• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    The present invention relates to a cut fiber based polyvinyl chloride floor comprising, in sequence, an abrasion resistant layer, at least one colored film layer, an intermediate layer and a base layer. The percentage of polyvinyl chloride in the intermediate layer is of the order of 15% to 20% by weight of the intermediate layer, said intermediate layer also comprising: a plasticizer in a percentage of 4% to 8% by weight of the intermediate layer; a stabilizing agent in a percentage of 1% to 5% by weight of the intermediate layer; calcium carbonate in a proportion of 65% to 75% by weight of the intermediate layer; secondary materials in a percentage of 0.5% to 3% by weight of the intermediate layer; fibers cut at a percentage of 2% to 10% by weight of the intermediate layer.
    公开号:FR3038251A1
    申请号:FR1656274
    申请日:2016-06-30
    公开日:2017-01-06
    发明作者:Huibin Dai
    申请人:Zhejiang Kingdom Plastics Ind Co Ltd；
    IPC主号:
    专利说明:

    BACKGROUND OF THE INVENTION
    Technical area
    The present invention relates to the field of floor production, including a polyvinyl chloride floor based on staple fibers having good dimensional stability and a method of manufacturing the latter.
    Description of the related art
    Polyvinyl chloride floors have generally been used in everyday life. However, conventional polyvinyl chloride-based floors have a high rate of contraction and a high rate of expansion. During the process of use, the dimensions of the product vary considerably and hollow spaces are easily created in polyvinyl chloride floors where polyvinyl chloride planks repel each other creating deformations or even breaks and other types of irreversible damage due to expansion due to heat or contraction due to cold. In addition, conventional polyvinyl chloride floors are rigid and are often more likely to break at the edge when punching and cutting. This therefore affects the normal use of polyvinyl chloride floors as well as the life of such polyvinyl chloride floors, which is shortened.
    BRIEF DESCRIPTION OF THE INVENTION
    In order to solve the existing problems, the present invention provides a polyvinyl chloride and cut fiber floor having satisfactory dimensional stability and impact resistance and a method of manufacturing the same.
    In order to achieve the above-mentioned object, the present invention relates to a cut fiber based polyvinyl chloride floor comprising superimposed an abrasion-resistant layer, a colored film layer, at least one intermediate layer and a base layer, the percentage of polyvinyl chloride in the intermediate layer being of the order of 15% to 20% by weight of the intermediate layer which comprises a plasticizer in a percentage of 4% to 8% by weight of the layer; intermediate, a stabilizing agent in a percentage of 1% to 5% by weight of the intermediate layer, calcium carbonate in a percentage of 65% to 75% by weight of the intermediate layer, secondary materials in a percentage of 0, 5% to 3% by weight of the intermediate layer, fibers cut in a percentage of 2% to 10% by weight of the intermediate layer.
    According to one embodiment of the invention, the intermediate layer may comprise, by weight, 15% of polyvinyl chloride, 6% of plasticizer, 2% of stabilizing agent, 71% of calcium carbonate, 1% of secondary materials. and 5% of cut fibers.
    According to one embodiment of the invention, the secondary materials may comprise chlorinated polyethylene.
    According to one embodiment of the invention, the intermediate layer may comprise a first intermediate layer and a second intermediate layer, the first intermediate layer and the second intermediate layer being tightly laminated.
    According to one embodiment of the invention, the cut fibers may be glass fibers and the length of the fibers is from 2 mm to 10 mm.
    According to one embodiment of the invention, a particle size of the calcium carbonate is of the order of 125 to 177 microns.
    According to one embodiment of the invention, a thickness ratio of the first intermediate layer with respect to the second intermediate layer and with respect to the base layer is 1: (0.5-1): (0, 5-1). The invention further relates to a method of manufacturing the cut fiber based polyvinyl chloride floor comprising the steps of: a. Increase the temperature of a baking oven in a range from 170 ° C to 185 ° C, then place the secondary materials and cut fibers mixed in a regular way ® 11 inside the baking oven and maintain the heat for 10 to 15 minutes. minutes; b. Steadily mix the polyvinyl chloride, plasticizer, stabilizer, calcium carbonate to form a mixture and place this mixture inside an internal mixer for internal mixing; vs. Add secondary materials and thermally treated cut fibers in step a. to the internal mixer for continuous internal mixing to obtain an intermediate layer; d. Make an open mixture of the intermediate layer obtained in step c. in an open mixing apparatus; summer. Hot pressing the intermediate layer obtained in step d. with the abrasion resistant layer, the colored film layer and the base layer.
