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    • 专利摘要:
    The invention relates to a process for converting a heavy hydrocarbon feedstock, said process comprising the following steps: a) a step of hydroconversion of the heavy hydrocarbon feedstock in the presence of hydrogen in at least one or more reactors three-phase units arranged in series or in parallel, containing at least one hydroconversion catalyst, so as to obtain a liquid effluent containing a reduced content of Conradson Carbon, of metals, of sulfur and of nitrogen, b) one or more optional separation steps of the effluent from step a) making it possible to obtain at least one light liquid fraction boiling at a temperature below 350 ° C. and a heavy liquid fraction boiling at a temperature above 350 ° C., c) a step of hydroconversion of the liquid effluent resulting from the hydroconversion step a) in the case where the separation step b) is not carried out or the heavy liquid fraction resulting from the separation step ion b) when said step b) is carried out, in the presence of hydrogen in at least one or more three-phase reactors arranged in series or in parallel, containing at least one hydroconversion catalyst, process in which the overall space velocity implementation is between 0.05 and 0.18 h-1.
    公开号:FR3033797A1
    申请号:FR1552092
    申请日:2015-03-16
    公开日:2016-09-23
    发明作者:Matthieu Dreillard；Frederic Feugnet；Joao Marques；Frederic Morel
    申请人:IFP Energies Nouvelles IFPEN；
    IPC主号:
    专利说明:

    [0001] The present invention relates to a process for converting a heavy hydrocarbon feed advantageously from either a crude oil, or the atmospheric and / or vacuum distillation of a crude oil and containing at least 80% wt. a fraction having an initial boiling point of at least 300 ° C.
    [0002] More specifically, the feedstocks that are treated in the context of the present invention are either crude oils or heavy hydrocarbon fractions derived from the atmospheric distillation and / or vacuum of a crude oil and containing at least 80 % by weight of a fraction having an initial boiling point of at least 300 ° C, preferably at least 350 ° C and preferably at least 375 ° C and preferably vacuum residues containing at least less than 80% by weight of a fraction having an initial boiling point of at least 450 ° C and preferably of at least 500 ° C. These fillers are generally hydrocarbon fractions having a sulfur content of at least 0.1% by weight, preferably at least 1% by weight and preferably at least 2% by weight, a content Conradson carbon of at least 3% by weight and preferably at least 5% by weight, an asphaltene content of at least 0.1% by weight and preferably at least 3% by weight and a metal content at least 20 ppm and preferably at least 100 ppm. The recovery of these oil residues is relatively difficult. In fact, the market is mainly seeking fuels, distillable at atmospheric pressure at a temperature below 320 ° C or 380 ° C. Crude oils are characterized by variable levels of atmospheric residues that depend on the origin of the treated crudes. This content generally varies between 20 and 50% for conventional crudes, but can reach 50 to 80% for heavy and extra heavy crudes such as those produced in Venezuela or in the Athabasca region in northern Canada. It is therefore necessary to convert these residues, transforming the heavy residue molecules to produce refined products made up of lighter molecules. These refined products generally have a higher hydrogen-to-carbon ratio than heavy starting cuts. A series of processes used to produce refined light cuts, such as hydrocracking, hydrotreating and hydroconversion processes, is therefore based on the addition of hydrogen in the molecules, preferably at the same time as the cracking of these heavy molecules.
    [0003] The conversion of heavy cuts depends on a large number of parameters such as the composition of the feedstock, the reactor technology used, the severity of the operating conditions (temperature, pressure, hydrogen partial pressure, residence time, etc. ), the type of catalyst used and its activity. By increasing the severity of the operation, the conversion of heavy cuts to light products is increased, but by-products such as coke precursors and sediments begin to be significantly formed via side reactions. The high thrust conversion therefore very often results in the formation of solid (so-called sediment), highly viscous and / or sticky particles composed of asphaltenes, coke and / or fine particles of catalyst. The excessive presence of these products then leads to the deactivation of the catalyst, the fouling of the process equipment, and in particular the separation and distillation equipment. As a result, the refiner is forced to reduce the conversion of heavy cuts in order to avoid stopping the hydroconversion unit. The formation of these sediments in hydroconversion processes is highly dependent on the quality of the load and the severity of the operation. Indeed, the asphaltenes present in the feedstock 10 are mainly converted by dealkylation under the severe hydroconversion conditions and thus form highly condensed aromatic rings which render the effluents unstable and which precipitate in the form of sediments. One of the aims of the invention is to provide a schematic of a hydroconversion process for improving the effluent stability for a given level of conversion of heavy cuts, and thus to be able to increase the conversion over the processes. conventional hydroconversion. The conventional schemes for the hydroconversion of residues as described in US Pat. No. 4,521,295, US Pat. No. 4,495,060 or US Pat. No. 4,457,831, advocate an operation at hourly volume (VVH) or space velocities (volume flow rate of charge relative to the reaction volume) between 0.1 and 2.5 h-1, temperatures between 300-550 ° C and partial hydrogen pressures between 1000 and 5000 psig. In these diagrams, temperature remains the key parameter to control the conversion level of heavy cuts. For a high conversion operation, a high temperature is thus recommended to increase the thermal cracking of heavy cuts. In this configuration the maximum conversion level allowing a suitable operation of an industrial unit will always be limited by the formation of sediments. In fact, the temperature increases the kinetics of the condensation / polymerization reactions more rapidly than that of the hydrogenation reactions, thus causing secondary and undesirable reactions, responsible for the formation of sediments and coke precursors.
