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    • 专利摘要:
    The present invention relates to a method of manufacturing a cellulose product having a non-flat product shape. The method comprises the steps of: providing an isostatic pressure moulding apparatus comprising a forming mould having a forming surface defining the product shape, and a pressure mould; arranging a cellulose blank containing less than 45 weight percent water between the forming mould and the pressure mould; heating the cellulose blank to a forming temperature in the range of 100°C to 200°C; and pressing, by means of the pressure mould, the cellulose blank against the forming mould with a substantially equal forming pressure acting on the cellulose blank across the forming surface, the forming pressure being in the range of 1 MPa to 100 MPa.Publication fig: Fig. 2b
    公开号:SE1630058A1
    申请号:SE1630058
    申请日:2016-03-18
    公开日:2017-09-19
    发明作者:Larson Ove；Larsson Linus
    申请人:The Core Company Ab；
    IPC主号:
    专利说明:

    ISOSTATIC PRESSURE FORIVIING OF HEATED DRY CELLULOSE FIBERS Field of the lnvention The present invention relates to a method of manufacturing a celluloseproduct having a non-flat product shape, and to an apparatus for manufacturing such a cellulose product.
    Background of the lnvention There are many situations where it is desirable to provide 3D shapedobjects made of sustainable materials. One such situation relates topackaging of sensitive goods, such as mechanical high precision items,electronic equipment and other household and hardware items, that needprotective packaging in order to avoid damage of the sensitive goods, due tofor example mechanical shock, vibrations or compression during transport,storage, or other handling. Such packages typically require a protective insertthat has a shape adapted to the goods contained, and thus securely holds thegoods in the package. Such inserts are commonly made of expandedpolystyrene (EPS), which is a lightweight petroleum derived material and isnot regarded as a sustainable material.
    A low price material commonly used for packaging inserts is mouldedpulp. l/loulded pulp has the advantage of being considered as a sustainablepackaging material, since it is produced from biomaterials and can berecycled after use. As a consequence moulded pulp has been quicklyincreasing in popularity for both primary and secondary packagingapplications (packaging next to the article and assembly of such packages).Moulded pulp articles are generally formed by immersing a suction mould intoa pulp suspension, while suction is applied, whereby a body of pulp is formedwith the shape of the desired article by fibre deposition. The suction mould isthen withdrawn from the suspension and the suction is generally continued to compact the deposited fibres while exhausting residual liquid.
    A common disadvantage with all wet-forming techniques is the needfor drying of the moulded product, which is a time and energy consumingstep. Another drawback is that strong inter-fibre bonds, often explained ashydrogen bonds, are formed between the fibres in the material, which restrictthe flexibility of the material. l/loreover, many modern lean production lines require in-line on-demand package or component manufacturing where a wet-forming processnot is preferred.
    Lately, new fibre-based materials have been developed with thepurpose of enabling dry forming of three-dimensional objects. One approachis disclosed by WO2014142714A1. WO2014142714A1 discloses a dry-laidcomposite web being an intermediate product for thermoforming of three-dimensionally shaped objects, comprising 40-95 wt-°/> CTl/IP fibres, 5-50 wt-°/> thermoplastic material, and 0-10 wt-°/> additives, wherein the dry-laidcomposite web has been impregnated with a dispersion, an emulsion, or asolution containing the thermoplastic material, polymer, and dried, obtaining adensity of 50-250 kg/m3, or, if compressed by calendering 400-1000 kg/m3.According to WO2014142714A1, bonding of the polymer is activated by thehigher temperature applied in the thermoforming process and contributes tothe final strength of the thermoformed object.
    Although the polymer according to WO2014142714A1 may becontributing to the final strength and enabling forming of dry-laid web, suchthermoplastic ingredient will erase the sustainable features of the cellulosesince the composite will not be recyclable. This disadvantage is applicableeven if a renewable and compostable bio-plastic, e.g. polyactide (PLA) isused as proposed by WO2014142714A1, since logistics for material recyclingis not available.
    Recent findings and political decisions, e.g. Paris agreement on globalwarming 2015, stipulates that the carbon footprint of consumed goods andpackages, in so called life cycle analysis (LCA), is highly influenced by theability to recycle and reuse materials. Even renewable materials like cellulose and PLA must be recycled in order to measure up with multi recycled non-renewable materials like polyethylene terephthalate (PET). l/laterial recycling is slowly and gradually becoming more and moreestablished in most parts of the world. Europe has the global lead withapproximately 30% recycling while United States only has reached 10% andstill many development countries has not yet started to recycle. Common forall recycling efforts is a focus on the most frequently used materials such aspaper, card board, glass, aluminium, steel and PET. These recyclablefractions represent a vast majority of wasted goods and it is not likely thatother fractions, like bio-polymers, will be established as public availablerecycle logistics in a foreseeable future.
    The global demand for 3D formed packages, boxes, cups, plates,bowls, inserts and covers in renewable and recyclable material withmechanical properties close to plastics, is therefore huge.
    ISBN 978-91-7501-518-7 (Helena Halonen, October, 2012) hasstudied one approach - hydroxyethylcellulose (HEC) for creating a new all-cellulose composite material by compression moulding of commercialchemical wood pulps processed with only water. The objective was to studythe structural changes during processing and the complexity of relating themechanical properties of the final bio composites to the nano scale structure.
    The combination of high temperature (150 - 170 °C) and high pressure(45 lVlPa) during compression moulding yields a remarkable increase in fibrilaggregation, possibly including cellulose-cellulose fusion bonds, i.e., fibrilaggregation in the fibre-fibre bond region. This fibril aggregation is resulting ina bio-composite with remarkable mechanical properties including improvedstrength (289 lVlPa), modulus (12.5 GPa) and toughness (6°/>) to becompared to e.g. PET-strength (75 l/lPa) and PET-modulus (PET SGPa).
    Although WO2014142714A1 proposes non-recyclable thermoplasticingredient and ISBN 978-91-7501-518-7 presents scientific results for formingrecyclable cellulose fibres, to obtain good mechanical properties, no practicalor industrial method has so far been invented enabling commercial production, with reasonable cycle time, of packages and gods in cellulose asreplacement for plastics which are possible to recycle as cardboard.
    Summaryln view of the above-mentioned and other drawbacks of the prior art, it is an object of present invention to provide for cost-efficient and rationalproduction of a cellulose product with improved mechanica| properties.
    According to a first aspect of the present invention, it is thereforeprovided a method of manufacturing a cellulose product having a non-flatproduct shape, comprising the steps of: providing an isostatic pressuremou|ding apparatus comprising a forming mould having a forming surfacedefining the product shape, and a pressure mould; arranging a cellulose blankcontaining less than 45 weight percent water between the forming mould andthe pressure mould; heating the cellulose blank to a forming temperature inthe range of 100 °C to 200 °C; and pressing, by means of the pressure mould,the cellulose blank against the forming mould with a substantially equalforming pressure acting on the cellulose blank across the forming surface, theforming pressure being in the range of 1 l/lPa to 100 lVlPa.
