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    • 专利摘要:
    Transparent cosmetic compositions are described which contain - based on their total weight - a) 0.1 to 10% by weight of a conditioning polymer, b) 0.5 to 25% by weight of a thickening polymer, c ) 0.01 to 30% by weight of a film-forming polymer, d) 1 to 35% by weight of a humectant, e) 0.1 to 6% by weight of an acid and f) 1 to 90% by weight of water. The cosmetic compositions are particularly suitable for the temporary shaping of keratinous fibers, in particular curly human hair.
    公开号:FR3048180A1
    申请号:FR1751346
    申请日:2017-02-21
    公开日:2017-09-01
    发明作者:Anna Puls
    申请人:Henkel AG and Co KGaA；
    IPC主号:
    专利说明:

    This invention relates to the technical field of the temporary shaping of keratin fibers, especially human hair.
    Hair styling products for the temporary shaping of keratinous fibers have been known for a long time and are used in various forms to make, refresh or fix hairstyles that can only be obtained through the use of active principles for the preparation of hair. many types of hair. Thus, hair treatment agents that serve to shape hair permanently as well as temporarily, play an important role.
    Sprayable products are suitable for the temporary shaping of keratinous fibers, as well as presentations integrated into the hairstyle using a comb or with the fingers. The last group of products cited includes oils as well as gels, creams or powder.
    Frizz is one of the main problems that occurs when the hair is exposed to high humidity. This problem is mostly amplified in people with curly hair and causes what is called in everyday language the head of the bad days. In such a case, the hair loses its natural shape and / or the holding of its loops ("spring loop").
    In people who have naturally curly hair or have a perm, it is also often the problem that the loops hang over time and lose their elasticity. This occurs when for example the hair treatment agents used such as shampoos, rinses or styling products make the hair heavier.
    Unlike smooth hair, curly hair does not reflect as much light and therefore shines a little less than usual.
    Patent EP1741470 B1 describes a composition intended to improve the brightness, the ease of styling, the holding of the loops ("spring of the loop") and the definition of the loops ("separation of loops") of the curly hair. This composition contains a film-forming polymer, a polyol in an amount of greater than 5% by weight and a polyacryloyldimethyltaurate and / or its salts.
    Another problem in the formulation of styling products lies in the manufacture of transparent clear compositions because the polymers generally used in styling products often give turbid and turbid compositions. A milky visual appearance, however, may give the impression to the user that the formulation may be particularly visible in the hair and reduce the acceptance of the styling product by the customers.
    The present invention therefore aimed to provide a transparent hair treatment product for the temporary shaping of curly hair, giving the hair a curly appearance that lasts a long time, a large volume, an intense brightness and easy styling.
    A curly aspect that lasts a long time is characterized by a good behavior and / or high elasticity of the loops and / or a good definition of the loops. This last element means that the loops can be clearly identified in a lock of hair. It has been found that this object can be achieved by a combination of a conditioning polymer, a thickening polymer, a film-forming polymer, a humectant and an acid.
    A first object of the present invention is a transparent cosmetic composition, containing, with respect to its total weight, a) 0.1 to 10% by weight of a conditioning polymer, b) 0.5 to 25% by weight of a thickening polymer, c) 0.01 to 30% by weight of a film-forming polymer, d) 1 to 35% by weight of a humectant, e) 0.1 to 6% by weight of an acid, and 1 to 90% by weight of water.
    The composition is in the form of a gel, which is preferably applied directly with the hand or with a comb, in the form of a viscous lotion, cream or paste, wax, sprayable liquid which is sprayed by means of a spray. mechanical device or in the form of liquid that can expand, which is foamed before application. "The cosmetic composition is preferably in the form of a gel.
    The corresponding hair treatment agents are designated by capillary sprays, capillary gel, capillary wax, capillary foam, capillary fixing agent or hair lotion. Clay "refers to another possible form of product. These are very viscous cosmetic compositions of the wax type containing, inter alia, clay compounds (for example kaolin). Preferred cosmetic compositions are hair gels.
    If the compositions are in the form of gels, creams, pastes or waxes, the viscosity of the compositions is preferably between 5,000 and 150,000 mPas, preferably between 20,000 and 80,000 mPas (20 ° C., rotary viscometer DV 2T "Brookfield", Spindel 5, 5 revolutions per minute and Helipath).
    Transparent transparent compositions are understood in the context of the present invention as compositions which appear clear to the naked eye on the palm of the hand (limpid on the hand). These compositions have a transmission value of> 93% at room temperature and for a transmission measurement of 600 nm.
    A first essential ingredient of the cosmetic composition is a conditioning polymer.
    Conditional polymers are polymers that swell on the hair and exert a conditioning effect. To improve inflation, the conditioning polymers generally have cationic charges and are therefore cationic or amphoteric polymers.
    The conditioning polymers may be homopolymers or copolymers based on natural or synthetic polymers. The conditioning polymers may be cationic or amphoteric. The conditioning polymers contain quaternary nitrogen groups which are present in the polymer chain or preferably as a substituent on one or more of the monomers. Suitable cationic monomers are the unsaturated compounds, polymerizable by radical polymerization, which carry at least one cationic group, in particular ammonium-substituted vinyl monomers, for example trialkylmethacryloxyalkylammonium, trialkylacryloxyalkylammonium, dialkyldiallylammonium or vinylammonium monomers. quaternary containing cyclic nitrogen containing groups, such as pyridinium, imidazolium or quaternary pyrrolidone, such as for example alkylvinylimidazolium, alkylvinylpyridinium or alkylvinylpyrrolidone salts. The alkyl groups of these monomers are preferably lower alkyl groups such as, for example, C1 to C7 alkyl groups, particularly preferably C1 to C3 alkyl groups.
    Monomers containing ammonium groups may be copolymerized with non-cationic monomers. Suitable comonomers are, for example, acrylamide, methacrylamide; alkylacrylamide and dialkylacrylamide, alkyl acrylate, alkyl methacrylate, vinylcaprolactone, vinylcaprolactam, vinylpyrrolidone, a vinyl ester such as vinyl acetate, vinyl alcohol, propylene glycol or ethylene glycol, the alkyl groups of these monomers being preferably C1-C7 alkyl groups, particularly preferably C1-C3 alkyl groups.
    Among this multitude of polymers, the following have been found to be particular: the homopolymers of general formula - {CH 2 - [CR 1 COO- (CH 2) mN + R 2 R 3 R 4] n X 'where R 1 = -H or -CH 3, R 2, R 3 and R 4 are selected independently from each other from C1-4 alkyl, alkenyl or hydroxyalkyl groups, m = 1, 2, 3 or 4, n is a natural number and X is a physiologically acceptable organic or inorganic anion. In the context of these polymers, those for which one of the following conditions apply: R1 represents a methyl group, R2, R3 and R4 represent methyl groups, ma the value 2. It is envisaged that Physiologically acceptable X ions, for example, halide ions, sulfate ions, phosphate ions, methosulphate ions and organic ions such as lactate, citrate, tartrate and acetate ions. Methosulfates and halide ions, in particular chloride, are preferred.