    [0004] To overcome this operability limit of the hydroconversion units, conventional prior art residue conversion schemes can incorporate additional steps such as deasphalting to achieve higher conversion levels at reduced severity. This is the case of the concept described in US Patents 2008/0083652, US 7,214,308, US 5,980,730. In fact, in the residue hydroconversion schemes combining a deasphalting unit with a fixed bed hydroconversion unit, a moving bed, an ebullated bed and / or a slurry-driven bed, the deasphalting unit can be positioned upstream in the indirect way, such as in US Pat. No. 7,214,308, or downstream of the hydroconversion process according to the direct route, as for example in patents FR 2776297 and US 5,980,730. Patents FR 2776297, US 5,980,730 and US 7,214,308 describe in detail these two types of possible conversion scheme. A residue hydroconversion scheme generally combines two main successive unit steps: a hydroconversion step and a deasphalting step, an intermediate atmospheric distillation and optionally an intermediate vacuum distillation being carried out between these two unit steps. Generally, recycling of the deasphalted oil (DAO) to the hydroconversion stage can be implemented in this type of scheme. The biggest limitations of this type of scheme are the amount of asphalt produced which is difficult to value; recycling the CAD cut at the entrance to the hydroconversion zone which requires a significant increase in the volume of the reaction zones as well as separation zones (as described in US Patents 2012 / 061292A and WO 14096591A1) increasing the investment required and the operating cost compared to the process without CAD recycling. Fluxing agents such as aromatic cuts, among which not limited to, light cycle oil (LCO) and heavy cycle oil (HCO) cuts from the fluidized catalytic cracking process can be used to stabilize the effluents. residue hydroconversion units. However, their use greatly impacts the profitability of the process insofar as these cuts have a cost and that their use leads to an increase in the size of the units. In addition, these stabilizing cuts are not always available on the site and their use is necessarily at the expense of producing a valuable cut. All of these reasons explain why the use of stabilizing cutting is very limited. In the present invention, it is proposed to simultaneously improve the conversion level and stability of the liquid effluents by a heavy load conversion scheme having optimized thermal level and load residence time. The process according to the invention makes it possible to achieve a conversion of the feedstock greater than that obtained by a so-called conventional configuration for comparable liquid effluent stability. In another way, the present invention can also make it possible to produce effluents at a level of conversion identical to a conventional method according to the prior art but with a better stability of the liquid effluents produced.
    [0005] SUMMARY OF THE INVENTION The present invention relates to a process for converting a heavy hydrocarbon feedstock, comprising the following steps: a) a step of hydroconversion of the heavy hydrocarbon feedstock in the presence of hydrogen in at least one or more three-phase reactors arranged in series or in parallel, containing at least one hydroconversion catalyst, the hydroconversion stage a) being carried out under an absolute pressure of between 2 and 35 MPa, a temperature of 10 between 300 and 550 ° C, and under a quantity of hydrogen mixed with the load of between 50 and 5000 normal cubic meters (Nm3) per cubic meter (m3) of charge, so as to obtain a low carbon liquid effluent Conradson, made of metals, sulfur and nitrogen, b) one or more optional steps for separating the effluent from step a) to obtain at least one light liquid fraction boiling at a time. temperature below 350 ° C and a heavy liquid fraction boiling at a temperature above 350 ° C, c) a hydroconversion step of the liquid effluent from the hydroconversion step a) in the case where the step b) of separation is not implemented, or of the heavy liquid fraction resulting from the separation step b) when said step b) is carried out, in the presence of hydrogen in at least one or more reactors three-phase units arranged in series or in parallel, containing at least one hydroconversion catalyst, the hydroconversion stage c) being carried out under an absolute pressure of between 2 and 38 MPa, at a temperature of between 300 and 550 ° C. and under a quantity of hydrogen of between 50 and 5000 normal cubic meters (Nm3) per cubic meter (m 3) of liquid charge taken under standard conditions of temperature and pressure, in which the overall hourly space velocity rate is used. is included between 0.05 and 0.1811-1. In the present invention, the term "overall space velocity" is understood to mean the space velocity used throughout the entire process scheme, that is to say taking into account all the reactors involved in the process in the process. steps a) and c). In one embodiment, the method according to the invention can contain several hydroconversion stages, preferably at least two hydroconversion stages and several optional separation steps between the hydroconversion stages.
    [0006] The feedstock treated in the process according to the invention is a heavy hydrocarbon feedstock (referred to as a residue). Advantageously, this feedstock is a feedstock comprising hydrocarbon fractions produced in the refinery. The fillers according to the invention include feedstocks containing hydrocarbon fractions of which at least 80% w / w have a boiling point above 300 ° C., atmospheric residues and / or residues under vacuum, atmospheric residues. and / or under vacuum from hydrotreatment, hydrocracking and / or hydroconversion, fresh or refined vacuum distillates, cuts from a cracking unit such as FCC, coking or visbreaking. , aromatic cuts extracted from a lubricant production unit, deasphalted oils from a deasphalting unit, asphalts from a deasphalting unit or similar hydrocarbon feedstocks, or a combination of these fresh and / or refined effluents. Said feed may also contain a residual fraction resulting from the direct liquefaction of coal (an atmospheric residue and / or a vacuum residue resulting for example from the H-CoalTm process), a vacuum distillate resulting from the direct liquefaction of coal, such as for example the HCoalTM process, pyrolysis residues of coal or shale oils, or a residual fraction resulting from the direct liquefaction of the lignocellulosic biomass alone or mixed with coal and / or a fresh petroleum fraction and / or refined.
