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    • 专利摘要:
    An imperfection-correcting cosmetic product that conceals wrinkles and pores and has good make-up compatibility at the time of application can be easily provided using a polyacrylate-based water-absorbing polymer having a water absorption capacity. specific water, but no water-soluble macromolecule having a thickening effect and commonly used in cosmetics. In other words, the present invention is directed to an imperfection-correcting cosmetic comprising a polyacrylate-based water-absorbing polymer that has an excellent effect of concealing wrinkles and pores, and said water-absorbing polymer based on Polyacrylate has an average size of swollen particles of 10 to 150 μm, an average dry particle size of 10 to 50 μm and a water absorption capacity of 5 to 50 g / g.
    公开号:FR3051671A1
    申请号:FR1754659
    申请日:2017-05-26
    公开日:2017-12-01
    发明作者:Rikako Mori；Shunsuke Yamaguchi；Takamasa SATONAKA
    申请人:Toagosei Co Ltd；Cosmos Technical Center Co Ltd；Nikko Chemicals Co Ltd；
    IPC主号:
    专利说明:

    COSMETICS PROPERTIES OF IMPERFECTIONS Field of invention
    The present invention relates to an imperfection-correcting cosmetic comprising a water-absorbing polymer which has an excellent effect of concealing wrinkles and pores.
    Technological background
    A lot of women have problems with wrinkles and pores and use makeup to hide them. The effect of makeup depends on its optical properties such as the concealment effect and the diffusion effect of the powders. Conventionally used techniques involving powders having a high refractive index such as titanium oxide have great concealing power but do not provide a natural result. In recent years, a technique of concealing wrinkles without artifice consists, for example, in incorporating methyl polysiloxane having a high degree of polymerization and a volatile oil solution and a translucent powder in an emulsion cosmetic to hide wrinkles (literature patents 1), but it hardly allows for a sufficient correction of wrinkles and pores. There is also a technique for rendering wrinkles and pores invisible by forming a continuous film containing a powder in a layer thereof with a film-forming agent so that the film has a specific surface roughness (patent literature 2). In particular, the silicone-based film-forming agents can remove wrinkles by stretching them, and can be included in makeup bases to allow the proper spreading of the makeup that will be applied to them. However, they have problems of poor fitness for use such as a sticky feeling or a feeling of stretching and restriction of muscle movement. In addition, there is a method of concealing skin imperfections by applying to the skin a cosmetic product to conceal imperfections comprising a water-absorbing polymer having a water content of less than a saturated quantization of water absorption and a binder, then by contacting the application site with another cosmetic comprising a water-soluble ingredient which can swell the water-absorbing polymer (Patent Literature 3). However, this method has a problem in that it is long and requires effort because of its use in two stages, and in that it requires a high content, ie 10% by weight or more. , water absorbing polymer.
    Patent literature
    Patent Literature 1: Japanese Patent Published Before Examination No. 2000-007551
    Patent Literature 2: Japanese Patent Published Before Examination No. 2002-179530
    Patent Literature 3: Japanese Patent Laid-Open No. 2004-210654 Summary of the Invention
    It is an object of the present invention to provide a cosmetic imperfection-correcting product which has an excellent effect of concealing wrinkles and pores and of correcting skin imperfections and which has good compatibility with makeup.
    The present inventors have discovered that an imperfection-correcting cosmetic product that conceals wrinkles and pores and has good make-up compatibility can be readily provided using a polyacrylate-based water-absorbing polymer having absorption of the specific water, and thus achieved the present invention.
    More specifically, the present invention relates to an imperfection-correcting cosmetic having an excellent effect of concealing wrinkles and pores, characterized in that it comprises a polyacrylate-based water-absorbing polymer having an average size of the swollen particles from 10 to 150 μm, an average size of the dry particles of 10 to 50 μm and a water absorption rate of 5 to 50 g / g.
    According to the present invention, an imperfection-correcting cosmetic which has an excellent effect of concealing wrinkles and pores and has good compatibility with a cosmetic can be provided.
    Detailed description of the invention
    The present invention will now be described in detail as follows.
    The polyacrylate-based water-absorbing polymer used in the present invention (referred to hereinafter as the polyacrylate-based water-absorbing polymer of the present invention) is characterized in that it has a medium size swollen particles of 10 to 150 μm, average dry particle size of 10 to 50 μm and a water absorption capacity of 5 to 50 g / g.
    The average size of the swollen particles and the average size of the dry particles in the present invention mean a median size based on the volume of the saturated polyacrylate-based water-absorbing polymer swollen with deionized water and a median size based on the volume of the water-absorbing polymer based on dried polyacrylate in n-heptane solvent in which 2% by weight of an emulsifier is dissolved, respectively, as measured by a device for measuring the particle size distribution of laser diffraction-diffusion type (e.g., Microtrac MT-3000, manufactured by NIKKISO CO., LTD.).