    Suitable cationic conditioning polymers are, for example, copolymers according to the formula (Copo).
    Formula (Copo) where we have:
    x + y + z = QQ represents values ranging from 3 to 55,000, preferably from 10 to 25,000, particularly preferably from 50 to 15,000, more preferably from 100 to 10,000, even more preferably, and in particular from 1000 to 5000, x represents (0 to 0.5) Q, preferably (0 to 0.3) Q and in particular the values 0.1, 2, 3, 4, 5, the value 0 being preferred, y represents (0.1 to 0.95) Q, preferably (0.5 to 0.7) Q and in particular values ranging from 1 to 24000, preferably from 5 to 15000, particularly preferably from 10 to 10000; and in particular from 100 to 4800, z represents (0.001 to 0.5) Q, preferably (0.1 to 0.5) Q and in particular values ranging from 1 to 12500, preferably from 2 to 8000, of particularly preferably from 3 to 4000 and in particular from 5 to 2000.
    Whatever the preferred copolymers of formula (Copo) used, cosmetic compositions are preferred which are characterized in that the ratio (y: z) ranges from 4: 1 to 1: 2, preferably 4: 1 to 1 1.
    Whatever the copolymers used in the compositions, cosmetic compositions are preferred in which the copolymer has a molar mass of from 10 000 to 20 million g / mol, preferably from 100 000 to 10 million g / mol, more preferably 500 000. to 5 million gmol -1 and particularly preferably from 1.1 million to 2.2 million gmol -1.
    A most preferred copolymer, which is constituted as indicated above, is commercially available as Polyquaternium-74.
    Suitable cationic polymers, which are derived from natural polymers, are cationic derivatives of polysaccharides, for example cationic derivatives of cellulose, guar or starch. In addition, chitosan and chitosan derivatives are suitable.
    Cationic polysaccharides have the general formula G-O-B-N + RaRbRc A 'G is an anhydroglucose radical, for example anhydroglucose starch or cellulose; B is a divalent linking group, for example, alkyls, oxyalkyls, polyoxyalkyls or hydroxyalkyls;
    Ra, Rb and Rc are independently alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl or alkoxyaryl each having up to 18 carbon atoms, the total number of C atoms in Ra, Rb and Rc being preferably maximum; A- is a common counterion and is preferably chloride.
    Cationic celluloses, thus quaternized, are available on the market with varying degrees of substitution, cationic charge density, nitrogen content and molecular weight. For example, Polyquatemium-67 is marketed under the names SoftCat © Polymer SL or SoftCat® Polymer SK (Dow). Other cationic celluloses are Ucare® Polymer JR 400 (Dow, INCI name Polyquaternium-10) and Polymer Quatrisoft® LM-200 (Dow, INCI name Polyquaternium-24). Other commercial products are Celquat® H 100 and Celquat® L 200.
    A suitable chitosan is marketed for example by Kyowa Oil & Fat, Japan, under the trade name Flonac®. A preferred chitosan salt is chitosonium pyrrolidonecarboxylate, which is marketed for example as Kytamer® PC by Amerchol, USA. Other chitosan derivatives are commercially available under the trade names Hydagen® CMF, Hydagen® HCMF and Chitolam® NB / 101.
    Another group of cationic, conditioning polymers, which must become preeminent, are the glucose-based polymers. The following figure shows a cationic alkyloligoglucoside of this type.
    In the formula described above, the radicals R represent, independently of each other, a linear or branched C 6 to C 30 alkyl radical, a linear or branched C 6 -C 30 alkyl radical; the radical R preferably represents a radical R chosen from: lauryl, myristyl, cetyl, stearyl, oleyl, behenyl or arachidonyl.
    The radicals R 1 represent, independently of each other, a linear or branched C 6 to C 30 alkyl radical, a linear or branched C 6 to C 30 alkyl radical, preferably the radical R represents a radical chosen from: butyl, capryl, caprylyl, octyl, nonyl, decanyl, lauryl, myristyl, cetyl, stearyl, oleyl, behenyl or arachidonyl. It is particularly preferred that the radicals R 1 are identical. More preferably, the radicals R1 are selected from technical mixtures of fatty alcohol cuts consisting of C6 / C8 fatty alcohols, C8 / C10 fatty alcohols, C10 / C12 fatty alcohols, C12 / C14 fatty alcohols, of C12 / C18 fatty alcohols, and technical fatty alcohol cuts of plant origin are most preferred. The counter ion for the cationic charge is a physiologically acceptable anion, for example a halide, methosulfate, phosphate, citrate, tartrate, etc. The counterion is preferably a halide such as fluoride, chloride, bromide or methosulphate. The chloride anion is most preferred.
    Particularly preferred cationic alkyloligoglucosides are, for example, compounds having the names INCI Polyquaternium-77, Polyquaternium-78, Polyquaternium-79, Polyquaternium-80, Polyquaternium-81 and Polyquaternium-82. The cationic alkyloligoglucosides bearing the names Polyquaternium-77, Polyquaternium-81 and Polyquaternium-82 are most preferred.
    Compounds of this type may for example be purchased from Colonial Chemical Inc. under the designation Poly Suga® Quat.
    Of course, this also includes the fact that several mixtures of cationic alkyloligoglucosides can be used. In this case, it is preferred to use simultaneously a cationic alkyloligoglucoside long chain and a short chain.
    Another cationic polymer, a preferred conditioning agent, can be obtained based on ethanolamine. This polymer is commercially available as Polyquaternium-71.
    It may for example be purchased under the designation Cola® Moist 300 P from Colonial Chemical Inc.
    In addition, a cationic alkyloligoglucoside can be used in a particularly preferred manner, as shown in the following figure.
    In the formula described above, the radical R 2 represents a linear or branched C 6 to C 30 alkyl radical, a linear or branched C 6 -C 30 alkyl radical, preferably the radical R represents a radical R chosen from: lauryl, myristyl, cetyl, stearyl, oleyl, behenyl or arachidonyl.
    The radical R 1 represents a linear or branched C 6 to C 30 alkyl radical, a linear or branched C 6 to C 30 alkyl radical, preferably the radical R 1 represents a radical chosen from: butyl, capryl, caprylyl, octyl, nonyl, decanyl, lauryl, myristyl, cetyl, stearyl, oleyl, behenyl or arachidonyl. More preferably, the radical R1 is selected from technical mixtures of fatty alcohol cuts consisting of C6 / C8 fatty alcohols, C8 / C10 fatty alcohols, C10 / C12 fatty alcohols, C12 / C14 fatty alcohols, C12 / C18 fatty alcohols, and technical fatty alcohol cuts of vegetable origin are most preferred. The index n represents a number between 1 and 20, preferably between 1 and 10, more preferably between 1 and 5 and most preferably between 1 and 3. The counter-ion for the cationic charge, A ' is a physiologically acceptable anion, for example a halide, methosulphate, phosphate, citrate, tartrate, etc. The counterion is preferably a halide such as fluoride, chloride or bromide, or methosulphate. The chloride anion is most preferred.
