratio of the mixture of methacrylic acid esters and ethylene copolymer with vinyl acetate is 1: 2.07.
    Getting additive
    108.3 g of a solution of the obtained graft copolymer, 247 g of a copolymer of ethylene with vinyl acetate (28 wt.% Of vinyl acetate, mol.m. 20000), 193.3 g of isodecanol and 101.4 g diethylene glycol and the mixture is stirred for 16 hours at 70 ° C and 200 rpm. A whitish-cloudy, stable emulsion of the following composition is obtained, wt.%: Ethylene copolymer with vinyl acetate 38; grafted polymer 10; liquid
    5 carrier 52. In this case, the mass ratio of isodecanol and diethylene glycol in the mixture is 1.9: 1, and the mass ratio of the solution of the graft copolymer, copolymer of ethylene with vinyl acetate and liquid
    0 media is 1: 2.28: 2.72.
    Particle size 2-10 microns; viscosity 4100 mm2 / s at 20 ° С and 4500 mm2 / s at 40 ° С; solidification point -30 ° C
    PRI me R 3. Getting vaccinated
    5 copolymer.
    In the manner described in Example 2, 100 g of ethylene-vinyl acetate copolymer (28% by weight of vinyl acetate, mol.m. 20,000) are dissolved at 500 ° C in 500 g of isodecanol. 50 g of butyl methacrylate, 16.7 g and 2-hydroxyethyl methacrylate and 2.1 g of tert-butyl peroctoate are then added at 90 ° C for 3 1/2 hours, after which 250 g of butyl methacrylate are added, 83.4 g of 2- hydroxyethyl methacrylate and 3.3 g of tert-butyl peroctoate. After 2 hours from the end of the addition, 0.8 g of tert-butyl peroctoate is added. The total polymerization time is 20 hours. A cloudy, viscous solution is obtained containing 50% by weight of the graft copolymer. The mass ratio of the mixture of methacrylic acid esters and ethylene copolymer with vinyl acetate is 1: 1.5.
    five
    Getting additive 130.3 g of the solution of the copolymer obtained, 247 g of a copolymer of ethylene with vinyl acetate (28 wt.% Of vinyl acetate, mol.m. 20,000),
    0 171.4 g of isodecanol and 101.4 g of diethylene glycol are fed into the container and are stirred in the manner described in example 1 at 70 ° C. Get whitish-turbid emulsion of the following composition, wt.%: A copolymer of ethyl5 on vinyl acetate 38; grafted polymer 10; liquid carrier 52.
    The mass ratio of isodecanol and diethylene glycol in the mixture is 1.69: 1, and the mass ratio of the solution of the graft copolymer, ethylene copolymer
    with vinyl acetate and liquid carrier is 1: 1.89.2.09.
    Particle size 2-10 microns; viscosity 4600 mm2 / s at 20 ° С and 4700 mm2 / s at 40 ° С; solidification point -32 ° C.
    PRI me R 4. Obtaining a graft copolymer.
    In a four-liter flask with a capacity of 4 liters, equipped with a stirrer, a reflux condenser, and an internal thermometer, 200 g of a copolymer of ethylene with vinyl acetate (28 wt.% Of vinyl acetate, mol.m. 20000) are dissolved at 100 ° C of 1000 g of isodecanol. To this solution, 99.9 g of isodecyl methacrylate, 33.4 g of 2-hydroxyethyl methacrylate and 4.18 g of tert-butyl peroctoate are added. In an atmosphere of carbon dioxide at 90 ° C, a mixture of 500 g of isodecyl methacrylate, 166.7 g of 2-hydroxyethyl methacrylate and 6.7 g of tert-butyl peroctoate is added over 3.5 hours. After 2 hours, at the end of the addition, an additional 6.6 g of tert-butyl peroctoate is added. The total polymerization time is 20 hours. A cloudy, viscous solution containing 50% by weight of the graft copolymer is obtained. The mass ratio of the mixture of methacrylic acid esters and ethylene copolymer with vinyl acetate is 1: 1.5.