    The water absorption capacity of the polyacrylate-based water-absorbing polymer in the present invention is calculated with the following equation:
    Absorption capacity of water = [weight after water absorption (g) - dry weight (g)] / dry weight (g) in which the weight after water absorption is the weight after swelling with deionized water for at least 30 minutes; and the dry weight is the weight after drying at 150 ° C for 60 minutes in an airless drier.
    The average size of the swollen particles of the polyacrylate-based water-absorbing polymer of the present invention is 10 to 150 μm, preferably 10 to 100 μm, and more preferably 15 to 60 μm. As for the average size of the dry particles, if it is less than 10 μm or greater than 50 μm, the cosmetic tends to have a weak effect of correcting imperfections of wrinkles and pores, and can generate a bad feeling when use and insufficient compatibility with makeup. In view of the foregoing, the average size of the dry particles is preferably in the range of 10 to 40 μm, more preferably in the range of 10 to 30 μm, and even more preferably in the range of 10 to 25 μm. pm.
    When the water absorption rate of the polyacrylate-based water-absorbing polymer of the present invention is less than 5 g / g or greater than 50 g / g, the cosmetic tends to have a weak corrective effect. imperfections of wrinkles and pores, and may also have poor compatibility with makeup. Given the foregoing, the water absorption rate is preferably in the range of 10 to 30 g / g, and more preferably in the range of 15 to 30 g / g.
    The polyacrylate-based water-absorbing polymer of the present invention is used in the neutralized form, and there is no limit to the neutralizing agent. The degree of neutralization may be 10 to 100 mol%, preferably 30 to 90 mol%, and more preferably 40 to 80 mol%.
    The polyacrylate-based water-absorbing polymer of the present invention comprises a polyacrylate-based water-absorbing polymer selected from ammonium polyacrylate, potassium polyacrylate, and sodium polyacrylate.
    The form of the polyacrylate-based water-absorbent polymer of the present invention is not particularly limited, but may be of an ellipsoidal or spherical shape, or of an irregular shape. From the point of view of good swelling ability with water, an ellipsoid or spherical polymer is preferred.
    Polyacrylate polymers are generally classified into thickening polymers and water absorbing polymers. The thickening polymers have solubility in solvents and extremely absorb water so that they exhibit a concentration-dependent thickening effect. The polyacrylate-based water-absorbing polymer of the present invention is a water-absorbing polymer. As water absorbing polymers, those used in sanitary materials such as disposable diapers and sanitary napkins are well co-usable, and the water-absorbing polymers used in these applications generally have a high absorption capacity of water from 50 to 1000 g / g. In contrast, the polyacrylate-based water-absorbing polymer of the present invention has a relatively low water-absorbing capacity of 5 to 50 g / g.
    Examples of the polyacrylate-based water-absorbing polymer of the present invention include cross-linked copolymers derived from monomer (s) (of a monomer mixture) comprising a hydrophilic vinyl monomer such as (Meth) acrylic acid or its salts Examples of hydrophilic vinyl monomer include: vinyl monomers having carboxyl group or alkali-neutralized (partially) products thereof such as crotonic acid, itaconic acid , maleic acid, fumaric acid, monobutyl itaconate, monobutyl maleate, cyclohexane dicarboxylic acid in addition to (meth) acrylic acid, vinyl monomers having an amino group or products thereof. (partially) neutralized with an acid, or products thereof (partially) quaternized such as N, N-dimethylaminoethyl (meth) acrylate, N, N-diethylaminoethyl (meth) acrylate, (meth) N, N-dimethylaminoacrylate n-propyl, N, N-dimethylaminopropyl (meth) acrylamide; N-vinylpyrrolidone, acryloyl morpholine; vinyl monomers having a phosphoric acid group or alkali-neutralized (partially) products thereof such as phosphooxyethyl methacrylate, phosphooxypropyl acid methacrylate, 3-chloro-2-acid phosphooxypropyl methacrylate; vinyl monomers having a sulfonic or phosphonic acid group or alkali-neutralized (partially) alkaline products thereof such as 2- (meth) acrylamide-2-methylpropanesulfonic acid, 2-sulfoethyl (meth) acrylate 2- (meth) acryloyl ethanesulfonic acid, allylsulfonic acid, styrenesulfonic acid, vinylsulfonic acid, allylphosphonic acid, vinylphosphonic acid; nonionic hydrophilic monomers such as (meth) acrylamide, N, N-dimethylacrylamide, N-isopropyl acrylamide, N-methylol (meth) acrylamide, N-alkoxymethyl (meth) acrylamide, (meth) acrylonitrile, hydroxyethyl (meth) acrylate, hydroxypropyl (meth) acrylate, methoxypolyethylene glycol mono (meth) acrylate, and one or more thereof may be used. (Meth) acrylic acid means acrylic and / or methacrylic acid. Other compounds having the prefix (meth) as above mentioned will also be understood in a similar manner.
