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    • 专利摘要:
    A method of producing a paper or paperboard product having at least one ply comprising high yield pulp (HYP), comprising the steps of:- providing a furnish comprising at least 50% of high yield pulp (HYP) of a total pulp content in said furnish, said high yield pulp being produced with a wood yield above 85%;- dewatering the furnish to form a moist web and pressing said moist web to a dry solids content of 40-70%; and- densifying the moist web in a press nip of a paper machine at a temperature above a softening temperature of water-saturated lignin comprised in said high yield pulp to provide a paper or paperboard product containing at least 30% high yield pulp (HYP) of a total pulp content of said product.
    公开号:SE1630229A1
    申请号:SE1630229
    申请日:2016-09-21
    公开日:2018-03-22
    发明作者:Höglund Hans；Pettersson Gunilla；Norgren Sven；Engstrand Per
    申请人:
    IPC主号:
    专利说明:

    A PAPER OR PAPERBOARD PRODUCT COMPRISING AT LEAST ONE PLYCONTAINING HIGH YIELD PULP AND ITS PRODUCTION METHOD TECHNICAL FIELD The present invention relates to a method of producing a paper or paperboard producthaving at least one ply containing high yield pulp, and to a paper or paperboard productcomprising at least one ply containing high yield pulp.
    BACKGROUND ART In the production of High Yield Pulps (HYP), single fibers are separated from the woodraw material as a result of mechanical treatments of chips in disc refiners or of logs inwood grinders after softening of the wood lignin at enhanced temperature and/or withchemical pretreatments (Sundholm, J. (1999): “What is mechanical pulping” inMechanical pulping, Volume 5 of Papermaking science and technology, ed. Gullichsen,J. and Paulapuro, H., 199, Helsinki: Finnish Paper Engineers Association, p 17-21).The wood yield in these types of pulping processes (e. g. therrnomechanical (TMP),chemi-thermomechanical (CTMP), high temperature cherr1i-therrnomechanical(HTCTMP), chemimechanical (CMP), stone groundwood (SGW) and pressuregroundwood (PGW) processes) is high, typically over 90% (Sundholm, J. (1999),above). To make fibers from these processes suitable for papermaking, their structuresare generally loosened up by energy demanding mechanical treatments in the pulpingprocesses, to improve the flexibility of the separated originally very stiff fiber material.To reach this goal, fibers are delarninated and so-called fines are peeled off from theouter layers of the fibers. Ideally, the surfaces of the remaining fibers will be wellfibrillated. Up until to now HYP, has primarily been used in the production of two typesof products: graphic paper and paperboard.
    Mechanical pulps for graphic papers (news and magazine papers) are characterized by ahigh light scattering ability at certain sheet strength. To manufacture pulp with a highlight scattering coefficient, a lot of fines from the outer fiber layers have to be producedin the chip refiners or wood grinders, which means that the energy consumption in theproduction of these types of HYP qualities is very high (Sundholm, J. (1993): Can wereduce energy consumption in mechanical pulping , International Mechanical PulpingConference, Oslo, Norway, June 15-17, Technical Association of the Norwegian Pulpand Paper Industry, Oslo, Norway, 133-42). The conditions necessary for manufacturing pulps with high light scattering ability are deteriorated if wood lignin is softened to a too great extent in wood pretreatments during HYP processing or in thepapermaking process (Atack, D. (1972): On the characterization of pressurizedmechanical pulps, Svensk Papperstidning 75,89). At efficient softening of lignin withinthe fiber walls, fiber flexibility can certainly be improved in papermaking, whichincreases the fiber-fiber bond areas in the sheet structure and the overall strength.However, improved sheet strength is achieved on the eXpense of light scattering ability(opacity) and sheet bulk, which is not desired in production of HYP for graphic papersproducts. Therefore, the positive effect of lignin softening at enhanced temperatures israrely used in the manufacturing of HYP containing papers to be used in high quality graphic papers.
    In the manufacturing of HYP for paperboard products, where a high sheet bulk atcertain strength levels is required, the high stiffness of HYP fibers compared tochemical pulp fibers, can be used. Manufacturing of such HYP qualities is less energydemanding than the manufacturing of HYP for graphic papers, as light scattering, i.e.creation of fines, is of minor importance. In multi-ply paperboard products, the bendingstiffness is improved significantly when the materials are designed to have outer plieswith a high tensile strength and tensile stiffness combined with a bulky middle plybased on stiff HYP fibers as a main component (Fellers, C., deRuvo, A., Htun, M.,Calsson, L., Engman, C. and Lundberg, R. (1983): In Carton Board, Swedish ForestProducts Research Laboratory, Stockholm, Sweden; Fineman, I. (1985): “Let the paperproduct guide the choice of mechanical pulp", Proceedings from InternationalMechanical Pulping Conference, Stockholm, p 203-214; Tomas, H. (1997): Mechanicalpulp in paperboard packaging, Proceedings from 1997 International Mechanical PulpingConference, Stockholm, p 9-15; and Bengtsson, G. (2005): CTMP in production ofhigh quality packaging board, Proceedings from International Mechanical PulpingConference, Oslo p 7-13 (2005), for eXample.).