    Particularly preferred cationic alkyloligoglucosides are, for example, compounds having the names INCI Laurdimoniumhydroxypropyl Decylglucosides Chloride, Laurdimoniumhydroxypropyl Laurylglucosides Chloride, Stearyldimoniumhydroxypropyl Decylglucosides Chloride, Stearyl-dimoniumhydroxypropyl Laurylglucosides Chloride, Stearyldimoniumhydroxypropyl Laurylglucosides Chloride or Cocoglucosides Hydroxypropyltrimonium Chloride.
    Compounds of this type may for example be purchased from Colonial Chemical Inc. under the designation Suga® Quat.
    Of course, this also includes the fact that several mixtures of cationic alkyloligoglucosides can be used. In this case, it is preferred to use simultaneously a cationic alkyloligoglucoside long chain and a short chain.
    Another preferred cationic conditioning polymer comprises at least one structural unit of formula (I), at least one structural unit of formula (II), at least one structural unit of formula (III) and at least one structural unit of formula (IV) ,
    where R1 and R4 represent, independently of one another, a hydrogen atom or a methyl group, X1 and X2 represent, independently of each other, an oxygen atom or a group NH, A1 and A2 independently of one another are ethane-1,2-diyl, propane-1,3-diyl or butane-1,4-diyl, R2, R3, R5 and R6 are independently each other, a (C 1 -C 4) alkyl group, R 7 represents an alkyl group (Ce to C 30).
    According to the formulas above and all the following formulas, a chemical bond which is characterized by the symbol * represents a free valence of the corresponding structural fragment.
    All physiologically acceptable anions, such as, for example, chloride, bromide, hydrogen sulfate, methylsulfate, ethylsulfate, tetrafluoroborate, phosphate, hydrogenphosphate, dihydrogenphosphate or p-toluolsulfonate, triflate.
    (C 1 to C 4) alkyl groups according to the invention are, for example, methyl, ethyl, propyl, isopropyl, butyl, sec-butyl, isobutyl or tert-butyl. .
    (C 1 -C 30) alkyl groups according to the invention are, for example, octyl (capryl), decyl (caprinyl), dodecyl (lauryl), tetradecyl (myristyl), hexadecyl (cetyl), octadecyl (stearyl), eicosyl (arachidonyl), docosyl (behenyl).
    The following cationic, conditioning polymers may be used in the agents if the conditioning polymers according to formulas (I) to (IV) above fulfill one or more of the following characteristics: R 1 and R 4 each represent a methyl group, X 1 represents a group NH, X2 is NH, A1 and A2 are, independently of each other, ethane-1,2-diyl or propane-1,3-diyl, R2, R3, R5 and R6 represent, independently of one another, methyl or ethyl (particularly preferably methyl), R7 represents a (C10-C24) alkyl group, especially decyl (caprinyl), dodecyl (lauryl), tetradecyl (myristyl), ), hexadecyl (cetyl), octadecyl (stearyl), eicosyl (arachidonyl) or docosyl (behenyl). It is preferred to choose the structural unit of formula (III) from at least one structural unit of formulas (III-1) to (III-8)
    Furthermore, it turns out that it is particularly preferable to choose as structural unit of formula (III) the structural unit according to formula (III-7) and / or formula (III-8). The structural unit of formula (III-8) is a very preferred structural unit.
    In addition, it has proved preferable, in view of the solution of the problem, to choose the structural unit of formula (IV) from at least one structural unit of formulas (IV-1) to (IV-8)
    where R7 is (C8-C30) alkyl.
    The structural units of formula (IV-7) and / or formula (IV-8), wherein R7 represents octyl (capryl), decyl (caprinyl), dodecyl (lauryl), tetradecyl (myristyl), hexadecyl (cetyl), octadecyl (stearyl), eicosyl (arachidonyl) or docosyl (behenyl) are in turn adapted as a particularly preferred structural unit of formula (IV). The structural unit of formula (IV-8) constitutes a very particularly preferred structural unit of formula (IV).
    A particularly preferred cationic polymer contained in the agent comprises at least one structural unit of formula (I), at least one structural unit of formula (II), at least one structural unit of formula (III-8) and at least one at least one structural unit of formula (IV-8),
    where R7 represents octyl (capryl), decyl (caprinyl), dodecyl (lauryl), tetradecyl (myristyl), hexadecyl (cetyl), octadecyl (stearyl), eicosyl (arachidonyl) or docosyl (behenyl).
    A particularly preferred cationic polymer is the copolymer of N-vinylpyrrolidone, N-vinylcaprolactam, N- (3-dimethylaminopropyl) methacrylamide and 3- (methacryloylamino) -propyl-lauryl-dimethylammonium chloride (INCI name: Polyquaternium). -69), which is for example marketed under the trade name AquaStyle® 300 (28-32% by weight of active substance in the mixture ethanol-water, molecular weight 350000) by the company ISP. Other preferred cationic polymers are, for example, cationized honey, for example the commercial product Honeyquat 50, dimethyldiallylammonium salts polymers and copolymers thereof with esters and amides of acrylic acid and methacrylic acid. The products commercially available under the names Merquat®100 (poly (dimethyldiallylammonium chloride)) and Merquat®550 (copolymer of dimethyldiallylammonium chloride and acrylamide) are examples of these conditioning cationic polymers bearing the INCI name Polyquatemium-7. of copolymers of vinylpyrrolidone and of vinylimidazolium methochloride, as they are proposed under the names Luviquat® FC 370, FC 550 and the INCI names Polyquaternium-16, FC 905 and HM 552, a quaternized polyvinyl alcohol, and the polymers known under the names Polyquaternium-2, Polyquaternium-17, Polyquatenium-18 and Polyquaternium-27 comprising quaternary nitrogen atoms in the main polymer chain, terpolymers of vinylpyrrolidone, of vinylcaprolactam and of acrylate, as they are marketed for example under the name Aquaflex® SF 40 with acrylic acid esters and acrylic acid amides as troi second monomer block.