    The heating step and the pressing step may at least partly take placeat the same time, or the cellulose blank may be pre-heated and no additionalheat supplied during pressing.
    The cellulose product may for example be a container or a part of acontainer where the cellulose product manufacturing using the methodaccording to embodiments of the present invention may, for example, replaceplastic products that are more difficult to recycle. Accordingly, celluloseproducts manufactured using the inventive method may, for example, bepackages, inserts for packages, boxes, bowls, plates, cups, trays, or covers.
    By the term “isostatic” should be understood the volumetric pressureon the fibres, of the heated bio-composite during the process of fibrilaggregation, is substantially equal in all geometrical locations of the final 3Dobject during production.
    The cellulose blank may be provided in various forms, for example as aweb, a rug, felt, lose fibres, foam, sheets, etc The blank might contain minorsubstances (0-10°/-.~) of agents for increasing strength, decreasing hygroscopyor making the final component hydrophobic, flameproof, colouring thecomponent or in other way alter the features of the final material. The amountof additives should however not jeopardize the purpose of this invention tomake the components recyclable as cardboard.
    The blank may be produced in a pulp converting plant as rug in rolls.
    The present invention is based upon the realization that a non-flatcellulose product can be made more homogeneous and with shorter cycletimes using an isostatic pressure moulding apparatus. ln particular, thepresent inventors have found that, depending on the desired shape of thecellulose product, an isostatic pressure acting on the cellulose blank willprovide for a remarkable decrease in the holding time needed to obtain thesame mechanical properties of the final product. Experiments have shownthat, for a given non-flat shape, an even temperature of 168 °C but an non-isostatic, i.e. uneven pressure, on the blank in or on the mould, that variesspatially for example 4.8 l/lPa +/- 10% will increase the required hold timeseveral times in order to secure acceptable mechanical properties in thoseareas of the component with the lowest pressure. ln this context it should be noted that the required process time toobtain acceptable mechanical properties of the final product is related to thehumidity of the blank and a specific temperature and a specific isostaticpressure.
    A temperature, preferable between 150 - 170 °C, and a pressure,preferable between 3-7 l/lPa, can generate different mechanical properties.For example, an isostatic temperature of 168 °C and an isostatic pressure of4.8 l/lPa at an air humidity of 50% relative humidity will generate a hard andstiff component at a holding time of 10 seconds. Lower temperature andpressure gives softer and more flexible components.
    Also too much water in the blank will increase holding times a lot. ISBN978-91 -7501 -518-7 describes holding times of 20 minutes and uses essentially wet pulp for the research. Experiments have shown that theoptimum water content in the cellulose blank at the time of processing shouldbe in the range 0.5 -10°/> weight. ln severe cases, with large pressure variations, in the blank duringbonding, parts of the component will never be acceptable regardless anyholding time.
    Prior art describes pulp compressing devices using traditional presseswith hydraulic cylinders that converts hydraulic pressure, called the pressuremedia, to a force on a tool or a mould via a piston of the cylinder. Whenforming non-planar objects, like hollow 3D-objects, a positive and a negativemould, with a cavity representing the desired thickness and shape of thecomponent in between, called mould cavity, which said mould is compressedby the force from the piston. Such a shape defined compressing device willlead to large variations in local pressure in the blank during heat processing, ifno compensation to the component thickness versus processing pressure isperformed. Any shape defined compressing device, without compensation forobtaining isostatic pressure, will thereby lead to uneven component qualityand, in most industrial cases, unacceptable cycle times for production. l/loreover, the inventors have found that the required pressure leveldrastically can be reduced if an isostatic pressure method is used. ISBN 978-91 -7501-518-7 has used a hollow hemisphere as reference object for theresearch using 45 l/lPa and 20 minutes in a shape defined compressingdevice. The internal pressure of the blank in the mould cavity is extremelyhigh on top (by the pole) and close to zero at the bottom (adjacent to theequator). The present inventors have now surprisingly found that, by using anisostatic pressure such an object can be produced with one tenth of the usedpressure at holding times counted in seconds.
    According to various embodiments of the present invention, thecellulose blank may contain wood pulp. Although so-called mechanical pulpcan be used for the cellulose blank, it has been found that chemical woodpulp yields better material properties of the product. ln embodiments, the cellulose blank may comprise at least 90 weightpercent wood pulp and thus be almost exclusively made by easily recyclablematerial.
    According to various embodiments, the pressure mould mayadvantageously comprise a flexible membrane, and the isostatic pressuremoulding apparatus further comprises a fluid control device for controlling afluid to exert an isostatic pressure on the cellulose blank via the fluidimpermeable membrane. ln this context it should be noted that the term fluid encompasses bothliquids and gases. ln some embodiments, the isostatic moulding apparatus may containthe pressure fluid in an enclosure partly bounded by the membrane. Byincreasing the amount of fluid in the enclosure and/or reducing the size of theenclosure, the fluid pressure will increase. The increasing fluid pressure will inturn result in an increased isostatic pressure acting on the cellulose blank.
    Accordingly, the above-mentioned fluid control device may be anactuator compressing the fluid or a fluid flow control device for controllableallowing pressurized fluid to enter a pressure chamber having the flexiblemembrane as a portion of a wall thereof. ln some embodiments, the above-mentioned membrane may be anintegral part of the apparatus, and may be used during a large number ofpressing operations. ln other embodiments, the membrane may be fixed to the celluloseblank, for instance by means of an adhesive, during pressing, and the methodmay further comprise the step of providing a new membrane following thepressing step. ln these embodiments, the membrane may for example beprovided on a roll, and may be added to the manufactured product to addfunctionality to the product. ln yet further embodiments, the above-mentioned membrane may beprovided on the cellulose blank.
    According to a second aspect of the present invention, it is provided anisostatic pressure moulding apparatus for manufacturing a cellulose product having a non-flat product shape starting from a cellulose blank, the isostaticpressure moulding apparatus comprising a forming mould having a formingsurface defining the product shape; an a f|uid control device for contro|ing af|uid to exert an isostatic pressure on the cellulose blank to press the celluloseblank against the forming surface.
    According to embodiments of the present invention, an isostaticpressure is obtained in force defined compressing devices, wherein saidcompressing devices comprises a flexible barrier or a membrane surroundingand separating the blank from the pressure media, e.g. gas, hydraulic oil,water, beverages to be packed, elastomer or dilatant material.
    A method and a device according to embodiments of the presentinvention relates to blow moulding of hollow 3D objects like bottles, milkpackages, cans and jars. Classic cellulose based packages for dairies andjuice experience competition from blow moulded PET-bottles. Despite the factthat cellulose and paper based packages are renewable and recyclable, themouldabillity of blow moulded PET has restrained the growth for folded paperpackages.
