![]() ELECTRICAL RADIATOR WITH PHASE CHANGE
专利摘要:
The device (10) includes a heater (12) configured to be connected to a power source, an energy storage tank (26) thermally coupled with the heater (12), and a receptacle (18) inside which extend the heating body (12) and the tank (18). In addition, the reservoir (26) comprises at least one phase change material with a predefined transition temperature from a first phase to a second phase. The reservoir (26) is configured to assume a discharged state and a charged state respectively corresponding to the first phase and the second phase of the material by thermal coupling with the heater (12). 公开号:FR3026471A1 申请号:FR1459270 申请日:2014-09-30 公开日:2016-04-01 发明作者:Frederic Daniel Rene Joubert 申请人:Verelec; IPC主号:
专利说明:
[0001] The present invention relates to an electric heating device, particularly adapted for home use and an electric heating system comprising the device. The invention relates more particularly but not exclusively to an electric heating device used as the main or auxiliary heating of premises of all types. Such an electric heater may be installed in a fixed or movable manner. It is common to use electrical energy for space heating such as homes, offices or business premises. [0002] Electrical energy has many advantages over other traditionally used energy sources such as gas and oil. Among the many advantages are cleanliness, comfort, ease of adjustment and low initial investment. The heaters currently used for electric heating operate on the principle of the Joule effect to create a source of heat through a potential drop in a resistor. The heat thus produced is transferred to the environment according to different principles. According to a first principle, the heat is transferred by convection. [0003] In this case, the electric heater generally comprises a resistor housed inside a receptacle provided with air inlet and outlet. The temperature of the air in the vicinity of the heated resistance increases so that the density of the air decreases. This hot air tends to rise and an updraft of air is established. Hot air is replaced by cold air, which in turn warms up. Such an electric heater is commonly referred to as a "convector". According to a second principle, the heat is transferred by radiation. In this case, the transfer of the energy produced by the heated resistor is essentially obtained by the radiation emitted by it. Such electric heaters are commonly referred to as "radiant panel" or "radiant panel". According to a third principle, the heat is transferred by conduction. In this case, this transfer is done by contact. [0004] The present invention relates more specifically but not exclusively to the electric heating device operating according to the second principle. In particular, within the meaning of the present invention, the expression "radiative" or "essentially radiative" is understood to mean that most of the heat transfer takes place by radiation, which does not exclude that a minority part is done by convection. A disadvantage of the use of electric power is that its cost per kilowatt hour is significantly higher than that of other energies. In order to reduce the cost of electricity consumption of the current heating devices, various solutions have been made. It has thus been proposed in the state of the art to incorporate in the receptacle of the electric heating device a core or energy storage block which in particular allows heat to be stored for later retrieval. Such a device is for example described in EP0860666B1. This document describes an electric heating device comprising a heating body formed by a plurality of electrical resistors and an energy storage core formed by a refractory brick inside which the electrical resistances are embedded. The brick is also enclosed in an envelope forming a generally metallic carcass. Thanks to this device, it is possible to postpone the production of heat from its restitution. The electrical consumption of the radiator is then optimized according to the hourly cost of the electrical energy: the electrical energy is consumed during the so-called hollow hours, generally at night, for which there is a reduced rate of consumption and the heat is accumulated in the core or accumulator block and stored heat is returned during so-called full hours, usually during the day. This reduces the total daily cost of electricity consumption of such heaters. The disadvantage of such a heating device is that it turns out to be particularly bulky. Moreover, the weight of the refractory brick is not negligible and it is often necessary to have the radiator on the ground. Also the present invention aims to overcome all or part of these disadvantages while allowing a significant improvement in efficiency and therefore a significant reduction in energy consumption. To this end, the subject of the invention is an electric heating device, in particular adapted for heating for domestic use, of the type comprising: a heating