    Of these monomers, vinyl monomers having a carboxyl group and vinyl monomers having a sulfonic acid group and alkaline (partially) neutralized products thereof are preferred in that they exhibit excellent polymerization ability. and provide polyacrylate-based water-absorbent polymers which have high hydrophilicity, excellent water absorption and water retention performance, and the like. Monomers of (meth) acrylic acid, 2- (meth) acrylamide-2-methylpropanesulfonic acid, are particularly preferred. Thus, the polyacrylate-based water-absorbing polymer of the present invention is im polymer, more preferably a cross-linked polymer, comprising as monomer (s) constituting a selected monomer (s) ( s) among acrylic acid, methacrylic acid, 2-acrylamido-2-methylpropanesulfonic acid, 2-methacrylamido-2-methylpropanesulfonic acid and their salts. The polyacrylate-based water-absorbing polymer of the present invention preferably comprises as monomer (s) constituting a monomer (s) selected from acrylic acid, methacrylic acid, and the like. and their salts.
    From the standpoint of water absorption performance, the amount of the hydrophilic vinyl monomer used is preferably 50% by weight or more, more preferably 70% or more, and even more preferably 90% or more, based on the total amount of the monomers that make up the polyacrylate-based water-absorbing polymer of the present invention (excluding the crosslinking agent as mentioned above). The upper limit of the amount of hydrophilic vinyl monomer used is 100% by weight.
    As a process for crosslinking the copolymer, any known method can be used, but generally a method using a crosslinking agent has been used. As the crosslinking agent, for example, a polyfunctional vinyl monomer having two radical-polymerizable groups may be copolymerized with the hydrophilic vinyl monomer, or a polyfunctional compound having two or more groups that can be reacted with a The functional group of the hydrophilic vinyl monomer can be used.
    Examples of the polyfunctional vinyl monomer include di or tri (meth) acrylates of polyols such as polyethylene glycol di (meth) acrylate, propylene glycol di (meth) acrylate, glycerol tri (meth) acrylate, trimethylolpropane tri (meth) acrylate, trimethylolpropane tri (meth) acrylate modified with ethylene oxide, bisamides such as methylenebis (meth) acrylamide, divinylbenzene and allyl (meth) acrylate, and a or more of these may be used.
    Examples of the polyfunctional compound include polyfunctional epoxy compounds such as ethylene glycol diglycidyl ether and polyethylene glycol diglycidyl ether, polyfunctional amine compounds such as hexamethylenediamine and N, N'-diciimamylidene-1,6-hexanediamine and polyfunctional isocyanate compounds such as hexamethylene diisocyanate, dimethyl diphenylene diisocyanate and isophorone diisocyanate, and one or more thereof may be used.
    The amount of the crosslinking agent used may vary depending on the type of crosslinking agent used and the like, but is preferably from 0.1 to 30 mol%, and more preferably from 0.5 to 10% by weight. in moles, based on the total amount of the monomers that make up the polyacrylate-based water-absorbing polymer of the present invention excluding the crosslinking agent. Insofar as the amount of crosslinking agent used is in the range of 0.1 to 30 mol%, the water absorption capacity can be adjusted within a suitable range.
    The process for producing the polyacrylate-based water-absorbing polymer of the present invention is not particularly limited, but a polymerization process such as solution polymerization, suspension polymerization, reverse phase suspension polymerization, dispersion polymerization, and bulk polymerization can be used. Suspension polymerization, reverse phase polymerization and dispersion polymerization are preferred in that they readily provide the polymer in a spherical form, and reverse phase suspension polymerization is particularly preferred in that it can produce easily and stably the water-absorbing polymer based on polyacrylate. Those skilled in the art can adjust the average particle size and water absorption capacity of the polyacrylate-based water-absorbing polymer of the present invention as appropriate by regulating the type and amount of monomers used. the type and amount of dispersion stabilizer used at the time of polymerization, and polymerization conditions such as polymerization temperature and stirring conditions, and the like. For example, in the case of reverse phase suspension polymerization, generally, the particle size of the resulting polymer is lower under higher agitation conditions and the particle size of the resulting polymer increases under lower agitation conditions. In addition, when the degree of crosslinking of the polyacrylate-based water-absorbing polymer is increased, the water absorption capacity decreases, whereas in the case of a polymer having a lower degree of cross-linking, the capacity of the water-absorbing polymer is reduced. water absorption increases. Specific examples of the polyacrylate-based water-absorbent polymer of the present invention include Aron NT series absorbent resin fine particles (manufactured by Toagosei Co., Ltd.).
