Agrochemical formulations for water-surface application

专利摘要:
A sleeping pesticide composition containing at least one pesticide active ingredient and at least one surfactant selected from particle nuclei having an apparent specific gravity of less than 1, α-olefinsulfonate salts, α-sulfoaliphatic acid salts, and oleoylmethyl taurate salts; A method of producing the composition; A packaged pesticide composition containing the composition; And an application method for paddy fields of the pesticide active ingredient using the packaged pesticide composition.
公开号:KR20000048402A
申请号:KR1019990061879
申请日:1999-12-24
公开日:2000-07-25
发明作者:오꼬우찌다께오；호소다히또시；도미오까마사까즈
申请人:가와무라 요시부미；상꾜 가부시키가이샤；
IPC主号:

专利说明:

Pesticide composition for sleep {AGROCHEMICAL FORMULATIONS FOR WATER-SURFACE APPLICATION}
The present invention is a sleeping pesticide composition containing at least one pesticide active ingredient, a surfactant selected from specific surfactants, and a particle nucleus having an apparent specific gravity of less than 1, a method for preparing the pesticide composition, a packaged pesticide composition, and an pesticide active ingredient It is about how to apply to the rice field.
Until now, pesticides have been prepared in various forms for easy application, including powders, granules, hydrating agents, water soluble powders, concentrated flowables, aqueous solutions, concentrated emulsions and the like. Spraying agents such as a hydrating agent, a water-soluble powder, an emulsion, and the like are mainly used in paddy fields or non-cropland. Unfortunately, they cause worker health problems or environmental pollution by many problems with hydrating and water soluble powders, such as their dusting. They also present problems with concentrated emulsions, such as solvents or emulsifiers present in the concentrate, which can cause environmental pollution, and organic solvents present a risk of fire. In addition, most of the pesticide active ingredients are insoluble in water, and as a result, it is difficult to make a liquid. For this reason, there is an increasing tendency to use aqueous or oily flowables or dry flowables with less of these problems. However, there are other problems with such flowables. They must be made completely before use and require a special spreading device. This is difficult and time consuming.
In addition, powder, granules, and the like have been prepared as the discussion sleeping reagent, and granules have been most widely used. Granulation is generally used in an amount of 3 to 4 kg per 10 ar, but in recent years, the demand for labor force is high in the application of pesticides, and it is necessary to develop a small amount of dispersant which reduces the dosage of the pesticide preparation. One example of such formulations that has recently been developed is the so-called "1-kg granules" with a higher content of active ingredients. However, attempting to reduce the granulation dosage will inevitably increase the content of the pesticide active ingredient in the granules, leading to a decrease in the particle count per unit area. If the active ingredients of such preparations do not diffuse rapidly and uniformly, they can cause crop weakness and are likely to exhibit non-uniform biological activity. As far as possible, it is preferable to treat the pesticide uniformly throughout the paddy field. However, in order for an operator to uniformly spread 1-kg granules into a freshwater paddy field, considerable skill and experience are required, and in some cases, a power expansion device is required. Therefore, this formulation is not entirely satisfactory.
Discussion In the field of sleeping application formulations, many aqueous concentrated flowables have been developed for achieving labor savings and improving efficacy in expansion. Unlike aqueous suspension formulations used in paddy fields, non-crop lands, etc., the formulations do not require dilution of the formulations directly, nor do they require special spraying equipment directly from the container, and the throughput is 200 ml to 1 l per 10 liters. Because it is so small, it can be handled lightly and easily. Shaking this formulation from the paddy field allows processing of the paddy field (so-called paddy field paddle) or treatment of only irrigation in the water polo at the time of acquisition (so-called paddle padding), and the actual choice of the technique depends on the surface area of the discussion. do. This formulation is capable of very labor-saving treatments and is rapidly expanding the market after release. However, since an aqueous flowable agent is a formulation which disperse | distributed or emulsified the pesticide active ingredient in water, it cannot apply to the pesticide active ingredient which is easy to hydrolyze.
Recently, considerably developed formulations (pack formulations and jumbo formulations) suitable for incorporation into agrochemical paddy fields, which are prepared by packaging solid formulations such as tablets, balls, granules and the like into water-soluble sheets such as water-soluble films. This results in labor savings in application and environmental protection. Such formulations have the advantage of being easy to apply pesticides to paddy fields, but do not have a uniform treatment, such as conventional granulation or powder treatment. In addition, when the preparation is thrown in water, the preparation is settled on the soil surface and the pesticide active ingredient is dispersed in paddy water with or without foaming. As a result, particles of the active ingredient are settled around the dropping point, and the dissolved pesticide active ingredient also forms a high concentration of solution near the soil surface of the dropping point, and therefore is easily adsorbed to the soil. Therefore, even when the water solubility of the agent-containing pesticide active ingredient thrown into the paddy field is quite high, the pesticide active ingredient is often adsorbed to the soil near the agent dropping point at a high concentration. As a result, the preparations are likely to cause chemical damage to crops or to produce non-uniform efficacy due to segregation of the pesticide active ingredient (homogeneous spreading). Depending on field conditions, weather conditions, etc., it can often affect crops.
In order to avoid such segregation of agrochemical active ingredients, sleeping formulations containing blowing agents in solids have been developed. This formulation easily disintegrates, disperses the solid agent, and then diffuses the pesticide active ingredient with the foaming power of the blowing agent. Organic acids and carbonates are typically used as the blowing agent, utilizing a reaction in which the former reacts in the presence of the latter with water to form carbon dioxide. However, pesticide preparations containing a blowing agent have a problem that some of the organic acids and carbonates in the preparation react during storage, thereby generating gas well, resulting in swelling of the package or weakening of the foam when the package is used in rice fields. do. In particular, it is necessary to form a uniform treated layer on the soil surface by dispersing the active ingredient in water as quickly as possible and dispersing the active ingredient in water with foaming force even if the water temperature is low. The lowering of the foaming force due to some previous reactions results in insufficient diffusion of the pesticide active ingredient, and these problems are not solved.
In view of this problem, several proposals have recently been made regarding sleep reagents containing no blowing agent. For example, after dissolving the active ingredient of the pesticide in an organic solvent or the like, using the obtained solution and the water-soluble film, the organically packaged into the formulation obtained by dividing the oil substance having electrostatic capacity on the water in a small package, and the water-soluble film Preparations comprising a solvent and an oil substance having expansion ability on the surface (Japanese Patent Laid-Open No. 5-78207); Consisting of an agricultural chemical active ingredient, hollow glass particles having an average particle diameter of 250 µm or less, and a water-soluble polymer, and molded into 10 to 100 g per package (JP-A-5-58804); 10 to 100 g of a solid composition having a pesticide active ingredient, an inorganic suspended solids having an average particle diameter of 250 µm or less, and a high boiling point solvent, having a particle diameter of 600 µm or less, is packaged with a water-soluble polymer film (JP-A-5-78204). number); A particle core having an apparent specific gravity of less than 1 coated with an active substance and a substance for changing air and water surface tension with an oily substance (Japanese Patent Laid-Open No. 5-155703); A floating particulate insecticide composition adsorbed on a pesticide active ingredient to a carrier composed of particulate pumice or vermiculite and coated with a higher fatty acid (Japanese Patent Publication No. 44-8600); Floating granules in which insecticide is fixed with polybutene to calcined pearlite (Japanese Patent Publication No. 47-1240); Granules that float on the water surface a drug that is effective for pneumococcal disease (Japanese Patent Publication No. 48-1179); Preparations in which insecticides and water repellents are supported on foamed pearlite (Japanese Patent Publication No. 48-1181); Granules in which an herbicide emulsion is supported on an inorganic carrier floated in water (Japanese Patent Publication No. 48-1182); Particulate pesticide compositions (Japanese Patent Publication No. 48-15612) carrying a cellulose ether or a polycarboxylic acid type high molecular surfactant as an expanding agent and floating in water; Water-insoluble solid preparations containing an active ingredient of agrochemicals and a solid carrier and polyoxyalkylene silicone (Japanese Patent Publication No. 64-25702); A bioactive component is attached to an inorganic or organic porous body or a hollow body with synthetic resin or gypsum, and a hole is made to be a hollow body by adjusting the specific gravity to 1.0 or less and 5 mm or less in particle diameter. ) And a liquid stock solution containing an active ingredient and an emulsifier are adsorbed onto a thermally expanded gypsum powder (Japanese Patent Laid-Open No. 3-76281). However, these formulations are not particularly different from conventional granules and powders in that they are spraying methods, and considerable labor savings cannot be achieved.