body configured to be connected to a power supply source; accumulation of energy coupled thermally with the heating body, and a receptacle within which the heating body and the reservoir extend, characterized in that the reservoir comprising at least one phase change material with a predefined transition temperature from a first phase to a second phase, the reservoir is configured to adopt a discharged state and a charged state respectively corresponding to the first phase and the second phase of the material by thermal coupling with the heating body and the heating body comprises a high emissivity support layer and a low emissivity electroconductive layer deposited on the support layer, the heating body being arranged in the receptacle to generate a heat transfer substantially outward and a secondary heat transfer to the tank. For the purposes of the present invention, two elements are thermally coupled when they have significant heat exchange. In a manner known per se, any object or terrestrial body emits energy by radiation. This ability to emit is referred to as emissivity. Thus, in the context of the present invention, the heat exchange is preferably carried out essentially by radiation. For the purposes of the present invention, the state of the reservoir when the material is in the second phase and in the discharged state means the state of the reservoir when the material is in the first phase. The states charged and discharged can be defined more precisely by adding a temperature condition. Thus, it will be possible to define a so-called unloaded state temperature and a so-called charged state temperature, these temperatures being able to differ from the phase transition temperature. For example, we can consider that the tank is in an unloaded state when in addition to being in the first phase, it is at room temperature for example at 20 ° C and that it is in a loaded state when in addition to be in the second phase, it has a preset temperature higher than the phase transition temperature. In a manner known per se, phase change materials are materials that have the property of storing a lot of thermal energy during the phase change. The return of the material in its initial phase is accompanied by a release of heat energy equivalent to the latent heat that was necessary for the change of state of the material. When the heating body is electrically powered, it heats and produces heat which is generally transmitted mainly towards the outside but also in a minority way backwards, for example in the direction of the wall against which the heating device is square. Thanks to the invention, the minority part of the energy is recovered by its storage in the tank comprising the latent heat material. When the temperature of the latent heat material reaches its transition or phase change temperature, then the latent heat material changes phase, and for example changes from a liquid state to a gaseous state (or from a solid state to a solid state). a liquid state). When the temperature of the heating body decreases, that of the reservoir also and the latent heat material passes from the gaseous state to the liquid state (or from the liquid state to the solid state) by releasing a quantity of energy important. Due to the deposition in the electroconductive layer on the support layer, the radiation emitted by the heating element is homogeneous and reaches the reservoir in a substantially homogeneous manner. The tank recovers the radiated heat homogeneously which allows a very efficient heat transfer. [0005] In a preferred embodiment of the invention, the reservoir comprises a plurality of capsules each containing at least said phase change material. The capsules thus form an envelope for surrounding the phase change material. For example, the phase change material is based on paraffin, polymers, etc. In a preferred embodiment of the invention, the distance separating the heating body and the reservoir is non-zero. Thus, the heat transfer between the heating body and the reservoir is achieved essentially by radiation. As the heating body and the reservoir are not in contact, there is no heat transfer by conduction. The heating body and the reservoir are separated by a distance between, for example, 2 millimeters and 50 millimeters. In a preferred embodiment of the invention, the electrically conductive layer is a thin layer made by a vacuum metallization process. This metallization process makes it possible to form a layer with a very homogeneous distribution of the electrically conductive material or materials. The radiation heat transfer between the heater and the tank is thus still significantly improved. In a preferred embodiment of the invention, the phase change material has a transition temperature greater than or equal to 75 ° C. The thermal recovery is thus optimized with this temperature. [0006] In a preferred embodiment of the invention, the heating body forms a front wall of the receptacle. The receptacle