    [0007] Preferably, the filler treated in the context of the present invention consists of hydrocarbon fractions derived from a crude oil or the atmospheric distillation of a crude oil or the vacuum distillation of a crude oil, said fillers containing at least 80% by weight of a fraction having an initial boiling point of at least 300 ° C, preferably at least 350 ° C and preferably at least 375 ° C and more preferably vacuum residues having a boiling point of at least 450 ° C, preferably at least 500 ° C and more preferably at least 540 ° C. All of these fillers cited above contain impurities such as metals, sulfur, nitrogen, Conradson carbon and heptane insolubles, also known as asphaltenes 07. These types of fillers are indeed generally rich. in impurities with metal contents greater than 20 ppm, preferably greater than 100 ppm. The sulfur content is greater than 0.1%, preferably greater than 1%, and preferably greater than 2% by weight. The level of C 7 asphaltenes amounts to at least 0.1% by weight and is preferably greater than 3% by weight. C7 asphaltenes are known compounds for inhibiting the conversion of residual cuts, both by their ability to form heavy hydrocarbon residues, commonly known as cokes, and by their tendency to produce sediments which severely limit the operability of the coke units. hydrotreating and hydroconversion. The Conradson carbon content is greater than 3%, and preferably at least 30% by weight. The Conradson carbon content is defined by ASTM D 482 and represents for the skilled person a well-known evaluation of the amount of carbon residues produced after pyrolysis under standard conditions of temperature and pressure.
    [0008] Hydroconversion stage a) In accordance with the invention, said hydrocarbon heavy charge is treated in a hydroconversion stage a) comprising at least one or more three-phase reactors arranged in series or in parallel. These hydroconversion reactors may, among other things, be fixed-bed reactors, mobile bed, bubbling bed, and / or slurry-driven bed, depending on the charge to be treated. Preferably, a bubbling bed reactor is used. In this step, said charge is transformed under specific hydroconversion conditions. Step a) is carried out under an absolute pressure of between 2 and 35 MPa, preferably between 5 and 25 MPa and preferably between 6 and 20 MPa, at a temperature of between 300 and 550 ° C. and preferably between between 350 and 500 ° C and preferably between 370 and 430 ° C, and more preferably between 380 ° C and 430 ° C. The quantity of hydrogen mixed with the feedstock is preferably between 50 and 5000 normal cubic meters (Nm3) per cubic meter (m3) of liquid feedstock taken under standard conditions of temperature and pressure, preferably between 100 and 2000 Nm3. / m3 and very preferably between 200 and 1000 Nm3 / m3.
    [0009] This first hydroconversion stage is advantageously carried out in one or more three-phase hydroconversion reactors, which may be in series and / or in parallel, advantageously using bubbling bed reactor technology. This step is advantageously carried out using the technology and under the conditions of the HOilTM process as described for example in US Pat. Nos. 4,521,295 or US 4,495,060 or US Pat. No. 4,457,831 or in the article Aiche, March 19-23. 1995, Houston, Texas, paper number 46d, "Second generation ebullated bed technology." In this implementation, each reactor is operated in a three-phase fluidized bed, also known as a bubbling bed, In one of the operations of the reactors operating in a fluidized bed, each reactor advantageously comprises a recirculation pump enabling the bubbling bed catalyst to be maintained by continuous recycling of at least a portion of a liquid fraction advantageously withdrawn at the top of the reactor and reinjected at the bottom of the reactor. in step a) of hydroconversion of the process according to the invention contains one or more elements from groups 4 to 12 of the periodic table of LEMENTS, 35 which can be deposited on a carrier or not. It is advantageous to use a catalyst comprising a support, preferably amorphous, such as silica, alumina, silica-alumina, titanium dioxide or combinations of these structures, and very preferably alumina, and at least one Group VIII metal selected from nickel and cobalt and preferably nickel, said Group VIII element preferably being used in combination with at least one Group VIB metal selected from molybdenum and tungsten and preferably the Group VIB metal is molybdenum. Advantageously according to the invention, the hydroconversion catalyst of step a) is a catalyst comprising an alumina support and at least one group VIII metal chosen from nickel and cobalt, preferably nickel, said element of the group VIII being used in combination with at least one Group VIB metal selected from molybdenum and tungsten, preferably the Group VIB metal is molybdenum. Preferably, the hydroconversion catalyst comprises nickel as part of group VIII and molybdenum as part of group VIB. The nickel content is advantageously between 0.5 and 10%, expressed by weight of nickel oxide (NiO) and preferably between 1 and 6% by weight, and the molybdenum content is advantageously between 1 and 30% expressed. by weight of molybdenum trioxide (MoO 3) and preferably between 4 and 20% by weight. This catalyst is advantageously used in the form of extrudates or beads.
    [0010] A type of "slurry" catalyst according to the English terminology or entrained catalyst can be used in the process according to the invention. Said slurry catalyst has a particle size and a density suitable for its training. The term "entrainment of the dispersed catalyst" is understood to mean its circulation in the three-phase reactor (s) by the liquid streams, said second catalyst circulating from bottom to top, with the charge, in the said three-phase reactor (s), and being withdrawn from said one or more three-phase reactors with the liquid effluent produced. In one of the implementations of the process according to the invention, each reactor of hydroconversion step a) can use a different catalyst adapted to the feed that is sent to this reactor. In one of the implementations of the process according to the invention, several types of catalyst can be used in each reactor. In a preferred embodiment, each reactor of step a) and / or step c) may contain one or more supported catalysts and / or one or more unsupported catalysts. The hydroconversion catalyst used according to the process according to the invention can be partially replaced by fresh catalyst by withdrawal, preferably at the bottom of the reactor, and by introducing, either at the top or at the bottom of the reactor, fresh catalyst and and / or used catalyst and / or regenerated catalyst and / or rejuvenated catalyst, preferably at regular time interval and preferably by puff or almost continuously. Catalyst replacement can be done in whole or in part by spent and / or regenerated and / or rejuvenated catalyst from the same reactor and / or another reactor of any hydroconversion step. The catalyst may be added with the metals as metal oxides, metals as metal sulfides, or after preconditioning. For each reactor, the replacement rate of the spent hydroconversion catalyst by fresh catalyst is advantageously between 0.01 kilogram and 3033797 8 10 kilograms per cubic meter of treated feed, and preferably between 0.1 kilogram and 3 kilograms per cubic meter of processed load. This withdrawal and replacement are performed using devices advantageously allowing the continuous operation of this hydroconversion step.