    According to said blow moulding embodiments, devices comprising, atleast two negative forming moulds surrounding said cellulose fibres and asingle use film layer barrier, to become an integrated part of the finalcomponent, wherein said cellulose fibres and said film layer barrier areprovided to the cavity of the moulds in a tube shape and wherein said filmlayer barrier will separate the pressure media, when filled into said tubeshape, from the cellulose fibres and wherein said pressure media will bepressurised to create an isostatic pressure on every portion of said cellulosefibres towards said forming moulds.
    Present invention will thereby provide a method, tube shaped blank, ablow moulding device and renewable packages with similar properties asthermoplastics wherein said packages are recyclable as paper and cardboard.
    Such a blow moulding device can preferably constitute the fillingequipment on site at a diary, brewery or juice factory by using the beverage orliquid to be packed, as said pressure media.
    According to other embodiments, an isostatic pressure is obtained inshape defined compressing devices, comprising two rigid moulds, onepositive and one negative wherein the cavity between the closed mouldsdefine the shape of the final three dimensional object and wherein thethickness of said cavity or the thickness of said blank, is designed to createan isostatic pressure on every portion of said cellulose fibres towards said moulds.
    Brief Description of the Drawinqs These and other aspects of the present invention will now be describedin more detail, with reference to the appended drawings showing exampleembodiments of the invention, wherein: Figs 1 a-c schematically show a conventional press method,compressing device and component Figs 2 a-b schematically show a first alternative configuration of thecompressing device, using multi-use membrane, shown initial stage (a) andcompressed stage (b) according to an example embodiment of the presentinvenfion; Figs 3 a-b schematically show a second alternative configuration of thecompressing device, comprising single-use material integrated barrier, showninitial stage (a) and compressed stage (b) according to an exampleembodiment of the present invention; Figs 4 a-d schematically show a third alternative configuration of thecompressing device and component, using single-use material integratedbarrier and blow moulding, shown initial stage (a & b) and compressed stage(c) according to an example embodiment of the present invention; Figs 5 a-b schematically show a fourth alternative configuration of thecompressing device, using multi-use membrane, shown initial stage (a) and compressed stage (b) according to an example embodiment of the presentinvenfion; Figs 6 a-c schematically show a fifth alternative configuration of thecompressing, using cavity compensating pressure control, shown initial stage(a & b) and compressed stage (c) according to an example embodiment ofthe present invention; Figs 7 a-b schematically show a sixth alternative configuration of thecompressing device, using blank thickness compensation, shown initial stage(a) and compressed stage (b) according to an example embodiment of the present invention.
    Detailed Description of Example Embodiments ln the present detailed description, various embodiments of blankaccording to the present invention are mainly discussed with reference to apiece of a rug or felt placed in position for forming in the mould, in a flatshape. lt should be noted that this by no means limits the scope of the presentinvention, which equally well includes, for example, blank pre-shaped into a3D object. For instance, the blank may be presented to the forming mould in ashape similar to the desired final shape of the object. Another embodimentcould comprise a flat rug or felt supplied to the mould in a web on a roll. l/loreover, by schematically showing a coherent sheet of cellulosefibres, this will by no means limit the scope of present invention, which equallywell includes, for example, blank with loos and separate fibres applied to theforming mould. ln the present detailed description, various embodiments of the threedimensional object to be formed and the mould to form the objects accordingto the present invention are mainly discussed with reference to a hollow bowl,a hollow cup or a hollow bottle, with mainly uniform thickness. lt should be noted that this by no means limits the scope of the presentinvention, which equally well includes, for example, complex shapes withdifferent thickness, non-hollow portions or massive objects. For instance, the 11 object can advantageously comprise stiffeners, creases, holes, 3D shapedtext, hinges, locks, threads, snaps, feet, handles or surface patterns.
    Figs 1a-c illustrate a conventional press method, compressing deviceand a component produced with non-isostatic pressure method and device.
    Fig 1a is a schematic side view of a prior art compressing device in anon-compressed state having a negative upper mould 102b and a positivelower forming mould 102a and a sheet of cellulose fibres 101 a.
    Fig 1b is a schematic side view of a prior art compressing device in acompressed state having a negative upper pressure mould 102b and apositive lower forming mould 102a and a sheet of cellulose fibres 101 a partlycompressed by the force F forming the desired final shape 101 b by usingheat and pressure P.
    As is customary, the thickness of the final component 101 b is uniformand consequently the thickness of the cavity t1 = rb - ra between the twomoulds 102a and 102b is uniform. Since conventional tools for compressingis made of stiff metal, or similar non-flexible material, and since dry cellulosefibres not behave as a pressure equalising fluid, the pressure P in said cavitywill depend on the amount of present blank 101 and the local pressuregenerating principle.
    The local pressure generating principle at pressure P2 and P5 isdefined by the force F. The local pressure generating principle at P4 is definedby the geometry of the cavity and the amount of present blank 101. The localpressure P3 is determined by a combination of force and shape definedpressure generating principle.
    A shape defined pressure, like P4, is highly dependent of the actualpresent amount of blank 101. Small and normally stochastic variations in thelocal material supply will drastically affect the obtained local pressure. Forcedefined pressure has linear gain and is a far more robust process forindustrial usage.
    Fig 1c illustrate a three dimensional object, component, a hemi sphere101 b produced with above described conventional compression method.Since it is likely that some blank 101 a will be stretched when the blank 101 a 12 bends over the lower mould 102a when the upper pressure mould 102bcloses the tool over the blank 101a, the mechanical properties is different inlocation 101b P4 than in location 101b P2 of the finished component 101b.
    A force defined compressing device according to an exampleembodiment of the present invention will now be described with reference tofigs 2a-b.
    Turning first to fig 2a, which is a schematic side view of the inventiveisostatic compressing device for cellulose fibres using heat shown in an openstate.
    This embodiment of the present invention uses only one stiff formingmould 2a placed under a multi-use membrane 4. The membrane 4 constitutesa seal for a pressure media or fluid 5, preferably, a hydraulic oil, contained ina pressure chamber, not shown in the figure. The membrane 4, also calleddiaphragm, can preferably be made of rubber, silicon, elastomer orpolyurethane.
    Similar press devices is found in completely different industries likeforming metal sheets for air crafts, processing of metallic powder intohomogeneous material. lsostatic presses for conventional purposes normallyuses very high pressures 1000 - 2000bar.
    The blank 1a, mainly cellulose fibres with some additives and agents,has been placed in the gap between the membrane 4 and the lower formingmould 2a.
    The blank 1a holds some humidity of water.
