ACQUISITION DEVICE, METHOD FOR MANUFACTURING THE SAME, FORCE MEASURING METHOD

专利摘要:
Acquisition device (20) having a wall and a transducer (23) constituted by a body (24,324) to which electrodes (25) are attached at a distance from one another. An electrical impedance (R) of the transducer is variable depending on the deformations thereof. In a view in a direction perpendicular to a surface (36) of the wall, at least two electrodes (25) of said plurality of electrodes are separated from each other. The transducer is integrated below the surface (36) of the wall.
公开号:FR3019291A1
申请号:FR1452842
申请日:2014-03-31
公开日:2015-10-02
发明作者:Berengere Lebental；Boutheina Ghaddab；Vincent Gaudefroy；Eduardo Ruiz-Hitzky；Gallego Pilar Aranda；Gracia Cristina Ruis；Birger Hennings
申请人:Consejo Superior de Investigaciones Cientificas CSIC；Ecole Polytechnique；Institut Francais des Sciences et Technologirs des Transports de lAmenagement et des Reseaux；
IPC主号:

专利说明:

[0001] A first aspect of the invention relates to a transducer for detecting and / or measuring force when integrated in a force sensor; a transducer in which the applied force is not measured directly, but is measured by means of a deformation measurement: under the effect of a force, the transducer undergoes a deformation; this deformation induces a variation of a measurable magnitude of the transducer; a measuring portion of the sensor detects and / or quantifies this variation, and provides an output signal representative of the deformation and as a result of the applied force. Naturally, such a transducer can also be used for detecting or measuring deformations. A first application of such transducers and sensors is the weighing of vehicles on a roadway, at a standstill or preferably in motion.
[0002] When a vehicle is on a roadway, at a standstill or in motion, the roadway deforms locally under its tires. This deformation, which is a function inter alia of the weight of the vehicle, can be detected and / or measured by a sensor or a network of sensors. This or these deformation information can then be interpreted in order to detect the presence and to determine the number of wheels of the vehicles present or circulating on the roadway, their speed and / or their direction of displacement, or their weight. A second application is the monitoring of the state of the roadway, for example the monitoring of irreversible deformations of the roadway and / or the detection of cracks and / or the anticipation of cracks, for example by analyzing the drift of the measurements of the sensors are obtained in the absence of vehicle or aggregated following the passage of several vehicles. Background of the First Aspect of the Invention Numerous deformation or force sensors have been developed for vehicle weighing applications on a roadway, at a standstill or in motion, and for monitoring the condition of the vehicle. floor. In some of these sensors, the transducer is formed by a body on which electrodes are attached, and which is formed of a material such that when a pair of electrodes are attached to this material, the resistance between electrodes varies as a function of the deformation experienced by the material (i.e., a piezoresistive material).
[0003] The specificity of these sensors is that the electrodes are then fixed on either side of said body, on body faces which are normal, that is to say perpendicular, to the direction of application of the force to be measured. . When this force is applied to the transducer, the body deforms in this direction; as a result, the resistance measured between the electrodes on the faces normal to the applied force varies; this variation of resistance is detected and / or measured by the sensor so as to provide the information sought. Such transducers are produced, for example, in the form of "smart concretes" or "smart bituminous mixes", that is to say concretes or mixes loaded with nanoparticles and exhibiting a piezoresistive behavior. They can also be made using piezoresistive polymers. There are also transducers made in the form of piezoelectric tapes, in particular based on polymer, ceramics and piezoelectric crystalline materials. However, these different transducers are not fully satisfactory because each of them poses at least some of the following problems: - the length of time necessary for the introduction of the transducers and therefore the time of unavailability of the roadway; the unreliability of these transducers in the medium and long term, due to the incompatibilities between the materials of the transducers and filler materials with the pavement material, the transducers being subjected to very large and repeated stresses; - the deterioration of the pavement caused by the implementation of the transducers, which have a significant height, which reduces the life of the roadway in the vicinity of the sensors; - the low precision of the transducers, which is affected by the speed and trajectory of the vehicles, the variations of temperature and humidity; - The important cost finally, due to both the price of transducers, and their cost of implementation in the pavement. OBJECT AND SUMMARY OF THE PREFERRED EMBODIMENT OF THE INVENTION A first object of the invention is to propose a transducer and consequently a deformation or force sensor, making it possible to eliminate or reduce all or some of the disadvantages mentioned above.
[0004] This first objective is achieved by means of an acquisition device comprising a wall and a transducer, in which device the transducer consists of a body and a plurality of electrodes fixed to said body at a distance from one another; the transducer is such that an electrical impedance determined from said plurality of electrodes is variable as a function of the deformations experienced by the transducer; in a view in a direction perpendicular to a surface of the wall, at least two electrodes of said plurality of electrodes are separated from each other; and the transducer is integrated below the surface of the wall.
[0005] By "wall" is meant a body (or a set of bodies) delimited by a free surface, that is to say a surface on one side of which is a fluid, including the atmosphere. A wall may optionally be flexible as in the case of a textile. A wall is not necessarily flat. The fact that the transducer is integrated below the surface of the wall means, on the one hand, that in a view in the direction perpendicular to the wall surface, the wall surrounds the transducer, and on the other hand that the transducer is placed on the side of the wall with respect to the surface of the wall (The transducer may, however, possibly be itself delimited by the surface of the wall).
[0006] The only impedance cited in this document is electrical impedance; it is subsequently called simply "impedance". An impedance determined from a plurality of electrodes is a magnitude dependent on at least one ratio between a voltage and an intensity; for each of said at least one ratio, the voltage is measured between a first pair of electrodes of said plurality of electrodes and the intensity is applied to a second pair of electrodes of said plurality of electrodes. The first and second pair of electrodes may be the same or different. Most often, the impedance is classically equal to the ratio between the voltage and the intensity for a single pair of electrodes. Impedance can also refer to the "average resistance", which is equal to the average slope (determined for example by linear regression) of the curve (right) indicating the current as a function of the voltage (or the voltage as a function of the current).
[0007] In the acquisition device defined above, the surface of the wall includes the surface provided to receive the force to be detected or measured. When this force is applied to the surface of the wall, this causes deformation of the transducer. This deformation causes a variation of electrical impedance between the electrodes that is measurable. The measurement of the deformation of the transducer (via the measurement of the impedance variation between electrodes) thus makes it possible to measure the force applied to the wall.
[0008] An acquisition device may comprise several transducers of the type defined above. Unlike the transducers used previously, in the acquisition device according to the invention the electrodes of the transducer are not aligned in the direction of application of the force, but on the contrary, in a view along a direction perpendicular to the surface of the wall, at least one pair of electrodes are separated: that is to say that according to this view, these two electrodes have no overlap and appear disjoint. This arrangement advantageously allows that at least these electrodes are possibly arranged at the same level in the direction perpendicular to the surface, which allows to have a more compact acquisition device, possibly even extremely compact, in this direction. The acquisition device can therefore, for example, be included in the surface of a roadway in a very little intrusive manner. In what follows, the term "thickness" for the acquisition device, the dimension thereof in the direction perpendicular to the surface of the wall, and this direction is called "perpendicular direction". In general, the body of a transducer according to the invention is thin. It is not necessary that the transducer is disposed at the surface of the wall: it may be located at a distance from this surface. As a result, in one embodiment of the invention the acquisition device may further comprise a transfer layer separating the transducer from the surface of the wall. By deforming, this transfer layer causes a corresponding deformation of the transducer which is representative of the force applied to the surface of the wall. Preferably, the transfer layer adheres to the face of the transducer located on the surface side, namely the upper face if the transducer is disposed horizontally. The transfer layer preferably has a thickness greater than three times the size of the transducer body in the perpendicular direction. The transfer layer may optionally be laminated and itself be formed of at least two sublayers.
[0009] The transfer layer may be arranged in particular so as to deform in particular in a transverse plane perpendicular to the direction of application of the force. The transfer layer in this case converts the applied force into a 'transverse' deformation of the transducer occurring in this transverse plane; and it is this transverse deformation that creates a measurable impedance variation between electrodes. The transfer layer may also be arranged such that the applied force induces deformation of the transducer in the perpendicular direction, and the transducer may be provided such that such deformation is sufficient to create a measurable impedance variation between electrodes. The transfer layer may also be arranged to combine the two effects. The transfer layer and the wall may be formed of the same material, in particular bituminous mixes. It is understood that in the preceding sentence, the term 'wall' designates the part of the wall surrounding the transducer (in a view along the perpendicular direction). The transfer layer and the wall may in particular be integrally formed. The fact that the transfer layer and the wall are integrally formed means that the transfer layer is then formed continuously with the material of the wall portion surrounding the transducer. Alternatively, the transfer layer is a material added after the formation of the wall, in the case where the transducer is placed in a hole in a wall.
[0010] The acquisition device defined above can be used to produce a sensor, in particular a sensor for detecting or measuring the deformation of the transducer, and / or the force applied to the wall. The sensor may also be provided to indicate changes in the force applied to the wall surface (rather than the force itself), which are then generally determined as a function of transducer impedance variations. The sensor then comprises at least one acquisition device as defined above, and an impedance determination system, connected to electrodes of at least one transducer of said at least one acquisition device, and able to determine a impedance and / or an impedance variation of said at least one transducer. The sensor may comprise in particular a set of transducers arranged in a network, as well as means for identifying which transducers are activated or stressed at a given instant. A sensor including such a transducer array can be used to measure the speed and / or direction of travel of a vehicle. The transducers may in particular be arranged in rows and columns, that is to say in a matrix arrangement. In one embodiment, the sensor may comprise two (or more) transducers, placed one above the other in the thickness direction of the sensor. In this case, in view perpendicular to the surface of the wall of the acquisition device, the respective electrodes of the different transducers may in particular have different orientations; and for example forming in this view an angle of 90 °. The impedance determination system may be a resistance determination system, consisting mainly of an ohmmeter that detects and / or quantifies the resistance and / or resistance variation between the electrodes. In another embodiment, the impedance determination system evaluates the complex impedance between the electrodes, possibly as a function of the frequency or with a predefined frequency, to deduce, for example, the capacitance and the relative permittivity of the material between the electrodes. . The sensor may further comprise a correlation system for determining the deformation of the transducer (s), and / or the force (s) applied to the wall, based on the impedance of the one or more transducers and / or variations thereof.
[0011] On the basis of the information provided by the impedance determination system, the correlation system generates an analog or digital output signal correlated quantitatively or qualitatively with the deformation of the transducer (s) or the force (s) applied to the wall surface. . The correlation between the impedance or the impedance variations between the electrodes and the output signal (considered representative of the deformation or the applied force) is established by means of a preliminary calibration step and / or by a physical model (electromechanical) of the acquisition device. The sensor can also be a sensor of the state of deformations of the roadway or of the material that receives the sensor, in particular the irreversible deformations of a roadway, and a system for the early detection of cracks. The sensor may comprise for example at least one acquisition device as defined above, and an ohmmeter connected to the electrodes of the transducer (s), or a matrix of transducers as defined above. The sensor works, for example, by analyzing the drift of the measurements of the transducer (s), that is those obtained in the absence of vehicles or those aggregated following the passage of several vehicles. The sensor may also be a sensor for speed and orientation of a moving object on a material, comprising at least one acquisition device as defined above, and an ohmmeter connected to the electrodes of the transducer (s), or preferably a matrix of transducers as defined above. The acquisition device or the sensor according to the invention can be used both for the detection of a localized force (point support) and for the detection of a distributed force.
