• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    An optical fiber having reduced attenuation comprises a silica glass core and a silica glass sheath. The silica glass core has virtually no germanium and includes a first heart and a second heart. The second heart encloses the first heart, the refractive index of the second heart is greater than the refractive index of the first heart, and the average value of the halogen concentration in the second heart is 5000 ppm or more. The silica glass sheath surrounds the second core and contains practically no germanium. The refractive index of the sheath is smaller than the refractive index of the first core.
    公开号:FR3042606A1
    申请号:FR1659952
    申请日:2016-10-14
    公开日:2017-04-21
    发明作者:Yoshiaki Tamura；Tetsuya Haruna；Masaaki Hirano；Hirotaka Sakuma
    申请人:Sumitomo Electric Industries Ltd；
    IPC主号:
    专利说明:

    Field of the invention
    The present invention relates to an optical fiber.
    BACKGROUND ART The attenuation of an optical fiber comprises Rayleigh scattering loss, structural imperfection loss, OH absorption loss, and infrared absorption loss. Of these, the Rayleigh scattering loss represents about 80% of the attenuation at a wavelength of 1550 nm, including that resulting from a density fluctuation and that resulting from a fluctuation of concentration (see FIG. E. Lines, J. Appl Phys 55, 4052 (1984)).
    An optical fiber having a pure silica core which contains substantially no metal dopants such as GeO 2 to increase the refractive index is designed to have an optical waveguide structure in which the refractive index of the sheath is rendered inferior to that of the core by addition of fluorine to the sheath. In such an optical fiber having a pure silica core, diffusion loss due to a concentration fluctuation is reduced since the core contains chlorine (Cl) only and contains substantially no dopants other than chlorine (see Japanese Patent placed under public inspection N ° 2005-202440). On the other hand, it is known that splice loss can be reduced if the core has a ring-shaped refractive index profile (see Japanese Patent Laid-Open No. 2013-61620). In order to obtain the ring-shaped profile, it is necessary to dope the core with dopants to change the refractive index, such as germanium and fluorine. SUMMARY OF THE INVENTION OBJECT OF THE INVENTION The object of the present invention is to provide an optical fiber in which the attenuation is reduced.
    Means to reach the object
    An optical fiber of the present invention comprises: (1) a silica glass core having substantially no germanium and comprising a first core and a second core, the second core enclosing the first core, the refractive index of the second core; heart being greater than the refractive index of the first core, and the average value of halogen concentration in the second core being 5000 ppm or more; and (2) a silica glass sheath surrounding the second core and substantially free of germanium, the refractive index of the sheath being less than the refractive index of the first core.
    In the optical fiber of the present invention, the relative refractive index difference of the second core may be -0.05% or more and +0.05% or less with respect to the refractive index of the second glass. pure silica. The concentration of fluorine in the second core may be 500 ppm or more and 10000 ppm or less. The concentration of chlorine in the second core can be 4500 ppm or more and 15000 ppm or less. In addition, in the second core, the concentration of chlorine may be higher than the fluorine concentration.
    In the optical fiber of the present invention, the concentration of fluorine in the first core may be 5000 ppm or more and 15000 ppm or less. The concentration of chlorine in the first core may be 10 ppm or more and 1000 ppm or less. The difference in relative refractive index between the first core and the second core may be preferably 0.05% or more and 0.15% or less. If H2 is considered to be the second core halogen concentration and H1 is the first core halogen concentration, the H2 / H1 ratio can preferably be 1 or more and 2 or less. In addition, the aforementioned core may contain both an alkali metal and an alkaline earth metal, or any of these. The term "silica glass" as used in this specification means a glass that contains SiO 2 as the main component. The term "atomic ppm" means the number of dopant atoms in one million SiO 2 units.
    Effect of the invention
    According to the present invention, it is possible to provide an optical fiber in which the attenuation is reduced.
    BRIEF DESCRIPTION OF THE DRAWINGS
    Figure 1 is a schematic diagram showing the refractive index profile of an optical fiber according to an embodiment of the present invention.
    Figure 2 is a graph showing the relationship between the average halogen concentration in the second core and the amount of increase / decrease of its attenuation at a wavelength of 1550 nm with respect to the optical fiber of Figure 1 .
