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  • 专利说明
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    • 专利摘要:
    COMPOSITE GLASS WITH ELECTRICALLY SWITCHABLE OPTICAL PROPERTIES. The present invention relates to a composite glazing with electrically switchable optical properties, at least comprising:, - an outer glazing (1) and an inner glazing (2), which are laminarly connected together via an intermediate layer (11), - within the intermediate layer (11), a switchable functional element (4), with at least one active layer (5) and - an infrared protective coating (3) laminarly arranged between the outer pane (1) and the active layer ( 5). wherein the infrared protective coating (3) contains at least three functional layers (14) with reflective properties for the infrared strip.
    公开号:BR112015002977B1
    申请号:R112015002977-9
    申请日:2013-06-28
    公开日:2020-11-10
    发明作者:Julius MENNIG；Franz PENNERS
    申请人:Saint-Gobain Glass France；
    IPC主号:
    专利说明:

    [0001] The invention relates to a composite glazing with electrically switchable optical properties, a method for its production and the use of an infrared protective coating on such a composite glazing.
    [0002] Glazings with electrically switchable functional elements are known. The optical properties of the functional elements can be modified by an applied voltage. Electrochromic functional elements known, for example, from US 20120026573 A1 and WO 2012007334 A1 are an example of this. The SPD (suspended particulate device) functional elements known, for example, from EP 0876608 B1 and WO 2011033313 A1 are another example. The transmittance of visible light through electrochromic elements or functional SPDs can be controlled by the applied voltage. Glazing with such functional elements can therefore be conveniently darkened electrically.
    [0003] Many suitable functional elements have limited long-term stability. This is particularly true for functional elements in the glazing of billboards, for example, on building facades or in the motor vehicle sector, where the functional elements are exposed to sunlight. In particular, the infrared spectral component of sunlight results in the aging of functional elements. Aging can, for example, manifest itself in non-aesthetic discoloration of the functional elements, which can be homogeneous or even non-homogeneous. However, aging can also result in degradation of the functionality of the switchable functional element, in particular in a reduced contrast between the switching states.
    [0004] Consequently, WO 2007122426 A1 proposes to protect the functional element within a composite glazing by a protective coating against infrared radiation. The protective coating preferably contains one or two functional silver layers through which the infrared radiation is reflected. However, protective coatings with one or two layers of silver have high transmittance in the near-infrared range. Consequently, the failure of the functional element can certainly be reduced by such a protective coating, but it cannot be completely avoided.
    [0005] The purpose of the present invention is to provide a composite glazing with electrically switchable optical properties, which has improved protection of the switchable functional element against infrared radiation.
    [0006] The purpose of the present invention is achieved according to the invention by a composite glazing with electrically switchable optical properties, according to independent claim 1. Preferred embodiments emerge from the dependent claims.
    [0007] The composite glazing according to the present invention, with electrically switchable optical properties, comprises at least the following characteristics: - an external glazing and an internal glazing, which are laminarly connected together via an intermediate layer, - within the layer intermediate, a switchable functional element with at least one active layer, and - an infrared protective coating, disposed laminarly between the outer pane and the active layer, where the infrared protective coating includes at least three functional layers with reflective properties for the range of infra-red.
    [0008] The composite glazing according to the present invention is preferably provided in an opening, for example, of a motor vehicle or a building, to separate the interior from the external environment. In the context of the invention, “external glazing” refers to that glazing that, in its installed position, faces the external environment, “internal glazing” means that the glazing, in the installed position, faces the interior. In principle, the composite glazing according to the present invention can, of course, also be used inside a building, in particular when protection against infrared radiation is required in it. The external pane is then that pane that faces the source of infrared radiation.
    [0009] If an element includes at least one material, it includes, in the context of the invention, the case in which the element is made of the material.
    [0010] In the context of the invention, “a composite glazing with electrically switchable optical properties” refers not only to a composite glazing, whose optical properties, for example, the visible light transmittance, can be switched between two different states, for example, an opaque and a transparent state. It also refers to composite glazing whose optical properties are continuously variable.
