• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    1. A sheet of transparent plastics material of high optical quality comprising a layer based on polyurethane having energy-absorbing properties, characterised in that the layer having energy-absorbing properties is formed essentially of a polyurethane obtained by reactive casting on a flat horizontal support of a reaction mixture of an isocyanate component of viscosity less than 5 Pas at 40 degrees C and a polyol component, the isocyanate component comprising at least one aliphatic or cycloaliphatic di-isocyanate or an isocyanate prepolymer, the isocyanate component containing urea functions, the content of urea being up to 10% of the total weight of isocyanate component, the content of urea preferably being from 5 to 7%, the polyol component comprising at least one long difunctional polyol of molecular weight from 500 to 4000 and at least one short diol as a chain lengthening agent, the ratio of isocyanate group equivalents to hydroxyl group equivalents is about 1, the proportions of the different polyols are selected such that the number of hydroxyl group equivalents due to the short polyol represents from 20 to 70% of the total hydroxyl groups, and this layer having at a thickness of about 0.5 mm, a flow stress sigma y at -20 degrees C not exceeding 3 daN/mm**2, a rupture stress sigma R at 40 degrees C of at least 2 daN/mm**2, a lengthening at rupture vepsiln R at + 20 degrees C from 250 to 400%, and a tear resistance Ra at + 20 degrees C of at least 9 daN/mm.
    公开号:SU1611212A3
    申请号:SU843768329
    申请日:1984-07-10
    公开日:1990-11-30
    发明作者:Браве Жан-Луи；Кольмон Даниель；Дод Жерар；Моншо Мишель-Жан
    申请人:Сэн-Гобэн Витраж (Фирма)；
    IPC主号:
    专利说明:

    The invention relates to a composition for the manufacture of a sheet that can be used to obtain a laminated glass, consisting of a single layer of silicate glass and at least one layer of plastic and intended, for example, to be used as a windshield.
    The aim of the invention is to improve the optical quality of the laminated glass.
    PRI me R 1o 75.6 May,% of a mixture of polytetramethylene glycol mol, .may 1000 and butanediol-1, 4, with cooTHoiiieiinn hydroxyl equivalents of 0.37: 0.63, is mixed with 0.66 weight ,. % Bis (2,2,6,6-tetramethyl-4-piperid1sh) -Sells 1Npt as a stabilizer, 0.05 weight Z horse resin as an improved rheological cBoficTBa at-yelt and 0.02 weight, % dilaurate.) jiuoyTiL-io. iiJisa as kata. P1zpto} 1a i iKviyxjeiiHoi i in such a way,; o ()., I, 4ioT
    o y
    s
    23.67 nec ,,% 3-exc) 11, and anatomical) 11) 1-3, b, 5-trimethylcyclohexane poghexl pdiispssimat, containing urine groups and pzocyanatnie groups in the amount of 31, 5% s Get the composition, in which the equivalent ratio of isocyanate and hydro strong groups is 1 s
    After degassing and in vacuum, the mixture heated to 40 ° С, with a thickness of 0.775 mm is poured with POMATS-E of the lithium head onto a movable carrier substrate coated with a separating layer, followed by polymerization at 120 ° C for 35 minutes after polymerization of the abrasive1 The film is removed from the substrate. It can be stored or used directly to make multilayer glass.
    The mechanical properties of laminated glasses manufactured using the film of Example 1 are determined as follows.
    The film is placed on a glass thickness of 256 mm. The connection of the two layers is carried out in two stages. During the first stage, the preliminary connection is made by passing the 1-compound between the two rollers of the rolling machine, during the second stage, c1, the obtained two-layer glass is placed in an autoclave, where it is held for about 1 hour under pressure. about 10 bar and at about 135 ° C.