    Figure 3 is a graph showing the relationship between the average fluorine concentration in the second core and the amount of increase / decrease in attenuation at a wavelength of 1550 nm relative to the optical fiber of Figure 1 .
    Figure 4 is a graph showing the relationship between the average chlorine concentration in the second core and the amount of increase / decrease in attenuation at a wavelength of 1550 nm relative to the optical fiber of Figure 1 .
    Figure 5 is a graph showing the relationship between the fluorine concentration in the first core and the amount of increase / decrease in attenuation at a wavelength of 1550 nm relative to the optical fiber of Figure 1.
    Figure 6 is a table summarizing the average potassium concentration in the core region of an optical fiber blank, the average fluorine concentration and the average chlorine concentration in the first core, the average fluorine concentration and the concentration of average chlorine in the second core, and the attenuation at a wavelength of 1550 nm with respect to the optical fiber of Figure 1.
    Figure 7 is a graph showing the relationship between the average potassium concentration in the core region of an optical fiber blank and the attenuation of the resulting optical fiber at a wavelength of 1550 nm.
    Figure 8 is a graph showing the relationship between attenuation at a wavelength of 1550 nm and the ratio H2 / H1 in which H2 represents the concentration of halogens in the second core and H1 represents the concentration of halogens in the first core, with respect to the optical fiber of Figure 1.
    DETAILED DESCRIPTION OF THE INVENTION
    Preferred embodiments of the present invention will hereinafter be described in detail with reference to the accompanying drawings. The invention is not limited to these embodiments, and it is intended that the invention be represented by the scope of the claims, including an equivalent to a claim and any modifications within the scope of the claim. invention.
    Figure 1 is a schematic diagram showing the refractive index profile of an optical fiber 1 according to an embodiment of the present invention. The optical fiber 1 has a core 10 made of silica-based glass and a sheath 20 enclosing the core 10 and made of silica-based glass. The heart 10 consists of a first core 11 and a second core 12 enclosing the first core 11. The refractive index of the second core 12 is greater than the refractive index of the first core 11. The index The refraction of the sheath 20 is smaller than the refractive index of the first core 11. The core 10 and the sheath 20 contain substantially no germanium.
    The core contains fluorine and chlorine. Sheath 20 contains fluorine. By doping the glass with fluorine, the viscosity of the glass can be reduced and the refractive index of the glass can be decreased. Also, by doping the glass with chlorine, the viscosity of the glass can be reduced and the refractive index of the glass can be increased. The optical fiber 1 can be produced by drawing an optical fiber blank having the same refractive index profile as that of the optical fiber of FIG. 1.
    Figure 2 shows a graph showing the relationship between the average halogen concentration in the second core 12 and the amount of increase / decrease in attenuation at a wavelength of 1550 nm. Table 1 is a summary of the relationship between the average halogen concentration in the second core 12 and the amount of increase / decrease in attenuation at a wavelength of 1550 nm. The halogen concentration is the sum of the fluorine concentration and the concentration of chlorine in the glass. The amount of increase / decrease of the attenuation of an optical fiber is represented on the basis of the attenuation in the case where the first core 11 of the optical fiber 1 contains 5000 ppm of fluorine and the second core 12 contains practically no halogen.
    Table I
    As can be seen from Figure 2 and Table I, the attenuation of the optical fiber 1 at a wavelength of 1550 nm is reduced compared with the standard value when the average halogen concentration in the second core 12 of the optical fiber 1 is 5000 atomic ppm or more and 20,000 atomic ppm or less. When the average halogen concentration in the second core 12 of the optical fiber 1 is 20000 atomic ppm or more, the diffusion loss due to a concentration fluctuation increases when the concentration of halogens increases, and therefore the attenuation of the optical fiber 1 increases. Therefore, the optimum range of the average halogen concentration in the second core 12 of the optical fiber 1 is 5000 to 20000 atomic ppm.
    It is possible to calculate the optical power of each region of the optical fiber 1 by integration according to the following formula (1):
    --- (1), where the radial distance from the central axis of the optical fiber 1 is r, and the distribution of the optical power is P (r). As a result of this calculation, the integration value of the optical power of the second core 12 is greater than the integration value of the optical power of the first core 11, and it is assumed that the influence of the glass of the second core 12 affects significantly the attenuation of the optical fiber 1.
