• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    The present invention relates to a method for producing a three-dimensional preform comprising the production of an initial preform (4) comprising several superimposed folds, said folds being formed from unidirectional continuous fibers and a first polymer, and the thermoforming of the initial preform between the male forming tool (92) and the female forming tool (91) of a press (9) to obtain a three-dimensional preform (1). During forming, an outer web is positioned at the interface between the initial preform (4) and the male tool (62) and at the interface between the initial preform and the female tool (91) said outer webs being formed from a second polymer, so that, during forming, the outer webs remain in the solid state and deform.
    公开号:FR3047196A1
    申请号:FR1670024
    申请日:2016-02-02
    公开日:2017-08-04
    发明作者:Johannes Treiber
    申请人:Coriolis Composites SAS；
    IPC主号:
    专利说明:

    The present invention relates to a method for producing three-dimensional preforms of composite material.
    There are known methods for producing a three-dimensional preform comprising the production of an initial preform formed of several folds of superposed fibers, and the forming of the initial preform between the male forming tool and the female forming tool. a press to obtain a three-dimensional preform with its desired final shape. The three-dimensional preform is then used to form a composite material part.
    The initial preform can be made from woven or non-woven unidirectional fibers pre-impregnated with a thermoplastic or thermosetting polymer. The forming is conventionally carried out hot, at a so-called forming temperature in order to increase the formability of the initial preform. During forming, several deformation mechanisms intervene, including inter-ply friction mechanisms, friction mechanisms between the preform and the tools, intra-fold shear mechanisms, and bending mechanisms.
    Depending on the shape of the final preform, especially in the case of a complex shape preform, for example double curvature, the fibers tend to wrinkle.
    The object of the present invention is to propose a solution for limiting defects in three-dimensional preforms of complex shapes. For this purpose, the present invention proposes a method for producing a three-dimensional preform comprising the production of an initial preform comprising several superimposed folds, said folds being formed from unidirectional continuous fibers and a first polymer, and thermoforming of the initial preform between the male forming tool and the female forming tool of a press to obtain a three-dimensional preform, characterized in that during forming, an outer web is arranged at the interface between the initial preform and the male tool and at the interface between the initial preform and the female tool, said outer webs being formed from a second polymer, different from the first polymer so that, during forming, the outer webs remain at the same location. solid state and deform.
    According to the invention, webs are arranged between the preform and the tools of the press, the temperature of the preform during forming, called a forming temperature, is defined so that the webs can be deformed to take up the frictional forces between the sails and the tools. The sails remain in a solid state during forming, deform by elongation or breakage and allow the preform to slide in the press without adherence. The outer sails stabilize the outer surfaces of the preform by limiting or eliminating the local deformations of the preform and thus ensure a homogeneous deformation of the fibers of the preform. The sails limit the contact between the first polymer and the surface of the tools. The dry friction forces between the webs and the tools are less important than the viscous friction forces between the polymer fibers and the tools.
    The method according to the invention thus makes it possible to promote the sliding mechanisms between the forming tools and the preform, and thus to limit, or even eliminate, the fiber defects of the outer plies of the preforms resulting from the friction between the preform and the tooling of the preforms. forming in previous forming processes.
    The initial preform can be two-dimensional, obtained by draping on the flat surface of a tool, or three-dimensional, the forming can then be performed to obtain three-dimensional pieces of complex shape that can not be obtained by draping, including fiber placement.
    The method according to the invention may advantageously be used for the production of composite material parts, particularly in the field of automotive or aerospace.
    Furthermore, the sails limit or even eliminate the direct contact of the first polymer with the tools and thus the problems of adhesion between the preform and the tools, thus facilitating demolding.
