• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
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  • 优先权
    • 专利摘要:
    The present invention a) at least one pesticide active ingredient, b) 2-ethyl-hexanol alkoxylate of formula (I) c) optionally additives Novel pesticide formulations, methods of making these formulations and their use for applying the agrochemically active compounds which these formulations comprise: Where P is Indicates, E represents -CH 2 -CH 2- , Numbers 8 and 6 are averages.
    公开号:KR20010104306A
    申请号:KR1020017006728
    申请日:1999-12-06
    公开日:2001-11-24
    发明作者:뢰흘링안드레아스；수티안네；라이즈라인카를；레크만우도
    申请人:빌프리더 하이더；바이엘 악티엔게젤샤프트；
    IPC主号:
    专利说明:

    Agrochemical formulations
    [2] Many crop treatment formulations have already been disclosed, including fatty alcohol ethoxylates as wetting and / or penetrating agents (see EP-A 0 579 052). The activity of these agents is good. However, in some cases, there is a disadvantage that many bubbles are formed when these preparations are stirred with water.
    [3] In addition, agrochemical formulations comprising fatty alcohol propoxylates as formulation auxiliaries have already been disclosed (see US-A 3 673 087). However, the properties of these formulations are also not always satisfactory, because propoxylates with relatively long alkyl moieties are less soluble in water and tend to form precipitates.
    [4] In addition, it is also known that fatty alcohol epoxylates and propoxylates, and mixtures thereof, can be used as low-bubble wetting agents to formulate active compounds in crop protection (see EP-A 0 681 865). ). In practice, however, the properties of such formulations are in some cases unsatisfactory.
    [5] Therefore, the present invention
    [6] a) at least one pesticide active compound,
    [7] b) 2-ethyl-hexanol alkoxylate of formula (I)
    [8] c) optionally additives
    [9] It provides a novel pesticide formulation comprising:
    [10]
    [11] Where
    [12] P is Indicates,
    [13] E represents -CH 2 -CH 2- ,
    [14] Numbers 8 and 6 are averages.
    [15] In addition, the pesticide preparation according to the present invention
    [16] At least one pesticide active compound
    [17] 2-ethyl-hexanol alkoxylate of formula (I) above, and
    [18] It has been found that it can be prepared by mixing with additives optionally.
    [19] Finally, it has been found that the pesticide preparations according to the invention are very suitable for applying the active compounds contained in these preparations to plants and / or their habitats.
    [20] It is surprising that the formulations according to the invention are significantly superior to the preceding formulations with the most similar compositions for the properties of these formulations. In addition, based on the disclosure of EP-A 0 681 865, it can be inferred that a mixture of different alkoxylates is required for the resulting composition to meet all practical requirements. Contrary to expectations, however, it is not. In particular, in the presence of 2-ethyl-hexanol alkoxylate of formula (I), it is sufficient to produce a formulation with the desired properties.
    [21] The formulations according to the invention have many advantages. Thus, bubbles are hardly generated when the preparations according to the invention are mixed with water. In addition, these agents have a beneficial effect on the biological activity of the active ingredient they contain. In addition, weakly water-soluble active compounds in the preparations according to the invention show a tendency to reduce crystallization when diluted with water.
    [22] The preparations according to the invention comprise one or more agrochemically active compounds. Herein, agrochemically active compounds are to be understood as meaning all substances customary for plant treatment. Fungicides, fungicides, insecticides, acaricides, nematicides, herbicides, plant growth regulators, plant nutrients and insect repellents may be mentioned as preferred.