On the other hand, in terms of achieving a reduction in labor in spraying pesticide formulations, sleeping suspension formulations have been discussed. Among them, a formulation in which a composition containing an agricultural chemical active ingredient and calcined vermiculite or foamed pearlite, foamed cyrus, cork, and an acetylene surfactant is packaged in a water-soluble film (Japanese Patent Laid-Open No. 6-336403); Granules or tablets obtained by uniformly dispersing a pesticide active ingredient and a powder base having a specific gravity of 1 or less and a surfactant having a lowering force in interfacial tension (Japanese Patent Laid-Open No. 7-233002); And a pesticide preparation (Japanese Patent Application Laid-open No. Hei 9-183701) having a pesticide active ingredient coated with a surfactant having a high interfacial tension-lowering force and an oily substance on a particle nucleus having a specific gravity of 1 or less. However, formulations according to these methods are not necessarily satisfactory in sleep integrity in practical use. In particular, in terms of practical use, algae, rice flakes, and other suspended matter may cover rice paddy water, and even when the paddy field is treated with the sleeping agent, sufficient floating expansion of the pesticide preparation may not be expected. The reagents cannot be processed. In rice fields where no floats seem to exist at all, there are often floats that are invisible in the rice paddies. In such conditions, it is common for the float to prevent the expansion of sufficient suspended and pesticide preparations.
It is an object of the present invention to provide an agrochemical formulation in which the agrochemical formulation sufficiently floats sleep well even in rice fields in which some float is present.
More specifically, it is an object of the present invention to provide an agrochemical formulation that satisfies the following requirements, and methods for its preparation and application:
① do not require special equipment for application;
② reduce labor;
③ safe for the workers and the environment applied to the field;
④ can be packed in easy to handle containers;
⑤ There is no fear of weakening of the efficacy of the pesticide effect due to segregation of the active ingredient of pesticides and weakening;
(6) has excellent surface floating potential even in the presence of obstacles;
⑦ Stable for a long time.
The present inventors made an in-depth study in terms of developing a pesticide formulation which satisfies the above conditions, and a method of manufacturing and applying the same. As a result of the study, a pesticide composition was found to be well spread and sprayed on rice fields and applied by the following two methods. The first method consists in directly shaking a specific type of pesticide composition prepared using a specific surfactant and a particle nucleus having an apparent specific gravity of less than 1 using a suitable container to which a shaking sprayer is attached to the paddy field. The second method consists of throwing a pesticide composition prepared in the same way into a paddy field and then dividing it into small packages that rot upon exposure to water to disperse it, or are coated with a water soluble film.
Summary of the invention
The present invention includes a sleeping pesticide composition containing at least one pesticide active ingredient, at least one surfactant selected from the following compound groups, and a particle nucleus having an apparent specific gravity of less than one. The composition may also optionally contain a nonvolatile material that is liquid at room temperature. The surfactant group in the composition of the present invention includes α-olefinsulfonate salt, α-sulfoaliphatic acid salt and oleoylmethyl tauride salt. The invention also relates to methods of application and preparation of the composition.
When the sleeping pesticide composition of the present invention is applied to freshwater paddy fields. By dissolving the surfactant, the sleeping pesticide composition is expanded in water in all directions, and the active ingredient of the pesticide is quickly dispersed uniformly in the paddy water and dissolved. In addition, the sleeping pesticide composition of the present invention has significant advantages in practical use. Since the release rate of the pesticide active ingredient to the water is very fast, even if the particle nuclei remaining on the surface are gathered by the wind, the pesticide active ingredient is already released before gathering, and therefore does not affect the expression of the action effect.
Embodiment of the invention
Pesticide active ingredients usable in accordance with the invention include, for example, herbicides, insecticides, fungicides, acaricides, plant growth regulators, and are not particularly limited in their physical properties. Herbicidal active ingredients include, for example, bensulfuronmethyl, azimsulfuron, imazosulfuron, pyrazosulfuronethyl, ethoxysulfuron, cynosulfuron, cyclosulfamuron, chlorsulfuron, chlorimuronethyl, neophensulfuronmethyl, plaza Sulfuron, Sulfomethuronmethyl, Primisulfuronmethyl, Limussulfuron, Dimepiperegart, Mefenacet, Prelylachlor, Molinate, Pyributycarb, Tenylchlor, Esprocarb, Butamifos, Bromobutide, dimuron, carfenstrol, sihalofofbutyl, benzophenaf, pyrazolate, pyrazoxifen, benflesate, benthiocarb, epoprodan, quinoclamine (ACN), Cimetrin, dimethamethrin, pentoxazone, etobenzanide, dithiopyr, butachlor, oxadiargyl, naproanilide, cynmethylline, (2,4-dichlorophenoxy) acetic acid (2,4 -D) and alkyl esters or salts thereof, 4- (4-chloro-O-tolyloxy) butyric acid (MCPB), Oxadiclomepon, 4- (2-chlorophenyl) -N-cyclohexyl-4,5-dihydro-N-ethyl-5-oxo-1H-tetrazol-1-carboxamide (NBA-061), MT-128, 3- (2-chloro-4-methylsulfonylbenzoyl) -4-phenylthio) bicyclo [3.2.1] oct-3-en-2-one (SB-500), 2- [2 -(3-chlorophenyl) -2,3-epoxypropyl] -2-ethylidene-1,3-dione (MK-243), 1- (2-chlorobenzyl) -3- (α, α-dimethylbenzyl Urea (JC-940) and ventazone.
Insecticidal active ingredients have an effect on rice weevil and water snail cucumber insects such as silafluorophene, cycloprothrin, etofenprox, isoxation, ethylthiomethone, imidacloprid, nitenpyram and acetamiprid. Persistent, permeable pesticides are included.
The bactericidal active ingredients include long-acting and permeable bactericides effective for blasting and blight, such as capropamide, pyroquilon, isoprothiolane, probenazole, ifprobenfoss, tricyclazole, fipronil, flutoranil, furamepyr (S-658), Mepronyl, trifluzamide (MON-240), (RS) -2- (4-fluorophenyl) -1- (1H-1,2,4-triazol-1-yl ) -3-trimethylsilylpropan-2-ol (F-155), tecloftalarm and benomyl.
Plant growth regulators include, for example, maleic acid hydrazide and its salts, absic acid, calcium peroxide and psychocells.
The pesticide active ingredient usable in accordance with the present invention may be at least one compound selected from herbicides, insecticides, fungicides, acaricides, plant control agents, or combinations of two or more of the agents regardless of the nature of the active ingredient. .
Although the compounding ratio of the pesticide active ingredient used for this invention is not specifically limited, Usually, it is 1-90 weight%, Preferably it is 10-80 weight%, More preferably, 20-70 weight in the sleeping pesticide granular composition of this invention. Present in an amount of%.
The α-olefinsulfonate salts usable as surfactants used in the present invention are sulfonated compounds usually prepared by sulfonation of crude oil (petroleum), which are nontoxic to humans and not harmful to the environment. It is highly biodegradable, very safe for skin and eyes, and stable for both acids and alkalis. Typical examples include C ₁₂ -C ₁₆ α-olefinsulfonates.
The type of the α-olefinsulfonate salt used in the present invention is not particularly limited, but typical examples thereof include sodium salts, potassium salts, calcium salts, ammonium salts and various kinds of amine salts, and sodium salts, ammonium salts and calcium salts. This is preferable.
The α-olefinsulfonates usable in accordance with the present invention include, for example, Liporan LB-440, Liporan LB-840, Liporan PJ-400, Kliporan PJ-400, Liporan PB-800, Dt- 95 (above Lion Kabuki Shikai Co., Ltd.), M-3801, M-3801G (above, Daiichi Kogyo Seiyaku Kabu Shika Kaisha) and Hostapur OSB (Hex Keyboard Kabuki Kaisha), but are limited to these examples It doesn't happen.
Α-sulfoaliphatic acid salts usable as surfactants in the present invention include compounds obtained by sulfonation of natural fats and oils, for example, methyl C ₁₀ to C ₁₄ α-sulfoaliphatic acid salts.
The kind of the salt of α-sulfoaliphatic acid salt used in the composition of the present invention is not particularly limited, and examples thereof include sodium salt, potassium salt, calcium salt, ammonium salt and various kinds of amine salts, and sodium salt, ammonium salt and calcium salt. This is preferable.
Α-sulfoaliphatic acid salts usable in the present invention include, but are not limited to these examples, such as those sold under the trade names FA-615B, FA-616B, FA-617B (products of Lion Corporation).
The oleoylmethyl tauride salt which can be used as a surfactant in the present invention is not particularly limited, but includes, for example, sodium salt, calcium salt, potassium salt and ammonium salt, and sodium salt and calcium salt are preferred.