    [0011] It is also possible to send the spent catalyst withdrawn from the reactor into a regeneration zone in which the carbon and the sulfur contained therein are removed and then to return this regenerated catalyst to the hydroconversion stage. It is also possible to send the spent catalyst withdrawn from the reactor to a rejuvenation zone in which the major part of the deposited metals is removed before sending the spent and recycled catalyst to a regeneration zone in which the carbon is removed. and the sulfur contained therein and then returning this regenerated catalyst to the hydroconversion stage. b) Optional Separation Step The effluent from hydroconversion step a) can then undergo one or more separation steps. According to the invention, this separation remains optional, the effluent of the hydroconversion stage a) can be sent directly to the hydroconversion stage c).
    [0012] In the case where said separation step is carried out, at least a portion of the effluent from hydroconversion step a) is sent to said separation step. This separation step is carried out with the objective of advantageously obtaining at least one so-called light liquid fraction boiling predominantly at a temperature below 350 ° C. and at least one so-called heavy liquid fraction boiling predominantly at a temperature above 350 ° C. . The light liquid fraction can then be sent at least partly to a fractionation section where it is then advantageously separated from the light gases (H2 and C1-C4) to obtain the light liquid fraction boiling predominantly at a temperature below 350 ° C. by any means of separation known to those skilled in the art such as for example by passing through a flash balloon (or flash balloon according to the English terminology), so as to recover hydrogen gas which can be advantageously recycled at the inlet of the hydroconversion stage a). Said light liquid fraction, advantageously separated from said light gases and boiling predominantly at a temperature below 350 ° C., contains the dissolved light gases, a fraction boiling at a temperature below 150 ° C. corresponding to the naphthas, a fraction boiling between 150 and 250 ° C. ° C corresponding to the kerosene fraction and at least a portion of the fraction 3033797 9 The heavy liquid fraction from the separation step b) boiling predominantly at a temperature above 350 ° C may optionally contain a portion of the boiling gas fraction between 250 and 375 ° C, but it contains at least one fraction boiling between 375 and 540 ° C called vacuum distillate and a fraction boiling at a temperature above 540 ° C, called unconverted vacuum residue. This heavy liquid fraction is then sent at least in part to the hydroconversion stage c), in the case where the separation step is carried out. The separation step can be carried out by any separation means known to those skilled in the art. Preferably, the separation step b) is carried out by one or more flash balloons in series, and preferably by a single flash ball. Preferably, this flash balloon is operated at a pressure and a temperature close to the operating conditions of the last reactor of the hydroconversion stage a).
    [0013] In another implementation, the separation step is carried out by a sequence of several flash balloons, operating at operating conditions different from those of the last reactor of the hydroconversion stage a) and making it possible to obtain several light liquid fractions, which will then be sent at least partly to a fractionation section, while the heavy liquid fraction is then sent at least partly to the hydroconversion stage c) according to the invention.
    [0014] In another embodiment, the separation step is carried out by one or more steam and / or hydrogen stripping columns. By this means, the effluent resulting from the hydroconversion stage a) will be separated into a light liquid fraction and a heavy liquid fraction, which will then be sent at least partly to the hydroconversion stage c). invention.
    [0015] In another implementation, the separation step is carried out by an atmospheric distillation column separating the effluent from the hydroconversion stage a). The heavy liquid fraction recovered at the bottom of the atmospheric distillation column can then be sent at least partly to the hydroconversion stage c) according to the invention.
    [0016] In another implementation, the separation step is carried out by an atmospheric distillation column separating the effluent from the first hydroconversion stage, followed by a vacuum distillation column on the residue of the column. atmospheric distillation. The heavy liquid fraction recovered at the bottom of the vacuum distillation column can then be sent at least in part to the hydroconversion stage c) according to the invention. The separation step may also consist of a combination of these different implementations described above, in a different order from that described above.