    The polyacrylate-based water-absorbing polymer of the present invention can be used as an imperfection-correcting cosmetic in the form of a formulation comprising the polymer alone or in combination with an ingredient (s) to be incorporated. in a cosmetic or by adding the cosmetic ingredient (s) to the polymer. In the imperfection-correcting cosmetic of the present invention, the polyacrylate-based water-absorbing polymer content of the present invention is preferably from 0.1 to 10% by weight, and more preferably from 0.1 to 10% by weight. at 9.0% by weight. If this content is less than 0.1% by weight, the cosmetic may not be able to exert a sufficient effect of concealing wrinkles and pores. If the content is greater than 10% by weight, the cosmetic may lose its fluidity by excessive water absorption, resulting in an unstable formulation.
    In addition, the imperfection-correcting cosmetic comprising a polyacrylate-based water-absorbing polymer which has an excellent effect of concealing wrinkles and pores according to the present invention may comprise any one or more ingredients suitably selected from ingredients. incorporated into conventional cosmetics, depending on the type of cosmetics provided. Examples of this ingredient (of these ingredients) include, but are not limited to, hydrocarbon oils such as liquid paraffin and petrolatum, vegetable oils and fats, waxes, synthetic ester oils, silicone components in the oily phase, higher alcohols, lower alcohols, fatty acids, thickeners, UV absorbers, powders, inorganic / organic pigments, color materials, different surfactants, polyhydric alcohols, saccharides, macromolecular compounds, physiologically active ingredients, transdermal absorption promoting agents, solvents, antioxidants, fragrances and various additives. Specifically, the imperfection-correcting cosmetic may include inorganic powders such as titanium oxide, mica, hectorite, colcotar, montmorillonite, kaolin, smectite, talc, perlite, or oxide. iron, for example yellow iron oxide, red iron oxide or black iron oxide. Alternatively, the formulation comprising the polymer alone may be used in combination with a composition comprising a cosmetic ingredient (cosmetic ingredients), for example, by applying the formulation and then applying a cosmetic composition comprising an inorganic powder.
    Examples of the imperfection-correcting cosmetic of the present invention include, but are not limited to, a basic skin care product such as an imperfection-correcting skin lotion, an imperfection-correcting serum, and an anti-corrective emulsion. imperfections, a blemish-correcting make-up base, and makeup, such as an imperfections makeup foundation.
    The present invention is based on the finding that the polyacrylate-based water-absorbing polymer having an average particle size of 10 to 150 μm inflated particles, an average dry particle size of 10 to 50 μm and an absorption capacity of 10 to 50 μm. water from 5 to 50 g / g has an excellent effect of concealing cutaneous imperfections such as wrinkles and pores. Accordingly, the present invention relates to a polyacrylate-based water-absorbing polymer for imperfection-correcting cosmetic which has an average particle size of 10 to 150 microns inflated, 10 to 50 micron average particle size, and a water absorption capacity of 5 to 50 g / g. The present invention also relates to a skin irregularity corrector or a cosmetic irregularity corrector comprising a polyacrylate-based water-absorbing polymer having an average particle size of 10 to 150 microns inflated, an average particle size from 10 to 50 μm and a water absorption rate of 5 to 50 g / g. In addition, the present invention relates to an imperfection-correcting cosmetic comprising this irregularity correcting agent.
    The present invention is also based on the discovery that the above-mentioned predetermined polyacrylate-based water-absorbent polymer has a low makeup compatibility which further has an excellent effect of concealing skin imperfections such as wrinkles and pores. . Accordingly, the present invention relates to a makeup base comprising a polyacrylate-based water-absorbent polymer which has a median size of the swollen particles of 10 to 150 μm, an average particle size of 10 to 50 μm and a capacity of 10 to 50 μm. water absorption of 5 to 50 g / g. In addition, the present invention relates to a cosmetic method for correcting imperfections comprising applying this makeup base to irregular parts of the skin and then applying another cosmetic to these parts.
    Specific examples and preferred embodiments of the polyacrylate-based water-absorbing polymer used in the present invention are as described above.
    Examples
    The present invention will be specifically described with reference to the following examples, but is not intended to be limited thereto. The contents are expressed in% by mass.
    Production Example 1: Polymer A Production
    For the polymerization, a reactor equipped with a stirring mechanism consisting of a rotary blade-type stirring blade and two vertical baffles, and a thermometer, a reflux condenser and a stirrer were used. a nitrogen inlet tube. This two-tube nitrogen inlet tube was connected out of the reactor, one of which was used to supply nitrogen, and the other was used to supply polymerization catalyst via a pump. In addition, the nitrogen inlet tube was connected to a wall surface of the reactor substantially at the same height as the upper end of the stirring blade.