The oleoylmethyl tauride salt which can be used in the composition of the present invention includes, for example, the brand name Diapon T powder (manufactured by Nippon Yushi Kabushiki Kaisha), Hostapon T powder (manufactured by Hexton Kabuki Kaisha) And Arkopon T powder (manufactured by Hexton Corporation), but are not limited to these examples.
The surfactant usable in the pesticide composition of the present invention is preferably α-olefinsulfonate salt or α-sulfoaliphatic acid.
The usage-amount of the said specific surfactant which can be used for this invention is 0.01 to 40 weight% normally, Preferably it is 0.1 to 30 weight%, More preferably, it is 1 to 20 weight% in the sleeping application agricultural chemical composition of this invention. It should also be noted that one or more of the surfactants may be used.
In addition to the above surfactants, other agents may be added to the sleeping application pesticide composition, if desired, to aid sleep expansion. Examples of the sleep expanding agent include polysulfonic acid-type polysorbs such as sodium salts, potassium salts and ammonium salts of (co) polymers of carboxylic acids such as acrylic acid and maleic acid, and copolymerized styrenesulfonic acid and vinyl groups thereof; Soaps such as sodium oleate and potassium stearate, anionic surfactants such as sodium dialkylsulfosuccinate, sodium dodecylbenzenesulfonate, sodium lauryl sulfate and perfluoroalkylcarboxylates; Nonionic surfactants such as polyoxyethylene alkylaryl ethers, polyoxyethylene alkyl ethers, polyoxyethylene alkyl esters, alkyl esters of sorbitan, silicone surfactants, acetylene surfactants, and pluronic surfactants; Surfactant which made polyoxyethylene alkyl aryl ether, polyoxyethylene alkyl ether, polyoxyethylene alkyl ester, the alkyl ester of sorbitan, etc. into ester of phosphoric acid or sulfuric acid, and neutralized these with appropriate alkali in some cases; Fluorine-based surfactants containing fluorine; Various cationic surfactants; Zwitterionic surfactants; Liquid paraffin or naphthenic high boiling point solvents; Mineral oils such as low viscosity polybutene, silicone oil and machine oil; Various animal and vegetable oils; Various resins such as pine oil; Camphor white milk; α-pinene; camphor; And naphthalene. Among these, preferred sleep expanding agents include acetylene surfactants, silicone surfactants or fluorine surfactants.
Acetylene-based surfactants include acetylene alcohols, acetylene diols and alkylene oxide adducts of these alcohols and diols.
The acetylene alcohol is a compound represented by the formula HOCR ¹ R ² -C≡CH (wherein R ¹ and R ² represent the same or different alkyl groups of C ₁ to C _8. ). Compounds in which R ¹ is a methyl group and R ² is an butyl group are Sufinol 61, R ¹ and R ² are all methyl groups Compounds are Olpin B, R ¹ is methyl group, and R ² is ethyl group It is marketed under the brand name of this all-pin P.
The acetylene diol is a compound represented by the formula HOCR ¹ R ² -C≡C-CR ¹ R ² OH (R ¹ and R ² represent the same or different alkyl groups of C ₁ to C _8. ). Compound where R ¹ is methyl group, R ² is ethyl group is suminol 82, R ¹ is methyl group, R ² is isobutyl group is compound, and suminol 104, R ¹ and R ² are all methyl groups. It is commercially available.
In addition, surfactants obtained by adding alkylene oxide to the acetylene alcohol or acetylene diol include, for example, those obtained by adding ethylene oxide and propylene oxide to the acetylene alcohol or the acetylene diol. As the surfactant obtained by adding the alkylene oxide, an alkylene oxide added, for example, the addition of ethylene oxoxide to the suffinol 104 is a brand name Sufinol 400 series, Sufinol 104 (wax type) and amorphous dioxide. Powdered premixes obtained by mixing and pulverizing silicon in a 40:60 ratio include those sold under the trade name of Sufinol 104S (all manufactured by Aero Products Co., Ltd., sold by Nisshin Chemical Co., Ltd.).
Silicone surfactants are polyether-modified silicone oils in which polyethylene oxide or polypropylene oxide or both are introduced into a methyl group of the terminal and / or side chain of dimethylpolysiloxane, and optionally a hydroxyl group of the terminal is etherified with an alkyl group. As nonionic surfactants, for example, the Silgard series (manufactured by Dow Corning Silicon Co., Ltd.), the Silhouette series (manufactured by Nippon Yunika Kabuki Co., Ltd.), the silicone oil KF series (Shin-Etsu Chemical Co., Ltd.) And those sold under the trade names, such as manufactured by Kaisha) and Kinetic (manufactured by Helena Chemical Co., Ltd.).
Fluorine-based surfactants are those obtained by substituting some or all of the hydrogen atoms of conventional anionic, nonionic, cationic or amphoteric surfactants with fluorine atoms. These are excellent in surface tension lowering powers, such as the Unidain series (manufactured by Daikyo Kogyo Kabuki Kaisha), the Megafac series (manufactured by Dai Nippon Inki Kagaku Kogyo Kabushiki Kaisha), and Futa. Available under the trade names such as the Futergent series (manufactured by Kabushi Kaisha Neos), the Suflon series (manufactured by Asahigarasu Kabushiki Kaisha), and F-Top (manufactured by Tochem Products Kabushiki Kaisha) Things that are included.
The amount of other sleep extenders that may optionally be included in the compositions of the present invention may be determined by the nature and amount of the active ingredient of the pesticide, the type of essential surfactants and other optional sleep extenders of the present invention, and the types of other ingredients in the composition. Depending on the formulation and form of the formulation, including factors such as the amount, usually, the optional sleep extender is in an amount of 0.1 to 10% by weight, preferably 0.3 to 5% by weight, more preferably 0.5 to 3% by weight. exist.
The particle nucleus having an apparent specific gravity of less than 1 usable in the present invention is not particularly limited as long as it is a granular material that can float on water, and examples thereof include hollow minerals such as calcined vermiculite, foamed pumice, foamed silas, and foamed pearlite. carrier; Plant carriers such as cork; Granulated materials, such as synthetic resin foams such as foamed styrol, and molded granules or pellets containing one or more carriers thereof, which can float in water, are preferably calcined vermiculite, foamed pearlite or cork.
The sleeping pesticide composition of the present invention may be, for example, a pesticide active ingredient, a particle nucleus having an apparent specific gravity of less than 1, at least one of the above-mentioned essential surfactants, and, if necessary, other optional ingredients, and then the obtained mixture is dry or wet granulated. It can manufacture.
The particle nucleus of the present invention has an apparent specific gravity of less than 1, which means that they must be able to float on the surface of the water. The apparent specific gravity of the particle nucleus can be measured, for example, using the following method.
A stainless cylinder with a volume of 100 ml and a diameter of 50 mm is placed on a flat surface and then wrapped in a larger cylinder of thick paper, where the length of the paper cylinder is 20 cm longer than the length of the stainless steel cylinder. A sieve with an opening of 2380 μm is placed at the top of the paper cylinder. The particle nuclei for which the apparent specific gravity is to be measured are then slowly poured through a sieve, causing them to gradually fill the stainless steel cylinder. Continue working until the particle nucleus starts to fill from the stainless steel cylinder. The nucleus is then cut out on the top surface of the stainless steel cylinder so that the nuclei remaining in the cylinder completely fill it. Subsequently, the particle nucleus in the stainless steel cylinder is weighed (Wg). The apparent density of the weight per unit volume is then calculated (W / 100 gcm ^-3 ). Next, the apparent density of the particle nucleus is calculated by dividing the apparent density by the density (1 gcm ^-3 ) of water at 4 ° C.
When the sleeping pesticide composition of the present invention is molded (for example, using a granulator) and granules or pellets are obtained using a particle nucleus having an apparent specific gravity of less than 1, the particle nucleus is added in a sufficient amount to form a particulate pesticide composition. You should be able to float on this water.
Although the amount of particle nucleus present in the pesticide composition of the present invention, including granules or pellets, depends on the type or grade of the particle nucleus, the type of pesticide active ingredient (s) or the amount of other optional ingredients, the particle nucleus is typically In the composition, it is present in an amount of 0.1 to 40% by weight, preferably 1 to 25% by weight. When present in this amount, the particle nucleus imparts suspension to the shaped granules or pellets of the composition of the present invention. If the particle diameter of the particle nucleus is too large, molding using a granulator or the like becomes very difficult. As a result, when forming a granulated granule or pellet, 80% or more, preferably 90% or more of the particle nucleus has a cross-sectional diameter of 200 to 600 µm.
The pesticide composition of the present invention can be produced by, for example, supporting an agrochemical active ingredient in a particle nucleus having an apparent specific gravity of less than 1, or by coating an agrochemical active ingredient or the like on a particle nucleus surface having an external specific gravity of less than 1.
