• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    A retroreflective sheeting and a method for producing the same are disclosed. The retroreflective sheeting includes a heat-resistant film, a first thermoplastic bonding layer, a first non-flammable layer, a colored layer, a light-transmissive layer, a colored portion for emitting a portion of light diffused outward through a first a light-condensing layer, a second thermoplastic bonding layer, a second non-flammable layer, a reflective layer, and a reflective portion reflecting a light input to a reflective zone through a second light-condensing layer.
    公开号:FR3055975A1
    申请号:FR1758466
    申请日:2017-09-13
    公开日:2018-03-16
    发明作者:Se Won YOON
    申请人:Se Won YOON；
    IPC主号:
    专利说明:

    055 975
    58466 ® FRENCH REPUBLIC
    NATIONAL INSTITUTE OF INDUSTRIAL PROPERTY
    COURBEVOIE © Publication number:
    (to be used only for reproduction orders)
    ©) National registration number
    ©) Int Cl 8 : G 02 B 5/128 (2017.01)
    PATENT INVENTION APPLICATION
    A1
    ©) Date of filing: 13.09.17. © Applicant (s): YOONSE WON— KR. (30) Priority: 13.09.16 KR 1020160117845. ©) Inventor (s): YOON SE WON. ©) Date of public availability of the request: 16.03.18 Bulletin 18/11. (56) List of documents cited in the report preliminary research: The latter was not established on the date of publication of the request. @) References to other national documents ©) Holder (s): YOON SE WON. related: ©) Extension request (s): ©) Agent (s): GEVERS & ORES.
    RETROREFLECTIVE SHEET AND MANUFACTURING METHOD THEREOF.
    FR 3 055 975 - A1
    Disclosed is a retroreflective sheet and a method of manufacturing the latter. The retro-reflective sheet includes a heat-resistant film, a first layer of thermoplastic bonding, a first non-flammable layer, a colored layer, a light-transmitting layer, a colored part allowing a portion of light scattered to the outside through a first to be emitted. light condensing layer, a second thermoplastic bonding layer, a second non-flammable layer, a reflective layer, and a reflective portion reflecting a light entry to a reflective area through a second light condensing layer.
    , - 'Χ Mb
    V'CXXÜ-11
    Embodiments of the inventive concept described here relate to a retroreflective sheet and a method of manufacturing the latter, and more particularly, a retroreflective body which can enhance visibility by improving the efficiency of reflection of light in a colored area at night, and a method of manufacturing the latter.
    A retroreflective sheet is a retroreflective body which directly reflects the incident light including a layer condensing the light and a layer reflecting in an incident direction. The retro-reflective sheet generally has a sheet shape, and is machined into a desired pattern on a surface of a body of a fastener to be attached to a road sign or a selected part of a uniform of a firefighter or similar by fusion or thermal stitching, thus increasing visibility so that it is easily displayed in a place, the immediate environment is dark. Consequently, if the retro-reflective sheet is attached to the clothing of a person, who works on a road or in a dangerous place, such as a garbage collector, a fireman, a police officer, a worker in a factory, a construction worker, and a site security officer, the protection and safety of the carrier can be effectively guaranteed by allowing those around to identify a location of the carrier firmly.
    In addition, the retroreflective sheeting has a striped pattern shape which is alternately formed with reflective areas in which a colored area reflects light and can then guarantee visibility even at night. The reflective area has a structure in which a light-collecting layer is formed by attaching beads to the reflective layer, on which a metal such as aluminum is deposited, and the colored area includes a colored layer, on which an organic binder including a colored pigment having fluorescent or light accumulation characteristics is applied.
    The related art retroreflective sheeting is disclosed in Korean Patent No. 10-0,935,540 (entitled "Retroreflective sheeting and process for making the same").
    The related art retroreflective sheet includes: a base in which reflective areas RA and colored areas FA are alternately formed; a colored part including a first bonding layer formed by applying a synthetic bonding resin to an entire surface of the base, a colored layer formed by applying a synthetic bonding resin in which fluorescent pigments are mixed on the first bonding layer, and a first light-condensing layer formed by diffusing a plurality of beads of the colored layer so that portions of the bodies of the beads are buried; and a reflective part including a second bonding layer formed by applying the synthetic bonding resin on the reflective area RA on the first light-condensing layer of the colored part, a reflective layer formed by depositing a metal having reflection characteristics of the light on the second bonding layer so that the metal has a thin film shape, a primer layer formed by applying a synthetic bonding resin having transparency characteristics on the reflective layer, and a second light-condensing layer formed by diffusing a plurality of beads onto the primer layer so that portions of the bodies of the beads are buried.
    In this case, the colored layer may selectively include a fluorescent pigment and a fluorescent material including a fluorescent pigment, or a light accumulating pigment and a light accumulating material including a light accumulating pigment, or may include a fluorescent material and a material accumulating light together to emit light by fluorescent operation at night or emitting light that has been accumulated by absorbing light during the day or inside a building at night, thereby enhancing visibility at night or in a dark place. Furthermore, if the colored layer includes a fluorescent material and a light accumulating material together, it can perform a fluorescence operation and a light accumulation operation at the same time. In this case, the light emitted by the colored layer has colors such as red (R), green (V), and blue (B) depending on the fluorescent material or the material accumulating the light.