    [23] Examples of fungicides that may be mentioned are:
    [24] 2-aminobutane; 2-anilino-4-methyl-6-cyclopropyl-pyrimidine; 2 ', 6'-dibromo-2-methyl-4'-trifluoromethoxy-4'-trifluoromethyl-1,3-thiazole-5-carboxanilide; 2,6-dichloro-N- (4-trifluoromethylbenzyl) -benzamide; (E) -2-methoximino-N-methyl-2- (2-phenoxyphenyl) acetamide; 8-hydroxyquinoline sulfate; Methyl (E) -2- {2- [6- (2-cyanophenoxy) -pyrimidin-4-yloxy] -phenyl} -3-methoxyacrylate; Methyl (E) -methoximino [alpha- (o-tolyloxy) -o-tolyl] -acetate; 2-phenylphenol (OPP),
    [25] Aldimorph, Ampropyl Force, Anilazine, Azaconazole,
    [26] Benalacyl, benodanil, benomil, vinapacryl, biphenyl, biteranol, blasticidin-S, bromuconazole, burimate, butiobate,
    [27] Calcium Polysulfide, Captapol, Captan, Carbendazim, Carboxin, Quinomethionate, Chloronev, Chloropicrin, Chlorotalonyl, Clozolinate, Cupraneb, Cymoxanyl, Cyproconazole, Cyprofuram ,
    [28] Dichlorophene, diclobutrazole, diclofloanide, diclomezin, dichloran, dietofencarb, difenokazole, dimethymolol, dimethomorph, diconazole, dinocap, diphenylamine, Depyrithione, ditalimfoss, dithianon, dodine, drazoxolone,
    [29] Edifene Force, Epoxyconazole, Ethirimol, Etridiazole,
    [30] Phenarimol, fenbuconazole, fenfuram, phenytropane, fenpiclonil, fenpropidine, fenpropormoff, fentin acetate, fentin hydroxide, ferbam, perimzone, fluazinam, fludioxo Neil, Fluoride, Fluquinconazole, Flusilazole, Flusulfamid, Plutolanil, Flutriafol, Polpet, Pocetyl-aluminum, Phthalide, Fuberidazole, Furlaxyl, Purmecyclox,
    [31] Guazatin,
    [32] Hexachlorobenzene, hexaconazole, hymexazole,
    [33] Imazalil, imibenconazole, iminooctadine, ifprobenfos (IBP), ifprodione, isoprothiolane,
    [34] Kasugamycin, mancozeb, maneb, mepanipyrim, mepronil, metalaccil, metconazole, metasulfocarb, metfuroxam, metiram, metsulfobox, michaelrobutanyl,
    [35] Nickel dimethyldithiocarbamate, nitrotal-isopropyl, noarimol,
    [36] Opuras, Oxadixyl, Oxamocarb, Oxycarboxine,
    [37] Pepurazoate, fenconazole, fensaicuron, phosphodifen, fimaricin, piperaline, polyoxin, provenazole, prochloraz, prosaimidone, propamocarb, propiconazole, propineb, Pyrazophos, pyriphenox, pyrimethanyl, pyroquilon,
    [38] Quintozen (PCNB), quinoxyfen,
    [39] Tebuconazole, Teclophthalam, Tecnazene, Tetraconazole, Tiabendazole, Tiothiophene, Thiophanate-methyl, Thiram, Tollclofos-methyl, Tolylufluoride, Triadimefon, Triadimenol, Triazoside, triclamide, tricyclazole, tridemorph, triflumizol, tripolin, triticonazole,
    [40] Validamycin A, vinclozoline,
    [41] Geneva,
    [42] 8-tert-butyl-2- (N-ethyl-N-n-propyl-amino) -methyl-1,4-dioxa-spiro- [4,5] decane,
    [43] N- (R)-[1- (4-Chlorophenyl) -ethyl] -2,2-dichloro-1-ethyl-3t-methyl-1r-cyclopropanecarboxamide (diastereomer mixture or individual isomers),
    [44] 1-methylethyl [2-methyl-1-[[[1- (4-methylphenyl) -ethyl] -amino] -carbonyl] -propyl] -carbamate,
    [45] N- (2,3-dichloro-4-hydroxy) -1-methyl-cyclohexyl-1-carboxanilide,
    [46] 2- [2- (1-chloro-cyclopropyl) -3- (2-chlorophenyl) -2-hydroxypropyl] -2,4-dihydro- [1,2,4] -triazole-3- Tion,
    [47] 1- (3,5-dimethyl-isoxazole-4-sulfonyl) -2-chloro-6,6-difluoro- [1,3] -dioxolo- [4,5-f] -benzimidazole And
    [48] (5,6-Dihydro-1,4,2-dioxazin-3-yl)-{2-[[6- (2-chloro-phenoxy) -5-fluoro-4-pyrimidinyl]- Oxy] phenyl} -methanone-O-methyloxime.