When the pesticide active ingredient or the like is supported on the particle nucleus having an apparent specific gravity of less than 1, the compounding quantity of the particle nucleus should be an amount such that the sleeping pesticide composition can float on the water surface. The amount of the particle nucleus varies depending on the type and grade of the particle nucleus, the type of the active ingredient of the pesticide, and the type and amount of the other ingredients, but the particle nucleus is typically 10 to 90% by weight in the pesticide composition carrying the active ingredient. Preferably in an amount of 20 to 70% by weight. When present in this amount, the particle nucleus imparts suspension to the obtained composition of the present invention. When most of the particles produced by the immersion of the particle nucleus have a particle diameter of less than 0.6 mm, the granules are submerged in water, or the particle heaving collapse tends to be too fast. On the other hand, when most of the particles have a particle diameter of more than 5 mm, it takes time to disintegrate and disperse the particles as the particles are blown by the wind. As a result, disintegration and dispersion of the immersed particles may occur where they are collected, causing segregation of the pesticide active ingredient. As a result, in order to avoid this, when the pesticide composition of the present invention contains granules or pellets formed by immersion of the particle nucleus, it is preferable that at least 90% of the granules or pellets have a particle diameter of 0.710 mm to 4.760 mm.
As already mentioned, another method for preparing the pesticide composition of the present invention comprises coating a particle nucleus surface having an apparent specific gravity of less than 1 with the pesticide active ingredient, the essential surfactant and other optional ingredients of the composition. There are two options for the production of the coated particles. The first approach is to first coat the granules formed by bonding together particle nuclei having an apparent specific gravity of less than 1, or particle nuclei having an apparent specific gravity of less than 1, first with a nonvolatile and liquid material at room temperature. This “wet” particle nucleus is then coated with agrochemical active ingredient (s), said surfactant which is an essential property of the composition of the invention, or with other optional ingredients such as disintegrants and extenders. “Weting” the surface of the particle nucleus with a liquid non-volatile material at room temperature allows the surface of the particle nucleus to be uniformly coated with the other components of the pesticide composition of the present invention. After this coating, the coated particles are often further coated with agents that assist in the expansion of water on the surface, such as the acetylene-based alcohol surfactants described above.
The second option relates to pre-immersion of the granules formed by the binding of the particle nucleus with an apparent specific gravity of less than 1 or by the combination of particle nuclei with an apparent specific gravity of less than 1 before coating. This can be done by immersing the granules formed by the particle nucleus or a combination of the particle nuclei with at least one pesticide active ingredient, at least one surfactant described above as an essential ingredient of the invention, and other optional ingredients as appropriate. The immersed particle nucleus or particles are coated with a non-volatile, liquid material at room temperature. The wetted particle nucleus or particles are then coated with the remaining ingredients of the composition, such as other pesticide active ingredients, other essential surfactants described above, and other optional ingredients, if desired. After this coating process, the coated particle nucleus or granules are further coated with a surfactant such as an acetylene-based alcohol surfactant, which aids in the expansion of water on the surface.
The above-mentioned nonvolatile and liquid substance at room temperature does not affect the activity of the active ingredient of the pesticide, and acts to uniformly coat the surface of the particle nucleus or granule formed therefrom with the active ingredient of the pesticide without having an apparent specific gravity. Do it. The substance is preferably a solvent having high boiling point, low toxicity, high flash point, low viscosity, specific gravity of less than 1, and low dissolvability of the agrochemical active ingredient. Such solvents include, for example, mineral oils such as low viscosity liquid paraffin, chlorinated paraffin, isoparaffin, machine oil, polybutene, paraffinic, naphthenic and aromatic high boiling point solvents; Vegetable oils such as palm oil, soybean oil, and rapeseed oil; Animal oils such as whale oil and sardine oil; Silicone oil and its derivatives, various esters of monomers or dicarboxylic acids such as oleic acid, palm oil fatty acid, maleic acid, fumaric acid, phthalic acid and adipic acid; Plasticizers such as various esters of phosphoric acid such as tributyl phosphate and tris (chloroethyl) phosphate; Glycols such as ethylene glycol, diethylene glycol, butanediol and various esters and ethers thereof; lactones such as ε-caprolactone and γ-butyrolactone; N-methylprolidone; And various liquid surfactants, and preferably, ethers of glycols or lactic acid alkyl esters, and specifically, hexyl glycol (HeG, ethylene glycol monohexyl ether, Nippon Yukazai Kabushika Kaisha), hexyl diglycol (HeDG, diethylene glycol monohexyl ether, Nippon Yukazai Kabushi Kaisha), 2-ethylhexyl glycol (EHG, ethylene glycol mono-2-ethylhexyl ether, Nippon Yukazai Kabushi Kaisha), 2-ethylhexyl di glycol (EHDG, diethylene glycol mono-2-ethylhexyl ether, Nippon Yukazai Co., Ltd.), methyl lactate, ethyl lactate, and butyl lactate.
The amount of the nonvolatile liquid liquid at room temperature, which can be used according to the present invention, depends on the type of the active ingredient of the pesticide, the type of the other optional ingredients, the blending amount, and the like, and imparts good sleep flocculability to the sleeping application pesticide composition of the present invention. In order to do that, it is usually 1 to 60% by weight, preferably 5 to 40% by weight in the sleeping trial pesticide composition.
A binder is used when molding a mixture of a particle nucleus with an apparent specific gravity of less than 1, an active ingredient (s) of pesticides, a surfactant which is an essential component of the present invention, and other sleep expanding agents into granules. Such binders include, for example, dextrin or polyvinyl alcohol, polyvinylpyrrolidone, salts of carboxymethyl cellulose, methyl cellulose, gum arabic, polyethylene glycol and derivatives thereof, tub powder and bentonite. In addition, polysorbs of the lignin sulfonate, carboxylic acid and sulfonic acid type, for example, can be used both as binders and dispersants, and bentonite and lignin sulfonate are particularly useful because they are relatively inexpensive and can also be used as extenders.
As the binder used to form the shaped particles according to the present invention, the sodium salt of bentonite or carboxymethyl cellulose is particularly good because the bonding strength is strong and the particle disintegration time can be adjusted in water. Furthermore, since it has swelling property in itself, it has the advantage that the granules can be completely collapsed once collapsed. The amount of the binder to be used in the agrochemical composition of the present invention may include the kind of the binder, the particle nucleus type having a specific gravity of less than 1, the composition and the preparation method, the formulation of the pesticide preparation, the preparation method and the shape, the kind and physical properties of the pesticide active ingredient, Other optional ingredients may vary depending on the type of formulation or formulation. As an example, bentonite is usually present in an amount of from 3 to 70% by weight, preferably from 5 to 30% by weight in the sleeping pesticide composition of the present invention. For other binders it is usually present in an amount of from 0.1 to 30% by weight, preferably from about 0.5 to 20% by weight.
In the pesticide composition of the present invention, other optional ingredients may be added for various purposes. Such optional components include disintegrants, dispersants, wetting agents, extenders, solvents, emulsifiers, water repellents, anti-particle growth agents, stabilizers and the like.
Examples of disintegrants or dispersants usable in the present invention include, for example, lignin sulfonates, (alkyl) naphthalenesulfonates and their condensates, phenolsulfonates and their condensates, condensates of styrenesulfonates, and condensates of maleic acid and styrenesulfonic acids. Salts, salts of carboxylic acid condensates such as acrylic acid and maleic acid, alkylbenzene sulfonates, dialkyl sulfosuccinates, salts of lauryl sulfate, salts of polyoxyethylene alkyl ether sulfates, polyoxyethylene alkylaryl ether sulfes Anionic surfactants such as salts of pates, polyoxyethylene alkyl ether phosphates and salts thereof, polyoxyethylene alkylaryl ether phosphates and salts thereof, and phosphate salts such as sodium tripolyphosphate and sodium hexametaphosphate. It is not limited. Most of these disintegrants or dispersants are also useful as wetting agents.
Extenders may be used in the present invention to dilute the pesticide active ingredient and provide an amount that is easy to spray. Examples thereof include resin powders such as vinyl chloride, chlorinated polyethylene, chlorinated polypropylene, glucose, in addition to mineral fine powders commonly used as carriers of agrochemicals such as bentonite, talc, cray, diatomaceous earth, amorphous silicon dioxide, calcium carbonate and magnesium carbonate. Sugars such as sugar and lactose, carboxymethyl cellulose and its salts, starch and derivatives thereof, microcrystalline cellulose, wood flour, sawdust, rice bran, bran, chaff powder, coffee fruit powder, cellulose powder, licorice powder and other organic substances, sodium sulfate, Water-soluble inorganic salts such as ammonium sulfate and potassium chloride, urea and the like. In particular, wood flour and sawdust are advantageous because they are inexpensive and light, and are easy to float particles in water.
