Process and reactor for producing synthesis gas

专利摘要:
Synthesis gas is manufactured by burning a fuel in an atmosphere containing a deficiency of oxidiser, the said oxidiser being gaseous, the said apparatus comprising first means for introducing the fuel and part of the oxidiser into a reactor. …<??>The apparatus is characterised in that it comprises second means for introducing a second part of the oxidiser into the reactor (1), these second means comprising a porous wall (7, 30), the said porous wall defining at least one part of the reactor. …<??>The present invention may be applied to the manufacture of synthesis gas from natural gas and oxygen. …<IMAGE>…
公开号:SU1634127A3
申请号:SU874355034
申请日:1987-12-17
公开日:1991-03-07
发明作者:Гато Поль；Мот Мишель；Фегье Ален；Пертюис Эдмон
申请人:Энститю Франсэ Дю Петроль (Фирма)；
IPC主号:

专利说明:

. The invention relates to a flame method method and apparatus for producing synthesis gas.
The aim of the invention is to intensify the process.
Figure 1 shows the reactor, including a cylindrical porous wall, a longitudinal section; 2 is a two-part reactor, longitudinal section; Fig. 3 shows a reactor consisting of several reaction zones with walls of porous material, a longitudinal section; in fig. 4 - section A-A in FIG. 3 in FIG. 3 - a porous element in the form of several blocks; figure 6 is a porous element with a partition; Fig.7 - section BB in Fig.6.
The reactor 1 contains a burner (nozzle) 2, which may consist of several tubes 3. Some of these tubes can serve to introduce an oxidizing gas containing oxygen, and others to introduce a fuel.
The pipes 3 (Fig. 1) serve to introduce oxygen and there are free spaces 4 between the pipes, which serve to introduce the gas to be converted (methane).
Gases can be supplied to nozzle 2 via conduit 5 (combustible gas) and conduit 6 (oxidizing gas).
The nozzle 2 is located in a cylindrical porous casing 7. This casing includes a conduit 8 in its upper part for outputting eluents.
A porous jacket (jacket) 7 with a burner (nozzle) located at its lower end separates the reaction zone 9.
The porous casing (jacket) 7 itself is included in a sealed enclosure 10 equipped with a pipeline 8 for the withdrawal of eluents and pipelines 5 and 6
ABOUT
with
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for loading the burner with methane and oxygen.
In addition, this enclosure is charged with an oxidizing gas (oxygen) through line 11.
The reactor operates as follows.
Oxygen entering through conduit 11 enters it 12 and passes through the porous wall, thus supplying oxygen through it. Oxygen enters the reaction zone 9 and participates in the reaction to achieve complete methane conversion to CO, Hg, CCY and
The amount of oxygen that is introduced into the reaction zone 9 through the pipeline 6 of the nozzle 2 is not enough to effect the complete conversion of methane, and the oxygen penetrating 20 through the porous casing 7 is not enough to realize the complete conversion.
The porous casing 7 may have a variable porosity, depending on which one or the other 25 site of the reaction zone 9 is loaded, in order to vary the input rate at different points of the reaction zone 9. For example, the porosity may vary along the axis of the reactor 1.30
This change in porosity can be achieved especially by combining modular elements 13, such as slabs or bricks of various sizes of porosity. 15
At the level of the Nozzle 2, the porous wall can be continued by means of hermetic walls or the same nozzle body 2.
Water vapor or any other gas can also be introduced into reaction zone 9 to supplement the process. This can be realized either through the pipeline 6 of the burner, or through the pipeline 1 loading zone 12. 45
The inner walls of the housing may preferably be covered with a protective, anti-radiation layer 14 or thermal protection.
This device has several CQ benefits. The gas that passes through the porous wall is heated and thus cools this wall. However, when producing synthesis gas, the walls are too cold.
55
excluded because they reduce the conversion efficiency (freezing the reaction) and can lead to carbon accumulation. R this case
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In this case, oxygen that diffuses creates a boundary reaction layer capable of protecting the wall colder from the gases during the conversion process.
It is possible to introduce a portion of the oxygen at a distance from the nozzle 2. The combustion at the exit of the nozzle 2 is much more abundant, since there is not enough oxygen in there to be sufficient for complete conversion.
Thus, combustion at the level of the nozzle 2 is carried out at a lower temperature, thus protecting the burner.
Oxygen is gradually introduced through the porous jacket 7 to supplement the conversion.
The temperature of the effluent from the burner is lower than that which would have been obtained if all the conversion products were introduced through a nozzle.
In addition, it is possible to increase the diffusion rate in the most loaded part of the wall due to heat exchange, and this affects the porosity of this part of the wall.
In the proposed reactor, it is possible to exclude the introduction of oxygen preheated to very high temperatures to feed the burner.
The first part 15 is limited to the part of the elongated element 16, which may be made of refractory material.
Burner 2 is placed at the lower end 17 of the elongated element 16. At the other (upper) end 18 of the element 16, there is an opening 19 through which the second part of the reactor 20 is loaded, which covers the upper end 18 of the elongated element 16 and is bounded by the outer wall 2 of the elongated element 16, a cylindrical casing 22 of refractory material, and a dome 23 or a spherical segment that rises above this cylindrical casing 22 to cover the upper end 18 of the elongated element 16..
The dome 23 is placed opposite the outlet 19 to discharge the eluents from the first part of the reactor.
This opening is located along axis 24 of the burner, which also represents the axis of the reactor.
The stream leaving the orifice 19 is deflected towards the dome 23 by 180 and moves into the second part of the reaction.
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tor.1 20, follow along the internal THRU of the elongated element 16 to exit through the pipelines 25.
The dome 23, which is a shielding wall, is made of a porous material, in some cases refractory, and serves to introduce another part of the oxidizing gas through the nozzle pipe 26.
The surface 27 of the dome 24, which does not limit the reactor, is surrounded by a hermetic housing 28, which defines the chamber 29.
Chamber 29 is loaded with an oxidizing agent (oxygen) through line 30. Oxygen diffuses through the porous wall of the dome 23 and oxygenates the second part of the reactor 20.
The hermetic housing 28 enters the outer housing 31, which encloses the entire reactor, including pipes 30 for introducing oxygen, pipelines 25 for withdrawing flow into the chamber for nozzle 2.
The nozzle 2 is a multi-tubular or other type, and therefore contains several pipes 32 for injecting fuel (natural gas). It enters the burner 2 through the pipeline 33.
The oxidant (oxygen) is introduced into the first reactor over a gap of 34, remaining free between the nozzle pipes 32.
According to this method of implementation
the soot leaving the first reactor is collected on a porous dome-shaped wall.
The soot layer is increased by coalescence, and in fact the soot can be more easily assembled on this wall.
In a porous dome 23 in contact with the reactor, the oxygen passing it is preheated, which allows for additional oxidation of the soot collected on the inside of the dome. The catalytic effect of a porous material, which may include, for example, zircon, may also be taken into account.
The soot is retained on the porous wall, re-incinerated by an oxidizing agent, which seeps through the pores. However, the shape of the reactor (Fig. 1) is unfavorable for adhesion. The shape of the reactor, represented by 1 lenna in FIG. 2, is more efficient,
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moreover, the soot gets on the gta surface of the surface 27 through the opening 19, but a part of the soot is subjected to an effort to be carried away with eluents.
Ways of making a porous wall facilitate the adhesion of soot and its subsequent removal due to oxidation due to an oxidizing agent penetrating through these porous walls.
According to these implementation methods, the surface / volume ratio is increased.
Porous element 35 (FIG. 3) contains a plurality of primary channels 36 for passing synthesis gas and secondary channels 37 for introducing an oxidant that must pass through the porous element 35. The primary and secondary openings have a Larm channel, more precisely, pipes. The secondary channels 37 can be loaded with an additional oxidizing agent through the loading chamber 38, bounded by a housing 39, surrounded by another housing 40 in which the porous element 35 is located. The housing 40 has openings 41 for loading the secondary channels 37.
The soot that deposits on the walls of the primary channels 36 is oxidized by an oxidizing agent that passes from the secondary channels 37.
The porous element 35 can be single-block or multi-block, which facilitates industrial implementation.
The porous element is realized by stacking several porous sub-elements 42 and 43. Each of these elements has channels 44, which form the primary channels after the stacking of these sub-elements into the primary channels.
The secondary channels are realized by means of straight drainage channels 45, which in certain cases act in conjunction with the spikes 46.
The interface plane 47 can also be as it is, or coated with a layer (porous or not) to fill the gap.
This layer may be of refractory mortar.
If the porosity of the subelements 42 and 43 is sufficient, then this layer is not needed, since part of the gas that passes the interface plane is insignificant compared to that which diffuses into the pores.
 The shape of the primary and / or secondary channels can be varied, especially to realize the best soot trapping and / or better distribution of the additional oxidizing gas, and / or to increase the surfaces of exchanges.
The channels can be provided with partitions 48.
Channels can be offset and have different diameters.
Formula and h