    According to one embodiment of the invention, the hot pressing step comprises the steps of: stacking a first intermediate layer on a second intermediate layer and performing a pre-rolling by means of heat treatment and pressure to to obtain the intermediate layer; sequentially placing the abrasion-resistant layer, the colored film layer, the intermediate layer and the base layer appropriately and then hot rolling; and allow to cool naturally in the air after hot rolling.
    According to one embodiment of the present invention, the internal mixing temperature can range from 175 ° C to 195 ° C and the internal mixing time of step b. and step c. can last from 2 to 8 minutes, the internal mixing time in step c. may be more equal to or longer than the internal mixing time of step b.
    According to one embodiment of the invention, the temperature of the open mixture is between 135 ° C and 170 ° C.
    The polyvinyl chloride floor made from chopped fibers has the following advantages:
    The Shore hardness of the conventional interlayer is 65 ° to 68 ° while the Shore hardness of the intermediate layer of the present invention is 55 ° to 57 °. The hardness of the intermediate layer being considerably reduced by using the cut fibers, the overall hardness of the products can be reduced and the impact resistance of the product as well as the robustness of the product are improved. In addition, the weatherability and flexibility of the product are improved by adding chlorinated polyethylene. Breaks at the edges during punching and cutting due to temperature variations are then effectively prevented.
    The chlorinated polyethylene and chopped fibers are pre-heated in the baking oven to modify their interface performance so that the chlorinated polyethylene and chopped fibers can better exploit the elastic properties and compatibility by being mixed internally with other raw materials. As a result, the contraction rate and the rate of expansion of the products are effectively reduced and the dimensional stability of the products is improved.
    It is not necessary to interpose 9rHl® glass fibers between the first intermediate layer and the second intermediate layer since the intermediate layer containing the cut fibers is subjected to a hot pressure. Therefore, the corresponding firmness will not be affected by situations such as improper grid size and / or improper operation during the use of grid glass fibers. The rate of contraction and the rate of expansion of the product can not therefore increase and the manufacturing process is optimized.
    These and other features, aspects and advantages of the present invention will be more understandable following reading of the following description of the appended claims.
    DETAILED DESCRIPTION OF THE INVENTION
    Embodiment 1
    The present embodiment relates to a cut fiber based polyvinyl chloride floor which comprises in a superimposed manner from top to bottom an abrasion resistant layer, a colored film layer, an intermediate layer and a base layer. The components of the raw materials comprised in a first intermediate layer and a second intermediate layer forming the intermediate layer are identical and comprise polyvinyl chloride, a plasticizer, a stabilizing agent, calcium carbonate, chlorinated polyethylene and chopped fibers. According to this embodiment, the cut fibers are glass fibers and the length of the glass fibers ranges from 3 mm to 6 mm. The size of the calcium carbonate particles is 149 microns.
    The method of manufacturing the cut fiber based polyvinyl chloride floor comprises the steps of: increasing the temperature of the baking oven in a range of 170 ° C to 185 ° C, then placing 1% by weight of chlorinated polyethylene by weight and 5% by weight of glass fibers which are mixed evenly inside the baking oven and maintain the heat for 10 to 15 minutes; then steadily mix 15% polyvinyl chloride, 6% plasticizer, 2% stabilizer and 71% calcium carbonate in percent by weight to form a mixture, place the mixture in an internal mixing apparatus to perform an internal mixture at a temperature of 175 ° C to 195 ° C for 3 minutes and then add chlorinated polyethylene and chopped fibers which are immediately subjected to heating and heat preservation in the internal mixing apparatus for continuously perform internal mixing for 6 minutes; then to make an open mixture of the semi-finished product obtained once the internal mixture is finished at a temperature ranging from 150 ° C to 170 ° C to obtain the second intermediate layer and to press the semi-finished product obtained once the mixture is finished to form the first intermediate layer.