    Suitable amphoteric polymers are those polymers in which a cationic group is derived from at least one of the following monomers: (i) monomers having quaternary ammonium groups of the general formula (Monol),
    (Monol) wherein R1 and R2 represent, independently of each other, hydrogen or a methyl group and R3, R4 and R5 represent, independently of each other, alkyl groups having 1 to 4 carbon atoms, Z, an NH group or an oxygen atom, n an integer of 2 to 5 and A (_) the anion of an organic or inorganic acid, (ii) monomers containing quaternary ammonium groups of the general formula (Mono2 )
    (Mono2) wherein R6 and R7 represent, independently of each other, a (C1-C4) alkyl group, in particular a methyl group and A 'is the anion of an organic or inorganic acid, (iii) monomeric carboxylic acids of general formula (Mono3), R8-CH = CR9-COOH (Mono3) wherein R8 and R9 are, independently of one another, hydrogen or methyl groups. Especially preferred are polymers in which type (i) monomers are used, wherein R3, R4 and R5 are methyl, Z is NH and A (-) is halide, methoxysulfate or ethoxysulfate ion; acrylamidopropyltrimethylammonium chloride is a particularly preferred monomer; Monomers (ii) are preferably used for the mentioned polymers, acrylic acid.
    Amphoteric polymers, which are particularly preferred, are copolymers consisting of at least one monomer (Monol) or (Mono2) and monomer (Mono3), in particular copolymers consisting of monomers (Mono2) and (Mono3). Particularly preferred amphoteric polymers used are copolymers of diallyldimethylammonium chloride and acrylic acid. These copolymers are sold under the INCI name Polyquaternium-22, in others with the trade name Merquat® 280 (ex Lubrizol).
    In addition, the amphoteric, conditioning polymers contain in addition to a monomer (Monol) or (Mono2) and a monomer (Mono3), a monomer (Mono4) (I) carboxylic acid amides monomers of the general formula (Mono4 )
    wherein R10 and R11 are, independently of one another, hydrogen or methyl groups, and R12 is hydrogen or (C1-C8) alkyl.
    Amphoteric polymers, conditioners based on a comonomer (Mono4) that can be used in a very particularly preferred manner are terpolymers of diallyldimethylammonium chloride, acrylamide and acrylic acid. These copolymers are marketed under the INCI name Polyquaternium-39, in others with the trade name Merquat® Plus 3330 (ex Lubrizol).
    The amphoteric conditioning polymers can generally be used both directly and in salt form, which are obtained by neutralization of the polymerisates, for example using an alkaline hydroxide.
    The polymers described so far represent only a part of the usable conditioning polymers. In order not to be obliged to describe all suitable cationic and / or amphoteric polymers and their composition, the INCI statements of the preferred polymers are given as a summary. The preferred polymers bear the INCI name:
    Polyquaternium-2, Polyquaternium-4, Polyquaternium-6, Polyquaternium-7, Polyquaternium-10, Polyquaternium-11, Polyquaternium-15, Polyquaternium-16, Polyquaternium-17, Polyquaternium-18, Polyquaternium-22, Polyquaternium-24, Polyquatemium-28, Polyquaternium-32, Polyquaternium-33, Polyquaternium-34, Polyquaternium-35, Polyquaterna-37, Polyquaternium-39, Polyquaterna-41, Polyquaterna-42, Polyquaternium-44, Polyquaternium-46, Polyquaternium-47, Polyquatemium-55, Polyquaternium-67, Polyquaternium-68, Polyquaternium-69, Polyquaternium-72, Polyquaternium-74, Polyquaternium-76, Polyquaternium-86, Polyquaternium-89, Polyquaternium-95 and Polyquaternium-101, as well as mixtures of these.
    It is preferred that the conditioning polymer be selected from the group consisting of cationic guar compounds, poly (methacryloyloxyethyltrimethylammonium chloride), polymers known as INCI
    Polyquaternium-11, Polyquaternium-46 and Polyquaternium-72, and mixtures thereof.
    Guar is a polysaccharide obtained from guar bean seed. The cationic guar compounds are usually quaternized guar compounds which are obtained by transformation of the polysaccharide with trimethylammonium substituted epoxides.
    Suitable cationic guar compounds are marketed under the trade name Jaguar® and bear the INCI name Guar Hydroxypropyltrimonium Chloride. In addition, particularly suitable cationic guarate compounds, also from Hercules, are marketed under the designation N-Hance®. Other cationic guar compounds are marketed by BASF SE under the designation Cosmedia®. A preferred cationic guar compound is the commercial product AquaCat® from Hercules. This raw material corresponds to a cationic guar compound already pre-dissolved.
    Poly (methacryloyloxyethyltrimethylammonium chloride), which may also be cross-linked, is a homopolymer known as INCI Polyquaternium-37. These products are commercially available for example under the names Cosmedia® CTH or Cosmedia® Ultragel 300 (BASF SE) or Synthalen® CR (3V Group). The homopolymer is preferably used as a non-aqueous polymeric dispersion. These polymer dispersions are commercially available under the names Salcare® SC 95 and Salcare® SC 96. A polymer dispersion marketed under the designation Cosmedia® Triple C (formerly BASF SE) is also suitable.
    Polyquaternium-11 is the reaction product of diethyl sulfate with a copolymer of vinylpyrrolidone and dimethylaminoethyl methacrylate. Suitable commercial products are, for example, available under the names Dehyquart® CC 11 and Luviquat® PQ 11 PN from BASF SE, or Gafquat 440, Gafquat 734, Gafquat 755 or Gafquat 755N from Ashland Inc. Polyquaternium-11 is used to preferably in an amount ranging from 1 to 10% by weight - relative to the total weight of the cosmetic composition.
    Polyquatemium-46 is the reaction product of vinylcaprolactam and vinylpyrrolidone with methylvinylimidazolium methosulfate and is available, for example, under the designation Luviquat® Hold aurfès from BASF SE. Polyquatemium-46 is preferably used in an amount ranging from 1 to 5% by weight relative to the total weight of the cosmetic composition.
    A cationic polymer, conditioning, usable particularly preferably is Polyquatemium-72. Polyquatemium-72 corresponds to a special cellulose. This cellulose is a hydroxyethylcellulose, which has been quaternized. Polyquaternium-72 is a hydroxyethylcellulose of trimonium and cocodimonium. Polyquaternium-72 can be used both in solid form and already pre-dissolved in an aqueous solution. It is preferred to use, for example, the commercial product Mirustyle® CP from Croda. Polyquaternium-72 is present in the cosmetic compositions, preferably in an amount of at least 0.5% by weight - based on the total weight of the cosmetic compositions. Polyquaternium-72 is preferably used in an amount ranging from 1 to 10% by weight relative to the total weight of the cosmetic composition.
    Polyquaternium-72 is preferably used as the conditioning polymer among all the conditioning polymers mentioned.
    The total amount of conditioning polymer is - based on the total weight of the cosmetic composition - preferably 0.1 to 10% by weight, more preferably 1 to 9% by weight, and particularly preferably 2.5 to 7% by weight. , 5%.
    As a second essential ingredient, the cosmetic composition contains - relative to its total weight - a thickening polymer. The cosmetic composition may also contain several thickening polymers. By thickening polymers is meant polymers which increase the viscosity of the cosmetic composition.