comprises a rear wall arranged opposite and at a distance from the front wall, the reservoir extending between the two walls. In a preferred embodiment of the invention, the device comprises an insulating element thermally configured in the receptacle so as to limit the emission of an energy flow towards the rear wall. Preferably, the electrically conductive layer is a reflective layer of light. This allows the electric heater to be used as a mirror as well. [0007] The invention also relates to an electric heating system comprising a device according to the invention, characterized in that it comprises means for controlling the supply of the heating body as a function of a state of charge of the tank. [0008] In a preferred embodiment, the means are configured to drive the supply of the heater to generate a plurality of charge-discharge cycles of the tank. In a preferred embodiment, the means is configured to deactivate the supply of the heating body when the tank is charged and to activate the supply of the heating body when the tank is discharged. In a preferred embodiment, the system comprises means for determining the state of charge by measuring a first temperature and a second temperature respectively at two points of the energy storage tank, the points being chosen so that the difference between these two temperatures is related to a state of charge of the tank or by a measurement of a predetermined duration corresponding to a duration of charge or discharge. Other characteristics and advantages of the invention will emerge in the light of the description which follows, made with reference to the appended drawings in which: FIG. 1 represents a perspective view of a heating device according to the invention; FIG. 2 represents an exploded perspective view of the device represented in FIG. 1; FIGS. 3A and 3B show views respectively of an external face and an internal face of a front wall of the heating device represented on FIG. Figures 1 and 2; - Figure 4 shows a schematic view of a heating system according to the invention. FIG. 1 shows a heating device according to the invention. This heating device is designated by the general reference 10. This device 10 is in this example a radiant panel. Thus, preferably, the electric heating device 10 is essentially radiative emission. The electric heater for example transfers heat in the form of infrared radiation in a wavelength range substantially between 15 micrometers and 1 millimeter. For example, the heating device 10 has a substantially radiative component, for example representing more than 40% of the total emitted power and preferably more than 50%. For the purposes of the present invention, the effectiveness of the radiant panel means the thermal power directly useful for heating and transmitted solely by the radiation of the emitting face of the heating body towards the zone to be heated. Efficiency is also defined as the ratio of the power radiated by the emitting face of the heating body to the zone to be heated. The various elements constituting the heating device 10 are shown in detail in FIG. 2. The heating device 10 comprises a heating body 12 configured to be powered electrically by a power supply source (not shown). This heating body 12 is illustrated in detail in FIGS. 3A and 3B. The heating body 12 operates according to the principle of Joule effect. The heating body 12 thus forms an electrical resistance in which the electricity that passes through it turns into heat by Joule effect. In this case, the radiated infrared energy is in first approximation proportional to the fourth power of the Kelvin temperature, according to the law of Stephan and Boltzmann. It follows that the electrical resistance must be raised to high temperature, for example at least equal to 100 ° C for domestic use. The French electrical standard regulating this temperature characteristic is the standard NF EN 60335-2-30. The heating body 12 is configured to be connected to a power source (not shown), for example by means of electrical conductors 30. The heating element 12 comprises an electrically conductive layer 14 with low emissivity, for example less than 0 , 2 and a high emissivity support layer 16 on which the layer 14 is deposited. As an indication, the thickness of the resistive or electrically conductive layer is between 200 and 2000 angstroms. This resistive layer 14 called low emissivity is for example configured so that the power flux released by the heating body 12 is between 300 VV / m2 and 1500 VV / m2. Furthermore, the electrically conductive layer 14 is preferably formed by a thin layer of one or more electrically conductive materials. This thin layer deposition makes it possible in particular to obtain the emission of a very homogeneous radiation flux. For example, the electroconductive layer 14 is made of a material consisting essentially of pure chromium and chromium oxide, the proportion of chromium oxide being chosen so as to give the said electroconductive