• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    Storage of energy from electrolessable sulphate-based electrical energy to produce pressurized hydrogen on demand without a compressor in the same reactor.
    公开号:FR3029536A1
    申请号:FR1501811
    申请日:2015-08-26
    公开日:2016-06-10
    发明作者:Jean Edmond Chaix
    申请人:Ergosup；
    IPC主号:
    专利说明:

    [0001] 1 STORAGE OF ELECTRICITY USING AN ELECTROLYSABLE METAL AS A VECTOR 1. TECHNICAL FIELD AND PRIOR ART The storage of electrical energy is one of the main obstacles to the implementation of intermittent energies produced by wind turbines, solar thermal, or photovoltaic light. . The energy storage methods currently used, in the absence of knowing how to store the electricity directly, are based on compressed air, hydrogen, hydraulic potential energy, flywheel etc. The quantities of energy In the case of the use of a carrier gas, this gas must be strongly compressed and stored under pressure, which in the case of hydrogen poses some serious safety problems. The use of hydrogen as an energy vector is developing in Germany around a so-called "power to gas" concept which consists in storing the electrical energy produced and not consumed in the form of hydrogen electrolysis under pressure, and injecting it on demand into the natural gas distribution networks so as to boost it. Another way to meet the energy demand is to burn the hydrogen stored in a high temperature steam turbine or to fuel a fuel cell. An alternative to the storage of hydrogen is the storage of zinc produced by electrolysis of zinc sulphate which can restore hydrogen under pressure by acid attack in a suitable reactor. This process of hydrogen generation was used during the First World War to inflate the observation balloons. Zinc is a particularly interesting material for the development of electrochemical storage solutions: its metallurgy is well known, and it is produced via an industrial mass process: electrolysis in sulfuric medium. Zinc is both a very abundant element (availability 100 times greater than lithium) and whose physicochemical properties are well known. It has the advantage of having a high energy content (> 1 kWh / kg zinc) while still being electrolyzable in an aqueous medium. This is what sets it apart from other metals with a high energy density (magnesium, aluminum), which themselves can only be electrolysed in molten salts medium, zinc being the last most reductive material that can be electrolyzed. in an aqueous medium. This is particularly related to the fact that hydrogen has an electrode overvoltage greater than that of zinc deposit. As a result, zinc is at the heart of electrochemical applications: its primary manufacture is by electrolysis, but also it is recycled by electro-refining and it is deposited as protection by electroplating. It is also historically the most used material as anode in batteries. Other metals such as iron or manganese could be used in this concept although being less energetic than zinc. 2. PRIOR ART Patent WO 2011/015723 describes a high-capacity electricity and hydrogen cogeneration device that can be operated with a single cell comprising two electrodes, for example titanium nitride and copper and alternatively allowing electrolysing an electrolysable metal (the latter may be zinc), then to restore hydrogen and electricity by cell dissolution effect. The device described can also work with differentiated cells and electrodes to optimize the operating parameters. The described electrochemical storage system operates for example with an electrolyte composed mainly of sulphate and sulfuric acid and with the following electrochemical mechanisms: at the charge (electrical storage): the metal is deposited on the negative and the oxygen at the positive-discharge (electric storage): the metal is put back in solution to the negative by generating sulfate of degree 2 and water and hydrogen is released in the positive. French Patent No. 3009654 describes a massive electricity storage system which uses an electrolysable metal as a vector in which this metal is deposited on a mobile structure in the pool and then put back into solution in attack reactors in which the hydrogen is produced under pressure all transfers being fully robotic. The object of the invention is a device for storing electrical energy in the form, for example, of zinc and of acid sulphate solution, which restores hydrogen under pressure on demand in a single reactor. EXPOSURE OF THE INVENTION 4. PRESENTATION OF THE FIGURES FIG. 1/5 gives a vertical section of Ergomegastore in a 2nd embodiment FIG. 2/5 gives a view of the fixed and mobile electrodes in a 2 ° Embodiment 10 FIG. 3/5 shows a cross-section of the shaft sealing system in a 2nd embodiment FIG. 4/5 shows a vertical section of the fixed and moving electrodes in a second embodiment of FIG. FIG. 5/5 gives a section of the closure of the capacity in a 2nd embodiment. DETAILED DESCRIPTION OF AN EMBODIMENT In a preferred embodiment of the invention, the zinc is deposited during the period electricity must be stored, and attacked when we want to produce hydrogen in the same equipment. This equipment consists of a horizontal high pressure tank Rep 200 crossed by a hollow shaft Rep 305.