    Therefore, in order to reduce the diffusion loss due to a fluctuation of the refractive index of the dopants in the second core 12, the refractive index of the second core 12 is preferably closer to that of the pure silica glass. In fact, when the difference in relative refractive index of the second core is -0.05% or more and +0.05% or less with respect to the refractive index of pure silica glass, then observe no attenuation due to a fluctuation of the refractive index. In addition, when the absolute value of the relative refractive index difference of the second core 12 is greater than 0.05% relative to the pure silica glass which contains practically no halogen, the attenuation of the optical fiber 1 is greater than 0.001 dB / km or more with respect to an optical fiber having a second core made of pure silica glass.
    Figure 3 is a graph showing the relationship between the average fluorine concentration in the second core 12 and the amount of increase / decrease in attenuation at a wavelength of 1550 nm. Table II is a summary of the relationship between the average fluorine concentration in the second core 12 and the amount of increase / decrease in attenuation at a wavelength of 1550 nm. The average chlorine concentration in the second core 12 is 11000 ppm. The amount of increase / decrease of the attenuation of the optical fiber 1 is based on the attenuation in the case where the average fluorine concentration in the second core 12 of the optical fiber 1 is zero atomic ppm.
    Table II
    As shown in Figure 3 and Table II, when the average fluorine concentration in the second core 12 is 500 ppm or more and 10000 ppm or less, the attenuation of the optical fiber 1 at a wavelength of 1550 nm decreases by 0.001 dB / km compared to the standard value. Also, when the average fluorine concentration in the second core 12 is 2000 ppm or more and 5000 ppm or less, the attenuation of the optical fiber 1 at a wavelength of 1550 nm decreases by 0.002 dB / km by compared to the standard value. In the case where the concentration of fluorine in the second core 12 is increased, the attenuation due to distortion of the glass is reduced as a result of a decrease in the viscosity of the glass. On the other hand, in the case where the concentration of fluorine in the second core 12 is 5000 ppm or more, the attenuation due to a fluctuation of the refractive index increases because of the fluorine doping. When the concentration of fluorine in the second core 12 is 10000 ppm or more, which exceeds the effective range of the attenuation reduction due to a decrease in viscosity, the attenuation generally worsens.
    Figure 4 is a graph showing the relationship between the average chlorine concentration in the second core 12 and the amount of increase / decrease in attenuation at a wavelength of 1550 nm. Table III is a graph showing the relationship between the average chlorine concentration in the second core 12 and the amount of increase / decrease in attenuation at a wavelength of 1550 nm. The average fluorine concentration in the core of the optical fiber 1 is set at 2000 atomic ppm. The amount of increase / decrease of the attenuation of the optical fiber 1 is based on the attenuation in the case where the average chlorine concentration in the second core 12 of the optical fiber 1 is 2000 atomic ppm.
    Table III
    As can be seen from Figure 4 and Table III, the attenuation of the optical fiber 1 at a wavelength of 1550 nm decreases from 0.001 to 0.015 dB / km compared to the standard value when the concentration Average chlorine in the second core 12 of the optical fiber 1 is 4500 atomic ppm or more and 15000 atomic ppm or less. The reason for this is that the viscosity of the glass is reduced by the addition of chlorine to the second core 12, and the attenuation due to the distortion of the glass is reduced. When the concentration of chlorine in the second core 12 increases, the attenuation available at the time when 15,000 ppm of chlorine are added is less than the available attenuation in the case where no chlorine is added. It is presumed that when chlorine is added in the second core 12 at a higher concentration, a reduced loss should be achievable. However, from the point of view of the glass manufacturing process, addition at a higher concentration can be difficult.
    In order to produce an optical fiber 1 having a ring-shaped refractive index profile, it is desirable that the first core 11 contain fluorine. However, as mentioned above, it is known that when the first core 11 contains a lot of fluorine, the attenuation worsens due to a fluctuation of the refractive index due to the addition of fluorine. Thus, the concentration of fluorine in the first core 11 is preferably 5000 ppm or more and 15000 ppm or less. In order to make the relative refractive index difference of the first core 11 less than -0.05% relative to the second core 12, it is necessary to add fluorine in the first core 11 at a concentration greater than 5000 ppm.