    [0017] Optionally, before being sent to the hydroconversion stage c) according to the invention, the heavy liquid fraction can be subjected to a stripping step with steam and / or hydrogen using one or more stripping columns. This step makes it possible to eliminate at least part of the vacuum distillate fraction (hydrocarbons with a boiling point below 540 ° C.) contained in the heavy liquid fraction. Step c) hydroconversion 10 According to the invention, the liquid effluent from the hydroconversion step a) in the case where the separation step b) is not implemented or the heavy liquid fraction from the separation step b) when this is implemented is treated in step c) of hydroconversion. This hydroconversion step c) is composed of one or more three-phase reactors, which can be in series and / or in parallel. These hydroconversion reactors may, in addition, be fixed bed type reactors, moving bed, bubbling bed, and / or slurry driven bed, depending on the feedstock to be treated, in particular the effluent from step a) hydroconversion or heavy liquid fraction from step b) separation. Preferably, a bubbling bed reactor is used. In this step, the feedstock to be treated is generally converted under standard hydroconversion conditions of a liquid hydrocarbon fraction. The operation is usually carried out under an absolute pressure of between 2 and 35 MPa, preferably between 5 and 25 MPa and preferably between 6 and 20 MPa, at a temperature of between 300 and 550 ° C., preferably between 350 and 500. ° C and preferably between 370 and 430 ° C. The quantity of hydrogen mixed with the charge to be treated is preferably between 50 and 5000 normal cubic meters (Nm3) per cubic meter (m3) of liquid charge taken under standard conditions of temperature and pressure, and preferably, between 100 and 2000 Nm3 / m3 and very preferably between 200 and 1000 Nm3 / m3. This hydroconversion stage c) is advantageously carried out in one or more three-phase hydroconversion reactors, which may be in series and / or in parallel, using ebullated bed reactor technology. This step is advantageously carried out using the technology and under the conditions of the HOILTM process as described for example in US Pat. Nos. 4,521,295 or US 4,495,060 or US Pat. No. 4,457,831 or US Pat. No. 4,354,852 or in the article Aiche, March 1923, 1995, Houston, Texas, paper number 46d, "Second generation ebullated bed technology". In this implementation, each reactor is operated in three-phase fluidized bed, also called bubbling bed. In one of the operations of the reactors operating in a fluidized bed, each reactor advantageously comprises a recirculation pump for maintaining the catalyst in a bubbling bed by continuous recycling of at least a portion of a liquid fraction advantageously withdrawn at the top of the reactor. reactor and reinjected at the bottom of the reactor. The hydroconversion catalyst used in the hydroconversion stage c) of the process according to the invention contains one or more elements from groups 4 to 12 of the periodic table of the elements, which may be deposited on a support or not. Advantageously according to the invention, the hydroconversion catalyst of step c) is a catalyst comprising an alumina support and at least one group VIII metal chosen from nickel and cobalt, preferably nickel, said group VIII element. being used in combination with at least one Group VIB metal selected from molybdenum and tungsten, preferably the Group VIB metal is molybdenum. The nickel content in the hydroconversion catalyst is advantageously between 0.5 and 10%, expressed by weight of nickel oxide (NiO) and preferably between 1 and 6% by weight, and the molybdenum content is advantageously between 1 and 30% by weight of molybdenum trioxide (MoO 3), and preferably between 4 and 20% by weight. This catalyst is advantageously used in the form of extrudates or beads. The catalyst used in the hydroconversion stage c) is identical to or different from that used in the hydroconversion stage a). Advantageously, the catalyst used in the reactor (s) of the hydroconversion stage c) may also be a catalyst more suitable for the hydroconversion of residual cuts resulting from the hydroconversion stage a).
    [0018] A type of "slurry" catalyst according to the English terminology or entrained catalyst can be used in the process according to the invention. Said slurry catalyst has a particle size and a density suitable for its training. The term "entrainment of the dispersed catalyst" is understood to mean its circulation in the three-phase reactor (s) by the liquid streams, said second catalyst circulating from bottom to top, with the charge, in the said three-phase reactor (s), and being withdrawn from said one or more triphasic reactors with the liquid effluent produced. In one of the implementations of the process according to the invention, each reactor of the hydroconversion stage c) can use a different catalyst adapted to the feed that is sent to this reactor. In one of the implementations of the process according to the invention, several types of catalysts can be used in each reactor. In a preferred embodiment, each reactor of step a) and / or step c) may contain one or more supported catalysts and / or one or more unsupported catalysts. For each reactor, the replacement rate of the spent hydroconversion catalyst with fresh catalyst is advantageously between 0.01 kilograms and 10 kilograms per cubic meter of treated feedstock, and preferably between 0.1 kilogram and 3 kilograms per meter. load cube processed. This withdrawal and replacement are performed using devices advantageously allowing the continuous operation of this hydroconversion step.
    [0019] In accordance with the invention, the hourly space velocity (VVH) with respect to the volume and the liquid charge rate of the entire process taken under standard conditions of temperature and pressure is between 0.05 h -1. and 0.18 hr-1, preferably between 0.05 hr-1 and 0.09 hr-1, and preferably between 0.0511-1 and 0.0811-1. These conditions of the process of the invention make it possible to simultaneously improve the level of conversion and the stability of the liquid effluents by a heavy-load conversion scheme having optimized thermal level and residence time of the feedstock.
    [0020] Step d) Fractionation The effluent from hydroconversion step c) may advantageously then be subjected at least in part to a fractionation step d). This separation comprises any fractionation means known to those skilled in the art. This fractionation is performed by one or more flash balloons in series, preferably by a sequence of at least two successive flash balloons, preferably by one or more steam stripping columns and / or hydrogen, more preferably by an atmospheric distillation column, more preferably by an atmospheric distillation column and a vacuum column on the atmospheric residue, still more preferably by one or more flash flasks, an atmospheric distillation column and a vacuum column on the atmospheric residue. This fractionation can also be achieved by a combination of the different separation means described above. The fractionation step is carried out with the objective of separating the effluents at different cutting points and advantageously of obtaining at least one heavy liquid fraction called unconverted vacuum residue boiling predominantly at a temperature above 300.degree. preferably greater than 500 ° C and more preferably greater than 540 ° C. DESCRIPTION OF FIGURE FIG. 1 schematically represents the method according to the invention in the case where the separation step b) is implemented. The charge is sent via line (1) into a hydroconversion section (A) at high hydrogen pressure preferably operating as a bubbling bed. (A) represents step a) hydroconversion of the charge (1) in the presence of hydrogen, the hydrogen arriving via the pipe (2). The hydroconversion stage a) may be composed of one or more reactors arranged in parallel and / or in series.