    [0002] This tank has an autoclave Rep 214 removable closure consisting of a lid with a conical bearing, a conical segment Rep 216, a segmented segmented rod Rep 217. Pressure screws implanted in ears welded on the cover allows to closely-tighten the conical seal between the inner wall of the capacity and the conical bearing surface of the lid Rep 215.
    [0003] On this through shaft are fixed discs of dielectric composite material Rep 402. Rep. 406 spacers allow, according to their nature, spacing them, isolating them from one another or bypassing them on the central bar Rep 304. At each of its ends the shaft Rep 305 is equipped with a system rotating seal 5 Rep 204 and a slip-on manifold Rep 205. The sealing system consists of a Rep 300 sealable metal o-ring with a lip seal Rep 301. Rep 303 is used to purge the joint. A gear motor Rep 206 is mounted on one end of the shaft Rep 307 and allows it to make a rotation of 1/2 turn.
    [0004] Discs of composite material Rep 401 are interposed between the mobile discs Rep 402 with a pitch of about 10 mm. These discs are centered by the fixed bars Rep 208 spaced by Rep spacers 407 and form a one-piece assembly with the support of the bars Rep 309.The mobile discs Rep 402 are guided at their periphery by a plurality of rollers Rep 405 supported by the discs Rep 401 This assembly 15 is recentered in the capacity by the bosses Rep 308. On each movable disk are fixed on both faces vis-à-vis two sheets of stainless steel or titanium in the form of a half-moon Rep 403 serving cathode and receive zinc deposition Fe or Mn. On each of the fixed discs Rep 401 are fixed on both faces facing each other four sheets in the form of a half-moon. On the lower part of these fixed disks these sheets are made of nickel made of copper, of carbon fabric or of stainless steel: they play the role of counter electrode during the acid attack of zinc. On the top: they are made of lead or titanium nitride, and play the role of anode during the deposition phase of zinc.
    [0005] Depending on the type of material of the spacers Rep 407 and Rep 406, the fixed and mobile electrodes may be connected in a "press filter type" structure (the power supply is connected to the fixed end electrodes) or be paralleled by via the Rep 208 fixed bars and the Rep 304 rotary bar. A Rep205 rotary pad connector makes it possible to electrically connect the Rep 30 304 bar to the continuous electrical supply Rep 600, itself connected to a 10KV network. Rep 601 The Rep200 capacity is connected to a high pressure separator tank Rep 201 via a couple of valves Rep210. At the outlet of the balloon Rep 201 is disposed, after an isolation valve Rep 227, a hydrogen purification system Rep 500 and a weir Rep 501. The capacitor Rep 200 is connected to a circuit on which are arranged in series. : a high pressure motor valve, a low pressure separation tank, a regulation valve Rep209, a circulation pump Rep 224, a low pressure tank Rep 222, a second high pressure motor valve. A weir valve Rep 213 isolates the ball Rep 202. A ball containing neutral gas Rep 220 can inerter the capacity Rep 200 and balloons Rep 201 and 202.
    [0006] A lift pump Rep 212 transfers electrolyte from the reservoir Rep 222 to the capacity Rep 200. METHOD 15 STORAGE OF ENERGY To deposit the zinc during periods of overproduction of the electrical network: The valves Rep 210 are closed to isolate the ball Rep 201 The electrodes Rep 403 of the mobile disks Rep 401 are placed in the high position: high above the horizontal diametral plane of the capacitance Rep200, opposite the lead electrodes Rep 404 of the fixed disks Rep 400. The capacitor Rep 200 and the Ball Rep 202 is completely filled by starting the pump Rep 224. The inter-electrode spaces are scanned from top to bottom by the electrolyte flow of the pump Rep 224.
    [0007] The electrodes are then polarized by the feed Rep 600. The zinc is deposited on the mobile electrodes Rep 403 and the oxygen which is released concentrates in the degassing drum Rep 202. When the pressure therein is sufficient the weir opens by regulating the pressure in the balloon Rep 202 to a few bars. The level in the flask is regulated by the valve Rep 212 and the pump Rep 223.