    2.94 parts by weight of sorbitan monooleate (trade name "RHEODOL AO-10 V" manufactured by Kao Corporation) and 375.0 parts by weight of n-heptane as a polymerization solvent in the reactor were charged, then mixed with stirring while maintaining the temperature of the solution at 40 ° C to prepare the oil phase. The oil phase was allowed to stir at 40 ° C for 30 minutes and then cooled to 15 ° C. On the other hand, 100.0 parts by weight of acrylic acid, 9.7 parts by weight of polyethylene glycol diacrylate (trade name "ARONIX M-243", average molecular weight 425, by Toagosei Co., Ltd.), 0.02 parts by weight of p-methoxyphenol and 82.4 parts by weight of deionized water, then the mixture was allowed to stir to dissolve it uniformly. Further, while cooling the mixture to maintain the temperature at 40 ° C or lower, 73.1 parts by weight of a 48% aqueous solution of potassium hydroxide was gradually added to neutralize it (degree of neutralization: 45 mol%) to prepare a liquid monomer mixture.
    After allowing the stirrer speed to rotate at 900 rpm, the liquid monomer mixture prepared in the reactor was charged to prepare a dispersion having the liquid monomer mixture dispersed in the oily phase. At this time, the internal temperature of the reactor was maintained at 15 ° C. Nitrogen was blown into the dispersion to remove oxygen in the reactor. One hour and 30 minutes after loading the monomer mixture, an aqueous solution containing 0.09 parts by weight of sodium hydrosulfite and 3.0 parts by weight of sodium hydrosulfite was added thereto via an inlet provided above the reactor. permuted water body. Three minutes later, a solution obtained by diluting 0.04 parts by weight of an 80% solution of cumene hydroperoxide (trade name ") was supplied via a nitrogen inlet tube via a pump. Percumyl H80, manufactured by NOF CORPORATION) with 3.0 parts by weight of n-heptane. The solution was supplied in 30 seconds. Immediately after the start of the supply, the internal temperature of the reactor increased, confirming that the polymerization had begun. The increase in internal temperature peaked in about 40 seconds, at which time the temperature was 61.9 ° C. Then, the reaction liquid was cooled to 15 ° C to obtain a polymer A dispersion.
    Each of the raw materials such as the monomers, the polymerization solvent, and the polymerization initiator is a commercially available industrial product and has been used as received without treatment such as purification.
    The polymer A dispersion was then heated to allow the water contained in the particles and heptane to undergo azeotropic distillation and thus dehydrated at a dehydration rate of 95%, and then filtered to remove a heptane phase. Heptane was added to the same weight as the filtrate, stirred and filtered. This procedure was repeated twice, and the solvent was volatilized with a forced air dryer to obtain a dry powder of Polymer A. In addition, observation under a scanning electron microscope confirmed that Polymer A was present. in the form of spherical particles.
    Examples of production 2 to 10: production of polymers B at J
    The same procedures as in Production Example 1 were carried out to obtain dry powders of polymers B to J except that the swollen particle size was adjusted by controlling the number of stirring rotations and that Γοη adjusted the water absorption capacity by modifieation of the number of crosslinking agent parts, Aronix M-243. However, as the neutralizing agent, an aqueous solution of sodium hydroxide was used to modify the type of salt as appropriate. Further, scanning electron microscope observation confirmed that polymers B to J were in the form of spherical particles.
    Example 1
    The average particle size and the water absorption capacity of the polyacrylate-based water-absorbing polymer were measured. (1) Method for measuring the average particle size
    Preparation of a Sample for Measuring the Average Size of the Inflated Particles: The polyacrylate water-absorbing polymer was swelled with deionized water for 30 minutes or more and used as a sample measurement.
    Preparation of a sample for measuring the average size of the dry particles: A polyacrylate water-absorbing polymer was dispersed for dehydration in n-heptane having 2% by weight of tetraglycerol polyricinoleate (product name: CRS -75, manufactured by SAKAMOTO YAKUHIN KOGYO CO., LTD.) As an emulsifier dissolved therein, and then used as a measurement sample.
    Mean particle size measurement: The average size was measured on the basis of the volume of the prepared swab and dry measuring samples with a diffraction-diffusion type particle size distribution device. laser (Microtrac MT-3000, manufactured by NIKKISO CO., LTD.). The average size of the swollen particles was measured using deionized water (refractive index 1.333) as the medium, and the average dry particle size was measured using n-hexane having 2% by weight of CRS. -75 (indie refraction 1.39) dissolved therein. The refractive index of the polyacrylate-based water-absorbing polymer used was 1.53. (2) Method for measuring the water absorption capacity
    The water absorption capacity was calculated with the following equation:
    Absorption capacity of the water = [weight of the sample of measurement 30 minutes after the beginning of the absorption of the water (g) - dry weight of the sample of measurement (g)] / dry weight of the measurement sample (g).