[0012] As has been indicated, in general the transducer is thin. The body of the transducer is therefore generally in the form of a layer or even one (or more) wire (s) or strip (s) connecting the electrodes. The body of the transducer may for example form a thin layer, that is to say of thickness less than 1 / 10th of at least one of the two other characteristic dimensions of the body of the transducer. The thickness of this layer may in particular be less than 1 mm, and preferably 0.5 mm or even 0.1 mm. The electrodes are generally arranged to be at the same level with respect to the transducer body, in the direction perpendicular to the surface. For example, the electrodes may be placed on the surface-facing side and the surface-opposite side of the transducer body, or at the same intermediate level thereof. These faces are the upper and lower faces of the body of the transducer, when the device is arranged 'horizontally', that is to say so that the surface of its wall is horizontal (which is a possibility among others , for the implementation of the acquisition device according to the invention). Conventionally, in the following, an element will be referred to as "superior", if it is situated on the side of the surface of the wall relative to the body of the transducer, and below an element situated on the opposite side.
[0013] As indicated above, a significant application of the sensor according to the invention is the weighing of vehicles or for measuring the deformations of a roadway.
[0014] The acquisition device is then implanted under the surface of the roadway. Its small thickness allows it to be implanted in a little intrusive way. Moreover, as will be developed further, it can be made with materials compatible with bituminous mixes.
[0015] Consequently, despite the multiple stresses (climatic, mechanical, ..) to which an acquisition device implanted in a roadway is subjected, advantageously the acquisition device according to the invention can have a long service life. The acquisition device or a sensor incorporating such a device can naturally be used to detect the presence and weight of objects (or persons, animals, etc.) on a surface, or else any forces likely to be present. applied on a surface. To increase the lifetime and accuracy of the transducer, it may further comprise a bonding layer interposed between the transducer body and a surface adjacent to the transducer body, the bonding layer adhering to the transducer body and to said transducer body. neighboring surface. This neighboring surface may in particular be a surface of the transfer layer mentioned above. The bonding layer is then an upper bonding layer, which provides a tight bond between the transfer layer and the transducer body. This neighboring surface may also be a support surface supporting the transducer on the lower side; the bonding layer is then a lower bonding layer, disposed between the piezoresistive body and the support surface. The transducer may have both lower and upper link layers. In one embodiment, the transducer further comprises a second pair of electrodes separated from each other in a second direction perpendicular to the transverse direction (The transverse direction being the direction in which the electrodes of the pair are spaced apart). of electrodes cited above, said first pair of electrodes). The second pair of electrodes makes it possible to carry out a complementary measurement and thus to better know the impedance variations of the piezoresistive body, and by extension, its state of deformations. In one embodiment, the transducer has a plurality of pairs of electrodes forming the parallel sides in pairs of a polygon. The non-parallel sides of the polygon may have different lengths. The pairs of electrodes make it possible to better know the resistance of the transducer because of the direction and the geometry chosen for the electrodes, and by extension, to better know the state of deformation of the body of the transducer.
[0016] The electrodes may benefit from all or part of the following improvements: the pair of electrodes may consist of interdigital electrodes (that is, forming two nested combs) to decrease the resistance of the transducer and increase its sensitivity; the part of the electrodes in contact with the piezoresistive body may be substantially flat. - The part of the electrodes in contact with the piezoresistive body may be composed of a thin wire or a network of thin son forming a comb or a grid, regular or non-regular. the electrodes may be rigid, and may for example be made of a material whose flexural modulus is significantly greater (at least twice as much) than that of the piezoresistive body. This arrangement makes it possible to increase the sensitivity of the transducer to deformations perpendicular to the surface of the wall. the electrodes may be flexible, and for example be made of a material whose flexural modulus is comparable to or less than that of the piezoresistive body. This arrangement makes it possible to increase the robustness of the transducer. Different materials can be used to make the piezoresistive body.
[0017] To allow the measurement of a force applied to the surface of the wall, it is necessary that the impedance of the piezoresistive body (that is to say generally its electrical resistance) between the electrodes, and thus in the transverse direction, varies. - preferably strongly - depending on the applied force. To produce the transducer, it is possible in particular to use a body and electrodes having one and / or the other of the following characteristics: e if a force is applied to the acquisition device in a direction perpendicular to the surface of the wall, the transducer deforms mainly or substantially in said direction perpendicular to the wall, and an impedance measured between the electrodes of said plurality of electrodes varies. Optionally, this impedance variation occurs even in the absence of deformation of the material in said perpendicular direction. e if a force is applied to the acquisition device in a direction perpendicular to the surface of the wall, the transducer deforms mainly or substantially in a plane substantially parallel to the wall, and an impedance measured between the electrodes of said plurality Electrodes vary. Deformation occurring mainly (or respectively substantially) in one direction means that the displacement of the points of the material occurs in a direction making an angle less than 45 ° (respectively less than 20 °) with respect to said direction. The characteristics indicated above can be obtained by the choice of a piezoresistive material adapted to form the body of the transducer, and / or by a choice of electrodes having a suitable rigidity. An example of transducers with these characteristics will be given later.
[0018] The body of the transducer may have different chemical compositions. In one embodiment, the transducer body comprises a percolating network of micro- and / or nanoparticles. The term "microparticles" or "nanoparticles" is used here to mean particles in which at least one of the characteristic dimensions is less than 100 μm and 100 nm, respectively. These micro- and / or nanoparticles may in particular comprise one or more particles from the following list: a) carbon nanotubes, in particular random or organized lattice, b) micro or nanoparticles self-assembled, c) graphene sheets, graphite or oxide of graphene reduced or not. The percolating network may also comprise clay particles, some of said particles having an outer surface covered at least in part with a conductive substance.
[0019] The transducer body may also comprise a piezoresistive polymer, or a mixture of a plurality of piezoresistive polymers, or a mixture of at least one polymer, for example a bitumen, with conductive micro- and nanoparticles (thereby forming a polymer composite with micro- or nano-particles) or a mixture of cementitious material with micro and nanoparticles (sometimes called 'smart cement' or 'smart concrete'). The invention also relates to a ribbon comprising a plurality of acquisition devices as defined above, fixed on a band. The strip may be formed of a flexible polymer. It may in particular be provided to be packaged in a reel or roll. The tape may act as a transfer layer and / or a layer having a support surface, in order to protect or support the acquisition devices, as previously discussed.
[0020] The invention also relates to a control station, for example a toll barrier, comprising at least one traffic lane equipped with a force sensor as defined above. The invention also relates to a display, for example a touch screen, capable of displaying variable information, comprising at least one acquisition device as defined above. The invention also relates to a force measuring method comprising the following steps: a) providing a transducer consisting of a body and a plurality of electrodes fixed to said body at a distance from each other, the transducer being such that an impedance electrical determined from said plurality of electrodes is variable depending on the deformations experienced by the transducer; b) applying a force to said transducer in a direction such that in a view along this direction at least two electrodes of said plurality of electrodes are separated from each other; and c) the variation of the impedance is measured under the effect of the applied force. d) determining the applied force as a function of said impedance variation. Step d) is performed using prior knowledge regarding the relationship between the deformation of the transducer and the force applied thereto. It is also understood that the force can be applied directly or indirectly to the transducer. For example, the transducer may be placed under a transfer (force transfer) layer, and a force is applied to the transfer layer and a portion of this force is transmitted to the transducer via the transfer layer. A second objective of the invention is to propose a method of manufacturing a transducer integrated into a wall, which makes it possible to integrate in a wall in a simple manner a transducer for detecting and / or measuring deformations and forces, in particular a transducer that can be used in a force sensor for measuring a force applied to a road surface.
[0021] This objective is achieved by a method of manufacturing an acquisition device comprising a wall and a transducer, the method comprising the following steps: a) positioning a plurality of electrodes in contact with a body, the body and said electrodes being such that an electrical impedance determined from said plurality of electrodes is variable as a function of the deformations experienced by the body associated with said plurality of electrodes; the body and said plurality of electrodes thus forming a transducer; b) the wall is formed; and wherein steps a) and b) are performed such that the transducer is integrated beneath a surface of the wall, and in a view in a direction perpendicular to said surface, at least two of said electrodes are separated from each other. the other. This method can in particular be implemented in the case where the wall is the floor or the wall of a floor. In this method, step b) is preferably performed after step a), that is to say that after making the transducer, it integrates it under the surface of a wall. Step a) may comprise two sub-steps: a1) the electrodes are positioned; a2) the body of the transducer is formed. These two sub-steps can be performed in order a1 and then a2), if the body of the transducer is above the electrodes, or a2) then a1) in the opposite case, or simultaneously, if the electrodes in particular are inside the body of the transducer.
[0022] At the end of step b), the upper surface of the body of the transducer constitutes a wall surface. The method thus makes it possible to obtain an acquisition device comprising a transducer integrated in a wall according to the invention. Step b) of this method may include including depositing a transfer layer on the transducer. Preferably, this transfer layer is designed to adhere to the transducer. The transducer manufacturing method described above can be implemented in the factory; the transducer is then prefabricated. The body of the transducer formed in step a) can then in particular be formed on an upper surface of a ribbon, for example a plastic tape. Alternatively, the transducer may be manufactured and integrated with a wall in situ. The method can then in particular be used to produce integrated transducers in the ground. Step b) indicated above of formation of the wall may then consist in depositing a surface layer on the ground on the transducer. This superficial layer may for example be a bituminous mix layer (mixture of aggregates bound by a bituminous compound).
[0023] In this case, the method integrates with the pavement manufacturing process by making it possible to integrate one or more acquisitions with the roadway. As a result, the invention also relates to a pavement manufacturing method comprising the following steps: A) A support surface is prepared; B) on said support surface, depositing at least one layer of bituminous mix by incorporating at least one transducer, so that the pavement comprises an acquisition device formed by a method as defined above. The bituminous mix layer may also, in the context of the invention, consist of any other material capable of producing a roadway, for example aggregates bound by a hydraulic binder, bituminous, etc. This method therefore makes it possible to produce roadways in which one or more transducers are integrated. The preparation step A) may consist in particular of cleaning or scouring the upper layer of an existing pavement, or of depositing a lower layer of pavement, which is generally a layer of bituminous mix. The layer of bituminous mix deposited in step B) is preferably the upper layer of the roadway, which layer is deposited as part of the realization (or rehabilitation) of the roadway. Such an upper layer of roadway usually extends in the direction of circulation of the roadway over a length of at least 10 meters on either side of the transducer. When the transducer is put in place or made during the manufacture of the roadway, advantageously the installation of the transducer is carried out without prior step of digging a trench in the roadway and burying the transducer in the trench. In one embodiment of the method, step A) comprises the deposition of a lower bituminous mix layer, the upper surface of which constitutes said support surface; and the thicknesses of the lower asphalt layer and said at least one layer of bituminous mix are such that the transducer is located at a depth of between 15% and 50% of the cumulative thickness of said asphalt layers .