    In this case, the amount of light reflected by the reflecting area is approximately 500 cd / lux * m 2 , and the amount of light reflected by the colored area is not more than 30 cd / lux * m 2 ). Consequently, when the widths of the reflective layer and the colored layer are the same, the amount of light reflected by the retroreflective sheet is approximately 265 cd / lux * m 2 .
    Consequently, since the retroreflective sheet according to the related art reflects a small amount of light on the colored area with the exception of the reflective area, it decreases visibility.
    summary
    Embodiments of the inventive concept provide a retroreflective sheet which can improve visibility by increasing the amount of light reflected on a colored area at night and thereby increasing the amount of light reflected by the retroreflective sheet.
    Embodiments of the inventive concept also provide a method of manufacturing a retroreflective sheeting which can improve visibility by increasing the amount of light reflected from a colored area at night and thereby increasing the amount of light reflected from the retroreflective sheeting.
    In accordance with another aspect of the inventive concept, there is provided a retroreflective sheet including a colored portion including a light transmitting layer configured to transmit light input through a first layer condensing light from a colored area and configured to emit a portion of light obtained by diffusing light which is transmitted through the light transmitting layer on an interface with the light transmitting layer through the first layer condensing the light together with the fluorescent or accumulated light of a colored layer, and a reflecting part formed by thermal pressing on a reflecting zone with the exception of the colored zone on the colored part and configured to emit an entry of light through a second layer condensing the light towards the outside.
    In accordance with one aspect of the inventive concept, a retro-reflective sheet is proposed including a heat-resistant film, a first layer of thermoplastic bonding formed on the heat-resistant film, a first non-flammable layer formed on the first layer of thermoplastic bonding, a colored layer formed on the first non-flammable layer, a light transmitting layer formed on the colored layer, a colored part including a first light condensing layer formed on the light transmitting layer and in which a colored area is defined such that the light transmitting layer of the colored area transmits an input of light through the first layer condensing the light and diffuses the input light over an interface with the colored layer so that a portion of the scattered light is emitted outward through the first light-condensing layer, conjo intimately with the fluorescent light or the light accumulated in the colored layer, a second thermoplastic bonding layer thermally pressed on a reflective zone on the first layer condensing the light to define the colored zone, a second non-flammable layer formed on the second bonding layer thermoplastic, a reflective layer formed on the second non-flammable layer, and a reflective portion including a second light-condensing layer formed on the reflective layer such that the reflective layer reflects an entry of light to the reflective area through the second condensing layer the light.
    In accordance with another aspect of the inventive concept, there is provided a method of making a retroreflective sheeting, the method including forming a first light-condensing layer including a first layer of bead arrangement and a plurality of beads , on a first carrier film, the formation of a colored part by sequential stratification of a light-transmitting layer, of a colored layer, of a first non-flammable layer, of a first thermoplastic bonding layer, and of a first protective film, on a surface of the first light-condensing layer, the formation of a second light-condensing layer including a second bead arrangement layer, and a plurality of beads, on a second carrier film, the formation of a reflecting part by sequential stratification of a reflecting layer, of a second non-flammable layer, of a second c thermoplastic bonding sheet, and a second protective film, on a surface of the second light-condensing layer, the separation of the reflecting part into a plurality of sections having a striped pattern shape with a width of a reflecting zone and removing the second protective film so that the second thermoplastic bonding layer is exposed, exposing the first thermoplastic bonding layer by removing the first protective film and in turn attaching a heat resistant film on the first thermoplastic bonding layer, and exposing the first light-condensing layer by removing a first carrier film and the first bead arrangement layer so that the first light-condensing layer is exposed, and pressing thermal of the reflective part on the colored part while the second thermoplastic bonding layer is exposed ed on a surface of the first layer condensing light at an interval from the colored area.
    The heat-resistant film may be formed from a released heat-resistant sheet.
    The colored layer may be formed from a polyurethane-based resin, an ethylene-vinyl acetate copolymer (EVA), a polyester-based resin, a meta-acrylic-based resin, or of an acrylic copolymer.
    The colored layer may selectively include any of a fluorescent material or a light accumulating material, or includes a fluorescent material and a light accumulating material together.
    The light transmitting layer can be formed of SiO 2 , indium tin oxide (ITO), tin oxide (TO), indium zinc oxide (IZO), TiO 2 , ZnS , ZnO, AI 2 O 3 or CeO 2 .
    The light transmitting layer can be formed from a plurality of layers of two or more from SiO 2 , indium tin oxide (ITO), tin oxide (TO), indium zinc oxide (IZO), TiO 2 , ZnS, ZnO, AI 2 C> 3 or CeO 2 .
    The light transmitting layer can be deposited to have a thickness of 100 to 3000 Å.
    Brief description of the figures
    The foregoing and other objects and features will become apparent from the following description with reference to the following figures, in which identical reference numerals refer to identical parts throughout the various figures unless otherwise specified, and in which:
    Figure 1 is a plan view of a retroreflective sheet according to an embodiment of the inventive concept;
    Figure 2 is a sectional view taken along line A-A of Figure 1; and Figures 3A to 3E are views of the manufacturing process of a retroreflective sheet according to one embodiment.
    detailed description
    The inventive concept will be described in detail below with reference to the accompanying drawings.
    Figure 1 is a plan view of a retroreflective sheet according to an embodiment of the inventive concept. Figure 2 is a sectional view taken along line A-A of Figure 1.