    [0008] 302 95 36 6 DESTOCKING HYDROGEN The production of high pressure hydrogen is carried out according to the following procedure: The power supply of the electrodes is cut off; the oxygen skirt of the balloon Rep 202 is purged by the complete electrolyte filling to the weir Rep 213. The electrolyte level in the balloon Rep 200 is reduced to a few cm below its diametral plane by injecting neutral gas via the valve Rep 226. The motorized valves Rep 203 are closed, the valves Rep 210 are open, the valve 10 Rep 227 and closed. The purification is in hydrogen pressure until weir Rep 501 closed the inflatable O-ring Rep 302 is supported by a neutral gas pressure. The shaft Rep 305 is progressively half a turn to plunge the mobile electrodes in the electrolyte thus causing the dissolution of zinc and the evolution of hydrogen.
    [0009] The electro-chemical battery effect produced by the dissolution makes it possible to recover low-voltage electrical current between the fixed and moving electrodes in the low position. This energy is converted by a BARLOW wheel-running unit and a Rep 602 inverter which allows low-voltage alternating current to be injected into a user network Rep 603. INDUSTRIAL APPLICATIONS 25 This high-capacity electrical storage can be used in photovoltaic or thermal solar power plants to ensure nighttime production and wind turbine fields to smooth their production. 9.ABREGE: Energy storage based on electrolessable sulphate-based electrical energy, making it possible to produce pressurized hydrogen without the need for a compressor within the same reactor. 10. Figure for the summary: FIGURE 1/5
    权利要求:
    Claims (16)
    [0001]
    CLAIMS1- Storage of electricity using the vector Zn, Fe or Mn, characterized in that it may consist of a horizontal high pressure tank Rep 200 crossed by a hollow shaft Rep 305, in which Zn the Fe or the Mn is deposited, during the period when the electricity must be stored, and attacked when one wants to produce hydrogen
    [0002]
    2- Electricity storage using the vector Zn, Fe or Mn according to claim 1 10 characterized in that the tank Rep200 has a removable autoclave closure Rep 214.
    [0003]
    3- Electricity storage using the vector Zn Fe or Mn, according to claims 1 to 2, characterized in that the autoclave Rep 214 removable closure is composed of a lid with a conical seat Rep 215, d a conical segment Rep 216, of a segmented square section rod Rep 217, pressure screws implanted in lugs welded to the cover making it possible to prestress the conical segment Rep 216 between the inner wall of the capacitor Rep 200 and the span conical cover Rep 215. 20
    [0004]
    4- Electricity storage using the vector Zn, Fe or Mn, according to claims 1 to 3, characterized in that on the shaft Rep 305 are fixed discs Rep. 402 dielectric composite material alternating with spacer rings Rep 406 allowing, according to their nature, to space them, to isolate them from each other, or to short-circuit them on the central bar Rep 304, each end of the shaft Rep 307 being equipped with a system of rotational seal Rep 204 and a slip manifold Rep 205.
    [0005]
    5. Electricity storage using the vector Zn, Fe or Mn, according to claims 1 to 4, characterized in that at each of its ends the shaft Rep 305 is equipped with a rotary sealing system composed of an inflatable metal o-ring Rep 300 lined with a lip seal Rep 301, a stitching Rep 303 for purging the joint seal Rep 204. 302 95 36 8
    [0006]
    6- Electricity storage using the vector Zn Fe or Mn, according to claims 1 to 5, characterized in that a gear motor Rep 206 is mounted on one end of the shaft Rep 305 and allows him to rotate 1/2 turn.
    [0007]
    7- Electricity storage using the vector Zn Fe Mn, according to claims 1 to 6, characterized in that discs of composite material Rep 401 are interposed between the mobile discs Rep 402 with a pitch of about 10 mm, centered by the fixed bars Rep 208, spaced by spacers Rep 407, forming a one-piece assembly with the support of the bars Rep 309,
    [0008]
    8- Electricity storage using the vector Zn Fe or Mn, according to claims 1 to 7, characterized in that the mobile disks Rep 402 are guided at their periphery by a plurality of rollers Rep 405 supported by the fixed disks Rep 401 , this assembly being recentered in the capacity by bosses Rep 308.
