• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    According to this method, the fumes to be purified (1) are admitted into a scrubber (100) by a vertical chimney (200) which opens substantially centrally in the bottom (101) of the scrubber. The fumes circulate upwards inside the scrubber and, so that the velocity profile of these fumes is as flat as possible, they successively meet: - a protection device (300), which protects the downstream outlet (201 ) of the chimney against the introduction of liquid while maintaining the flow of fumes, - a spraying device (500), which projects a first washing liquid (3), in the form of veils of liquid, from substantially a geometric axis central (Z100) of the washer to the peripheral wall (102) of the washer, then - a dispensing device (600), which distributes a second washing liquid (4) in the form of rain falling downwards in a free volume (V100) of the washer, arranged between the spray device and the dispensing device.
    公开号:FR3050654A1
    申请号:FR1653724
    申请日:2016-04-27
    公开日:2017-11-03
    发明作者:Bernard Siret；Frank Tabaries
    申请人:LAB SA；
    IPC主号:
    专利说明:

    Process and installation for wet scrubbing exhaust fumes from an engine of a marine vessel
    The present invention relates to a method and a plant for wet scrubbing the exhaust fumes of an engine of a marine vessel.
    Marine vessels, whether ships or other vessels, primarily use fuel oil as fuel for diesel engines propelling them. This fuel contains up to 5% by weight of sulfur, most often between 0.5 and 3.5% by weight. During the combustion process in engines, this sulfur is converted into sulfur dioxide (SO2). Therefore, the exhaust fumes from these engines are acidic.
    Current maritime regulations require, in certain areas, to limit the discharge of ships by the stack to an equivalent of 0.1% sulfur by weight in the fuel oil. In practice, the discharge limit value depends on the navigation zone: near the coast or in a port, sulfur dioxide emissions must be lower than in the open sea. It should be noted that even at the port, a passenger liner The cruise must continue to run its engines to provide on-board power, and potentially, emits sulfur dioxide. To comply with the regulations, it is therefore necessary for the ship to incorporate means to reduce sulfur dioxide emissions from its fumes before discharging them into the atmosphere. Several solutions are possible.
    The sulfur content of the fuel used can first be reduced, or even liquefied gas can be used, which immediately leads to a reduction of sulfur dioxide emissions. However, very low sulfur fuel oil or liquefied gas is expensive, so this approach is not economical.
    Another approach is to use a wet scrubber, in which is dispersed a neutralization reagent such as sodium hydroxide. However, the quantities of soda to be expected are important, since the flow of sulfur dioxide to be treated can reach 500 kg per hour and per washer for very large steamers. In addition to the price of soda, it must be planned for storage and take into account its very caustic and therefore dangerous nature.
    Also, exhaust smoke is more often operated with seawater. This technique, which is implemented by scrubbers using the natural alkalinity of seawater to neutralize sulfur dioxide, is known and controlled, especially for power plants located on the seafront. In practice, two technologies exist.
    A first technology is based on the implementation of scrubbers using a lining. This lining is either made of rings or internals, introduced loose in the tower of the washer, or provided with a structured character, that is to say that the lining has a pattern repeating structurally in space. In terms of transfer efficiency, i.e., the ability to capture sulfur dioxide back to the volume used in the scrubber, these packings are very good. However, two limitations are to be considered. On the one hand, the pressure drop induced by the packings can be important: in the case where the washers must be placed downstream of a diesel engine, it forces to use a fan to overcome this loss of load, which costs energy and an extra investment. On the other hand, the fumes from a diesel engine are very hot and, despite the presence of a quenching device, it is necessary to provide the case where, following a malfunction, very hot and uncooled fumes, for example at more than 200 ° C, enter the scrubber. Since a by-pass is not always possible, the washer and its lining must be able to withstand dry running at the very least, and therefore their constituents withstand temperatures above 200 ° C. This makes it necessary to select, for the washer and its lining, temperature-dependent materials. This being so, in the case of shipboard washers, the marine environment, which is rich in chloride, which is acidic and which is reducing, is highly corrosive so that the cost of the packing is substantially affected.
    The second technology using seawater to reduce the sulfur oxides contained in fumes, is widely used in power plants that produce energy on land: the second technology is to use empty scrubbers, in which the water sea is scattered. This dispersion can be carried out either in the form of a rain, as shown very schematically in FIG. 1, or in the form of veils of liquid, as taught in FR 1 231 173 and as shown very schematically in FIG.
    In the known situation of FIG. 1, fumes to be purified F are introduced into the bottom of a scrubber V via a chimney C centered on the bottom of the scrubber. At the top of the scrubber V, nozzles D dispense a washing liquid L in the form of rain falling downward, countercurrent flue F flowing upward inside the scrubber.
    In the known situation of FIG. 2, fumes to be purified F are also introduced into the bottom of a scrubber V via a chimney C centered on the bottom of the scrubber. In the center of the scrubber V, a sprayer P projects a washing liquid in the form of webs, from the region of a central geometric axis ZV of the scrubber V to the peripheral wall of this scrubber.