    Figure 5 is a graph showing the relationship between the fluorine concentration in the first core 11 and the amount of increase / decrease in attenuation at a wavelength of 1550 nm. Table IV is a summary of the relationship between the concentration of fluorine in the first core 11 and the amount of increase / decrease in attenuation at a wavelength of 1550 nm. As can be seen from Figure 5 and Table IV, the increase in attenuation due to a concentration fluctuation in the first core 11, in which the optical power integration is small, tends to occur to a lesser extent than in the second core 12, and the maximum fluorine concentration in the first core 11 can be set to as high as 15000 ppm.
    Table IV
    In the second core 12, the concentration of chlorine is preferably greater than the concentration of fluorine. It is known that the variation in refractive index due to the concentration of chlorine is lower than that due to the concentration of fluorine. On the other hand, with respect to the amount of viscosity reduction with respect to the concentration, fluorine and chlorine are equivalent, and therefore chlorine is suitable as a dopant to reduce viscosity while suppressing the attenuation due to to a fluctuation of refractive index. It can therefore be expected that the attenuation is lower if the concentration of halogens to reduce the viscosity of the glass is reached with a concentration of chlorine higher than the concentration of fluorine in the second core 12.
    The concentration of chlorine in the first core 11 is preferably 10 ppm or more and 1000 ppm or less. Chlorine is a dopant for increasing the refractive index, and therefore, to form a ring-shaped refractive index profile, it is preferable to set the chlorine concentration at a low level. In this case, when the concentration of chlorine in the first core 11 is 1000 ppm or less, the influence of chlorine on the refractive index will be 0.01% or less, which is negligible. On the other hand, when the concentration of chlorine in the first core 11 is set to 0, there is a visible increase in attenuation due to imperfections of the glass, and therefore it is necessary to add 10 ppm or more of chlorine. .
    It is preferred that the two or one of an alkali metal element and an alkaline earth metal element be present at least in a portion of the core region of the optical fiber blank to produce the optical fiber. 1 of the present embodiment by stretching. Preferably, the alkali metal elements comprise any of sodium (Na), potassium (K), rubidium (Rb), cesium (Cs), magnesium (Mg), calcium (Ca), and strontium (Sr). In this case, the viscosity of the core region of the optical fiber blank can be further reduced, and the attenuation of the optical fiber 1 can be further reduced. It is preferable that the core region of the optical fiber blank is composed of a first core region comprising a central axis and a second core region enclosing the first core region and that of these first and second heart regions, the first core region contains an alkali metal element or an alkaline earth metal element.
    Figure 6 is a table summarizing the average potassium concentration in the core region of an optical fiber blank, the average fluorine concentration and the average chlorine concentration in the first core 11 of the optical fiber 1, the concentration of medium fluorine and the average chlorine concentration in the second core 12 of the optical fiber 1, and the attenuation of the optical fiber 1 at a wavelength of 1550 nm. The average potassium concentration in the core region of an optical fiber blank means the concentration obtained in a manner in which the concentration of added potassium in the first core region is averaged in terms of both the first region of the heart than the second heart region. In the fiber manufacturing process, the alkali metals diffuse throughout the core by thermal diffusion, and therefore the concentration available after such diffusion, rather than the available concentration at the initial stage, has a strong correlation with the attenuation. The first core 11 and the second core 12 of the optical fiber 1 correspond to the first core region and the second core region of the optical fiber blank. Preferably, sheath 20 of optical fiber 1 contains fluorine at an average concentration of 20000 atomic ppm or more. Figure 7 is a graph showing the relationship between the average potassium concentration in the core region of an optical fiber blank and the attenuation of the optical fiber at a wavelength of 1550 nm.
    If an alkali metal is added to a glass in which the average chlorine concentration is greater than 500 atomic ppm, crystallization tends to occur easily in the glass, and therefore the production yield of the optical fiber will decrease. Therefore, preferably, the first core region to which an alkali metal is to be added contains chlorine at a low concentration of 200 atomic ppm or less, so that crystallization is suppressed in the optical fiber blank, and the second core region contains chlorine at a high concentration so that the appearance of imperfections in the glass during the drawing process is restricted.