    [0011] According to the invention, the infrared protective coating is disposed laminarly between the outer pane and the active layer. The sunlight entering the external environment through the composite glazing thus first collides with the protective coating and then the functional element. The infrared radiation component of sunlight is reflected and / or absorbed by the infrared protective coating and, consequently, does not collide with the functional element (or does so to a significantly reduced extent). The main advantage of the invention lies in the infrared protective coating with at least three functional layers implemented in accordance with the invention. Such infrared protective coating has high transmittance in the visible spectral range, however it has high reflectance already in the near infrared range, adjacent to the visible spectral range. The functional element is particularly effectively protected against components of infrared radiation by the infrared protective coating according to the invention, without the transparency of the composite glazing being disruptedly diminished in the visible spectral range. Through the arrangement between an active layer and an external pane, the protective infrared coating is advantageously protected inside the composite pane against damage and corrosion.
    [0012] Of course, the composite glazing can also have more than one infrared protective coating according to the present invention. According to the invention, at least one protective infrared coating must be disposed between the active layer of the functional element and the outer pane. For example, another protective infrared coating can be placed between the active layer and the inner pane.
    [0013] The electrically switchable functional element comprises at least one active layer, which has switchable optical properties. The active layer is disposed laminarly between an internal transparent plate electrode. The outer plate electrode faces the outer pane and the inner plate electrode faces the inner pane. The plate electrodes and the active layer are typically arranged parallel to the surfaces of the outer pane and the inner pane. The plate electrodes are electrically connected to an external voltage source in a manner known to you. The electrical contact is made by means of suitable connection cables, for example, foil conductors, which are optionally connected to the plate electrodes via the so-called collecting bars, for example, strips of an electrically conductive material or electrically conductive impressions.
    [0014] The switchable functional element is embedded in the intermediate layer of the composite glazing according to the present invention. The outer pane and the inner pane are stably connected to each other by lamination via the intermediate layer. The intermediate layer includes at least one thermoplastic adhesive film. The thermoplastic adhesive film includes at least one thermoplastic polymer, preferably ethylene vinyl acetate (EVA) and / or polyvinyl butyral (PVB). Thus, a particularly advantageous connection of the intermediate layer to the outer pane and the inner pane is achieved. However, the thermoplastic adhesive film may also include, for example, at least polyurethane, polyethylene, polyethylene terephthalate, polypropylene, polycarbonate, polymethyl methacrylate, polyacrylate, polyvinyl chloride, polyacetate resin, foundry resins, fluorinated ethylene propylene fluorines, polyvinyl fluorides and / or ethylene tetrafluoroethylene. The thickness of the thermoplastic adhesive film is preferably 0.25 mm to 1 mm, for example, 0.38 mm or 0.76 mm.
    [0015] In principle, the functional element can, for example, be applied to the inner surface of the outer pane or the inner pane. The “inner surface” refers to that surface of a window that faces the middle layer. In a preferred embodiment, the functional element is disposed laminarly between at least two thermoplastic adhesive films. The functional element is connected to the external pane via at least one first thermoplastic adhesive film and to the internal pane via at least one second thermoplastic adhesive film. The first and second thermoplastic adhesive films are in contact with the external pane or the internal pane, respectively, and connect the functional element to the external pane and the internal pane to form the composite pane.
    [0016] In a preferred embodiment, the functional element is provided during the production of the composite glazing as a functional element of pre-laminated film. In the case of such a pre-laminated functional element, the actual functional element is arranged laminarly between at least one first and at least a second carrier film. The first carrier film is preferably attached to the external pane at least via a first thermoplastic adhesive film and the second carrier film is attached to the internal pane via at least a second thermoplastic adhesive film. The intermediate layer then comprises, with increasing distance from the outer pane, at least the first thermoplastic adhesive film, the first carrier film, the outer plate electrode, the active layer, the inner plate electrode, the second carrier film and the second adhesive film thermoplastic. The advantage lies in the simple production of composite glazing. The pre-laminated functional element can, during production, simply be inserted into the compound, which is then laminated using the methods of the prior art, to form the composite glazing. The functional element is advantageously protected against damage, in particular corrosion, by the carrier film and can even be prepared in relatively large quantities, before the production of the composite glazing, which may be desirable for economic and processing engineering reasons.