Solvents may be used in the present invention to dilute the liquid pesticide active ingredient or to convert the low melting point pesticide active ingredient into the liquid phase. A high boiling point low toxicity and a high flash point solvent can be used, For example, such a high boiling point solvent of paraffin type, aromatic type, and naphthenic type; Fatty acids obtained from various animals and plants such as oleic acid, maleic acid, fumaric acid and palm oil; Esters such as phthalic acid, adipic acid and phosphoric acid; Vegetable oils such as palm oil and rapeseed oil; And animal and vegetable oils such as whale oil and sardine oil.
In addition to the disintegrating agent or dispersing agent of this invention mentioned above, the emulsifier used as needed by this invention emulsifies in water the solution of a liquid pesticide active ingredient or a pesticide active ingredient. The choice of suitable emulsifiers depends on the pesticide active ingredient and the nature of the solvent, and emulsifiers commonly used in the preparation of concentrated emulsions are generally selected from, for example, polyoxyethylene styrylphenyl ethers and polyoxyethylene nonyl phenol ethers.
When the water solubility of the pesticide active ingredient is high, the water-repellent agent used in the present invention is used in the present invention to suppress the elution of the pesticide active ingredient and widen it to the surface as widely as possible, and then dissolve in water. Such water repellents include, for example, fatty acid salts such as magnesium stearate, calcium stearate and sodium oleate, higher alcohols such as stearyl alcohol, higher fatty acids such as stearic acid, silicone oils and derivatives thereof, fluorine-based surfactants, cationic surfactants, Hydrophobic silica, liquid paraffin, machine oil, and the like.
Depending on the nature of the pesticide active ingredient, particle growth inhibitors or stabilizers may be used in the present invention. In addition, pigments, bitters, and various other optional agents may be added to the sleeping application pesticide composition of the present invention as needed.
In order to produce the sleeping pesticide composition of the present invention, when the pesticide active ingredient is a solid, the pesticide active ingredient is usually pulverized by a dry or wet method, and the pulverized pesticide active ingredient obtained thereby is 1 in appearance specific gravity. Granules or pellets are obtained by dry or wet granulation after mixing with less than one particle nucleus, one or more of the aforementioned surfactants, which are an essential component of the present invention, and other optional components. Examples of wet molding machines that can be used include extrusion granulators, mixing granulators, fluidized bed granulators, and electric granulators. As dry molding machines, roller compactors, tablet presses, briquetting machines, hydraulic molding machines, and the like can be given.
When preparing granules or pellets of the sleep application agrochemical composition of the present invention, the particle obtained by mixing the particle nucleus with an external specific gravity and, if necessary, other optional components, is mixed with the molding machine to contain no pesticide active ingredient. Or so-called "basal granules" which contain no or only some active ingredients. Alternatively, a similar method can be used, in which the pesticide active ingredient is included in a mixture forming a part to obtain an erector containing some but not all of the active ingredient. The resulting stand can then be coated with the other pesticide active ingredients along with any other ingredients of the composition, or the stand can be made to absorb some or all of these remaining ingredients. Alternatively, all the components can be premixed and the resulting mixture can be molded directly into granules or pellets using the molding machine.
In the case of using a liquid pesticide active ingredient or a liquefied pesticide active ingredient, the pesticide active ingredient is absorbed into a particle nucleus or an oil absorbing carrier having an apparent specific gravity of less than 1, and then the solid pesticide active ingredient is used. Form a pesticide composition. Alternatively, the particle nucleus with an apparent specific gravity of less than 1 and, if appropriate, additional optional ingredients may be preformed into granules or pellets, and the granules or pellets obtained thereby absorb or coat liquid pesticide active ingredients or liquefied pesticide active ingredients. To obtain the sleeping pesticide composition of the present invention.
When the particle size of the granules or pellets of the surface-use agricultural pesticide composition of the present invention is thinner than 0.6 mm of the granules or pellets, it becomes easy to sink in water or the particles collapse too quickly, while the particle diameters are too large than 5 mm. In addition, the wind is easy to gather and takes time to disintegrate and disperse the particles, where they disintegrate and disperse where they gather, causing segregation of the active ingredient of the pesticide. As a result, in order to avoid it, at least 90% of the granules or pellets should have a particle diameter of 0.710 mm to 4.760 mm.
The agrochemical composition for sleep application of the present invention, prepared as described above, is sprayed directly on rice fields from a box, a bottle, a bag, etc. with a spraying nozzle capable of shaking spraying, or packaged separately by a water-soluble film, and sprayed from paddy fields or the like. do. Alternatively, the composition is divided into small packages of water soluble films and sprayed on the paddy fields in paddy fields and the like. The pesticide composition of the present invention is rapidly and uniformly expanded on the surface of rice paddies, releasing the pesticide active ingredient. As a result, unlike the conventional granules, uniform biological effects can be achieved by applying the composition to the paddy field in the paddy field without entering the paddy field to expand the composition.
The water-soluble film usable in the present invention is a film or sheet which can be dissolved or dispersed in water, and suitable components thereof include, for example, polyvinyl alcohol or its derivatives, polyvinyl alcohol-based fibers (such as nonwoven fabric), pullulan film And combinations of sodium salts of carboxymethyl cellulose with cellulose, polyethylene oxides and derivatives thereof, and in particular, films made of polyvinyl alcohol or derivatives thereof (hereinafter abbreviated as PVA films) are easily incorporated in water. It is dispersed or dissolved, and the sleeping pesticide effective composition of the present invention is spread on the water surface.
The PVA film usable in the present invention is, for example, a polyvinyl alcohol having a degree of polymerization of 1000 to 2000 and a degree of reduction of 85 to 95% with a small amount of a plasticizer, a stabilizer, etc., and a small amount of carboxylic acid or the like in the polymer. And a film containing a copolymer of. As a result of considering the film strength and the dissolution time, the PVA film thickness is usually 25 to 70 µm, preferably 30 to 50 µm. Moreover, it is preferable that the edge part of a PVA film can be heat-sealed.
When the pesticide composition of the present invention is divided into a small amount of packaging of the PVA film, the weight per package is usually 10 to 200 g, preferably 20 to 60 g, and satisfactorily 2 to 40 packages are satisfied per 10 ar. The biological effect can be exerted and sprayed per 10 ar, preferably 4 to 20 packages.
In the present specification, the following 'expansion index' is a numerical value of the sleep integrity of the pesticide composition of the present invention in the range of 0 to 15 points (maximum: 15 points). Preferably it is five or more, More preferably, it is seven or more, More preferably, it is nine or more. The test for sleep integrity is as follows.
25 liters of tap water was placed in a drip tray having a length of 4 m and a width of 14 cm, and 2 g of Sumizelko (manufactured by Sumiganebusan Kabushiki Kaisha, powdered rice hulls) as a test obstacle (float) on paddy water surface. Apply evenly to the water surface. After leaving the water to sleep, 280 mg of the pesticide composition to be tested is added to a point 10 cm from one end of the drip tray, and 1.5 m arrival time and the longest arrival distance from the injection point of each sleeping pesticide composition after the injection Measure After 5 minutes of input, visually inspect the state of expansion according to the evaluation criteria shown in Table 1 below, and then evaluate the document according to the evaluation criteria shown in Table 1 below. The integrity index of the test composition is obtained by summing the integrity indexes of all items.
The integrity index for the conventional pesticide formulations is reviewed throughout this test system, with each test formulation having an integrity index of less than five. On the other hand, if the sleep pesticide composition of the present invention is evaluated in the same manner, the probability of its expansion is as high as 9 or more. From this, it can be clearly seen that the sleep pesticide composition of the present invention has considerably superior sleep integrity compared to the prior art even when there are obstacles such as suspended solids on the surface.
Evaluation Items and Evaluation Criteria Evaluation itemCriteriaScore 1.5 m arrival timeMore than 2 minutes Less than 1 minute, less than 2 minutes More than 30 seconds, less than 1 minute More than 20 seconds, less than 30 seconds More than 10 seconds, less than 20 seconds Less than 10 seconds012345 Longest Arrival DistanceLess than 0.5 m More than 0.5 m More than 1.0 m Less than 1.0 m More than 1.5 m Less than 1.5 m More than 2.0 m Less than 2.0 m More than 2.5 m More than 2.5 m More than 3.0 m Less than 3.0 m More than 3.5 m More than 3.5 m01234567 After 5 minutes of treatmentThe extended tip is returned to the treatment point. The return point is 1 m or more from the longest point. The return point is less than 1 m from the longest point.0123 Sum 15