    The solutions of Figures 1 and 2 both have advantages. They are simple and, insofar as the washer V is empty, the pressure drop is low, compared to a solution using an internal lining the scrubber. In addition, they are economical, although, insofar as the transfer capacity is less than for a washer using a lining, the height of the washer V will be greater. Finally, since the washer V is essentially empty, there is no need to worry about the constituents of the packing, in particular their resistance to corrosion and temperature, as well as their fouling. However, the weakness of the pressure drop, which is an important advantage from the operating point of view, makes problematic the distribution of flue gases F inside the scrubber V. In fact, in the case of the installation of FIG. any instability, whether due to the movements of the vessel, a small distortion in the distribution of the washing liquid, for example due to the clogging of some of the nozzles D, or even to instabilities in the sense of chaos theory will cause the fumes to be treated F to concentrate on one side of the scrubber V while the washing liquid is discharged from the opposite side of the scrubber, as shown schematically in FIG. 1: the flue gases F then present, at inside the scrubber V, an asymmetrical speed profile and unbalanced, which is not necessarily stable over time, a pendulum effect may indeed occur for example at the discretion of the external movements of the scrubber. As for the case of the installation of FIG. 2, the fumes to be purified F go, by transfer of the amount of movement of the washing liquid towards these fumes F, gradually to deviate from the central axis ZV, concentrating against the peripheral wall of the washer V as shown schematically in Figure 2: the smoke velocity profile F then undergoes a distortion that makes it inhomogeneous. In both cases, despite the central introduction of the flue gases F at the bottom of the scrubber V, the heterogeneity of the flue velocity profile F, inside the scrubber V, is such that the ratio of liquid to gas is that is, the ratio of the amount of washing liquid to the amount of smoke present at a given location inside the washer V is inhomogeneous within the scrubber, resulting in a significant loss of efficiency for scrubbing F. fumes
    The object of the present invention is to provide an arrangement of a scrubber, which aims to remedy its disadvantages, on the basis of a clever and inexpensive implementation. For this purpose, the subject of the invention is a process for the wet cleaning of the exhaust fumes of an engine of a marine vessel, in which fumes to be purified are admitted into a scrubber by a vertical chimney which opens substantially centered in the bottom of the scrubber. and in which the fumes circulate upwards inside the scrubber and successively meet therewith: - a protective device, which protects the downstream outlet of the chimney against the introduction of liquid while maintaining the circulation of the fumes, - a spray device, which projects a first washing liquid, in the form of liquid webs, from substantially a central geometric axis of the scrubber to the peripheral wall of the scrubber, then - a dispensing device, which distributes a second scrubbing liquid in the form of rain falling downward in a free volume of the washer, provided between the spray device and the dispensing device. The invention also relates to a wet scrubber installation of the exhaust fumes of an engine of a marine vessel, which installation comprises: - a scrubber in the bottom of which emerges in a substantially centered way a vertical chimney d admission of the fumes to be purified in the scrubber, - a protection device, which is adapted to protect the downstream outlet of the chimney against the introduction of liquid while letting the fumes exit the chimney, - a spraying device, which is adapted to project a first washing liquid, in the form of liquid webs, from substantially a central geometric axis of the scrubber to the peripheral wall of the scrubber, and - a dispensing device, which is adapted to dispense a second scrubbing liquid. in the form of downward falling rain in a free volume of the scrubber, formed between the spraying device and the spraying device. tribution, the protective device, the spraying device and the dispensing device being arranged inside the washer, so that the fumes, coming out of the chimney and flowing upwards inside the scrubber, successively meet the protection device, the spraying device and then the dispensing device.
    Thanks to the invention, the fumes to be treated, which pass through the scrubber from bottom to top, have a velocity profile that is as flat as possible, thus ensuring a very efficient purification of these fumes by the first and second wash liquids dispersed in the scrubber. washer. In addition, the implementation of the invention remains economical, relying on facilities that individually are simple to install and operate.