layer the appropriate resistivity. In a variant, the electroconductive layer may be formed by an alloy essentially based on nickel and chromium. Preferably, the electrically conductive layer 12 is formed by vacuum deposition, for example by means of a magnetron, according to a vacuum metallization process. In a variant not shown in the figures, the electroconductive layer may comprise a film made of a plastic material incorporating an electrically conductive wire. This film is for example glued directly to the rear face of the support layer. [0009] Preferably, the electrically conductive layer 14 is a reflective layer. This provides a mirror which provides a particularly aesthetic appearance particularly appreciated for home use. The electric heating device 10 also comprises a receptacle 18. The receptacle 18 comprises in this example a front wall 20 and a rear wall 22 disposed at a distance and facing the front wall 20. The receptacle 18 preferably forms a sealed enclosure in the air. [0010] This has the advantage of limiting convective heat transfer. Thus, in this example, the receptacle 18 comprises a peripheral frame 24 made of aluminum. In a variant not shown in the figures, the receptacle may form a partially open enclosure. Furthermore, in the example described, the front wall 20 comprises an outer face 20A and an inner face 20B facing the inside of the receptacle 18. The electroconductive layer 14 is preferably arranged on the inner face 20B. According to the invention, the front wall 20 is formed by the high emissivity support layer 16 on which is deposited the electrically conductive layer 14 low emissivity. Such an arrangement has the advantage that most of the infrared radiation is emitted to the room and a small portion towards the wall, because of the low emissivity (for example at most 0.2 and preferably 0.15) of the conductive layer 14 and the high emissivity of the support layer 16 (greater than 0.9). For example, the support layer 16 is made of a material with little electrical conductivity or even electrically insulating. The material includes, for example, glass or ceramics. Preferably, the glass plate 16 forming the support layer is constituted by a thermally resistant glass and sufficiently insulating at the operating temperature of the heating body. For example, borosilicate-based glasses or vitro-ceramics are suitable for this application. Preferably, the glass plate is quenched to improve its resistance to thermal shock. [0011] According to the invention, the electric heating device 10 comprises a storage tank 26 of energy accumulation. This reservoir 26 comprises at least one phase-change material. The phase change material has a predefined transition temperature from a first phase to a second phase, for example from a solid phase to a liquid phase. In particular, the reservoir 26 is configured to adopt a discharged state and a charged state respectively corresponding to the first phase and the second phase of the material by thermal coupling with the heating body 12. [0012] Within the meaning of the invention, it can be considered that the reservoir 26 is in a charged state when the latent heat material is fully in its second phase, for example liquid. It will be considered that the reservoir 26 is in an unloaded state, when the material is in its first phase, for example solid. It will also be possible to define charged state and discharged state temperatures, different from the phase transition temperature. For example, it can be considered that the discharged state corresponds to a state in which the reservoir is at ambient temperature, for example that of the room in which the radiator is located. The reservoir 26 preferably comprises a plurality of capsules containing the phase change material (s). These capsules have for example a general shape of ball. In the example described, the reservoir 26 has a general shape of plate defined in particular by two front and rear faces and the reservoir 26 forms a closed chamber for containing the plurality of capsules. [0013] Alternatively, the reservoir 26 may comprise a matrix structure incorporating a plurality of capsules containing the phase change material (s). The structure of the reservoir can be made for example in a thermally conductive resin or in a material such as graphite. [0014] In particular, according to the invention, the phase-change material has a transition temperature from a first phase to a second phase such that the thermal coupling of the reservoir 26 with the heating element 12 can allow the passage of the material of the first phase to the second phase. [0015] The phase change material has a phase transition temperature of, for example, 60 ° C to 80 ° C, preferably greater than 75 ° C. More specifically, and as illustrated in FIG. 2, the heating body 12 is arranged in the receptacle 18 to generate an outward main radiation and a secondary radiation towards the reservoir 26. The heat flows are schematically represented