    In order to measure the water absorption capacity, the water-absorbing polymer was sufficiently swollen as a measuring sample by adding water permuted thereto, dispersed in the water, and then dissolved in water. water for 30 minutes or more to bring the water-absorbing polymer into a swollen state, saturated with water, and then weighed. For dry weight measurement, the measurement sample was weighed and dried at 150 ° C for 60 minutes in an airless dryer, and then the residue was weighed. The procedure was performed according to JIS K 0067-1992 (Test Procedures for Loss and Residues of Chemicals). (3) Measurement results
    The results of the measurements are presented in Table 1.
    Table 1
    Example 2
    Formulations comprising polymers A to J of Example 1 were prepared and their effect of correction of wrinkle and pore imperfections and compatibility with makeup evaluated. (1) Process for the preparation of formulations
    Each polyacrylate-based water-absorbing polymer and purified water were weighed at the ratio proposed in Table 2, and then mixed by stirring at room temperature to prepare the formulation. (2) Sensory test of the effect of the correction of imperfections of wrinkles and pores
    Using five female subjects, the effect of the correction of wrinkle and pore imperfections was evaluated when applying each formulation of Table 2 to the face according to the following scores, and the mean was determined. scores. 3; imperfections of wrinkles and pores are corrected. 2: imperfections of wrinkles and pores are slightly corrected. 1: the imperfections of wrinkles and pores are not corrected. (3) Image analysis of the effect of the correction of imperfections of wrinkles
    Each formulation of Table 2 was applied to the faces of five female subjects, and the change in the number of wrinkles before and after application was measured using the VISIA Evolution Imaging Device. The number of wrinkles was calculated based on the image analysis. Before the measurement, the subjects' faces were washed with the designated facial cleanser and wiped off to remove any moisture. (4) Effect of pore imperfection correction
    Each formulation in Table 2 was applied to the faces of five female subjects, and the number of pores before and after application was measured using the VISIA Evolution Imaging Device. The number of pores was calculated based on the image analysis. Before the measurement, the subjects' faces were washed with the designated facial cleanser and wiped off to remove any moisture. (5) Evaluation of sensation during use
    Using five female subjects, sensation was assessed at the time of application based on the following scores, and the average score was determined. 3: good 2: slightly good 1: bad (6) Method of assessing compatibility with make-up
    Using five female subjects, the compatibility effect of each formulation of Table 2 was evaluated with a liquid foundation when the formulation was applied to the face before the liquid foundation was applied according to the following scores, and the average score was determined. 3; compatible 2; slightly compatible 1: incompatible (7) Results of Evaluation
    The results of the evaluation are presented in Table 2.
    Table 2
    1) Relative value of the number of wrinkles when the number of wrinkles before the application of each formulation is taken as 100% 2) Relative value of the number of pores when the number of pores before the application of each formulation is taken as 100%
    Applied examples comprising the polyacrylate polymer according to the present invention are provided in the list below, but the present invention is not intended to be limited thereto. All the cosmetics of Examples 3 to 6 were also evaluated in the same manner as in Example 2, and excellent effects were confirmed.
    Example 3 Imperfection corrective serum 1. Xanthan gum 0.4 (wt%) 2. Hydroxyethylcellulose 0.1 3. Polymer E 5.0 4. 1,3-butylene glycol 5.0 5. Purified water q.s. up to 100.0 6. Hydroxyproline q.s. 7. Purified water 5.0 8. Preservative q.s. 9. Ethanol 3.0
    Process of Preparation: Each of ingredients 1 to 5, 6 and 7, and 8 and 9 were dissolved at room temperature. While ingredients 1 to 5 are stirred, ingredients 6 and 7 and ingredients 8 and 9 are added thereto. When the uniform mixture is obtained, the preparation is complete.
    Example 4
    Imperfection-correcting emulsion 1. Sorbitan monostearate POE (20) 1.0 (% by mass) 2. Sorbitol tetraoleate POE (40) 1.5 3. Glyceryl monostearate, lipophilic 1.0 4. Stearic acid 0, 5. Behenyl alcohol 1.5 6. Cetyl palmitate 0.5 7. Squalane 5.0 8. Cetyl 2-ethyl hexanoate 5.0 9. Methyl polysiloxane 0.5 10. Preservative qs 11. Polymer A 6.0 12. 1,3-butylene glycol 7.0 13. Dipropylene glycol 4.0 14. Purified water q.s. up to 100.0
    Preparation process: Ingredients 1 to 10 and ingredients 11 to 14 were warmed and dissolved. While leaving ingredients 1 to 10 stirring with a homogenizer mixer, ingredients 11 to 14 were gradually added to emulsify. The mixture. The mixture was allowed to cool with paddle stirring, and the preparation was complete.