    According to additional advantageous features of the method and the installation according to the invention, taken separately or in any technically possible combination: - before meeting the protective device, the fumes are rotated inside the washer in circulating through a rotating device; the cross section of the scrubber below the dispensing device consisting of a central part and a peripheral part having the same area, the distribution density of the second washing liquid on the said central part; that is, the flow of the second washing liquid which is distributed by the dispensing device into said central portion and which is brought back to the area of said central portion, is at most 0.9 times the distribution density of the second liquid of washing on said peripheral part, that is to say the flow of the second washing liquid which is distributed by the dispensing device in said peripheral part and which is brought back to the area of said peripheral part; the spraying device comprises a sprayer or several sprayers arranged in a staggered manner along the central axis of the scrubber, and the dispensing device comprises dispensers distributed over one or more stages; - The installation further comprises a rotation device, which is adapted to be traversed by the fumes exiting the chimney so as to rotate these fumes inside the washer before they meet the device. distribution; - The rotation device comprises smoke deflection vanes, which are distributed around the central axis of the washer and which are in particular provided in six to ten copies; the protective device consists of a Chinese hat, that is to say of a cone presenting a half-angle at the apex of at least 60 °; the protective device comprises a top cone and one or more coaxial and superposed conical truncated cones, which is or is coaxially surmounted by the summit cone, this cone and this or these truncated cones all having a half -angle at the top of at least 60 °; - The installation further comprises a mistletoe which is arranged inside the scrubber so as to be traversed by the flue gas after they have encountered the dispensing device. The invention will be better understood on reading the description which follows, given solely by way of example and with reference to the drawings, in which: FIGS. 1 and 2 are schematic views of purification plants which relate to the prior art and which have been described above; - Figure 3 is a schematic view of a purification plant according to the invention, implementing a purification process according to the invention; FIG. 4 is an elevational view of an embodiment of a device belonging to the installation of FIG. 3; - Figure 5 is an elevational view along the arrow V of Figure 4; FIG. 6 is a view similar to FIG. 4, illustrating an alternative embodiment of the device of FIG. 4; - Figure 7 is an elevational view along arrow VII of Figure 6; FIG. 8 is a detailed perspective view of another device belonging to the installation of FIG. 3; and - Figure 9 is a schematic section along the line IX-IX of Figure 3.
    In Figure 3 is shown an installation for purifying exhaust fumes 1 of a diesel engine propelling a marine vessel on which is embedded this installation. The fumes 1 contain sulfur oxides, in particular sulfur dioxide (SO2).
    At the level of the installation of FIG. 3, the fumes 1, which come from the exhaust outlet of the aforementioned engine and which may have undergone prior denitrification, are introduced into a desulphurization washer 100 by a fireplace 200.
    As shown schematically in Figure 3, the washer 100 is generally in the form of a tower which, in use, extends in length vertically. At its base, the washer 100 has a bottom 101 from which rises a peripheral wall 102 of the scrubber, ending in a top 103. The peripheral wall 102 of the scrubber 100 defines a central geometric axis ZI 00 which, when the scrubber 100 is in service, extends vertically.
    Note that the washer 100 is empty, in the sense that it lacks an internal lining, such as rings or internals mentioned in the introductory part of this document.
    The chimney 200, which is made for example in the form of a sheath or a similar duct, is arranged below the scrubber 100 and extends substantially vertically so as to open into the bottom 101 of the scrubber 100. The downstream end of the chimney 200 passes through the constituent wall of the bottom 101 in a centered manner on the central axis ZI 00 of the scrubber 100, so that the downstream outlet 201 of the chimney 200, which connects the remainder of the chimney to the bottom 101 of the scrubber 100, is substantially coaxial with the peripheral wall 102 of the scrubber. In use, the exhaust fumes are admitted by the chimney 200 into the bottom 101 of the scrubber 100, and then, once inside this scrubber, they circulate, from the bottom 101 of the latter, upwards, until at its summit 103 from where they are evacuated, in the form of purified fumes.
    This admission of the fumes 1 by the vertical stack 200 is advantageous for the installation of FIG. 3, embarked on a ship, since this arrangement takes up less space than a lateral introduction of the fumes into a washer, such a lateral introduction being common for washing columns of power plants on land.
    To give an order of magnitude, and without this being of a nature to limit the invention, the flue gas flow rate 1 is for example between 50 000 and 200 000 Nm% and the diameter of the inside of the peripheral wall 102 of the 100 is for example between 3 and 6 m.
    According to one of the characteristics of the invention, the washer 100 is internally equipped, at a lower part of its peripheral wall 102, with a protection device 300 whose function is to protect the outlet 201 of the stack 200 against the introduction of liquid inside this chimney, while letting the fumes 1 out of the chimney. In other words, the protection device 300 prevents any liquid falling or dripping from the region directly above the outlet 201 to enter the chimney 200 by gravity while allowing the fumes 1 coming out of this chimney to bypass the protection device for Spread inside the scrubber 100. The protective device 300 is of paramount importance, in the sense that, for safety reasons, a liquid introduction into the chimney 200, with a possible rise of liquid towards the diesel engine. where fumes 1 escape, can not be tolerated.
    In practice, various embodiments can be envisaged for the protection device 300. Fairly open embodiments are preferred, so as to limit the pressure drop at the level of the protection device 300. For this purpose, an embodiment of the device protection device 300, which is illustrated in Figures 4 and 5, consists of a Chinese hat 301, that is to say a cone, which has a half-angle at the apex of at least 60 ° and which, within the installation of Figure 3, is substantially centered on the axis ZI 00 of the washer 100. A more elaborate embodiment, which, compared to the Chinese hat 301, limits the flue gas flue 1 to the peripheral wall 102 of the scrubber 100, is shown in FIGS. 6 and 7: the protective device 300 then consists of an assembly 302 comprising a top cone 302.1 and two coaxial and superposed conical trunks 302.2 and 302.3, which are coa-surmounted xiale by the top cone 302.1, the cone elements 302.1, 302.2 and 302.3 all having a half-angle at the top of at least 60 °, all being substantially centered on the axis ZI 00 of the washer 100 within the installation of Figure 3. Of course. alternatively not shown, the number of truncated cones 302.2 and 302.3 can be reduced to one or, conversely, be greater than two.