    Finally, the pre-rolling of the first intermediate layer obtained and of the second intermediate layer obtained is carried out before superimposedly depositing the abrasion-resistant layer, the colored film layer, the intermediate layer and the base coat correctly. , on which hot rolling is carried out. The whole is then allowed to cool naturally.
    The cut fiber based polyvinyl chloride floor parameters are as follows: the thickness ratio of the first intermediate layer to the second intermediate layer and its ratio to the base layer is 1: 1: 0, 6, and the first intermediate layer has a thickness of 1.8 mm; the tested contraction rate of the product is 0.04% after the product has been heated for 6 hours at a temperature of 80 ° C; the tested expansion rate of the product in an environment at 50 ° C is 0.055% after the product has been heated for two hours at a temperature of 50 ° C. The contraction rate of existing products after being heated for six hours at a temperature of 80 ° C is 0.10% to 0.15% and the rate of expansion of existing products after being heated for two hours to one hour. temperature of 50 ° C is from 0.085% to 0.197%. As a result, the rate of contraction and the rate of expansion are considerably reduced. The Shore hardness of the intermediate layer of this invention is of the order of 55 °.
    Embodiment 2
    The present embodiment relates to a cut fiber based polyvinyl chloride floor which comprises in a superimposed manner from top to bottom an abrasion resistant layer, a colored film layer, a first interlayer, a second interlayer and a base layer. The raw material components included in the first intermediate layer and the second intermediate layer are identical and comprise polyvinyl chloride, a plasticizer, a stabilizing agent, calcium carbonate, chlorinated polyethylene and chopped fibers. According to this embodiment, the cut fibers are glass fibers and the length of the glass fibers ranges from 4 mm to 5 mm. The size of the calcium carbonate particles is 177 microns.
    The method of manufacturing the cut fiber based polyvinyl chloride floor comprises the steps of increasing the temperature of the baking oven in a range of 170 ° C to 185 ° C, then placing 1% chlorinated polyethylene in weight and 7% glass fibers by weight which are mixed evenly in the baking oven, and then continue to heat for 10 to 15 minutes; - * then mix 18% polyvinyl chloride, 4% plasticizer, 2% stabilizing agent and 68% calcium carbonate in a regular manner and place the mixture in an internal mixing apparatus to effect internal mixing at a temperature ranging from 185 ° C to 195 ° C for 4 minutes. Then placing the chlorinated polyethylene and chopped fibers, immediately subjected to heating and heat preservation in the internal mixing apparatus for continuous internal mixing for 5 minutes; then carry out an open mixing of the semi-finished product obtained once the internal mixture is finished, at a temperature ranging from 150 ° C to 160 ° C to obtain the second intermediate layer and press the semi-finished product obtained once the mixture is finished to form the first intermediate layer.
    Finally, the first intermediate layer obtained and the second intermediate layer obtained are pre-rolled and then the abrasion-resistant layer, the colored film layer, the intermediate layer and the protective layer are sequentially superimposed. base correctly. Hot rolling and natural cooling are then performed.
    The parameters of the cut fiber based polyvinyl chloride floor are as follows: the thickness ratio of the first interlayer with respect to the second interlayer and with respect to the base layer is 1: 0.6: 0.8, and the first intermediate layer has a thickness of 2 rom; the tested contraction rate of the product is 0.04% after the product has been heated for 6 hours at a temperature of 80 ° C; the tested rate of expansion of the product in an environment at 50 ° C is 0.058% after the product has been heated for two hours at a temperature of 50 ° C. The Shore hardness of the intermediate layer of this invention is of the order of 56 °.
    Embodiment 3
    The cut fiber based polyvinyl chloride floor of the present embodiment comprises in a superimposed manner from top to bottom an abrasion resistant layer, a colored film layer, an intermediate layer and a base layer, the first layer intermediate comprising by weight a percentage of: 20% polyvinyl chloride, 7% plasticizer, 4% stabilizer, 75% calcium carbonate and 10% glass fiber. The length of the glass fibers ranges from 6 to 10 mm and the size of the calcium carbonate particles is of the order of 125 microns.