    [0017] The carrier films preferably contain at least one thermoplastic polymer, particularly preferably polyethylene terephthalate (PET). This is particularly advantageous with respect to the stability of the pre-laminated functional element. However, carrier films may also contain, for example, ethylene vinyl acetate (EVA) and / or polyvinyl butyral (PVB), polypropylene, polycarbonate, polymethyl methacrylate, polyacrylate, polyvinyl chloride, polyacetate resin, foundry resins, acrylates, ethylene -Fluorinated propylene, polyvinyl fluoride and / or ethylene-tetrafluoroethylene. The thickness of each carrier film is preferably 0.1 mm to 1 mm, particularly preferably 0.1 mm to 0.2 mm. The total thickness of the composite pane is increased only insignificantly by a carrier film of such low thickness.
    [0018] In a preferred embodiment of the invention, the infrared protective coating is applied to the inner surface of the outer pane. The particular advantage lies in the simple and cost-effective production of composite glazing. In addition, an infrared protective coating of the external pane can be subjected in a simple way to temperature treatment, whereby, in particular, the transmittance of visible light through the pane is improved. The functional element includes an outer plate electrode and an inner plate electrode, among which the active layer is arranged congruently.
    [0019] In other embodiments of the invention, the infrared protective coating is applied to a film of the intermediate layer. The film of the intermediate layer can be, for example, the first thermoplastic adhesive layer, through which the functional element is connected to the outer glazing. The interlayer film may be, for example, the first film bearing a pre-laminated functional element that faces the outer pane. In principle, another thermoplastic film, which is provided with the protective infrared coating, can also be inserted into the compound, preferably between the first thermoplastic adhesive film and the first carrier film. However, such a solution has the disadvantage of an increased thickness of the composite glazing, as well as the risk of non-aesthetic distortions within the intermediate layer.
    [0020] In a preferred embodiment of the invention, the infrared protective coating is applied to the first film bearing a pre-laminated functional element. The functional element can then be prepared in an advantageous way, from the point of view of processing engineering, together with the internal sealing coating. In one embodiment, the protective infrared coating is disposed on the surface of the first carrier film facing away from the functional element and facing the first thermoplastic adhesive film. A pre-laminated functional element, previously prepared, possibly commercially purchased, can be provided with the infrared coating, before the production of the composite glazing. The functional element includes an outer plate electrode and an inner plate electrode, among which the active layer is arranged congruently. In another embodiment, the protective infrared coating is disposed on the surface of the drill string facing the functional element. The infrared protective coating is therefore advantageously already protected before the production of the composite glazing inside the pre-laminated functional element against damage and corrosion. Another advantage is that the protective infrared coating can simultaneously function as a plate electrode, as long as it has sufficient electrical conductivity.
    [0021] In a particularly preferable embodiment of the invention, the infrared protective coating is applied to the surface of the first carrier film facing the active layer and the infrared protective coating is the outer plate electrode. The functional element includes the protective infrared coating such as an outer plate electrode and an inner plate electrode, among which the active layer is arranged congruently. The infrared protective coating preferably makes electrical contact via at least one suitable cable and, optionally, a busbar, and is connected to the external voltage source. The particular advantage lies in simpler production of the composite glazing, when the infrared protective coating and the outer plate electrode are made by the same element and do not have to be introduced into the composite glazing as different elements.
    [0022] The inventive concept of using the infrared protective coating as the outer plate electrode is absolutely not limited to protective infrared coatings with at least three functional layers. It can, for example, also be carried out using protective infrared coatings, with at least two functional layers with reflective properties for the infrared range, for example, two or three functional layers.
    [0023] The infrared protective coating can be applied over the entire surface of the outer pane or a film of the intermediate layer. Then, the area of the infrared protective coating corresponds to the area of the composite glazing. However, the composite pane may also have an edge region with a width of, for example, 3 mm to 50 mm, which is not provided with the infrared protective coating. Then, the infrared protective coating has no contact with the outside atmosphere and is advantageously protected inside the composite pane against corrosion.