    The sails may be applied to the outer folds of the initial preform after the latter has been completed, automatically or manually, preferably with heat applied to ensure the sails remain on the preform during subsequent manipulations of the preform. According to another embodiment, the first fold is draped over a first outer web previously positioned on the draping tool. After draping the set of folds, a second outer web is applied on the last fold. According to another embodiment, the webs are positioned on the preform and / or on one or the tooling of the press. The unidirectional continuous fibers, preferably applied by placing fibers, are, for example, carbon fibers, glass fibers, synthetic fibers such as aramid fibers, polyethylene fibers, and / or natural fibers, such as that for example flax fibers.
    The forming is carried out hot, the initial preform being heated to a forming temperature before and / or during forming to increase the formability of the preform. The initial preform may be preheated prior to forming by passage through an oven or tunnel and / or the preform may be heated upon forming by heating the male forming tool and / or the female forming tool. Preferably, in particular in the case of dry preforms, the preform is only preheated by passage in an oven or tunnel, the tools of the press not being heated, thereby simplifying the press tools.
    The second polymer may be a thermoplastic or thermosetting polymer, preferably a thermoplastic polymer.
    According to one embodiment, the outer webs are formed of a second thermoplastic polymer, the forming is performed at a forming temperature lower than the melting temperature of the second polymer, and preferably below the glass transition temperature of the second polymer . In the case of a first thermoplastic polymer, the first polymer is preferably in a viscous liquid or liquid state at the forming temperature, the forming temperature is preferably greater than the glass transition temperature of the first polymer, preferably close to the melting temperature of the first polymer, for example slightly higher than the melting temperature of the first polymer, for better formability of the preform, the melting temperature of the second polymer being greater than that of the first polymer. In the case of a first thermosetting polymer, the first polymer is preferably in a viscous liquid or liquid state at the forming temperature, the forming temperature is preferably greater than the glass transition temperature of the first polymer and less than curing or crosslinking temperature of the first polymer.
    According to another embodiment, the outer webs are formed of a second thermosetting polymer, the forming is performed at a forming temperature, at which the second polymer remains solid, preferably less than the glass transition temperature of the second polymer.
    In the case of thermoplastic polymer, the first thermoplastic polymer and / or the second thermoplastic polymer are for example chosen from the group consisting of polyamides, polyesters such as polyethylene terephthalate, polyethersulfones, polyetheretherketones, polyphenylene sulfides, polyurethanes, epoxides, polyolefins, polylactic acid, or a mixture of one or more of these polymers.
    In the case of thermosetting polymer, the first thermosetting polymer and / or the second thermosetting polymer are for example chosen from the group consisting of epoxides, polyesters, vinyl esters, phenolics, polyimides, or bismaleimides,
    According to one embodiment, the outer webs are nonwoven webs formed of randomly oriented second polymer filaments. In this embodiment, the non-woven structure of the sails increases the permeability of the preform and thus makes it possible to promote infusion and / or injection, the sails conferring a draining effect, more particularly in the case of an infusion. The sails may further increase the impact strength of the preform and / or improve the surface appearance of the preform.
    According to one embodiment, the outer webs are nonwoven webs of thermoplastic polymer.
    According to another embodiment, the web is formed of a polymer film, in particular of thermoplastic polymer.
    According to one embodiment, said method comprises the production of an initial so-called dry preform, comprising fibers provided with a binder formed of the first polymer, the preform comprising less than 10% by weight of binder, preferably less than 5% by weight of binder, the so-called dry three-dimensional preform obtained after thermoforming being subjected to an impregnation operation of an impregnating polymer, compatible with the first polymer, by injection and / or infusion, to form a piece of composite material . Dry preforms with binder include a small amount of binder, generally less than 5%, to maintain the cohesion of the preform, while allowing its subsequent impregnation. The dry preforms are obtained by application of dry fibers provided with a binder and / or by application of dry fibers, without binder, and application of binder, for example by spraying a liquid binder and / or the projection of a binder in powder form, on the application surface and / or dry fibers previously draped.
    According to another embodiment, the initial preform is made from fibers pre-impregnated with a first thermoplastic or thermosetting polymer, in a quantity sufficient to form the matrix of the final composite part, the process comprising the production of a pre-impregnated initial preform comprising at least 30% by weight of first polymer, preferably at least 40% by weight, the first polymer constituting the matrix of the piece of composite material obtained from the three-dimensional preform, after a possible operation of consolidation or cooking.