    The manufacturing process comprises the steps of: - + increasing the temperature of the baking oven in a range from 170 ° C to 185 ° C, then quickly placing the glass fibers and the chopped fibers which are mixed in a regular manner with inside the baking oven, and continue to heat for 10 to 15 minutes; then regularly mix the polyvinyl chloride, the plasticizer, the stabilizing agent and the calcium carbonate and place the mixture in an internal mixing apparatus to effect an internal mixing at a temperature ranging from 185 ° C to 195 ° C for 6 minutes and then place the heat-treated glass fibers and chopped fibers in the internal mixing apparatus to continuously mix internally for 6 minutes to obtain the intermediate layer; then performing an open mixing of the resulting intermediate layer at a temperature of 140 ° C to 160 ° C to obtain the second intermediate layer and pressing another second intermediate layer obtained to form the first intermediate layer. finally, pre-rolling the first intermediate layer obtained and the second intermediate layer obtained and then sequentially superimposing the abrasion-resistant layer, the colored film layer, the intermediate layer and the base layer correctly, before running a hot rolling and let cool naturally afterwards. The Shore hardness of the intermediate layer of this invention is of the order of 570.
    The parameters of the polyvinyl chloride floor based on chopped fibers are as follows: the thickness ratio of the first intermediate layer with respect to the second intermediate layer and with respect to the base layer is 1: 0.5 : 1, and the first intermediate layer has a thickness of 1.6 mm; the tested contraction rate of the product is 0.05% after the product has been heated for 6 hours at a temperature of 80 ° C; the tested expansion rate of the product in an environment at 50 ° C is 0.064% after the product has been heated for two hours at a temperature of 50 ° C.
    Embodiment 4
    The cut fiber-based polyvinyl chloride floor of the present embodiment comprises from top to bottom an abrasion-resistant layer, a colored film layer, an intermediate layer and a base layer, the intermediate layer comprising by weight a percentage of 20% polyvinyl chloride, 4% plasticizer, 1% stabilizer, 75% calcium carbonate and 1% glass fiber. The length of the glass fibers ranges from 2 to 5 mm and the size of the calcium carbonate particles is of the order of 149 microns.
    The manufacturing process comprises the steps of: - * increasing the temperature of the baking oven in a range from 170 ° C to 185 ° C, then rapidly placing the glass fibers and the chopped fibers which are steadily mixed with inside the baking oven and continue to heat for 10 to 15 minutes; then regularly mix the polyvinyl chloride, the plasticizer, the stabilizing agent and the calcium carbonate and place the mixture in an internal mixing apparatus to effect an internal mixing at a temperature ranging from 180 ° C to 185 ° C for 3 minutes, then placing the heat-treated glass fibers and chopped fibers in the internal mixing apparatus to continuously mix internally for 8 minutes to obtain the intermediate layer; then perform an open mixture of the intermediate layer obtained at a temperature ranging from 140 ° C to 160 ° C. finally, sequentially superimposing the abrasion-resistant layer, the colored film layer, the intermediate layer and the base layer appropriately, then hot rolling and then cooling naturally.
    The parameters of the polyvinyl chloride floor based on cut fibers are as follows: the thickness ratio of the intermediate layer to the base layer is 1: 0.5, and the intermediate layer has a thickness of 2 , 5 mm; the tested contraction rate of the product is 0.47% after the product has been heated for 6 hours at a temperature of 80 ° C; the tested expansion rate of the product in an environment at 50 ° C is 0.076% after the product has been heated for two hours at a temperature of 50 ° C. The Shore hardness of the intermediate layer of this invention is of the order of 55 °.
    According to known manufacturing methods, a piece of glass fiber mesh has to be added between the first interlayer and the second interlayer during spreading but using too small grids of fiberglass grating blocks the adjustment force layers between the upper layer and the lower layer, affecting the overall robustness of adjustment of the product; conversely, using too large grids of glass fiber results in low vertical and horizontal interconnection stiffness among the glass fibers and susceptibility to tearing; when the grid glass fibers are superimposed during the spreading of the film, wrinkles can easily occur if the operation is performed incorrectly, and the failure rate of the product increases accordingly. The use of glass fiber gratings during conventional hot pressing aims to control the rate of contraction and the rate of expansion of the product, but a satisfactory result is not simply obtained by means of glass fiber gratings, which lead to contraction rates and overall expansion rates that remain high; the rate of contraction and the rate of expansion of cut fiber based polyvinyl chloride floors prepared by adopting the manufacturing method of the invention can be controlled to vary between close values, the size of the product remaining relatively stable during contraction and expansion. In addition, the polyvinyl chloride floor cut fiber has a low overall hardness, its strength is enhanced, and the crunching phenomenon of the edges of the product during punching no longer exists.