    [49] Examples of fungicides which may be mentioned are:
    [50] Bronopol, dichlorophene, nitrapyrin, nickel dimethyldithiocarbamate, kasugamycin, octylinone, furancarboxylic acid, oxytetracycline, probenazole, streptomycin, teclophthalam, copper sulfate and other copper agents.
    [51] Examples of pesticides, acaricides and nematicides that may be mentioned are:
    [52] Abamectin, acephate, acrinatrin, alanicab, aldicarb, alphamethrin, amitraz, avermectin, AZ 60541, azadirachtin, azinfos A, azinfos M, azocyclotin,
    [53] Bacillus thuringiensis, 4-bromo-2- (4-chlorophenyl) -1- (ethoxymethyl) -5- (trifluoromethyl) -1H-pyrrole-3-carbonitrile, bendiocarb, ben Furacarb, bensultap, betacyfluthrin, bifenthrin, BPMC, brofenprox, bromophos A, bufencarb, buprofezin, butacarcincin, butylpyridaben,
    [54] Kadusafos, carbaryl, carbofuran, carbophenothione, carbosulphan, cartope, cloetocarb, chloroethoxyforce, chlorophenbinfos, chlorofluazuron, chloromephos, N-[(6-chloro-3 -Pyridinyl) -methyl] -N'-cyano-N-methyl-ethaneimideamide, chloropyrifoss, chloropyrifos M, cis- resmethrin, clocitrin, clofentezin, cyanophosph, Cycloprotrin, cyflutrin, cyhalothrin, cyhexatin, cypermethrin, cyromargin,
    [55] Deltamethrin, Demethone-M, Demethone-S, Demethone-S-methyl, Diapentiouron, Diazinon, Diclopention, Dichlorbos, Diclifoss, Dicrotophos, Diethion, Difluben Juron, Dimethoate, Dimethylbinfos, Dioxation, Disulfotone,
    [56] Edifene force, emamectin, esfen valerate, thiophencarb, ethion, etofenprox, etoprofos, erythropose,
    [57] Fenamifos, phenazaquine, fenbutatin oxide, phenythrothione, phenobcarb, phenothiocarb, phenoxycarb, phenpropatrine, fenpyrad, fenpyroximate, pention, fenvalrate, fipro Neil, Fluazinam, Fluazuron, Flucycloxonon, Flucytinate, Flufenoxuron, Flufenprox, Fluvalinate, Phonophos, Formomones, Phosthiazate, Pufenfenx, Fura Thiocarb,
    [58] HCH, heptenophos, hexaflumuron, hexthiaxans,
    [59] Imidacloprid, ifprobenfoss, isazofoss, isofenfoss, isoprocarb, isoxation, ivermectin,
    [60] Lambda-cyhalothrin, lufenuron,
    [61] Malathion, Mecarbam, Mevinforce, Mesulfenphos, Metaldehyde, Metacryphos, Metamidose, Metidathione, Methiocarb, Methomil, Mettolcarb, Milvemectin, Monoclotophosphate, Moxidecine,
    [62] Nalred, NC 184, nitenpiram,
    [63] Ometoate, oxamyl, oxydemethone M, oxydepropos,
    [64] Parathion A, Parathion M, Permethrin, Pentoate, Forate, Posalon, Phosmet, Phosphomidone, Bombardment, Pyrimicarb, Pyrimiphos M, Pyrimiphos A, Propenophos, Promecab, Propa Phos, propoxur, prothiophos, protoate, pymetrozine, pyraclophos, pyridapention, pyresmethrin, pyrethrum, pyridaben, pyrimidipene, pyriproxyfen,
    [65] Quinal Force,
    [66] Salitione, cebufoss, silafluorene, sulfotep, sulfpropos,
    [67] Tebufenozide, Tebufenpyrad, Tebupyrimifos, Teflubenzuron, Tefluthrin, Temefoss, Terbam, Terbufoss, Tetrachlorbinfos, Thiaphenox, Thiodicarb, Thiophanox, Thiomethone, thionazin, thuringiencin, tralomethrin, transfluthrin, triarathene, triazofoss, triazuron, trichlorphone, triflumuron, trimetacarb,
    [68] Bamidotion, XMC, xylylcarb, zetamethrin.