    The inventive concept retroreflective sheet is formed by laminating reflective portions 43 on a colored portion 26 in striped pattern forms such that the reflective portions 43 are spaced from the colored portion 26 at a specific interval. Consequently, the areas in which the reflective portions 43 are laminated define reflective areas L2, and the areas in which the reflective portions 43 are not laminated become colored areas L1.
    The colored part 26 includes a heat-resistant film 41, a first thermoplastic bonding layer 23, a first non-flammable layer 21, a colored layer 19, a light-transmitting layer 17, and a first light-condensing layer 15.
    In this case, the heat-resistant film 41 is adapted to prevent contamination of the first thermoplastic sticky layer 23, and can be formed from a heat-resistant sheet such as released PET.
    The first thermoplastic bonding layer 23 is attached to a surface of a product, such as clothing or shoes, by thermal fusion, and is formed of a thermoplastic resin, such as polyester, polyurethane, polyacryl, a polyolefin, a thermoplastic elastomer (TPE), or thermoplastic polyurethane (TPU) to have a thickness of 300 to 500 μm.
    The first non-flammable layer 21 is formed on the first thermoplastic bonding layer 23. In this case, the first non-flammable layer 21 includes an adhesive including a liquid synthetic resin, such as a polyurethane resin, a polyester resin, or a resin. acrylic, and a non-flammable material, and is coated by a process, such as comma coating, etching coating, microgravure coating, or flat die head coating to have a thickness from about 100 to 300 pm. The first non-flammable layer 21 includes a non-flammable material, such as aluminum hydroxide, a non-flammable material based on phosphorus, Sb2C> 3, a non-flammable material based on Br, or a non-flammable material based on melamine to have flammability characteristics.
    The colored layer 19 is coated with a synthetic bonding resin, such as a polyurethane-based resin, an ethylene vinyl acetate (EVA) copolymer, a polyester-based resin, a meta-acrylic-based resin, or an acrylic copolymer, by means of a process, such as comma coating, etching coating, microgravure coating, or flat die head coating.
    In this case, the colored layer 19 selectively includes any of a fluorescent pigment and a fluorescent material including a fluorescent pigment, and a light accumulating pigment and a light accumulating material including a light accumulating pigment to have a thickness of 100 to 500 µm. In addition, the colored layer 19 may include a fluorescent material and a light accumulating material together.
    Consequently, the amount of light reflected on the colored layer 19 at night or in a dark place becomes no more than 30 cd / lux * m 2 since the colored layer 19 emits light by means of a fluorescence operation at night or absorbs light during the day or inside a building to emit light at night. Furthermore, if the colored layer 19 includes a fluorescent material and a light accumulating material together, it can perform a fluorescence operation and a light accumulation operation at the same time. In this case, the light emitted by the colored layer 19 has colors such as red (R), green (V), and blue (B) depending on the fluorescent material or the material accumulating the light.
    The light transmitting layer 17 is formed on the colored layer 19. In this case, the light transmitting layer 17 is formed by depositing a metal having excellent light transmittance, such as SiO 2 , indium tin oxide (ITO ), tin oxide (TO), indium zinc oxide (IZO), TiO 2 , ZnS, ZnO, AI 2 O 3 , or CeO 2 , via a deposition process, such as evaporation, chemical vapor deposition (CVD), sputtering, or ion beam projection, to have a thickness of 100 to 3000 Å. In this case, while transmitting an input of light through the first light-condensing layer 15, which will be described below, through a thin transparent film without shielding the light, the light-transmitting layer 17 diffuses the light transmitted on an interface with the colored layer 19. Consequently, a portion of the light scattered on the interface of the light transmitting layer 17 and the colored layer 19 is emitted through the first layer condensing the light 15 towards the colored layer 19 together with fluorescent or accumulated light. Consequently, the amount of light emitted through the first light-condensing layer 15 formed in the colored area L1 increases to about 200 cd / lux * m 2 as the light reflected on the colored layer 19 and the light scattered on the interface of the light transmitting layer 17 and the colored layer 19 emerge so that the visibility of the colored layer 19 is improved.
    In addition, the light transmitting layer 17 may include a plurality of layers including two or more of S1O2, indium tin oxide (ITO), tin oxide (TO), indium zinc oxide (IZO), TiO 2 , ZnS, ZnO, AI2O3, or CeC> 2, for example, two layers of SiO 2 and T1O2. In this case, the reflection indices of SiO 2 and TiO 2 which constitute the light transmitting layer 17 have different values, for example, about 1.43 to 1.45 and about 1.7 to 1.9, respectively . Consequently, the amount of light which is supplied as input through the first light-condensing layer 15 and then is diffused increases on the interfaces of the plurality of layers constituting the light-transmitting layer 17, for example, on the interface between a layer of SiO 2 and a layer of TiO 2 , as well as on the interface of the light-transmitting layer 17 and the colored layer 19. Consequently, because a portion of the scattered light is emitted through the first light condensing layer 15 together with fluorescent or accumulated light, the amount of scattered light increases only on an interface of the light transmitting layer 17 and the colored layer 19 so that the visibility of the colored layer 19 is further enhanced. Namely, if the light transmitting layer 17 includes two layers, the amount of light emitted through the first light condensing layer 15 increases to about 400 cd / lux * m 2 as light reflected on the colored layer 19, and the light scattered on the interface of the light transmitting layer 17 and the light scattered in the interior of the light transmitting layer 17 emerge so that the visibility of the colored layer 19 is improved.
