![]() Screening device, rotor, wing package and production method
专利摘要:
lO 12 ABSTRACT The inVention re1ates to a screening apparatus for screening pu1p suspensions, comprising acasing (1), in Which casing (1) a cy1indrica1 screening member (5) is arranged for diVidingthe pu1p into accept and reject, an inlet (2) for the pu1p, an outlet (3) for the accept, anoutlet (4) for the reject, a rotor (8) comprising a rotor body (10) and at 1east one pu1sationmember (17) located on the inside of the screening member (5), so that a screening chamber(9) is formed between the rotor (8) and the screening member (5). According to theinVention the rotor (8) is provided With a detachab1e pu1sation member package (11)comprising at 1east one attachment ring (12) attached to the rotor body (10), at 1east onesupport ring (15, 16) attached to or supported by the rotor body (10) and the at 1east onepu1sation member (17) attached to the at 1east one attachment ring (12) and the at 1east one support ring (15, 16). Fig. 2a 公开号:SE1251345A1 申请号:SE1251345 申请日:2012-11-28 公开日:2014-05-29 发明作者:Anders Bergdahl;David Lindkvist 申请人:Valmet Oy; IPC主号:
专利说明:
lO SCREENING APPARATUS, ROTOR, WING PACKAGEAND METHOD FOR MANUFACTURE TECHNICAL FIELD The invention relates to a screening apparatus according to the preamble of claim l, to arotor and Wing package for said screening apparatus and to a method for manufacture of said screening apparatus.BACKGROUND Screening in papermaking means separation of foreign or different particles from a pulp suspension and may be done in different process steps in a f1bre line. Pulp from cooking inevitably contains unWanted solid material. Some of the chips may nothave cooked properly, and some of the f1brous material may not be completely in the formof individual f1bres. Defects in Wood may show up as non-fibrous solids. Contaminantsother than Wood may also enter cooking With chips. The purpose of screening is to removethese impurities from the main pulp stream for reject treatment as eff1ciently as possible andWash off the good fibres, retum these to the main pulp stream and prepare the reject for treatment. A screening apparatus, see e.g. EPO 444 051, may comprise a screen housing enclosing acylindrical barrier, called screen member, having apertures in the form of e. g. holes or slitsfor the actual screening. The screening apparatus may further comprise an i11let for the pulpsuspension leading into the screen member, an accept outlet for accept, i.e. material Withsmall particles that has passed through the screen member from the inside and out, and areject outlet for reject, i.e. material With large particles Which has not passed the screen member. To improve the screening, the screening apparatus may e. g. be provided With some sort ofrotor having pulsations members, e.g. blades or protrusions. Said rotor rotates inside thescreen member or else the screen member may be rotating. Further, the screen member may be provided With different variants of protrusions on its inner surface. lO In the prior art section of EP 205 623 is shown an open solution With Wings attached to a“spider” and a reinforcement ring. The loose structure is very unstable and not sufficientlyrigid to Withstand the forces especially since the Wings are attached With screWs or bolts. A similar loose, unstable structure is shown in US 4,328,096. In EP 444 051 and EP 868 564 the rotor is designed as a cylindrical rotor body having arrnsWith pulsation generating members, also called blades or Wings, Which are attached on themantle area of the rotor body. They have complicated manufacture, since a complicatedfixture is needed in order to position the Wings radially and circumferentially. Severalcomplicated fixtures are needed to be able to handle different screening apparatus sizes as Well. It is also complicated to change the Wings, When they are Wom or if you Want to change theWing design e.g. in order to optirnize the energy consumption. In order to get sufficientprecision, the Wings are preferably cast, Which may cause strength problems. Further, cast Wings may be Warped and have to be aligned. Cracks may occur in cast Wings. SUMMARY An object of the invention is to solve the above-mentioned problems With an invention as in claim l. An advantage is that manufacture is made simpler. Further, When the pulsation members areWom, the pulsation member package is easily replaced as a spare part, Without any need for replacing the Whole rotor. Thus, the rotor body may be reused. Another advantage is higher flexibility. A possibility is to have the rotor body as astandardized part, Which is the same for all or many different types of screeningapparatuses. The rotor body is then just used With the pulsation member package that isappropriate for the screening apparatus in question. This makes manufacture cheaper and simpler. lO Further, if there e.g. is a Wish to test different pulsation member configurations foroptimization of e.g. energy consumption, production or screening result, the pulsation member package may be easily exchanged and tested also by the customer