    Preferred compositions contain a polymer known as INCI Polyacrylate-1 Crosspolymer as a thickening polymer. Polyacrylate-1 Crosspolymer is a copolymer of one or more single esters of acrylic or methacrylic acid, methacrylate (C 1-4 alkyl dialkylamino), PEG / PPG-30/5 allylic ether, C10-30 alkyl ether methacrylate PEG-20-25, C2-6 hydroxyalkyl methacrylate crosslinked with ethylene glycol dimethacrylate. A particularly preferred polyacrylate-1 crosspolymer is Carbopol Aqua CC (ex Lubrizol / Noveon).
    The cosmetic compositions contain the thickening polymer, preferably in amounts of 0.5 to 25% by weight, more preferably 5 to 20% by weight, particularly preferably 12.5 to 17.5% by weight. , in relation to their total weight respectively.
    As a third essential ingredient, the cosmetic composition contains - with respect to its total weight - a film-forming polymer. The cosmetic composition may also contain several film-forming polymers. By film-forming polymers is meant polymers that leave a continuous film on the hair when they dry. In addition, the film-forming polymers are those polymers which are capable, when used in an aqueous, alcoholic or aqueous-alcoholic solution of 0.01% to 20% by weight, of depositing a transparent polymer film on the hair.
    Cationic, anionic, nonionic or amphoteric polymers, permanently or temporarily, are suitable as film-forming polymers. The film-forming polymers may be of synthetic or natural origin.
    Suitable film-forming polymers, preferably used, are homopolymers or copolymers consisting of at least one of the following monomers: vinylpyrrolidone, vinylcaprolactam, vinyl ester, for example vinyl acetate, vinyl alcohol, acrylamide, methacrylamide or alkylacrylamide. C1 to C7, C1 to C7 dialkylacrylamide, C1 to C7 alkyl methacrylamide, C1 to C7 dialkyl methacrylamide, C1 to C7 alkyl acrylate, acrylic acid, propylene glycol, ethylene glycol, the C1 to C7 alkyl groups of these monomers being preferably C1 to C3 alkyl groups. Homopolymers of vinylcaprolactam, vinylpyrrolidone or N-vinylformamide are mentioned by way of example. Other suitable film-forming, synthetic, hair-fixing polymers are, for example, copolymers of vinylpyrrolidone and vinyl acetate, vinylpyrrolidone and styrene or terpolymers of vinylpyrrolidone, vinyl acetate and vinylpropionate, and polyacrylamides. Suitable natural film-forming polymers are, for example, cellulose derivatives, such as hydroxypropylcellulose which has a molecular weight of 30,000 to 50,000 g / mol. Other examples of common film-forming polymers are Acrylamide / Ammonium Acrylate Copolymer, Acrylamide / DMAPA Acrylate / Methoxy PEG Methacrylate Copolymer, Acrylamidopropyltrimonium Chloride / Acrylamide Copolymer, Acrylamidopropyltrimonium Chloride / Acrylate Copolymer, Acrylate / Acetoacetoxyethyl Methacrylate Copolymer, Acrylate / Acrylamide Copolymer polymers, Acrylates / Ammonium Methacrylate Copolymer, Acrylates / t-Butylacrylamide Copolymer, Acrylates Copolymer, Acrylates / C1-2 Succinates / Hydroxyacrylates Copolymer, Acrylates / Lauryl Acrylate / Stearyl Acrylate / Ethylamine Oxide Methacrylate Copolymer, Acrylates / Octylacrylamide Copolymer, Acrylates / Octylacrylamide / Diphenyl
    Amodimethicone Copolymer, Acrylates / Stearyl Acrylate / Ethylamine Oxide Methacrylate Copolymer, Acrylates / VA Copolymer, Acrylates / VP Copolymer, Adipic Acid / Diethylenetriamine Copolymer, Adipic Acid / Dimethylamino-Hydroxypropyl Diethylenetriamine Copolymer, Adipic Acid / Epoxypropyl Diethylenetriamine Copolymer, Adipic Acid / Lsophthalic Acid / Neopentyl Glycol / Trimethylolpropane Copolymer, Allyl Stearate / VA Copolymer,
    Aminoethylacrylate Phosphate / Acrylates Copolymer, Aminoethylpropanediol-Acrylates / Acrylamide Copolymer, Aminoethylpropanediol-AMPD-
    Acrylates / Diacetoneacrylamide Copolymer, Ammonium VA / Acrylates Copolymer, AMPD-Acrylates / Diacetoneacrylamide Copolymer, AMP-Acrylates / Allyl Methacrylate Copolymer, AMP-Acrylates / C1-18 Alkyl Acrylates / C1-8 Alkyl Acrylamide Copolymer, AMP-Acrylates / Diacetone-Acrylamide Copolymer, AMP-Acrylates / Dimethylaminoethylmethacrylate Copolymer, Bacillus / Rice Bran Extract / Soybean Extract Ferment Filtrate, Bis-Butyloxyamodimethicone / PEG-60 Copolymer, Butyl Acrylate / Ethylhexyl Methacrylate Copolymer, Butyl Acrylate / Hydroxypropyl Dimethicone Acrylate Copolymer, Butylated PVP, Butyl Ester of Ethylene / MA Copolymer, Butyl Ester of PVM / MA Copolymer, Calcium / Sodium PVM / MA Copolymer, Com Starch / Acrylamide / Sodium Acrylate Copolymer, Diethylene Glycolamine / Epichlorohydrin / Piperazine Copolymer, Dimethicone Crosspolymer, Diphenyl Amodimethicone, Ethyl Ester of PVM / MA Copolymer, Hydrolyzed Wheat Protein / PVP Crosspolymer, Isobutylene / Ethylmaleimide / Hydroxyethyl-maleimide Copolymer, Isobutylene / MA Copolymer, Isobutylmethacrylate / Bis-Hydroxypropyl Dimethicone Acrylate Copolymer, Isopropyl Ester of PVM / MA Copolymer, Lauryl Acrylate Crosspolymer, Lauryl Methacrylate / Glycol Dimethacrylate Crosspolymer, MEA-Sulphite, Methacrylic Acid / Sodium Acrylamidomethyl Propane Sulfonate Copolymer, Methacryloyl Ethyl Betaine / Acrylate Copolymer, Octylacrylamide / Acrylates / Butylaminoethyl Methacrylate Copolymer, PEG / PPG-25/25 Dimethicone / Acrylates Copolymer, PEG-8 / SMDI Copolymer, Polyacrylamide, Polyacrylate-6, Polybeta-Alanine / Glutaric Acid Crosspolymer, Polybutylene Terephthalate, Polyester-1, Polyethylacrylate, Polyethylene Terephthalate , Polymethacryloyl Ethyl Betaine, Polypentaerythrityl Terephthalate, Polyperfluoroperhydrophenanthrene, Polysilicone-9, Polyurethane-1, Polyurethane-6, Polyurethane-10, Polyvinyl Acetate, Polyvinyl Butyral, Polyvinylcaprolactam, Polyvinylformamide, Polyvinyl Imidazolinium Acetate, Polyvinyl Methyl Ether, Potassium Butyl Ester of PVM / MA Copolymer, Potassium Ethyl Ester of PV M / MA Copolymer, PPG-70 Polyglyceryl-10 Ether, PPG-12 / SMDI Copolymer, PPG-51 / SMDI Copolymer, PPG-10 Sorbitol, PVM / MA Copolymer, PVP, PVP / VA / Aconic Acid Copolymer, PVP / VA / Vinyl Propionate Copolymer, Rhizobian Gum, Rosin Acrylate, Shellac, Sodium Butyl Ester of PVM / MA Copolymer, Sodium Ethyl Ester of PVM / MA Copolymer, Sodium Polyacrylate, Sterculia Urens Gum, Terephthalic Acid / Isophthalic Acid / Sodium Isophthalic Acid Sulfonate / Glycol Copolymer, Trimethylolpropane Triacrylate, Trimethylsiloxysilylcarbamoyl Pullulan, VA / Crotonates Copolymer, VA / Crotonates / Methacryloxybenzophenone-1 Copolymer, VA / Crotonates / Vinyl Neodecanoate Copolymer, VA / Crotonates / Vinyl Propionate Copolymer, VA / DBM Copolymer, VA / Vinyl Butyl