    At least, the mould 2a or the blank 1a, has to be pre heated to atemperature T1 and T2. lt is found preferable that the forming mould ispreheated to 150 - 170°C by pumping heated oil in internal channels 7. Analternative way to preheat the forming mould is to use integrated electricalresistors, not shown in the figure. The blank 1a can preferably be pre heatedusing infra read rays prior to tool entrance. Heating the pressure media 5 to atemperature T5 is also an alternative. ln fig 2b the hydraulic oil 5 has been pressurized to 1 - 100 l/lPa (P1) and the membrane 4 has wrapped the heated forming mould 2a with the 13 compressed material 1b in between. A uniform pressure P1 compresses thecellulose fibres evenly regardless of their relative position on the formingmould 2a and regardless of the actual local amount of fibres.
    The compressing device may comprise a fluid control device (notshown in figs) and may be an actuator compressing the fluid 5 or a fluid flowcontrol device for controllable allowing pressurized fluid 5 to enter saidpressure chamber having the flexible membrane 4 as a portion of a wallthereof.
    The apparatus may comprise the fluid 5, or the fluid 5 may be air takenfrom the surrounding atmosphere.
    The present inventors has found that a pressure of P1=4 lVlPa (40 bar)at 160°C gives a fibril aggregation in the cellulose fibres that compares withmany thermoplastics after 10 seconds of holding time. ln order to reduce the cycle time for industrial production ofcomponents 1b cooling of said component can preferably be done bypumping cooled oil into the channels 7 or into the pressure chamber whereinthe forming mould 2a temperature T2 and pressure media 5 temperature T5quickly can be lowered after the fibril aggregation has completed in thecellulose fibres.
    The process and the device will return to its open state shown in fig 2aby lowering the pressure media 5 to atmosphere pressure P0 wherein saidmembrane 4 will retract to its more or less flat initial state and wherein thefinished component 1b can be ejected and preferable be cut free from unwanted residual compressed or un-compressed cellulose fibres.
    The final thickness t1 of the component may vary slightly depending onthe actual local amount of cellulose fibres.
    The main difference between the inventive isostatic compressingmethod and device in fig 2a-b and the prior art method and device in fig. 1 a-blies in the configuration using a flexible or pliable membrane 4 instead of thestiff upper mould 102b. An isostatic compressing method and device resultsin a homogeneous component with high strength and short production cycle time. 14 Above, one example embodiment of the inventive isostaticcompressing method and device was described with reference to figs 2a-b. ltshould be understood that forming of three-dimensionally objects in all-cellulose composite using heated compression moulding of wood pulpsprocessed with only water can be obtained in other ways while still achievingisostatic pressure.
    Referring to figs 3a-b, the multi-use membrane 4 in fig 2a-b has beenreplaced with a single-use membrane comprising a thin film barrier 6 whereinsaid barrier 6 is pre applied to the cellulose fibres 1a preferably when theblank 1a and 6 was produced or wherein said barrier 6 is provided to thecompressing device, preferably from rolls, not shown in figure, and applied tothe cellulose fibres 1a during the isostatic compression of the component 1band 6.
    Said thin film barrier 6 can preferable be made of a thermoplasticmaterial like PET or PLA, having a thickness of 1- 700 um.
    Fig 3a schematically shows the method comprising a compressingdevice in its initial open state, using a thin film barrier 6 applied to thecellulose fibres 1a comprising a lower negative mould 2b preheated totemperature T2 and a pressure media or fluid 5, preferably gas or air atatmospheric pressure, contained in a pressure chamber, not shown in thefigure.
    Fig 3b show the same device and blank as Fig 3a in compressed statewherein said pressure media 5, preferably compressed air or a non-contaminating liquid as water, has been pressurized to the pressure P1 andwherein said thin film barrier 6 separates and seals said pressure media fromthe cellulose fibres 1b and wherein said pressure media 5 and membrane 6forming equal pressure acting on the cellulose fibres across the heatedforming surface, with a temperature T2, of said forming mould 2b.
    By holding the said equal pressure P1 at the temperature T1/T2 forperiod of X seconds, as an example P1=4 l/lPa (40 bar), T1= 140 °C, T2 = 160 °C and X = 10 seconds, the fibril aggregation in the cellulose fibres will create a bio composite component 1b with mechanical properties close to thermosplastics.
    By removing the pressure media 5 and lower the pressure toatmosphere pressure P0 after X seconds the component 1b can be ejectedand if needed cut.
    One advantage with the method discussed in fig 3a-b is that the barrier6 also can function as a barrier towards other media to be exposed to thecomponent during usage. For example, if the component 1b + 6 is a bowl foron-the-go salads it is preferred to have a barrier 6 to protect the cellulosefibres 1b from contact with the vegetables and to decrease the hygroscopicfeatures of the bowl.
    Turning to figs 4a-d, the mould 2a and 2b comprise at least two openand closable negative forming surfaces surrounding a tube shaped blankcomprising two layers 1a and 6 wherein the outer layer is uncompressedcellulose 1a fibres and its additives and the inner layer 6 a single-usemembrane comprising a thin film barrier 6. The blank can preferably besupplied to the compressing device in rolls, not shown in the figure, in flatshape wherein the blank is formed into a tube shape, not shown in the figure,surrounding a pressure media nozzle 8. ln fig 4a said forming moulds 2a and 2b, pre heated to T2, isschematically shown in the open initial stage of the forming process method.The tube shaped blank 1a and 6 is supplied from the top surrounding thefixed pressure media nozzle 8.
    By closing the pre heated forming moulds 2a and 2b with a closingforce Fc which is higher than an opening force created by the pressure P1shown in fig 4c. The closed state of the forming moulds 2a and 2b isschematically shown in fig 4 b-c. The closing force Fc and the design of theforming moulds 2a and 2b adjacent to the top and bottom of the cavity willseal the inner volume of the blank from the outside atmospheric pressure P0.lt is even more advantageous if the blank is cut by the forming moulds fromresidual material when the tool is closed. 16 Fig 4c shows the forming and febrile aggregation phase of the methodof present invention wherein said inner volume of the blank has been filledwith pressure media 9 from the pressure media nozzle 8 and pressurized tothe pressure P1 wherein said pressure media 9 and the single-use membrane6 forming equal pressure acting on the cellulose fibres across the heatedforming surface of said forming moulds 2a and 2b.
    The filling process taking place between fig 4b and 4c requires airchannels 10 to enable the air outside the blank 1a and 6 in the cavity of theforming mould 2a and 2b to be drained during the blank expansion process.
    Fig 4d illustrates a three dimensional hollow object 1b and 6, e.g. abottle for beverages, formed by the method described in fig 4a-c filled withsaid pressure media 9 wherein said barrier 6 separates the pressure media 9from the compressed cellulose fibres 1b.
    According to present invention it is advantageous that said pressuremedia 9 is made of the beverage that is intended to be delivered by saidbottle 1b and 6, e.g. milk, juice, water and carbonated beverages.
