• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    This invention relates to an insecticidal agent in the form of an emulsion concentrate. The invention makes it possible to increase insecticidal activity by 20-65% through the use of an agent containing, in wt.%: The active substance is a compound of the formula, CH N-CX CH-CH ; deg; CH-Nj, where X is cyano, trifluoromethyl or 2,2,2-trifluoroethoxy, m 2 or 3, 20; the solvent is xylene 60; emulsifier - polyoxyethylene alkylphenyl ether 20, as compared with the known agent based on 1- (4-chlorophenyl) -2-nitromethylene-tetrahydropyrimidine. 2 tab. § ABOUT)
    公开号:SU1435139A3
    申请号:SU864027973
    申请日:1986-08-20
    公开日:1988-10-30
    发明作者:Шиокава Козо；Тсубои Шинихи；Кагабу Шинзо；Мория Коихи；Баазнер Бернд
    申请人:Нихон Токушу Нойяку Зейцо К.К. (Фирма)；
    IPC主号:
    专利说明:

    four
    00
    ate
    WITH
    with
     cm
    1U
    The invention relates to chemical plant protection agents, namely, insecticidal agents in the form of an emulsion concentrate based on a 1- (substituted methyl) -2- -nitromethylene-1,3-diazo-tetrahydroheterocyclic derivative, solvent and emulsifier.
    The aim of the invention is to increase the insecticidal activity of the agent.
    Derivatives of 1- (substituted methyl) - -2 Nitromethylene-1,3-diazo-tetrahydroheterocyclic compounds Formulas
    (CH,) / CHNOj (I)
    SI
     --N
    where m 2 or 3;
    X - cyan, trifluoromethyl, 2,2,2-trifluoroethoxy,
    is obtained by reacting approximately equimolar amounts of the compound of Formula
    jgj- CH2-BH- (-n Ng
    X n
    in which Hit have the indicated 3sia,
    with compound of formula
    R-s.
    H-S
    X CHNOg
    where R is lower alkyl or benzyl
    or both groups, R together means alkylene with at least two carbon atoms, in the presence of an inert solvent 45 at a temperature of from -29 to the boiling point of a mixture or compound of the formula
    (d)
    seko2
    where m has the specified value, with the compound of the formula
    .-§
    d
    five
    0
    five
    0
    five
    0
    five
    0
    five
    where h has a decree: values;
    Y is halogen or, where R -} is shzshee alkyl or aryl, in the presence of an inert solvent (except water and alcohols) and a base (sodium, potassium hydrides) at a temperature of 0-100.
    Compounds (I) are obtained by these methods, presented in Table. one,
    The following example illustrates the high effectiveness of the proposed funds. In this example, along with the proposed agents, a known agent is used containing 1- (4 chlorophenyl) -2-nitromethylene-tetrahydropyrimidine (compound A) -
    Example. Experience with Nilaparvata lugens, Sogatella furcifera N Horvath and Laodelphax striatellus.
    GO us.A. xylene, 20 wt.%, polyoxyethylene alkylphenyl ether and 20 wt.% of the compound are vigorously stirred. The emulsion concentrate thus obtained is diluted with water to a concentration of the active substance of 40 ppm. Rice plants 10 cm high planted in 12 cm pots are sprayed with 10 ml of insecticidal agent per pot. The plants are left to stand until the applied product dries, then they are covered with a wire basket 7 cm in diameter and 14 cm high, under which 30 adult females of the named insects are served. The pots are left to stand in a room with a constant temperature. After 2 days, the degree of killing is determined in percent relative to the control (untreated plants).