    Specific embodiments are only used for purposes of describing the invention and are not intended to limit it. The scope of the claims of the present invention includes the substitutions and modifications made to the invention without creating work.
    权利要求:
    Claims (10)
    [1" id="c-fr-0001]
    1) Cut fiber-based polyvinyl chloride flooring comprising an abrasion-resistant layer, a colored yarn layer, at least one intermediate layer and a base layer, the percentage of polyvinyl chloride in the intermediate layer being in the range of 15% to 20% by weight of the intermediate layer which comprises a plasticizer in a percentage of 4% to 8% by weight of the intermediate layer, a stabilizing agent in a percentage of 1% to 5% by weight of the intermediate layer, calcium carbonate in a proportion of 65% to 75% by weight of the intermediate layer, secondary materials in a percentage of 0.5% to 3% by weight of the intermediate layer, fibers cut according to a percentage of 2% to 10% by weight of the intermediate layer.
    [0002]
    2) cut fiber based polyvinyl chloride flooring according to claim 1, the intermediate layer comprising, by weight, 15% polyvinyl chloride, 6% plasticizer, 2% stabilizing agent, 71% calcium carbonate , 1% of secondary materials and 5% of cut fibers.
    [0003]
    3) cut fiber based polyvinyl chloride flooring according to claim 1, the secondary materials comprising chlorinated polyethylene.
    [0004]
    4) cut fiber polyvinyl chloride flooring according to claim 1, the intermediate layer may comprise a first intermediate layer and a second intermediate layer, the first intermediate layer and the second intermediate layer being tightly laminated.
    [0005]
    5) Cut fiber polyvinyl chloride flooring according to claim 1, the staple fibers being glass fibers and the length of the glass fibers ranging from 2 to 10 mm.
    [0006]
    6) cut fiber polyvinyl chloride flooring according to claim 1, a particle size of calcium carbonate being of the order of 125 to 177 microns.
    [0007]
    7) A method of manufacturing the cut fiber based polyvinyl chloride floor according to claim 1, comprising the following steps: a. Increase the temperature of a baking oven in a range of 170 ° C to 185 ° C, then place the secondary materials and cut fibers mixed evenly inside the baking oven and hold the heat for 10 to 15 minutes; b. Steadily mix the polyvinyl chloride, plasticizer, stabilizer, calcium carbonate to form a mixture and place this mixture inside an internal mixer for internal mixing; vs. Add the secondary materials and thermally cut fibers in step a. to the internal mixer for continuous internal mixing to obtain an intermediate layer; d. Make an open mixture of the intermediate layer obtained in step c. in an open mixing apparatus; summer. Press hot the intermediate layer obtained in step d. with the abrasion resistant layer, the colored film layer and the base layer.
    [0008]
    8) The manufacturing method according to claim 7, the hot pressing step comprising the steps of: stacking a first intermediate layer on a second intermediate layer and perform a pre-rolling by means of heat treatment and pressure to to obtain the intermediate layer; sequentially placing the abrasion-resistant layer, the colored film layer, the intermediate layer and the base layer appropriately and then hot rolling; and leave to cool naturally to the air after hot rolling.
    [0009]
    9) The manufacturing method according to claim 7, the internal mixing temperature ranging from 175 ° C to 195 ° C and the internal mixing time in step b. and in step c. can last from 2 to 8 minutes, the internal mixing time in step c. may be equal to or longer than the internal mixing time of step b.
    [0010]
    10) The manufacturing method according to claim 7, the open mixing temperature is between 135 ° C and 170 ° C.
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    法律状态:
    2017-06-19| PLFP| Fee payment|Year of fee payment: 2 |
    2018-07-02| PLFP| Fee payment|Year of fee payment: 3 |
    优先权:
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    CN201510371626.8A|CN104947913A|2015-06-30|2015-06-30|Chopped strand PVC floor and production method thereof|
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