    According to an optional and advantageous feature of the invention, the washer 100 is internally equipped, at the lower part of its peripheral wall 102, with a rotation device 400 which is designed to be traversed by the outgoing fumes 1. of the chimney 200, so as to rotate these fumes inside the scrubber 100 before they meet the protection device 300. The rotational device 400 is for example placed in the outlet 201 of the chimney 200, as shown schematically in Figure 3. Alternatively, the rotating device 400 caps the outlet 201 or is arranged a little downstream of this outlet 201.
    In practice, the embodiment of the rotation device 400 is not limiting of the invention. By way of example, and as indicated schematically in FIG. 3, the rotational device 400 comprises smoke deflection vanes 401, which are fixedly arranged within the rotational device 400, while being the where appropriate, carried by a central core 402, and which, in the installation of FIG. 3, are distributed in a substantially regular manner around the central axis ZI00 of the scrubber 100. These deflection vanes 401 are advantageously provided in FIG. six to ten copies. Figure 8 shows in more detail a corresponding embodiment of this rotating device 400. As a variant not shown, the rotating device 400 may be similar to those employed at the input of cyclonic separators. Whatever its embodiment, the rotating device 400 has the effect of imparting a swirling movement to the fumes 1 flowing through this device, by preventing the fumes 1 from concentrating inside the washer 100, on one side of this washer at the expense of the diametrically opposed side as in Figure 1.
    According to another characteristic of the invention, the washer 100 is internally equipped, at a current portion of its peripheral wall 102, with a spraying device 500 which makes it possible to spray a washing liquid 3, in the form of sails. of liquid, from substantially the central axis ZI 00 to the peripheral wall 102 of the washer 100. Because the spray device 500 is not punctual, the sails of the liquid 3 are projected by the spray device 500 from a zone which is not rigorously limited to the central axis ZI 00 of the washer 100, but from an area which is located in the immediate vicinity of this axis ZI 00, where appropriate including the latter. As indicated in FIG. 3, each web of the liquid 3, projected by the spraying device 500, forms with the axis ZI 00 an angle α whose value is advantageously between 50 ° and 70 °. In any case, when the installation of FIG. 3 is in operation, the fumes 1, which, after having met the protection device 300, circulate upwards inside the washer 100, pass through the sails of the liquid 3 , projected by the spraying device 500, thus making it possible to capture the sulfur oxides contained in these fumes, by transfer of these sulfur oxides into the washing liquid 3.
    The spray device 500 is thus used to provide a large amount of the washing liquid 3, without generating a lot of pressure drop. The spraying device 500 thus operates the quenching of the flue gases 1, that is to say the reduction of their temperature between the flue gas inlet temperature 1 in the scrubber 100, typically between 150 ° C. and 450 ° C. anda final temperature of thermodynamic equilibrium, typically between 20 ° C and 70 ° C, the value of this final temperature depending on the initial temperature and the water content of the fumes 1. In addition, in the current part of the washer 100 where the spray device 500 is located, the liquid-to-gas ratio has a high value which makes it possible to rapidly capture the sulfur oxides, in particular the sulfur dioxide, where their concentration is highest.
    In practice, the embodiment of the spraying device 500 is not limiting of the invention, this spraying device 500 being, in any case, arranged above the protection device 300. By way of example, as shown diagrammatically in FIG. 3, the spraying device 500 comprises sprayers 501 which belong to a technology known per se: each sprayer 501 is located substantially on the central axis ZI 00 of the scrubber 100 and these sprays 501 are arranged in a stepped manner along this axis ZI 00. The number of sprayer 501, in other words the number of spray stage of the spray device 500, depends on the purification rate to be ensured, as well as the sulfur oxide concentration of the fumes 1, this number being for example between 1 and 12.
    In relation to the order of magnitude mentioned above, the flow of the washing liquid 3 sprayed by each sprayer 501 is for example between 30 and 200 m 2 / h.
    According to another characteristic of the invention, the washer 100 is internally equipped, at an upper part of its peripheral wall 102, with a dispensing device 600, which is placed above the spraying device 500 and which allows to distribute a washing liquid 4 in the form of downward falling rain in a free volume VI00 formed inside the peripheral wall 102 of the scrubber 100, between the spraying device 500 and the dispensing device 600 In this free volume VI00, the fumes 1, which, after passing through the webs of the liquid 3, circulate upwards inside the scrubber 100, meet against the current the rain formed by the washing liquid 4, which which performs a complementary purification of these fumes by capturing in the liquid 4 of the sulfur oxides still present in the fumes.