    According to one embodiment, the outer webs have a basis weight of 4 to 35 g / m 2, preferably of at least 10 g / m 2.
    According to one embodiment, the webs are polyamide (PA) webs, in particular copolyamide webs.
    According to one embodiment, the forming is carried out at a forming temperature at which the first polymer is in the liquid or viscous liquid state, the forming temperature being greater than the glass transition temperature of the first polymer.
    According to one embodiment, said initial preform comprises at least one internal web interposed between two folds of the initial preform, said internal web being formed from a third polymer, said third polymer preferably being in the solid state during the forming so as to favor the sliding mechanisms between the two folds. The internal veils limit the contacts between the two plies, and thus the bonding of the two plies by the first polymer. Such internal webs thus make it possible to increase the formability of the preform. The third polymer is a thermoplastic or thermosetting polymer, the forming temperature being lower than the glass transition temperature of the third polymer.
    Moreover, in the case of dry preforms, the internal webs increase the permeability of the preform and favor the infusion and / or injection operation,
    According to one embodiment, the initial preform is produced by the so-called fiber placement method 12, the production of the initial preform comprises the production of superimposed folds in defined orientations, by application to the contact, by means of a roll of application or compacting of unidirectional continuous fibers on a draping tool, each fold being made by applying one or more strips in an orientation on the draping tool or on strips of the preceding fold, each strip being formed of one or more fibers. The placement of fibers is advantageously automated by means of a fiber placement head, known per se, comprising a compacting roller intended to come into contact against the tooling for applying a strip formed of one or more continuous flat fibers, and a guide system for guiding the at least one fiber on said roller, by relative movement of the applicator head relative to the drape surface along different paths.
    The said unidirectional continuous fibers are preferably in the form of flat unidirectional continuous fibers, conventionally called wicks, comprising a multitude of filaments. The fibers, for example, have widths of one-eighth, one-quarter or one-half inch (1/8 ", 1/4" or 1/2 "). also fibers of greater width, greater than 1/2 inch, conventionally called a strip in the placement technology The deposited fibers may be dry fibers provided with a binder, or fibers pre-impregnated with thermosetting or thermoplastic polymer.
    According to other embodiments, the folds of the preform are obtained by superposition of tissue. The invention will be better understood, and other objects, details, features and advantages will become more clearly apparent from the following detailed explanatory description of particular embodiments currently preferred of the invention, with reference to the accompanying schematic drawings, in which: - Figure 1 is a schematic sectional view of an example of a three-dimensional preform made according to the method according to the invention; - Figure 2 is a schematic side view illustrating the draping operation of the initial preform; - Figure 3 is a schematic side view illustrating the application of external webs on the initial preform; - Figures 4 and 5 are schematic sectional views of the press illustrating the forming operation of the initial preform of Figure 3; and - Figure 6 is a schematic view of the stack of folds of an initial preform according to a second embodiment, provided with two outer webs, and two internal webs.
    FIG. 1 illustrates an example of a three-dimensional preform 1 that can be produced according to the method according to the invention, by lay-up of continuous fibers and forming. The preform has the shape of a spherical cap 11 with an annular rim 12.
    Figures 2 to 5 illustrate the steps of the method of producing this three-dimensional preform 1.
    In a first step, as shown in Figure 2, continuous unidirectional fiber plies are draped flat on a lay-up tool 2 in different orientations to form a two-dimensional initial plate or preform.