    [69] Examples of herbicides that may be mentioned are:
    [70] Anilides such as, for example, diflufenican and propanyl; Acrylic carboxylic acids such as, for example, dichloropicolinic acid, dicamba and picloram; Aryloxyalkanoic acids such as, for example, 2,4-D, 2,4-DB, 2,4-DP, fluoxy oxypyr, MCPA, MCPP and triclopyr; Aryloxyphenoxy-alkanoic acid esters such as, for example, diclofo-methyl, phenoxaprop-ethyl, fluazifop-butyl, haloxop-methyl and quinazopof-ethyl; Azinones such as for example chloridazone and norflurazone; Carbamates such as, for example, chlorprofam, desmedipham, phenmedipham and profam; Chloroacetanilides such as for example alachlor, acetochlor, butachlor, metazachlor, metolachlor, pretilachlor and propachlor; Dinitroaniline such as, for example, oryzaline, pendimethalin, and trituralin; Diphenyl ethers such as acifluorfen, biphenox, fluoroglycopene, pomesafen, halosafen, lactofen and oxyfluorfen; Ureas such as, for example, chlortoluron, diuron, fluormethuron, isoproturon, linuron and metabenzthiazuron; Hydroxylamines such as, for example, alkoxydim, cletodim, cycloxydim, cetoxydim and trakoxydim; Imidazolinones such as for example imazetapyr, amizamethabenz, imazapyr and imazaquin; Nitriles such as, for example, bromoxynil, diclobenyl and oxynyl; Oxyacetamides such as mefenacet; Sulfonylureas such as amidosulfuron, bensulfuron-methyl, chlorimuron-ethyl, chlorsulfuron, cynosulfuron, metsulfuron-methyl, nicosulfuron, prisulfuron, pyrazosulfuron-ethyl , Thifensuluron-methyl, triasulfuron and tribenuron-methyl; Thiocarbamates such as, for example, butyrate, cycloate, dialate, EPTC, esprocarb, molinate, prosulfocarb, thiobencarb and trialate; Triazines such as atrazine, cyanazine, simazine, cymetrine, terbutryn and terbutylazine; Triazinones such as, for example, hexazinone, metamitrone and metribuzin; Other examples include, for example, aminotriazole, 4-amino-N- (1,1-dimethylethyl) -4,5-dihydro-3- (1-methylethyl) -5-oxo-1H-1, 2,4-triazole-1-carboxamide, benfuresate, bentazone, synmethylin, clomazone, clopyralide, dipfencuart, dithiopyr, etofumesate, fluorochloridone, glue Forcinate, glyphosate, isoxaben, pyridate, quinclolac, quinmerak, sulfosate and tridiphane.
    [71] Plant growth regulators that may be mentioned include chlorocholine chloride and etepon.
    [72] Examples of plant nutrients that may be mentioned are conventional inorganic or organic fertilizers for providing macro- and / or micronutrients to plants.