    At a given in-plane or out-of-plane strength, HYP can be formed into sheets withsignificantly higher sheet bulk than sheets from kraft pulps (Fineman, Tomas, andBengtsson, all three above, and Höglund, H. (2002): Mechanical pulp fibers for new andimproved paper grades, Proceedings from 7th International Conference on new availabletechnology, Stockholm, p 158-163, for example). Both in-plane and out-of-planestrength of bulky sheets based on stiff HYP fibers can be further improved by surfacemodification of the fiber surfaces, e. g. by adding rr1iXtures of cationic starch and CMC(Pettersson, G., Höglund, H. and Wågberg, L. (2006): The use of polyelectrolyte multilayers of cationic starch and CMC to enhance strength properties of papers formed from mixtures of unbleached chemical pulp and CTMP Part I and II, NordicPulp&Paper Research Journal 21(1), p 115-128; Pettersson, G., Höglund, H., Sjöberg,J., Peng, F., Bergström, J., Solberg, D., Norgren, S., Hallgren, H., Moberg, A. andLjungqvist, C-H. (2015): Strong and bulky paperboard sheets from surface modifiedCTMP, manufactured at low energy, Nordic Pulp&Paper Research J oumal, 30(2), 318-324; and Hallgren, H., Peng, F., Moberg, A., Höglund, H., Pettersson, G. and Norgren,S. (2015): Process for production of at least one ply of paper or board and a paper orboard produced according to the process, WO 2015/ 166426 A1, for example). Theimproved strength from such surface treatment can be achieved at a maintained highsheet bulk as long as the fiber stiffness is preserved. However, if the fiber walls aresoftened at elevated temperatures at consolidation of the paper structure, such as in hotpress drying operations, sheet strength improvement is achieved on the eXpense ofreduced sheet bulk (Nygren, O., Back, R. and Höglund, H. (2003): On characterizationof Mechanical and Chemimechanical Pulps. International Mechanical Pulping,Proceedings, Quebec City, Canada, p 97-104). Consequently, softening of fiber walls inpapermaking processes at manufacturing of paperboard products is not favorable.However, efficient softening of wood lignin at temperatures well above the softeningtemperature of water- saturated lignin can be used in the manufacturing of HYP to getvery low shive content at low energy input in the refining stage, and from which it isadvantageous to make sheets characterized by a very high bulk (the two Höglund papersabove; and Höglund, H., Back, R., Danielsson, O. and Falk, B. (1994): A method ofproducing mechanical and chemimechanical pulp, WO 94/ 16139 A1, for example). Thesoftening temperature of water-saturated lignin is generally somewhat higher forsoftwoods than for hardwoods (Olsson, A-M, Salmén, N.L. (1992): Viscoelasticity of insitu lignin as affected by structure. Softwood vs. Hardwood. 1992 American ChemicalSociety, Chapter 9, p 134-143) and is affected of several processing conditions in pulpand paperrnaking unit processes like loading frequencies in grinders and refiners as wellas loading rates in press nips of paper-machines (Irvine, G.M. (1985): The significanceof glass transition of lignin in thermomechanical pulping. Wood Science andTechnology, 19, 139-149). The softening temperature of water-saturated lignin can alsobe changed, typically lowered, by chemical treatments of the fiber walls (Atack,D andHeitner,,C.(1997): Dynamic mechanical properties of sulphonated eastern black spruce.Trans. of Technical Section CPPA 5(4): TR99) and is consequently altered in CTMP,HTCTMP and CMP processes. In native lignin the softening effect has a limit at watercontents as low as 5%, when the lignin is water-saturated. Additional water does notresult in a considerable further softening of the native lignin or change of the softening temperature (Back,E.L. and Salmen,N.L.(1982): Glass transition of wood components hold implication for molding and pulping processes, TAPPI, 65(7),107-110). Atprocessing in CTMP, HTCTMP and CMP processes, where the lignin becomeschen1ically modified, water-saturation occurs at somewhat higher water content than in native lignin HYP is not commonly used in paper grades with very high requirements on dry and wetstrength, e.g. packaging papers, paper bags, liner or fluting. Papers with very highstrength based on pulps from CTMP and CMP processes can certainly be manufacturedunder conventional paperrnaking conditions (Höglund, H. and Bodin, O. (1976):Modified thermo-mechanical pulp, Svensk Papperstidning 79(11), p 343-347), but toachieve that the fiber material has to be refined to very high flexibility to get highdensity and strength, which is extremely energy demanding (Klinga, N., Höglund, H.and Sandberg, C. (2008): Energy efficient high quality CTMP for paperboard, Journalof Pulp and Paper Science 34(2), p 98-106). The energy consumption is on such highlevel that up until now, there has been little interest in using HYP in paper products with very high requirements on strength for economic reasons.
    In a hot press of a paperrnaking machine, where a moist paper or paperboard webcontaining HYP is subjected to high pressure at a temperature that may rise above thesoftening temperature of water-saturated lignin, the lignin is changed, i.e. becomestacky (Gupta, P.R., Pezanowich, A. and Goring, D. (1962): The Adhesive Properties ofLignin,63(1), T21-31; and Goring, D. (1963): Thermal Softening of Lignin,Hemicellulose and Cellulose, Pulp and Paper Magazine of Canada, 64(12), T517-T527,for eXample).This will result in enhanced fiber-fiber bond strength at both final dry andwet conditions in sheet structures. However, if the press-drying stage is carried out attoo low dry content, compressed stiff fibers easily spring back to their original shapewhen the pressure is released, since creation of permanent fiber-fiber bonds areprevented by the water between fiber surfaces in the paper sheet (Norgren, S.,Pettersson, G. and Höglund, H. (2014): High strength papers from high yield pulps,Paper Technology 56(5), p 10-14). However, if the dry content is too high, i.e. abovethe wet fiber saturation point of the fiber material, permanent fiber-fiber bonds cannot be established in any wood fiber based paper structures.
    SUMMARY OF THE INVENTIONThe objects of the present invention are to make it possible to reduce the energyconsumption in the production of HYP containing paper and paperboard products with very high requirements on strength, as HYP that is manufactured with low energy consumption in chip refining or wood grinding can be used, as Well as making itpossible to manufacture paper and paperboard products with very high dry strength, wet strength, compression strength as well as tensile stiffness based on such HYPs.