    The resulting two-layer glass is completely transparent,
    The adhesion between the glass layers and the polyurethane film is determined in the following way:
    A 2 cm thick goirin band is drawn out of a two-layer glass. One end of this band is fixed and pulled in a direction perpendicular to the surface of the glass at a speed of 5 cm / mitg. The test is carried out at about. The value of the average pull force is recorded, neo for the separation of the stripe. This value is 10 daN / 5 cMo.
    Testing for impact strength at different temperatures is also carried out. The first test for impact resistance is carried out with a steel ball weighing 2.260 kg (test with a heavy ball), which falls on the central part of the sample, which forms the shape of a square with a side of 30J5 cm and fixed in a rigid frame. The height of the p, 1 day is measured approximately. At KOTOpoii, 90% of the samples are not punched by the ball.
    five
    0
    5 n
    Q
    g
    5 5
    0
    through LL of double-layer glass, obtained in the described manner, this height is 12 m. The second test for impact strength is carried out with a steel ball weighing 0.227 kg and 38 mm in diameter (test with a light ball). One test is carried out at a temperature of - 20 ° C, and the second at a temperature of 40 ° C. The obtained results are 12 and 11 m, respectively. The resistance of the double layer glass is 32 g. After the abrasive of the 1st treatment, the film shows a transparency deviation of 0.94%. The scratch resistance is determined as follows: the magnitude of the load on the diamond head needed to produce a scratch in a film connected to a glass substrate is measured.
    Abrasion resistance is measured according to European standard P42. For this purpose, the sample is subjected to an abrasive treatment with an abrasive aid. After 100% of the abrasive wheel, the deviation of transparency with the abrasive part treated with the abrasive circle and the untreated part is measured using a spectrophotometer.
    Example 2o Example is repeated.
    I with the difference that a mixture of polytetramethylene glycol molomaso1000, 1,4-butanediol and caprolactonolol dosage with a ratio of hydroxyl equivalents of 0.35: 0.55: 0.100 is used as the polyol component; ,%, stabilizer in the amount of 0.5 wt%, and the isocyanate component - in the amount of 24.08 weight „%. 11o.t students take part in gshenku 0.66 mm with
    Mechanical properties of double-layer glass manufactured using npiiMepa 2 film: adhesion
    I1daN / 5 cm; 11 m durability with a ball test and 13.5 and 13.5 m with a light ball test at -20 and 40 C, respectively; scratch resistance 35 g; transparency deviation at abrasive processing 1, 2% „
    Example 3: Example 1 is repeated with the difference that polytetramethylene glycol mol, May, 1000, 1,4-butanediol and polycaprolactone triol are used as a polyol component with a ratio of PVDROX equivalent of 35, O, 45: O, -20 . With
    In this, the polyol component is used with an IB amount of 75.84 VECo%, a stabilizer in the amount of 0.5%, and an isocyanate component in the amount of 23.59 wt.% “The resulting composition is processed into a film with the total 51: 0.70% mm Mechanical properties of double-layer glass made using the film of example 3: adhesion 11 daN / 5 cm; strength is 8 meters for a dough with a hard ball, 11 and 11 s for a dough with a light ball at -20 and +40 C, respectively, scratch resistance 35 g; abrasion tolerance due to abrasion 1.2% „
    Example 4 (comparative) Example 1 is repeated, with the difference that polyetherdiol based on adipic and sebaic acids, caprolactone, 2,2-dimethyl-1,3-propanediol and 1,4-butadiol — is used as the polyol component. .