    [0024] The functional layers of the infrared protective coating according to the present invention are preferably metal and contain at least one metal, for example, silver, gold, copper, nickel and / or chromium, or a metal alloy. The more particularly preferable functional layers contain at least 90% by weight of the metal, in particular at least 99.9% by weight of the metal. Functional layers can be made of metal or alloy. The particularly preferable functional layers contain silver or an alloy containing silver. Such functional layers have particularly advantageous reflectance in the infrared range with simultaneously high transmittance in the visible spectral range.
    [0025] Each functional layer of the infrared protective coating according to the present invention preferably has a thickness of 5 nm to 50 nm, particularly preferable from 8 nm to 25 nm and, most particularly particularly, from 10 nm to 20 nm. In this range for the thickness of the functional layer, an advantageously high transmittance of the visible spectral range and a particularly advantageous reflectance level in the infrared range are obtained.
    [0026] The infrared protective coating according to the present invention can include more than three functional layers, for example, four or five functional layers. Preferably, the infrared protective coating contains exactly three functional layers. Protective infrared coatings with three functional layers are simpler to produce than infrared coatings with more than three functional layers. It has been demonstrated that the protective infrared coating with exactly three functional layers allows effective protection of the functional element against infrared radiation together with high transmittance in the visible spectral range.
    [0027] In an advantageous embodiment, at least one dielectric layer is arranged in each case between two adjacent functional layers of the infrared protective coating. Two functional layers are considered to be adjacent if no additional functional layers are disposed between them. Preferably, another dielectric layer is disposed below the first functional layer. The first functional layer is that of at least three functional layers, which is the shortest distance from the surface to which the infrared protective coating is applied. A layer is arranged under another layer when they are a shorter distance from said surface than the other layer. Preferably, another dielectric layer is arranged above the last functional layer. The last functional layer is that of at least three functional layers that is the greatest distance from the surface on which the infrared protective coating is applied. A layer is arranged above another layer when it is at a greater distance from said surface than the other layer.
    [0028] The protective infrared coating thus comprises, in a particularly preferred embodiment, n functional layers and (n + 1) dielectric layers, with the functional layers and the dielectric layers applied alternately, so that each functional layer is arranged between two dielectric layers. Here, n is an integer. This is particularly advantageous with respect to the optical properties of the composite glazing, as well as the reflection properties of the infrared band. By means of the dielectric layers, the protective infrared coating can be provided, in particular, with anti-reflective properties in the visible spectral range, by means of which the transmittance is improved.
    [0029] Each dielectric layer contains at least a single layer made of a dielectric material. A dielectric layer can be made of a single layer of a dielectric material. The single layer made of dielectric material preferably contains at least one oxide (for example, tin oxide, zinc oxide, aluminum oxide, titanium oxide, silicon oxide, manganese oxide, tungsten oxide or niobium oxide, or bismuth oxide) and / or at least one nitride (eg silicon nitride, zirconium nitride or aluminum nitride). The only layer made of a particularly preferable dielectric material contains silicon nitride. Thus, particularly good results are obtained with respect to the optical properties of the infrared protective coating. The single layer made of a dielectric material may also have dopants, for example, aluminum, zirconium and / or boron.
    [0030] Each single layer made of a dielectric material preferably has a thickness of 10 nm to 100 nm, particularly preferable from 20 nm to 70 nm. This is particularly advantageous with respect to the optical properties of the composite glazing.
    [0031] However, one or a plurality of the dielectric layers can also include more than a single layer made of dielectric material, at least one smoothing layer. The smoothing layer smooths the surface of the layers applied above the smoothing layer. Thus, higher transmittance in the visible spectral range is obtained. The smoothing layer may, for example, contain a non-crystalline (i.e., amorphous or partially amorphous) oxide. Particularly suitable are oxides of one or more of the elements tin, silicon, titanium, zirconium, hafnium, zinc, gallium and indium, for example, mixed tin-zinc oxide. The smoothing layer can, for example, have a thickness of 3 nm to 20 nm. The dielectric layer may also contain, for example, in addition to said single layer made of a dielectric material, at least one complementary layer, which contains, for example, zinc oxide and has, for example, a thickness of 3 nm to 20 nm. The optical properties of the composite glazing are further enhanced by the complementary layers.