    The results of the experiments are given in table. 2
    权利要求:
    Claims (1)
    [1]
    Formula of gain
    Insecticidal agent in the form of an emulsion concentrate containing the active .. s-ingredient is a derivative of 1- - (substituted methyl) -2-nitrometsh1- -1,3-diazo-tetrahydroheterocyclic compound, the solvent is xylene and the emulsifier is polyoxyethylene-alkylphenyl ether, in the following ratio, wt.%; Active ingredient 20 Xylol60
    Polysyl carbonyl and alkylphenyl ether 20
    characterized in that, in order to increase the insecticidal activity, it contains as a derivative of 1- (substituted methyl) -2-nitromethylene-1,3-diao-tetrahydroheterocyclic compound
    Table 1
    类似技术:
    公开号 | 公开日 | 专利标题
    SU1435139A3|1988-10-30|Insecticide agent in form of emulsion concentrate
    SU518105A3|1976-06-15|Fungicide
    CZ278965B6|1994-11-16|Heterocyclically substituted alkylene quinolinyloxyphenoxypropenoates, herbicide containing such substance and process for suppression of undesired plant growth
    KR930021635A|1993-11-22|Novel fungicidal triazoles and imidazole derivatives
    US3409646A|1968-11-05|Aminoamides
    US2981619A|1961-04-25|Method of inhibiting plant growth
    HU176584B|1981-03-28|Herbicide preparation containing of active mateirals of two types
    JPH0647537B2|1994-06-22|Emulsifying concentrate containing azole
    US4068081A|1978-01-10|Δ-Triazine-2,6-dione
    US3754093A|1973-08-21|Method for protecting plants from powdery mildew fungus and fungicidal composition to be used therefor
    US3681406A|1972-08-01|N-alkoxyalkylidenesulfonamide compounds
    US3973945A|1976-08-10|Pyran-2,4-dione derivatives
    US4166854A|1979-09-04|Substituted 1-pyridinyloxy-1-|-2-butanone compounds and their use as fungicides
    US4596801A|1986-06-24|4H-3,1-benzoxazine derivatives, process for producing the same and agricultural or horticultural fungicide containing the same
    SU820646A3|1981-04-07|Herbicidic composition
    US3959469A|1976-05-25|Triazinedione compounds as fungicidal and bactericidal agents
    US4782053A|1988-11-01|Fungicidal compositions
    JP2819304B2|1998-10-30|Hexahydrotriazinone derivatives and selective herbicides containing the same as an active ingredient
    JPH03133959A|1991-06-07|Pyridylcyclopropane carboxamidine derivative, preparation of the same, fungicide composition including the same, and fungicidal method
    EP0152131B1|1989-08-23|Carboxamide derivatives, their preparation and their use as fungicides
    PL94896B1|1977-09-30|
    US3646210A|1972-02-29|Fungicidal and bactericidal composition and method containing 3-thiocyanoindole derivatives
    US4212869A|1980-07-15|Substituted 1-pyridinyloxy-1-|-2-butanone compounds and their use as fungicides
    SU1210650A3|1986-02-07|Herbicide |
    JPH01102070A|1989-04-19|Carbamoyltriazole derivative, its production, and herbicide containing the same as an active ingredient
    同族专利:
    公开号 | 公开日
    DK405786D0|1986-08-26|
    AU6187586A|1987-03-05|
    KR950005740B1|1995-05-30|
    BR8604076A|1987-04-14|
    DD249175A5|1987-09-02|
    DK405786A|1987-02-28|
    GR862189B|1986-12-23|
    US4812454A|1989-03-14|
    HUT42272A|1987-07-28|
    EP0212600A2|1987-03-04|
    KR870002127A|1987-03-30|
    EP0212600A3|1988-03-30|
    CN86106238A|1987-04-08|
    PH23068A|1989-03-27|
    ZA866448B|1987-04-29|
    ES2001396A6|1988-05-16|
    EP0212600B1|1991-11-27|
    US4772620A|1988-09-20|
    AT69815T|1991-12-15|
    JPH072736B2|1995-01-18|
    DE3682633D1|1992-01-09|
    AU583651B2|1989-05-04|
    JPS6248680A|1987-03-03|
    IL79830D0|1986-11-30|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    DE2514402A1|1975-04-02|1976-10-21|Hoechst Ag|INSECTICIDAL AGENTS|
    JPH0629256B2|1983-10-06|1994-04-20|日本バイエルアグロケム株式会社|Nitromethylene-tetrahydropyrimidine derivative, production method and insecticide, acaricide, sentinelicide|
    JPH032155B2|1984-02-16|1991-01-14|Nihon Tokushu Noyaku Seizo Kk|