    Furthermore, the first light-collecting layer 15 is formed so that a plurality of beads is diffused over the light-transmitting layer 17. In this case, the plurality of beads constituting the first light-condensing layer 15 is adapted to condense the incident light, and is formed from a glass having sizes from 20 to 200 µm, a transparent non-vitreous ceramic, or a transparent synthetic resin.
    In this case, the first primer layer (not shown) can be formed between the light-transmitting layer 17 and the first light-condensing layer 15. The first primer layer is adapted to gently adhere a metal during a deposition process to form the light transmitting layer 17 in the first light condensing layer 15, and must be transparent to prevent loss of light which is input to the light transmitting layer 17 through the first layer condensing light 15.
    The reflecting part 43 includes a second thermoplastic bonding layer 37, a second non-flammable layer 35, a reflecting layer 33, a second light-condensing layer 31, a bead arrangement layer 29, and a carrier film 27.
    A lower surface of the second thermoplastic bonding layer 37 is attached to the first light-condensing layer 15 of the colored part 26 so that the second thermoplastic bonding layer 37 defines a reflective zone L2. In this case, part of the colored part 26, on which the second thermoplastic bonding layer 37 is not attached, becomes a colored zone L1. The second thermoplastic bonding layer 37 is attached to the first bonding layer 15, by thermal fusion, and is formed from a thermoplastic resin, such as polyester, polyurethane, polyacryl, a polyolefin, a thermoplastic elastomer (TPE) , or thermoplastic polyurethane (TPU) to have a thickness of 300 to 500 μm like the first layer of thermoplastic bonding 23.
    The second non-flammable layer 35 is formed on the second thermoplastic bonding layer 37. In this case, the second non-flammable layer 35 includes an adhesive including a liquid synthetic resin, such as a polyurethane resin, a polyester resin, or a resin. acrylic, and a non-flammable material, and is coated by a process, such as comma coating, etching coating, microgravure coating, or flat die head coating to have a thickness from about 100 to 300 pm. The second non-flammable layer 35 includes a non-flammable material, such as aluminum hydroxide, a non-flammable material based on phosphorus, Sb 2 O 3 , a non-flammable material based on Br, or a non-flammable material based on melamine for have flammability characteristics.
    The reflective layer 33 is formed by depositing a metal having excellent light reflection characteristics, such as AI, Ag, Cu, Zn or Sn. In this case, the reflective layer 33 is adapted to reflect an entry of light from the outside to the outside again, and can be formed in the form of a thin film by deposition of a metal, such as AI, Ag, Cu, Zn or Sn, through a process such as evaporation, chemical vapor deposition (CVD), sputtering, or ion beam projection. Because the reflection characteristics of the reflective layer 33 deteriorate if the thickness of the reflective layer 33 is less than 100 Å, it is preferable that the reflective layer 33 to be deposited has a thickness of 100 to 3000 Å. In this case, the amount of light reflected on the reflective layer 33 becomes approximately 500 cd / lux * m 2 .
    The second light-condensing layer 31 is formed so that a plurality of beads are diffused to form a layer. In this case, the plurality of beads constituting the second light-condensing layer 31 is adapted to condense the incident light, and is formed from a glass having sizes from 20 to 200 µm, from a transparent non-vitreous ceramic, or d '' a transparent synthetic resin.
    In this case, the second primer layer (not shown) can be formed between the reflective layer 33 and the second light-condensing layer 31. The second primer layer is adapted to gently adhere a metal during a process of deposit intended to form the reflective layer 33 on the second light-condensing layer 31, and must be transparent to prevent loss of a light which is supplied to the reflecting layer 33 through the second light-condensing layer 31.
    The bead arrangement layer 29 is formed on the second light-condensing layer 31. In this case, the bead arrangement layer 29 is adapted to arrange a plurality of beads when the beads are diffused to form the second condensing layer the lumen 31, and is formed of a thermoplastic synthetic resin, such as an ethylene-vinyl acetate copolymer (EVA), an ethylene copolymer (EAA), a polyethylene (LDPE, LDPE, or HDPE), polypropylene, or a polyacryl copolymer. In addition, the carrier film 27 is formed on the bead arrangement layer 29. In this case, the carrier film 27 is formed of a synthetic resin, such as polyester.
    The above-described retroreflective sheet according to the inventive concept is attached by removing the heat-resistant film 41 and pressing the retroreflective sheet while applying heat to the carrier film 27 in a state in which the first thermoplastic adhesive layer 23 comes into contact with a surface of a product, such as clothing or shoes. In this case, the carrier film 27 prevents damage to the first light-condensing layer 15 when the retroreflective sheet is thermally pressed, and the carrier film 27 is removed together with the bead arrangement layer 29 after thermal pressing.
    In this case, since the heat-resistant film 41 is formed from a heat-resistant sheet such as released PET, heat damage is prevented when the second thermoplastic bonding layer 37 of the reflective part 43 is mounted on the first layer condensing the light 15 of the colored part 26 by thermal pressing.