    In a preferred embodiment of the present invention these objects are achieved by amethod of producing a paper or paperboard product having at least one ply comprisinghigh yield pulp (HYP), said method comprising the steps of:- providing a furnish comprising at least 50% of high yield pulp (HYP) of a totalpulp content in said furnish, said high yield pulp being produced with a woodyield above 85%;- dewatering the furnish to form a moist web and pressing said moist web to a drysolids content of 40-70%; and followed by- densifying the moist web in a press nip of a paper machine at a temperature insaid press nip above a softening temperature of water-saturated lignin comprisedin said high yield pulp to provide a paper or paperboard product containing atleast 30% high yield pulp (HYP).
    After thermal and/or chemical pretreatments HYP can be manufactured at a wood yieldabove 85% and at a comparatively low energy input when single fibers are separatedfrom the wood raw material as a result of mechanical treatments of chips in disc refinersor logs in wood grinders. By preparing a fumish containing high yield pulp (HYP)produced with a wood yield above 85%, dewatering the fumish, pressing the formedwet web in a press section to a dry solids content of 40-70% and densifying the web ina press nip of a paper machine at a temperature above the softening temperature ofwater-saturated lignin, the produced HYP containing sheets will have final high ply density, dry and wet strength, tensile stiffness and compression strength.
    In a product having only one ply, it is preferred that the content of HYP is at least 50%of a total fiber content in said ply. This means that also the furnish for producing theproduct have to comprise at least 50% HYP of the total pulp content in the fumish. In aproduct having more than one ply, it is suitable that the total content of HYP in theproduct is at least 30%, suitably at least 50%, preferably at least 70%, and mostpreferred at least 80%. This makes it possible to take advantage of lignin as a bondingagent in the sheet structure to get high dry and wet strength properties, when the water-saturated lignin becomes tacky at temperatures above the softening temperature oflignin. As HYP is less expensive to produce than chemical pulps, as high content of HYP as possible is always an economic advantage.
    Suitably, the Wood yield of the high yield pulp (HYP) is above 90%. Thereby, itbecomes possible to use fiber materials With very high stiffness, Which is an advantagein products Where a high bending stiffness or compression strength (SCT) is givenpriority. High yield may also be a more eco-friendly altemative as more products can beproduced from a certain quantity of Wood and the amount of Waste material is rninimized.
    A suitable temperature for the press nip is above 160 °C, preferably above 180 °C, andmost preferred above 200 °C. This makes it possible to take advantage of Water-saturated lignin as a bonding agent in the sheet structure to get high dry and Wetstrength properties. The bonding between fibers increase With increased press niptemperature. As the demands regarding strength in fiber-fiber bonds may be different invarious products, the optimum press nip temperature can be changed according to specific requirements.
    The high yield pulp is preferably manufactured in a TMP, CTMP, HTCTMP, CMP,SGW or PGW process from softWood or hardWood. This makes it possible to use highyield pulp With different property characteristics. Different characteristics may be preferred in paper or board products depending of desired final product specifications.
    In another aspect of a preferred embodiment of the present invention, the above objectis achieved in that a paper or paperboard product comprises at least one ply, Where atleast one ply contains at least 50% high yield pulp (HYP) produced With a Wood yieldabove 85%. Said product is produced in a paper machine by forn1ing a moist Web froma fumish including said HYP, pressing said moist Web to a dry solids content of 40-70%and densifying said moist Web in a press nip at a temperature above the softeningtemperature of Water-saturated lignin. This makes it possible to make products Withboth high dry and Wet strength properties, When the lignin becomes tacky attemperatures above the softening temperature of Water-saturated lignin. As HYP is lessexpensive to produce than chemical pulps, a high content of HYP is an economic advantage.
    Preferably, the ply comprising at least 50% HYP has a density above 600 kg/m3, atensile index above 50 kNm/kg, a compression index (SCT) above 25 kNm/kg, a tensilestiffness above 6 MNm/kg, and an initial relative Wet strength, i.e. (Wet tensileindex)/(dry tensile index), above 10% Without Wet strength additives. This makes it possible to manufacture products, like packaging papers, paper bags, liner or fluting,with the same or better properties regarding dry and wet strength and compressibility, ata lower cost than those made from kraft pulps. Following, a paper or board productconsisting of only one ply, i.e. said HYP ply, then has the same physical properties asthe ply. The HYP content in this product is the same as in the one ply, i.e. at least 50%of the total pulp content in said ply. An example of a one-ply product may be paper bags for groceries.
    Suitably, the paper or paperboard product comprising more than one ply, has a tensileindex above 60 kNm/kg, a compression index (SCT) above 30 kNm/kg, a tensilestiffness above 7 MNm/kg and an initial relative wet strength, i.e. (wet tensileindex)/(dry tensile index), above 15% without wet strength additives. This makes itpossible to manufacture products, like packaging papers, paper bags, liner or fluting,with better properties regarding dry and wet strength and compressibility than productsmade from kraft pulps.
    Preferably, and irrespective of the number of plies, the relative wet strength is above30%, suitably above 40%. This makes it possible to manufacture products, likepackaging papers, paper bags, liner or fluting, with considerably better wet strengthproperties than products made from kraft pulps.
    BRIEF DESCRIPTION OF THE DRAWINGSIn the following, the invention will be described in more detail with reference topreferred embodiments and the appended drawing.
    Fig. 1 is a principle sketch showing a hot press in a paper or paperboard machine.
    Fig. 2a is a diagram showing the variation in ply density with various press temperatures at pressing of furnishes of high yield pulps (HYPs).