Although an Example, a comparative example, and a test example are given to the following and this invention is demonstrated to it further more concretely, this invention is not limited to these. The following parts mean parts by weight.
Example
Example 1: granulation
5.30 parts of bensulfuron methyl (purity 99.47%), 20.88 parts of carpentrol (purity 98.39%) and 36.18 parts of dimuron (purity 99.4%) were mixed and the mixture was jet-milled (SK-Jet-O-Mizer). 0101 type, and Seishingyo Co., Ltd.) to obtain a premix powder. 62.36 parts of the premix powder, Sanekis P252 (manufactured by Nippon Seishi Kabushiki Kaisha, lignin sulfonate) 7.50 parts, M-3801G (manufactured by Daiichi Kogyo Seiyaku Kabushiki Kaisha, α-olefinsulfone salt) 3.42 parts, Neopelex No. 6F powder (Kao Kaobushiki Kaisha, alkylbenzenesulfonate) 0.68 parts, Amicool No. 1 (Nichiden Kagaku Kabushiki Kaisha, starch) 5.48 parts, Bentonite (Neolite Koosan Kabushiki Kaisha) 10.28 parts And 10.28 parts of cork (appearance specific gravity: 0.04-0.09) are mixed, transferred to a kneader (Mt. Fuji, KK, FM-NW-5 type), 18 parts of water is added, and the mixture is kneaded. The mixed dough is assembled by pressing Dom Gran (Fuji Powder Co., Ltd., DG-L1 type, screen 1.0 mm-diameter). After drying the obtained granules for 2 hours in a blower type dryer (blow temperature 90 degreeC), the granules of 850-1410 micrometers in diameter containing 5% of bensulfuronmethyl, 20% of carpentrol, and 35% of dimuron are filtered. Get
Example 2 granulation
Bensulfuron methyl element (purity 99.4%) 2.73 parts, carpentrol element (purity 98.3%) 11.37 parts, Daimuron element (purity 99.4%) 24.09 parts, Olpin STG-E (manufactured by Nissin Kagaku Kogyo Kabushiki Kaisha, 0.5 parts of 2,4,7,9-tetramethyl-5-decine-4,7-diol, 0.4 parts of KP-1436 (manufactured by Kao Kabushiki Kaisha, Polyoxyethylenephenylphenol ether phosphate), Perrex NP (Nippon 5.64 parts of lignin sulfonate) and 55.27 parts of water are mixed, and the mixture is grind | pulverized with the attritor (made by Mitsui Koozan Co., Ltd.), and a slurry is obtained. To 95 parts of the obtained slurry, 5 parts of Toxanon GR31A (Sanyo Kasei Co., Ltd. make, polyacrylate salt) is added, and it mixes and stirs again, and makes this slurry 2. Cork (Appearance Specific Gravity: 0.04-0.09) 22.0 parts, Cellogen 5A (Daiichi Kogyo Seiyaku Co., Ltd., carboxymethyl cellulose) 8.0 parts, Roca HELP B439 (Mitsui Ginzo Kuo Gyo Co., Ltd., foamed pearlite ) 7.0 parts, Perrex NP (made by Nippon Seishi Kabushiki Kaisha, lignin sulfonate tank) 6.0 parts, wood flour (neolight Koosan Kabuki Seiki Co., Ltd., α-olefin sulfonate) 7.0 parts, M-3801G (Daiichigo 3.0 parts of Ogyo Seiyaku Co., Ltd., α-olefinsulfonate), 3.0 parts of Supinol 104S (made by Nissin Kagaku Co., Ltd.) and 16.0 parts of bentonite were mixed in a kneader, and 65.94 parts of the slurry 2 was added to the mixture. do. The mixed dough is assembled by pressing it into the dome gran (1.2 mm diameter screen). The granules thus obtained were dried in a blower dryer (blow temperature 70 ° C.), and then sieved to a final diameter of 4760 to 710 μm, containing 1.7% by weight of bensulfuronmethyl, 7.0% by weight of carpentrol, and 15% by weight of dimuron. Get granules
Example 3: granulation
77.56 parts of F-155 raw material (purity 96.7%), 10.0 parts of M-3801G and 12.44 parts of Carplex # 1120 (manufactured by Shino Seiyaku Co., Ltd., white carbon) were mixed, and the mixture was ground with a jet mill. , Pre-mixer powder containing 75% of F-155 is obtained. Hilcon SI-600 (fired vermiculite, Hirushi Kagaku Kogyo Co., Ltd., 0.6 mm undercut product, appearance specific gravity: 0.1) 35 parts of Co., Ltd. was added to wet the granulation surface, and then 12.0 parts of the premixer powder was added and coated on the surface of the granules by mixing. Then, 1.5 parts of supinol 104S was added, followed by mixing to coat the surface of the granules. A granule containing 9.0 weight% of -155 is obtained.
Example 4 granulation
77.56 parts of F-155 raw material (purity 96.7%), 10.0 parts of M-3801G and 12.44 parts of Carflex # 1120 are mixed, and the mixture is ground with a jet mill to obtain a premixer powder containing 75% of F-155. 51.5 parts of Hilcon SI-600 (plastic vermiculite, Hirushi Kagaku Kogyo Co., Ltd., 0.6 mm undercut product) was placed in a mixer, and EHDG (diethylene glycol mono-2-ethylhexyl ether, Nippon Neukazai) 35 parts of Kabushi Kaisha Co., Ltd. are added to wet the granular surface granule surface, and then 12.0 parts of the premixer powder is added and mixed to coat the granulated surface by mixing, and then 1.5 parts of supinol 104S is added and mixed to the granulated surface. By coating, a final granule containing 9.0 wt% of F-155 is obtained.
Example 5 granulation
77.56 parts of F-155 original substance (purity 96.7%), Liporan PJ-400 (α-olefin sulfonate, manufactured by Lion Corporation) and 10.0 parts of Capflex # 1120 (manufactured by Shino Seiyaku Co., Ltd., white carbon) ) 12.44 parts are mixed and the mixture is ground with a jet mill to obtain a premixer powder containing 75% of F-155. 51.5 parts of Hilcon SI-600 were placed in a Nauter mixer, 35 parts of EHDG was added to wet the granulation surface, and then 12.0 parts of the premixer powder was added and mixed to coat the granulation surface by mixing, and then the obtained mixture was subjected to Sufinol 104S 1.5. The parts are mixed to coat the granule surface to obtain a final granule containing 9.0 wt% of F-155.
Example 6 granulation
77.56 parts of F-155 original substance (purity 96.7%), 10.0 parts of Hostapon T powder (oleoylmethyl tauride salt, manufactured by Hoechst Japan) and 12.44 parts of Carflex # 1120 were mixed and the mixture was pulverized with a jet mill. Thus, a premixer powder containing 75% of F-155 is obtained. 51.5 parts of Hilcon SI-600 were placed in a Nauter mixer, 35 parts of EHDG was added to wet the granulation surface, and then 12.0 parts of the premixer powder was added and mixed to coat the granulation surface by mixing, and again, 1.5 parts of Surfinol 104S was added, Coating on the surface of the granules by mixing yields a final granule containing 9.0% by weight of F-155.
Example 7 granulation
77.56 parts of F-155 original substance (purity 96.7%), 10.0 parts of Hostapur OSB (oleoylmethyl tauride salt, manufactured by Hoechst Japan) and 12.44 parts of Carflex # 1120 were mixed, and the mixture was ground with a jet mill to prepare F-155. Obtain a premixer powder containing 75%. 51.5 parts of Hilcon SI-600 were placed in a Nauter mixer, 35 parts of EHDG was added to wet the granulation surface, and then the obtained mixture was coated on the surface of the granulation by adding and mixing 12.0 parts of the premixer powder, and again, the surfynol 104S 1.5 Part is added and mixed to coat the surface of the granules to obtain a final granule containing 9.0 wt% of F-155.
Example 8 granulation
77.56 parts of F-155 original substance (purity 96.7%), 10.0 parts of FA-617B (α-sulfoaliphatic acid, Lion Co., Ltd.) and 12.44 parts of Carflex # 1120 were mixed, and the mixture was pulverized with a jet mill to obtain F-155. A premixer powder containing 75% of 155 is obtained. 51.5 parts of Hilcon SI-600 were placed in a Nauter mixer, 35 parts of EHDG was added to wet the granulation surface, and then 12.0 parts of the premixer powder was added and mixed to coat the granulation surface by mixing, and again, 1.5 parts of Surfinol 104S was added, Coating on the surface of the granules by mixing yields a final granule containing 9.0% by weight of F-155.
Example 9: granulation
Pyroquillone original (purity 97.2%) 87.45 parts, M-3801G 6 parts and Carplex # 80D (Siono Seiyaku Co., Ltd., white carbon) 6.55 parts are mixed, and the mixture is a hammer mill (Fuji Powder Co., Ltd.) Production) to obtain a premix containing 85% of pyroquilon. Put 33.09 parts of Hilcon SI-600 into the outer mixer, add 36 parts of super oil C (manufactured by Nippon Sekiyu Chemical Co., Ltd.), wet the granulation surface, and then add 29.41 parts of the premixer powder and mix the coating on the granulation surface Then, 1.5 parts of Suminol 104S is added and mixed to coat the surface of the granules to obtain a final granule containing 25% by weight of pyroquilon.
Example 10 granulation
87.45 parts of pyroquilon original (purity 97.2%), 6 parts of M-3801G and 6.55 parts of Carflex # 80D are mixed and the mixture is ground with a hammer mill to obtain a premix containing 85% of pyroquilon. 33.09 parts of Hilcon SI-600 were placed in a Nauter mixer, 36 parts of EHDG were added to wet the granulation surface, and then 29.41 parts of the premixer powder was added and mixed to coat the granulation surface by mixing, again adding 1.5 parts of Surfinol 104S and mixing Thus, the final granules were coated on the granular surface and contained 25% by weight of pyroquilon.
Comparative Example 1: granulation
5.30 parts of bensulfuronmethyl (99.47% purity), 20.88 parts of carpenstrol (98.39% pure) and 36.18 parts of dimuron (99.4% pure) are mixed, and the mixture is pulverized with a jet mill to obtain a premix powder. 62.36 parts of the premix powder, 7.50 parts of Sanecax P252, Neopelex No. 0.68 parts of 6F powder, 5.48 parts of Amicool No. 1 and 23.98 parts of bentonite are mixed, transferred to a kneader, 18 parts of water is added, and the mixture is kneaded. The mixed dough is assembled by pressing the dome gran (screen 1.0 mm-diameter). After drying the obtained granules for 2 hours in a blower type dryer (blow temperature 90 degreeC), 850-1410 micrometers diameters which sift out and contain 5 weight% of bensulfuronmethyl, 20 weight% of carpentrol, and 35 weight% of dimuron Gets the granularity of
Comparative Example 2: Granulation