    [73] Examples of insect repellents which may be mentioned are diethyltolylamide, ethylhexanediol and butopyronixyl.
    [74] Particularly preferred examples of fungicides which may be mentioned are active compounds of the structure
    [75]
    [76]
    [77]
    [78] The preparations according to the invention comprise 2-ethyl-hexanol alkoxylates of formula (I) above. In this equation, the numbers 8 and 6 are averages. Thus, the 2-ethyl-hexanol alkoxylate of formula (I) is preferably a mixture of materials having 8 propylene oxide and 6 ethylene oxide units.
    [79] The 2-ethyl-hexanol alkoxylate of formula (I) is already known (see EP-A 0 681 865).
    [80] Suitable additives which may be present in the preparations according to the invention are all conventional preparation auxiliaries such as, for example, organic solvents, emulsifiers, dispersants, preservatives, colorants, fillers and water.
    [81] Suitable organic solvents are all conventional organic solvents in which the pesticide active compound to be used is well dissolved. Preferably, aliphatic and aromatic, optionally halogenated hydrocarbons, such as toluene, xylene, sorbetho Solvesso); Mineral oils such as refined petroleum, petroleum, alkylbenzenes and axial lubricants; Carbon tetrachloride, chloroform, methylene chloride and dichloromethane; Esters such as ethyl acetate; Lactones such as butyrolactone; Lactams such as N-methylpyrrolidone, N-octyl-pyrrolidone and N-methylcaprolactam; Alkancarboxamides such as N, N-dimethyl-decancarboxamide and N, N-dimethyl-octanecarboxamide; And dimethylformamide.
    [82] Suitable emulsifiers are conventional surfactants present in agrochemically active compound formulations. Examples that may be mentioned are ethoxylated nonylphenols, polyethylene glycol ethers of linear alcohols, reaction products of ethylene oxide and / or propylene oxide with alkylphenols, fatty esters, alkylsulfonates, alkyl sulfates, aryl sulfates, ethoxylated arylalkylphenols Such as, for example, tristyryl-phenol ethoxylates having an average of 16 ethylene oxide units per mole, also ethoxylated and propoxylated arylalkylphenols, and sulfated or phosphorylated arylalkylphenol ethoxylates or ethoxy- and Propoxylates.
    [83] Suitable dispersants are all materials conventionally used for this purpose in crop protection compositions. Preferably natural and synthetic water soluble polymers such as gelatin, starch and cellulose derivatives, in particular cellulose esters and cellulose ethers, as well as polyvinyl alcohol, polyvinylpyrrolidone, polyacrylic acid, polymethacrylic acid, and (meth) acrylic acid and ( Copolymers of methacrylic acid esters and methacrylic acid and methacrylic acid esters which are neutralized with alkali metal hydroxides.
    [84] Suitable preservatives are all materials conventionally present for this purpose in crop processing compositions. Examples that may be mentioned are preventols (Preventol ) And proxel (Proxel There is).
    [85] Suitable colorants are all inorganic or organic colorants commonly used in the preparation of crop protection compositions. Examples that may be mentioned are zinc dioxide, color black, zinc oxide and blue pigments.
    [86] Suitable fillers are all materials conventionally used for this purpose in crop protection compositions. Preferably, inorganic particles, such as carbonates, silicates and oxides, have an average particle size of from 0.005 to 5 μm, particularly preferably from 0.02 to 2 μm. Examples that may be mentioned are silicon dioxide, so-called fine silicic acid, silica gel, and natural and synthetic silicates and aluminosilicates.
    [87] In the preparations according to the invention the content of the individual components can be varied within a relatively wide range. therefore,
    [88] The concentration of the pesticide active compound is generally from 1 to 90% by weight, preferably from 5 to 30% by weight,
    [89] The concentration of 2-ethyl-hexanol alkoxylate of formula (I) is 1 to 90% by weight, preferably 10 to 50% by weight,
    [90] The concentration of the additive is generally from 0 to 98% by weight, preferably from 20 to 85% by weight.