    Getting additive
    162.9 g of the solution of the obtained graft copolymer, 308.7 g of a copolymer of ethylene with vinyl acetate (28 wt.% Of vinyl acetate, mol.m., 20,000), 74.5 g of isodecanol and 103.9 g of diethylene glycol are fed into a Witt vessel with a capacity of 1 l, equipped with a stirrer, and stirred for 16 hours at 70 ° C and 200 rpm. A whitish-turbid, stable, viscous emulsion of the following composition is obtained, wt%: ethylene-vinyl acetate copolymer 47.5; grafted polymer 12.5; liquid carrier 40. In this case, the mass ratio of isodecanol and diethylene glycol in the mixture is 0.7: 1, and the mass ratio of the solution of the graft copolymer, copolymer of ethylene with vinyl acetate and liquid carrier is 1: 1.89: 1.09.
    The particle size of 2-20 microns; viscosity 30,000 mm2 / s at 20 ° C and 23,900 mm2 / s at 40 ° C; solidification point -30 ° C.
    EXAMPLE 5 Preparation of a Graft Copolymer.
    In a four-necked flask with a capacity of 4 liters, equipped with a stirrer, a reflux condenser, and an internal thermometer, 200 g of ethylene-vinyl acetate copolymer (28 wt.% Vinyl acetate, mol.m., 20,000) are dissolved at 1000 ° C in 1000 g of isodecanol. To this solution are added 20 g of 2-hydroxyethyl methacrylate, 113.3 g of methacrylic acid esters formed by the mixture
    alcohols with 12–18 carbon atoms, and 4–18 g of tert-butyl peroctoate, In a carbon dioxide atmosphere at 90 ° C, a mixture of 566.7 g of methacrylic acid esters formed from a mixture of 12–18 atoms is added over 3.5 h. carbon, 100 g of 2-hydroxyethyl methacrylate and 6.7 g of tert-butyl peroctoate. After 2 hours, 1.6 g of tert-butyl peroctoate is further added at the end of the addition. The total polymerization time is 20 hours. A turbid, viscous solution containing 50% by weight of the graft copolymer is obtained.
    The mass ratio of the mixture of methacrylic acid esters and ethylene copolymer with vinyl acetate is 1: 1.5.
    Getting additive
    130.3 g of a solution of the obtained graft co-polymer, 247.0 g of a copolymer of ethylene with vinyl acetate (28 wt.% Of vinyl acetate, mol.m.20000), 17-1.4 g of isodecalon and 101.3 g of diethylene glycol are fed into a 1-liter Witt vessel. and the mixture is stirred for 16 hours at 70 ° C and 200 rpm. A whitish-turbid, stable, viscous emulsion of the following composition is obtained, wt.%: a copolymer of ethylene with vinyl acetate 38; grafted polymer 10; liquid carrier 52; The weight ratio of isodecanol and diethylene glycol in the mixture is 1.69: 1, and the mass ratio of the solution of the graft copolymer, copolymer of ethylene with vinyl acetate and liquid carrier is 1: 1.89: 2.09,
    Particle size 4-20 microns; viscosity at 40 ° С is 3900 mm2 / s; solidification point -23 ° C.
    PRI me R 6 Getting a graft copolymer.
    In the manner described in Example 5, 200 g of ethylene-vinyl acetate copolymer (28% by weight of vinyl acetate, mol.m. 20,000) are dissolved at 100 ° C in 1000 g of isodecanol, 33.3 g of 2-dimethylaminoethyl methacrylate, 100 g of isodecyl methacrylate and 4.18 g of t-butyl peroctoate and, at 90 ° C, a mixture of 500 g of isodecyl methacrylate, 166.7 g of 2-dimethylaminoethylmethacrylate and 6.7 g of tert-butyl peroctoate is added over 3.5 hours. After 2 hours at the end of the addition, an additional tert-butyl peroctoate is added. The total polymerization time is 20 hours. A cloudy, viscous solution is obtained containing 50% by weight of the graft copolymer.
    The mass ratio of the mixture of methacrylic acid esters and ethylene copolymer with vinyl acetate is 1: 1.5.