himself BRIEF DESCRIPTION OF THE DRAWINGS The invention, together With further objects and advantages thereof, may best be understood by reference to the following member description and appended draWings, in Which: Fig. la-b are a schematic cross-sectional View With a detail View illustrating a screeningapparatus according to a first embodiment of the inVention. Fig. 2a-f are 3D Views, a side cross section view, a top View and a detail view illustrating arotor With a pulsation member package according to a second embodiment of the inVention.Fig. 3a-b are a 3D view and a side cross section View illustrating a rotor With a pulsationmember package according to a third embodiment of the inVention. Fig. 4 is a floW chart illustrating a manufacture process according to the inVention. DETAILED DESCRIPTION In the draWings, similar or corresponding elements are denoted by the same reference numbers. In Fig. la-b is shown a screening apparatus. In this example the screening apparatus is asingle screening apparatus, but the invention may of course be used in any screening apparatus - coarse or fine - having one or more screening members. The screening apparatus in Fig. la-b comprises an air-tight casing l With an inlet 2 for pulpsuspension, an accept outlet 3, a reject outlet 4 and a dilution Water inlet 25. In the casing la cylindrical screening member 5 is arranged, preferably With the axis of syrnrnetry being Vertical. Within the screening member 5 a rotor 8 is located, Which rotor 8 comprises a cylindrical or conical rotor body l0 and a detachable pulsation member package ll. The rotor 8 is concentric With the screening member 5, so that a screening Chamber 9 is formed between the rotor 8 and the screening member 5. A not shown motor drives the rotor 8. It is to be understood that the rotor embodiments described in the following description isnot restricted to the screening apparatus shown in Fig. 1a-b, but may be used in any kind ofscreening apparatus for coarse or fine screening, for screening from inside and out or for screening outside and in, etc. In Fig 2a-f another embodiment of the rotor 8 is shown in more detail. In Fig. 2b the rotorbody 10 is shown without the pulsation member package 11. In Fig. 2c the pulsation member package 11 is shown without the rotor body 10. The rotor body 10 preferably has a cylindrical, conical or similar stable shape. The pulsationmember package 11 in Fig. 2a-c comprises an attachment ring 12, a first support ring 15, asecond support ring 16 and seven pulsation generating members 17, such as wings. Theattachment ring 12 in Fig 2a-c is preferably located in one end of the pulsation memberpackage 11, while the first support ring 15 is located in the other end of the pulsationmember package 11 and the second support ring 16 is located in between the attachmentring 12 and the first support ring 15. The pulsation members 17 are attached to theattachment ring 12, the first support ring 15 and the second support ring 16. The attachment ring 12 is preferably attached to an end surface 13 of the rotor body 10. It isof course possible to instead attach the attachment ring 12 on a mantle surface 14 of therotor body 10 and then e.g. have the attachment ring 12 between the first support ring 15and the second support ring 16. However, an attachment on the end surface 13 will be morestable and less influenced by the passing pulp. The attachment is especially stable if theattachment is made all around the attachment ring 12, especially if the inner part 20 of theattachment ring 12 is provided with a circular profile, and said inner part 20 is attached to the rotor body 10. Since the pulsation member package 11 is meant as a wear part, the attachment is preferablymade by screws or bolts, but welding is of course also possible. It is possible to have more than one attachment ring 12. The first support ring 15 and the second support ring 16 have inner diameters 22, 21 thatare adapted so that the support rings 15, 16 will be supported by the rotor body 10. In smallconfigurations it might be suff1cient with only one support ring 15 and in large configurations more support rings might be needed for improved stability. It is not necessary to attach the support rings 15, 16 to the rotor body 10, as long as thesupport rings 15, 16 are supported by the rotor body 10. It is of course possible to attachalso the support rings 15, 16 to the rotor body 10, but that gives a higher fit requirementand thus a higher manufacture cost. A solution with less fit requirements might be just a pin23 attached to the rotor body 10 and a notch 24 in the support ring 15, 16 or vice versa, seeFig. 