    Said thin film barrier 6 can preferable be made of a thermoplasticmaterial like PET or PLA, having a thickness of 1- 700 um wherein saidbarrier 6, conventionally applied in paper packages for beverages, also sealthe cellulose fibres 1b from contact with said beverage 9 during storage andusage of said bottle 1b and 6.
    The cycle time for the process step shown in fig 4c can be reduced ifthe beverage 9 is cooled to the temperature Tg, preferably 1-20 °C, and filledfast, preferably in less than a second. lf the forming moulds 2a and 2b ispreheated T2, preferably 200 °C and the blank is preheated to T1, preferably140 °C, said pressure media temperature Tg will enable release of the filledbottle 1b from the forming moulds 2 a and 2b in cycle times of seconds orless.
    Fig 5a-b schematically shows another principle of present inventionwherein the compressing device comprises at least one positive formingmould 2a, at least one negative pressure mould 2b and a multi-use preshaped membrane 4 wherein the pressure media 5 is pressurized to the 17 pressure P1 after the moulds 2a and 2b, surrounding the blank 1a, has beenclosed.
    The final forming stage where febrile aggregation in the cellulose fibres1a take place is shown in fib 5b. The enlarged cross section shown upperright in fig 5b illustrates how the pressure media 5 penetrates between theupper pressure mould 2b and the membrane 4 wherein an isostatic pressureP1 uniformly will compress the cellulose fibres 1a-b towards the formingsurface of the pre heated T2 lower positive forming mould 2a. Saidpenetration can be facilitated by minor indentations, not shown in the figure,in the surface of the upper pressure mould 2b acting as micro channels forthe pressure media 5.
    The embodiment of the compressing device according to figs 5a-b isbeneficial compared to the method discussed in figs 2a-b wherein shortercycle times if preferred. The membrane 4 does not have to deform to thesame extent in fig 5a-b.
    Above, examples of embodiment of the inventive isostatic compressingmethod, with reference to figs 2 - 5, comprises a flexible membrane. lt shouldbe understood that forming of three-dimensionally objects in all-cellulosecomposite using heated compression moulding of wood pulps processed withonly water can be obtained using conventional tools while still achievingisostatic pressure.
    Referring to figs 6a-c, an upper pre heated T2 negative non-flexiblepressure mould 2b and a lower pre heated T2 positive non-flexible formingmould 2a, surrounds the blank 1a wherein the cavity thickness t(P) betweensaid forming 2a and said pressure mould 2b deviate from nominal eventhickness wherein said deviation is theoretically and/or practically establishedto create an isostatic pressure P1 on every portion of said cellulose fibres 1atowards said moulds 2a and 2b when said moulds are pressed together withthe force F.
    Fig 6a schematically shows the embodiment in an initial open state with the blank in a flat state fed to the moulds in a continuous web 1a. 18 Fig 6c schematically shows the embodiment in a closed state with theblank 1a in a compressed non-flat state.
    Fig 6b schematically shows the embodiment in a state in betweenopen fig 6a and closed fig 6c in a non-compressed non-flat state.
    Figs 6a-c show an example of a compressing device for a hollow bowlwhere the forming mould 2a has a nominal, preferred, shape and where thepressure mould 2b has a compensated shape in order to obtain equalpressure P1.
    As shown in fig 6b the blank is deformed by the two moulds 2a and 2bwherein the thickness t of the blank 1a varies due to friction and deformationrestrain in the blank 1a. ln this schematic example, which can be altered inmany ways, the blank 1a will end up with a thinnest thickness t,11111, adjacent tothe cavity entrance of the pressure mould 2b and a thickest thickness tmax onthe top of the forming mould 2a.
    The cavity thickness s between the two moulds 2a and 2b is thereforecompensated so the most narrow cavity thickness s,11111 is situated adjacent towhere the blank is thinnest tmm and the most wide cavity thickness smax issituated adjacent to where the un-compressed blank 1a is thickest tmax bymeans of said pressure mould 2b, said cellulose blank 1a against saidforming mould 2a with a substantially equal forming pressure P1 acting on thecellulose blank 1a across said forming surface. l/loreover, the relation between t and s and the final cavity shape, isalso related to the geometrical pressure generation of the cavity. The force Fdetermines the pressure P1 on top of the forming mould 2a while theconvexity, thickness and angel of the cavity adjacent to sm111 determines thefinal pressure P1.
    The inventors of present invention has found that the final shape of thecavity is a complex algorithm t(P) to obtain substantially isostatic pressure P1where both mathematical, preferably FEl/I-analysis, and empirical tests,preferably trial-and-error, is required to obtain equal pressure all over the component. 19 According to another embodiment of the present invention, withoutflexible membrane, the geometrically pressure compensated cavity in figs 6a-c can be substituted with thickness compensation of the blank.
    Figs 7 a-b schematically shows a traditional non-compensatedpressure mould 2b and a non-compensated forming mould 2a, with apreferred equal and nominal cavity thickness t wherein the blank has apressure compensated thickness tmin - tmax established with same theory andin the same manner as described for the embodiment discussed in figs 6a-c.
    The preference for the method of creating isostatic pressure withoutflexible membrane, presented in figs 6 a-c and 7 a-b, relates to shorter cycletime and lower cost for the compressing device. However, the developmenteffort might be more costly for the method using stiff moulds.
    The advantage for using the method described in figs 7 a-b over 6 a-cis even thickness t1 of the final component 1b. However, the blanks might bemore costly to produce in the method described in figs 7 a-b. ln the claims, the word "comprising" does not exclude other elementsor steps, and the indefinite article "a" or "an" does not exclude a plurality. Themere fact that certain measures are recited in mutually different dependentclaims does not indicate that a combination of these measured cannot be used to advantage.
    权利要求:
    Claims (14)
    [1] 1. A method of manufacturing a cellulose product having a non-flatproduct shape, comprising the steps of: providing an isostatic pressure moulding apparatus comprising aforming mould having a forming surface defining said product shape, and apressure mould; arranging a cellulose blank containing less than 45 weight percentwater between said forming mould and said pressure mould; heating said cellulose blank to a forming temperature in the range of100°C to 200 °C; and pressing, by means of said pressure mould, said cellulose blankagainst said forming mould with a substantially equal forming pressure actingon the cellulose blank across said forming surface, said forming pressurebeing in the range of 1 l/lPa to 100 l/lPa.
    [2] 2. The method according to claim 1 wherein said cellulose blank contains less than 25 weight percent water.
    [3] 3. The method according to claim 2 wherein said cellulose blankcontains less than 15 weight percent water.
    [4] 4. The method according to any one of the preceding claims wherein said cellulose blank comprises wood pulp.
    [5] 5. The method according to claim 4, wherein said cellulose blank comprises at least 90 weight percent wood pulp.