    The embodiment of the dispensing device 600 is not limiting of the invention. By way of example, as indicated diagrammatically in FIG. 3, this dispensing device 600 comprises distributors 601 which are known per se and which are, for example, spray nozzles, distribution manifolds, projection heads, etc. Where appropriate, also as shown in FIG. 3, these distributors 601 are distributed over one or more, for example four, preferably two, stages succeeding one another vertically.
    In relation to the order of magnitude mentioned above, the flow of the washing liquid 4 distributed by each stage of the dispensing device 600 is about 200 m 2 / h.
    The respective compositions of the washing liquids 3 and 4 are not limiting of the invention. Each of these liquids 3 and 4 preferably comprises seawater, optionally added with an alkaline reagent. This being the case, one and / or the other of the washing liquids 3 and 4 may consist of a suspension of limestone, lime or a sodium solution. Moreover, according to a first operating possibility, the respective compositions of the washing liquids 3 and 4 are the same. According to an alternative operating possibility, the composition of the washing liquid 4 is not the same as that of the washing liquid 3: in particular, the washing liquid 4 is for example composed of fresh sea water, with or without addition of an alkaline reagent, while the washing liquid 3 may be a recirculated liquid, in particular partially depleted seawater. In any case, it is understood that the total quantity of the washing liquors 3 and 4, which are respectively projected by the spraying device 500 and dispersed by the dispensing device 600, depends on the flow, for example in kg / h, of sulfur oxides in fumes 1.
    According to an optional and advantageous feature of the invention, the washer 100 is internally equipped, at the level of the upper end of its peripheral wall 102, with a mistletoe 700 which, in a manner known per se, makes it possible to retain the droplets of liquid which, in the absence of this stripper, would be entrained outside the scrubber 100, in the purified fumes 2. The stripper 700 is located above the dispensing device 600, so as, in use, to be crossed by the fumes 1 which, after having met the dispensing device 600, flow upwards inside the washer 100.
    The embodiment of the flyer 700 is not limiting of the invention. For example, the mist separator 700 consists of a herringbone basket. The purification plant of FIG. 3 is particularly effective for purifying the fumes 1 by stabilizing the flow of these fumes inside the scrubber 100, under the combined effect of the washing liquid sails 3, projected by the spraying device 500, and the rain of the washing liquid 4, distributed by the dispensing device 600, in conjunction with the vertical vertical introduction of the fumes 1 into the bottom 101 of the scrubber via the chimney 200. , the profile of the flue gas velocity 1, which is necessarily very inhomogeneous just downstream of the protection device 300, is progressively and rapidly re-homogenized under the combined action of the spraying device 500 and the dispensing device 600. Advantageously, the rotation of the fumes 1, by the rotational device 400, further stabilizes the flue gas flow 1 inside the scrubber 100, in integer in particular, reducing any smoke oscillation instability 1 between two diametrically opposite zones of the washer 100. As an optional and advantageous arrangement, the dispensing device 600 is designed so that the distribution density of the washing liquid 4 is less important. in the center of the scrubber on the outskirts of this scrubber. In practice, this arrangement is based on a dedicated choice and arrangement of the distributors 601 of the distribution device 601: the term "dedicated choice" means that the distributors 600 are not necessarily all identical, and the term "dedicated arrangement" means that the Location of distributors 601 is not necessarily homogeneous. In other words, the type and number of distributors 601 per square meter may be variable over the cross section of the scrubber 100.
    To better understand this aspect, Figure 9 shows the fictitious distribution of a cross section of the washer 100, at its free volume V100, in two parts, namely a central portion S100.1, crossed by the central axis Z100 of the washer, and a peripheral part SI 00.2 running around the central part SI00.1, the respective areas of the central part SI 00.1 and the peripheral part S100.2 being equal to one another: the density of dispensing the washing liquid 4 on the central part SI 00.1, that is to say the flow of the washing liquid 4 which is distributed by the dispensing device 600 in this central part SI00.1 and which is brought back to the area of this central portion SI 00.1, for example expressed in m ^ / m ^ / h, is at most 0.9 times the distribution density of the washing liquid 4 on the peripheral portion SI00.2, that is to say say the flow of the washing liquid 4 which is distributed by the dispensing device 600 in this peripheral part SI 00.2 and which is brought back to the area of this peripheral part SI 00.2, expressed in the same unit.
    More drops of rain of the washing liquid 4 thus fall in the portion of the volume V100, whose section corresponds to the peripheral part S 100.2, than in the rest of the volume VI00, that is to say that in the portion of this volume whose section corresponds to the central part SI 00.1. The liquid 4 distributed in the portion of the volume VI00 associated with the peripheral portion SI00.2 thus creates a greater friction with respect to the fumes 1 flowing upwards in this portion of the volume VI00, forcing a rebalancing vis-à-vis the remainder of the volume VI00 and thus compensating, at least partially, the effect on the fumes 1 of the spraying device 500 and the protection device 300.
