前苏联专利SU1676455A3 Method of obtaining mesophase pitch

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专利摘要:
A process for the preparation of an excellent mesophase pitch suitable for use as a spinning pitch for the production of high performance carbon fibers is disclosed. The mesophase pitch can satisfy the four remarkable characteristics at the same time, i.e., a softening point of below 320 DEG C as determined by Mettler method, a mesophase content of above 90% as examined on a polarized microscope, a quinoline insoluble content of less than 20%, and a xylene soluble content of less than 20%. The mesophase pitch is particularly homogeneous and is easily spinnable. The process can be characterized by a preliminary extraction step, a continuous heat treatment step, and an extraction step. In some cases, the preliminary extraction step can be omitted. Graphite fibers having a tensile strength of about 400 Kg/mm<2> and a modulus of elasticity of above 60 ton/mm<2> can be obtained from the mesophase pitch. Further, even carbon fibers prepared at a carbonization temperature of 1000 DEG C have a tensile strength of about 300 Kg/mm<2> .
公开号:SU1676455A3
申请号:SU874202682
申请日:1987-05-18
公开日:1991-09-07
发明作者:Тсучитани Масатоси；Наито Сакае；Накадзима Риоичи
申请人:Кодзо Иидзуко (Фирма)；Марузен Петрокемикал Ко, Лтд (Фирма)；
IPC主号:

专利说明:

The invention relates to methods for producing a mesophase pitch and can be used in the petroleum refining and coking industries.
The aim of the invention is to improve the quality of the target product.
Example 1. Coal tar with a specific gravity of 1.1644 g / cm and containing 4.7 wt.% Of xylene soluble components (CNK) and 0.6 wt.% Of quinolin insoluble components (CNA), is subjected to single evaporation in a single evaporation column at 280 ° C , under atmospheric pressure in order to obtain a heavy component with a content of CNS and CNS of 6.3 wt.% and 1.1 wt.%, respectively, at a yield of 80 wt.%. This heavy component is dissolved in double the amount of xylene, and the mixture is continuously filtered at 25 ° C using a continuous filter to remove the insoluble components. The filtrate is distilled to isolate xylene, resulting in a purified heavy oil with a yield of 69.4% by weight relative to the coal tar.
The properties of coal tar, heavy component and purified heavy oil are given in table 1.
10 kg / h of purified oil and 7.6 kg / h of absorbing oil with a boiling range of 240-280 ° C without a CLA, obtained from coal tar, are separately pumped into a tubular heater equipped with a heating pipe with an inner diameter of 6 mm and 40 mm long, immersed in a molten salt bath, where the mixture is heat treated at 510 ° C at a pressure of 20 kgf / cm2 g. The heat-treated fluid is added to double the amount of xylene and the contents are mixed. The mixture is then centrifuged at a rotational speed of 2000 rpm at ambient temperature to obtain insoluble components, to which double the amount of xylene is added and the contents are mixed, and the mixture is again centrifuged to rinse the insoluble components. High molecular weight bituminous material is obtained by drying only the above mentioned insoluble components in a yield of 12.4% by weight with respect to the purified heavy component. Analysis of the high molecular weight bituminous material gives the following results: the content of the CNS is 80% by weight, and the content of the CNS is 0.3% by weight.
250 g of a bituminous material are added to 500 g of tetrahydroquinoline and subjected to hydrogenation for 30 minutes at 440 ° C and under autogenous pressure in a 1-liter autoclave. The final treatment pressure is 111 kgf / cm g. The hydrogenated liquid is filtered off with a glass filter and subjected to distillation under reduced pressure to remove the solvent to obtain a hydrogenated high molecular weight bituminous material. The hydrogenated high molecular weight bituminous material thus obtained is placed in a polymerization flask and subjected to
heat treatment in a salt bath maintained at 450 ° C for 50–70 min at atmospheric pressure with bubbling nitrogen gas at a flow rate
80 l / min per kg of bituminous material to be treated. The properties of the pitch obtained in this way are listed in Table 2.
Mesophase pitch from test 3 of the table, 2 is subjected to spinning using a spinning device, with a spinneret opening of a diameter equal to 0.25 mm and a length of 0.75 mm at 335 ° C with a drawing speed of 600 m / min to obtain fibers from pitch. The carbon5 native fibers are obtained by imparting to the fibers of the pitch infertility as a result of their heating in air at 320 ° С for 20 minutes and their subsequent carbonization at 1000 ° С in a nitrogen atmosphere. Carbon
0 fibers have a tensile strength of 300 kgf / mm and a modulus of elasticity of 19.4 tons / mm. These fibers are further subjected to grafting at 2500 ° C. Volo kn have a tensile strength of 423
5 kgf / mm2 and modulus of elasticity 92.1 t / mm2.
Example 2. The purified heavy oil obtained in Example 1, in the absence of aromatic oil, is heat treated in a tubular heater with an internal diameter of 6 mm and a length of 40 m at 510 or 530 ° C and a pressure of 20 kg / cm (2.1 MPa ) and at a flow rate of 17.6 kg / h. The properties of the heat-treated materials are given in table 3.
5 High molecular weight bituminous
materials are obtained by adding a double amount of xylene to each of the heat treated materials, and their mixtures are processed in
0 according to Example 1. The outputs of the bituminous materials are 14.9 and 21.3% by weight with respect to the purified heavy oil for each of the materials subjected to heating at 510 or 530 ° C,
5, respectively. Mesophase pitches are obtained by hydrogenation and heat treatment of high molecular weight bituminous material. A similar procedure to Example 1. The heat treatment conditions are given in
0 is table 4, and the conditions for hydrogenation and the second degree of heat treatment do not differ from the conditions described in example 1, the properties of the pitches are given in table 4. Meo-phase pitch from experiment 6 (Table 5) is fed to spinning at 377 ° C. P. In accordance with the technology used in Example 1, and then obtained from this process, inferred water is added and carbonization at 1000 ° C obtained by this method. Carbon fibers have a limit
rj
tensile strengths of 294 kgf / mm and a modulus of elasticity of 18.0 t / mm2.
Example 3 (comparative). The same coal tar used in Example 1 is subjected to a single evaporation at 280 ° C to obtain a heavy oil, which is mixed with xylene and filtered. The CNS obtained in this way is added to a double amount of tetrahydroquinoline and subjected to hydrogenation in the same manner as in Example 1. After filtration, the solvent is removed from the hydrogenated product, and the product is subjected to heat treatment in a salt bath at 450 ° C for 90 minutes under atmospheric pressure to produce mesophase pitch. The softening temperature of the pitch is 320 ° C, the content of compounds insoluble in quinoline is 12.6% by weight, the content of compounds soluble in xylene is 5.1% by weight, and the content of the mesophase is 85% . This pitch is spun at 355 ° C. The pitch fibers impart inferiority and are subjected to carbonization at 1000 ° C. Carbon fibers have a tensile strength of 228 kgf / mm and a modulus of elasticity of 16.2 tons / mm.