5.30 parts of bensulfuronmethyl (99.47% purity), 20.88 parts of carpenstrol (98.39% pure) and 36.18 parts of dimuron (99.4% pure) are mixed, and the mixture is pulverized with a jet mill to obtain a premix powder. 62.36 parts of the premix powder, 7.50 parts of Sanecax P252, Neopelex No. 0.68 parts of 6F powder, 5.48 parts of Amicool No. 1, 13.7 parts of bentonite, and 10.28 parts of cork are mixed, transferred to a kneader, 18 parts of water is added, and the mixture is kneaded. The mixed dough is assembled by pressing the dome gran (screen 1.0 mm-diameter). The granules thus obtained were dried in a blower dryer (blow temperature 90 ° C.) for 2 hours, and then sieved to a final diameter of 850 to 1410 μm, containing 5% by weight of bensulfuronmethyl, 20% by weight of carpenstrol and 35% by weight of dimuron. Get granules
Comparative Example 3: Granulation
7.23 parts of bensulfuron methyl (purity 99.47%), 28.50 parts of carpenstrolt (purity 98.39%) and 49.36 parts of dimuron element (purity 99.4%) are mixed, and the mixture is triturated with a jet mill to obtain a premix powder. 62.36 parts of the premix powder, 7.50 parts of Sanecax P252, 3.42 parts of M-3801G, Neopelex No. 0.68 parts of 6F powder, 5.48 parts of Amicool No. 1 and 20.56 parts of bentonite are mixed, transferred to a kneader, 18 parts of water is added, and the mixture is kneaded. The mixed dough is assembled by pressing the dome gran (screen 1.0 mm-diameter). After drying the obtained granules for 2 hours in a blower type dryer (blow temperature 90 degreeC), 850-1410 micrometers diameters which sift out and contain 5 weight% of bensulfuronmethyl, 20 weight% of carpentrol, and 35 weight% of dimuron Gets the final granularity.
Comparative Example 4: Granulation
Bensulfuronmethyl Element (purity 99.4%) 2.73 parts, Carpentrol Element (purity 98.3%) 11.37 parts, Dimuron Element (purity 99.4%) 24.09 parts, Olpin STG-E 0.5 part, KP-1436 0.4 part, Perlex After mixing 5.64 parts of NP and 55.27 parts of water, the mixture is ground with an attritor to obtain a slurry. To 95 parts of the obtained slurry, 5 parts of toxanone GR31A is added, mixed and stirred to obtain slurry 2. 8.0 parts of Cellogen 5A, 7.0 parts of LocaHelp B439, 6.0 parts of Perrex NP, 7.0 parts of wood flour, 3.0 parts of Supinol 104S and 41.0 parts of bentonite are mixed in the kneader, and 65.94 parts of the slurry 2 are added and kneaded. The mixed dough is assembled by pressing it into the dome gran (1.2 mm diameter screen). The obtained granules were dried in a blower dryer (air blowing temperature 70 ° C.), and then sieved through a sieve containing granules having a diameter of 710 to 4760 μm, containing 1.7 wt% of bensulfuronmethyl, 7.0 wt% of carfenstrol, and 15 wt% of dimuron. Get
Comparative Example 5: granulation
Bensulfuronmethyl Element (purity 99.4%) 2.73 parts, Carpentrol Element (purity 98.3%) 11.37 parts, Dimuron Element (purity 99.4%) 24.09 parts, Olpin STG-E 0.5 part, KP-1436 0.4 part, Perlex After mixing 5.64 parts of NP and 55.27 parts of water, the mixture is ground with an attritor to obtain a slurry. To 95 parts of the obtained slurry, 5 parts of toxanone GR31A is added, mixed and stirred to obtain slurry 2. 22.0 parts of cork, 8.0 parts of Celogen 5A, 7.0 parts of LocaHelp B439, 6.0 parts of Perrex NP, 7.0 parts of wood flour, 3.0 parts of Supinol 104S and 19.0 parts of bentonite were mixed in the kneader, and 65.94 parts of the slurry 2 were added and mixed Knead. The mixed dough is assembled by pressing it into the dome gran (1.2 mm diameter screen). The obtained granules were dried in a blower dryer (blow temperature 70 ° C.), and then filtered through a furnace to contain 1.7 wt% of bensulfuronmethyl, 7.0 wt% of carfenstrol, and 15 wt% of dimuron. Get
Comparative Example 6: granulation
Bensulfuronmethyl Element (purity 99.4%) 2.73 parts, Carpentrol Element (purity 98.3%) 11.37 parts, Dimuron Element (purity 99.4%) 24.09 parts, Olpin STG-E 0.5 part, KP1436 0.4 part, Perlex NP 5.64 After mixing 55.27 parts of water and 55 parts of water, the mixture is ground with an attritor to obtain a slurry. To 95 parts of the obtained slurry, 5 parts of toxanone GR31A is added, mixed and stirred to obtain slurry 2. 8.0 parts of Cellogen 5A, 7.0 parts of LocaHelpB439, 6.0 parts of Perrex NP, 7.0 parts of wood flour, 3.0 parts of M-3801G, 3.0 parts of Supinol 104S and 38.0 parts of bentonite were mixed in the kneader, and 65.94 parts of the slurry 2 was added thereto. Dough, mix. The resulting mixture is assembled by pressing with a dome gran (screen 1.2 mmφ). The obtained granules were dried in a blower type dryer (air blowing temperature of 70 ° C.), and then sieved through a sieve containing granules having a diameter of 710 to 4760 μm, containing 1.7 wt% of bensulfuronmethyl, 7.0 wt% of carfenstrol, and 15 wt% of dimuron. Get
Comparative Example 7: Granulation
77.56 parts of F-155 element (purity 96.7%) and 22.44 parts of Carplex # 1120 are mixed and the mixture is ground with a jet mill to obtain a premixer powder containing 75% of F-155. Place 51.5 parts of Hilcon SI-600 in a Nauter mixer, add 35 parts of daphnioyl SY-15, wet the granulation surface, then add 12.0 parts of the premixer powder, mix and coat the granulation surface, and again, the Sufinol 104S 1.5 parts are added and mixed to coat the surface of the granules to obtain a final granule containing 9.0 wt% of F-155.
Comparative Example 8: Granulation
87.45 parts of pyroquilon original (purity 97.2%) and 12.55 parts of Carplex # 80D are mixed, and the mixture is ground with a hammer mill to obtain a premix containing 85% of pyroquilon. 33.09 parts of Hilcon No. 1 are placed in a nut mixer, 36 parts of super oil C is added to wet the granulation surface, and then 29.41 parts of the premixer powder are added and mixed to coat the granulation surface. Subsequently, 1.5 parts of Suminol 104S is added and mixed to coat the granulation surface and to obtain a final granule containing 25% pyroquilon.
Test Example 1: Test of granularity
25 liters of tap water was placed in a drip tray with a length of 4 m and a width of 14 cm, assuming obstacles (floating matter) on the surface of the paddy field, 2 g of Sumizelko (manufactured by Sumigane-Busan Kabuki Kaisha, powdered rice husk) Treat it to be even on the surface. After allowing the surface to stand, 280 mg of the granules described in Examples 1 to 10 and Comparative Examples 1 to 8 were charged at a 10 cm mark at one end of the drip tray, and then 1.5 m arrival time was added at the feed point of each granule after the addition. The longest arrival distance from the point and the state of expansion after 5 minutes of input are visually examined, determined according to the evaluation criteria described in Table 1 above, and the respective reliability indexes are determined by summing the integrity indexes of each item. The results are shown in Table 2. In the table, '-' indicates that the granules were not expanded. The granules obtained in Comparative Examples 1 to 3 are directly comparable to those obtained in Example 1; The granules obtained in Comparative Examples 4 to 6 are directly comparable to those obtained in Example 2; The granules obtained in Comparative Example 7 are directly comparable to those obtained in Example 3; The granules obtained in Comparative Example 8 are directly comparable to those obtained in Example 9.
Probability test of granulation Examination1.5 m Arrival timeExpansion distance (m)State 5 minutes after treatmentExpansion Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8 Example 9 Example 1045 sec 57 sec 27 sec 19 sec 27 sec 28 sec 27 sec 28 sec 28 sec 15 sec2.42.62.43.12.62.82.82.42.43.1No change is not visible no change is not visible no change is not visible no change is not visible no change is not visible no change is not visible no change is not visible no change is not visible99913101111101013 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Comparative Example 6 Comparative Example 7 Comparative Example 8-2 minutes or more--2 minutes or more-2 minutes or more-0.2--0.8-0.70.5---- no change is seen-Particle return of less than 1 m Particle return of less than 1 m00004033
Probability test of granulation TestState of expansion Examples 1-10Granules show good sleep integrity and disperse quickly after expansion Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Comparative Example 6 Comparative Example 7 Comparative Example 8Granules settle immediately after dosing and do not spread Granules do not settle, but are almost unextended and dispersed in water Immediately after injection, the granules settle and do not extend Immediately after injection, the granules settle and do not develop. The power is weak After the injection, the granules settle and do not get expanded The granules confirm sleep, but the rate of expansion is slow and the expansion power is weak The granules confirm sleep, but the rate of expansion is slow and weak power
Test Example 2: Paddy spray test of the spray formulation
Water is added to a paddy field of approximately 27 m x 28 m to maintain the depth of 5 cm. 50 g of the granules of Examples 7 and 8 and Comparative Example 8 are wrapped in a nonwoven fabric that is a water-soluble film and heat sealed to prepare a spray formulation. Each spray formulation was sprayed into the paddy field and the break time of the film, the time all particles emerge from the film (total spray time), and the area of the expanded portion of the particles were examined. The results are shown in Table 4. In addition, the wind speed at the time of treatment is 4 m / sec.
Test formulationBreak time of filmTotal spraying timeExpansion area of particles (㎡) Example 7 Example 816 seconds 20 seconds3 minutes 30 seconds 3 minutes 30 seconds104361 Comparative Example 818 sec2 minutes 30 seconds42
As can be seen from the above test examples, the sleep pesticide composition of the present invention has a very good sleep propagation richness even in the presence of obstacles, and it is considerably more than the conventional water-floating pesticide granules simply by spraying from rice paddy fields. It is excellent in sleep expansion and can uniformly disperse the pesticide active ingredient throughout the paddy field even when some obstacles exist.