    In practice, depending on the operating speed of the installation, that is to say according to the flow of fumes 1, their composition and their temperature, it is possible to adjust, manually or automatically, the amounts of the washing liquid 4 distributed respectively on the central part SI00.1 and on the peripheral part S100.2.
    This restores an overall profile for the liquid-to-gas ratio inside the scrubber 100, which is more favorable to the purification of flue gases 1.
    Example: The invention has been tested with the following specificities. The installation of FIG. 3 processes 105,000 Nm.sup.3 / h of exhaust fumes 1, admitted via the stack 2 into the bottom 101 of the scrubber 100 at a temperature of 390.degree. The washer 100 has, at its peripheral wall 102, an inside diameter of 3200 mm and a total height of about 10 m. The chimney 200 has an inside diameter of 1800 mm. The rotation device 400 comprises eight deflection vanes 401. The protection device 300 is in the form of the Chinese cap 301 of FIGS. 4 and 5. Four tiered sprayers 501 each project 80 m% of the washing liquid 3. One stage distributor 601 distributes 200 m% of the washing liquid 4. The stripper 700 is herringbone.
    The implementation of this example makes it possible to note the rapid homogenization of the smoke velocity profile 1 inside the scrubber 100, this profile being very inhomogeneous just downstream of the protection device 300 while it is substantially flat at free volume level VI00.
    权利要求:
    Claims (10)
    [1" id="c-fr-0001]
    1. - Process for the wet scrubbing of exhaust fumes from an engine of a marine vessel, in which fumes to be purified (1) are admitted into a scrubber (100) via a vertical chimney (200) which opens substantially centrally in the bottom (101) of the scrubber, and wherein the fumes (1) flow upwards inside the scrubber (100) and successively meet therewith: - a protection device (300), which protects the downstream outlet (201) of the stack (200) against the introduction of liquid while maintaining the flow of fumes (1), - a spraying device (500), which projects a first washing liquid (3), in the form of liquid webs, from substantially a central geometric axis (ZI 00) of the scrubber (100) to the peripheral wall (102) of the scrubber, and - a dispensing device (600), which distributes a second scrubbing liquid ( 4) in the form of rain falling downwards in a free volume (VI0 0) of the scrubber (100), formed between the spraying device (500) and the dispensing device (600).
    [2" id="c-fr-0002]
    2. - Method according to claim 1, wherein, before encountering the protection device (300), the fumes (1) are rotated inside the washer (100) circulating through a device rotating (400).
    [3" id="c-fr-0003]
    3. - Method according to one of claims 1 or 2, wherein, the cross section of the washer (100) below the dispensing device (600) consisting of a central portion (SI00.1) and a peripheral part (SI 00.2) which have the same area, the distribution density of the second washing liquid (4) on said central part, that is to say the flow of the second washing liquid which is distributed by the device of distribution (600) in said central portion and which is brought back to the area of said central portion, is at most 0.9 times the distribution density of the second washing liquid on said peripheral portion, that is to say the flow of the second washing liquid which is dispensed by the dispensing device into said peripheral portion and which is brought back to the area of said peripheral portion.
    [4" id="c-fr-0004]
    4. - Installation for wet scrubbing of exhaust fumes from an engine of a marine vessel. which installation comprises: - a washer (100) in the bottom (101) which opens substantially a vertical chimney (200) for the admission of fumes to be purified (1) in the scrubber, - a protective device (300) , which is adapted to protect the downstream outlet (201) of the chimney (200) against the introduction of liquid while allowing the fumes (1) to flow out of the chimney, - a spraying device (500), which is adapted for spraying a first washing liquid (3), in the form of liquid webs, from substantially a central geometric axis (ZI 00) of the scrubber (100) to the peripheral wall (102) of the scrubber, and - a dispensing device ( 600), which is adapted to dispense a second washing liquid (4) in the form of downward falling rain into a free volume (VI00) of the scrubber (100), formed between the spraying device (500) and the distribution device (600), the protective device (3 00), the spraying device (500) and the dispensing device (600) being arranged inside the scrubber (100), so that the fumes (1) leaving the chimney (200) and circulating to the high inside the scrubber, meet successively the protective device, the spraying device and the dispensing device.
    [5" id="c-fr-0005]
    5. - Installation according to claim 4, wherein the spraying device (500) comprises a sprayer (501) or several sprayers (501) arranged staggered along the central axis (ZI00) of the scrubber (100), and in which the dispensing device (600) comprises distributors (601) distributed over one or more stages.
    [6" id="c-fr-0006]
    6. - Installation according to one of claims 4 or 5, wherein the installation further comprises a rotation device (400), which is adapted to be traversed by the fumes (1) out of the chimney (2). ) to rotate said fumes within the scrubber (100) before they meet the dispensing device (300).
    [7" id="c-fr-0007]
    7. - Installation according to claim 6, wherein the rotation device (400) comprises vanes (401) flue gas deflection (1), which are distributed around the central axis (ZI 00) of the washer ( 100) and which are in particular provided in six to ten copies.