Example 4 (comparative). The purified heavy oil obtained in the same manner as in Example 1 is heat treated in a tubular heater under the same conditions as used in Example 1. The heat-treated fluid is sent without cooling to an evaporation column at 480 ° C, where the light fractions are removed in order to obtain a high softening point pitch, with a yield of 28.6% by weight with respect to the purified heavy oil. In order to hydrogenate the pitch under the same conditions as used in Example 1, double the amount of tetrahydroquinoline is added to the pitch, and the hydrogenated pitch is heat treated, resulting in a mesophase pitch. The duration of heat treatment is shown in Table 5, and other heat treatment conditions, as in the example
The properties of the pitch are given in the table. Mesophase pitch from test 10 (table 5) is spun at 342 ° C according to a method similar to that described in Example 1, and then the melted pitch fibers obtained in this way are carbonized at 1000 ° C. Carbon fibers have a tensile strength of 242 kgf / mm and a modulus of elasticity of 14.2 tons / mm.
Example 5 A purified heavy oil, as in Example F, is heat treated in accordance with Example 1 at 510 ° C in a tubular heater. Rubbed ter
the microprocessing material is sent to an evaporation column and subjected to a single evaporation at 280 ° C under atmospheric pressure in order to remove the used absorption oil,
0 Heat-treated material obtained from the bottom of the column is cooled in a refrigerator to 100 ° C. This product has 3.5 wt.% AHC. After the continuous introduction of a double amount of xylene to heat treated material inside the pipeline, the mixture is cooled to 25 ° C. The mixture is sent to a continuous centrifuge and the resulting insoluble component is separated and withdrawn. After dispersing the insoluble component in a double amount of xylene, the dispersion is again sent to the same continuous centrifuge to flush out the insoluble component.
5 After drying the insoluble component in vacuo, a high molecular weight bituminous material is obtained with a yield of 8.8% by weight relative to the purified heavy oil of the feedstock. The resulting poo
In addition, the high molecular weight bituminous material has a CNS of 70.5 wt.% And a CNS of 0.1 wt.%.
The high molecular weight bituminous material is dissolved in a threefold amount of hydrogenated anthracene oil and the solution is subjected to continuous heat treatment in a tubular heater containing a heating tube with an internal diameter of 10 mm and a length of 100 m, immersed in a molten salt bath at a flow rate of 6.5 kg / h. , 440 ° С, pressure 50 kgf / cm g. Then, the treated solution is directly sent to the evaporation column and subjected there
5 single evaporation at atmospheric pressure at 400 ° C. Thus, hydrogenated bituminous material is obtained from the bottom of the column. Hydrogenated bituminous material has
0 softening temperature by method. К / Hi 132 ° С СНС 51.6 May% and ХНС 0 1 mds%
The hydrogenated bituminous material is heat treated v with a polymerization flask at atmospheres.
5 than pressure, as in example 1 and yopuchzgs-mesophase pitch.
The properties of the pitch are given in tabg. 6 A spindle pitch of fireplate 1B tchl & is also subjected to the broadcasting of the L-ch1 TV also of the most pristyl device, i - L
Example 1, at a drawing rate of 850 m / min at 325 ° C. The extruded fibers are not melted and carbonized at 1000 ° C, as in Example 1, and carbon fibers are obtained as a result. Carbon fibers have a tensile strength of 298 kgf / mm and a modulus of elasticity of 45.9 tonnes / mm2. fibers by graphitization at 2500 ° C, have a tensile strength of 405 kgf / mm and a modulus of elasticity of 67.9 t / mm2.
For example, Tar (specific gravity 1.0751 g / cm3, asphaltene content 15.1 wt.%, CNS 0 wt.%, Conradson carbon content 12.3 wt.%, Viscosity at 100 ° C 6.3 eats) is subjected heat treatment in the same tubular heater as in example 1, at 500 ° C and a pressure of 20 kg / cm at a flow rate of 17 5 kg / h. The naphtha used as a feedstock is the remainder of the resin produced by the pyrolysis of naphtha to obtain olefins, for example ethylene, propylene, etc. A high molecular weight bituminous material is obtained by mixing a heat treated material with double The amount of xylene, centrifugation, washing and drying as in Example 1 The yield of bituminous material is 8 9 May% This bituminous material with high molecular weight contains 76.9 May% xylene insoluble component and less than 0.2 May% insoluble in the quinoline component, 125 g of a high molecular weight bituminous material is dissolved in 250 g of tetrahydroquinoline, and the solution is loaded into a 1 liter autoclave and heat treated at 460 ° C under autogenous pressure for 80 minutes. The final treatment pressure is After filtering the treated liquid using a glass filter, the used solvent is removed by distillation and a hydrogenated bituminous material is obtained. The hydrogenated bituminous material is heat treated as in Example 1 at a salt bath temperature of 450 ° C at atmospheric pressure for 30 min. The pitch obtained in this way has a softening temperature of 310 ° С, the content of CNS is 0.8 mA%, the content of compounds soluble in xylene is 8.5 wt.%, The content of the mesophase is 100%.
The pitch is spun using the same spinning device as used in Example 1 at 341 ° C. at a drawing speed of 500 m / min. The melting fibers of the pitch are infused and they
carbonized at 1000 ° C. Carbon fibers have a tensile strength of 279 kgf / mm and a modulus of elasticity of 15.5 t / mm.
Example The hydrogenated pitch obtained as in example 1 was heat treated as in example 1 using a polymerization flask at 470 ° C for 25 minutes. Properties obtained in this way mesophase pitch Mettler softening temperature 300 ° C, quinoline-insoluble compounds 1 9 May%, content of xylene soluble compounds 72 May%, content
5 mesophases 100%
The mesophase pitch is molded in the same way and under the same conditions by using the same fiber spinning machine that is used in