    [91] Agrochemical formulations according to the invention are prepared by mixing the components in the desired specific proportions. If the pesticide active compound is a solid, it is generally used in finely ground form or in the form of a solution or suspension in an organic solvent. If the pesticide active compound is a liquid, it is often not necessary to use an organic solvent. Solid pesticide active compounds may also be used in the form of lysates.
    [92] The temperature for carrying out the method according to the invention can be varied within a certain range. In general, the process is carried out at temperatures between 0 ° C and 80 ° C, preferably between 10 ° C and 60 ° C.
    [93] The process according to the invention is generally carried out by mixing the 2-ethyl-hexanol alkoxylate of formula (I) with at least one agrochemically active compound, if necessary, with vigorous stirring with additives. The components can be mixed with each other in any order. However, in another preferred method according to the invention, the 2-ethyl-hexanol alkoxylate of formula (I) is mixed with one or more pesticide active compounds and other additives, and the resulting premix is dispersed in water to give an emulsion, Obtain a suspension or solution.
    [94] For carrying out the process according to the invention it is possible to use conventional devices suitably used to prepare the pesticide preparation.
    [95] The pesticide preparations according to the invention can be applied in the form of conventional liquid preparations, per se or diluted with water, ie emulsions, suspensions or solutions. Application is carried out by conventional methods, eg by spraying, watering or infusion.
    [96] The application rate of the pesticide preparation according to the invention can be varied within a relatively wide range. Each pesticide active compound in the formulation and its content are dependent.
    [97] The formulations according to the invention can be used to apply agrochemically active compounds to plants and / or their habitats in a particularly advantageous manner. It is possible to substantially prevent the formation of unwanted bubbles during dilution of the concentrate with water and during spraying. In addition, the tendency of crystallization of the solid active compound is reduced, thereby increasing the biological activity of the active ingredients compared to conventional formulations.
    [98] The invention is illustrated by the following examples.
    [99] Preparation Example
    [100] Example 1
    [101] In order to prepare a preparation according to the invention, 10 g of the active compound of the following structural formula was first mixed with 40 g of butyrolactone and then 50 g of 2-ethyl-hexanol alkoxylate of formula (I) with stirring at room temperature. . After the addition was complete, the mixture was stirred for an additional 30 minutes at room temperature. A homogeneous solution was obtained.
    [102]
    [103] Example 2
    [104] In order to prepare the preparations according to the invention, 10 g of the active compound of the following structure is first mixed with 35 g of butyrolactone and then stirred at room temperature with 35 g of 2-ethyl-hexanol alkoxylate of the formula (I) and the average per mole 20 g of tristyryl-phenol ethoxylate with 16 ethylene oxide units was mixed. After the addition was complete, the mixture was stirred for an additional 30 minutes at room temperature. A homogeneous solution was obtained.
    [105]
    [106] Comparative Example I
    [107] To prepare a conventional formulation, 10 g of the active compound of the following structural formula was first mixed with 70 g of butyrolactone and then with 20 g of tristyryl-phenol ethoxylate having an average of 16 ethylene oxide units per mole with stirring at room temperature. . After the addition was complete, the mixture was stirred for an additional 30 minutes at room temperature. A homogeneous solution was obtained.
    [108]
    [109] Example of use
    [110] Example A
    [111] Eritife ( Erysiphe) Test (barley) / protective activity
    [112] Each concentrate was diluted with water to the desired concentration to prepare ready-to-use formulations of the active compounds.
    [113] To test for protective activity, young plants were sprayed with the preparation of the active compound at the designated application rate.
    [114] One day after spraying, the plants were sprayed with spores of Erysiphe graminis f.sp.hordei .
    [115] The plants were introduced into a greenhouse at a temperature of about 18 ° C. and a relative humidity of about 80% to promote the development of mildew pustules.