    [6] 6. The method according to any one of the preceding claims, wherein said step of heating at least partly takes place before said step of pressing. 21
    [7] 7. The method according to any one of the preceding claims, whereinat least one of said forming mould and said pressure mould is heated before said step of pressing.
    [8] 8. The method according to any one of the preceding claims, wherein: said pressure mould comprises a flexible membrane; and said isostatic pressure moulding apparatus further comprises a f|uidcontrol device for contro|ing a f|uid to exert an isostatic pressure on said cellulose blank via said f|uid impermeable membrane.
    [9] 9. The method according to claim 8, wherein: said membrane becomes fixed to said cellulose blank during pressing;and the method further comprises the step of providing a new membrane following said step of pressing.
    [10] 10. The method according to claim 9, wherein said cellulose blankcomprises said membrane on a side of said cellulose blank facing away from said forming mould.
    [11] 11. An isostatic pressure moulding apparatus for manufacturing acellulose product having a non-flat product shape starting from a celluloseblank, said isostatic pressure moulding apparatus comprising: a forming mould having a forming surface defining said product shape;and a f|uid control device for contro|ing a f|uid to exert an isostatic pressureon said cellulose blank to press said cellulose blank against said forming surface.
    [12] 12. The apparatus according to claim 11, further comprising a pressuremould comprising a flexible membrane arranged between said f|uid controldevice and said cellulose blank. 5 22
    [13] 13. The apparatus according to claim 12, wherein said flexiblemembrane becomes fixed to said ce|u|ose blank during pressing.
    [14] 14. The apparatus according to claim 13, wherein said apparatusfurther comprises a membrane feeding arrangement for feeding new membrane material between consecutive pressing operations.
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    同族专利:
    公开号 | 公开日
    RU2018136582A|2020-04-20|
    EP3967615A1|2022-03-16|
    AU2017233234A1|2018-09-13|
    ZA201805706B|2020-01-29|
    RU2018136582A3|2020-06-10|
    JP2019513597A|2019-05-30|
    PL3429927T3|2021-08-23|
    MX2018010665A|2019-06-17|
    DK3429927T3|2021-03-29|
    RU2735554C2|2020-11-03|
    US20210245407A1|2021-08-12|
    MX2018010761A|2019-05-20|
    JP6940582B2|2021-09-29|
    JP2021191638A|2021-12-16|
    US20190070819A1|2019-03-07|
    JP2019513098A|2019-05-23|
    RS61751B1|2021-05-31|
    PT3429928T|2022-01-28|
    SE539948C2|2018-02-06|
    EP3429927A4|2019-12-25|
    CO2018009542A2|2018-11-30|
    EP3429927B1|2021-03-03|
    CL2018002601A1|2019-02-22|
    EP3429928A4|2019-11-27|
    HUE054335T2|2021-08-30|
    HRP20210628T1|2021-05-28|
    JP6884848B2|2021-06-09|
    JP6884848B6|2021-06-30|
    CN109415131B|2021-01-01|
    BR112018068720A2|2019-01-22|
    UA124012C2|2021-07-07|
    DK3429928T3|2022-01-31|
    CN109311547A|2019-02-05|
    WO2017160218A1|2017-09-21|
    CN109311547B|2021-12-14|
    AU2017233235A1|2018-09-13|
    US20190118426A1|2019-04-25|
    US11020883B2|2021-06-01|
    ES2863244T3|2021-10-11|
    EP3429928A1|2019-01-23|
    KR102268776B1|2021-06-23|
    JP2021119060A|2021-08-12|
    EP3736099A1|2020-11-11|
    SI3429927T1|2021-07-30|
    EP3882167A1|2021-09-22|
    CN112477072A|2021-03-12|
    EP3429928B1|2021-11-10|
    WO2017160217A1|2017-09-21|
    BR112018068731A2|2019-01-22|
    EP3429927A1|2019-01-23|
    KR20180129816A|2018-12-05|
    LT3429927T|2021-06-10|
    PT3429927T|2021-04-05|
    CA3017725A1|2017-09-21|
    CA3017728A1|2017-09-21|
    CN109415131A|2019-03-01|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    CN112166016A|2018-04-04|2021-01-01|斯道拉恩索公司|Method of making a dry-laid mat for thermoforming|GB895081A|1959-02-27|1962-05-02|Kurashiki Rayon Kk|Papers and unwoven cloths containing synthetic fibres of polyvinyl alcohol|
    SE391757B|1973-03-26|1977-02-28|Kuesters E|METHOD OF MANUFACTURING SHEET-SHAPED FOREMALS OF IN INDIVIDUAL FIBERS SPECIFIED CELLULOSA|
    SE399015B|1976-10-06|1978-01-30|Reinhall Rolf|WAY TO MAKE FIBER PLATES|
    US4474846A|1981-04-06|1984-10-02|Van Dresser Corporation|Moldable fibrous mat and product molded therefrom|
    US4640810A|1984-06-12|1987-02-03|Scan Web Of North America, Inc.|System for producing an air laid web|
    US4708626A|1985-03-14|1987-11-24|Denki Kagaku Kogyo Kabushiki Kaisha|Mold assembly|
    SU1493706A1|1987-09-14|1989-07-15|Всесоюзное научно-производственное объединение целлюлозно-бумажной промышленности|Method of producing pulp|
    JPH04166970A|1990-10-31|1992-06-12|Ricoh Co Ltd|Fixing device|
    US5302445A|1991-08-22|1994-04-12|Leucadia, Inc.|Process for making a reinforced fibrous mat and product made therefrom|
    CN2115359U|1991-12-06|1992-09-09|湖南纸浆模塑厂|Die set for moulding paper fibre tray|
    DE69412846T2|1993-10-28|1999-02-11|Kobs Kroyer Ingelise|METHOD FOR PRODUCING FIBROUS, LEAF-SHAPED MATERIAL|
    US6010595A|1996-10-11|2000-01-04|Eastman Chemical Company|Multiply paper comprising a mixture of cellulose fibers and cellulose ester fibers having imparted softening properties and a method of making the same|
    US5904643A|1997-06-13|1999-05-18|Tenneco Packaging|Tray-forming and apparatus|
    RU2215648C2|1997-07-18|2003-11-10|Мейсонайт Интернэшнл Корпорейшн|Method of deformation of semifinished product of wood-fiber board and device for method embodiment |
    CN1230386A|1998-03-27|1999-10-06|江苏南浦机电集团股份有限公司|Plant fiber tableware, food and article packing products and their production|
    US6454906B1|1999-02-18|2002-09-24|Kao Corporation|Process for producing pulp molded article|
    JP3249800B2|1999-11-17|2002-01-21|花王株式会社|Method for producing pulp molded article|
    US7077933B2|2000-03-01|2006-07-18|Kao Corporation|Pulp molded body|
    JP2001322190A|2000-05-17|2001-11-20|Kondo Machinery Co|Equipment and method for forming|
    NO320290B1|2000-05-31|2005-11-21|Oji Paper Co|Moldable base paper and scales made from this|