    The mechanical properties of the double-layer glass produced using comparative example 4 are as follows: clutch 8 daN / 5 cm; 8 m ball test; test with a light ball 9.5 and 9 m; scratch resistance 2.2 g; transparency deviation 3% 0
    Example 5o Example 1 is repeated with the difference that diazabicyclo (2.2, 2) -octane is used as a catalyst, and bis (2,2,6,6-tetramethyl-4-M-methyl-pi-) as a stabilizer. peridyl) -sebacinate, and as an improving rheological agent, it is a fluoroalkylated ester product (trading product Flurade GS 430 of foreign company ZM)
    The following results are obtained: clutch. 10 daN / 5 cm; impact strength of 12 and 12 and 11 m, respectively; scratch resistance 31.9 g; transparency deviation of 0.94%. Example b The example is repeated, 1 with the difference that 2- (4-hydroxy-5-methyl-phenyl) -2H-benzotriazole and penta-erythryl-tetrakis are used as stabilizers. 3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate
    The following results are obtained: a clutch of 10 daN / 5 cm; impact strength of 12, 12 and 11 m, respectively in one and the other cases
    Example 7: Example 1 is repeated with the difference that, as a poly,

    112126
    The molar component uses a mixture of polytetramethylene glycol mol. mas, YOS 1,4-butanediol and the condensation product of polypropylene glycol moloma about 250 and dimeric acids - a mixture of new, stearic, oleic and linoleic with molomas. 210 with a ratio of hydroxyl equivalents of 0.35: 0.55:, d: 0.10 “The following results are obtained: a clutch of 10 daN / 5 cm; impact strength of 11, 13.5 and 13.5 m, respectively; scratch resistance 34.5 g; transparency deviation 1s, 1% o, 15 Example 8 (comparative). Example 1 is repeated, with the difference that 75.60 weight% polytetramethylene glycol mol masO 1000 1000 are used as the polyol component. The following results are obtained:
    grip 8.5 daN / 5 cm;-impact strength of 8.5, 9.5 and 9.5 m, respectively; scratch resistance 23 g; transparency deviation 2.8% 25 Example 9 (comparative) o
    Example 1 is repeated, with the difference that polyetherdiol based on adipic and sebacic acids, calrolac-3Q tone and 2,2-dimethyl-1,3-propanediol „is used as a polyol component.
    The mechanical properties of a two-layer glass made using a film of example 9 are: a grip of 7.5 daN / 5 cm; test with a ball of 7 m; the test with a light ball of 8.5 and 8 m; scratch resistance 19 g; transparency deviation of 3%, -
    40
    权利要求:
    Claims (1)
    [1]
    Invention Formula
    A composition for producing a polyurethane sheet used to make laminated glass, including
    3-isocyanatomethyl-3,5,5-trimethylcyclohexyldiisocyanate, 31.5% urea groups and isocyanate groups, a polyol component, a catalyst, a stabilizer derived from organic yuli and an agent that improves rheological properties — an resin that is characterized by that, in order to improve the optomechanical characteristics of laminated glass, as a polyol component it includes a mixture of molomeso 1000 and 1,4-butanediol polytetra at a ratio of hydroxyl equivalents
    0.3 /: and, 63, or a mixture of yolite-polymer and iglyode mol.m., 1000, 1,4-but-tnndol and polycaprolitriitriol i) the ratio of hydroxyl steroids alents 0.35: 0.45- 0.55: 0.10–0.20 structurally, or a mixture of hyulitetramethylene-- g: lycol mole on May, 1000, 1, 4-butanediol and non condensation product nogashenglykol mol.mee, 250 and a mixture of palmitic stearic, oleic, and linoleic acids with a molar content of 210 prn and a ratio of hydroxyl equivalents of 0.35: 0.55:: C, 1, respectively, do1 butyldylau: 1at-tin or diazabi as a catalyst; octane, as stabil tora bis (2 52,6,6-tsgramethyl-4-pineridsh1) seba) pcs, bis- (2,2,6,6-tetramethyl-4-N-methyl-p1teri-dsh1) -eba1 2- (4 hydroxy-5-methylfe
    Nile) -211-benzotrilgkig or ient-viewer-te-n) akis-3- (3 ,,, he-butyl-4-oxy-fenchO-nronionate, and as yru ruia-U1: (its rheological properties of the agent SILICONONUT .,) resin with lUiOTFrOCTblO
    0.95 g / cm 3 at 4 °;
    3-Isocyanatomes1- 3,5, 5-trimethyl1 and 1C-hexyl diisocyanate Polyolyl: Component C but on the other hand) But it improves the properties of the agent Catalyst
    23.59-24.08 75.35-75.84 0.5-0.66
    0.05 0.02
    The ratio is from; i1natny. and iroxyl equivalents are 1.