    Getting additive
    130.3 g of a solution of the obtained graft copolymer, 247.0 g of a copolymer of ethylene with vinyl acetate (28% by weight of vinyl acetate, mol.m. 20000), 171.4 g of isodecanol and 101.3 g of ethylene glycol and the mixture stir for 16 hours at 70 ° C and 200 rpm. In this way, a brownish, turbid, stable, viscous emulsion of the following composition is obtained, in wt%: ethylene-vinyl acetate 38; grafted polymer 10; liquid carrier 52. The weight ratio of isodecanol and diethylene glycol in the mixture is 1.69: 1, and the mass ratio of the solution of the graft copolymer, copolymer of ethylene with vinyl acetate and liquid carrier is 1: 1.89: 2.09.
    Particle size 2-4 microns; viscosity at 40 ° С 2500 mm2 / s; solidification point -46 ° C.
    Example. Preparation of polybenyl acrylate.
    In a four-necked flask with a capacity of 2 liters, equipped with a stirrer, an internal thermometer and a reflux condenser, 1020 g of behenyl acrylate (acrylate with 18-22 carbon atoms) and 180 g of xylene are heated to 70 ° C. After degassing with dry ice in an atmosphere of carbon dioxide, 2.04 g of dodecyl mercaptan and 4.08 g of tert-butyl perpivalate are sequentially added. The reaction temperature rises to 139 ° C. 4 h after the start of the reaction, 0.51 g of dodecyl mercaptan and 2.04 g of tert-buty perpivalate are added. The total polymerization time is 16 hours. By distilling off the solvent, the polymer is obtained as a brownish solid; d (at 20 ° C in xylene) 30 ml / g; mol.m. (light scattering) 400,000 g / mol; conversion 99.5%.
    Getting additive
    130.3 g of the solution of the graft copolymer prepared according to Example 4, 247 g of ethylene-vinyl acetate copolymer (28% by weight of vinyl acetate, mol.m. 20000), 171.4 g of isodecanol are fed into a Witt vessel with a capacity of 2 l, equipped with a mixer. and 101.3 g of diethylene glycol and the mixture is stirred at 70 ° C and 200 rpm. Then, 130.1 g (14.1% by weight per 100% by weight of the total mixture) of polybuhenyl acrylate heated to 60 ° C are added and stirred at 60 ° C for 1 hour. Then it is diluted by adding 98 g isodecanol and 42.7 g of diethylene glycol. Intensively stirred, cooled to room temperature. Get a muddy brownish emulsion of the following composition, wt.%: A copolymer of ethylene with vinyl acetate 26,8; grafted polymer 7; polybenyl acrylate 14.1; liquid carrier 52.1. At the same time
    The ratio of isodecanol and diethylene glycol in the mixture is 1.69: 1, and the weight ratio of the solution of the graft copolymer, ethylene vinyl acetate copolymer and liquid carrier is 1: 1.89: 3.17.
    Particle size 4-25 microns; viscosity 3000 mm2 / s at 20 ° С and 3900 mm2 / s at 40 ° С; solidification point -40 ° C.
    Try on Example 2 is repeated, but 108.3 g of the solution obtained according to example 2 of the grafted sotulimer, 247.0 g of a copolymer of ethylene with vinyl acetate (33 May.% Of vinyl acetate, mol.m. 13000), 159, are fed into the Vitit vessel equipped with a mixer. 5 g of isodecanol and 135.2 g of diethylene glycol and then the mixture is stirred for 16 hours at 60 ° C and 200 rpm. A whitish-turbid stable emulsion of the following composition is formed, wt%: ethylene copolymer with vinyl acetate 38; graft polymer as a solid 10, liquid carrier 52. The weight ratio of isodecanol and diethylene glycol in the mixture is 1.18: 1, and the mass ratio of the solution of graft copolymer, ethylene-vinyl acetate copolymer and liquid carrier is 1: 2.28 : 2.72.
    Particle size 2-10 microns; viscosity at 40 ° С 7200 mm2 / s; solidification point -44 ° C.