0 example 1 at 335 ° C. Pitch fibers are made non-meltable and carbonized at 1000 ° C in the same way and under the same conditions as used in example 1 Carbon fibers thus obtained
5 have a tensile strength of 305 kg / mm2 and a modulus of elasticity of 18.9 t / mm
PRI me R 8 2 sample (first received: heat treatment at 510 ° C and the other obtained by heat treatment at 530 ° C)
0 of the hydrogenated pitch obtained according to example 2 (250 g each), respectively, are placed in 500 ml stainless steel reactors. The hydrogenated pitch obtained by heat treatment at 510 ° C contains x5 l soluble compounds in
Amount 50.1 May% and quinoline-insoluble compounds in the amount of 0.2 wt.%
Heat-treated hydrogenated pitch
by treatment at 530 ° C, contains soluble xolyne in the amount of 49.3 may% and quinoline-insoluble compounds in the amount of 0.2 weight%. The reactors are flushed with gaseous nitrogen, after which their contents are melted by heating to
5,300 ° C. Next, the reactors are gradually evacuated with vacuum pumps until an absolute pressure of 3 mm Hg is reached. Then the temperatures are raised until an absolute pressure of 3 mm Hg is reached. The temperatures are then raised until the predetermined temperatures are reached. The reactors are kept for 5 min at predetermined temperature after
5 of which the heating is stopped. Vacuum pumps are also turned off. The pressure in the reactors is reduced to atmospheric pressure by introducing nitrogen gas. The reactors are then cooled. The properties of the pitches are given in Table 7. The mesophase pitches thus obtained are molded in the same manner and under the same conditions as used in Example 1 at 340 ° C. Pekov vokokn give infertility and carbonize at 1000 ° C in the same way and under the same conditions as in example 1. Characteristics of carbon fibers obtained in this way are shown in Table 7.
Example 9. Coal tar having a specific gravity of 1.213 g / cm and containing 7.2 wt.% Xylene-soluble compounds and 1.0 May. % quinoline-insoluble compounds, distilled at 300 ° C to remove lighter components. The heavy component thus obtained is dissolved in a double amount of xylene and the insoluble materials thus formed are filtered off. The resulting filtrate is distilled to remove xylene, thereby obtaining a purified heavy oil. The yield of purified heavy oil is 76.3 May. % in terms of coal tar, i.e. on raw materials. The purified heavy oil contains xylene-soluble compounds in an amount of 2.2 wt.% And quinolin-insoluble compounds in an amount of less than 0.1 wt.%.
The purified heavy oil is heat treated at 510 ° C in the same way and under the conditions used in Test 4 of Example 1. After heat treatment, the material is subjected to a single equilibrium distillation at 285 ° C at atmospheric pressure in a single distillation column. A heavy oil is obtained from the bottom of the column, the content of which is 6.9% by weight. The heavy oil is dissolved in twice the amount of xylene and the mixture is centrifuged to remove the insoluble component. The insoluble component is re-dispersed in twice the amount of xylene and the dispersion is filtered to recover the insoluble component. The insoluble component is vacuum dried to obtain a high molecular weight bituminous material. The yield of high molecular weight bituminous material will be 7.3% by weight, based on purified heavy oil.
The high molecular weight bituminous material is dissolved in a triple amount of hydrogenated anthracene oil and the high molecular weight bituminous material is hydrogenated and subjected to a single distillation as in Example 5 to obtain a hydrogenated bituminous material. Hydrogenated bituminous material is subjected to heat treatment at 430 ° C for 70 min, as indicated in example 1, Mesophase pitch, obtained in this way.
has a Mettler softening temperature of 300 ° C, a content of quinoline-insoluble compounds of 0.3 wt.%, a content of xylene-soluble compounds of 5.3 wt.% and a content of mesophase 100%.
Mesophase pitch is molded in the same way and under the same conditions as used in Example 1. Pitch fibers
0 impart infertility and carbonize at 1000 ° С in the same way and under the same conditions as used in example 1. Carbon fibers have a tensile strength of 301 kg / mm2 and a modulus of elasticity of 17.0
5 t / mm2.
Example 10. Coal tar having a specific gravity of 1.266 g / cm3 and containing 10.2% by weight, x-soluble insoluble components and 2.0% by weight quinoline-soluble components, is dissolved in a triple amount of xylene. The insoluble materials thus formed are filtered off, then the filtrate is distilled to remove xylene and a purified, yellow oil is obtained. The yield of purified heavy oil is 31.2 wt.% Based on coal tar, i.e. on raw materials. The purified heavy oil contains xylene-soluble components in amounts of 0.4% by weight and quinolin-insoluble components in an amount of less than 0.1% by weight. Purified heavy oil is heat treated in a tubular heater of Example 2 at 480 ° C under pressure
5 30 kg / cm. After heat treatment, the material is immediately cooled, as a result of which a heavy oil is obtained in the amount of 7.9 wt.%. The heavy oil is dissolved in double the amount of xylene and the mixture is centrifuged to remove the insoluble component. The insoluble component is again dispersed in double the amount of xylene and the dispersion is filtered to remove the insoluble component. The insoluble component is dried under vacuum to obtain a high molecular weight bituminous material. The yield of high molecular weight bituminous material is 8.6% by weight, based on the purified heavy oil.
The high molecular weight bituminous material is dissolved in a triple amount of hydrogenated anthracene oil. The bituminous material is hydrogenated and subjected to a single distillation, as shown in Example 5.
The hydrogenated bituminous material is heat treated at 450 ° C for 35 minutes as indicated in Example 1. The mesophase pitch thus obtained has a softening temperature of 307 ° C according to Mettler. The content of quinoline-insoluble components is 0.8 wt.%, The content of xylene soluble compounds is 3.6 wt.%. The content of the mesophase 100%.