    类似技术:
    公开号 | 公开日 | 专利标题
    US4705721A|1987-11-10|Polyurethane-based adhesive coating or film, and use of same in laminated glass panes
    FI80255C|1990-05-10|Laminate glass intended for use as a safety glass
    SU1517756A3|1989-10-23|Laminated glass
    US3808077A|1974-04-30|Method for laminating plastic to glass employing glass mold
    US4784916A|1988-11-15|Bilayer windshield and preformed two-ply sheet for use therein
    US4997901A|1991-03-05|Reaction curable composition comprising a polyisocyanate component and a polyol component
    SU1611212A3|1990-11-30|Composition for producing polyurethane sheet for laminated glass
    US4379904A|1983-04-12|Novel polyurethane product
    EP2236536B1|2012-11-28|Polyurethane |and methods of preparation
    US4921759A|1990-05-01|High optical quality transparent sheet of plastic which is scratch- and abrasion-resistant, method of manufacturing the same and glazings using the same
    JP2559396B2|1996-12-04|Transparent glazing with a flexible elastic polyurethane coating
    US4741961A|1988-05-03|Polyurethane-based adhesive coating or film, and use of same in laminated glass panes
    US4241140A|1980-12-23|Laminated safety glass with polyurethane film
    US4404353A|1983-09-13|Urethane elastomer for printing belts and process therefor
    SU1491326A3|1989-06-30|Laminated glass
    GB1558453A|1980-01-03|Manufacture of heat-resistant polyurethane elastomers
    CA1253286A|1989-04-25|Prepolymer for low heat buildup polyurethanecompositions
    US4732725A|1988-03-22|Process and device for the production of a safety pane
    KR970006670B1|1997-04-29|Process and device for the manufacture of high optical quality transparent plastic film
    US5047494A|1991-09-10|Castable polyurethane elastomers chain extended with 2,3-bis|bicyclo[2,2,1]heptane
    JPH07196913A|1995-08-01|Moisture-setting urethane sealant composition
    JPH05213058A|1993-08-24|Shield for window of soft plastic and manufacture thereof
    JP2012102151A|2012-05-31|2 pack-curing type molding composition for aliphatic polyurea resin
    MXPA99011641A|2000-07-01|Composite elements comprising | thermoplastic polyurethane and | polyurethane microcelute elastomer
    同族专利:
    公开号 | 公开日
    CS534984A2|1988-07-15|
    FI842767A0|1984-07-10|
    NZ208855A|1987-10-30|
    NO161966C|1989-10-18|
    FI77253C|1989-02-10|
    KR850001512A|1985-03-30|
    DE3468649D1|1988-02-18|
    PH23091A|1989-04-10|
    CS261870B2|1989-02-10|
    ZA845291B|1986-10-29|
    AU3045584A|1985-01-17|
    FR2548956B1|1985-10-18|
    KR920002355B1|1992-03-23|
    YU120884A|1986-12-31|
    EP0133090B1|1988-01-13|
    AU575330B2|1988-07-28|
    BR8403427A|1985-06-25|
    MA20176A1|1985-04-01|
    DK337284A|1985-01-12|
    MX171709B|1993-11-10|
    PT78884B|1986-06-05|
    ES8507380A1|1985-09-01|
    HUT40383A|1986-12-28|
    IL72361A|1988-01-31|
    EP0133090A1|1985-02-13|
    FI77253B|1988-10-31|
    NO842803L|1985-01-14|