2f To improve the pulp flow through the screening apparatus and around the pulsationmembers 17, the attachment ring 12 and the support rings 15, 16 may be provided with cut- outs 18 in their outer peripheries 19. The pulsation members 17 are preferably attached with one end 28, 29 to one attachmentring 12 or support ring 15 and with another end 28, 29 to another attachment ring 12 orsupport ring 15, because that makes the most stable configuration. It is, however, possibleto have pulsation members 17 having a free end 28, 29 that extend a bit outside theattachment ring 12 or support ring 15 as in Fig. la. Said extension is, however, preferablynot longer than 200 mm, for stability. The pulsation members 17 are preferably attached by welding, but may also be e. g. screwed or bolted. Fig. 2a-c shows an embodiment with seven pulsation members 17, but any number ispossible. For stability, the pulsation members 17 are preferably evenly arranged around therings 12, 15, 16. The pulsation members 17 are simplest and cheapest made of bent plate.An altemative is to cast the pulsation members 17 in a more prof1led shape. An advantagewith a cast pulsation member 17 is that any shape can be achieved, e.g. like an aeroplane wing. Fig. 2a-c shows straight pulsation members 17 that are parallel to an axis of the rotor body10 in two dimensions. It is, however, possible also to have pulsation members 17 that are e.g. inclined in one dimension. Preferably, the distance between two pulsation members 17 is the same as the width of a pulsation member 17. The thickness of the pulsation members 17 may be e.g. 10-12 mm. When the pulsation members 17 are wom, the pulsation member package 11 is easilyreplaced as a spare part, without any need for replacing the whole rotor 8. Thus, the rotor body 10 may be reused. A possibility is also to have the rotor body 10 as a standardized part, which is the same forall or many different types of screening apparatuses. The rotor body 10 is then just usedwith the pulsation member package 11 that is appropriate for the screening apparatus in question. This makes manufacture cheaper and simpler. Further, if there e.g. is a wish to test different pulsation member conf1gurations foroptimization of e.g. energy consumption, production or screening result, the pulsation member package 11 may be easily exchanged and tested also by the customer himself In Fig. 3 is shown an embodiment where the pulsation member package 11 is a cylinder 30with an attachment ring 12 and a support ring 15 and a number of pulsation members 17. Inthis embodiment the pulsation members 17 are attached to the cylinder 30, which cylinder30 is attached to the attachment ring 12 and support ring 15. This means that the pulsationsmembers 17 are indirectly attached to the attachment ring 12 and the support ring 15, unlikethe other embodiments where the pulsation members are directly attached to the attachment ring 12 and the support ring 15. The screening apparatus may be provided with an i11let 25 for dilution water, see Fig. 1a-b.If there in the other end is an outlet 26 for dilution water arranged at the rotor body 10,then there is a risk that the rotor body 10 will wear. If e.g. the dilution water is not highenough and f1bres stick at the outlet 26, torsion and thus wear may occur. In order to keepthe rotor body 10 as a part that will not wear unnecessarily, the rotor 8 may therefore be provided also with a wear ring 27 in the proximity of the dilution water outlet 26. In this embodiment the Wear ring 27 is attached on the bottom of the rotor body 10. This meansthat the rotor 8 in Fig. 1 is provided With two Wear parts: a pu1sation member package 11 and a Wear ring 27. The Wear ring 27 may of course a1so be used separate1y as spare part. When the rotor 8 is manufactured there is no need for any comp1icated fixtures. Either thepu1sation member package 11 is app1ied directly on the rotor body 10 or, if the pu1sationmember package 11 is made as a spare part, the pu1sation member package 11 is app1ied onto a simp1e fixture having the contours of a rotor body 10. First the rotor body 10 or sirnple fixture is made, if necessary, step 101, Fig. 4. See a1so any of the figures 1a-b, 2a-f, and 3a-b. The attachment and support rings 12, 15, 16 are each precision cut, e.g. Water cut, bycutting the contours and positions for the pu1sation members 17 and the contours andpositions for the cut-outs 18, if any, between the pu1sation members 17, step 102. If the cutis made With suff1cient precision the attachment and support rings 12, 15, 16 may 1ater serve as a fixture for the pu1sation members 17. The pu1sation members 17 are made by e. g. cutting and bending the pu1sation members 17 from a p1ate or by e. g. casting the pu1sation members 17 to an appropriate shape, step 103.The rotor body 10 or the simp1e fixture is positioned, preferab1y Vertica11y, step 104. At 1east one attachment ring 12 and at 1east one support ring 15, 16 are a1igned a1ong therotor body 10 or sirnple fixture and are attached or supported, step 105. Supports attachedto the rotor body 10 or sirnp1e fixture is preferab1y used for the Vertical alignment. At 1east one pu1sation member 17 is attached to the at 1east one attachment ring 12 and theat 1east one support ring 15, 16, step 106. This Wi11 a1so enab1e the rotary alignment of the at 1east one attachment ring 12 and the at 1east one support ring 15, 16. The invention is of course not restricted to the shown embodirnents, but may be Varied Within the scope of the clairns.