    [0032] In an advantageous embodiment, the infrared protective coating is tempered. For this, the infrared protective coating is subjected to a temperature treatment. The infrared protective coating is preferably heated to a temperature of at least 200 ° C, particularly preferably at least 300 ° C. Such temperature treatment influences, in particular, the crystallinity, in particular, of the functional layer and results in improved transmittance in the visible spectral range. If the protective infrared coating is applied to the outer pane of a curved composite pane, the temperature treatment can take place within the curving process of the outer pane, which is typically carried out at elevated temperatures of, for example, 500 ° C to 700 ° Ç.
    [0033] The functional element may, in principle, be any switchable functional element known to the person skilled in the art. The invention is, of course, advantageous in particular in conjunction with those functional elements that age under irradiation with infrared radiation.
    [0034] In an advantageous embodiment of the invention, the active layer of the functional element is an electrochemically active layer. Such functional elements are known as electrochromic functional elements. The transmittance of visible light depends on the level of storage of the ions in the active layer, with the ions being provided, for example, by an ion storage layer between the active layer and the plate element. Transmittance can be influenced by the voltage applied to the plate electrodes that trigger an ion migration. Suitable functional layers contain, for example, at least tungsten oxide or vanadium oxide. Electrochromic functional elements are known, for example, from WO 2012007334 A1, US 20120026573 A1, WO 2010147494 A1 and EP 1862849 A1.
    [0035] In another advantageous embodiment of the invention, the active layer of the functional element contains liquid crystals which are embedded, for example, in a polymeric matrix. Such functional elements are known as PDLC (liquid crystal dispersed in polymer) functional elements. When no voltage is applied to the plate electrodes, the liquid crystals are randomly oriented, which results in strong scattering of light passing through the active layer. When a voltage is applied to the plate electrodes, the liquid crystals are oriented in a common direction and the transmittance of light through the active layer is increased. Such a functional element is known, for example, from DE 102008026339 A1.
    [0036] In another advantageous embodiment of the invention, the functional element is an electroluminescent functional element. In this case, the active layer contains electroluminescent materials, which can be inorganic or organic (OLEDs). By applying a voltage to the plate electrodes, the luminescence of the active layer is stimulated. Such functional elements are known, for example, from US 2004227462 A1 and WO 2010112789 A2.
    [0037] In another advantageous embodiment of the invention, the active layer of the functional element contains suspended particles, with the absorption of light by the variable active layer by applying a voltage over the plate electrodes. Such functional elements are known as SPD (suspended particle device) functional elements, for example, from EP 0876608 B1 and WO 2011033313 A1.
    [0038] SPD functional elements are particularly preferred within the scope of the invention. Surprisingly, it has been shown that SPD functional elements can be very particularly effectively protected against aging by an infrared protective coating according to the invention.
    [0039] Naturally, the functional element may have, in addition to the active layer and the plate electrodes, other layers known by itself, for example, barrier layers, blocking layers, anti-reflective layers, protective layers and / or smoothing layers.
    [0040] The area of the functional element can equal the area of the composite glazing. Then, an advantageous uniform browning of the composite glazing is achieved by means of the switchable functional element. The lateral edges of the composite glazing are then preferably provided with an adequate seal in order to protect the functional element against corrosion. However, the composite glazing may, alternatively, also have a circumferential edge region, which is not provided with the functional element, particularly if this edge region is covered by fasteners, structures or impressions. The functional element is then advantageously protected against corrosion within the intermediate layer.
    [0041] The inner and / or outer plate electrodes are preferably designed as transparent, electrically conductive layers. The plate electrodes preferably contain at least one metal, a metal alloy or a transparent conductive oxide (TCO). Plate electrodes may, for example, contain plate, gold, copper, nickel, chromium, tungsten, tin indium oxide (ITO), gallium-doped or aluminum-doped zinc oxide, and / or fluorine-doped tin oxide or doped-antimony. The plate electrodes preferably have a thickness of 200 nm at 2 pm.