    Example 5
    Blemish correcting makeup base 1. NIKKOL NIKKOMULESE LC * "4.0 (wt%) 2. Cetearyl alcohol 1.0 3. Squalane 3.0 4. Phenyl trimethicone 5.0 5. Polypropylsilsesquioxane 2.0 6. ICP-545 1.0 7. Carbomer 0.15 8. Copolymer hydroxyethyl acrylate / sodium acryloyldimethyl taurate 0.3 9. Polymer D 0.1 10. Chelating agent qs 11. Preservative qs 12. Purified water qs up to at 100.0 13. Arginine 0.05 14. Purified water 3.0 15. 1,3-butylene glycol 4.0 16. Glycerin 1.0 17. Titanium oxide grade pigment qs 18. Iron oxide red qs 19 PLASTIC POWDER D-400 3.0 20. HV45 PM20 3.0 21. Ethanol 5.0 22. Purified water 5.0 NDCKOL NIKKOMULESE LC (manufactured by Nikko Chemicals Co, Ltd.): cetyl alcohol, stearyl alcohol, behenyl alcohol, phytosterols, glyceryl stearate, PEG-20 phytosterol, hydrogenated lecithin, caprylic / capric triglyceride KP-545 (manufactured by Shin-Etsu Chemical Co., Ltd.): Alkyl acrylate copolymer dimethicone, cyclopentasiloxane D-400 PLASTIC POWDER (manufactured by Nikko Chemicals Co, Ltd.): HDE trimethylol hexyllactone crosslinked copolymer, HV45 PM20 silica (manufactured by Kobo Products, Inc.): mica, polymethyl methacrylate, titanium oxide
    Preparation Process: Each of ingredients 7 to 12, 13 and 14, 15 to 20, and 21 and 22 were homogenized at room temperature. Each of ingredients 1 to 6 and ingredients 7 to 12 were warmed and then homogeneously mixed and allowed to stir. While stirring ingredients 7 to 12, ingredients 13 and 14 were added to mix them homogeneously. While stirring ingredients 7 to 14, ingredients 15 to 20 were added to mix them homogeneously. While leaving the ingredients 7 to 20 under stirring with a homogenizer mixer, ingredients 1 to 6 were gradually added to emulsify the mixture. The mixture was cooled with stirring, ingredients 21 and 22 were added thereto at 30 ° C to homogenize the mixture, and the preparation was complete.
    Example 6
    Imperfection emulsion-type foundation 1. NIKKOL NIKKOMULESE WO * 5.0 (% by weight) 2. NIKKOL SILBLEND-91 2.5 3. KSG-15 2.0 4. Cyclopentasiloxane 20.0 5. Dimethicone (6 mPa-s) 2.5 6. Diphenylsiloxy phenyl trimethicone 2.5 7. KP-545 1.0 8. Pentaerythrityl tetraethylhexanoate 2.0 9. Diisostearyl malate 1.0 10. Titanium oxide, siliconized pigment grade 6, 7 11. Siliconized red iron oxide qs 12. Siliconized yellow iron oxide q.s. 13. Siliconized black iron oxide q.s. 14. Polymer B 0.2 15. Glycerin 8.0 16. 1,3-butylene glycol 3.0 17. sodium chloride 0.5 18. Ethanol 3.0 19. Chelating agent q.s. 20. Conservative q.s. 21. Purified water q.s. up to 100.0 NIKKOL NIKKOMULESE WO (manufactured by Nikko Chemicals Co, Ltd.): cyclopentasiloxane, PEG-10 dimethicone, NIKKOL SILBLEND-91 disteandimonium hectorite (manufactured by Nikko Chemicals Co, Ltd.): cyclomethicone, dimethicone, polymer crosslinked dimethicone / vinyl dimethicone KSG-15 (manufactured by Shin-Etsu Chemical Co., Ltd.): cyclopentasiloxane, crosslinked dimethicone / vinyl dimethicone polymer KP-545 (manufactured by Shin-Etsu Chemical Co., Ltd.): Copolymer acrylate Alkyl / dimethicone, cyclopentasiloxane (Process of preparation) The ingredients 1 to 13 were left stirring with a homogenizer mixer to disperse them, ingredients 14 to 21 were gradually added to emulsify the mixture, and the preparation was finished.
    Industrial applicability
    The present invention relates to an imperfection-correcting cosmetic which conceals wrinkles and pores and has good compatibility with makeup at the time of application.