权利要求:
Claims (17) [1] 1. A screening apparatus for screening pu1p suspensions, comprising a casing (1), in Whichcasing (1) a cy1indrica1 screening member (5) is arranged for dividing the pu1p into acceptand reject, an in1et (2) for the pu1p, an out1et (3) for the accept, an out1et (4) for the reject, arotor (8) comprising a rotor body (10) and at 1east one pu1sation member (17) 1ocated onthe inside of the screening member (5), so that a screening chamber (9) is formed betweenthe rotor (8) and the screening member (5), characterized in that the rotor (8) is providedWith a detachab1e pu1sation member package (11) comprising at 1east one attachment ring(12) attached to the rotor body (10), at 1east one support ring (15, 16) attached to orsupported by the rotor body (10) and the at 1east one pu1sation member (17) attached to theat 1east one attachment ring (12) and the at 1east one support ring (15, 16). [2] 2. A screening apparatus according to c1airn 1, characterized in that an attachment ring (12) is attached to an end surface (13) of the rotor body (10). [3] 3. A screening apparatus according to clairn 2, characterized in that an inner part (20) ofthe attachment ring (12) is provided With a circu1ar profile, and in that the attachment ring (12) is attached With said inner part (20) to the rotor body (10). [4] 4. A screening apparatus according to c1airn 1, characterized in that the at 1east onepu1sation member (17) is attached With one end (28) to one attachment ring (12) and With the other end (29) to one support ring (15). [5] 5. A screening apparatus according to clairn 1, characterized in that a free end (28, 29) ofthe at 1east one pu1sation member (17) extends 1ess than 200 mm outside the attachment to an attachment ring (12) or a support ring (15). [6] 6. A screening apparatus according to clairn 1, characterized in that the at 1east oneattachment ring (12) is provided With cut-outs (18) in its outer periphery (19) between the attachments of the at 1east one pu1sation member (17), in order to improve the pu1p flow. [7] 7. A screening apparatus according to clairn 1, characterized in that the at least onesupport ring (15, 16) is provided With cut-outs (18) in its outer periphery (19) between the attachments of the at least one pulsation member (17), in order to improve the pulp flow. [8] 8. A screening apparatus according to clairn 1, characterized in that the at least one pulsation member (17) is made of a bent plate. [9] 9. A screening apparatus according to clairn 1, characterized in that the at least one pulsation member (17) is made of a cast profile. [10] 10. A screening apparatus according to claim 1, characterized in that the screeningapparatus is provided With a dilution Water outlet (26) near the rotor body (10), and in thatthe rotor body is provided With a Wear ring (27) in the proximity of the dilution Water outlet (26). [11] 11. A rotor for a screening apparatus for screening pulp suspensions, Which screeningapparatus comprises a casing (1), in Which casing (1) a cylindrical screening member (5) isarranged for dividing the pulp into accept and reject, an inlet (2) for the pulp, an outlet (3)for the accept and an outlet (4) for the reject; Wherein the rotor (8) comprises a rotor body(10) and at least one pulsation member (17) located on the inside of the screening member(5), characterized in that the rotor (8) is provided With a detachable pulsation memberpackage (11) comprising at least one attachment ring (12) attached to the rotor body (10),at least one support ring (15, 16) attached to or supported by the rotor body (10) and the atleast one pulsation member (17) attached to the at least one attachment ring (12) and the at least one support ring (15, 16). [12] 12. A rotor according to clairn 11, characterized in that an attachment ring (12) is attached to an end surface (13) of the rotor body (10). [13] 13. A pulsation member package for a screening apparatus for screening pulp suspensions,Which screening apparatus comprises a