The mesophase pitch is molded in the same way and under the same conditions as used in Example 1. The pitch fibers are melted and carbonized at 1000 ° C in the same way and under the same conditions as used in Example 1. Carbon fibers have tensile strength of 293 kg / mm and a modulus of elasticity of 17.4 t / mm
Example 11. The raw material used is hard coal tar, which has the properties shown in Table 8. One part of the hard coal tar is mixed and dissolved in 2 parts of xylene, then the formed insoluble components are separated on a continuously operating filter. Xylene is removed from the filtrate by distillation, and in this way a purified heavy oil is obtained, the properties of which are shown in Table 8. The yield of purified heavy oil is 92.1 mas.% Based on hard coal tar.
Purified heavy oil is subjected to continuous heat treatment at a loading rate of 175 kg / h, at 470-520 ° C and a pressure of 20 kg / cm in a tubular heater, with an internal diameter of 6 mm and a pipe length of 40 m immersed in a salt bath. The material exiting the heater is sent to a single distillation column at a column head temperature of 250 ° C at atmospheric pressure in order to remove lighter components from the head section and recover heavy oil after thermal cracking on the bottom of the column. The content of heavy oil after thermal cracking is as follows: experiment 19: 6.9 wt.%, Experiment 20: –8.8 wt.%. experience 21: 9.8 wt.%, experience 22: 11.1 wt.%, experience 23: 12.4 wt.% 2 weight.h. xylene is added to one part of heavy oil at 100 ° C. The crude oil is dissolved in xylene with stirring, then the solution is cooled to room temperature. The solution containing the insoluble component is centrifuged with a continuous centrifuge to separate and obtain the insoluble component. Two parts by weight of xylene are added to one part insoluble component and the mixture is stirred. The mixture is then filtered under pressure to separate the insoluble component from the solution of the soluble component in the solvent. Insoluble
the component is heated under vacuum to remove xylene. The purified insoluble component thus obtained is a high molecular weight bituminous material. The yield and properties of the high molecular weight bituminous material are shown in Table 9.
Then one weight part of the high molecular weight bituminous material is dissolved in 3 parts by weight. hydrogenated anthracene oil and the mixture is hydrogenated continuously at a feed rate of loading of 6.5 kg / h, at 400 ° C, under a pressure of 50 kg / cm2 in a tubular heater having a heating tube with an inner diameter of 10 mm and a length of 100 m, immersed in a bath from molten salt. Then, the hydrogenated mixed solution is fed into the single distillation column and subjected to single distillation at a temperature in the head part of 400 ° C at atmospheric pressure in order. to remove spent solvent and lighter material components at the top of the column. As a result, hydrogenated pitch is obtained from the lower part of the column.
Next, 100 g of hydrogenated pitch is placed in a polymerization flask, immersed in a bath of molten salt with
0 temperature of 450 ° C. The heat treatment is carried out for 30 minutes at atmospheric pressure by bubbling nitrogen gas at a flow rate of 8 l / m. Thus receive mesophase pitch.
5 The yield and properties of the hydrogenated pitch and mesophase pitch are shown in Table 10, respectively.
Optically anisotropic pitches, i.e. mesophase pitches obtained from experiments 20,
0 21.22, molded using a fiber spinning machine with a hollow spinning die with an inner diameter of 0.25 mm and a length of 0.75 mm. Molding temperature 340 ° C at molding speed
5 700m / min.
The pitch fibers are infused by increasing the temperature at a rate of 1 ° C / min to 320 ° C and keeping the fibers at 320 ° C for 20 minutes. The filament is carbonized at 1000 ° C in an atmosphere of nitrogen gas. In this way, carbon fibers are obtained. Characteristics of carbon fibers are shown in table. 15 kg / h of purified oil,
5 of the absorption oil prepared in Example 1 and 2.6 kg / h are mixed and sent to a tubular heater equipped with a heating tube having an internal diameter of b mm and a length of 40 mm. In the heater, the mixture is subjected to thermal
When processed at 510 ° C and a pressure of 20 kg / cm, the content of the heat-treated oil is not determined, as it contains absorption oil and therefore cannot be directly compared with other examples.
The oil thus obtained is treated with xylene in the same manner and under the same conditions as used in Example 1, resulting in a high molecular weight bituminous material. The yield of high molecular weight bituminous material is 14.1% by weight. in terms of purified heavy oil, i.e. on raw materials.
The bituminous material (250 g) is added to 500 g of tetrahydroquinoline. the mixture is placed in a 1 liter autoclave and hydrogenated in the same manner and under the same conditions used in Example 1. Then, hydrogenated pitch is obtained by removing the solvent by vacuum distillation.
The mesophase pitch is obtained by thermally treating the hydrogenated pitch in the same manner and under the same conditions used in Test 2 of Example 1 at 450 ° C for 60 minutes. The mesophase pitch has the following properties: Mettler softening temperature is 303 ° C, the content of xylo-soluble compounds is 5.8 wt.%, The content of quinoline-insoluble compounds is 1.5 May. and the mesophase content is 100%.
The mesophase pitch is molded in the same manner and under the same conditions as used in Example 1. The pitch fibers are infused and melted at 1000 ° C in order to obtain carbon fibers. Characteristics of carbon fibers: tensile strength of 297 kg / mm2, modulus of elasticity of 17.6 t / mm.
Thus, in the proposed method, a mesophase pitch is obtained, having a softening temperature according to Mettler of 289-310 ° C and containing 95-100% of the mesophase.