权利要求:
Claims (10)
[1]
1. A reactor for producing synthesis gas, including a vertical housing for means for introducing oxidant and fuel and outputting the finished product, is also distinguished by the fact that, in order to intensify the process, it (provided with additional means
to introduce an additional oxidant stream, made in the form of one or more porous walls, dividing the reaction space into sections.
[2]
2. The reactor according to claim 1, about tl and h a - n and k so that the porous wall is made as a cylindrical cup with a means for introducing fuel
and part of the oxidizing agent, while the porous glass is provided with a conduit for discharging products.
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[3]
3. Renctor on PP. 1 and 2, which is based on the fact that the bottom of the porous cylinder is partially porous to supply part of the oxidant.
[4]
A. A reactor according to claims 1-3, characterized in that the porous takanes are mounted concentrically, while the outer glass with its cylindrical walls tightly adjoins the inner wall of the reactor.
[5]
5. Reactor according to claims 1-4, characterized in that the porous wall is made of a material having catalytic properties, such as zircon.
[6]
6. Reactor according to claims 1-5, characterized in that the porous walls are made of monoblocks.
[7]
7. The reactor according to claims 1-6, which is based on the fact that the porous walls are made of porous elements mounted on each other.
[8]
8. The reactor according to claim 7, characterized in that drainage channels and / or spikes are made in porous elements.
[9]
9. A method of producing synthesis gas by burning a fuel with a lack of oxidizing agent in the gas phase, characterized in that, in order to intensify the process, an additional stream of oxidizing gas is introduced.
[10]
10. Method pop.9, which differs in that the additional oxidizing gas stream contains oxygen and water vapor.
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法律状态:

优先权:

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申请号 | 申请日 | 专利标题

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FR8617926A|FR2608581B1|1986-12-18|1986-12-18|FLAME-OPERATING METHOD AND DEVICE FOR THE MANUFACTURE OF SYNTHESIS GAS|

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