    HU212186B|1996-03-28|
    IN160868B|1987-08-08|
    FR2548956A1|1985-01-18|
    ES534173A0|1985-09-01|
    JPS6071213A|1985-04-23|
    JPH0464849B2|1992-10-16|
    YU44236B|1990-04-30|
    NO161966B|1989-07-10|
    CA1245798A|1988-11-29|
    FI842767A|1985-01-12|
    DK337284D0|1984-07-09|
    PT78884A|1984-08-01|
    AT31898T|1988-01-15|
    IL72361D0|1984-11-30|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    US9593200B2|2012-08-06|2017-03-14|Kuraray Co., Ltd.|Thermoplastic polyurethane and a composition thereof|US4024113A|1976-04-28|1977-05-17|Ppg Industries, Inc.|Polycarbonate polyurethanes based on particular aliphatic/cycloaliphatic polycarbonates|
    DE2629779C3|1976-07-02|1985-04-04|Saint Gobain|Process for the production of a two-layer film with self-healing properties using polyurethanes as a shatterproof layer on safety glass|
    FR2385751B1|1977-03-28|1980-12-26|Ppg Industries Inc|
    FR2442128B1|1978-11-23|1981-06-26|Saint Gobain|
    CA1174577A|1980-04-30|1984-09-18|Vernon G. Ammons|Polyurethane composition for safety glass interlayer|
    FR2496089B1|1980-12-11|1984-08-24|Saint Gobain Vitrage|
    DE3135672A1|1981-09-09|1983-03-24|Bayer Ag, 5090 Leverkusen|Use of low-viscosity self-curing mixtures for polyurethane interlayers in laminated panes|US4592947A|1984-06-04|1986-06-03|Sierracin Corporation|Low temperature laminatable polyurethane|
    FR2574396B1|1984-12-06|1987-01-02|Saint Gobain Vitrages Sa|COATING LAYER HAVING SELF-HEALING PROPERTIES FOR WINDOWS ESPECIALLY EXPOSED TO ATMOSPHERIC AGENTS|
    FR2577935B1|1985-02-26|1988-06-17|Saint Gobain Vitrage|POLYURETHANE-BASED ADHESIVE LAYER AND ITS USE IN LAMINATED GLAZING|
    FR2579609B1|1985-03-28|1987-08-21|Saint Gobain Vitrage|HIGH OPTICAL SELF-ADHESIVE SHEET|
    IT1204812B|1986-02-19|1989-03-10|Siv Soc Italiana Vetro|PROCEDURE FOR THE MANUFACTURE OF A SAFETY GLASS FOR VEHICLES AND BUILDINGS, AND PRODUCT SO OBTAINED|
    FR2623120B1|1987-11-12|1990-04-27|Saint Gobain Vitrage|PROCESS AND DEVICE FOR MANUFACTURING A SHEET OF HIGH OPTICAL QUALITY PLASTIC MATERIAL COMPRISING A POLYURETHANE LAYER OBTAINED BY EXTRUSION AND PRESSING|
    FR2644468B1|1989-03-20|1992-12-31|Saint Gobain Vitrage|POLYURETHANE LAYER HAVING ENERGY ABSORBER PROPERTIES AND USE IN SECURITY GLAZING|
    LU88270A1|1993-05-17|1994-12-01|Wesley S A|Transparent polyurethane film - is made by depositing a reaction mixt. of a polyether polyalcohol, di:isocyanate and chain extender on a support|
    US7072115B2|2002-03-26|2006-07-04|Keiwa Inc.|Light diffusion sheet and backlight unit using the same|
    US7294401B2|2003-09-02|2007-11-13|E. I. Du Pont De Nemours And Company|Mar-resistant oligomeric-based coatings for glass-plastic glazing products|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    FR8311508A|FR2548956B1|1983-07-11|1983-07-11|HIGH OPTICAL QUALITY TRANSPARENT PLASTIC SHEET|
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