    ZW5085A1|1984-04-13|1985-09-18|Nihon Tokushu Noyaku Seizo Kk|Nitromethylene derivatives,intermediates thereof,processes for production thereof,and insecticides|
    DE3681465D1|1985-02-04|1991-10-24|Nihon Bayer Agrochem K.K., Tokio/Tokyo, Jp|
    JPH07613B2|1985-02-12|1995-01-11|日本バイエルアグロケム株式会社|Nitromethylene derivative, its manufacturing method and insecticide|ZW5085A1|1984-04-13|1985-09-18|Nihon Tokushu Noyaku Seizo Kk|Nitromethylene derivatives,intermediates thereof,processes for production thereof,and insecticides|
    DE3681465D1|1985-02-04|1991-10-24|Nihon Bayer Agrochem K.K., Tokio/Tokyo, Jp|
    JPH07121909B2|1986-09-10|1995-12-25|日本バイエルアグロケム株式会社|Novel heterocyclic compound and insecticide|
    DE3717837A1|1987-05-27|1988-12-08|Bayer Ag|HETEROCYCLIC SUBSTITUTED 2--1,3-HETEROCYCLES|
    JP2583429B2|1987-11-06|1997-02-19|日本バイエルアグロケム株式会社|Imidazolines and insecticides|
    MY106503A|1989-12-28|1995-06-30|Ishihara Sangyo Kaisha|Imidazolidine derivatives, process for producing the same and pesticides containing the same|
    DE4232561A1|1992-09-29|1994-03-31|Bayer Ag|Fighting fish parasites|
    DE4414569A1|1994-04-27|1995-11-02|Bayer Ag|Use of substituted amines for the treatment of brain disorders|
    DE4426753A1|1994-07-28|1996-02-01|Bayer Ag|Means for controlling plant pests|
    US6828275B2|1998-06-23|2004-12-07|Bayer Aktiengesellschaft|Synergistic insecticide mixtures|
    DE19548872A1|1995-12-27|1997-07-03|Bayer Ag|Synergistic insecticidal mixtures|
    DE19622355A1|1996-06-04|1997-12-11|Bayer Ag|Molded bodies that release agrochemicals|
    DE19807630A1|1998-02-23|1999-08-26|Bayer Ag|Water-based composition useful for controlling parasitic insects and mites, especially lice, on humans|
    DE19823396A1|1998-05-26|1999-12-02|Bayer Ag|Synergistic insecticidal mixtures|
    US6149913A|1998-11-16|2000-11-21|Rhone-Poulenc Ag Company, Inc.|Compositions and methods for controlling insects|
    DE19913174A1|1999-03-24|2000-09-28|Bayer Ag|Synergistic insecticidal mixtures|
    US6156703A|1999-05-21|2000-12-05|Ijo Products, Llc|Method of inhibiting fruit set on fruit producing plants using an aqueous emulsion of eicosenyl eicosenoate and docosenyl eicosenoate|
    DE19948129A1|1999-10-07|2001-04-12|Bayer Ag|Active ingredient combinations with insecticidal and acaricidal properties|
    DE10024934A1|2000-05-19|2001-11-22|Bayer Ag|Pesticidal agent contains synergistic mixture of 3-aryl-4-hydroxy-2-oxo-pyrroline derivative and nicotinergic acetylcholine receptor agonist or antagonist|
    US20020103233A1|2000-11-30|2002-08-01|Arther Robert G.|Compositions for enhanced acaricidal activity|
    DE10117676A1|2001-04-09|2002-10-10|Bayer Ag|Pesticidal composition, useful for controlling fleas and ticks on animals, contains permethrin and imidacloprid, in N-methylpyrrolidone|
    EP1306374A1|2001-10-29|2003-05-02|Council of Scientific and Industrial Research|1--2-nitroiminoimadozolidine and a process for the preparation thereof|
    US8232261B2|2003-07-18|2012-07-31|Bayer Cropscience Lp|Method of minimizing herbicidal injury|
    DE102004006075A1|2003-11-14|2005-06-16|Bayer Cropscience Ag|Composition for controlling animal pests comprises a synergistic combination of a nicotinergic acetylcholine receptor agonist or antagonist and an anthranilamide derivative|
    AU2005245264B2|2004-05-13|2011-02-17|Bayer Intellectual Property Gmbh|Method for improving plant growth|
    AU2005290165A1|2004-08-25|2006-04-06|Bayer Cropscience Lp|Method of controlling termites|
    DE102004054960A1|2004-11-13|2006-05-18|Bayer Cropscience Ag|Fly gel bait|
    US9919979B2|2005-01-21|2018-03-20|Bayer Cropscience Lp|Fertilizer-compatible composition|
    CN102702082B|2006-11-30|2014-12-17|陶氏益农公司|Process for the preparation of 2-substituted-5- alkylpyridines|
    CN103524489B|2012-07-04|2018-02-09|华东理工大学|The synthesis technique of 2 chlorine 5imidazolidine 1) methyl) pyridines|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    JP60186592A|JPH072736B2|1985-08-27|1985-08-27|Nitromethylene derivative, its manufacturing method and insecticide|
    [返回顶部]