    Furthermore, in the retroreflective sheet according to the inventive concept, the light-transmitting layer 17 formed in the colored area L1 transmits the light which has passed through the first light-condensing layer 15, and the light which has passed through the first light-condensing layer 15 is diffused on an interface with the colored layer 19. A portion of the light is diffused on the surface of the first layer condensing the light 15 and the colored layer 19, is emitted towards the outside through the first layer condensing the light 15 together with fluorescent light or accumulated light. The amount of light emitted through the first layer condensing the light 15 is obtained as a portion of the light scattered on the interface of the first layer condensing the light 15 and the colored layer 19 and the fluorescent light or the light accumulated in the colored layer 19 merge, and is approximately 200 cd / lux * m 2 .
    Consequently, in the retroreflective sheet according to the inventive concept, the light is reflected on the reflective layer 33 of the reflective zone L2 so that the quantity of light corresponding to approximately 500 cd / lux * m 2 is emitted through the second condensing layer light 31, and the quantity of light corresponding to 500 cd / lux * m 2 is emitted through the first layer condensing light 15 from the colored area L1. Consequently, in the retro-reflective sheet according to the inventive concept, the amount of light reflected when the widths of the reflective area L2 and the colored area L1 are the same becomes approximately 350 cd / lux * m 2 , which is higher the night.
    Furthermore, according to the inventive concept, the light transmitting layer 17 includes a plurality of layers of two or more layers of transparent thin films so that the light is scattered on an interface between the transparent thin films as well as on an interface with the layer. colored 19, and thus the amount of light corresponding to approximately 400 cd / lux * m 2 . Consequently, when the light transmitting layer 17 includes two or more layers, for example two layers and the widths of the reflecting area L2 and the colored area L1 are the same, the amount of reflected light is approximately 450 cd / lux * m 2 so that visibility is improved at night, which is better than when the light-transmitting layer 17 includes only one layer.
    Table 1 shows a difference in the amounts of light between the inventive concept and the related art. The unit is cd / lux * m 2 .
    [Table 1]
    Related art Layertransmitting thelight of alayer Layertransmitting thetwo lightlayers Partreflective 500 500 500 Colorful part 30 200 400 Average 255 350 450
    As described above, although it has been described that the reflective part 43 is laminated on the colored part 26 in the form of a striped pattern to be spaced from the colored part 26 in the retro-reflective sheet according to the embodiment of the inventive concept, the colored part 26 can be laminated in the form of a striped pattern to be spaced from the reflecting part 43 in another embodiment.
    Furthermore, although the colored area L1 and the reflective area L2 have stripe pattern shapes in the inventive concept, various shapes, such as waveforms or sawtooth shapes, can be continuously formed in the leaf length direction.
    Figures 3A to 3E are views of the manufacturing process of a retroreflective sheet according to one embodiment.
    Referring to Figure 3A, a first bead arrangement layer 13 is formed on a first carrier film 11. In this case, the first carrier film 11 is formed of a synthetic resin, such as polyester. In addition, the first bead arrangement layer 13 is formed from a synthetic thermoplastic resin, such as an ethylene vinyl acetate copolymer (EVA), an ethylene copolymer (EAA), a polyethylene. (LDPE,
    LDPE, or HDPE), polypropylene, or a polyacryl copolymer.
    A first light condensing layer 15 is formed by diffusing a plurality of beads on the first bead arrangement layer 13. In this case, the first light condensing layer 15 is formed by attaching the plurality of scattered beads to only a portion of the first bead arrangement layer 13, for example, a narrow area of the first bead arrangement layer 13 while intermediate portions of the beads are not buried. In this case, the plurality of beads constituting the first light-condensing layer 15 can be formed from glass having sizes from 20 to 200 μm, from transparent non-vitreous ceramic, or from transparent synthetic resin.
    Referring to Figure 3B, a light transmitting layer 17 is formed on a surface of the first light condensing layer 15. In this case, the light transmitting layer 17 is formed by depositing a metal having excellent transmittance of the light, such as SiO 2 , indium tin oxide (ITO), tin oxide (TO), indium zinc oxide (IZO), ΤίΟ 2 , ZnS, ZnO, AI2O3 or CeC> 2, via a deposition process, such as evaporation, chemical vapor deposition (CVD), sputtering, or ion beam projection, to have a thickness of 100 to 3000 Å. In this case, because the first bead arrangement layer 13 is formed from a thermoplastic synthetic resin, such as an ethylene-vinyl acetate copolymer (EVA), an ethylene copolymer (EAA), polyethylene (LDPE, LDPE, or HDPE), polypropylene, or a polyacryl copolymer, a solvent does not volatilize when the light-transmitting layer 17 is formed, and degradation of the degree of vacuum can therefore be prevented. As a result, the light transmitting layer 17 can be easily formed. The light transmitting layer 17 is a thin transparent film and transmits light input through the first light condensing layer 15 without shielding the light.
    In this case, although the light transmitting layer 17 is formed of a layer, for example, of SiO 2 , indium tin oxide (ITO), tin oxide (TO), oxide indium zinc (IZO), T1O2, ZnS, ZnO, AI 2 O 3 or CeO 2 , it can be formed from a plurality of layers of two or more from S1O2, indium tin oxide (ITO), tin oxide (TO), indium zinc oxide (ΙΖΟ), T1O2, ZnS, ZnO, AI2O3 or CeC> 2, for example, two layers of SiO 2 and TiO 2 in the inventive concept.
    In this case, since the reflection indices of S1O2 and TiO 2 constituting the light-transmitting layer 17 have different values, for example, from approximately 1.43 to 1.45 and approximately 1.7 to 1, 9, respectively, the amount of light which is input through the first layer condensing the light 15 and the scattered light increases even on the interfaces of the plurality of layers if the light transmitting layer 17 has a plurality of layers.