    Fig. 2b is a diagram similar to Fig. 2a but with starch added to the HYPs.
    Fig. 3a is a diagram showing the variation in ply tensile index with various press temperatures at pressing of furnishes of HYPs.
    Fig. 3b is a diagram similar to Fig. 3a but with starch added to the HYPs.
    Fig. 4a is a diagram showing the variation in ply SCT index with various press temperatures at pressing of furnishes of high yield pulps (HYPs).
    Fig. 4b is a diagram similar to Fig. 4a but with starch added to the HYPs.
    Fig. 5a is a diagram showing the variation in ply tensile stiffness with various press temperatures at pressing of furnishes of high yield pulps (HYPs).
    Fig. 5b is a diagram similar to Fig. 5a but with starch added to the HYPs.
    Fig. 6 is a diagram showing the variation in ply wet strength index with various presstemperatures at pressing of furnishes of HYPs with and without addition ofstarch.
    MODE(S) FOR CARRYING OUT THE INVENTION To produce the paper or paperboard product of the invention with the method of theinvention, a high yield pulp (HYP) produced with a wood yield above 85% is used tomake a furnish, which can be delivered to a forming fabric in a forming section of apaper or paperboard machine and dewatered on the forn1ing fabric to form a moist web.The paper or paperboard machine may have more than one forn1ing fabric for separateforming of different plies from different furnishes in a multi-layer product. It could alsobe possible to use a multi-layer headbox to deliver different furnishes simultaneously,e. g. one fumish for each ply in a multi-ply product to be produced by the inventive method, to the forming fabric.
    Downstream of the forming section is preferably a press section arranged where themoist/wet web while running through the press section is pressed to a dry solids contentof 40-70%. Said press section may be any conventional, known press section. At saidinterval of dry solids content the lignin comprised in the HYP-fibers is a water-saturatedlignin, a so called wet lignin, having a moisture content between approximately 5-l5%.The wet web, of which the high yield pulp (HYP) constitutes at least 50% of the at leastone ply to be produced, is transferred from the press section to a hot press nip, wherethe web is densified at a temperature above the softening temperature of water-saturatedlignin to provide a paper or paperboard product containing at least 30 wt-% high yieldpulp (HYP) of the total pulp content in said product.
    It is beneficial that the dry solids content of the dewatered wet web, when entering the(hot) press nip is at least 40% since a too high water content in the web will preventcreation of permanent fiber-fiber bonds. It is further beneficial that the dry solidscontent of the dewatered wet web, when entering the hot press nip is 70% at the most.The reason for this is that if the hot nip stage is carried out at a higher dry content strongperrnanent fiber-fiber bonds cannot be established. Hence, the dry solids content of thewet web is 40-70% when entering the press nip. The dry solids content of the web after the press nip may be 80% or more.
    The hot press nip stage may be placed either upstream of a drying section or as a part ofthe drying section of the paper or paperboard machine. It is also conceivable that theweb after having passed the hot press drying step has reached a final dryness and that no further drying is needed.
    Fig. 1 is a principle sketch showing a hot press for press drying according to theinvention in a paper or paperboard machine. The hot press comprises a press memberand a heated counter member, which together form a press nip PN. In the shownembodiment the counter member is a rotary cylindrical dryer 1 usually internally heatedby steam, and the press member is preferably a variable crown press roll 2 that can bepressed against the dryer 1 by any desired force. It is conceivable that also the press roll2 is heated. Further, the hot press comprises an endless dryer fabric 3 and a plurality ofguide rolls 4 to guide the travel of the dryer fabric 3 as it travels through the very pressnip PN and around about half of the envelope surface of the cylindrical dryer 1 whilepressing the web 5 against the hot dryer surface. The steam that forms by evaporation ofwater in the web 5 passes through the dryer fabric 3 into surrounding air. The suppliedheat and the pressure in the nip PN are adjusted to achieve the desired softening of thelignin, so that the lignin becomes tacky, which results in enhanced fiber-fiber bond strength at both final dry and wet conditions in sheet structures.
    The hot press drying on a paper machine can be carried out in all available types of suchmachine concepts, where the web can be subjected to a temperature above the softeningtemperature of lignin at a simultaneous sufficient high pressure and dwell time toachieve the desired density according to the invention. At temperatures well above thewater-saturated lignin softening temperature, fiber-fiber bonds with very high wetstrength are formed between HYP fibers, when the fibers are brought into close contactat conditions according to the invention, as the chemical and physical properties of wood lignin are changed. Thus, the present invention is not restricted to the use of a dryer cylinder and a variable crown press roll. lf desired, a shoe press roll may besubstituted for the variable crown press roll, and to increase the speed of the hot press orperrnit an increased thickness of the web, a Yankee dryer may be substituted for theusual dryer cylinder. lt would even be possible to substitute a Condebelt drying systemor a BoostDryer for the usual roll nip hot press. The Condebelt drying system isdisclosed in FI-54514 B (Lehtinen), US 4,461,095 (Lehtinen), and US 5,867,919(Retulainen), for example, and the BoostDryer is disclosed in US 7,294,239 B2 (Lornicet al.).