    [0009]
    9- Electricity storage using the vector Zn Fe or Mn, according to claims 1 to 8, characterized in that on each mobile disc are fixed on both faces in facing relation, two stainless steel sheets or in the form of a half-moon Rep 403 serving as a cathode and which receive the zinc deposit.
    [0010]
    10- mass storage of electricity using the vector Zn Fe Mn, according to claims 1 to 9, characterized in that on each fixed disc Rep 401 are fixed on both faces in facing relation to four metal sheets in the form of half Moon . 25
    [0011]
    11- Electricity storage using the vector Zn Fe or Mn, according to claims 1 to 10, characterized in that on the lower part of these fixed disks these plates Rep 403 are copper nickel or carbon fabrics playing the counter electrode role during acid attack of zinc, on the upper part these Rep 404 sheets are lead or titanium, playing the role of anode during the deposition phase of zinc. 30
    [0012]
    12- Electricity storage using the vector Zn Fe or Mn, according to claims 1 to 11, characterized in that according to the type of the material of the spacers Rep 407 and Rep 406 the fixed electrodes Rep 400 and mobile Rep 401 can be connected in "filter-press" structure (the power supply being connected to the fixed end electrodes) or being connected in parallel via the fixed bars Rep 208 and the rotating bar Rep 304, a rotating connector with pad 205 for electrically connecting the bar Rep 304 to the continuous power supply Rep 600, itself connected to a network 100 KV Rep 601. 5
    [0013]
    13- Electricity storage using the vector Zn Fe Mn according to claims 1 to 12, characterized in that it has a high pressure separator tank Rep 201, three isolation valves Rep 210 and Rep 227, a purification system of the high pressure hydrogen Rep 500 and a spillway Rep 501. 10
    [0014]
    14- Electricity storage using the vector Zn, Fe or Mn according to claims 1 to 13, characterized in that it has a circuit on which are arranged in series: a motorized high pressure valve Rep 203, a separation balloon low pressure, equipped with a weir valve Rep 213, a control valve Rep 209, a circulation pump 15 Rep 224, a low pressure tank Rep222, a second high pressure motor valve.
    [0015]
    15- Electricity storage using the vector Zn Fe or Mn, according to claims 1 to 14, characterized in that it has a ball containing neutral gas Rep 220 20 for inerter capacity Rep 200 and balloons Rep 201 and 202, a lift pump Rep 223 for transferring electrolyte reservoir Rep 222 to the capacity Rep 200. 25
    [0016]
    16- Electricity storage using the vector Zn Fe or Mn, according to claims 1 to 15, characterized in that it has a wheel spinning unit BARLOW and an inverter Rep 602, which allows to inject alternating current low voltage on a user network Rep 603, the effect of electrochemical cell produced by the dissolution for recovering electric current under low voltage between the fixed electrode and the mobile electrodes in the low position.
    类似技术:
    公开号 | 公开日 | 专利标题
    FR3029536B1|2019-11-15|ELECTRICITY MASS STORAGE USING ELECTROLYSABLE METAL AS VECTOR
    JP2021137807A|2021-09-16|Aqueous solution supply device comprising water-repellent porous fluorocarbon resin film
    CA1079222A|1980-06-10|Electrolitie cell for the industrial production of fluorine
    KR20120059516A|2012-06-08|Method for the cogeneration of electrical and hydrogen power
    EP3183770B1|2018-07-18|Electrochemical device for storing electrical energy and producing hydrogen, and method for producing hydrogen
    CN102864463A|2013-01-09|H2 collection system for kitchen wastes
    EP2002033B1|2017-11-01|A device for production of hydrogen by electrolysis
    CN106532141B|2017-09-19|A kind of chemical synthesizing method of battery
    FR2976597A1|2012-12-21|ADSORBENT OF RADIOACTIVE MATERIALS IN THE FORM OF A GARMENT AND METHOD OF MANUFACTURING THE SAME.