    [0021] The effluent from the hydroconversion section (A) is sent via line (3) to the separation section (B). The heavy liquid fraction from the separation section (B) is sent to the hydroconversion step c) represented by section (C) via line (5) while the light effluent is removed from the separation ( B) by the pipe (4). The latter may partially or wholly be sent to the fractionation section (D) via the line (42) and / or partially or wholly directed to another unitary operation via the line (41). The hydroconversion step (c) (C) is composed of one or more reactors arranged in parallel and / or in series. The pipe (6) represents the injection of hydrogen in the hydroconversion stage c). The effluent of the hydroconversion stage (c) (C) can be sent entirely to the fractionation section (D) via line 7 to be divided into several sections. In this diagram only two cuts are shown, a light cut (8) and a heavy cut (9).
    [0022] Figure 2 illustrates the invention in a preferred embodiment. The charge is sent via the pipe (1) in the hydroconversion stage a) (section A) which is composed of several more reactors arranged in series and / or in parallel and preferably composed of two reactors operating in a bubbling bed. (A1 and A2) arranged in parallel and operating in hydrogen (lines 21 and 22 respectively). The effluents obtained at the end of the hydroconversion section (A) are combined and sent via line (3) to the separation section (B). In the separation section (B), the conditions are generally chosen so as to obtain two liquid fractions, a so-called light fraction (4), and a so-called heavy fraction (5), by any separation means known to man. of the craft, preferably without intermediate atmospheric distillation columns and vacuum, preferably by stripping, more preferably by a sequence of flash balloons and even more preferably by a single flash ball.
    [0023] The heavy liquid fraction at the outlet of the separation section is then sent via line (5) into the hydroconversion section (C) composed of one or more reactors arranged in parallel and / or in series and in a preferred manner. composed of a single high-pressure hydrogen reactor (6) operating as a bubbling bed.
    [0024] In the fractionation section (D), the conditions are generally chosen so as to obtain at least two liquid fractions, a so-called light fraction (8), and a so-called heavy fraction (9), preferably with the aid of a set of atmospheric and vacuum distillation columns. The following examples illustrate the invention without limiting its scope.
    [0025] EXAMPLES Charge The heavy load is a vacuum residue (RSV) from an Ural crude and whose main characteristics are shown in Table 1 below. Table 1: Composition of the process feedstock Stage A load RSV load Ural Density 1.0165 Viscosity at 100 ° C cSt 880 Conradson carbon ° / 0 wt 17.0 C7 Asphaltenes ° / 0 wt 5.5 C5 Asphaltenes ° Wt. 10.9 Nickel + Vanadium ppm 254 Nitrogen ppm 6150 Sulfur ° / wt. 2,715 This RSV heavy load is the same fresh feed for the various examples. EXAMPLE 1 (Comparative): Conventional Diagram at High Hourly Space Velocity (Global VVH = 0.3 1-1-1) and at High Temperature In this example, the state of the art is illustrated in a flow diagram with two ebullated bed reactors arranged in series, operated at high hourly space velocity (VVH) and at high temperature and with a separation section. Section a) Hydroconversion The fresh feed from Table 1 is sent entirely into a hydroconversion section (A) in the presence of hydrogen. Said section comprising a three-phase reactor containing a NiMo / alumina hydroconversion catalyst having a NiO content of 4 ° A> weight and a MoO3 content of 9 ° A> weight, the percentages being expressed relative to the total mass of the catalyst. The section operates as a bubbling bed with an upward flow of liquid and gas.
    [0026] The conditions applied in the hydroconversion section (A) are shown in Table 2.
    [0027] Table 2: Operating Conditions Section A Total MPa 16 Temperature ° C. 430 Amount of Hydrogen Nm3 / m3 640 These operating conditions make it possible to obtain a liquid effluent with a reduced content of Conradson carbon, of metals and of sulfur. Separation Section The hydroconverted liquid effluent is then sent to a separation section (B) composed of a single gas / liquid separator operating at the pressure and temperature of the reactors of the first hydroconversion section (A). A so-called light fraction and a so-called heavy fraction are thus separated. The so-called light fraction is mainly composed of molecules with a boiling point below 350 ° C. and the so-called heavy fraction is mainly composed of hydrocarbon molecules boiling at a temperature above 350 ° C.
    [0028] Section c) Hydroconversion The characterization of the heavy fraction sent to the second hydroconversion section (C) is presented in Table 3. Table 3: Composition of the charge of the bubbling bed hydroconversion section b) ( C) Charge of Step C Charge Heavy Fraction Density 0.9742 Conradson Carbon% wt 11.9 C7 Asphaltene% wt 5.2 C5 Asphaltene% wt 5.2 Nickel + Vanadium ppm 104.4 Nitrogen ppm 5890 Sulfur% wt In this reference scheme, the heavy fraction (5) is sent alone and entirely in a second hydroconversion section (C) in the presence of hydrogen (6). Said section comprises a three-phase reactor containing a NiMo / alumina hydroconversion catalyst having a NiO content of 4 '' / 0 weight and a MoO3 content of 9 '' / 0 weight, the percentages being expressed relative to the mass total catalyst. The section operates as a bubbling bed with an upward flow of liquid and gas. The conditions applied in the hydroconversion section (C) are presented in Table 4.