    The draping is carried out by means of a fiber placement head 3, known per se, allowing automatic draping in contact with strips formed of one or more fibers. The fibers F enter the head 3 in the form of two plies of fibers, and the head comprises a guide system 31 for guiding the fibers to the compaction roller 32 in the form of a fiber web in which the fibers are arranged side by side, for example substantially edge to edge. The head comprises, on either side of the guiding system, cutting means 33 for individually cutting each fiber passing through the guiding system, locking means 34 for blocking each fiber that has just been cut, and means rerouting 35 to individually drive each fiber, so that at any time stop and resume the application of a fiber, and choose the width of the band. The draping of a strip is achieved by relative movement of the head relative to the substantially planar draping surface of the draping tool. The head comprises for example a support structure (not shown) on which is mounted the guide system and by which the head can be assembled to a displacement system, able to move the head in at least two directions perpendicular to each other. 'other. The head is for example designed to receive eight fibers, and allow the application of strips of 1 to 8 fibers 6.35 mm (1/4 inch) wide. For example, the head is used for the production of a dry preform, from dry fibers provided with a binder conventionally called "binder", to impart a stickiness to the fibers during the draping and ensure the cohesion of the preform. The binder consists of a first polymer in powder form and / or one or more webs. The fibers are, for example, carbon fibers, continuous flat, of the wick type, comprising a multitude of carbon threads or filaments, with a thermoplastic binder in the form of powder, present in an amount of about 2% by weight. . The initial preform 4 is for example made by draping seven plies of fibers in different orientations, according to the following stack: + 45% 4570790707-45 7 + 45 °.
    The head 3 is equipped with a heating system (not shown), for example of the IR or laser lamp type, in order to heat the binder while the fibers are being applied, and thus to allow at least one adhesion of the fibers of the various plies. and ensuring the cohesion of the set of folds of the preform for its subsequent transfer and forming. The heating system heats the fibers before they are applied to the application surface, as well as the application surface or the fibers previously deposited, upstream of the roll relative to the direction of advance of the head.
    After completion of the initial preform, external webs 51, 52 are applied to the two surfaces of the initial preform, as schematically illustrated in FIG. 3. The outer webs are here of non-woven type, formed of filaments in one. second thermoplastic polymer, having a melting point higher than the melting point of the first thermoplastic polymer constituting the binder of the preform.
    The sails can be applied automatically, semi-automatically or manually. To ensure the maintenance of the webs on the preform, the webs are for example placed on the outer folds of the preform which form the two main surfaces of the preform, then pressed against the preform by heating to at least soften the binder of the preform and glue a first outer veil 51 on the first 45 ° fold of the preform and a second outer veil 52 on the last 45 ° fold of the preform. Preferably, the heating is carried out at a temperature below the melting point of the second polymer, preferably below its glass transition temperature. The non-woven structure of the sails ensure a good bond of the sails to the preforms, the first polymer coming between the filaments of the sails.
    The initial preform provided with external webs is then transferred to a press for the forming operation, also referred to as a stamping operation.
    As illustrated in FIG. 4, the press 9 comprises a female forming tool 91 or die, having a recess whose shape corresponds to that of the spherical cap 12 of the preform to be produced, and a male forming tool 92, or punch, comprising a boss of complementary shape. The forming is performed by relative approximation of the male forming tool and the female forming tool, an open position of the press illustrated in Figure 4 to a closed position of the press illustrated in Figure 5.
    The forming is performed hot, the preform being at a forming temperature greater than or equal to the melting temperature of the first polymer and lower than the melting temperature of the sails, so that the sails remain in the solid state during forming . During forming, the outer webs deform by elongation or tearing. The sails glued to the outer folds of the preform stabilize said folds, the sails distributing the friction forces and limiting the local deformations of the fibers of said folds. This forming temperature of the preform is obtained by preheating the preform before positioning in the press and / or by heating the two tools 91, 92. This preheating is for example carried out by passing the initial preform between the upper infrared lamp ramps. and bottom of an oven or preheating tunnel. Preferably, during forming, the preform is kept under tension by a tensioning system, for example of the blank type, as shown schematically under the reference 8. By way of example, the first polymer of the preform is formed of a thermoplastic epoxy polymer having a melting point of the order of 130 ° C. The outer webs are each formed of a nonwoven copolyamide thermoplastic web having a basis weight of 12 g / m 2 and a melting point of about 180 ° C as sold by Spunfab or Protechnic. . The sails are applied to the initial preform at a temperature of 140 ° C, and the forming is carried out at a temperature of 140 ° C.