[0024] Furthermore, preferably, the thickness of said at least one layer of bituminous mix is a significant fraction (greater than 1 / 10th) of the cumulative thickness of said asphalt pavement layers. Advantageously, this pavement manufacturing method ensures optimum compatibility with the surrounding pavement materials (in particular in terms of conformability, service life, absence of disturbing foreign bodies), which allows the absence of connections or stable connections between the rest of the roadway and the measuring device, for a better durability of the whole.
[0025] The implementation of the method is simple, hence a minimum unavailability of the roadway, with the possibility of making the transducer either in the factory at very low cost or directly on site with simple production steps. Finally, the method can be adapted according to the road tracking problems studied. The characteristic size of the transducer can thus vary from millimeter to meter; its sensitivity can be optimized by a suitable choice of the number of layers of piezoresistive material and electrodes. In addition, the conditioning of the currents passing through the transducers is simple and inexpensive, which makes it easier to use simultaneously a large number of transducers integrated in the same sensor, and for example arranged in a matrix. A second aspect of the invention now relates to a material that can be used to make a transducer.
[0026] The transducer may in particular be a transducer which has a variable electrical variable of electric impedance type, in particular a resistor or a resistivity, this quantity being capable of being detected and / or measured, the transducer being arranged in such a way that this magnitude varies under the effect of a bias, for example a force or deformation, applied to the transducer. BACKGROUND OF THE SECOND ASPECT OF THE INVENTION A known family of materials useful for making transducers of the type defined above are piezoresistive materials. Among the piezoresistive materials, the compositions based on carbon nanotubes are particularly known. The carbon nanotubes can be dispersed within a matrix to form a percolating network and thus confer conductivity properties and in some cases piezoresistivity to the matrix. However, the cost of carbon nanotubes is high. OBJECT AND SUMMARY OF THE SECOND ASPECT OF THE INVENTION An objective of the second aspect of the invention is therefore to propose a low-cost material that can be used to produce a transducer of the type defined above. This object is achieved by a composite material comprising a plurality of clay particles mixed with conductive carbon fiber elements, said particles having an outer surface covered at least in part with a conductive substance. A material or a substance is said conductor (conductive) if its resistivity p in (52.m) at 20 ° C is less than 100 52.m. Preferably, the conductivity of the conductive carbon fiber elements and the conductive substance is less than 0.1 μm, more preferably less than 0.01 μm. Thanks to the conductivity properties of the thus-coated clay particles and the conductive carbon-fiber elements, the material thus defined advantageously has the desired quality of presenting an impedance, and in particular (but not only) a resistance, which varies when a force is applied to the transducer. Advantageously, the qualities of this material are obtained with components of low price: carbon fiber elements, which have a high price per kilogram, but can be used only in very small quantities; and a conductive substance and clay particles, which are or may be very low cost components. In addition, as will be detailed later, the material has the desired properties even when it is formed in a very thin layer. As a result, a small volume of material is sufficient to produce large surface transducers. The following different improvements can be made to the composite material according to the second aspect of the invention, alone or in any combination: the conductive substance may for example be a substance predominantly composed of carbon atoms in SP2 hybridization (Indeed, the carbon-based materials in SP2 hybridization are conductive, unlike carbon-based materials in SP3 configuration.); The conductive substance may preferably be a graphenoid substance, that is to say a substance composed for the most part of graphene or a graphene type material (graphene-like material). is not necessarily formed of a material having a single layer of carbon atoms); - The conductive substance can form on the surface of particles a layer of average thickness less than 10 pm; The carbonaceous fibrous elements may comprise single-walled and / or multi-walled carbon nanotubes, and / or carbon nanofibers; and / or - The clay may be a fibrous clay, i.e. sepiolite and / or palygorskite. In one embodiment, the clay particles covered at least in part by a layer of conductive substance are such that the material constitutes a composition defined by any one of claims 1 to 12 of the international patent application WO2012 / 160,229. The invention also relates to a transducer consisting of a body made of the previously defined material (the material possibly benefiting from all or part of the improvements indicated above), and a plurality of electrodes fixed to said body and arranged at a distance from one another . The electrical impedance between the electrodes varies when the transducer undergoes deformation, for example when a force is applied to it.
[0027] In a preferred embodiment, the body of the transducer forms a layer, and at least one pair of electrodes of said plurality of electrodes are spaced from each other in a transverse direction located substantially in a plane of the layer. . This layer may be less than 1 mm thick, or even 0.1 mm thick.
[0028] The invention also relates to a display capable of displaying variable information, a display surface comprising at least one transducer as defined above, in particular a transducer made in the preferred embodiment cited above. The invention also relates to a method for detecting and / or measuring a force, in which a transducer as defined above, in particular a transducer made in the preferred embodiment mentioned above, is used and detected. and / or measuring a variation of a determined electrical impedance between transducer electrodes that occurs when the force is applied to the transducer. The method can in particular be used in the case where the electrical impedance variation is a variation in resistance or resistivity of the transducer, under the effect of the applied force. The invention also relates to a method for preparing a material comprising the following steps: a) providing conductive carbonaceous fibrous elements; b) mixing said elements with clay particles in a polar liquid medium; c) adding an organic compound capable of being converted into a conductive substance by carbonization; d) a heat treatment of carbonization is applied to the mixture thus obtained.
[0029] In one embodiment, the organic compound added in step c) is a substance that is capable of being converted by carbonization into a substance predominantly composed of carbon atoms in the SP2 configuration, and more particularly a substance capable of being converted into a graphenoid substance.
[0030] The organic compound added in step c) is a precursor component, allowing step d) to form a layer of conductive substance on the surface of the clay particles. By carbonization is meant heating in the absence of oxygen. The polar liquid solvent may in particular be based on water, methanol, ethanol and / or propanol. The organic compound may be in particular a biopolymer, sugar, and / or caramel. The biopolymer may for example be selected from chitosan, alginate, pectin, guar gum cellulose, gelatin, collagen, zein, DNA, or any combination thereof. The heat treatment of carbonization serves to degrade the organic compound, and to condense it on the clay particles so that the surface thereof is covered at least in part with a layer of a conductive substance.
[0031] Advantageously, although the carbonaceous fibrous elements (which may in particular be carbon nanotubes) are incorporated in the clay particles from step b), they are not destroyed and their properties are not affected by step d) heat treatment.
[0032] As a result, the process defined above makes it possible to benefit from the dispersive properties of the clay particles, which make it possible to obtain a homogeneous dispersion of the carbonaceous fibrous elements. In the material obtained, as indicated above, the conductivity and piezoresistivity properties of the carbon nanotubes are advantageously associated with the electrical conductivity properties of the conductive layer formed on the clay particles. In one embodiment of the material preparation process defined above, in step b), the mixing of said elements with the clay particles may in particular be carried out by sonication, that is to say by subjecting these particles to ultrasounds. Advantageously, the transducer and the manufacturing method have a very low cost, thanks to the use of active materials (carbon fiber elements) in very small quantities, and generally only in a thin layer of very small thickness. The invention will be better understood and its advantages will appear better on reading the following detailed description of embodiments shown as non-limiting examples. The description refers to the accompanying drawings, in which: - Figure 1 is a schematic perspective view showing a sensor in a first embodiment of the invention, implanted in a roadway not shown; Figure 2 is a schematic partial perspective view of the sensor shown in Figure 1; - Figure 3 is a schematic sectional view of a roadway in which is integrated the acquisition device shown partially in Figure 2, in the absence of a vehicle; FIG. 4 is the same diagrammatic sectional view of a roadway as in FIG. 3, but represented during the passage of a vehicle; FIG. 5 is a diagram representing the variation curves of distance between electrodes and of resistance, in an acquisition device according to the invention; FIG. 6 is a schematic sectional view of a roadway equipped with an acquisition device according to the invention, comprising two transducers; FIG. 7 is a schematic perspective view of a roadway equipped with an acquisition device according to the invention, comprising three transducers; FIG. 8 is a schematic view illustrating the steps of implementing a pavement manufacturing method according to the invention; FIG. 9 is the same schematic sectional view of the road surface obtained by implementing the method illustrated in FIG. 8; FIG. 10 is a partial schematic view from above of an acquisition device in another embodiment of the invention; FIG. 11 is a partial schematic view from above of an acquisition device in another embodiment of the invention; and FIG. 12 is a diagram showing the resistance curve between pairs of electrodes as a function of the spacing between pairs of electrodes in the device of FIG. 11. Identical or similar elements in different embodiments include the same numerical reference.
[0033] A composite material according to the second aspect of the invention, particularly suitable for producing transducers as defined above, without however being limited to this sole use, will now be presented. This composite material comprises clay particles mixed with carbonaceous fibrous elements; the clay particles have an outer surface covered at least in part with a conductive substance, preferably of the graphenoid type. The term "carbonaceous fibrous elements" refers to single-walled and / or multi-walled carbon nanotubes, as well as carbon fibers.
[0034] The graphenoid substance generally forms a thin layer on the surface of the particles, or at least some particles. The average thickness of this layer may especially be less than 10 μm. The composition of this layer will be detailed below, during the presentation of a method of producing a layer of the composite material.
[0035] Advantageously, the layer of conductive substance on the surface of the particles makes the particles thus coated conductive electricity. This property can be verified for example by using a scanning electron microscope: when a conductive substance is observed with a scanning electron microscope, its surface does not have significant electron accumulation, as can be seen for example on graphene, considered here as a typical example of conductive material.
[0036] The clay may be chosen in particular from fibrous clays, that is to say sepiolite and palygorskite. In a manner known per se, the carbonaceous fibrous elements allow the realization of percolating conductive networks (electricity).
[0037] Advantageously, the material described above makes it possible to benefit from the conductivity and percolation qualities of the carbonaceous fibrous elements, but without the need to use a large quantity of these. Indeed, in the composite material defined above, a large part of the electrical conduction is provided not by the carbon fiber elements, but by the particles, thanks to the fact that they are covered at least in part with conductive substance. It is therefore possible to use a small amount of carbonaceous fibrous elements because, as these are scattered among clay particles, they constitute only a small proportion of the material.
[0038] In addition, advantageously the composite material defined above can be used in a thin layer (for example a few tens of microns thick), which obviously limits the amount of carbon fiber elements used.
[0039] The embodiment of a body composed of the composite material as defined above can be done for example via the following two steps: the manufacture of the composite material, which is obtained in powder form; then - the deposition of this material on a surface and the actual manufacture of the body of composite material on this surface. Manufacture of the composite material The composite material may be produced by the following steps: a) carbon nanotubes (and / or linear carbon fibers) are provided; b) dispersing said carbon nanotubes (and / or linear carbon fibers) among clay particles by means of a polar liquid solvent; c) adding an organic compound capable of being converted into a conductive substance by carbonization, for example caramel; c2) the solvent is removed; d) the resulting mixture is carbonized so as to convert the organic compound into a conductive substance at least partly covering the outer surface of the clay particles.