    [116] Evaluation was made 7 days after inoculation. 0% means effectiveness corresponding to the control and 100% means no infection was observed.
    [117] The formulations, the application rates of the active compounds and the test results are shown in the table below.
    [118] TABLE A-1
    [119] Eritife ( Erysiphe) Test (barley) / protective activity
    [120] Formulations According to Examples Application rate of active compound (g / ha) Effectiveness (%)Known compound: (I) 62.5 76Compounds According to the Invention: (1) 62.5 90
    [121] Table A-2
    [122] Eritife ( Erysiphe) Test (barley) / protective activity
    [123] Formulations According to Examples Application rate of active compound (g / ha) Effectiveness (%)Known compound: (I) 62.5 72Compounds According to the Invention: (2) 62.5 89
    [124] Example B
    [125] Eritife ( Erysiphe) Test (wheat) / therapeutic activity
    [126] Each concentrate was diluted with water to the desired concentration to prepare ready-to-use formulations of the active compounds.
    [127] To test the therapeutic activity, plants were sprayed with spores of Erysiphe graminis f.sp.tritici . 48 hours after inoculation, young plants were sprayed with the preparation of the active compound at the designated application rate.
    [128] Plants were introduced into a greenhouse at a temperature of about 18 ° C. and a relative humidity of about 80% to promote the development of powdery foam.
    [129] Evaluation was made 7 days after inoculation. 0% means effectiveness corresponding to the control and 100% means no infection was observed.
    [130] The formulations, the application rates of the active compounds and the test results are shown in the table below.
    [131] TABLE B-1
    [132] Eritife ( Erysiphe) Test (wheat) / therapeutic activity
    [133] Formulations According to Examples Application rate of active compound (g / ha) Effectiveness (%)Known compound: (I) 62.5 38Compounds According to the Invention: (1) 62.5 86
    [134] Table B-2
    [135] Eritife ( Erysiphe) Test (wheat) / therapeutic activity
    [136] Formulations According to Examples Application rate of active compound (g / ha) Effectiveness (%)Known compound: (I) 62.5 60Compounds According to the Invention: (2) 62.5 77
    [137] Example C
    [138] Leptosperia nodorum Leptosphaeria nodorumA) Test (wheat) / therapeutic activity
    [139] Each concentrate was diluted with water to the desired concentration to prepare ready-to-use formulations of the active compounds.
    [140] To test the therapeutic activity, young plants were sprayed with a conidia suspension of Leptosphaeria nodorum . The plants were kept for 48 hours in a culture room at a temperature of 20 ° C. and a relative humidity of 100%, followed by spraying the preparation of the active compound at the designated application rate.
    [141] The plants were introduced into a greenhouse at a temperature of about 22 ° C. and a relative humidity of about 80%.
    [142] Evaluation was made 10 days after inoculation. 0% means effectiveness corresponding to the control and 100% means no infection was observed.
    [143] The formulations, the application rates of the active compounds and the test results are shown in the table below.
    [144] Table C
    [145] Leptosperia nodorum Leptosphaeria nodorumA) Test (wheat) / therapeutic activity
    [146] Formulations According to Examples Application rate of active compound (g / ha) Effectiveness (%)Known compound: (I) 62.5 87Compounds According to the Invention: (1) 62.5 100
    [147] Example D
    [148] Pyrenopora Teres ( Pyrenophora teresA) test (barley) / therapeutic activity
    [149] Each concentrate was diluted with water to the desired concentration to prepare ready-to-use formulations of the active compounds.
    [150] To test the therapeutic activity, young plants were sprayed with a conidia suspension of Pyrenophora teres . The plants were maintained for 48 hours in a culture room at a temperature of 20 ° C. and a relative humidity of 100%. Formulations of the active compounds are sprayed onto the plants at the specified application rates.
    [151] The plants were introduced into a greenhouse at a temperature of about 20 ° C. and a relative humidity of about 80%.