    Thus, the present invention provides a method for the manufacturing of paper orpaperboard products from a HYP containing fumish, comprising at least one plycomprising at least 50 wt-% HYP pulp calculated on the total pulp content in said ply,and as will be clarified below, with outstanding paper or paperboard propertiesregarding dry and wet strength, compression strength (SCT) and tensile stiffness. Toreach this goal, the at least one ply of the paper or paperboard product is treated in a hotpress drying process in a paper or paperboard machine by subjecting the moist paperweb having a dry solids content between 40-70% to high pressure at a temperatureabove the softening temperature of water-saturated lignin to get a high initial relativewet strength (i.e. (wet tensile index)/(dry tensile index)) of above 10% or 15%. Fromthis level, the wet strength can be further improved to above 30% or above 40% byadding different kinds of conventional wet strength agents, like wet strength additives orneutral sizing agents. According to the invention, the at least one ply of the paper orpaperboard product will be pressed to a density typically above 600 kg/m3, 700 kg/m3 or800 kg/m3 to reach a tensile index above 50 kNm/kg, 60 kNm/kg or 70 kNm/kg, acompression index (SCT index) of above 25 kNm/kg or 30 kNm/kg. Dry tensile index,wet tensile index, SCT and tensile stiffness refer to the geometric mean values in thesheet structure. All sheet properties refer to values from tests according to ISO methods,see below. The sheet strength levels can be further improved by adding such dry andwet strength additives to the fumish that work at temperatures above the softening temperatures of lignin in the hot press drying stage.
    Said at least one HYP-containing ply may further comprise pulp or pulps other thanHYP. The pulp/-s is/are suitably one or more of chemical pulps, e. g. kraft pulp, sulphitepulp and semi-chemical pulps, e.g. NSSC.
    The total content of HYP as compared to a total pulp content in the product to be produced decreases for every added ply not comprising HYP. Therefore, in a product 11 having more than one ply, the total content of HYP in the product should preferably beat least 30 Wt-%, suitably at least 50%, preferably at least 70%, and most preferred atleast 80% of the total pulp content. This makes it possible to take advantage of the highdry and Wet strength properties of HYP containing plies, When the lignin becomes tackyat temperatures above the softening temperature of Water-saturated lignin. As HYP isless expensive to produce than chemical pulps, a high content of HYP is usuallyconsidered to be an advantage. lt is to be understood that in a multi-layer product HYPmay be present in more than one of the plies forn1ing the product. The other plies notcomprising HYP may typically but not necessarily consist of chemical pulps, e. g. kraftpulp, sulphite pulp, and/or semi-chen1ical pulps, e.g. NSSC.
    A preferred example of a HYP product according to the invention may be a productconsisting of three plies; a middle-ply comprising at least 50% HYP, and outer pliescomprising chemical pulp. The total content of HYP in the three-layered product is atleast 30%. Said outer plies may be formed from one and the same furnish or fromdifferent fumishes having different compositions so as to reach the desired finalproperties of the product. Another preferred example may be a multi-ply product, e.g. aproduct having three, four, five or six or more plies and comprising a HYP-ply madefrom a HYP having a high freeness and another HYP-ply made from a HYP having alow freeness. Additional pulp in the respective HYP-layers may be kraft pulp.
    In addition, the product may also comprise one or several plies of made of non- cellulosic materials, e. g. plastic, biopolymer or alun1inum foils, coatings etc.
    Generally, plies comprising chemical pulps have higher densities than HYP-plies. Thismeans that the density of the final product increases for every added ply comprisingchemical pulp. A product consisting of only the HYP-ply may as already mentionedhave a density above 600 kg/m3, While a tWo-layer product consisting of a HYP-ply anda ply made of chemical pulp may have a density above 650 kg/m3.
    In multi-ply products With high requirements of strength and stiffness, outer plies can bedesigned to obtain other properties than those given priority in the present invention.This means that the inventive paper or board product may comprise different kinds of cellulosic fibers from different pulping processes.
    Suitably, the Wood yield of the high yield pulp (HYP) is above 90%. This makes itpossible to use HYP fibers With high stiffness, especially in middle plies, Which is an 12 advantage in products With the highest demands on bending stiffness or compressionstrength (SCT). High yield is also advantageous as more products can be produced from a certain quantity of Wood, n1inimizing the amount of Waste material.
    The softening temperature of Water-saturated lignin during papermaking may beapproximately 140-170 °C, but can also be higher than 170 °C depending e.g. onsoftWood or hardWood pulps used, the chen1istry in the pulping process, processingconditions in the pulp and papermaking unit, processes like loading rates in press nipsof paper-machines etc. Higher loading rates lead to higher softening temperature. Asuitable temperature in the press nip may therefore be above 160 °C, preferably above180 °C, and most preferred above 200 °C. This makes it possible to efficiently takeadvantage of lignin as a bonding agent in the sheet structure. As the strength in fiber-fiber bonds increases With increased press nip temperature, different demands regardingstrength can be met by changing press nip temperature. Paper-machines are most oftenoperated at very high machine speeds Which means that the dWell time of the Wet paperor board Web in the press nip is very short and that the Web passes through the press nipvery quickly. lt may thus be advantageous if the temperature in the press nip is Wellover the softening temperature of the Water-saturated lignin so as to assure that thelignin in the fibers of the Web may reach the softening temperature during the shortdWell time in the nip. HoWever, a high temperature requires more energy. Hence, atemperature above 200 °C may be a preferred temperature in the hot press nip. Theexamples presented below are performed in a pilot machine operated at a lower machinespeed (i.e.) than ordinary mill paper machines. Therefore, the dWell time in the press nipof the pilot machine is longer and there is more time for the Wet Web to be heated in thepilot press nip, Whereby the press nip temperatures in the examples are 200 °C and notabove 200 °C. Due to the longer dWell time in the pilot press nip, it is ascertained thatthe Water- saturated lignin in the Wet Web Will reach a temperature above the softeningtemperature of the Wet lignin already at a temperature of about 200 °C. For multi-plyproducts comprising several plies it may be beneficial to perform the press nip at a temperature Well above 200 °C due to the many layers that have to be heated.