[0040] Steps a) and b) can be done for example by a method defined by any one of claims 16 to 20 of international patent application WO2011 / 070208. In addition, step c2) can be done for example according to the process step c) defined by any one of claims 21 to 25 of the international patent application WO2011 / 070208. WO2011 / 070208 provides examples of implementation of processes according to claims 16 to 25. Step d) can be made for example by a process for preparing carbonaceous material as defined by any one of claims 22 41 of International Patent Application WO2012 / 160229; examples of implementation of such a method are given on pages 10 and 11 of this document.
[0041] Example of manufacture of the composite material The following three components are used: clay particles: 2.5 g of sepiolite particles; . fibrous carbon elements: 50 mg of multiwall carbon nanotubes (ie 2% by mass with respect to sepiolite), and. a polar liquid solvent: 43 ml of water. The carbon nanotubes are obtained previously independently by the CVD (chemical vapor deposition) method. The nanotubes are grown so that they have an average diameter of 10 nm and an average length of 1 to 2 μm.
[0042] The material is then prepared as follows: Step b) is divided into three elementary steps b1, b2 and b3: b1) The three components listed above are mixed. b2) The mixture obtained is homogenized. Homogenization is carried out by sonication. Vibracell VCX750 Sonics equipment is used with a 13 mm diameter tip of Ti-AI-V operating at a resonant frequency of 20 kHz. The energy chosen is 4.4 Id (94.3 3 / g). Pulses of 10 seconds separated by pauses are applied. The homogenization by sonication can be alternated with one or more kneading operations of the mixture. b3) The mixture is dried. The mixture is dried at 60-70 ° C overnight. c) an organic compound is added as a precursor, in this case 6.5 g of liquid caramel (Royal TM caramel, 80%), in a ratio of 2: 1 caramel-clay mass. c2) The mixture is again dried at 60-70 ° C overnight. d) The dried mixture thus obtained is cooked: The mixture of sepiolite-carbon nanotubes-caramel obtained after drying is fired at a temperature of 800 ° C. under a stream of nitrogen with a temperature ramp at the beginning of cooking of 5 ° C. C / min. The material is maintained at this temperature for 1 hour to achieve the transformation of the caramel into a conductive substance. The material is then reduced to powder by grinding, so that it can be deposited. Preferably, the particles obtained by grinding have larger ferret diameters, the average value of which is less than 50 μm; and preferably less than 15 μm.
[0043] The powder material thus obtained can then be deposited so as to form a piezoresistive body, making it possible to produce a transducer or a deformation or force sensor. Transducer and Sensor Structure In order to provide the body of a transducer according to the first aspect of the invention, any piezoresistive material (but not only such materials) may be used. In particular, it is possible to use the composite material comprising clay particles mixed with conductive carbon-fiber elements presented previously.
[0044] Preferably, a material that can form a layer, in particular a thin layer, is used. The body of the transducer can form a continuous layer (without holes). It can also form a layer having holes and / or discontinuities, being noted that it is preferable that there is at least one continuous path passing through the body of the transducer and connecting the different electrodes to each other. The material of the transducer body is preferably made of a piezoresistive material selected such that the resistance between two measurement points (where the electrodes are placed) varies greatly when a force is applied to the transducer body in a perpendicular direction to the direction connecting the two measuring points. This material may consist in particular of a percolating network of micro or nanoparticles (particles of which at least one of the characteristic dimensions is less than 100 μm and 100 nm respectively) or of a percolating network consisting of a mixture of different types of micro or nanoparticles. nanoparticles. Particularly suitable particles are: a) carbon nanotubes in random or organized lattice, b) self-assembled micro or nanoparticles, c) graphene, graphite or oxide graphene sheets, reduced or not, d) different combinations of components above, mixed, or e) a piezoresistive polymer or a mixture of different piezoresistive polymers, or f) a mixture of one or more polymers with conductive micro and nanoparticles (nanoparticle polymer composites) or g) a mixture of asphalt or asphalt with micro and nanoparticles (intelligent asphalt). The body of the transducer may in particular be made with the composite material comprising clay particles and fibrous carbon elements presented above. The ability of the material to exhibit a variable resistance in a specific direction (along which the resistance measurement points will be arranged) can be increased by promoting a certain orientation of the micro- or nanoparticles in the piezoresistive body. This can be done for example by dielectrophoresis, for particles having a dipole moment. Thus a transducer using such a material has an increased sensitivity to any force inducing deformations in the specific direction indicated above.
[0045] A force sensor 10 according to a first embodiment of the invention will now be presented in relation with FIGS. 1 to 7. The sensor 10 comprises a set of identical acquisition devices 20 and an ohmmeter 12 constituting a determination device. Impedance. Each device 20 is connected by two electrical wires 14 to the ohmmeter 12. Each device 20 mainly comprises a ribbon 21 having the same structure along its entire length (In FIGS. 1 and 2, in the devices 20, only the ribbons 21 are represented). Each ribbon 21, which moreover constitutes in itself an acquisition device within the meaning of the invention, consists mainly of a middle layer 24 sandwiched between two connecting layers 22 and 26, constituted in the following manner: a lower bonding layer 22 and an identical upper bonding layer 26, constituted by a flexible plastic film, and - a central piezoresistive layer 24 made of piezoresistive material, which constitutes the body of a transducer within the meaning of the invention. Each device 20 is normally set up so as to be arranged flat on a horizontal plane. The three layers then each have a horizontal flat shape.
[0046] In the thickness of each ribbon 21 are further housed two electrodes 25. Each electrode is constituted by a thin flat silver wire interposed between the lower bonding layer 22 and the piezoresistive layer 24. The electrodes 25 are attached to the piezoresistive layer 24 and integral therewith. The layer 24 associated with the electrodes 25 therefore constitutes a transducer 23.
[0047] Indeed, thanks to the piezoresistivity properties of the layer 24, in case of deformation of the transducer 23, the resistance between the electrodes 25 varies. The surface area of the piezoresistive layer 24 generally comprised between the two electrodes and which is involved in the determination of the impedance between the electrodes is called the active surface.
[0048] The extent and shape of the active surface are chosen according to the intended use of the device 20 (local monitoring of the deformations or damage of a roadway, detection or static or dynamic weighing of vehicles ...). This active surface can be very small (for example less than 1 cm 2) or reach several m2.
[0049] The active surface may have any shape, isotropic (for example circular or square) or anisotropic (for example elliptical or rectangular). An example of implementation of an acquisition device 20 in a roadway is illustrated in FIG.
[0050] This figure has a section in a vertical plane of a roadway 30 in which the device 20 is integrated. The roadway 30 consists of a lower layer 32 and an upper layer 34, both formed of bituminous mixes. The layers 32 and 34 rest on a soil not shown. The ribbon 21 is disposed between the two road layers 32 and 34. Each device 20 is constituted by the road portion located in the vicinity of the ribbon 21, and therefore comprises a portion of the layer 32, the ribbon 21, and a portion of the layer 34.
[0051] In FIG. 3, in the transducer 20 the electrodes 25 are disposed below the piezoresistive layer 24. It is also possible to arrange the electrodes 25 above this layer, or even within the piezoresistive layer ( as an example of transducer body).
[0052] The upper layer 34 constitutes a wall having a free upper surface 36. The transducer 23 is integrated under the surface 36. In a view along the direction perpendicular to the surface 36, that is to say in the vertical direction (arrow A 4), the electrodes 25 are separated from each other. They are placed at the same height in the roadway 30, which advantageously allows the device 20 to be thin. The bonding layers 22, 26 may be made of bicomponent silicone elastomer or poly (ethylene-co-tetrafluoroethylene) or ETFE. These materials in fact have a strong adhesion with the bitumen of the lower 32 and upper 34 layers of the roadway. Thanks to this adhesion, during deformations of the roadway 30, the sensor 20 accompanies these deformations without there being delamination or appearance of cracks internal to the roadway at the interfaces between the transducer 23 and the layers 32 and 34 of the floor. The lower bonding layer 22 as the upper bonding layer 26, however, are not in themselves necessary for the operation of a device according to the invention. Moreover, each of these layers may itself consist of one or more sub-layers. For example, it is possible to use a bimaterial bonding layer, that is to say composed of two sub-layers, each being composed of a specific material: the material of the sub-layer brought into contact with the piezoresistive layer 24 may be chosen to adhere closely thereto, and the sub-layer material brought into contact with a roadway material (layer 32 or 34) may be chosen to adhere firmly to that roadway material.
[0053] While Figure 3 shows the road portion 30 at rest, Figure 4 shows the same portion of road when passing a vehicle. A portion of tire 38 of a vehicle is shown. The tire 38 exerts a pressing force on the upper surface 36 of the roadway, in the vertical direction Z. Under the effect of this force, the roadway 30 is deformed: it is compressed (arrow A), and the bituminous mixes of the roadway moves slightly laterally in the lateral direction X, horizontal and parallel to the surface 36 of the roadway (arrows B).
[0054] At rest (FIG. 3), the electrodes 25 are spaced apart from one another in the X direction by a distance OD, which is of the order of a few centimeters. When passing a truck (Fig.4), the roadway deforms. The electrodes 25 following the deformation of the bituminous mixes constituting the roadway and deviate from each other: When passing the vehicle, their distance takes a value D1 strictly greater than the value DO. The piezoresistive material of the layer 24 is chosen so that it has a resistance between the electrodes variable as a function of the distance between the electrodes. This operation is illustrated in FIG. 5. This represents two function curves of the force F (weight of the vehicle) applied to the roadway 30: the first curve shows the increase in the distance D between the electrodes (which goes from OD to D1); and - the second curve shows, for the same increase in force, the decrease in the resistance R between the electrodes 25. As a result, during the passage of the vehicle, the resistance between the electrodes 25 varies. This change in resistance is measured by the ohmmeter 12. Thus, depending on the resistance measured between the electrodes 25, the ohmmeter 12 is able to detect and measure the force applied to the right of the electrodes 25 in the vertical direction. This curve shows that in this embodiment, the transducer 23 deforms under the effect of the weight of the truck (of the applied force) so that the electrodes 25 deviate laterally; and that under the effect of this spacing, the resistance between the electrodes decreases.
[0055] The acquisition devices illustrated in FIGS. 1 to 7 comprise electrodes 25 made of a flexible material, in this case formed of a thin layer of silver. With such electrodes made of flexible material or a material of similar rigidity, the transducer behaves as follows: if a force is applied to the acquisition device in a direction perpendicular to the surface of the wall, the transducer deforms mainly in a plane substantially parallel to the surface of the wall, and an impedance measured between the electrodes of said plurality of electrodes varies.
[0056] Note: The figures are not represented with realistic scales. In the figures, the height (dimension along the Z axis) is expanded to facilitate understanding. In reality, the transducer 20 is of very small thickness. The lower layers 22 and upper 26 each have a thickness of 0.4 mm. The piezoresistive layer 24 has a thickness of 0.01 to 0.05 mm. However, a sensor according to the invention can however operate differently. An entirely different operation can be obtained by choosing rigid electrodes. In fact, if electrodes 25 made of a rigid material, for example copper or a material of similar stiffness, are used, the transducer behaves as follows: if a force is applied to the acquisition device 20 following the vertical direction perpendicular to the surface 36, the transducer and in particular the body of the transducer (piezoresistive layer 24) deform essentially in this direction (vertical); and it is this compression that varies the resistance of the layer 24 between the electrodes 25.
[0057] Another example of implantation of transducers 20 in a roadway is illustrated in FIG. 6. This figure shows a section of a roadway comprising an acquisition device 40 including two transducers 23 placed one above the other (in the vertical direction Z).
[0058] If connection layers are omitted (which will be presented later), the acquisition device 40 consists successively, starting from the bottom, of a lower layer 42 of bituminous mix, a lower transducer 23, a second layer 44 of bituminous mix, an upper transducer 23, and an upper layer 46 also in bituminous mix, and constituting a wall having a free upper surface. The lower transducer 23 is interposed between the two layers of bituminous mixes 42 and 44; the upper transducer 23 is interposed between the layers of bituminous mix 44 and 46. This provision provides information on the importance of the deformations of the roadway, depending on the depth. It is possible to increase the number of transducers arranged in the ground one above the other. The two transducers 23 are not implanted in the acquisition device 40 in the same way. The lower transducer 23 is sandwiched between two connecting layers 22 and 26 and is part of a ribbon 21 identical to that shown in FIGS. 1-4. Conversely, the transducer 23 is part of a ribbon 121 comprising a lower link layer 22, the transducer 23, and an upper link layer consisting of two sub-layers 126 and 128. The sub-layer 126 is chosen so as to have good adhesion to the piezoresistive layer 24, and is formed for example of ETFE; the upper sub-layer 128 is chosen so as to have good adhesion with the bituminous mixes of the layer 46, and is formed for example of bicomposite silicone elastomer. On the other hand, depending on the information that one seeks to acquire on the deformations of the roadway (or of the material in which the acquisition device is placed), the electrodes can be placed according to different orientations: Thus in a mode embodiment of the invention (FIG. 7), two transducers 23 according to the invention, and a third transducer 50 are implanted in a roadway 60. The roadway 60 is composed, starting from the bottom, of four parallel (and horizontal) layers. ) bituminous mixes 62,64,66,68.