权利要求:
Claims (1)
[1]
Invention Formula
A method for producing mesophase pitch by hydrogenating a high molecular weight starting bituminous material at elevated temperature and pressure in the presence of a hydrogen donor solvent, followed by heat treatment of hydrogenation at 390-470 ° C for 5-80 minutes
obtaining the target product, characterized in that, in order to improve the quality of the target product, ligroin tar or
coal tar, or a heavy component obtained from coal tar by single evaporation, in the case of using the last two bituminous materials, they are pre-extracted with xylene in a mass ratio of 1: 2-3 to obtain a product containing 0.4-2.2 wt.% xylol soluble compounds, the bituminous material is heat treated in a tubular heater
at 470-530 ° C and 2-3 MPa, if necessary in the presence of an absorption oil having a boiling range of 240-280 ° C. not containing compounds that are not soluble in xylene, taken in a mass ratio
with the material 0.17-0.76: 1 to obtain a product containing 3.5-15.9% by weight of xylene-insoluble compounds, which is then treated with xylene, taken in a mass ratio of 2-4: 1 and fed for hydrogenation carried out in the presence of a hydrogen donor - hydrogenated anthracene oil or tetrahydroquinoline, the hydrogenation is heat treated to obtain the desired product having
The softening temperature according to Mettler is 289-310 ° C and containing 0.2-7.9% by weight of chilin-insoluble compounds, 3.6-9.4% by weight of xylene-soluble compounds and 95-100% of the mesophase.
45
Table 1
Continued table. one
table 2
Table 3
Table 4
. Continued table. four
Table 5
Table 6
Table 7
Continued table. 7
Table 8
Table 9
21
1676455
22 Table 10
Ta bl and tsa 11