    In addition, a first primer layer (not shown) can be formed first before the light transmitting layer 17 is formed on a surface of the first light condensing layer 15. In this case, the first layer d the primer is adapted to gently adhere a metal during a deposition process to form the light transmitting layer 17 on surfaces of the plurality of beads, and must be transparent to prevent loss of light which is provided entry to the light transmitting layer 17 through the first light condensing layer 15.
    In addition, a colored layer 19 is formed on the light-transmitting layer 17. In this case, the colored layer 19 is coated with a synthetic bonding resin, such as a resin based on polyurethane, an ethylene copolymer. -vinyl acetate (EVA), a polyester-based resin, a meta-acrylic-based resin, or an acrylic copolymer, which includes a fluorescent or accumulated pigment, via a process, such as comma coating, etching coating, microgravure coating, or flat die head coating so that the colored layer 19 has a thickness of approximately 100 to 500 µm. In this case, the colored layer 19 selectively includes any of a fluorescent pigment and a fluorescent material including a fluorescent pigment, and a light accumulating pigment and a light accumulating material including a light accumulating pigment. In addition, the colored layer 19 may include a fluorescent material and a light accumulating material together.
    Furthermore, a first non-flammable layer 21 is formed on the colored layer 19. In this case, the first non-flammable layer 21 includes an adhesive including a liquid synthetic resin, such as a polyurethane resin, a polyester resin, or a resin. acrylic, and a non-flammable material, and is coated by a process, such as comma coating, etching coating, microgravure coating, or flat die head coating to have a thickness from about 100 to 300 pm. In this case, the first non-flammable layer 21 includes a non-flammable material, such as aluminum hydroxide, a non-flammable phosphorus-based material, Sb 2 O 3 , a non-flammable Br-based material, or a non-flammable material to melamine base to have flammability characteristics.
    Then, the first thermoplastic bonding layer 23 is formed on the first non-flammable layer 21. In this case, the first thermoplastic bonding layer 23 is suitable for attaching the retroreflective sheeting produced on a surface of a product, such as clothing or shoes, via thermal fusion, and is a sheet formed from a thermoplastic resin, such as polyester, polyurethane, polyacryl, polyolefin, thermoplastic elastomer (TPE), or thermoplastic polyurethane ( TPU) to have a thickness of 300 to 500 µm.
    In addition, a first protective film 25 is formed on the first thermoplastic bonding layer 23. In this case, the first protective film 25 is formed of a polyolefin film to prevent contamination of the first thermoplastic bonding layer 23.
    Referring to Figure 3C, as illustrated in Figure 3A, a second bead arrangement layer 29 and a second light-condensing layer 31 are formed sequentially on the second carrier film 27. In this case, the second film carrier 27 is formed of a synthetic resin, such as polyester, such as the first carrier film 11, and the second bead arrangement layer 29 is formed of a thermoplastic synthetic resin, such as an ethylene copolymer vinyl acetate (EVA), an ethylene copolymer (EAA), a polyethylene (LDPE, LDPE, or HDPE), polypropylene, or a polyacryl copolymer, such as the first layer of pearl arrangement 13. In this case , the second carrier film 27 and the second bead arrangement layer 29 are the same as the carrier film 27 and the bead arrangement layer illustrated in FIG. 1.
    Furthermore, the second light-condensing layer 31 is formed by diffusing a plurality of beads on the second bead arrangement layer 29 like the first light-condensing layer 15. In this case, the second light-condensing layer 31 can be formed on the second bead arrangement layer 29 as the first light-condensing layer 15. In this case, the plurality of beads constituting the second light-condensing layer 31 can be formed of glass having sizes from 20 to 200 µm, a transparent non-vitreous ceramic, or a transparent synthetic resin.
    Next, a reflective layer 33 is formed on a surface of the second light-condensing layer 31. The reflective layer 33 is formed by depositing a metal having excellent light-reflecting characteristics, such as AI, Ag, Cu, Zn or Sn, via a process, such as evaporation, chemical vapor deposition (CVD), sputtering, or ion beam projection. In this case, the reflective layer 33 is adapted to reflect the entry of light from the outside to the outside again, and because the reflection characteristics of the reflective layer 33 deteriorate if the thickness of the reflective layer 33 is smaller than 100 Å, it is preferable that the reflective layer 33 be deposited to have a thickness of 100 to 3000 Å. In this case, because the second bead arrangement layer 29 is formed from a thermoplastic synthetic resin, such as an ethylene-vinyl acetate copolymer (EVA), an ethylene copolymer (EAA), polyethylene (LDPE, LDPE, or HDPE), polypropylene, or a polyacryl copolymer such as the first bead arrangement layer 13, a solvent does not volatilize when the reflective layer 33 is formed and this can thus be prevented degradation of the degree of vacuum. As a result, the reflective layer 33 can be easily formed.
    In this case, a second primer layer (not shown) can be formed first before the reflective layer 33 is formed on a surface of the second light-condensing layer 31. In this case, the second primer layer is adapted to gently adhere a metal during a deposition process to form the reflective layer 33 on the surfaces of the plurality of beads, and it must be transparent to prevent loss of light which is supplied to the layer reflecting 33 through the second light-condensing layer 31.