    [0029] Table 4: Operating conditions Total CP section MPa 15.6 Temperature ° C 430 Quantity of hydrogen Nm3 / m3 420 Fractionation section The effluent of the hydroconversion section (C) is sent to a fractionation section (D) Composed by an atmospheric distillation from which a light fraction (8) boiling at a temperature substantially below 350 ° C and an unconverted heavy-duty atmospheric residue (RA) fraction boiling at a temperature substantially greater than 350 ° C whose yields are recovered are recovered. compared to fresh load and quality are given in Table 5 below.
    [0030] Table 5: Fractionation effluent effluent efficiencies and grades Fraction Unconverted Atmospheric Residue Yield relative to fresh feed (1)% wd s 58.4 Density 0.9678 Conradson Carbon% wd s 9.55 C7 Asphaltenes% pd s 4.0 Nickel + Vanadium ppm 41.5 Nitrogen ppm 5885 Sulfur% pd s 0.7849 Sediment (IP-375)% pd s 0.54 3033797 18 Overall performance With this classic scheme, for a space velocity (VVH ) overall of 0.3 h -1, the total conversion of the heavy cut 540 ° C + is 75.4% by weight and the sediment content (IP-375) in the unconverted residual heavy cut RA is 0, 54% wt. EXAMPLE 2 (according to the invention): Scheme according to the invention at low hourly space velocity (global VVH = 0.089h-1) and at low temperature In this example, the present invention is illustrated in a flow diagram with two reactors in a bubbling bed arranged in series, operated at low hourly space velocity (VVH) and at a low temperature and with a separation section. Section a) Hydroconversion The fresh feed of Table 1 is sent entirely in a hydroconversion section (A) in the presence of hydrogen, said step comprising a three-phase reactor containing a hydroconversion catalyst NiMo / alumina with a content in NiO of 4 ° A> weight and a MoO3 content of 9 ° A> weight, the percentages being expressed relative to the total mass of the catalyst. The section operates as a bubbling bed with an upward flow of liquid and gas.
    [0031] The conditions applied in the hydroconversion step (A) are shown in Table 6. Table 6: Operating conditions Total AP section MPa 16 Temperature ° C 410 Quantity of hydrogen Nm3 / m3 1000 These operating conditions make it possible to obtain a Conradson carbon-reduced liquid effluent, metals and sulfur.
    [0032] Separating Section The hydroconverted liquid effluent is then sent to an intersecting separation section (B) composed of a single gas / liquid separator operating at the pressure and temperature of the reactors of the first hydroconversion section. A light fraction and a so-called heavy fraction are thus separated. The light fraction is mainly composed of molecules with a boiling point below 350 ° C. and the so-called heavy fraction is mainly composed of hydrocarbon molecules boiling at a temperature above 350 ° C. Section c) Hydroconversion The characterization of the heavy fraction sent to the second hydroconversion section (C) is presented in Table 7. Table 7: Composition of the charge of the bubbling bed hydroconversion section (C) Charge Step C Charge Heavy fraction Density 0.9665 Conradson Carbon ° / 0pd s 10.57 C7 Asphaltenes ° / 0pd s 3.6 C5 Asphaltenes ° / 0pd s 4.2 Nickel + Vanadium ppm 65.7 Nitrogen ppm 5680 Sulfur ° In this scheme according to the present invention, the heavy fraction (5) is sent alone and entirely into a second hydroconversion section (C) in the presence of hydrogen (6), said step comprising a triphasic reactor. containing a NiMo / alumina hydroconversion catalyst having a NiO content of 4 ° A> weight and a MoO3 content of 9 ° A> weight, the percentages being expressed relative to the total mass of the catalyst. The section operates as a bubbling bed with an upward flow of liquid and gas. The conditions applied in the hydroconversion step (C) are presented in Table 8.
    [0033] Table 8: Operating conditions Total CP section MPa 15.6 Temperature ° C 410 Quantity of hydrogen Nm3 / m3 560 Fractionation section 5 The effluent from the hydroconversion stage (C) is sent to a section of fractionation (D) composed by an atmospheric distillation from which a light fraction (8) boiling at a temperature essentially below 350 ° C and an unconverted heavy-duty atmospheric residue (RA) fraction boiling at a temperature substantially greater than 350 ° C. are recovered. whose yields relative to fresh load and quality are given in Table 9 below.
    [0034] Table 9: Fractionation effluent effluent efficiencies and grades Fraction Unconverted Atmospheric Residue Yield relative to fresh feed (1)% pd s 54.0 Density 0.9590 Conradson Carbon% pd s 7.42 C7 Asphaltenes% pd s 2.1 Nickel + Vanadium ppm 10.3 Nitrogen ppm 5305 Sulfur% pd s 0.4684 Sediment (IP-375)% pd s 0.15 Overall performance 15 With this scheme according to the invention at global VVH = 0.089 h -1 the total conversion of the heavy cut 540 ° C + is 75.3% by weight and the sediment content (IP-375) in the unconverted residual heavy cut RA is only 0.15% by weight. Compared to the conventional scheme treated in Example 1, the purification performance is higher for a conversion level of the heavy cut 540 ° C 540 ° C + almost identical. The stability of the liquid conversion effluents is very much improved. 5
    权利要求:
    Claims (2)
    [0001]
    REVENDICATIONS1. A method of converting a heavy hydrocarbon feedstock, said method comprising the steps of: a) a step of hydroconversion of the heavy hydrocarbon feedstock in the presence of hydrogen in at least one or more three-phase reactors arranged in series or in parallel, containing at least one hydroconversion catalyst, the hydroconversion step a) being carried out under an absolute pressure of between 2 and 35 MPa, a temperature of between 300 and 550 ° C., and in a quantity of hydrogen mixed with the load of between 60 and 5000 normal cubic meters (Nrn3) per cubic meter (m3) of filler, so as to obtain a liquid effluent with a reduced content of Conradson carbon, of metals, of sulfur and of nitrogen, b ) one or more optional steps for separating the effluent from step a) making it possible to obtain at least one light liquid fraction boiling at a temperature below 350 ° C. and a heavy liquid fraction boiling at a temperature above 350 ° C, C) a step of hydroconversion of the liquid effluent from the hydroconversion step a) in the case where the separation step b) is not implemented. of the heavy liquid fraction resulting from the separation step b) when said step b) is carried out, in the presence of hydrogen in at least one or more three-phase reactors arranged in series or in parallel, containing at least a hydroconversion catalyst, the hydroconversion stage c) being carried out under an absolute pressure of between 2 and 38 MPa, at a temperature of between 300 and 550 ° C., and under a quantity of hydrogen of between 50 and and 5000 normal cubic meters (Nm3) per cubic meter (m3) of liquid charge taken under standard conditions of temperature and pressure, in which process the overall hourly space velocity employed is between 0.05 and 0.1811-1 .