    JP2002008237A|2000-06-23|2002-01-11|Fujitsu Ltd|Information recording method and information recorder used for execution thereof|
    KR100858041B1|2000-10-03|2008-09-10|오지 세이시 가부시키가이샤|Molding base paper and molded paper vessel produced from it|
    SE519670C2|2000-11-24|2003-03-25|Nyboms Ingenjoerer Ab|Manufacture of plastic laminated cellulose fiber containing products for packaging of foodstuffs|
    US6830797B2|2001-02-21|2004-12-14|Gfp Strandwood Corporation|Wood strand molded part having holes with densified and thinner perimeters and method of making same|
    DE60237523D1|2001-06-19|2010-10-14|Sarong Spa|DEVICE, MANUFACTURER AND METHOD FOR PRODUCING SURFACE MATERIAL|
    US20040045690A1|2001-08-03|2004-03-11|Keiji Eto|Molded pulp product, and method and apparatus for production thereof|
    CN1165658C|2001-08-31|2004-09-08|武汉第二机床厂|Process and mould for forming food or beverage container with plant fibres|
    JP2003311721A|2002-04-23|2003-11-05|Kukida Teiichi|Molding method using wood flour as raw material and molded article|
    JP2004346441A|2003-05-21|2004-12-09|Toppan Printing Co Ltd|Fiber sheet and its laminate, molded article, and method for decorating them|
    US7481645B2|2003-06-27|2009-01-27|Biosphere Industries, Llc|Method for use in baking articles of manufacture and mold for use in said method|
    CN1647948A|2005-01-01|2005-08-03|王志深|Pulp handicraft and its producing method|
    ITMI20060447A1|2006-03-14|2007-09-15|Paper Technologies S R L|METHOD TO PRODUCE ONE OR MORE PRODUCTS PRODUCED MADE WITH A CALLED METHOD AND SYSTEM FOR ITS REALIZATION|
    SE529897C2|2006-03-27|2007-12-27|Rottneros Ab|Molded trough|
    AT443003T|2006-03-30|2009-10-15|Hartmann As Brdr|THREE-DIMENSIONAL PACKAGING|
    KR100854731B1|2006-07-21|2008-08-27|네오프리라인|Method and apparatus for authentication of portable electronic devices|
    CN1958946B|2006-10-30|2010-05-12|上海嘉翰轻工机械有限公司|Dry-process papermaking machine through meshwork formed by airflow method|
    ES2354314T3|2007-02-28|2011-03-14|Basf Se|HOLES BODIES CONSTITUTED BY RESILIENT POLYSTYRENE, INJECTION PROCEDURE WITH BLOWING AND STRETCHING FOR THEIR OBTAINING AND EMPLOYMENT OF THE HOLLOW BODY.|
    US8545953B2|2007-02-28|2013-10-01|Styrolution GmbH|Hollow polystyrene body obtained by injection stretch blow moulding|
    CN101259752A|2007-03-06|2008-09-10|和成欣业股份有限公司|Composite material forming method|
    WO2008106993A1|2007-03-07|2008-09-12|Dsm Ip Assets B.V.|Method of making cellulose/plastic pellets having a low plastic content|
    CN201068210Y|2007-06-20|2008-06-04|潘震州|Full-automatic thermoforming paper-plastic packing machine|
    JP4953945B2|2007-07-03|2012-06-13|ユニ・チャーム株式会社|Individual package of absorbent article, packaging sheet, and method for producing packaging sheet|
    CN201287979Y|2008-06-30|2009-08-12|上海欧励达机械设备制造有限公司|Laminating machine employing down suction type paper transport mechanism|
    FI20085702A|2008-07-04|2010-01-05|Stora Enso Oyj|Method for making a board-based molded piece and a mold suitable for it|
    RU2533834C2|2009-06-16|2014-11-20|ХАНТСМЭН ИНТЕРНЭШНЛ ЭлЭлСи|Reaction system and method of obtaining lignocellulose product|
    EP2522772A1|2011-05-11|2012-11-14|Ecoxpac A/s|Container|
    WO2014142714A1|2013-03-11|2014-09-18|Sca Forest Products Ab|Dry-laid composite web for thermoforming of three-dimensionally shaped objects, a process for its production, thermoforming thereof, and a thermoformed three-dimensionally shaped object|
    JP6442857B2|2014-04-14|2018-12-26|セイコーエプソン株式会社|Sheet manufacturing equipment|
    US10086540B2|2015-02-27|2018-10-02|Teijin Limited|Method for manufacturing press molded product and manufacturing apparatus for press molded product|
    SE539948C2|2016-03-18|2018-02-06|The Core Company Ab|Isostatic pressure forming of heated dry cellulose fibers|
    WO2018033208A1|2016-08-18|2018-02-22|Mayr-Melnhof Karton Ag|Method for manufacturing a molded article from pulp, molded article made of pulp, and apparatus for manufacturing such a molded article|SE539948C2|2016-03-18|2018-02-06|The Core Company Ab|Isostatic pressure forming of heated dry cellulose fibers|
    DE102017103847A1|2017-02-24|2018-08-30|Voith Patent Gmbh|Method and device for producing a fibrous web in a paper machine|
    PL3631085T3|2017-06-02|2021-09-13|Huhtamaki Molded Fiber Technology B.V.|Method for manufacturing a 3-dimensional shaped product from a fluff pulp material|
    WO2019209160A1|2018-04-25|2019-10-31|Pulpac AB|A method for producing a cellulose product|
    DE202018103255U1|2018-06-11|2019-09-12|A&R Carton Gmbh|Folding box suitable for packaging a menu tray|
    EP3587665B1|2018-06-26|2021-01-06|AR Packaging GmbH|Method and device for producing a three-dimensional product based on cellulose|
    DE102019109911A1|2019-04-15|2020-10-15|Ar Packaging Gmbh|Method for producing a container with a barrier film and containers with a barrier film|
    CN111842605A|2019-04-30|2020-10-30|东莞市植本环保科技有限公司|Manufacturing method of pulp suction mold of stretching pore plate|
    WO2020229608A1|2019-05-16|2020-11-19|Pulpac AB|A method for producing cellulose products and a rotary forming mould system|
    WO2021037946A1|2019-08-30|2021-03-04|Pulpac AB|A method for producing cellulose products and a rotary forming mould system|
    SE1951346A1|2019-11-25|2021-05-26|Soedra Skogsaegarna Ekonomisk Foerening|Apparatus and method for pressure moulding|
    KR102192715B1|2019-12-01|2020-12-17|정기석|Method and apparatus for manufacturing naked bio cellulose sheet|
    WO2021148514A1|2020-01-23|2021-07-29|Gate Gourmet Switzerland Gmbh|Method of producing a cellulose-based product|
    SE2050129A1|2020-02-06|2021-08-07|Soedra Skogsaegarna Ekonomisk Foerening|Process for manufacturing a fiber based cellulose web for dry forming|
    CN111572901B|2020-05-27|2020-12-22|江苏帝全自动化机械有限公司|Packaging equipment for irregular articles|
    WO2022043225A1|2020-08-26|2022-03-03|Pulpac AB|A multi-cavity forming mould system and a method for forming cellulose products in a multi-cavity forming mould system|
    KR102300658B1|2021-04-19|2021-09-08|정명규|Injection Mold for Crops Cup Manufacturing|