    Benzoate / Crotonates Copolymer, Vinylamine / Vinyl Alcohol Copolymer, Vinyl Caprolactam / VP / Dimethylaminoethyl Methacrylate Copolymer, VP / Acrylates / Lauryl Methacrylate Copolymer, VP / Dimethylaminoethylmethacrylate Copolymer, VP / DMAPA Acrylate Copolymer, VP / Hexadecene Copolymer, VP / VA Copolymer, VP / Vinyl Caprolactam / DMAPA Copolymer Acrylates, Yeast Palmitate and Styrene / VP Copolymer. It is preferred that the film-forming polymer be a nonionic film-forming polymer. It is particularly preferred that the cosmetic compositions contain polyvinylpyrrolidone (PVP) and / or a copolymer containing vinylpyrrolidone as the film-forming polymer. Suitable polyvinylpyrrolidones are, for example, available under the designation Luviskol® K from BASF SE. For the copolymers containing vinylpyrrolidone, the polymers Styrene / VP Copolymer and / or Vinylpyrrolidon-Vinylacetate Copolymer and / or VP / DMAPA Acrylates Copolymer and / or VP / Vinyl Caprolactam / DMAPA Acrylates Copolymer are particularly preferably used. cosmetic compositions.
    Copolymers of vinylpyrrolidone and vinyl acetate are marketed under the designation Luviskol® VA by BASF SE. A VP / Vinyl Caprolactam / DMAPA Acrylate Copolymer is marketed for example under the trade name Aquaflex® SF-40 by Ashland Inc. A VP / DMAPA Acrylate Copolymer is marketed for example under the designation Styleze CC-10 by Ashland and is a copolymer most preferred, which contains vinylpyrrolidone. It may be preferred, in particular, when using poly (methacryloyloxyethyltrimethylammonium chloride) as conditioning polymer that the cosmetic composition contains polyvinylpyrrolidone and a VP / DMAPA Acrylate Copolymer as film-forming polymer.
    The cosmetic compositions contain the film-forming polymer, preferably in amounts of from 0.1 to 30% by weight, more preferably in amounts of from 1 to 25% by weight, and most preferably in amounts of from 5 to 10% by weight. and 20% by weight, based on their total weight respectively.
    The cosmetic composition contains at least one humectant as the fourth essential ingredient. The humectant is preferably selected from the group consisting of polyols, polyether modified polysiloxanes and mixtures thereof.
    Polyether-modified polysiloxanes of formula (I) below are preferably used as humectants:
    Wherein R 1 and R 3 represent, independently of one another, a hydrogen atom, an alkyl group having 1 to 30 C atoms, an alkoxy group having 1 to 30 C atoms or a phenyl group optionally substituted, the radical R2 represents the group -CcH2c-O- (C2H40-) a (C3H60-) bR5, the radical R5 represents a hydrogen atom or a linear or branched alkyl group containing 1 to 16 C atoms, n represents a number ranging from 0 to 500, - p represents a number ranging from 1 to 50, - a represents a number ranging from 0 to 50, - b represents a number ranging from 0 to 50, - a + b are at minus 1, and - c represents a number ranging from 1 to 4.
    More preferred polyether-modified polysiloxane compounds of general structural formula (I) are:
    Table 1
    Particularly preferred polyether-modified polysiloxane compounds of general structural formula (I) are:
    Table 2
    Particularly preferred polyether-modified polysiloxane compounds of general structural formula (I) are:
    Table 3
    Polyether-modified polysiloxane compounds, which are listed in the above-mentioned Tables 1-3, are commercially available, for example under the trade names 1: Dow Corning 190 (INCI: PEG / PPG-18/18 Dimethicone), 2: Dow Corning 193 (INCI: PEG-12 Dimethicone), 3: ABIL® B 8843 (INCI: PEG-14 Dimethicone), 4: Silwet L-77, 5: Mirasil DCMO (INCI: Cyclomethicone, PEG / PPG-22/24 Dimethicone ), 6: Dow Corning Q2-5220 (INCI: PEG / PPG-17/18 Dimethicone), 7: ABIL® B 88184 (INCI: PEG / PPG-20/6 Dimethicone), and 8: ABIL® B 8851 (INCI : PEG / PPG-14/4 Dimethicone).
    Particularly preferred cosmetic compositions are characterized in that they contain at least one polyether-modified polysiloxane compound according to formula (I), which satisfies the conditions of line 2 (Tables 1-3) (for example Dow Corning 193 ( INCI: PEG-12 Dimethicone)).
    Also particularly preferred cosmetic compositions are characterized in that they contain at least one polyether modified polysiloxane compound according to formula (I), which satisfies the conditions of line 2 in Tables 1 and 2 and of line 3 in Table 3 (eg ABIL® B 8843 (INCI: PEG-14 Dimethicone)).
    The cosmetic compositions may contain a polyol as a humectant.
    The polyol is preferably an organic polyol and may be used as an individual substance or as polyol mixtures. Preferred cosmetic agents are characterized in that they contain less than four polyols, preferably one to three, but in particular one or two polyol (s) only. Suitable for the manufacture of cosmetic compositions include polyols from the group comprising glycerin, 1,2-ethanediol, polyethylene glycol with MW> 400, propanediol, butanediol, especially 1,3-butanediol, hexanediol, especially 1,6-hexanediol, sorbitol, threitol, erythritol, arabitol, altritol, ribitol, xylitol, galactitol, mannitol, iditol and panthenol. Preferred cosmetic compositions are characterized in that they contain as organic polyol at least one polyol from the group glycerin, sorbitol, panthenol, polyethylene glycol, propylene glycol, butylene glycol and hexanediol. It is most preferred that the cosmetic composition contain at least three compounds selected from the group consisting of polyether modified polysiloxane known as INCI PEG-12 Dimethicone, glycerine, panthenol, propylene glycol and hexanediol. . The addition of a polyol can improve the properties of the cosmetic compositions during storage and application and has advantageous cosmetic effects.