    权利要求:
    Claims (15)
    [1" id="c-fr-0001]
    A polyacrylate-based water-absorbing polymer for an imperfection-enhancing cosmetic, wherein the polymer has an average size of the swollen particles of 10 to 150 μm after swelling with deionized water for 30 minutes or more, ime medium size of the dry particles from 10 to 50 μm, as measured by laser diffractometry, and xme water absorption capacity of 5 to 50 g / g, the water absorption capacity being calculated with the following equation: Absorption capacity of water = [weight after water absorption (g) - dry weight (g)] / dry weight (g) in which weight after absorption of water is the swollen weight with deionized water for at least 30 minutes, and the dry weight is the weight after drying at 150 ° C for 60 minutes in an airless dryer.
    [2" id="c-fr-0002]
    The polyacrylate-based water-absorbing polymer for an imperfection-correcting cosmetic according to claim 1, wherein the average size of the dry particles is from 10 to 40 μm.
    [3" id="c-fr-0003]
    3. The polyacrylate-based water-absorbing polymer for an imperfection-corrector cosmetic according to claim 1, wherein the average size of the dry particles is 10 to 30 μm.
    [4" id="c-fr-0004]
    The polyacrylate-based water-absorbing polymer for an imperfection-correcting cosmetic according to claim 1, wherein the average size of the dry particles is from 10 to 25 μm.
    [5" id="c-fr-0005]
    A polyacrylate-based water-absorbing polymer for an imperfection eosmetic according to claim 1, wherein the average size of the swollen particles is 10 to 100 μm.
    [6" id="c-fr-0006]
    6. The imperfection-correcting cosmetic xm polyacrylate-based water-absorbing polymer according to claim 1, wherein the average size of the swollen particles is 15 to 50 μm.
    [7" id="c-fr-0007]
    The polyacrylate-based water-absorbing polymer for an imperfection-correcting cosmetic according to claim 1, wherein the water absorption capacity is 10 to 30 g / g.
    [8" id="c-fr-0008]
    The polyacrylate-based water-absorbing polymer for an imperfection-correcting cosmetic according to claim 1, wherein the water absorption capacity is 15 to 30 g / g.
    [9" id="c-fr-0009]
    The polyacrylate-based water-absorbing polymer for an imperfection-correcting cosmetic according to claim 1, wherein the polymer is spherical or ellipsoid.
    [10" id="c-fr-0010]
    An imperfection-correcting cosmetic, comprising the polyacrylate-based water-absorbing polymer of claim 1.
    [11" id="c-fr-0011]
    The imperfection-correcting cosmetic of claim 10 comprising from 0.1 to 10.0% by weight of the polyacrylate-based water-absorbing polymer.
    [12" id="c-fr-0012]
    The imperfection-correcting cosmetic of claim 10 or 11, wherein the polyacrylate-based water-absorbing polymer is a polyacrylate-based water-absorbing polymer selected from the group consisting of ammonium polyacrylate, polyacrylate of potassium and sodium polyacrylate.
    [13" id="c-fr-0013]
    The imperfection corrective cosmetic according to claim 10, further comprising an inorganic powder.
    [14" id="c-fr-0014]
    The imperfection-correcting cosmetic of claim 13, wherein the inorganic powder is selected from the group consisting of titanium oxide, mica, hectorite, colcotar, montmorillonite, kaolin, smectite, talc, perlite and iron oxide.
    [15" id="c-fr-0015]
    The polyacrylate-based water-absorbing polymer for an imperfection-correcting cosmetic according to claim 1, wherein the polymer is used in combination with a composition comprising a cosmetic ingredient / cosmetic ingredient.
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    同族专利:
    公开号 | 公开日
    JPWO2017204281A1|2019-03-28|
    US11052034B2|2021-07-06|
    EP3459978A4|2020-01-01|
    WO2017204281A1|2017-11-30|
    CN109219622B|2021-09-21|
    CN109219622A|2019-01-15|
    JP6957458B2|2021-11-02|
    FR3051671B1|2020-10-23|
    EP3459978A1|2019-03-27|
    US20190133915A1|2019-05-09|
    EP3459978B1|2021-11-10|
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    法律状态:
    2018-04-27| PLFP| Fee payment|Year of fee payment: 2 |
    2019-05-24| PLFP| Fee payment|Year of fee payment: 3 |
    2019-11-29| PLSC| Publication of the preliminary search report|Effective date: 20191129 |
    2020-04-28| PLFP| Fee payment|Year of fee payment: 4 |
    2021-04-22| PLFP| Fee payment|Year of fee payment: 5 |
    优先权:
    申请号 | 申请日 | 专利标题
    JP2016106166|2016-05-27|
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