    法律状态:
    2020-03-17| CANC| Patent cancelled, revoked after opposition|
    优先权:
    申请号 | 申请日 | 专利标题
    SE1630058A|SE539948C2|2016-03-18|2016-03-18|Isostatic pressure forming of heated dry cellulose fibers|SE1630058A| SE539948C2|2016-03-18|2016-03-18|Isostatic pressure forming of heated dry cellulose fibers|
    MX2018010761A| MX2018010761A|2016-03-18|2017-03-16|Method for manufacturing a cellulose product, cellulose product forming apparatus and cellulose product.|
    SI201730724T| SI3429927T1|2016-03-18|2017-03-16|Method for manufacturing a cellulose product by a pressure moulding apparatus, pressure moulding apparatus and cellulose product|
    UAA201810218A| UA124012C2|2016-03-18|2017-03-16|Method for manufacturing a cellulose product, cellulose product forming apparatus and cellulose product|
    RU2018136582A| RU2735554C2|2016-03-18|2017-03-16|Method of producing cellulose product, device for molding cellulose product and cellulose product|
    CA3017725A| CA3017725A1|2016-03-18|2017-03-16|Method for manufacturing a cellulose product by a pressure moulding apparatus, pressure moulding apparatus and cellulose product|
    PCT/SE2017/050255| WO2017160218A1|2016-03-18|2017-03-16|Method for manufacturing a cellulose product, cellulose product forming apparatus and cellulose product|
    EP20175190.6A| EP3736099A1|2016-03-18|2017-03-16|Method for manufacturing a cellulose product by a pressure moulding apparatus, pressure moulding apparatus and cellulose product|
    DK17767071.8T| DK3429928T3|2016-03-18|2017-03-16|Method of making a cellulosic product, cellulosic product forming apparatus and cellulosic product|
    CN201780030538.9A| CN109415131B|2016-03-18|2017-03-16|Method for producing a cellulose product by means of a pressure moulding device, pressure moulding device and cellulose product|
    BR112018068731A| BR112018068731A2|2016-03-18|2017-03-16|method for producing a cellulose product, pressure molding apparatus, and cellulose product.|
    ES17767070T| ES2863244T3|2016-03-18|2017-03-16|Method of manufacturing a cellulose product by means of a die casting apparatus, a die casting apparatus and a cellulose product|
    AU2017233235A| AU2017233235A1|2016-03-18|2017-03-16|Method for manufacturing a cellulose product, cellulose product forming apparatus and cellulose product|
    US16/085,456| US20190118426A1|2016-03-18|2017-03-16|Method for manufacturing a cellulose product by a pressure moulding apparatus, pressure moulding apparatus and cellulose product|
    PT177670718T| PT3429928T|2016-03-18|2017-03-16|Method for manufacturing a cellulose product, cellulose product forming apparatus and cellulose product|
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    EP21162661.9A| EP3882167A1|2016-03-18|2017-03-16|Method for manufacturing a cellulose product, cellulose product forming apparatus and cellulose product|
    KR1020187029222A| KR102268776B1|2016-03-18|2017-03-16|Cellulose product manufacturing method, cellulosic product molding apparatus and cellulosic product|
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    PT177670700T| PT3429927T|2016-03-18|2017-03-16|Method for manufacturing a cellulose product by a pressure moulding apparatus, pressure moulding apparatus and cellulose product|
    RS20210473A| RS61751B1|2016-03-18|2017-03-16|Method for manufacturing a cellulose product by a pressure moulding apparatus, pressure moulding apparatus and cellulose product|
    AU2017233234A| AU2017233234A1|2016-03-18|2017-03-16|Method for manufacturing a cellulose product by a pressure moulding apparatus, pressure moulding apparatus and cellulose product|
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    MX2018010665A| MX2018010665A|2016-03-18|2017-03-16|Method for manufacturing a cellulose product by a pressure moulding apparatus, pressure moulding apparatus and cellulose product.|
    PCT/SE2017/050254| WO2017160217A1|2016-03-18|2017-03-16|Method for manufacturing a cellulose product by a pressure moulding apparatus, pressure moulding apparatus and cellulose product|
    JP2019500208A| JP6940582B2|2016-03-18|2017-03-16|Manufacturing method of cellulose products by pressure molding equipment and pressure molding equipment|
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    BR112018068720A| BR112018068720A2|2016-03-18|2017-03-16|method for manufacturing a cellulose product, cellulose product forming apparatus, and cellulose product.|
    EP17767070.0A| EP3429927B1|2016-03-18|2017-03-16|Method for manufacturing a cellulose product by a pressure moulding apparatus, pressure moulding apparatus and cellulose product|
    LTEP17767070.0T| LT3429927T|2016-03-18|2017-03-16|Method for manufacturing a cellulose product by a pressure moulding apparatus, pressure moulding apparatus and cellulose product|
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    ZA2018/05706A| ZA201805706B|2016-03-18|2018-08-27|Method for manufacturing a cellulose product, cellulose product forming apparatus and cellulose product|
    CL2018002601A| CL2018002601A1|2016-03-18|2018-09-11|Method for the manufacture of a cellulose product, apparatus for forming a cellulose product and cellulose product.|
    CONC2018/0009542A| CO2018009542A2|2016-03-18|2018-09-12|Method for manufacturing a cellulose product, apparatus for forming a cellulose product and cellulose product|
    HRP20210628TT| HRP20210628T1|2016-03-18|2021-04-21|Method for manufacturing a cellulose product by a pressure moulding apparatus, pressure moulding apparatus and cellulose product|
    US17/242,833| US20210245407A1|2016-03-18|2021-04-28|Method for manufacturing a cellulose product, cellulose product forming apparatus and cellulose product|
    JP2021081051A| JP2021119060A|2016-03-18|2021-05-12|Method for manufacturing cellulose product, cellulose product forming apparatus, and cellulose product|
    JP2021143393A| JP2021191638A|2016-03-18|2021-09-02|Method for manufacturing cellulose products using pressure molding equipment, pressure molding equipment, and cellulose products|
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