casing (1), in Which casing (1) a cylindricalscreening member (5) is arranged for dividing the pulp into accept and rej ect, an inlet (2) forthe pulp, an outlet (3) for the accept and an outlet (4) for the rej ect, a rotor (8) comprising a rotor body (10) and at least one pulsation member (17) located on the inside of the screening member (5), so that a screening Chamber (9) is forrned between the rotor (8) andthe screening member (5), characterized in that the detachable pulsation member package(11) is arranged to be attached to the rotor body (10); and in that the detachable pulsationmember package (11) comprises at least one attachment ring (12) attached to the rotorbody (10), at least one support ring (15, 16) attached to or supported by the rotor body(10) and the at least one pulsation member (17) attached to the at least one attachment ring (12) and the at least one support ring (15, 16). [14] 14. A pulsation member package according to clairn 13, characterized in that an attachment ring (12) is arranged to be attached to an end surface (13) of the rotor body (10). [15] 15. A method for manufacture of a rotor (8) for a screening apparatus, characterized by the following steps - manufacturing at least one attachment ring (12), at least one support ring (15, 16) andat least one pulsation member (17); - positioning a rotor body (10); - aligning the least one attachment ring (12) and the at least one support ring (15, 16)along the rotor body (10); - attaching the at least one pulsation member (17) to the at least one attachment ring(12) and the at least one support ring (15, 16) to the rotor body (10); and - attaching the at least one attachment ring (12) to the rotor body (10) and attach orsupport the at least one support ring (15, 16) to the rotor body (10). [16] 16. A method for manufacture of a rotor (8) for a screening apparatus according to clairn15, characterized by the following steps- attaching the at least one pulsation member (17) to the at least one attachment ring(12) and the at least one support ring (15, 16) on an end surface (13) of the rotorbody (10). [17] 17. A method for manufacture of a pulsation member package (11) for a screening apparatus, characterized by the following steps 11 manufacturing at least one attachment ring (12), at least one support ring (15, 16) andat least one pulsation member (17), so that the attachment ring (12) is arranged to beattached to a rotor body (10); positioning a fixture; aligning the least one attachment ring (12) and the at least one support ring (15, 16)along the fixture; and attaching the at least one pulsation member (17) to the at least one attachment ring (12) and the at least one support ring (15, 16) to the fixture.
类似技术:
公开号 | 公开日 | 专利标题 DE102006044781A1|2007-06-28|Centrifugal compressor SE1251345A1|2014-05-29|Screening device, rotor, wing package and production method FI122071B|2011-08-15|Processor handling fiber pulp US4571298A|1986-02-18|Sorting screen AU2014359034A1|2016-06-23|Agitator impeller arrangement AU2015341668B2|2018-11-08|Hydrofoil impeller US7597201B2|2009-10-06|Device for cleaning fibrous suspensions for paper production FI121672B|2011-02-28|A method for manufacturing a rotor of a screening apparatus and a rotor FI96044B|1996-01-15|Apparatus for screening fibrous cellulosic material US1656756A|1928-01-17|Ore-grinding machine US1696354A|1928-12-25|Pulp-screening machine CN109091931B|2021-09-10|Filter screen capable of automatically adjusting position US20050045529A1|2005-03-03|Vortex inducing rotor for screening apparatus for papermaking pulp US6942104B2|2005-09-13|Rotor with multiple foils for screening apparatus for papermaking pulp US7735655B2|2010-06-15|Screen and method for screening pulp US9855585B2|2018-01-02|Pressure screen EP0713078A1|1996-05-22|Measuring insert for flow rate sensors KR20150112243A|2015-10-07|Double suction type centrifugal pump BR102019022377A2|2020-05-26|TOOTH PLATES SUPPORTED IN A DISPERSER FI120630B|2009-12-31|A method for installing or replacing a refiner sharpener JP5934515B2|2016-06-15|Drainage pump DE102004003051A1|2005-08-18|Measuring chamber for the measuring insert of a water meter CN211217477U|2020-08-11|Anti-blocking vibrating screen convenient to clean CN211312003U|2020-08-21|Papermaking sand remover CN109091935A|2018-12-28|A kind of strainer self-checking device