in Figure 4 by arrows and have the references P for main flow and M for minority flow. Thus, preferably, the front wall 20, the rear wall 22, the reservoir 26 are joined together by a closed frame made for example of aluminum. Furthermore, the heating device 10 further comprises a thermally insulating element 28 for limiting the energy flow from the reservoir 26 to the rear wall 22. For example, the insulating element 28 is a thin multilayer reflective insulator essentially composed of a reflective films and associated separators (eg wadding, foams). These reflective films have the particular function of reflecting heat radiation. FIG. 4 shows an electric heating system according to the invention. This heating system is designated by the general reference 100. This system 100 incorporates the heating device 10 according to the invention. More particularly, the system 100 comprises means 102 for controlling the supply of the heating body 12 as a function of a state of charge of the reservoir 26. Preferably, these control means 110 are configured to control the supply of the body of the heater 12 to generate a plurality of charge-discharge cycles of the reservoir 26. This optimizes the power consumption of the electric heating system 100 by taking advantage of the thermal energy accumulated in the reservoir 26 at each charge cycle . Preferably, the control means 110 are configured to deactivate the supply of the heating body 12 when the tank 26 is loaded and to activate the supply of the heating body 12 when the tank 26 is unloaded or at least partially discharged. In addition, in this example, the system 100 comprises means 120 for determining the state of charge of the reservoir 26 by measuring a first temperature and a second temperature respectively at two points of the accumulation reservoir of energy 26, the points being chosen so that the difference between these two temperatures is related to a state of charge of the reservoir 26. For example, the determination means 120 comprise two temperature probes respectively positioned on a front face 26A and a rear face 26B of the tank 26. These two probes indicate a temperature difference which is transformed by a calculation of the load indication of the reservoir 26. Alternatively, the state of the charge can be determined as a function of the flow of a predetermined duration. This duration is determined beforehand and corresponds for example to a charging or discharging time of the reservoir 26. [0016] The main aspects of operation of the electric heating system according to the invention will now be described. At first, it will be considered that the room temperature is 14 ° C and the electric heating system 100 is off. [0017] In this initial state, the reservoir 26 is in an unloaded state, for example in the solid state. Its temperature is that of the room. In a first step, the electric heating system 100 is activated. The heating body 12 is thus electrically powered and its temperature increases for example until reaching 100 ° C. [0018] A charge cycle starts. Indeed, because of the thermal coupling of the heating body 12 with the reservoir 26, the latter also sees its temperature increase until reaching its phase transition temperature. The material of the reservoir 26 will then absorb heat energy in latent form, without its temperature increasing (the liquefaction is endothermic and absorbs energy). When the material of the reservoir 26 becomes liquid, the reservoir 26 is in a loaded state. The means 120 for determining the state of charge of the reservoir 26 then deliver to the control means 110 the indication that the reservoir 26 is loaded. The means 110 then drive the system 100 to deactivate the heating body 12. A discharge cycle starts. The temperature of the heating body 12 goes down and that of the tank 26 also. Since the reservoir 26 is no longer subjected to a nearby heat source, the temperature of the reservoir 26 decreases and the material balls change abruptly by releasing a relatively large amount of energy corresponding to the latent heat. The phase change material will solidify again. [0019] This transformation is exothermic which means that it rejects energy. The reservoir radiates heat essentially to the heating body 12 thanks in particular to the reflective element and thermally insulating 28. The device 100 then radiates the energy supplied by the reservoir 26 to the outside. [0020] When the temperature of the reservoir 26 drops below 40 ° C., for example 25 ° C., the state of charge determination means 120 give the control means 110 the indication that the reservoir 26 is in a state discharge. Therefore, the control means 110 control the activation of the supply of the heating body 12. A new charging cycle starts. Of course, other embodiments are possible without departing from the scope of the invention. Thus, various modifications may be made by those skilled in the art to the invention which has just been described by way of example.