[0059] Each of the first and second transducers 23 is constituted by a layer of piezoresistive material 24, and two electrodes 25 integral with this layer of material and spaced apart from each other in the plane of this layer. The first and second transducers 23 are arranged respectively between the layers 62 and 64, and between the layers 64 and 66. The first transducer 23 is arranged in such a way that its electrodes 25 extend parallel to each other according to the X direction: They are located at a distance from each other in the direction Y. Conversely, the second transducer 220 is arranged such that its electrodes 25 extend parallel to each other in the Y direction They are located at a distance from each other in the direction X. The third transducer 50 is constituted by a layer of piezoresistive material and two electrodes 55. The electrodes 55 are placed respectively above and below the piezoresistive material layer of the transducer 50. Thus, seen in the vertical direction, the electrodes 55 are not separated from each other. Thanks to the specific arrangement of the transducers 23 and 50, it is possible to simultaneously measure the deformations of the roadway along the three directions X, Y and Z. FIG. 10 shows another embodiment of an acquisition device according to the invention . In this device, the transducer comprises four elongate electrodes 425A, 425B, 425C, 425D (collectively referred to as the electrodes 425), arranged parallel to each other and equidistant in a plane substantially parallel to the surface of the wall. A so-called "4-point" measurement is carried out: An electric current is passed between the two furthest electrodes (the 'extreme' electrodes) 425A and 425D; The voltage is measured between the 'inner' electrodes 425B and 425C. The impedance is calculated by making the ratio between the current imposed between the extreme electrodes and the voltage measured between the two inner electrodes.
[0060] The found value corrected geometric effects, is called square resistance of the transducer. The resistivity of the piezoresistive material is then obtained by multiplying the square resistance by the average thickness of the body of the transducer. Advantageously, it is also possible to deduce the contact resistance of the electrodes from the resistivity of the material or the resistance per square. The use of the square resistor or the resistivity as the output value of the sensor makes it possible to minimize the sensitivity of the transducer to the behavior of the electrodes, for example in the case where the contacts adversely affect the quality of the measurement (degradation over time by example).
[0061] The use of the contact resistance as the output value of the sensor makes it possible to maximize the sensitivity of the latter to the behavior of the electrodes, for example when the relative displacement between the electrodes and the piezoresistive body is a major cause of the phenomenon of piezoresistivity. Figures 11 and 12 show another embodiment of acquisition device according to the invention. In this device, there are several electrodes in parallel, at least three and preferably more than four electrodes, with a distance D increasing between electrodes. In this case, there are four electrodes 525A, 525B, 525C and 525D (collectively called electrodes 525).
[0062] A measurement of the TLM type is carried out, that is to say that the resistance R between the different pairs of electrodes is measured, namely a set of resistors Rij measured between the different pairs of electrodes 525i-525j. The slope of the line representing the resistance R as a function of the spacing D between pairs of electrodes, corrected for the geometric factors, gives the resistivity or resistance per square; the ordinate at the origin of the line gives the contact resistance RO.
[0063] A sensor according to the invention mainly comprises one or more transducers as described above, connected to an impedance determination system, for example the ohmmeter 12 presented above, used to measure the resistance of the piezoresistive layer between the electrodes of the different transducers. . The impedance determination system may comprise a conventional signal conditioning chain. For example one (two for an automatic decorrelation of temperature) transducer can be interposed in a Wheatstone bridge supplemented by three (or two) resistors (preferably temperature-stable). The measurement is then performed by applying the voltage delivered by a voltage source 3V to 10V; the reading is done by an instrumental amplifier type acquisition chain, with filtering, offset correction, and analog / digital conversion. The analog part of the system is optionally supplemented by means making it possible to carry out the remote measurement, for example means making it possible to compensate the resistive losses in the wires in the event that the measurement system is moved away from the sensor), and by a shunt of 'calibration. Any other conventional system of acquisition and digitization of variable resistance may be suitable, especially systems that offer temperature compensation techniques. Alternatively, the variable resistor can be placed in a sigma-delta type system to simultaneously perform the analog-to-digital conversion and the reading of the resistance value. To produce a force sensor, the sensor further comprises a correlation system (also represented by the housing 12) making it possible to determine the deformation of the transducer (s), and / or the force (s) applied (s). ) to the wall, based on the impedance of the transducer (s) and / or variations thereof as measured by the impedance determination system.
[0064] When the sensor comprises several transducers, they can in particular be organized in a matrix network. In the case of a sensor for weighing vehicles, preferably the impedance determination system (the ohmmeter) and possibly the correlation system are deported on the edge of the roadway. This system or these systems can also be made in a flexible material, ad-hoc packaged and placed under or above the layer of piezoresistive material of the transducers, either in the heart of the asphalt or in a layer of link. Once the signal of one or more transducers has been digitized, the signal is processed or not on site and transmitted by any appropriate transmission means, for example by an acquisition unit, data logger or radio communicating node, autonomous or not in energy. , RFID, etc. Manufacture: the piezoresistive body, the acquisition device, the sensor The manufacture of the piezoresistive body is the main step for the realization of an acquisition device according to the invention. For this step, 10 different methods can be used. The choice of method depends on the desired piezoresistive material and the location of use (in the factory or on site). Certain types of piezoresistive material may be deposited in the vapor phase (evaporation, chemical or physical deposition) on a support surface. This operation can be carried out either on site (in situ manufacture) or in the factory. However, the liquid phase deposition of the components of the material may be preferred. Such a deposit is feasible in the factory or on site. The procedure may be as follows: i) The piezoresistive material, previously reduced to powder, is placed in solution in a solvent. This can be done according to conventional techniques (for example magnetic stirring, sonication in ultrasonic bath or by tip, centrifugation possible, ...). The solvent is preferably, but not exclusively, aqueous; the properties of the solvent can be optionally optimized by the use of additives (for example surfactants) capable of improving the quality of the deposit (for example its homogeneity). ii) The solution thus obtained is deposited on the surface on which the piezoresistive body (or layer) is to be formed. This deposit can be done according to conventional techniques. The technique used is chosen as a function of the physicochemical properties of the solution and of the surface to be covered, the requirement of homogeneity, any temporal constraints, the location of use. The deposition can be done for example by inkjet printing, drop deposition, spray, spin, or brush. Iii) The solvent is removed. This operation is carried out by any known method, in particular by natural or forced evaporation.
[0065] The manufacture of an acquisition device such as the device 20 (FIG. 3) is done in several steps: A) A support surface is prepared on which the roadway must be made.
[0066] B) The pavement is made by integrating the acquisition device. Step B) comprises several phases: i) depositing the lower layer 32 of bituminous mixes; ii) depositing the lower bonding layer 22 on the upper surface of the layer 32 so that the layer 22 adheres to the layer 32; iii) positioning the pair of electrodes 25 on the layer 22 by spacing them in the horizontal direction (X, Fig.4); iv) forming the piezoresistive layer 24 of piezoresistive material on the layer 22 and the electrodes 25; v) depositing the upper tie layer 26 on the piezoresistive layer 24 so that the tie layer 26 adheres to the piezoresistive layer 24; vi) the upper layer 34 of bituminous mix is then deposited on the tie layer 26. An acquisition device having the same structure as the device 20 (a lower layer, a tie layer, a piezoresistive layer, a layer of bond, top layer or transfer) can be manufactured in the factory. In this case, the transducers may in particular be made of ribbon (of plastic material), as is the case of the ribbon 21 shown in FIG. 1. The lower 22 and upper 26 layers are then plastic films or plates. Ribbon packaging facilitates subsequent placement of the transducer especially when a number of transducers are set or positioned together. Alternatively, the acquisition device can also be manufactured directly in situ. This method of manufacture is particularly suitable for producing dynamic vehicle weighing sensors. In the latter case, the manufacture of the acquisition device can be included in the normal operations of manufacture of the roadway. The integration of the acquisition device in the pavement makes it possible to give the latter an additional function (the dynamic weighing of vehicles), and this for an extremely reduced cost.
[0067] To make a sensor, it is then sufficient to connect the acquisition device obtained by the above method to an impedance determination system, for example an ohmmeter, itself optionally connected to a deformation or force determination system, if one wants to obtain as output value directly a deformation or a force. Several transducers may possibly be connected to the same impedance determination system.
[0068] An important application of the sensors presented above is the production of sensors integrated into roads and allowing the detection, counting and weighing of vehicles, or the monitoring of deformations of the roadway. The manufacture of a roadway integrating such a sensor can for example be carried out as follows (Figs.8 and 9): Stripping the road is carried a planer 102 which scours the surface layer 104 of a road 100. This operation reveals a stripped surface 106 on which a new floor 110 can be made.
[0069] Laying a first layer of bituminous mixes On the surface 106, a first layer of bituminous mix 112 is deposited and smoothed with a roller-compressor 108. The upper surface 113 of the bituminous mix layer 112 constitutes a support surface ready to receive the transducer.
[0070] In-situ fabrication of the acquisition device A prefabricated transducer can be used at the factory. In step iv) indicated above, it is then sufficient to position this transducer on the upper surface 113 of the layer 112. Alternatively, the transducer can be manufactured directly in step iv) on the surface of the layer In the following manner: - A powder of composite material comprising clay particles coated at least in part with a conductive substance, and nanotubes, of the type indicated above; This powder is diluted in water so as to obtain an aqueous solution at 0.5% mass of composite material; - On the still hot compacted asphalt constituting the bituminous mix layer 112, a few drops of this aqueous solution are deposited; Two electrodes 325 are then placed, separated by a few centimeters from one another, so that each electrode is in contact with the zone on which the aqueous solution has been poured. - The water is evaporated, first freely and then with the aid of a heat gun which projects on the aqueous solution a flow of air heated to about 200 ° C. A transducer body 324 of piezoresistive material formed on the surface 113 of the lower layer 112 is thus obtained. The body 324 associated with the electrodes 325 forms a transducer 323. The portion of the roadway comprising the layer 112, the transducer 323 and the diaper 116 forms an acquisition device 320. This embodiment does not include the installation of any bonding layer to bind the transducer 323 to the neighboring layers. Laying a second layer of bituminous mixes A second layer of bituminous mix 116 is then deposited on the first layer 112 and the transducer 323, and this second layer is smoothed with a roller-compressor 118.
[0071] In this embodiment, the layer 116 is formed directly on the piezoresistive layer 324 on which the electrodes 325 have been fixed. The operations of setting up the transducer are thus part of the normal planning of the manufacture of the roadway 11. .
[0072] Preferably, the thicknesses of the layers 112 and 116 are chosen such that the transducer 323 is located at a depth h between 15% and 50% of the thickness H of the roadway 110. Naturally, other methods than that presented herein below can be implemented while remaining within the scope of the invention.
[0073] In particular, a roadway can be composed of strictly more than two layers. A transducer according to the invention may preferably be placed between two layers. It can also alternatively be implanted inside the asphalt of a layer.