    [8" id="c-fr-0008]
    8. - Installation according to any one of claims 4 to 7, wherein the protective device (300) consists of a Chinese hat (301), that is to say a cone having a half angle at the summit of at least 60 °.
    [9" id="c-fr-0009]
    9. - Installation according to any one of claims 4 to 7, wherein the protection device (300) comprises a conical top (302.1) and one or more cone (302.2, 302.3) coaxial and superimposed, which is or are coaxially surmounted by the top cone (302.1), the top cone and the at least one truncated cone all having a top half-angle of at least 60 °.
    [10" id="c-fr-0010]
    10. - Installation according to any one of claims 4 to 9, wherein the installation further comprises a stripper (700) which is arranged inside the scrubber (100) so as to be traversed by the fumes (1). ) after they have encountered the dispensing device (600).
    类似技术:
    公开号 | 公开日 | 专利标题
    FR3050654A1|2017-11-03|METHOD AND INSTALLATION FOR WET PURIFICATION OF EXHAUST FUMES FROM AN ENGINE OF A SEA VESSEL
    RU2654027C2|2018-05-15|Marine exhaust gas scrubber
    TWI498514B|2015-09-01|Plant and process for purifying marine diesel exhausts
    EP2768592B1|2015-12-16|Device for collecting and separating aqueous and/or oily liquids and cryogenic liquid
    EP3034142A1|2016-06-22|Compact dispenser tray for offshore gas/liquid contact columns
    JP3124354U|2006-08-17|Scrubber
    WO2017198653A1|2017-11-23|Device for feeding exhaust fumes of a marine vessel engine into a scrubber
    KR20150024071A|2015-03-06|Exhaust gas desulfurization apparatus for marine diesel engines
    US20190099706A1|2019-04-04|Integrated system for seawater scrubbing of marine exhaust gas
    EP3015151B1|2017-03-29|Compact dispenser tray for offshore gas/liquid contact columns
    US1849932A|1932-03-15|Method and apparatus for preventing fire hazards in operating upon and cleaning containers of inflammable liquids or gases
    EP0362015A1|1990-04-04|Method for generating heat with desulfurization of effluents using sorbent particles with a fine particle size in an entrained bed
    FR3086188A1|2020-03-27|DEVICE FOR PROTECTING THE INTAKE OF SMOKE IN A WASHER, AS WELL AS A PURIFICATION INSTALLATION COMPRISING SUCH A PROTECTIVE DEVICE
    CN109069993A|2018-12-21|Ocean engineering power tail gas only uses seawer washing purification method and device
    EP0463957B1|1993-10-20|Method and device for generating heat with desulfurization of effluents using sorbent particles with a fine particle size in an entrained bed
    WO2018114696A1|2018-06-28|Column for the exchange of matter and/or heat between a gas and a liquid with means for recirculating the liquid and use of same
    FR3069459A1|2019-02-01|PROCESS AND INSTALLATION FOR WET PURIFICATION OF EXHAUST FUMES FROM AN ENGINE OF A SEA VESSEL
    EP0713479B1|1998-09-16|Method of obtaining uranium trioxide by directly heat denitrating uranyl nitrate
    WO2021110646A1|2021-06-10|System for wet scrubbing of exhaust fumes from an engine of a marine vessel
    WO2019120937A1|2019-06-27|Distributor tray with compartments and gas risers of the same shape for an offshore gas/liquid contact column
    FR3093652A1|2020-09-18|Installation for the wet purification of exhaust fumes from an engine of a marine vessel
    EP1184622A1|2002-03-06|Method of generating heat with reduced emission of sulphur oxides and low absorbant consumption
    FR3041689B1|2019-06-28|DEVICE FOR DELETION, PARTIAL OR TOTAL, OF A PANACHE OF SMOKE, AS WELL AS INSTALLATION OF REJECTION OF SMOKE AT THE ATMOSPHERE COMPRISING SUCH A DEVICE
    FR3112084A1|2022-01-07|Installation and method for the wet purification of exhaust fumes from an engine of a marine vessel
    CN209286923U|2019-08-23|Spray system on hazardous materials transportation ship in inert gas digester
    同族专利:
    公开号 | 公开日
    CN109069985B|2022-01-28|
    FR3050654B1|2021-02-12|
    KR102343017B1|2021-12-23|
    WO2017186769A1|2017-11-02|
    KR20180135953A|2018-12-21|
    CN109069985A|2018-12-21|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    US1783813A|1927-05-16|1930-12-02|Claude B Schneible|Column|