类似技术:

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同族专利:

公开号 | 公开日

DE3765836D1|1990-12-06|

CN87103595A|1988-02-24|

US4820401A|1989-04-11|

NO170224B|1992-06-15|

AU594769B2|1990-03-15|

EP0246591B1|1990-10-31|

JPH048472B2|1992-02-17|

NO170224C|1992-09-23|

AU7315187A|1987-11-26|

JPS62270685A|1987-11-25|

CA1264692A|1990-01-23|

KR930005525B1|1993-06-22|

NO872035L|1987-11-20|

NO872035D0|1987-05-15|

CN1008444B|1990-06-20|

KR870011225A|1987-12-21|

EP0246591A1|1987-11-25|

引用文献:

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RU2598452C2|2012-01-12|2016-09-27|ЭКО Энвайронментал Энерджи Ресёч Инститьют Лимитед|Process for producing mesophase pitch by hydrogenation of high-temperature coal tar|

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JPH0328473B2|1983-02-23|1991-04-19|Mitsubishi Petrochemical Co|

JPS6335195B2|1983-04-22|1988-07-13|Kogyo Gijutsuin|

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JPH0359112B2|1985-01-16|1991-09-09|Fuji Sutandaado Risaachi Kk|

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US4759839A|1985-10-08|1988-07-26|Ube Industries, Ltd.|Process for producing pitch useful as raw material for carbon fibers|JPH0354997B2|1985-04-16|1991-08-21|

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JP2535207B2|1988-06-30|1996-09-18|日本石油株式会社|Pitch-based carbon fiber having excellent compression properties and method for producing the same|

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法律状态:

优先权:

申请号 | 申请日 | 专利标题

JP61114221A|JPH048472B2|1986-05-19|1986-05-19|

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