权利要求:
Claims (15)
[0001]
REVENDICATIONS1. An acquisition device (20) having a wall and a transducer (23,323), wherein the transducer is constituted by a body (24,324) and a plurality of electrodes (25,325,425,525) attached to said body at a distance from each other; the transducer is such that an electrical impedance (R) determined from said plurality of electrodes is variable as a function of the deformations experienced by the transducer; and in a view in a direction perpendicular to a surface (36) of the wall, at least two electrodes (25) of said plurality of electrodes are separated from each other; the device being characterized in that the transducer is integrated under the surface (36) of the wall.
[0002]
2. Acquisition device according to claim 1, further comprising a transfer layer (34,46,116) adhering to one side of the transducer (23,323) and separating the transducer from the surface of the wall.
[0003]
3. Acquisition device according to claim 2, wherein the transfer layer (34,46,116) and the wall are formed of the same material, in particular bituminous mixes.
[0004]
4. Acquisition device according to claim 3, wherein the transfer layer (34,46,116) and the wall are integrally formed.
[0005]
5. Acquisition device according to any one of claims 1 to 4, arranged such that if a force is applied to the acquisition device in a direction (A) perpendicular to the surface (36) of the wall, the The transducer deforms primarily in said direction perpendicular to the wall surface, and an impedance measured between the electrodes of said plurality of electrodes varies.
[0006]
6. Acquisition device according to any one of claims 1 to 5, arranged such that if a force is applied to the acquisition device in a direction (A) perpendicular to the surface (36) of the wall, the The transducer deforms primarily in a plane substantially parallel to the wall (B), and an impedance measured between the electrodes of said plurality of electrodes varies.
[0007]
7. Acquisition device according to any one of claims 1 to 6, wherein the body (24) of the transducer forms a thin layer, that is to say less than 1 / 10th of a thickness of one at least two other characteristic dimensions of said body.
[0008]
8. Acquisition device according to any one of claims 1 to 7, further comprising a bonding layer (22,26) interposed between the transducer body and a surface adjacent the body of the transducer, the bonding layer adhering to the body of the transducer and to said neighboring surface.
[0009]
An acquisition device according to any one of claims 1 to 8, wherein the transducer body (24) comprises a piezoresistive polymer, or a mixture of a plurality of piezoresistive polymers, or a mixture of at least one polymer with conductive micro- and nano-particles or a mixture of bituminous mix or bitumen with micro and nanoparticles.
[0010]
10. Acquisition device according to any one of claims 1 to 8, wherein the body (24) of the transducer comprises a percolating network of micro- and / or nano-particles, said micro- and / or nanoparticles. comprising one or more particles from the following list: a) carbon nanotubes, in particular random or organized lattice, b) micro or nanoparticles self-assembled, c) graphene sheets, graphite or graphene oxide reduced or not.
[0011]
11. Tape (21,121) comprising a plurality of acquisition devices according to any one of claims 1 to 10, fixed on a strip. 30
[0012]
A sensor (10) having at least one acquisition device (20, 120) according to any one of claims 1 to 10, and an impedance determining system (12) connected to electrodes (25, 325, 255, 255) of least one transducer of said at least one acquisition device, and able to determine an impedance and / or an impedance variation of said at least one transducer.
[0013]
13. Sensor (10) according to claim 12, comprising a set of transducers arranged in an array, in particular so as to form a matrix, and further comprising means for identifying which transducers are activated or requested at a given instant.
[0014]
14 Display capable of displaying variable information, comprising at least one acquisition device according to one of claims 1 to 10.
[0015]
A force measuring method comprising the following steps: a) providing a transducer (23) consisting of a body (24) and a plurality of electrodes (25,325,425,525) fixed to said body at a distance from each other, the transducer being such that an electrical impedance (R) determined from said plurality of electrodes is variable as a function of the deformations experienced by the transducer; b) applying a force to said transducer in a direction such that in a view along this direction at least two electrodes of said plurality of electrodes are separated from each other; c) the variation of the impedance is measured under the effect of the applied force; and d) determining the applied force as a function of said impedance variation. A method of manufacturing an acquisition device having a wall and a transducer, the method comprising the following steps: a) positioning a plurality of electrodes (25,325,425,525) in contact with a body (24), the body and said electrodes being such that an electrical impedance (R) determined from said plurality of electrodes is variable as a function of the deformations experienced by the body associated with said plurality of electrodes; the body and said plurality of electrodes thereby forming a transducer (23); b) the wall is formed; The method being characterized in that steps a) and b) are performed such that the transducer (23) is integrated under a surface (36) of the wall, and that in a view in a direction perpendicular to said surface at least two of said electrodes (25,325,425,525) are separated from each other. 17. A pavement manufacturing method comprising the following steps: A) A support surface (113); B) is prepared on said support surface, at least one layer of bituminous mix (116) is deposited by integrating at least one transducer (320), such that the roadway comprises an acquisition device formed by a method according to claim 16.5