    When potassium is added only to the first core region in an optical fiber blank, the second core region will have a viscosity greater than that of the first core region. It is therefore preferable that the second core region has a higher halogen concentration than the first core region. Fig. 8 is a graph showing the relationship between attenuation at a wavelength of 1550 nm and the ratio H2 / H1 in which H2 represents the concentration of halogens in the second core 12 and H1 represents the concentration of halogens H1 in the first core 11. Table V is a summary of the relationship between attenuation at a wavelength of 1550 nm and the ratio H2 / H1. The average potassium concentration in the core region of an optical fiber blank is 12 ppm.
    Table V
    As can be seen from Figure 8 and Table V, preferably H2 / H1 is 1 or more and 2 or less. When H2 / H1 is less than 1, there is a distortion between the first heart and the second heart because the second heart becomes harder than the first heart, and therefore the attenuation becomes worse. On the other hand, when H2 / H1 is greater than 2, conversely the first core becomes harder than the second core and the attenuation due to distortion visibly increases.
    With respect to the core region of the optical fiber blank, it is confirmed that the viscosity decreases further depending on the increase in the average potassium concentration, so that the dummy temperature at the time of the treatment of stretching is reduced, resulting in a decrease in the attenuation of the resulting optical fiber. On the other hand, if the average potassium concentration exceeds 50 atomic ppm, crystallization will occur in the core region of the optical fiber blank. Therefore, the average potassium concentration in the core region of an optical fiber blank is preferably 5 to 50 atomic ppm. In addition, the ratio of the core region to the first core region is preferably from 5 to 7.
    权利要求:
    Claims (10)
    [1" id="c-fr-0001]
    An optical fiber comprising: a silica glass core containing substantially no germanium and comprising a first core and a second core, the second core enclosing the first core, the refractive index of the second core being greater than the index; of refraction of the first core, and the average value of the halogen concentration in the second core being 5000 ppm or more; and a silica glass sheath surrounding the second core and substantially free of germanium, the refractive index of the sheath being less than the refractive index of the first core.
    [2" id="c-fr-0002]
    Optical fiber according to claim 1, wherein the relative refractive index difference of the second core is -0.05% or more and +0.05% or less with respect to the glass refractive index. pure silica.
    [3" id="c-fr-0003]
    An optical fiber according to claim 1 or 2, wherein the concentration of fluorine in the second core is 500 ppm or more and 10000 ppm or less.
    [4" id="c-fr-0004]
    An optical fiber according to any one of claims 1 to 3, wherein the concentration of chlorine in the second core is 4500 ppm or more and 15000 ppm or less.
    [5" id="c-fr-0005]
    An optical fiber according to any one of claims 1 to 4, wherein the concentration of chlorine is greater than the concentration of fluorine in the second core.
    [6" id="c-fr-0006]
    An optical fiber according to any one of claims 1 to 5, wherein the concentration of fluorine in the first core is 5000 ppm or more and 15000 ppm or less.
    [7" id="c-fr-0007]
    An optical fiber according to any one of claims 1 to 6, wherein the concentration of chlorine in the first core is 10 ppm or more and 1000 ppm or less.
    [8" id="c-fr-0008]
    An optical fiber according to any one of claims 1 to 7, wherein the relative refractive index difference between the first core and the second core is 0.05% or more and 0.15% or less.
    [9" id="c-fr-0009]
    Optical fiber according to any one of claims 1 to 8, wherein the ratio H 2 / H 1 is 1 or more and 2 or less, H 2 being the concentration of halogens in the second core and H 1 being the concentration of halogens in the first heart.
    [10" id="c-fr-0010]
    An optical fiber according to any one of claims 1 to 9, wherein the core contains the two or one of an alkali metal and an alkaline earth metal.
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    法律状态:
    2017-10-23| PLFP| Fee payment|Year of fee payment: 2 |
    2018-03-30| PLSC| Publication of the preliminary search report|Effective date: 20180330 |
    2018-10-23| PLFP| Fee payment|Year of fee payment: 3 |
    2019-10-23| PLFP| Fee payment|Year of fee payment: 4 |
    2020-10-22| PLFP| Fee payment|Year of fee payment: 5 |
    2021-10-22| PLFP| Fee payment|Year of fee payment: 6 |
    优先权:
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    JP2015203490A|JP6551137B2|2015-10-15|2015-10-15|Optical fiber|
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