    JP6438741B2|2018-12-19|Electrical insulation method for electrolysis system
    CN104716404B|2017-02-15|Metal/air battery
    CN207031566U|2018-02-23|A kind of high electric density low power consumption electrolysis unit groove
    CN109841931A|2019-06-04|A kind of chlorine magnesium fuel cell
    JPS5742501A|1982-03-10|Method of storing renewable energy in the form of hydrogen compound
    CN204407417U|2015-06-17|A kind of magnesium alloy anode substep release type magnesium seawater dissolved oxygen battery
    EP3724372A1|2020-10-21|Method for storing electrical energy in solid matter
    TWM615759U|2021-08-21|Gas production system
    NL2022332B1|2020-07-23|Electrolytic cell for H2 generation
    CN111023554B|2021-07-09|Water storage type water heater
    WO2014073410A1|2014-05-15|Metal-air cell
    CN110048136B|2022-03-18|Electrochemical reactor equipped with lyophobic porous membrane
    Fray2013|Renewable energy and the role of molten salts and carbon
    JP2004169059A|2004-06-17|Apparatus for producing hydrogen by using atmospheric moisture
    JP6960211B2|2021-11-05|Free-standing hydrogen power generation and drinking water supply system
    Landman et al.2022|New electrolyzer principles: decoupled water splitting
    同族专利:
    公开号 | 公开日
    WO2017032835A1|2017-03-02|
    FR3029536B1|2019-11-15|
    FR3009654A1|2015-02-13|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    CN201464791U|2009-05-12|2010-05-12|赵登亮|Drying system for ammonia-free quick blue printing machine|
    FR2948654A1|2009-07-30|2011-02-04|Gerkaro|COGENERATION OF ELECTRIC ENERGY AND HYDROGEN|
    WO2013042640A1|2011-09-21|2013-03-28|エクセルギー工学研究所株式会社|Laminated battery and battery pack using same|
    US696157A|1901-12-30|1902-03-25|Auguste Henri Bainville|Electrode for secondary batteries.|
    US6162333A|1999-01-22|2000-12-19|Renovare International, Inc.|Electrochemical cell for removal of metals from solutions|CN109958882B|2017-12-26|2020-09-29|有研工程技术研究院有限公司|Integrated control system for hydrogen production by water electrolysis and alloy hydrogen storage|
    FR3093168A1|2019-02-22|2020-08-28|Patrice Chevalier|MULTI-SOURCE PROGRESSIVE THERMOVOLTAIC DEVICE WITH ENERGY STORAGE CAPACITIES, AND ASSOCIATED PROCESSES.|
    CN110380306B|2019-07-22|2021-04-06|东莞市勤本电子科技有限公司|Automobile wire harness joint connecting device|
    WO2022029776A1|2020-08-04|2022-02-10|H2Pro Ltd|Electrochemical systems and methods of use|
    法律状态:
    2016-09-07| PLFP| Fee payment|Year of fee payment: 4 Year of fee payment: 2 |
    2016-10-07| ST| Notification of lapse|Effective date: 20160906 |
    2016-10-21| RN| Application for restoration|Effective date: 20160921 |
    2016-12-30| FC| Favourable decision of inpi director general on an application for restauration.|Effective date: 20161201 |
    2017-06-16| PLSC| Search report ready|Effective date: 20170616 |
    2017-07-25| PLFP| Fee payment|Year of fee payment: 5 |
    2018-07-26| PLFP| Fee payment|Year of fee payment: 6 |
    2019-11-21| PLFP| Fee payment|Year of fee payment: 8 |
    2021-07-22| PLFP| Fee payment|Year of fee payment: 9 |
    优先权:
    申请号 | 申请日 | 专利标题
    FR1301918A|FR3009654A1|2013-08-12|2013-08-12|ELECTRICITY MASS STORAGE USING ELECTROLYSABLE METAL AS VECTOR|
    FR1301918|2013-08-12|
    FR1501811|2015-08-26|
    FR1501811A|FR3029536B1|2013-08-12|2015-08-26|ELECTRICITY MASS STORAGE USING ELECTROLYSABLE METAL AS VECTOR|FR1501811A| FR3029536B1|2013-08-12|2015-08-26|ELECTRICITY MASS STORAGE USING ELECTROLYSABLE METAL AS VECTOR|
    PCT/EP2016/070084| WO2017032835A1|2013-08-12|2016-08-25|Electricity storage using a metal that can be electrolysed as a vector|
    [返回顶部]