    It is also preferred that the high yield pulp is manufactured in a TMP, CTMP,HTCTMP, CMP, SGW or PGW process from softWood or hardWood. This makes itpossible to use the specific property profile of different HYP qualities. Differentcharacteristics may be preferred according to desired final product specifications, e. g. different densities, strength levels. 13 EXAMPLE Press drying of spruce CTMP containing sheets at temperatnres below and above thesoftening temperature of water-saturated lignin A press-drying trial was performed in the pilot plant shown schematically in Fig. 1 .Laboratory sheets 5 at 40% dry content, manufactured in a Rapid Köthen sheet former(ISO/DIS 5269-2) were fed into the nip between a heated cylinder 1 and a press roll 2.Sheets containing spruce CTMP with two different Canadian Standard freeness (CSF)levels, 420 and 720 rnl respectively, were tested. These pulps can be manufactured at alow input of electric energy in refining, i.e. below 1200 kWh/ton. Sheets from astandard bleached kraft pulp were used as reference. ln some trials the CTMP fibermaterials were surface modificated with a low dosage of cationic starch. Cylinder andpress nip temperature was Varied between 25 and 200 °C. The same nip pressure was applied in all trial points.
    Preparation of pulps for the trial A special low energy, high freeness (CSF 720 ml) HTCTMP from spruce (600 kWh/adtin refining stages including reject refining) was manufactured in a mill trial at the SCAÖstrand CTMP mill in Timrå, Sweden. ln the rnill the impregnation Vessel is situatedinside the preheater, and chips are atmospherically steamed before impregnation with15-20 kg NazSOs at pH 10. Preheating temperature was about 170 °C. The turbinerefiner plates used in the main refiner were of the feeding type. The pulp was peroXidebleached and flash dried. A standard type of bleached and flash dried CTMP (CSF 420rnl) from the same mill was also tested. ln the manufacturing of that pulp, the energy consumption in refining was 1200 kWh/adt.
    A standard market bleached softwood kraft pulp, also from the SCA Östrand rnill, wastested as a reference pulp. The chemical pulp was laboratory beaten to 25 SR.
    Before fiber preparation, (HT)CTMP was hot disintegrated according to SCAN M10:77and the bleached softwood kraft pulp was reslushed according to SCAN C: 1865.
    Some (HT)CTMP and CTMP fibers were treated with a lower dosage of cationic starch(25 mg/g).
    Fiber surface preparation with cationic starchPotato starch, CS, supplied by Lyckeby Starkelsen, Sweden, with a cationic degree ofsubstitution of 0.040, was used. The starch was laboratory cooked by heating a 5 g/l 14 starch slurry to 95 °C, maintaining this temperature for 30 min, and allowing the starchsolution to cool down under ambient conditions. Fresh solutions of starch were prepared each day in order to avoid the influence of starch degradation.
    Sheet preparation t0 40% d.c. in laboratory Sheets were made on a Rapid Köthen sheet former from Paper Testing Instruments(PTI), (ISO 5269-2) Pettenbach, Austria. Sheets with a grammage of 150 g/mz wereformed after vigorous aeration of the fiber suspension just before sheet preparation. Thesheets were then press-dried at 100 kPa and dried under restrained conditions at 94 °C until reaching a dryness content of 40%.
    Press drying equipment The moist sheets were inserted into the dryer fabric 3 between a press roll 2 and aheated dryer cylinder 1 of the pilot press drying machine. The diameter of the cylinder 1and the press roll 2 was 0.8 m and 0.2 m, respectively. The feeding rate was 1 m/min.The nip pressure was on a high level, which was selected to give sheets with highdensities. The cylinder temperature was varied between 20-200 °C. The press nipduration was about one second. The sheets, pressed at 20 °C, were fed into the dryer asecond time at a cylinder temperature of 100 °C without applied press load for finaldrying of the sheets. The sheets that were pressed and dried at 100-200 °C reached fulldryness during the first loop.
    Sheet testing After conditioning (ISO 187) tensile testing index and tensile stiffness index weremeasured according to ISO 5270/1924-3, SCT was measured according to ISO 9895,wet strength index was measured according to SCAN-P 20:95, soaking time 1 minute.
    Grammage, thickness and density were evaluated according to ISO 536 respectively534.
    Results In the current trial, sheets from a medium freeness (420 ml) CTMP and a high freeness(720 ml) HTCTMP were pressed in the hot press nip at temperatures both below andabove the softening temperature of water-saturated lignin. The effects on sheetproperties were compared with those on a beaten bleached kraft pulp. Furthermore, theeffect of surface modification of HTCTMP and CTMP fibers with just a low dosage of cationic starch were evaluated.
    The densification effect of sheet structures as a result of increased press nip temperatureis shown in Fig. 2. The effect is most evident for sheets containing untreated HT CTMPand CTMP fibers, whereas sheets from the kraft pulp are more or less unaffected bypress temperature, see Fig. 2a. The relative increase in density is the greatest on sheetsfrom the high freeness HT CTMP, where density is more than doubled when the pressnip temperature is increased from 25 to 200 °C. A sheet density close to that of the kraftpulp sheets is obtained at a press temperature of 200 °C, i.e. at a temperature well abovethe softening temperature of water-saturated lignin. Obviously, enhanced softening ofthe HYP fibers enables bringing the fiber material in close contact, and very strongpermanent bonds are created at pressure at temperatures well above the softeningtemperature of water- saturated lignin at an appropriate moisture content. If the press anddrying stage is carried out in a too low dry content range, compressed stiff HYP fiberseasily spring back to their original shapes when the pressure is released since creation ofpermanent fiber-fiber bonds are prevented by water between fiber surfaces in the papersheet. However, as stated above, if the dry content is too high, i.e. above the wetsaturation point of the fiber material, strong permanent fiber-fiber bonds are not established in any wood fiber based paper structures.