    [0042] The outer pane and / or the inner pane preferably contain unwanted glass, partially intended or intended, particularly preferable flat glass, float glass, quartz glass, borosilicate glass, sodium-calcium glass or transparent plastics, particularly preferable rigid transparent plastics, in particular polyethylene, polypropylene, polycarbonate, polymethyl methacrylate, polystyrene, polyamide, polyester, polyvinyl chloride and / or mixtures thereof. The outer pane and / or the inner pane can be clear and transparent and have, for example, transmittance of at least 70% in the visible spectral range, preferably at least 85%. However, the outer pane and / or the inner pane can also be dyed or colored and have, for example, 20% to 70% transmittance in the visible spectral range.
    [0043] The thickness of the external pane and the internal pane can vary widely and thus be adapted to the requirements in the individual case. The outer pane and / or the inner pane preferably have thicknesses from 0.5 mm to 15 mm, particularly preferable from 1 mm to 5 mm and, most particularly particularly, from 1.5 mm to 3 mm, for example, 1.6 mm, 1.8 mm or 2.1 mm.
    [0044] The area of the composite glazing according to the present invention can vary widely, for example, from 100 cm2 to 20 m2. Preferably, the composite glazing has an area of 400 cm2 to 6 m2, as is customary for motor vehicle glazing and structural and architectural glazing. The composite pane can have any three-dimensional shape. The composite glazing is preferably flat or slightly or greatly curved in one or a plurality of spatial directions.
    [0045] The outer pane, the inner pane and / or the intermediate layer films may have other suitable coatings known to you, for example, anti-reflective coatings, non-sticky coatings, scratch resistant coatings, photocatalytic coatings or radiation reflective coatings (low-E coatings).
    [0046] The transmittance of the infrared protective coating according to the present invention in the visible spectral range from 400 nm to 750 nm is preferably greater than or equal to 65%, particularly preferably greater than or equal to 70% (in particular if the infrared protective coating is tempered).
    [0047] The average transmittance of the infrared protective coating, according to the present invention, in the infrared spectral range from 800 nm to 2000 nm, is preferably less than or equal to 10%, particularly preferable less than or equal to 5 %.
    [0048] The average transmittance of the infrared protective coating according to the present invention in the near-infrared range of 800 nm to 900 nm is preferably less than or equal to 15%, particularly preferable less than u equal to 10%, most particularly preferable less than or equal to 5% and, in particular, less than or equal to 3%.
    [0049] The transmittance of the infrared protective coating can be determined by measuring the transmittance of the substrate (for example, the outer pane or the coating film) provided with the protective coating and correcting it with the transmission of the uncoated substrate . The transmittance of the uncoated substrate can be measured on the same substrate before coating or on an identically designed substrate.
    [0050] The purpose of the invention is further accomplished by a method to produce a composite glazing according to the invention with electrically switchable optical properties, in which at least a) the infrared protective coating is applied on the inner surface of the outer pane or a surface of the first carrier film, b) the intermediate layer with the switchable functional element is arranged laminarly between the external pane and the internal pane, and c) the external pane is connected to the internal pane via the intermediate layer.
    [0051] In an advantageous embodiment, the infrared protective coating is heated after the process step (a) to a temperature of at least 200 ° C, preferably at least 300 ° C, in order to improve the transmittance in the range visible spectral.
    [0052] The application of the infrared protective coating is done by methods known to you, preferably by cathodic sublimation assisted by a magnetic field. This is particularly advantageous with respect to the simple, fast, economical and uniform coating of the substrate. Cathodic sublimation is done in a protective gas atmosphere, for example, argon, or in a reactive gas atmosphere, for example, by adding oxygen or nitrogen. However, the infrared protective coating can also be applied by other methods known to the person skilled in the art, for example, by vapor deposition or chemical vapor deposition (CVD), by plasma enhanced chemical vapor deposition (PECVD) or by wet chemical methods.
    [0053] In the process step (b), the functional element is preferably inserted between at least one first thermoplastic adhesive film and at least one second thermoplastic adhesive film. The functional element is preferably arranged as a pre-laminated functional element between a first and a second carrier film. The pre-laminated functional element is produced by having the first carrier film, the outer plate electrode, the active layer, the inner plate electrode and the second carrier film laminarly on top of each other and joining them together under the action heat, vacuum and / or pressure.
