• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    1. COMPOSITION FOR BONDING A RUBBER WITH A HARD SUBSTRACT, including a polymer, p-dinitrosobenzene, pro, the interaction of the adduct with 1 mol of trimethylolpropane and 3 / mol of toluene dinzoyl shanate with butadiene oxime, emulsifier, zinc cement, zinc centane, and emulgator, octane-zinc, and custaric acid. water, characterized in that, in order to increase the safety of handling the composition without skirts, the adhesive strength of rubber with the substrate, the composition contains a copolymer of vinylidenehydride and methyl ester aca, as the polymer. rilic acid in a ratio of 85JI5: or a copolymer of butadiene and acrylonitrile. at a ratio of 70:30 and additionally polyvinylpyrrolidone at the following ratio of components, m.h.: A copolymer of vinylidene chloride and methyl acrylic ester in a ratio of 85:15 or a copolymer. . butadiene and: acrylonitrile in the ratio. 70: 30843 Polyvinylpyrrolidone 28 p-dinitrosobenzene 253 Adduct reactant product; mol of trimethylolpropane and 3 mol of CO with tolushlend1shzocyanate with butandIenoxime168 Emulsifier12 Zinc oxide8 Soot97 Antifoam8 Water154X583 2. The composition according to claim 1, about tl and h ay and ys so that it additionally contains a resol, or a water-soluble ophthalmic adm. 42 42 O) P1
    公开号:SU1050567A3
    申请号:SU802929446
    申请日:1980-06-09
    公开日:1983-10-23
    发明作者:Кольштадт Ганс-Петер；Нур Эцелли Рица；Гиренц Герхард
    申请人:Хенкель Коммандитгезельшафт Ауф Акциен (Фирма)；
    IPC主号:
    专利说明:

    And the acquisition relates to rubber impregnation, in particular, to compounds for bonding rubbers with a gesture. kimi prdlozhkami. The closest to the proposed is a rubber composition for adhering to a rigid substrate comprising a p-diiitrozob.enzol polymer, reacting the adduct product) Grim tilolprotsana mol and 3 mol of tolylene - diisocyanate with butadienoksimom, Gator, zinc oxide, carbon black, defoamer, and water, for example in a ratio of 10p: l55; 0.5: 3: 15: 0.5: lOOO tl 3However, this composition is dangerous in circulation, although it provides high adhesive strength of rubber with the substrate. The purpose of the invention is to improve safety in handling the composition without the adhesive strength of the rubber with the substrate. This goal is achieved by the fact that the composition for gluing rubber to a rigid substrate comprising p-dinitrosobenzene polymer. product of adduct interaction. 1 mole of trimethylpropanol and 3 moles of luylene diisoacetate with butadiene oxime, emulsification of zinc oxide soot antifoam and water as a polymer contains a 15.15 cophenimeric aperture or aryl aperture or acrylic acid anhydroxymethyl ester of acrylic acid; polyylpyrrolidone in the following ratio of components, wt .. h. : Vinyl-dichloride-methyl acrylic acid (PVDC / AM) copolymer in a ratio of 85:15 or a copolymer of butadiene and acrylonitrile (BA) in a ratio of 70:30 Polyvinylpyrrolidone (PVP) p-Dinitrosobenzene (DNB) Interaction product. . adduct 1 mol of trimethylolpropane and 3 mol of toluene diisocyanate with butadiene oxime (isocyanate) Emulsifier Zinc oxide (ZriO) Soot Antifoam (VOD) Water1541-1583 The composition may additionally compress the resole (FS) in water, which is also associated with the hydrofluoromeneellanter gauge and the gauge; Example. By dispersing the clothes, formulations J-VI are prepared, which are listed in Table 1. Table 1 3 Composition -Vl is used for rubber A-D rubbers with steel braces (qty. Qrs, qs., Rubber A) Natural rubber 100 Oxy zinc 10 Stearic acid 2 Phenyl-fj-naphthylamine 1 Pine resin 2 Soot 25 Dimethyldithiocarbamate of zinc 0,33-rs-3 - Sulfur 2.75 Vulcanization conditions: 10 min. Curing conditions: 30 min. 153 ° C. Ka Chuk B. Polychlorinated rubber Magnesium oxide Phenyl-ft-naphtylamine Sazh, Hydrocarbons (m.p. 300 C) Naphthenic oil Tetramethylthiuram monosulfide, di-0-Tolylguanidine ETA 30 min. ) 67 Stearic acid Zinc oxide Dibutyl phthalate Terpenova resin Disulfide tetramethyl and vulcanization conditions: 35 min at Kauchuk D. Butyl rubber Stearic acid Zinc oxide Soot Disulfide dibenzothiazide Diethyldithiocarbamate tellurium Sera Synthesis sulfon sulfate distillate Dehydrated dibenzothiazide Diethyl dithiocarbamate tellurium Sera Synthesis sulfate sulfon dibenzotiazide Cold-rolled steel tapes are degreased with 1,1,1-trichloroeth- steam. on and cleaned with a stream of sand, followed by repeated steam treatment of trichloroethane. Then the sheets are immersed in 20% piacTBop containing equal parts of novolak and chlorinated natural rubber (65% C1) g. After immersion, I-V is applied to the deists by immersion. The sheets are glued to rubber A-D by vulcanization under the specified conditions in a press. Apply the amount of rubber that provides a layer thickness of 5 mm. After storing the samples for 24 hours at room temperature, the rubber coating is peeled off at an angle of 45 to determine the peeling strength and rupture pattern. In addition, the sedimentation strength of the samples was determined after storage in hot water (95c) for 2 hours of experience (CS). The test results are shown in Table. 2. The number in front of the letter R means the percentage of the rupture zone inside the rubber layer. In those cases when the number 100 is not reached, the zone. The rupture is inside the coating or else the coating is separated from the metal.
    table 2
    High adhesion strength of Kau ChukavA-D to the hard oikyuidlokke not; EH-E is the ezulat cy cyaiai) horo influencing the j components of the components offered; , as svetideto yetvuet comparison-: data of tfimer 1 os data of comparative examples 2-4, / P p and. m y p 2 Polymer resin as in example 1, but using the following composition, m.ch .: Antifoam Water The data on adhesive strength are given in Table 3.