    The tools 91, 92 are then spaced apart from each other in the open position to be able to demold the three-dimensional preform of the press, the outer webs facilitating this demolding operation.
    The resulting three-dimensional preform is then subjected to an operation of adding an impregnating, thermosetting or thermoplastic polymer, by an injection and / or infusion process, and then to a trimming operation, to form a composite material part. .
    According to another variant embodiment, the initial preform is made from fibers pre-impregnated with a thermoplastic resin. The fibers are, for example, carbon fibers, continuous flat, of the wick type, comprising a multitude of carbon threads or filaments, with a thermoplastic polymer, present in an amount of the order of 40% by weight, this polymer constituting the matrix of the final piece.
    FIG. 6 illustrates an initial preform according to another embodiment, which differs mainly from the preceding preform in that internal webs are positioned between the folds at 0 ° and -45 °. The preform comprises as before a stack of seven folds at 45o / -4570o / 90 ° / 07-45% i-45o, formed from dry fibers provided with a binder or first thermoplastic polymer.
    A first thermoplastic nonwoven outer web is applied to the drape surface of the draping tool, and the first 40 ° oriented fold of the preform is draped directly by fiber placement on the first outer web. After draping the second fold at -45 °, a first internal nonwoven web 61 formed of a third thermoplastic polymer is positioned on the second fold. The third, fourth and fifth folds respectively, oriented respectively at 0 °, 90 ° and 0 ° are draped, and a second internal web 62 nonwoven, identical to the first internal web, is positioned on the fifth fold. The sixth and seventh plies at -45 ° and + 45 ° are draped, and a second thermoplastic nonwoven outer web 152 is positioned on the last ply.
    During forming, the temperature of the preform is raised to a temperature above the melting point of the first polymer, and lower than the melting point of the second polymer and the third polymer. By way of example, the external webs are, as before, non-woven webs of copolyamide, having a melting point of 180 ° C., and a basis weight of 12 g / m 2, and the internal webs are also nonwoven webs. copolyamide having a melting point of 180 ° C and a basis weight of 15 g / m 2.
    The forming is carried out at a temperature of 150 ° C, so that the internal webs and outer webs remain in a solid state. The internal sails promote sliding between the folds at 0 ° and 45 °, while the outer sails promote sliding on the forming tools. After forming, the three-dimensional preform is subjected to an infusion operation or injection of an impregnating polymer, the internal veils now the folds apart and thus promoting the infusion or injection.
    Although the invention has been described in connection with various particular embodiments, it is obvious that it is not limited thereto and that it comprises all the technical equivalents of the means described and their combinations if they are within the scope of the invention.
    权利要求:
    Claims (13)
    [1" id="c-fr-0001]
    A method of producing a three-dimensional preform (1) comprising: producing an initial preform (4) comprising a plurality of superposed plies, said plies being formed from unidirectional continuous fibers and a first polymer, and thermoforming the initial preform between the male forming tool (92) and the female forming tool (91) of a press (9) to obtain a three-dimensional preform (1), characterized in that during forming, a outer web (51, 52; 151, 152) is disposed at the interface between the initial preform (4) and the male tool (92) and at the interface between the initial preform and the female tool (91), said outer webs being formed from a second polymer so that, during forming, the outer webs remain in the solid state and deform.
    [2" id="c-fr-0002]
    2. Method according to claim 1, characterized in that the outer webs (51, 52; 151, 152) are formed of a second thermoplastic polymer, the forming is performed at a forming temperature lower than the melting temperature of the second polymer.
    [3" id="c-fr-0003]
    3. Method according to claim 1, characterized in that the outer webs (51, 52; 151, 152) are formed of a second thermosetting polymer, the forming is performed at a forming temperature, at which the second polymer remains solid. .