    The cosmetic compositions contain the humectant, preferably in amounts of 1 to 35% by weight, more preferably in amounts of 5 to 30% by weight, and most preferably in amounts of between 10 to 30% by weight. 25% by weight, based on their total weight respectively.
    A smaller amount of water is preferably added to compensate for cosmetic compositions having a high polyol content.
    The cosmetic composition contains at least one acid as the fifth essential ingredient. The acid used may be an inorganic acid such as hydrochloric acid or an organic acid. The use of an organic acid is preferred. In addition, it is preferred that the acid be selected from the group consisting of formic acid, acetic acid, glycolic acid, gluconic acid, lactic acid, mandelic acid, citric acid, glyoxylic acid and mixtures thereof. It is particularly preferred to use lactic acid in cosmetic compositions.
    The cosmetic compositions contain the acid, preferably in amounts of 0.1 to 6% by weight, more preferably in amounts of 0.25 to 4% by weight, and most preferably in amounts of between 0.5 and 2.5% by weight, based on their total weight respectively.
    The following section describes other ingredients of the cosmetic compositions, which may be contained in the compositions in addition to the mandatory ingredients described above. Other suitable ingredients include surfactants, fatty substances, waxes, protein hydrolysates, amino acids, oligopeptides, vitamins, provitamins, vitamin precursors, betaines, bioquinones, (derivatives) of purine, taurine derivatives, plant extracts, silicones, ester oils, UV light protection filters, structuring agents, thickeners, electrolytes, adjusting agents pH, blowing agents, dyes, anti-dandruff active ingredients, complexing agents, opacifying agents, pearlescent agents, pigments, stabilizing agents, propellants, antioxidants, perfume oils and / or preservatives.
    In addition, the cosmetic agents preferably contain at least one member representative of the group comprising anionic, amphoteric, zwitterionic, nonionic, cationic surfactants or mixtures thereof. Solid emulsifiers are preferably used at ambient temperature (20 ° C.), in particular nonionic solid emulsifiers at room temperature (20 ° C.).
    The partial glycerides of fatty acid, by which are meant monoglycerides, diglycerides and technical mixtures thereof, are suitable nonionic emulsifiers. Typical examples are mono and / or diglycerides based on caproic acid, caprylic acid, 2-ethylhexane acid, capric acid, lauric acid, isotridecanic acid, myristinic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, elaeostearic acid, arachidic acid, gadoleic acid, behenic acid and erucic acid, as well as technical households thereof. Oleic acid monoglycerides are preferably used. Another group of preferred emulsifiers is medium-chain surfactant fatty alcohols, particularly cetyl alcohol or stearyl alcohol.
    At least one cationic surfactant, selected from quaternary ammonium compounds, quaternary esters, amidoamines or mixtures thereof, is preferably usable. Preferred quaternary ammonium compounds are ammonium halides, particularly chlorides and bromides, such as alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides or trialkylmethylammonium chlorides. The long alkyl chains of these surfactants preferably have 10 to 18 carbon atoms, such as, for example, cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, distearyl dimethylammonium chloride, lauryldimethylammonium chloride, lauryldimethylbenzylammonium chloride and tricetylmethylammonium chloride. Other preferred cationic surfactants are the imidazolium compounds known under the INCI names Quaternium-27 and Quatemium-83.
    The additional surfactants are present in the compositions preferably in an amount of from 0.01% by weight to 5% by weight, particularly preferably from 0.1% by weight to 2.5% by weight, relative to the weight of the composition respectively.
    The water content of the cosmetic compositions represents at least 1% by weight, preferably at least 5% by weight and particularly preferably between 10 and 70% by weight, relative to the total weight of the cosmetic composition respectively.
    Preferred cosmetic compositions are characterized as follows: a) 0.1 to 10% by weight of a conditioning polymer selected from the group consisting of cationic guar compounds, poly (methacryloyloxyethyltrimethylammonium chloride), polymers known as INCI Polyquaternium-11, Polyquaternium-46 and Polyquaternium-72, and mixtures thereof b) 0.5 to 25% by weight of a thickening polymer, which comprises a compound known as INCI Polyacrylate-1 Crosspolymer, c 0.1 to 30% by weight of a film-forming polymer selected from the group consisting of polyvinylpyrrolidone (PVP), a copolymer containing vinylpyrrolidone and mixtures thereof, d) 1 to 35% by weight a humectant selected from the group consisting of polyols, polyether modified polysiloxanes and mixtures thereof, e) 0.1 to 6% by weight of an organic acid, and f) 1 to 70% by weight of water.
    In addition, more preferred cosmetic compositions are characterized as follows: a) 0.1 to 10% by weight of a conditioning polymer selected from the group consisting of cationic guar compounds, poly (methacryloyloxyethyltrimethylammonium chloride), known polymers under the INCI names Polyquatemium-11, Polyquaternium-46 and Polyquaternium-72, and mixtures thereof b) 0.5 to 25% by weight of a thickening polymer, which comprises a compound known as INCI Polyacrylate- Crosspolymer, c) 0.1 to 30% by weight of a film-forming polymer, which comprises polyvinylpyrrolidone and a VP / DMAPA Acrylate Copolymer, d) 1 to 35% by weight of a humectant selected from the group consisting of polyether modified polysiloxane, known as INCI PEG-12 Dimethicone or PEG-14 Dimethicone, glycerine, sorbitol, panthenol, polyethylene glycol, propylene glycol, butylene glycol, hexanediol and mixtures thereof ci, e) 0, 1 to 6% by weight of an organic acid selected from the group consisting of formic acid, acetic acid, glycolic acid, gluconic acid, lactic acid, mandelic acid, acid citric acid, glyoxylic acid and mixtures thereof, and f) 1 to 70% by weight water.
    More preferred cosmetic compositions are characterized as follows: a) 1 to 9% by weight of a conditioning polymer selected from the group consisting of cationic guar compounds, poly (methacryloyloxyethyltrimethylammonium chloride), polymers known as INCI Polyquaternium -11, Polyquaternium-46 and Polyquaternium-72, and mixtures thereof b) 5 to 20% by weight of a thickening polymer, which comprises a compound known as INCI Polyacrylate-1 Crosspolymer, c) 1 to 25% by weight of a film-forming polymer, which comprises polyvinylpyrrolidone and a VP / DMAPA Acrylate Copolymer, d) 5 to 30% by weight of a humectant selected from the group consisting of polyether modified polysiloxane, known as INCI PEG-12 Dimethicone or PEG-14 Dimethicone, glycerine, sorbitol, panthenol, polyethylene glycol, propylene glycol, butylene glycol, hexanediol and mixtures thereof, e) 0.25 to 4 % in weight of an organic acid selected from the group consisting of formic acid, acetic acid, glycolic acid, gluconic acid, lactic acid, mandelic acid, citric acid, acid glyoxylic and mixtures thereof, and f) 1 to 70% by weight of water.