类似技术:

---

公开号 | 公开日 | 专利标题

---

EP3126801B1|2021-03-17|Acquisition device, method for the production thereof, and force measurement method

---

EP2877911B1|2018-09-05|Method of manufacturing a transparent tactile surface and tactile surface obtained by such a method

---

EP2904595A1|2015-08-12|Capacitive sensor for detecting the presence of an object and/or of an individual

---

EP3471947B1|2020-02-19|Process and apparatus for manufacturing a mecatronic system by three-dimensional printing

---

JP2008511008A5|2008-10-09|

---

WO2013038083A1|2013-03-21|Piezoelectric pressure sensor

---

EP2233919A1|2010-09-29|Micro-device for in situ detection of particles of interest in a fluid medium and method for implementing the same

---

FR2964651A1|2012-03-16|SUSPENDED BEAM DEVICE AND MEANS FOR THE PIEZORESISTIVE DETECTION OF THE DISPLACEMENT THEREOF, AND METHOD FOR MANUFACTURING THE DEVICE

---

KR101551876B1|2015-09-09|Biosensor based on carbon nanotube using floating electrode and Manufacturing method of the same and Measuring method of electrophysiological responses from a non-adherent cell

---

KR101223475B1|2013-01-17|Fabrication method for carbon nanotube film and sensor based carbon nanotube film

---

EP2616386A1|2013-07-24|In-plane actuated resonant device and method of manufacturing the device

---

EP1895270B1|2011-06-01|Microsystem, in particular a microgyrometer, with a detection element having capacitive electrodes

---

Jiang et al.2015|The smallest resonator arrays in atmosphere by chip-size-grown nanowires with tunable q-factor and frequency for subnanometer thickness detection

---

Lillemose et al.2008|Epoxy based photoresist/carbon nanoparticle composites

---

Prashanthi et al.2012|Local piezoelectric response of ZnO nanoparticles embedded in a photosensitive polymer

---

CA2445285C|2009-12-22|Biosensor matrix and method for making same

---

FR3057958A1|2018-04-27|PROBE FOR MICROSCOPY WITH MINIATURIZED ATOMIC FORCE AND LOW SIZE

---

FR3089630A1|2020-06-12|HEAT FLOW SENSOR WITH HEATING NANOFILAMENTS

---

EP0209476A2|1987-01-21|Method and apparatus for detecting the appearance and quantification of the development of cracks in the surface of a material

---

WO2014041044A1|2014-03-20|Device for biological or chemical detection including electrical sensing

---

FR3033644A1|2016-09-16|NON-DESTRUCTIVE MEASUREMENT OF THE MOISTURE RATE OF A MATERIAL

---

WO2020074075A1|2020-04-16|Piezoelectric sensor

---

FR3064151A1|2018-09-21|METHOD OF MANUFACTURING ELECTRIC CIRCUITS, ELECTRIC CIRCUIT AND ELECTRONIC COMPONENT

同族专利:

---

公开号 | 公开日

---

BR112016022633A2|2017-08-15|

---

EP3126801A1|2017-02-08|

---

CN106461475A|2017-02-22|

---

FR3019291B1|2017-12-01|

---

WO2015150676A1|2015-10-08|

---

KR20170039616A|2017-04-11|

---

SG11201608066PA|2016-11-29|

---

US10989612B2|2021-04-27|

---

BR112016022633A8|2021-05-18|

---

US20170138804A1|2017-05-18|

---

EP3126801B8|2021-05-05|

---

EP3126801B1|2021-03-17|

---

RU2016142595A3|2018-07-13|

---

JP2017513003A|2017-05-25|

---

AU2015238959A1|2016-10-20|

---

CN106461475B|2020-06-02|

---

RU2682113C2|2019-03-14|

---

CA2943942A1|2015-10-08|

---

AU2015238959B2|2019-11-28|

---

RU2016142595A|2018-05-03|

引用文献:

---

公开号 | 申请日 | 公开日 | 申请人 | 专利标题

---

EP0218465A2|1985-10-02|1987-04-15|Raychem Limited|Pressure sensor|

---

US4799381A|1988-02-21|1989-01-24|Cmi International, Inc.|Vehicle road sensor|

---

US20110227836A1|2008-03-20|2011-09-22|Motorola, Inc.|Transparent force sensor and method of fabrication|LU93175B1|2016-08-12|2018-03-28|Innovationlab Gmbh|Sensor|US4013851A|1975-07-25|1977-03-22|Bofors America, Inc.|Vehicle detection apparatus|

---

JPS6220108Y2|1978-04-08|1987-05-22|

---

JPS54148885A|1978-05-15|1979-11-21|Toray Ind Inc|Bonding process of synthetic fibers to rubber|

---

FR2487555B1|1980-07-28|1983-08-26|Automatisme Cie Gle|

---

US4634917A|1984-12-26|1987-01-06|Battelle Memorial Institute|Active multi-layer piezoelectric tactile sensor apparatus and method|

---

US4712423A|1985-01-04|1987-12-15|Laboratoire Central Des Ponts Et Chaussees|Process and apparatus for measuring the dynamic loads applied to a highway by the road traffic|

---

US4839480A|1986-11-05|1989-06-13|The Gates Rubber Company|Vehicle sensing device|

---

AT141432T|1987-04-02|1996-08-15|Franz Josef Gebert|TRAFFIC MEASURING SYSTEM|

---

US4793429A|1988-04-20|1988-12-27|Westinghouse Electric Corp.|Dynamic vehicle-weighing system|

---

US4963705A|1989-04-11|1990-10-16|Chomerics, Inc.|Treadle assembly|

---

US5448232A|1989-05-03|1995-09-05|Mitron Systems Corporation|Roadway sensors and method of installing same|

---

US5463385A|1989-05-03|1995-10-31|Mitron Systems Corporation|Roadway sensor systems|

---

US5132583A|1989-09-20|1992-07-21|Intevep, S.A.|Piezoresistive material, its preparation and use|

---

CH683714A5|1990-12-19|1994-04-29|Kk Holding Ag|Force sensor arrangement, in particular for the dynamic axle load, speed, center distance and total weight determination of vehicles.|

---

US5554907A|1992-05-08|1996-09-10|Mitron Systems Corporation|Vehicle speed measurement apparatus|

---

US5477217A|1994-02-18|1995-12-19|International Road Dynamics|Bidirectional road traffic sensor|

---

EP0675472A1|1994-03-30|1995-10-04|Thermocoax|Device for the detection of data of passing vehicles on a road|