    [0002]
    2. Method according to claim 1 wherein the overall hourly space velocity used is between 0.05 h-1 and 0.09 h-1. . A process according to claim 1 or 2 wherein the effluent from hydroconversion step c) is subjected at least in part to one or more fractionation steps d) to separate the effluents at different cutting points. 4. Method according to one of the preceding claims wherein the feedstock contains hydrocarbon fractions of which at least 80% by weight have a boiling point above 300 ° C, atmospheric residues and / or residues under vacuum, atmospheric and / or vacuum residues from hydrotreating, hydrocracking and / or hydroconversion, fresh or refined vacuum distillates, cuts from a cracking unit such as FCC, coking or Viscoreduction, aromatic cuts extracted from a lubricant production unit, deasphalted oils from a duster unit, asphalts from a deasphalting unit or similar hydrocarbon feedstocks, or a combination thereof fresh loads and / or refined effluents or residues or distillates of direct liquefaction of coal, or residues or distillates of pyrolysis of coal or shale oils, or Residual volume resulting from the direct liquefaction of lignocellulosic biomass alone or mixed with coal and / or a fresh and / or refined petroleum fraction. 5. Method according to one of the preceding claims wherein step a) or step c) is carried out under an absolute pressure of between 5 and 25 IVIPa, at a temperature between 350 and 500 ° C. 6. Method according to one of the preceding claims wherein each reactor in step a) and / or in step c) may contain one or more supported catalysts and / or one or more unsupported catalysts. Process according to one of the preceding claims, in which the hydroconversion catalyst of step a) or of step c) is a catalyst comprising an alumina support and at least one group VIII metal chosen from nickel and cobalt, said group VIII element being used in combination with at least one Group VII3 metal selected from molybdenum and tungsten. 8. Method according to one of the preceding claims wherein the nickel content in the hydroconversion catalyst of step a) is between 0.5 and 10% by weight of nickel oxide (NiO) and the molybdenum content is between 1 and 30%, expressed by weight of molybdenum dioxide (MoO 3). Method according to one of the preceding claims wherein the step b) of separation is performed by one or more flash balloons in series. 10. Method according to one of claims 3 to 9 wherein the light liquid fraction separated from step b) is sent in step d) fractionation
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    同族专利:
    公开号 | 公开日
    PT3271441T|2019-11-26|
    CN107889498A|2018-04-06|
    RU2707509C2|2019-11-27|
    ES2754381T3|2020-04-17|
    EP3271441A1|2018-01-24|
    WO2016146326A1|2016-09-22|
    RU2017135386A|2019-04-05|
    US20180195013A1|2018-07-12|
    CN107889498B|2020-06-19|
    RU2017135386A3|2019-07-26|
    FR3033797B1|2018-12-07|
    EP3271441B1|2019-09-04|
    PL3271441T3|2020-03-31|
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    优先权:
    申请号 | 申请日 | 专利标题
    FR1552092|2015-03-16|
    FR1552092A|FR3033797B1|2015-03-16|2015-03-16|IMPROVED PROCESS FOR CONVERTING HEAVY HYDROCARBON LOADS|FR1552092A| FR3033797B1|2015-03-16|2015-03-16|IMPROVED PROCESS FOR CONVERTING HEAVY HYDROCARBON LOADS|
    PT167046499T| PT3271441T|2015-03-16|2016-02-16|Improved method for converting heavy hydrocarbon feedstocks|
    EP16704649.9A| EP3271441B1|2015-03-16|2016-02-16|Improved method for converting heavy hydrocarbon feedstocks|
    RU2017135386A| RU2707509C2|2015-03-16|2016-02-16|Improved method of converting heavy hydrocarbon feedstock|
    ES16704649T| ES2754381T3|2015-03-16|2016-02-16|Improved procedure for converting heavy hydrocarbon charges|
    US15/558,846| US20180195013A1|2015-03-16|2016-02-16|Method for converting heavy hydrocarbon feedstocks|
    CN201680028422.7A| CN107889498B|2015-03-16|2016-02-16|Improved process for converting heavy hydrocarbon feedstocks|
    PCT/EP2016/053255| WO2016146326A1|2015-03-16|2016-02-16|Improved method for converting heavy hydrocarbon feedstocks|
    PL16704649T| PL3271441T3|2015-03-16|2016-02-16|Improved method for converting heavy hydrocarbon feedstocks|
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