同族专利:
公开号 | 公开日 EP2925927A4|2016-07-06| US9410286B2|2016-08-09| BR112015010292A2|2017-07-11| EP2925927A1|2015-10-07| BR112015010292B1|2021-07-06| CN104769181B|2016-08-24| CA2883349A1|2014-06-05| US20150345077A1|2015-12-03| WO2014084788A1|2014-06-05| CN104769181A|2015-07-08| SE537379C2|2015-04-14|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题 US2752828A|1951-09-11|1956-07-03|Waterous Ltd|Screen for paper stock| US2975899A|1957-04-16|1961-03-21|Bird Machine Co|Screening device| US3034650A|1959-07-02|1962-05-15|Henry F Szepan|Method and apparatus for screening pulp| US3387708A|1966-01-24|1968-06-11|Beloit Corp|Paper machine screen| FR2002382A1|1968-02-22|1969-10-17|Voith| CA1007576A|1973-07-18|1977-03-29|Andrew C. Martin|Vertical pressure pulp screening device| US4328096A|1980-03-17|1982-05-04|The Black Clawson Company|Dual flow screening apparatus| US4374728A|1981-07-29|1983-02-22|Gauld W Thomas|Apparatus for screening fibrous stock| US4832832A|1984-12-25|1989-05-23|Mitsubishi Jukogyo Kabushiki Kaisha|Pressure type slit screen| US4744894A|1986-06-30|1988-05-17|Gauld W Thomas|Fibrous stock screening apparatus| SE464473B|1988-11-17|1991-04-29|Sunds Defibrator Ind Ab|A screening device| SE507905C2|1995-10-11|1998-07-27|Sunds Defibrator Ind Ab|Device for sieving pulp suspensions| SE511148C2|1997-12-19|1999-08-09|Sunds Defibrator Ind Ab|Screening device for fiber suspension| SE511142C2|1997-12-19|1999-08-09|Sunds Defibrator Ind Ab|Device with diluent supply for screening of fiber suspensions| SE511786C2|1998-03-06|1999-11-22|Sunds Defibrator Ind Ab|Screening device with two screening chambers for separating fiber suspensions| JP3396456B2|2000-02-04|2003-04-14|三菱重工業株式会社|Stock selection equipment| SE515896C2|2000-02-08|2001-10-22|Valmet Fibertech Ab|Screening device for fiber suspensions and a rotor for use in a screening device| SE526033C3|2003-11-06|2009-12-08|Metso Paper Inc|Screening device and strainer for screening of pulp suspensions| SE0303260D0|2003-12-04|2003-12-04|Metso Paper Inc|Screening apparatus for screening pulp suspensions with monitoring means|FI20186035A1|2018-12-03|2020-06-04|Valmet Technologies Oy|A screening device and a rotor|
法律状态:
优先权:
[返回顶部]
申请号 | 申请日 | 专利标题 SE1251345A|SE537379C2|2012-11-28|2012-11-28|Screening device, rotor, pulse element package and production method|SE1251345A| SE537379C2|2012-11-28|2012-11-28|Screening device, rotor, pulse element package and production method| EP13859140.9A| EP2925927A4|2012-11-28|2013-11-27|Screening apparatus, rotor, wing package and method for manufacture| US14/647,654| US9410286B2|2012-11-28|2013-11-27|Screening apparatus, rotor, wing package and method for manufacture| BR112015010292-1A| BR112015010292B1|2012-11-28|2013-11-27|sorting apparatus for sorting pulp suspensions, rotor for a sorting apparatus, pulsating element assembly for a sorting apparatus, and, methods for manufacturing a rotor and a pulsating element assembly for a sorting apparatus| CA2883349A| CA2883349A1|2012-11-28|2013-11-27|Screening apparatus, rotor, wing package and method for manufacture| CN201380058519.9A| CN104769181B|2012-11-28|2013-11-27|The encapsulation of screening installation, rotor, aerofoil profile and manufacture method| PCT/SE2013/051402| WO2014084788A1|2012-11-28|2013-11-27|Screening apparatus, rotor, wing package and method for manufacture| 相关专利
Sulfonates, polymers, resist compositions and patterning process
Washing machine
Washing machine
Device for fixture finishing and tension adjusting of membrane
Structure for Equipping Band in a Plane Cathode Ray Tube
Process for preparation of 7 alpha-carboxyl 9, 11-epoxy steroids and intermediates useful therein an
国家/地区
|