    In addition, a second non-flammable layer 35 is formed on the reflective layer 33. In this case, the second non-flammable layer 35 includes an adhesive including a liquid synthetic resin, such as a polyurethane resin, a polyester resin, or a resin. acrylic, and a non-flammable material, and is formed by a process, such as comma coating, etching coating, microgravure coating, or flat die head coating to have a thickness about 100 to 300 µm, like the first non-flammable layer 21.
    Then, the second thermoplastic bonding layer 37 is formed on the second non-flammable layer 35. In this case, the second thermoplastic bonding layer 37 is suitable for attaching the retroreflective sheeting produced on a surface of a product, such as clothing or shoes, by thermal fusion, and is a sheet formed from a thermoplastic resin, such as polyester, polyurethane, polyacryl, a polyolefin, a thermoplastic elastomer (TPE), or thermoplastic polyurethane (TPU) to have a thickness from 300 to 500 μm, like the first thermoplastic bonding layer 23.
    In addition, the manufacture of the reflecting part 43 is completed by forming a second protective film 39 on the second thermoplastic adhesive layer 37. In this case, the second protective film 39 is formed from a polyolefin film to prevent contamination of the first thermoplastic bonding layer 37, like the first protective film 25.
    Referring to Figure 3D, the reflective portion 43 is separated into a plurality of sections in the form of a striped pattern in a cutting process to have a width of a reflective area L2.
    Referring to Figure 3E, the second thermoplastic bonding layer 37 is exposed by removing the second protective film 39 from the reflective portion 43 separated into a plurality of sections.
    In addition, the first thermoplastic bonding layer 23 is exposed by removing the first protective film 25 from the colored part 26. In this case, since the polyolefin film constituting the first protective film 25 is sensitive to heat, it can be damaged by heat during thermal pressing and is therefore removed. In addition, a heat-resistant film 41 is attached to the exposed surface of the first thermoplastic bonding layer 23. The heat-resistant film 41 is formed from a heat-resistant sheet, such as released PET.
    In addition, the first carrier film 11 is removed. Next, the first bead arrangement layer 13 is also removed together with the first carrier film 11 so that the first light-condensing layer 15 is exposed.
    The reflecting part 43 is mounted on the colored part 26 by thermally pressing the second thermoplastic bonding layer 37 of the reflecting part 43 on the first layer condensing the exposed light 15 of the colored part 26 so that the second thermoplastic bonding layer 37 has a specific interval, for example, an interval of the colored area L1. The thermal pressing is achieved by applying pressure together with heat to the second carrier film 27 to prevent damage to the plurality of beads constituting the second light-condensing layer 16. In addition, since the heat-resistant film 41 under the portion colored 26 is formed from a heat-resistant sheet, such as released PET, heat damage is prevented during thermal pressing. In this case, an area in which the reflective portion 43 having a striped pattern shape is bonded to the first light-condensing layer 17 of the colored portion 26 becomes the reflective area 12, and an area in which the reflective portion 43 n is not glued to the first light-condensing layer 17 and where the first light-condensing layer 17 is exposed becomes the colored area L1.
    As described above, although it has been described that the reflective portion 43 is laminated to the colored portion 26 in the form of a striped pattern to be spaced from the colored portion 26 in the method of manufacturing a retroreflective sheeting according to the embodiment of the inventive concept, the colored part 26 can be laminated in the form of a striped pattern to be spaced from the reflecting part 43 in another embodiment.
    Accordingly, according to the inventive concept, visibility can be improved by increasing the amount of light reflected on a colored area at night and thereby increasing the amount of light reflected by the entire retroreflective sheet.
    Those skilled in the art to which the inventive concept is intended will note that the inventive concept is not limited to the embodiments described above and to the accompanying drawings but can be replaced, modified, and varied in various ways without departing from the spirit of the inventive concept.
    权利要求:
    Claims (14)
    [1" id="c-fr-0001]
    1. Retro-reflective sheet comprising: a heat-resistant film;
    a first thermoplastic bonding layer formed on the heat-resistant film;
    a first non-flammable layer formed on the first thermoplastic bonding layer;
    a colored layer formed on the first non-flammable layer;
    a light transmitting layer formed on the colored layer; a colored portion including a first light-condensing layer formed on the light-transmitting layer and in which a colored area is defined such that the light-transmitting layer of the colored area transmits light input through the first layer condensing the light and diffuses the input light over an interface with the colored layer so that a portion of the scattered light is emitted to the outside through the first light-condensing layer, together with the fluorescent light or the light accumulated in the colored layer;
    a second thermoplastic bonding layer thermally pressed on a reflective area on the first light condensing layer to define the colored area;
    a second non-flammable layer formed on the second thermoplastic bonding layer;
    a reflective layer formed on the second non-flammable layer; and a reflecting portion including a second light condensing layer formed on the reflecting layer such that the reflecting layer reflects an entry of light to the reflecting area through the second light condensing layer.
    [2" id="c-fr-0002]
    2. retroreflective sheet according to claim 1, wherein the heat resistant film is formed of a released heat resistant sheet.
    [3" id="c-fr-0003]
    3. Retro-reflective sheet according to claim 1, in which the colored layer is formed from a polyurethane-based resin, from an ethylene-vinyl acetate (EVA) copolymer, from a polyester-based resin, from '' a resin based on methacrylate, or an acrylic copolymer.