    US2596106A|1947-11-22|1952-05-13|Claude B Schneible|Column apparatus|
    GB1290363A|1969-08-22|1972-09-27|
    US3930816A|1973-04-23|1976-01-06|Gerhard Miczek|Structure for a gas and liquid contacting chamber in a gas effluent processing system|
    US4375976A|1981-02-27|1983-03-08|Potter George R|Method and apparatus for recovering particulate matter from gas stream|
    DE202009005612U1|2009-04-09|2010-09-02|Häufele, jun., Josef|Air cleaning system|
    US20160016109A1|2013-02-22|2016-01-21|Marine Global Holding As|Marine exhaust gas scrubber|
    CN2152592Y|1992-06-18|1994-01-12|尹春华|Purifier for smoke dust in air and waste gas|
    KR200269466Y1|2001-12-12|2002-03-23|주식회사 길광그린텍|Vortex wet scrubber for removing toxic gas and particle|
    CN2605057Y|2003-02-24|2004-03-03|赵雄飞|Dust-removing and deodorizing apparatus for organic fertilizer production|
    AU2003277193A1|2003-07-09|2005-02-25|Belco Technologies Corporation|WET SCRUBBING APPARATUS AND METHOD FOR CONTROLLING NOx EMISSIONS|
    CN101569831A|2008-04-29|2009-11-04|白福有|Flue-gas wet dust removal desulfurizer|
    CN201353476Y|2009-02-01|2009-12-02|中冶集团北京冶金设备研究设计总院|Seawater flue gas desulfurization spray adsorption tower|
    US20110247336A9|2009-03-10|2011-10-13|Kasra Farsad|Systems and Methods for Processing CO2|
    CN201692764U|2010-06-09|2011-01-05|同方环境股份有限公司|Desulfurization and dust removal device for smoke removal of ships by utilizing seawater|
    CN101874972A|2010-06-25|2010-11-03|北京紫光威肯环保工程技术有限公司|Boiler flue gas desulfurization device by in-column crystallization ammonia process|
    CN101869801A|2010-07-02|2010-10-27|中国海洋石油总公司|Flue gas washing device and washing method|
    KR101034385B1|2011-01-10|2011-05-16|선종국|Hybrid scrubber apparatus|
    US20130228074A1|2012-03-05|2013-09-05|Ronald G. Patterson|Methods and apparatuses for inhibiting backflow of liquid into engine ducts on a ship|
    CN202751925U|2012-08-20|2013-02-27|中国石油化工集团公司|Tower for flue gas cleaning|
    CN202921125U|2012-11-05|2013-05-08|中国石油化工集团公司|Flue gas purification tower|
    KR101541890B1|2014-08-27|2015-08-06|삼성케미텍|Wet scrubber with air chamber|
    CN104941326B|2015-06-05|2016-07-20|北京中晶环境科技股份有限公司|Dedusting demister, treating column and purposes|
    CN104959016B|2015-06-10|2017-08-22|浙江菲达脱硫工程有限公司|Twin-stage subregion spray desulfurizing tower|
    CN204768217U|2015-06-18|2015-11-18|济宁市技师学院|Be used for detaching acid gas's in chemical industry tail gas device|
    CN205095638U|2015-11-14|2016-03-23|黄盛珠|Boats and ships tail gas wet flue gas desulfurization device|CN110013765A|2019-04-03|2019-07-16|哈尔滨工程大学|A kind of ship tail gas denitration integrated device|
    KR200493546Y1|2019-07-01|2021-04-20|김대중|Exhaust fumes cleaning system for smokestack|
    AT523037B1|2020-02-07|2021-05-15|Avl List Gmbh|WET WASHER FOR GASES|
    CN111686555A|2020-07-24|2020-09-22|河南省中医院（河南中医药大学第二附属医院）|Purification device for department of respiration|
    CN112090202A|2020-09-28|2020-12-18|滁州市汊河之星高新技术研发有限公司|Harmful gas processing apparatus for environmental protection engineering|
    法律状态:
    2017-04-20| PLFP| Fee payment|Year of fee payment: 2 |
    2017-11-03| PLSC| Publication of the preliminary search report|Effective date: 20171103 |
    2018-03-22| PLFP| Fee payment|Year of fee payment: 3 |
    2020-03-13| PLFP| Fee payment|Year of fee payment: 5 |
    2021-03-11| PLFP| Fee payment|Year of fee payment: 6 |
    优先权:
    申请号 | 申请日 | 专利标题
    FR1653724A|FR3050654B1|2016-04-27|2016-04-27|METHOD AND INSTALLATION FOR WET TREATMENT OF EXHAUST FUMES FROM AN ENGINE OF A MARINE VESSEL|FR1653724A| FR3050654B1|2016-04-27|2016-04-27|METHOD AND INSTALLATION FOR WET TREATMENT OF EXHAUST FUMES FROM AN ENGINE OF A MARINE VESSEL|
    PCT/EP2017/059879| WO2017186769A1|2016-04-27|2017-04-26|Method and facility for wet desulphurisation of the exhaust fumes of an engine of a sea ship|
    CN201780026143.1A| CN109069985B|2016-04-27|2017-04-26|Method and installation for wet desulfurization of exhaust fumes of marine engines|
    KR1020187033596A| KR102343017B1|2016-04-27|2017-04-26|Method and equipment for wet desulfurization of exhaust gas of marine engine|
    [返回顶部]