    [152] Evaluation was made 7 days after inoculation. 0% means effectiveness corresponding to the control and 100% means no infection was observed.
    [153] The formulations, the application rates of the active compounds and the test results are shown in the table below.
    [154] Table D
    [155] Pyrenopora Teres ( Pyrenophora teresA) test (barley) / therapeutic activity
    [156] Formulations According to Examples Application rate of active compound (g / ha) Effectiveness (%)Known compound: (I) 62.5 54Compounds According to the Invention: (1) 62.5 73
    [1] The present invention relates to novel agrochemical formulations of particular 2-ethyl-hexanol alkoxylate bases, methods of making these formulations and their use for applying the agrochemically active compounds which these formulations comprise.
    权利要求:
    Claims (6)
    [1" claim-type="Currently amended] a) at least one pesticide active compound,
    b) 2-ethyl-hexanol alkoxylate of formula (I)
    c) optionally additives
    Pesticide Formulations Including:

    Where
    P is Indicates,
    E represents -CH 2 -CH 2- ,
    Numbers 8 and 6 are averages.
    [2" claim-type="Currently amended] The pesticide preparation according to claim 1, which contains as a pesticide active compound a compound of the structure:

    [3" claim-type="Currently amended] The pesticide preparation according to claim 1, which contains as a pesticide active compound a compound of the structure:

    [4" claim-type="Currently amended] The pesticide preparation according to claim 1, which contains as a pesticide active compound a compound of the structure:

    [5" claim-type="Currently amended] At least one pesticide active compound
    2-ethyl-hexanol alkoxylate of formula (I) as defined in claim 1, and
    A process for preparing the agrochemical formulation according to claim 1, characterized in that it is optionally mixed with additives.
    [6" claim-type="Currently amended] Use of the pesticide preparation according to claim 1 for applying the pesticide active compound contained in the pesticide preparation to plants and / or their habitats.
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    同族专利:
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    HU228829B1|2013-05-28|
    BR9916192B1|2011-05-31|
    IL143209D0|2002-04-21|
    AU1559300A|2000-07-03|
    HU0104573A3|2004-10-28|
    CA2355264A1|2000-06-22|
    ZA200103949B|2002-05-15|
    PL199424B1|2008-09-30|
    AU753844B2|2002-10-31|
    IL143209A|2004-09-27|
    CN1330512A|2002-01-09|
    TR200101715T2|2002-04-22|
    GT199900215A|2001-06-08|
    JP2002532391A|2002-10-02|
    CN1231123C|2005-12-14|
    AR021642A1|2002-07-31|
    EP1139739B1|2002-09-11|
    CA2355264C|2009-02-03|
    PT1139739E|2003-01-31|
    DK1139739T3|2003-01-20|
    WO2000035278A1|2000-06-22|
    PL349788A1|2002-09-09|
    ES2180336T3|2003-02-01|
    CO5210929A1|2002-10-30|
    ID30031A|2001-11-01|
    TWI225773B|2005-01-01|
    BR9916192A|2001-09-04|
    DE19857963A1|2000-06-21|
    US6602823B1|2003-08-05|
    KR100658487B1|2006-12-18|
    EP1139739A1|2001-10-10|
    RU2230455C2|2004-06-20|
    JP4596649B2|2010-12-08|
    AT223646T|2002-09-15|
    HU0104573A2|2002-03-28|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    法律状态:
    1998-12-16|Priority to DE19857963A
    1998-12-16|Priority to DE19857963.2
    1999-12-06|Application filed by 빌프리더 하이더, 바이엘 악티엔게젤샤프트
    2001-11-24|Publication of KR20010104306A
    2006-12-18|Application granted
    2006-12-18|Publication of KR100658487B1
    优先权:
    申请号 | 申请日 | 专利标题
    DE19857963A|DE19857963A1|1998-12-16|1998-12-16|Agrochemical formulations|
    DE19857963.2|1998-12-16|
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