    90 Р
    145 85 Р
    150 60 Р
    145
    Rubber B
    195 90 Р 90 Р. 190 1 195 55 Р.
    example
    Tear, kg / cm
    "
    2 3 4
    160 170 160
    Table 3
    80 Р
    90 Р
    290 85 Р 305 90 Р 45 Р 290 65 Р
    Rubber G
    O P
    ON 55 Р
    35 R 45 R 130
    O P TO 20 P
    Continued table. 3 Rubber D
    KWT
    gap picture
    picture
    rupture
    90 Р
    85 Р 75 Р 50 Р 60 Р 35 Р
    权利要求:
    Claims (2)
    [1]
    1. COMPOSITION · FOR GLUING RUBBER WITH A RIGID SUBSTRATE, including polymer, p-dinitrosobenzene, pro, product of the interaction of the adduct 1 mol of trimethylolpropane and 3 mol of toluene diisocyanate with butadiene pxim, emulsifier, zinc oxide, black and white, The fact is that, in order to increase the safety in handling the composition without reducing the adhesive strength of the rubber with the substrate, the polymer contains a copolymer of vinylide | sloride and methyl ester of acrylic acid in a ratio of 85) 15: 'or a butadiene copolymer and akrilonit843
    253 rila. In the ratio of 70:30 and additionally polyvinylpyrrolidone in the following ratio of components, parts by weight:
    A copolymer of vinylidene chloride and acrylic acid methyl ester in a ratio of 85:15 or a copolymer of butadiene and acrylonitrile in a ratio of 70:30 Polyvinylpyrrolidone p-dinitrosobenzene Adduct interaction product: 1 mol of trimethylolpropane and 3 mol of toluene diisocyanate with butadiene
    Emulsifier12
    Zinc Oxide8
    Soot97
    Antifoam8
    Water 1541-1583
    [2]
    2. The composition according to π.1, on the basis of the fact that it additionally contains a resol or water-soluble phenol-formaldehyde ymole in an amount of 42 parts by weight
    SU ", 1050567>
    ί 1050567
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    同族专利:
    公开号 | 公开日
    AT3649T|1983-06-15|
    CS226014B2|1984-03-19|
    DE2923651A1|1980-12-18|
    DD151316A5|1981-10-14|
    EP0021186A1|1981-01-07|
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    US4336171A|1982-06-22|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    DK125782B|1968-02-29|1973-05-07|Herberts & Co K|Packaging foil.|
    GB1340672A|1969-11-28|1973-12-12|Natural Rubber Producers|Treatment of rubber|
    US3758362A|1971-03-26|1973-09-11|Du Pont|Dual latex adhesive system|
    DE2228544C3|1972-06-12|1984-01-19|Henkel KGaA, 4000 Düsseldorf|Adhesion promoter based on polyisocyanates for vulcanizing rubber compounds onto metals or other stable substrates|
    US3925590A|1973-07-30|1975-12-09|Firestone Tire & Rubber Co|Laminate with an adhesive including an N-nitroso compound|
    US3879337A|1974-05-01|1975-04-22|Lord Corp|Adhesive compositions|
    US3939294A|1974-08-01|1976-02-17|The Firestone Tire & Rubber Company|Adhesives and their use|
    JPS574672B2|1974-08-12|1982-01-27|
    US3936576A|1974-08-12|1976-02-03|The Firestone Tire & Rubber Company|Rubber laminates|
    DE2529512C2|1975-07-02|1984-10-04|Henkel KGaA, 4000 Düsseldorf|Adhesives based on aqueous dispersions of copolymers of butadiene|
    DE2654352A1|1976-12-01|1978-06-08|Henkel Kgaa|BINDING AGENTS BASED ON Aqueous DISPERSIONS FOR BONDING RUBBER TO STABLE SUBSTRATES BY VULCANIZING|JPH0228449B2|1981-05-08|1990-06-25|Ihara Kemikaru Kogyo Kk|
    JPS5984963A|1982-09-07|1984-05-16|Nalco Chemical Co|Tire tread adhesive|
    DE3400851A1|1984-01-12|1985-07-25|Henkel KGaA, 4000 Düsseldorf|AQUEOUS VOLCANIZATION ADHESIVE|
    US4526913A|1984-01-13|1985-07-02|J. H. Diamond Company|Dimer polymeric coating selectively strippable as cohesive film|
    US4624969A|1986-02-18|1986-11-25|The Dow Chemical Company|Crosslinked silane-functional vinylidene chloride polymer and films or foams therefrom|
    US4689355A|1986-02-18|1987-08-25|The Dow Chemical Company|Crosslinked silane-functional vinylidene chloride polymer and films or foams therefrom|
    DE3815543A1|1988-05-06|1989-11-16|Henkel Kgaa|SURFACE TREATMENT FOR POLYMER FIBERS|
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    US5478654A|1994-05-06|1995-12-26|Gencorp Inc.|Solventless carboxylated butadiene-vinylidene chloride adhesives for bonding rubber to metal|
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    WO2015075618A1|2013-11-19|2015-05-28|Basf Se|Antifoaming agents for the paper industry, based on oil in water emulsions|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    DE2923651A|DE2923651C2|1979-06-11|1979-06-11|
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