    Even more preferred cosmetic compositions are characterized as follows: a) 2.5 to 7.5% by weight of a conditioning polymer selected from the group consisting of cationic guar compounds, poly (methacryloyloxyethyltrimethylammonium chloride), known polymers under the INCI names Polyquatemium-11, Polyquatemium-46 and Polyquatemium-72, and mixtures thereof b) 12.5 to 17.5% by weight of a thickening polymer, which comprises a compound known as INCI Polyacrylate-1 Crosspolymer, c) 5 to 20% by weight of a film-forming polymer, which comprises polyvinylpyrrolidone and a VP / DMAPA Acrylate Copolymer, d) 10 to 25% by weight of a humectant selected from the group consisting of polyether modified polysiloxane, known as INCI PEG-12 Dimethicone or PEG-14 Dimethicone, glycerine, sorbitol, panthenol, polyethylene glycol, propylene glycol, butylene glycol, hexanediol and mixtures thereof ci, e) 0, 5 to 2.5% by weight of an organic acid, which comprises lactic acid, and f) 10 to 70% by weight of water.
    Particularly preferred cosmetic compositions are characterized as follows: a) 2.5 to 7.5% by weight of a conditioning polymer, which comprises a polymer known as INCI Polyquaternium-72, b) 12.5 to 17, 5% by weight of a thickening polymer, which comprises a compound known as INCI Polyacrylate-1 Crosspolymer, c) 5 to 20% by weight of a film-forming polymer, which comprises polyvinylpyrrolidone and a VP / DMAPA Acrylates Copolymer d) 10 to 25% by weight of a humectant which contains at least three compounds selected from the group consisting of polyether modified polysiloxane known as INCI PEG-12 Dimethicone, glycerine, panthenol, propylene glycol and hexanediol, e) 0.5 to 2.5% by weight of an organic acid, which comprises lactic acid, and f) 10 to 70% by weight of water.
    A second object of this invention is the use of a cosmetic composition according to the invention for the temporary shaping of keratinous fibers, especially human hair. The human hair in question is most preferably human curly hair.
    A third object of this invention is the use of a cosmetic composition according to the invention for the improvement of at least one of the following properties of curly hair Loop holding, Elasticity of loops, Definition of loops, Shine and
    Hair styling facility
    The cosmetic compositions according to the invention can be used in a process for the temporary shaping of keratinous fibers, in particular of human hair, in which the keratinous fibers are impregnated with a cosmetic composition and temporarily fixed in the form they have outlet. The human hair in question is most preferably human curly hair. The cosmetic composition is preferably applied to shampooed hair and wiped with a towel and the hair is then dried in air or with heat, for example by means of an electric hair dryer, a curling iron or a charlotte, where appropriate using shaping means such as hair curlers or curl.
    With regard to the preferred embodiments of the use or the process according to the invention, what has been stated on the compositions applies mutatis mutandis.
    The composition of a preferred cosmetic composition A is found in the following table (the data in% by weight relate, unless otherwise indicated, to the total weight of the cosmetic agent).
    Formulation A is a transparent composition with pleasant, sensory properties. It does not leave a slippery / slippery sensation on the hand during application or on treated wet hair.
    Formulation A makes the hair treated with it easy to comb, gives it an intense shine, a healthy appearance and, in the presence of curls, a curly appearance, which lasts a long time, without sticking or stiffening the hair .
    权利要求:
    Claims (10)
    [1" id="c-fr-0001]
    claims
    1. Transparent cosmetic composition, containing, based on its total weight, a) 0.1 to 10% by weight of a conditioning polymer, b) 0.5 to 25% by weight of a thickening polymer, c) 0 0.1 to 30% by weight of a film-forming polymer, d) 1 to 35% by weight of a humectant, e) 0.1 to 6% by weight of an acid and f) 1 to 90% by weight. of water.
    [2" id="c-fr-0002]
    2. transparent cosmetic composition according to claim 1 characterized in that the film-forming polymer is selected from the group consisting of polyvinylpyrrolidone (PVP), a copolymer containing vinylpyrrolidone and mixtures thereof.
    [3" id="c-fr-0003]
    3. Transparent cosmetic composition according to any one of the preceding claims characterized in that the film-forming polymer comprises a mixture of polyvinylpyrrolidone (PVP) and a polymer known under the name INCIVP / DMAPA Acrylates Copolymer.
    [4" id="c-fr-0004]
    4. Transparent cosmetic composition according to any one of the preceding claims, characterized in that the conditioning polymer chosen from the group consisting of cationic guar compounds, poly (methacryloyloxyethyltrimethylammonium chloride), polymers known by the INCI name Polyquatemium-11, Polyquatemium-46 and Polyquatemium-72, and mixtures thereof.
    [5" id="c-fr-0005]
    5. Transparent cosmetic composition according to any one of the preceding claims, characterized in that the conditioning polymer comprises a compound known as INCI Polyquatemium-72.
    [6" id="c-fr-0006]
    6. Transparent cosmetic composition according to any one of the preceding claims, characterized in that the thickening polymer comprises a compound known by the name INCI Polyacrylate-1 Crosspolymer.
    [7" id="c-fr-0007]
    The transparent cosmetic composition according to any one of the preceding claims characterized in that the humectant is selected from the group consisting of polyols, polyether modified polysiloxanes and mixtures thereof.
    [8" id="c-fr-0008]
    8. Transparent cosmetic composition according to any one of the preceding claims, characterized in that the acid is an organic acid selected from the group consisting of formic acid, acetic acid, glycolic acid, gluconic acid, lactic acid, mandelic acid, citric acid, glyoxylic acid and mixtures thereof.
    [9" id="c-fr-0009]
    9. Transparent cosmetic composition according to any one of the preceding claims, characterized in that it additionally contains a cationic surfactant.
    [10" id="c-fr-0010]
    10. Use of a cosmetic composition according to any one of claims 1 to 9 for improving at least one of the following properties of curly hair: holding loops, elasticity loops, definition of loops, shine and ease of capping
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    法律状态:
    2018-02-23| PLFP| Fee payment|Year of fee payment: 2 |
    2020-02-19| PLFP| Fee payment|Year of fee payment: 4 |
    2021-02-24| PLFP| Fee payment|Year of fee payment: 5 |
    2021-03-26| PLSC| Publication of the preliminary search report|Effective date: 20210326 |
    2022-02-16| PLFP| Fee payment|Year of fee payment: 6 |
    优先权:
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    DE102016203231.3A|DE102016203231A1|2016-02-29|2016-02-29|Means for the temporary deformation of keratin-containing fibers with a polymer mixture|
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