    EXAMPLE 9 Example 2 is repeated, but 8.33 g of the graft copolymer solution prepared in Example 2, 10 g of ethylene-vinyl acetate copolymer (33% by weight of vinyl acetate, mol.m.) are introduced into a Vitt vessel equipped with a stirrer. . 13000), 55 g (55 wt.% Per 100 wt.% Of the total mixture) polybenyl acrylate, 17.07 g of isodecanol and 9 g of diethylene glycol and the mixture is stirred for 16 hours at 70 ° C and 200 rpm. A whitish-turbid stable emulsion of the following composition is formed, wt%: ethylene-vinyl acetate copolymer 10; graft copolymer 5; polybenyl acrylate 55; liquid carrier 30. In this case, the mass ratio of isodecanol and diethylene glycol in the mixture is 1.89: 1, and the mass ratio of the solution of the graft copolymer, copolymer of ethylene with vinyl acetate and liquid carrier is 1: 1.2: 3.2.
    Particle size 2-10 microns; viscosity at 40 ° С 7200 mm2 / s; solidification point -44 ° C.
    An example. Example 2 is repeated, but 228 g of the graft copolymer solution prepared in Example 2, 191.6 g of ethylene-vinyl acetate copolymer (28 wt.% Vinyl acetate, mol. 35000), 115 are fed into a 1-liter Vitit vessel equipped with a stirrer. , 2dimethyl phthalate and 115.2 gdibutyl phthalate and at 80 ° C in an atmosphere of carbon dioxide, the mixture is stirred at 200 rpm for 16 h. A whitish-turbid stable emulsion of the following composition is obtained, wt.%: Ethylene-vinyl acetate copolymer 29 ,five; grafted polymer 10.5; liquid carrier 60. In this case, the weight ratio of said diethyl phthalates is 1: 1, and the mass ratio of the solution of the graft copolymer, ethylene-vinyl acetate copolymer and liquid carrier is 1: 0.84: 1.01.
    Particle size 4-25 microns; viscosity 9,400 mm2 / s at 50 ° C and 10,600 mm2 / s at 20 ° C; solidification point 22 ° C.
    EXAMPLE 11 Example 2 is repeated, but 228 g of a solution of a graft copolymer, 191.6 g of a copolymer of ethylene with vinyl acetate (28% by weight of vinyl acetate, mol.m.) are fed into a 1 liter Witt vessel equipped with a stirrer. 10000), 193.3 g of isodecanol and 101.4 g of diethylene glycol and at 70 ° C in an atmosphere of carbon dioxide, the mixture is stirred at 200 rpm for 16 hours. A whitish-cloudy stable emulsion of the following composition is obtained, wt.%: Ethylene copolymer and in ethyl acetate38 ; grafted polymer 10; liquid carrier 52. The weight ratio of isodecanol and diethylene glycol in the mixture is 1.9: 1, and the mass ratio of the solution of the graft copolymer, copolymer of ethylene with vinyl acetate and liquid carrier is 1: 0.84: 1.29.
    The particle size of 0.2-1 microns; viscosity 340 mm2 / s at 50 ° C and 6000 mm2 / s at 20 ° C; solidification point 30 ° C.
    EXAMPLE 12 The additive according to examples 1-11 in the amounts indicated in Table 1 is added to oil H V, gas oil and diesel fuel of the following qualities,
    Oil I: from Germany; solidification point 18 ° C; the content of n-perafins 15%.
    Oil II: from West Africa; solidification point 24 ° C; the content of n-paraffins 10.6%.
    Oil III: from the North Sea; point of freezing is 27 ° C; the content of n-paraffin 14.7%.
    Oil IV: from the Baltic Sea; solidification point 12 ° C; the content of n-paraffin 8.9%.
    Gas oil: product of the Scandinavian refinery; solidification point 39 ° C; the content of n-alkanes 13.3%; bp 280-360 ° C.
    Diesel fuel: a product of the British oil refinery; cloud point -4 ° C (determined according to the German Standard DIN 51 597); point - filter plugging in a cold state of -4 ° C (determined according to DIN 51 428); n-paraffin content 16.3%: bp. 185-360 ° C
    The solidification point is determined as follows.