权利要求:
Claims (16) [0001] REVENDICATIONS1. Electric heating device (10), in particular adapted for heating for domestic use, of the type comprising: - a heating body (12) configured to be connected to a power source, - an accumulation tank (26) of energy coupled thermally with the heating body (12), and - a receptacle (18) within which the heating body (12) and the reservoir (26) extend, characterized in that the reservoir ( 26) comprising at least one phase change material with a predefined transition temperature from a first phase to a second phase, the reservoir (26) is configured to assume a discharged state and a charged state corresponding respectively to the first phase and in the second phase of the material by thermal coupling with the heating body (12) and in that the heating body (12) comprises a high emissivity support layer (16) and a low emitting electroconductive layer (14) sivity deposited on the support layer (16), the heating body (12) being arranged in the receptacle (18) to generate a heat transfer substantially outward and a secondary heat transfer to the reservoir (26). [0002] 2. Device (10) according to the preceding claim, wherein the reservoir (26) comprises a plurality of capsules each containing at least said phase change material. [0003] 3. Device (10) according to any one of the preceding claims, wherein the distance separating the heating body (12) and the reservoir (26) is non-zero. [0004] 4. Device (10) according to any one of the preceding claims, comprising a radiative component representing more than 40% of the total emitted power, preferably more than 50%. [0005] 5. Device (10) according to any one of the preceding claims, wherein the electroconductive layer (14) is a thin layer produced by a vacuum metallization process. [0006] 6. Device (10) according to any one of claims 1 to 4, wherein the electroconductive layer (14) comprises a film made of a plastic material incorporating an electrically conductive wire. [0007] The device (10) according to any one of the preceding claims, wherein the phase change material has a transition temperature greater than or equal to 75 ° C. [0008] 8. Device (10) according to any one of the preceding claims, wherein the heating body (12) forms a front wall (20) of the receptacle (18). [0009] 9. Device (10) according to the preceding claim, wherein the receptacle (18) comprises a rear wall (22) arranged opposite and at a distance from the front wall (20), the reservoir (18) extending between the two walls. [0010] 10. Device (10) according to the preceding claim, comprising a thermally insulating member (28) configured in the receptacle (26) so as to limit the emission of an energy flow towards the rear wall (22). [0011] 11. Device (10) according to any one of the preceding claims, wherein the electrically conductive layer (14) is a reflective layer of light. [0012] 12. Device (10) according to any one of the preceding claims, wherein the support layer (16) has an emissivity of at least 0.9 and the electroconductive layer (14) has an emissivity of at most 0 2. [0013] 13. System (100) for electric heating comprising a device (10) according to any one of the preceding claims, characterized in that it comprises means (110) for controlling the supply of the heater (12) in according to a state of charge of the tank (26). [0014] 14. System (100) according to the preceding claim, wherein the control means (110) are configured to control the supply of the heating body (12) so as to generate a plurality of charge-discharge cycles of the tank (26). ). [0015] The system (100) of claim 13 or 14, wherein the control means (110) is configured to turn off the supply of the heater (12) when the reservoir (26) is charged and to activate the power supply of the heating body (12) when the tank (26) is unloaded. [0016] 16. System (100) according to the preceding claim, comprising means (110) for determining the state of charge by measuring a first temperature and a second temperature respectively at two points of the accumulation tank of energy (26), the points being chosen so that the difference between these two temperatures is related to a state of charge of the tank (26), or by a measurement of a predetermined duration corresponding to a duration of charge or discharge .
类似技术:
公开号 | 公开日 | 专利标题 EP3009761B1|2018-04-04|Electric heating device and system FR3024215B1|2019-06-07|SEASONAL THERMOELECTRIC STORAGE DEVICE AND HEATING APPARATUS EMPLOYING SUCH A DEVICE FR2878023A1|2006-05-19|METHOD AND DEVICE FOR PROVIDING HOT WATER EP3017498A1|2016-05-11|Electric vehicle battery thermal management device FR3015780A3|2015-06-26|SYSTEM FOR HOLDING A BATTERY TEMPERATURE. EP3337963A1|2018-06-27|Cooling circuit and method on a vehicle WO1996027271A1|1996-09-06|Electric heating element of the convection or convection-radiation type WO2007088308A1|2007-08-09|Radiant panel comprising a radiating glass substrate WO2018167382A1|2018-09-20|Heat exchanger and thermal regulation device for at least one electrical energy storage element EP2048912A1|2009-04-15|Electric oven with radiating glass plates FR2948253A1|2011-01-21|INDUCTION HEATING DEVICE FR2882132A1|2006-08-18|Electric heating radiator, has heating units contained with coolant liquid that is heated by resistance connected to thermostatic switch and sector with rectifier, and thermocouple triggering supply of resistance connected to battery EP0033278A2|1981-08-05|Heating elements and thermostats for aquariums EP2692006B1|2017-08-16|Fuel-cell stack comprising a stack of cells and bipolar conductive plates EP3545726B1|2020-08-12|Electric radiator heating device having at least one radiant heater including two screened elements with resistive bodies operating under alternating current and direct current EP3008397B1|2020-09-02|Heating device comprising a phase change material EP3633304B1|2020-12-09|Standalone regulated thermo-box EP2036101A2|2009-03-18|Method of producing electrical connections for an electrical energy storage unit EP2299185A2|2011-03-23|Accumulation and/or inertia electric radiator FR2730118A3|1996-08-02|Electric storage heating radiator for room heating FR3113719A1|2022-03-04|Instantaneous electric water heater comprising a front face capable of capturing and emitting waste heat lost by the heating tank and installation BE1026401B1|2020-01-30|DEVICE FOR REGULATING THE TEMPERATURE IN A SPEAKER EP3214398B1|2018-11-14|Energy storage device by phase change material including an electrical load integrated in the fluid circuit FR2999279A1|2014-06-13|Portable or wall mounted dry electric radiator for heating environment, has heat generator formed as electric storage heater, which comprises storage unit for containing coolant, and resistor that is immersed in coolant for heating coolant FR3035199A1|2016-10-21|RADIANT HEATING APPARATUS COMPRISING A THERMALLY INERTIATED HEATING ELEMENT
同族专利:
公开号 | 公开日 FR3026471B1|2019-07-26| EP3009761B1|2018-04-04| EP3009761A1|2016-04-20|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题 EP1729070A1|2005-05-31|2006-12-06|Moletherm Holding AG|Wall constuction of an inner wall and heating module| WO2011007009A2|2009-07-17|2011-01-20|Gmeiner Emma|Solar heating system, air-conditioning system and accumulator heating plate therefor|EP3587834A1|2018-06-29|2020-01-01|Verelec|Anti-asbestos system for attaching an item to a wall, electrical heating device and method for mounting|FR2760073B1|1997-02-25|1999-04-16|Electricite De France|ELECTRIC RADIATOR WITH ACCUMULATION OR INERTIA AND RADIATION|CN108122486B|2017-12-31|2019-12-06|郑州航空工业管理学院|Anti-dewing method for transparent display| FR3097942A1|2019-06-27|2021-01-01|Verelec|Radiant heater for pig breeding| FR3097720A1|2019-06-27|2021-01-01|Verelec|Radiant heating device for poultry farming| FR3097718A1|2019-06-27|2021-01-01|Verelec|Radiant heating device for plant plants| FR3097941A1|2019-06-27|2021-01-01|Verelec|Radiant heater for equines and heating system.|
法律状态:
2015-09-30| PLFP| Fee payment|Year of fee payment: 2 | 2016-04-01| PLSC| Search report ready|Effective date: 20160401 | 2016-09-21| PLFP| Fee payment|Year of fee payment: 3 | 2017-09-28| PLFP| Fee payment|Year of fee payment: 4 | 2018-09-24| PLFP| Fee payment|Year of fee payment: 5 | 2020-03-27| PLFP| Fee payment|Year of fee payment: 6 | 2020-08-14| PLFP| Fee payment|Year of fee payment: 7 | 2020-10-02| CJ| Change in legal form|Effective date: 20200825 | 2021-09-30| PLFP| Fee payment|Year of fee payment: 8 |
优先权:
[返回顶部]
申请号 | 申请日 | 专利标题 FR1459270A|FR3026471B1|2014-09-30|2014-09-30|ELECTRICAL RADIATOR WITH PHASE CHANGE| FR1459270|2014-09-30|FR1459270A| FR3026471B1|2014-09-30|2014-09-30|ELECTRICAL RADIATOR WITH PHASE CHANGE| EP15187233.0A| EP3009761B1|2014-09-30|2015-09-28|Electric heating device and system| 相关专利
Sulfonates, polymers, resist compositions and patterning process
Washing machine
Washing machine
Device for fixture finishing and tension adjusting of membrane
Structure for Equipping Band in a Plane Cathode Ray Tube
Process for preparation of 7 alpha-carboxyl 9, 11-epoxy steroids and intermediates useful therein an
国家/地区
|