    After fiber surface modification with cationic starch the densification effect is very similar to that without fiber surface treatments, see Fig. 2b.
    With increased density, which is a result of enhanced temperature in pressing anddrying, the tensile index of HYP sheets is substantially improved, whereas the tensileindex of the kraft pulp sheets is just marginally changed, see Fig. 3a. Sheets fromCTMP (CSF 420 ml) and HTCMP (CSF 720 ml), where the fibers have been surfacetreated with cationic starch, reach tensile index at more or less the same level as theuntreated reference kraft pulp at the highest press temperature, see Fig. 3b. The bondstrength in the lignin rich sheet structure is very high and clearly related to the enhancedtemperature which resulted in the moist lignin becoming tacky. As the number of fibersin a HTCTMP web is only about half of that in a kraft pulp sheet, due to the differencein pulp yields, the strength of fiber-fiber bonds between lignin rich HTCTMP fiber surfaces in close contact could be higher than in a kraft pulp structure.
    The best compression strengths of CTMP as well as HTCTMP sheets, which have beenpressed at the highest temperature (200 °C), measured as SCT index (kNm/kg), is on thesame level as the reference sheets from the kraft pulp, see Fig. 4a. This could be expected as the density and tensile index of HYP sheets are quite similar to the kraft 16 pulp reference sheets, compression index (SCT) for HYP sheets should be as high as orhigher than the kraft pulp sheets as the HYP fibers are much stiffer. At surface treatmentwith cationic starch, the SCT values of sheets from high freeness (720 rnl) HTCTMPare improved somewhat, see Fig. 4b. The sheets from CTMP, which has a lower freeness value, are less affected, compare Fig. 4a and 4b.
    The development of tensile stiffness for the HYP sheets with increased press temperature follows almost the same pattern as tensile index and compression strength,see Fig. 5. lt is obvious that it is possible to reach the same level with HYP sheets as onreference sheets from the kraft pulp, see Fig. 5a. Surface treatment with cationic starch seem not to improve tensile stiffness, compare Fig 5a and 5b.
    The initial relative wet strength (i.e. (wet tensile index)/(dry tensile index)) of theCTMP containing sheets increases considerably, when the temperature enhances to wellabove the softening temperature of water-saturated lignin (200 °C), i.e. at a temperaturewhere the lignin becomes very tacky, see Fig. 6. At the highest temperature in the trialthe relative wet strength is more than twice as high on sheets from CTMP andHTCTMP fibers than on sheets from the reference kraft pulp.
    FINAL REMARKS The results in the example show that it is possible to manufacture sheets from HYP,which has been manufactured with a low input of electric energy in refining, i.e. below1200 kWh/adt, with tensile index, compression index (SCT) and tensile stiffness indexat the same or almost the same level as sheets from a bleach softwood kraft pulp, whenpapermaking conditions are changed to better suit the characteristics of lignin rich HYPfibers, i.e. at press temperatures above the softening temperature of water-saturatedlignin. lt is evident that HYP webs are consolidated to a stable structure at high pressloads in a dry content interval above 40%, and at temperatures above the softeningtemperature of water-saturated lignin. Under such papermaking conditions even HYPlike HTCTMP, which can be manufactured at very low electric energy consumption inrefining, could be used in the manufacturing of paper products with high strengthrequirements, e. g. packaging papers, paper bags, liner or fluting. In this study, presstemperatures of up to 200 °C were tested, which is a temperature well above thesoftening temperature of water-saturated lignin. The results indicate that sheetproperties may be further improved if even higher temperatures are used. The resultsshow that this is an as of yet unexploited potential of HYP, which could be used to manufacture paper products where strength requirements are very high if the processing 17 conditions according to the invention are used. Sheet characteristics from HYP webscan be changed within a broad range by changing the press temperature in papermaking,as the physical and chen1ica1 properties of 1ignin are marked different1y at differenttemperatures. It is evident that high density and strong sheets from HYP webs can beformed in a cost efficient way in papermaking if the moist web is pressed at conditionswhere the 1ignin is softened to temperatures above the softening temperatures of water- saturated 1ignin.
    In products having more than one p1y it is conceivab1e that high yie1d pu1p may bepresent in two or more p1ies depending on the desired fina1 product characteristics. Theinventive method and product are further not restricted to the number of HYP-containing p1ies and in which sequence the p1ies are arranged in the product, neither tothe tota1 number of p1ies in the product. The number of p1ies and their mutua1 p1acingsdepend on the desired characteristics of the fina1 product and may hence vary. Aproduct having two or three p1ies of HYP and one or two p1ies of chen1ica1 pu1p and a coating on at 1east one of the two outer sides may e. g. be conceivab1e.
    The percentages presented are, where app1icab1e, weight percentages and not vo1ume percentages.
    The production 1ine for producing the inventive product according to the inventivemethod may comprise equipment not mentioned above or shown in Fig. 1, e. g. aconventiona1 press section and further drying equipment. It is further conceivab1e thatthe web has reached fina1 dryness after the hot press drying step and that no fina1 dryingis needed after the hot press drying step. Moreover, in some embodiments it may bebeneficia1 to p1ace the hot press drying step as a step comprised in the drying section ofthe machine. The wet web 1eaving the press section and entering the drying section mayfirst be dried in a conventiona1 manner in the drying section and to a dry so1id contentsof 50-70%. Said web may then enter the hot press nip and be press dried in accordancewith the inventive method. Said hot press drying may be performed either to fina1dryness or to a higher dry so1ids content and thereafter, downstream of the press nip, dried to fina1 dryness, e. g. on a drying cy1inder.
    INDUSTRIAL APPLICABILITYThe invention is app1icab1e primari1y in the production of paper and paperboard grades, where strength requirements are high or very high.