    Method A. A sample of oil or gas oil is heated to 60 ° C. At this temperature, add a concentration emulsion of the polymer and stir. The sample is fed to a water bath with a temperature of 25 ° C, in which it is allowed to cool to 36 ° C. The pour point is then determined according to DIN 51 597 by placing the sample in a bath with a temperature of 0 ° C, however without reheating to 60 ° C.
    Method B. Method A is repeated, but oil is heated to 80 ° C.
    Method B. Method A is repeated, but the oil is heated to 50 ° C.
    Method D. To the diesel fuel preheated to 60 ° C, polymer emulsion is added and stirred after cooling to room temperature, the filter plugging point in a cold state is determined according to DIN 51 428.
    The results of the experiments are summarized in table 1.
    Example 13 (comparative). Example 12 is repeated, but the following additives are used.
    Additive A. Additive according to example 1, but without the grafted polymer.
    Additive B. Additive according to example 8, but without the grafted polymer.
    Additive B. Additive according to a known method, consisting of 50% by weight of copolymer 64% by weight of ethylene and 36% by weight of vinyl acetate mol%. 2300 and 50 wt.% Copolymer of 74 wt.% Of ethylene and 26 wt.% Of 2- ethoxyethyl methacrylate, with mol.m. 2050. This agent is used in the form of a 50% solution in toluene.
    Additive G. Additive according to a known method, consisting of 20 wt.% Copolymer 60 wt.% Ethylene and 40 wt.% Vinyl acetate, mol.m. 2500, 25 wt.% P-cresol and 55 wt.% Toluene.
    Additive D. Additive by a known method, consisting of 20 wt.% Copolymer 80 wt.% Ethylene and 20 wt.% Ethyl acrylate, mol.m. 2000, 25 wt.% P-cresol and 55 wt.% Toluene,
    The results of the experiments are summarized in table 2.
    权利要求:
    Claims (2)
    [1]
    1. A method for producing a depressant by mixing an ethylene copolymer with vinyl acetate with a vinyl acetate content of 28-33 May. % and mol.m. 10,000-35,000 with a liquid carrier, characterized in that, in order to increase the effectiveness of the additive when used to improve the flowability of oil and hydrocarbon fractions with
    boiling point 185-360 ° C, graft polymerization of a mixture of methacrylic acid esters on a copolymer of ethylene with vinyl acetate with a vinyl acetate content of 28-33 wt.% and mol.m. 10,000-35,000 in a solution of an inert organic solvent in the presence of a peroxide initiator with a weight ratio of a mixture of methacrylic acid esters and a copolymer of ethylene with vinyl acetate equal to 1: (0.94-2.7) to form in graft 30-60% by weight a copolymer, followed by mixing the resulting solution with a copolymer of ethylene with vinyl acetate and a liquid carrier
    0
    at a mass ratio of a solution of a graft copolymer, a copolymer of ethylene with vinyl acetate and a liquid carrier equal to 1: (0.84-2.28): (1.01-3.2), and a mixture of dimethyl phthalate with dibutyl phthalate is used as a liquid carrier when the mass ratio in a mixture of 1: 1 or a mixture of isodecanol with diethylene glycol in a mass ratio in a mixture (0.7-1.9): 1.
    [2]
    2. A method according to claim 1, characterized in that the mixing is carried out with the additional introduction of polybenyl acrylate with a mol.m. 400,000 in an amount of from 14.1 to 55.0 wt.% Per 100.0 wt.% Of the total mixture,
     The point of filter clogging in the slave state,
    The amount of added grsarki (ppm) in terms of ND with its polymer.
    The effectiveness of well-known substances to improve the fluid properties of petroleum and August 2010 Table 1
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    同族专利:
    公开号 | 公开日
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    引用文献:
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    申请号 | 申请日 | 专利标题
    DE3613247A|DE3613247C2|1986-04-19|1986-04-19|Concentrated emulsions of ethylene-vinyl acetate copolymers, processes for their preparation and their use as pour point improvers|
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