    [4" id="c-fr-0004]
    4. Method according to one of claims 1 to 3, characterized in that the outer webs (51, 52; 151, 152) are nonwoven webs formed of second polymer filaments.
    [5" id="c-fr-0005]
    5. Method according to claims 2 and 4, characterized in that the outer webs (51, 52; 151, 152) are nonwoven webs of thermoplastic polymer.
    [6" id="c-fr-0006]
    6. Method according to one of claims 1 to 5, characterized in that it comprises the production of a dry initial preform (4) comprising fibers provided with a binder formed of the first polymer, the dry three-dimensional preform obtained after the thermoforming being subjected to an impregnating operation of an impregnating polymer, by injection and / or infusion, to form a piece of composite material.
    [7" id="c-fr-0007]
    7. Method according to one of claims 1 to 5, characterized in that it comprises the production of an initial prepreg preform comprising at least 30% by weight of first polymer, the first polymer constituting the matrix of the piece composite material obtained from the three-dimensional preform.
    [8" id="c-fr-0008]
    8. Method according to one of claims 1 to 7, characterized in that the outer webs (51, 52; 151, 152) have a basis weight of 4 to 35 g / m2.
    [9" id="c-fr-0009]
    9. The method of claim 2 in combination with one of claims 4 to 8, characterized in that the outer webs are polyamide webs.
    [10" id="c-fr-0010]
    10. Method according to one of claims 1 to 9, characterized in that the forming is carried out at a forming temperature at which the first polymer is in the liquid or viscous liquid state.
    [11" id="c-fr-0011]
    11. Method according to one of claims 1 to 10, characterized in that said initial preform comprises at least one internal web (61, 62) interposed between two folds of the initial preform, said internal web being formed from a third polymer, said third polymer being in the solid state during forming.
    [12" id="c-fr-0012]
    12. Method according to one of claims 1 to 11, characterized in that the realization of the initial preform (4) comprises the realization of superimposed folds, by application to contact, by means of an application roller (32) , of unidirectional continuous fibers on a draping tool (2), each fold being made by applying one or more strips in an orientation on the draping tool or on strips of the preceding fold, each band being formed of a or more fibers.
    [13" id="c-fr-0013]
    13. Method according to one of claims 1 to 12, characterized in that the initial preform is preheated before forming.
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    同族专利:
    公开号 | 公开日
    FR3047196B1|2018-09-28|
    ES2785666T3|2020-10-07|
    EP3411207B1|2020-02-26|
    EP3411207A1|2018-12-12|
    CN108602205A|2018-09-28|
    WO2017134356A1|2017-08-10|
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    法律状态:
    2017-01-23| PLFP| Fee payment|Year of fee payment: 2 |
    2017-08-04| PLSC| Publication of the preliminary search report|Effective date: 20170804 |
    2018-01-23| PLFP| Fee payment|Year of fee payment: 3 |
    2018-12-07| TP| Transmission of property|Owner name: CORIOLIS GROUP, FR Effective date: 20180925 |
    2020-01-22| PLFP| Fee payment|Year of fee payment: 5 |
    2021-11-12| ST| Notification of lapse|Effective date: 20211005 |
    优先权:
    申请号 | 申请日 | 专利标题
    FR1670024A|FR3047196B1|2016-02-02|2016-02-02|METHOD FOR MAKING THREE DIMENSIONAL PREFORMS BY FORMING INITIAL PREFORMS WITH SAILS|
    FR1670024|2016-02-02|FR1670024A| FR3047196B1|2016-02-02|2016-02-02|METHOD FOR MAKING THREE DIMENSIONAL PREFORMS BY FORMING INITIAL PREFORMS WITH SAILS|
    ES17704806T| ES2785666T3|2016-02-02|2017-01-23|Procedure for making three-dimensional preforms by forming initial preforms with veils|
    PCT/FR2017/000017| WO2017134356A1|2016-02-02|2017-01-23|Method for producing three-dimensional preforms by forming initial preforms with webs|
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