权利要求:
Claims (41)
[1" claim-type="Currently amended] A sleeping pesticide composition comprising at least one active ingredient, at least one particle nucleus having an apparent specific gravity of at least one, and at least one surfactant selected from α-olefinsulfonate salts, α-sulfoaliphatic salts and oleoylmethyl taurate salts.
[2" claim-type="Currently amended] The sleeping pesticide composition according to claim 1, wherein the active ingredient is selected from herbicides, insecticides, fungicides, acaricides and plant control agents.
[3" claim-type="Currently amended] The sleeping pesticide composition according to claim 1 or 2, wherein the active ingredient of the pesticide is present in an amount of 1 to 90% by weight in the composition.
[4" claim-type="Currently amended] The sleeping pesticide composition according to any one of claims 1 to 3, wherein the α-olefin sulfonate is C ₁₂ -C ₁₆ α-olefin sulfonate.
[5" claim-type="Currently amended] The sleeping pesticide composition according to any one of claims 1 to 3, wherein the α-sulfoaliphatic acid salt is methyl C ₁₀ -C ₁₄ α-sulfoaliphatic acid salt.
[6" claim-type="Currently amended] The sleeping pesticide composition according to claim 4 or 5, wherein the salt is selected from sodium salt, potassium salt, calcium salt, ammonium salt and amine salt.
[7" claim-type="Currently amended] The sleeping pesticide composition according to any one of claims 1 to 3, wherein the oleoylmethyl tauride salt is selected from sodium, calcium, potassium and ammonium salts of oleoylmethyl tauide.
[8" claim-type="Currently amended] The sleeping pesticide composition according to any one of claims 1 to 7, wherein the surfactant is present in an amount of 0.01 to 40% by weight of the pesticide composition.
[9" claim-type="Currently amended] 8. The sleeping pesticide composition according to any one of claims 1 to 7, wherein the surfactant is present in an amount of 0.1 to 30% by weight of the pesticide composition.
[10" claim-type="Currently amended] 8. The sleeping pesticide composition according to any one of claims 1 to 7, wherein the surfactant is present in an amount of 1 to 20% by weight of the pesticide composition.
[11" claim-type="Currently amended] The polycarboxylic acid type polyimide according to any one of claims 1 to 10, wherein the agrochemical composition is an agent to assist in the expansion of the surface of the composition in addition to the surfactants as defined in claim 1. Soap; Soaps; Anionic surfactants; Nonionic surfactants; Surfactants which esterify polyoxyethylene alkylaryl ethers, polyoxyethylene alkyl ethers, polyoxyethylene alkyl esters or alkyl esters of sorbitan with phosphoric acid or sulfuric acid and, if necessary, neutralize the obtained esters with a suitable alkali; Fluorine-based surfactants; Cationic surfactants; Zwitterionic surfactants; Liquid paraffin or naphthenic high boiling point solvents; Mineral oil; Animal oils; Vegetable oils; Suzy; Camphor white milk; α-pinene; camphor; And naphthalene further comprising an agent selected from naphthalene.
[12" claim-type="Currently amended] 12. The sleeping pesticide composition according to claim 11, wherein the agent which aids in the sleep expansion of the composition is selected from acetylene surfactants, silicone surfactants and fluorine surfactants.
[13" claim-type="Currently amended] 13. The sleeping pesticide composition according to claim 11 or 12, wherein the additional agent to assist in the sleep expansion of the composition is present in an amount of 0.1 to 10% by weight in the composition.
[14" claim-type="Currently amended] The molded granule according to any one of claims 1 to 13, wherein the particle nucleus having an apparent specific gravity of less than 1 is formed from a hollow mineral carrier, a vegetable carrier, a foamed synthetic resin, and at least one particle nucleus of the above form. Sleeping pesticide composition selected from pellets.
[15" claim-type="Currently amended] The molded core according to claim 14, wherein the particle nucleus having an apparent specific gravity of less than 1 is formed from at least one of calcined vermiculite, foamed fumice, foamed syras, foamed pearlite, cork, foamed polystyrene, and particles of this type. Sleeping pesticide composition selected from granules or pellets.
[16" claim-type="Currently amended] The sleeping pesticide composition according to any one of claims 1 to 15, which further contains a nonvolatile material and a liquid at room temperature.
[17" claim-type="Currently amended] 17. The sleeping pesticide according to claim 16, wherein the substance which is non-volatile and liquid at room temperature has a high boiling point, low toxicity, high flash point, low viscosity, and specific gravity of less than 1, wherein the active ingredient of the pesticide is a solvent having low solubility. Composition.
[18" claim-type="Currently amended] 17. The sleeping pesticide composition according to claim 16, wherein said substance which is non-volatile and liquid at room temperature is selected from glycol ethers and alkyl lactates.
[19" claim-type="Currently amended] 19. The sleeping pesticide composition according to any one of claims 16 to 18, wherein the liquid is non-volatile and at room temperature, wherein the substance is present in an amount of 1 to 60% by weight of the composition.
[20" claim-type="Currently amended] 20. The composition according to any one of claims 1 to 19, wherein the composition further contains one or more optional ingredients selected from binders, disintegrants, dispersants, wetting agents, extenders, solvents, emulsifiers, water repellents, particle growth inhibitors and stabilizers. Sleep pesticide composition for sleep.
[21" claim-type="Currently amended] 21. The compound according to any one of claims 1 to 20, selected from at least one pesticide active ingredient, a particle nucleus having an apparent specific gravity of less than 1, an alpha -olefin sulfonate salt, an alpha -sulfoaliphatic acid salt and an oleoylmethyl taurate salt. A mixture containing the above surfactant, and optionally any other optional ingredients as defined in claims 11 to 13, and 16 to 20, is obtained by dry or wet granulation. Pesticide composition for sleep containing pellets or granules.
[22" claim-type="Currently amended] 22. The sleeping pesticide composition of claim 21, wherein the particle nucleus is present in an amount of from 0.1 to 40% by weight in said composition.
[23" claim-type="Currently amended] 23. The sleeping pesticide composition according to claim 21 or 22, wherein at least 80% of the particle nuclei have a cross-sectional diameter of 200 to 600 mu m.
[24" claim-type="Currently amended] The granules according to any one of claims 1 to 20, wherein the granules formed by bonding together the particle nucleus having an apparent specific gravity of less than 1 or the particle nucleus having an apparent specific gravity of less than 1 together are at least one pesticide active ingredient, α-olefin sulfonate, α At least one surfactant selected from sulfoaliphatic salts and oleoylmethyl taurate salts, optionally with any additional optional ingredients as defined in claims 11 to 13 and 16 to 20 Sleeping agrochemical composition coated or immersed in a component selected from them.
[25" claim-type="Currently amended] 25. The sleeping pesticide composition of claim 24, wherein said particle nucleus is present in an amount of 10 to 90 weight percent of said pesticide composition.
[26" claim-type="Currently amended] 26. The sleeping pesticide composition according to claim 24 or 25, wherein at least 90% of the granules or pellets formed by immersion of the particle nucleus have a particle diameter of 0.710 to 4.760 mm.
[27" claim-type="Currently amended] The granules according to claim 24, wherein the granules formed by bonding together the particle nucleus having an apparent specific gravity of less than 1 or the particle nucleus having an apparent specific gravity of less than 1 together are nonvolatile and room temperature as defined in any one of claims 16 to 18. Is first coated with a liquid substance at and at least one surfactant selected from the pesticide active ingredient, α-olefinsulfonate salts, α-sulfoaliphatic salts and oleoylmethyl tauride salts, Sleeping agrochemical compositions coated with any additional optional ingredients as defined in any of claims 13-16 and 20.
[28" claim-type="Currently amended] The granules according to claim 24, wherein the granules formed by bonding together the particle nucleus having an apparent specific gravity of less than 1 or the particle nucleus having an apparent specific gravity of less than 1 are used together with a pesticide active ingredient, an alpha -olefin sulfonate, an alpha -sulfoaliphatic acid salt, and an oleoylmethyl. Soaking first with at least one surfactant selected from tauride salts and at least one ingredient selected from at least one additional optional ingredient as defined in any one of claims 11 to 13 and 16 to 20. The particle nucleus or granules immersed therein are then coated with a non-volatile and liquid at room temperature, as defined in any one of claims 16 to 18, and the coated nucleus is finally applied to any of the compositions. Sleeping pesticide composition coated with the remaining ingredients.
[29" claim-type="Currently amended] 29. The sleeping pesticide composition according to claim 27 or 28, wherein the coated particle nucleus or granules are further coated with an agent to assist in the expansion of the surface of the composition.
[30" claim-type="Currently amended] The sleeping pesticide composition according to claim 29, wherein the agent which assists in the expansion of sleep is an acetylene-based surfactant.
[31" claim-type="Currently amended] Dry or wet milling of the solid pesticide active ingredient, and the milled pesticide active ingredient thus obtained is one selected from particle nuclei having a specific gravity of less than 1, α-olefinsulfonate salts, α-sulfoaliphatic salts and oleoylmethyl tauride salts. After mixing with at least one surfactant, optionally at least one additional optional component as defined in any of claims 11 to 13 and 16 to 20, the resulting mixture is subjected to dry or wet granulation. A process for producing a sleeping application pesticide composition as defined in any one of claims 1 to 20, which comprises obtaining a granule or pellet.
[32" claim-type="Currently amended] Particle nuclei with an apparent specific gravity of less than 1, optionally additional optional ingredients as defined in any of claims 11 to 13 and 16 to 20, and optionally some but not all of the pesticide active ingredient And the resulting granules are coated with the other pesticide active ingredients, along with any other ingredients of the composition, or the granules are coated with some of the remaining ingredients, or The manufacturing method of the sleeping application pesticide composition as defined in any one of Claims 1-20 which consists of immersing in all.
[33" claim-type="Currently amended] A particle formed by bonding together the particle nucleus having an apparent specific gravity of less than 1 or the particle nucleus having an apparent specific gravity of less than 1 is coated with a nonvolatile and liquid material at room temperature, as defined in any one of claims 16 to 18. The coated nucleus is then subjected to one or more surfactants selected from agrochemical active ingredients, α-olefinsulfonates, α-sulfoaliphatic salts and oleoylmethyl tauride salts, optionally with claims 11-13 and 21. A process for the preparation of a sleeping application pesticide composition as defined in any of claims 1 to 20, comprising coating with any additional optional ingredients as defined in any of claims 16 to 20.
[34" claim-type="Currently amended] A granule formed by combining together the particle nucleus having an apparent specific gravity of less than 1 or the particle nucleus having an apparent specific gravity of less than 1 is selected from a pesticide active ingredient, α-olefinsulfonate salt, α-sulfoaliphatic acid salt and oleoylmethyl taurate salt. Immersed in one or more surfactants, optionally in one or more components selected from one or more optional additional optional components as defined in any one of claims 11 to 13 and 16 to 20, The particle nucleus or granules soaked therein are coated with a non-volatile and liquid at room temperature, as defined in any one of claims 16 to 18, and then the coated nucleus is coated with any remaining components of the composition. A process for producing a sleeping application pesticide composition according to any one of claims 1 to 20, which consists of coating.
[35" claim-type="Currently amended] 35. The method of claim 33 or 34, further comprising the step of coating the obtained particle nucleus or granules with an agent that assists in the sleep of the composition.
[36" claim-type="Currently amended] 30. A packaged sleeping application pesticide composition comprising the pesticide composition as defined in any one of claims 1 to 29, packaged in a container, a bottle or a bag with a spraying device capable of shaking spraying.
[37" claim-type="Currently amended] 30. A packaged sleeping application pesticide composition comprising the pesticide composition as defined in any one of claims 1 to 29, divided by packaging using a water soluble film.
[38" claim-type="Currently amended] 38. The film of claim 37 wherein the water soluble film is a film formed from polyvinyl alcohol or a derivative thereof, a film formed from polyvinyl alcohol fibers, a film formed from pullulan, a film formed from a combination of sodium salt of carboxymethyl cellulose and cellulose, Or a film formed from polyethylene oxide or a derivative thereof.
[39" claim-type="Currently amended] 39. A packaged sleeping pesticide composition according to claim 37 or 38, having a weight of 10 to 200 g.
[40" claim-type="Currently amended] 30. A method of applying to a rice field of an agrochemical active ingredient, comprising spraying the pesticide composition according to any one of claims 1 to 29 from the packaged pesticide composition according to claim 36 to the above discussion sleep.
[41" claim-type="Currently amended] 41. A method of applying an agrochemical active ingredient to a paddy field, comprising throwing a packaged pesticide composition as defined in any one of claims 37 to 39 into the paddy field.

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同族专利:

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公开号 | 公开日

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KR100687514B1|2007-02-27|

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CN1261514A|2000-08-02|

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CN1251589C|2006-04-19|

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TW542695B|2003-07-21|

引用文献:

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公开号 | 申请日 | 公开日 | 申请人 | 专利标题

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法律状态:
1998-12-25|Priority to JP98-368701

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1998-12-25|Priority to JP36870198

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1999-12-24|Application filed by 가와무라 요시부미, 상꾜 가부시키가이샤

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2000-07-25|Publication of KR20000048402A

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2007-02-27|Application granted

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2007-02-27|Publication of KR100687514B1

优先权:

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申请号 | 申请日 | 专利标题

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JP98-368701|1998-12-25|

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JP36870198|1998-12-25|