---

US5510812A|1994-04-22|1996-04-23|Hasbro, Inc.|Piezoresistive input device|

---

US5571973A|1994-06-06|1996-11-05|Taylot; Geoffrey L.|Multi-directional piezoresistive shear and normal force sensors for hospital mattresses and seat cushions|

---

US5710558A|1996-01-16|1998-01-20|Gibson; Guy P.|Traffic sensor for roadway placement|

---

JP3528435B2|1996-06-27|2004-05-17|トヨタ自動車株式会社|Road object detection device|

---

CA2261606A1|1996-07-19|1998-01-29|Tracon Systems Ltd.|A passive road sensor for automatic monitoring and method thereof|

---

JPH1078357A|1996-09-04|1998-03-24|Alps Electric Co Ltd|Pressure sensitive resistance element|

---

US5835027A|1996-11-07|1998-11-10|Tyburski; Robert M.|Residual charge effect traffic sensor|

---

US5979230A|1997-05-20|1999-11-09|Hunter Engineering Company|Brake in motion plate brake tester and method|

---

JPH11148852A|1997-11-14|1999-06-02|Mitsubishi Heavy Ind Ltd|Measuring method and device for vehicle weight|

---

US6556927B1|1998-08-26|2003-04-29|Idaho Transportation Department|Picostrain engineering data acquisition system|

---

EP0997713A1|1998-10-29|2000-05-03|K.K. Holding AG|Traffic monitoring systems|

---

LU90309B1|1998-11-04|2000-05-05|Iee Sarl|Passenger detector|

---

US6121869A|1999-09-20|2000-09-19|Burgess; Lester E.|Pressure activated switching device|

---

JP2001230462A|2000-02-17|2001-08-24|Minolta Co Ltd|Piezoelectric transducer|

---

CA2310149C|2000-05-30|2004-12-07|International Road Dynamics Inc.|In road vehicle axle sensor|

---

JP2002039874A|2000-07-27|2002-02-06|Mitsumi Electric Co Ltd|Pressure-sensitive sensor|

---

GB0103665D0|2001-02-15|2001-03-28|Secr Defence|Road traffic monitoring system|

---

US6819316B2|2001-04-17|2004-11-16|3M Innovative Properties Company|Flexible capacitive touch sensor|

---

JP2002343208A|2001-05-15|2002-11-29|Ryochi Kato|Buried type loading detecting device|

---

FR2830966B1|2001-10-11|2005-04-01|Electronique Controle Mesure|PROCESS FOR PROCESSING SIGNALS PROVIDED BY PIEZOELECTRIC SENSORS IMPLANT IN A PAVEMENT FOR MEASURING SPEED OF VEHICLES|

---

JP2003139630A|2001-10-30|2003-05-14|Fujikura Ltd|Pressure sensitive film resistor and pressure sensitive sensor|

---

US6915702B2|2001-11-22|2005-07-12|Kabushiki Kaisha Toyota Chuo Kenkyusho|Piezoresistive transducers|

---

CN100530931C|2002-09-20|2009-08-19|丹福斯有限公司|An elastomer actuator and a method of making an actuator|

---

US6894233B2|2003-02-20|2005-05-17|The Revenue Markets, Inc.|Systems and methods for classifying vehicles|

---

FR2857092B1|2003-07-04|2005-09-09|Thales Sa|ELECTROMAGNETIC LOOP SENSOR FOR MEASURING DYNAMIC LOADS APPLIED TO A PAVEMENT BY ROAD TRAFFIC|

---

JP4367613B2|2003-09-25|2009-11-18|横浜ゴム株式会社|Tire tread surface measuring device and measuring method|

---

CN101336369B|2006-02-07|2011-04-20|米其林技术公司|Contact detector having piezoelectric sensor|

---

DE102006019942B4|2006-04-28|2016-01-07|Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V.|Force measuring device for measuring the force in solid state actuators, methods for measuring a force and use of the force measuring device|

---

JP5044196B2|2006-11-13|2012-10-10|アイシン精機株式会社|Piezoelectric sensor and manufacturing method thereof|

---

JP4368392B2|2007-06-13|2009-11-18|東海ゴム工業株式会社|Deformation sensor system|

---

US8132468B2|2008-05-29|2012-03-13|Zoran Radivojevic|Flexural deformation sensing device and a user interface using the same|

---

WO2010031192A1|2008-09-18|2010-03-25|Visualsonics Inc.|Methods for manufacturing ultrasound transducers and other components|

---

JP4810690B2|2008-11-11|2011-11-09|株式会社豊田中央研究所|Force sensing element|

---

US20100126273A1|2008-11-25|2010-05-27|New Jersey Institute Of Technology|Flexible impact sensors and methods of making same|

---

US8161826B1|2009-03-05|2012-04-24|Stryker Corporation|Elastically stretchable fabric force sensor arrays and methods of making|

---

US8724247B2|2009-10-05|2014-05-13|Hewlett-Packard Development Company, L.P.|Adjusting a transducer head for transferring data|

---

ES2361763B1|2009-12-09|2012-05-04|Consejo Superior De Investigaciones Cient�?Ficas |USE OF FIBROUS CLAYS AS COADYUVANTS TO IMPROVE THE COLLIDAL DISPERSION AND STABILITY OF CARBON NANOTUBES OF HYDROPHYTIC MEDIA.|

---

WO2011074125A1|2009-12-18|2011-06-23|国立大学法人 北海道大学|Graphene oxide sheet, article containing grapheme-containing substance produced by reducing the graphene oxide sheet, and process for production of the graphene oxide sheet|

---

US8564449B2|2010-01-12|2013-10-22|Siemens Energy, Inc.|Open circuit wear sensor for use with a conductive wear counterface|

---

US8587422B2|2010-03-31|2013-11-19|Tk Holdings, Inc.|Occupant sensing system|

---

JP2012065426A|2010-09-15|2012-03-29|Toyoda Gosei Co Ltd|Manufacturing method of actuator|

---

DE112011103678T5|2010-11-04|2014-01-23|Tokai Rubber Industries, Ltd.|bend sensor|

---

ES2393474B1|2011-05-23|2013-11-08|Consejo Superior De Investigaciones Científicas|COMPOSITION OF CARBON MATERIAL OBTAINABLE BY CARBONIZATION OF A BIOPOLYMER SUPPORTED ON CLAY.|

---

US9664717B2|2012-04-26|2017-05-30|The University Of Akron|Flexible tactile sensors and method of making|

---

WO2015143307A1|2014-03-20|2015-09-24|The University Of Akron|Flexible tactile sensors and method of making|

---

AU2015370928A1|2014-12-23|2017-07-20|Haydale Graphene Industries Plc|Piezoresistive device|

---

US10620062B2|2017-10-23|2020-04-14|Deborah D. L. Chung|Cement-based material systems and method for self-sensing and weighing|WO2019239194A1|2018-06-15|2019-12-19|Arcelormittal|A coated non-conductive substrate|

---

CN110044469A|2019-03-19|2019-07-23|深圳大学|A kind of motion detection apparatus and preparation method and application|

---

FR3096773B1|2019-05-28|2021-06-11|Ecole Polytech|Acquisition device, measuring system and soil|

---

RU2762026C1|2021-02-10|2021-12-14|Анастасия Валерьевна Лозицкая|Method for manufacturing a flexible deformation sensor|

法律状态:
2016-03-24| PLFP| Fee payment|Year of fee payment: 3 |

---

2017-03-23| PLFP| Fee payment|Year of fee payment: 4 |

---

2018-02-09| PLFP| Fee payment|Year of fee payment: 5 |

---

2020-02-17| PLFP| Fee payment|Year of fee payment: 7 |

---

2021-02-18| PLFP| Fee payment|Year of fee payment: 8 |

---

2022-02-16| PLFP| Fee payment|Year of fee payment: 9 |

优先权:

---

申请号 | 申请日 | 专利标题

---

FR1452842A|FR3019291B1|2014-03-31|2014-03-31|ACQUISITION DEVICE, METHOD FOR MANUFACTURING THE SAME, FORCE MEASURING METHOD|FR1452842A| FR3019291B1|2014-03-31|2014-03-31|ACQUISITION DEVICE, METHOD FOR MANUFACTURING THE SAME, FORCE MEASURING METHOD|

---

CA2943942A| CA2943942A1|2014-03-31|2015-03-27|An acquisition device, a method of fabricating it, and a method of measuring force|

---

AU2015238959A| AU2015238959B2|2014-03-31|2015-03-27|Acquisition device, method for the production thereof, and force measurement method|

---

CN201580028527.8A| CN106461475B|2014-03-31|2015-03-27|Acquisition device, manufacturing method thereof and force measuring method|

---

US15/300,510| US10989612B2|2014-03-31|2015-03-27|Sensor with a plurality of acquisition devices that measure force using impedance|

---

SG11201608066PA| SG11201608066PA|2014-03-31|2015-03-27|An acquisition device, a method of fabricating it, and a method of measuring force|

---

EP15718524.0A| EP3126801B8|2014-03-31|2015-03-27|Acquisition device, method for the production thereof, and force measurement method|

---

BR112016022633A| BR112016022633A8|2014-03-31|2015-03-27|acquisition device, tape, sensor, display, and, force measurement and manufacturing processes of an acquisition device and a road|

---

KR1020167030511A| KR20170039616A|2014-03-31|2015-03-27|Acquisition device, method for the production thereof, and force measurement method|

---

PCT/FR2015/050805| WO2015150676A1|2014-03-31|2015-03-27|Acquisition device, method for the production thereof, and force measurement method|

---

RU2016142595A| RU2682113C2|2014-03-31|2015-03-27|Measuring device, method for manufacture thereof and method for measuring force|

---

JP2016560012A| JP2017513003A|2014-03-31|2015-03-27|Acquirer, Acquiring Device Manufacturing Method and Force Measuring Method|