    [4" id="c-fr-0004]
    The retroreflective sheet according to claim 1, wherein the colored layer selectively includes any one of a fluorescent material or a light accumulating material, or includes a fluorescent material and a light accumulating material together.
    [5" id="c-fr-0005]
    5. A retroreflective sheet according to claim 1, in which the light-transmitting layer is formed of SiO 2 , indium tin oxide (ITO), tin oxide (TO), indium zinc oxide (IZO), TiO 2 , ZnS, ZnO, AI2O 3 or CeO 2 .
    [6" id="c-fr-0006]
    6. retroreflective sheet according to claim 1, wherein the light transmitting layer is formed of a plurality of layers of two or more from SiO 2 , indium tin oxide (ITO), tin oxide (TO), oxide indium zinc (IZO), TiO 2 , ZnS, ZnO, AI2O 3 or CeO 2 .
    [7" id="c-fr-0007]
    7. A retroreflective sheet according to claim 1, in which the light transmitting layer is deposited to have a thickness of 100 to 3000 Å.
    [8" id="c-fr-0008]
    8. A method of manufacturing a retroreflective sheet, the method comprising:
    forming a first light condensing layer including a first bead arrangement layer and a plurality of beads, on a first carrier film;
    the formation of a colored part by sequential stratification of a light-transmitting layer, a colored layer, a first non-flammable layer, a first thermoplastic bonding layer, and a first protective film, on a surface of the first light-condensing layer;
    forming a second light condensing layer including a second bead arrangement layer, and a plurality of beads, on a second carrier film;
    forming a reflective part by sequential lamination of a reflective layer, a second non-flammable layer, a second thermoplastic bonding layer, and a second protective film, on a surface of the second light-condensing layer ;
    separating the reflective portion into a plurality of sections having a striped pattern shape with a width of a reflective area and removing the second protective film so that the second thermoplastic bonding layer is exposed;
    exposing the first thermoplastic bonding layer by removing the first protective film and in turn attaching a heat-resistant film to the first thermoplastic bonding layer; and exposing the first light-condensing layer by removing a first carrier film and the first bead arranging layer so that the first light-condensing layer is exposed, and thermal pressing the reflective portion onto the portion colored while the second thermoplastic bonding layer is exposed to a surface of the first layer condensing light at an interval from the colored area.
    [9" id="c-fr-0009]
    9. The method of claim 8, wherein the heat resistant film is formed of a released heat resistant sheet.
    [10" id="c-fr-0010]
    10. The method of claims, wherein the colored layer is formed of a polyurethane resin, an ethylene vinyl acetate copolymer (EVA), a polyester resin, a resin based on meta acrylic, or an acrylic copolymer.
    [11" id="c-fr-0011]
    The method of claim 8, wherein the colored layer selectively includes any of a fluorescent material or a light accumulating material, or includes a fluorescent material and a light accumulating material together.
    [12" id="c-fr-0012]
    12. The method of claims, wherein the light transmitting layer is formed of SiO 2 , indium tin oxide (ITO), tin oxide (TO), indium zinc oxide (IZO ), TiO 2 , ZnS, ZnO, AI2O 3 or CeO 2 .
    5
    [13" id="c-fr-0013]
    13. The method of claims, wherein the light transmitting layer is formed of a plurality of layers of two or more from SiO 2 , indium tin oxide (ITO), tin oxide (TO), oxide indium zinc (IZO), TiO 2 , ZnS, ZnO, AI2O 3 or CeO 2 .
    [14" id="c-fr-0014]
    14. The method of claims, wherein the layer
    10 transmitting light is deposited to have a thickness of 100 to 3000 Å.
    1/3 [FIGURE] [FIG. 1]
    - -L2
    --L1 [FIG. 2]
    GO.
    ÿ, 31C "J
    ÎJOXCC xxrxixcccf:
    'γΎ’γ’ν'γ' '; ί <ΐ <3'.Τ tixxxxî
    4 - ..,
    ΥΎΎΎΎ’ΥΎ'ΎΎΎ '7'
    Ξίΐ • 4X L -Ί3 _a
    WW® '
    - » j - 1 [FIG. 3A]
    2/3 / “v
    J JXXXCXOXOXO X <X OXX = xxx <
    [FIG
    3B]
    The [FIG. 3C] [FIG. 3D]
    ...... d -,. · [FIG. 3E]
    3/3
    Λ *
    he
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    同族专利:
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    CN107817545A|2018-03-20|
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    CN107817545B|2020-02-11|
    DE102017008277A1|2018-03-15|
    US20180074238A1|2018-03-15|
    US10281625B2|2019-05-07|
    KR101773532B1|2017-08-31|
    FR3055975B1|2021-12-10|
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    法律状态:
    2018-07-18| PLFP| Fee payment|Year of fee payment: 2 |
    2019-07-30| PLFP| Fee payment|Year of fee payment: 3 |
    2020-07-23| PLFP| Fee payment|Year of fee payment: 4 |
    2021-05-07| PLSC| Publication of the preliminary search report|Effective date: 20210507 |
    2021-09-29| PLFP| Fee payment|Year of fee payment: 5 |
    优先权:
    申请号 | 申请日 | 专利标题
    KR1020160117845A|KR101773532B1|2016-09-13|2016-09-13|Retroreflective sheet and fabricating method thereof|
    KR1020160117845|2016-09-13|
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