    权利要求:
    Claims (14)
    [1] 1. . A method of producing a paper or paperboard product having at 1east one p1y comprising high yie1d pu1p (HYP), comprising the steps of: - providing a furnish comprising at 1east 50% of high yie1d pu1p (HYP) of a tota1pu1p content in said furnish, said high yie1d pu1p being produced With a Woodyie1d above 85%; - deWatering the furnish to form a moist Web and pressing said moist Web to a dryso1ids content of 40-70%; and - densifying the moist Web in a press nip of a paper machine at a temperatureabove a softening temperature of Water-saturated 1ignin comprised in said highyie1d pu1p to provide a paper or paperboard product containing at 1east 30% highyie1d pu1p (HYP) of a tota1 pu1p content of said product.
    [2] 2. . A method as c1aimed in c1aim 1, Wherein the content of high yie1d pu1p in said at 1east one p1y is at 1east 60%, suitab1y at 1east 70%, and preferab1y at 1east 80% of thetota1 pu1p content of said p1y.
    [3] 3. . A method as c1aimed in c1aim 1 or 2, Wherein the Wood yie1d of the high yie1d pu1p
    [4] 4. (HYP) is above 90%.
    [5] 5. . A method as c1aimed in any one of c1aims 1-3, Wherein the temperature in the press nip is above 160 °C, suitab1y above 180 °C, and preferab1y above 200 °C,
    [6] 6. . A method as c1aimed in any one of c1aims 1-4, Wherein the high yie1d pu1p is manufactured in a TMP, CTMP, CMP, HTCTMP, SGW or PGW process from softWood or hardWood.
    [7] 7. . A method as c1aimed in any one of c1aims 1-5, Wherein said method further comprises addition of at 1east one p1y comprising chemica1 pu1p and/or semi- cherr1ica1 pu1p to said at 1east one p1y comprising HYP.
    [8] 8. . A paper or paperboard product manufactured according to a method as c1aimed in any of c1aims 1-6.
    [9] 9. . A product as c1aimed in c1aim 7, Wherein the content of high yie1d pu1p in said product is at 1east 30 Wt-%, suitab1y at 1east 50%, preferab1y at 1east 60%, even
    [10] 10.
    [11] 11.
    [12] 12.
    [13] 13.
    [14] 14. 19 more preferred 70% and most preferred at 1east 80% of a total pu1p content in said product. A product as c1aimed in c1aim 7 or 8, Wherein the Wood yie1d of the high yie1d pu1p(HYP) is above 90%. A product as c1aimed in any one of c1aims 7-9, Wherein the high yie1d pu1p ismanufactured in a TMP, CTMP, CMP, HTCTMP, SGW or PGW process from softWood or hardWood. A product as c1aimed in any one of c1aims 7-10, Wherein said at 1east one p1y has adensity above 600 kg/m3, a tensi1e index above 50 kNm/kg, a compression index(SCT) above 25 kNm/kg, a tensi1e stiffness above 6 MNm/kg, and an initia1 re1ativeWet strength, i.e. (Wet tensi1e index)/(dry tensi1e index), above 10% Without Wet strength additives or neutra1 sizing agents. A product as c1aimed in any one of c1aims 6-10, having a tensi1e index above 60kNm/kg, a compression index (SCT) above 30 kNm/kg, a tensi1e stiffness above 7MNm/kg and an initia1 re1ative Wet strength, i.e. (Wet tensi1e index)/(dry tensi1e index), above 15% Without Wet strength additives or neutra1 sizing agents. A product as c1aimed in c1aim 11 or 12, Wherein the re1ative Wet strength is above30%, suitab1y above 40%. A product as c1aimed in any one of c1aims 7-13, Wherein said product may further comprise at 1east one p1y made of chemica1 and/or sen1i-chemica1 pu1p.
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    同族专利:
    公开号 | 公开日
    BR112019005554A2|2019-06-04|
    RU2019108182A3|2020-10-22|
    WO2018054957A1|2018-03-29|
    CN109715882A|2019-05-03|
    EP3516110A1|2019-07-31|
    RU2019108182A|2020-10-22|
    US20190218716A1|2019-07-18|
    RU2743392C2|2021-02-17|
    SE540115C2|2018-04-03|
    CA3036442A1|2018-03-29|
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    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    SE1630229A|SE540115C2|2016-09-21|2016-09-21|A paper or paperboard product comprising at least one ply containing high yield pulp and its production method|SE1630229A| SE540115C2|2016-09-21|2016-09-21|A paper or paperboard product comprising at least one ply containing high yield pulp and its production method|
    PCT/EP2017/073745| WO2018054957A1|2016-09-21|2017-09-20|A paper or paperboard product comprising at least one ply containing high yield pulp and its production method|
    BR112019005554A| BR112019005554A2|2016-09-21|2017-09-20|paper or cardboard product comprising at least one high yield pulp blade and its method of production|
    RU2019108182A| RU2743392C2|2016-09-21|2017-09-20|Paper or cardboard article having at least one layer containing high-yield cellulose and a method for production thereof|
    CN201780058242.8A| CN109715882A|2016-09-21|2017-09-20|The Paper or cardboard product and its production method of layer comprising at least one containing high-yield pulp|
    CA3036442A| CA3036442A1|2016-09-21|2017-09-20|A paper or paperboard product comprising at least one ply containing high yield pulp and its production method|
    EP17771425.0A| EP3516110A1|2016-09-21|2017-09-20|A paper or paperboard product comprising at least one ply containing high yield pulp and its production method|
    US16/334,371| US20190218716A1|2016-09-21|2017-09-20|A paper or paperboard product comprising at least one ply containing high yield pulp and its production method|
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