    [0054] The electrical contact of the plate electrodes is preferably made before the connection of the external pane and the internal pane forms the composite pane or before the connection of the carrier films to the functional element.
    [0055] The processing step (c) is preferably carried out under the action of heat, vacuum and / or pressure. Methods known to you for producing a composite glazing can be used, for example, autoclaving methods, vacuum bag methods, vacuum ring methods, calendering methods, vacuum laminators or combinations thereof.
    [0056] The composite glazing, according to the present invention, is preferably used in buildings, in particular in the access region or window or in means of transport for movement on land, in the air or in the water, in particular on trains, ships and motor vehicles, for example, such as a rear window, side window and / or roof panel.
    [0057] The composite glazing according to the present invention can be connected to another glazing to form an insulating glazing unit.
    [0058] The invention furthermore includes the use of an infrared protective coating according to the present invention, which contains at least three functional layers with reflective properties in the infrared range, in a composite glazing with switchable optical properties, for protection of a functional element switchable against infrared radiation.
    [0059] The invention is explained in detail with reference to the exemplary designs and embodiments. The drawings are schematic representations and are not in true scale. The drawings in no way limit the invention. They represent: Fig. 1, a cross section through a first embodiment of the composite glazing according to the present invention, with electrically switchable optical properties, Fig. 2, an enlarged view of the detail Z of Fig. 1, A Fig. 3, a cross section through another embodiment of the composite glazing according to the present invention, Fig. 4, a cross section through another embodiment of the composite glazing according to the present invention, Fig. 5, the transmittance of an infrared corrective coating, according to the invention and according to the prior art, using a diagram. Fig. 6, an exemplary embodiment of the method according to the present invention, using a flowchart, Fig. 7, another exemplary embodiment of the method according to the present invention, using a flowchart, and Fig. 8, another exemplary embodiment of the method according to the present invention, using a flow chart.
    [0060] Fig. 1 and Fig. 2 each represent a detail of an embodiment of the composite glazing according to the present invention, with electrically switchable optical properties. The composite glazing includes an external glazing 1, which is connected to an internal glazing 2, via an intermediate layer 11. The composite glazing is provided as a rear window of a motor vehicle and is arranged in the installed position, so that the external glazing 1 faces the external environment and the internal window 2 faces the interior of the motor vehicle. The outer pane 1 and the inner pane 2 are made of soda lime glass and are 1.6 mm thick.
    [0061] A switchable functional element 4 is embedded in the middle layer 11.0 functional element 4 is an SPD functional element with an active layer 5 between an outer plate electrode 6 and an inner plate electrode 7. The plate electrodes 6, 7 are connected to an external power supply, via busbars (not shown) and connecting cables (not shown). Plate electrodes 6, 7 are made of tin indium oxide (ITO) and are less than 1 pm thick. The active layer 5 contains polarized particles, suspended in a resin. As a function of the voltage applied to the plate electrodes 6, 7, the suspended particles are oriented along a common spatial direction. Through the orientation of the particles, the absorption of visible light is reduced. Consequently, the transmittance of visible light through the composite glazing can be conveniently controlled electrically.
    [0062] Functional element 4 was provided when the composite glazing was produced as a pre-laminated functional element 8. The pre-laminated functional element 8 comprises functional element 4 between a first carrier film 9 and a second carrier film 10. The carrier films 9, 10 are made of polyethylene terephthalate (PET) and have a thickness of 0.125 mm.
    [0063] The pre-laminated functional element 8 is connected to the outer pane 1 via a first thermoplastic adhesive film 12 and to the inner pane 2 via a second thermoplastic adhesive film 13. Thermoplastic adhesive films 12, 13 are made of ethylene vinyl acetate ( EVA) and have a thickness of 0.38 mm in each case. The intermediate layer 11 thus comprises the first thermoplastic adhesive film 12, the pre-laminated functional element 8 (with the first carrier film 9, the outer plate electrode 6, the active layer 5, the inner plate electrode 9 and the second film carrier 10) and the second thermoplastic adhesive film 13.
    [0064] To avoid damage to the active layer 5 of the functional element 4 of the infrared radiation, an infrared protective coating 3 is applied on the inner surface of the outer pane 1. The infrared radiation component of sunlight, penetrating into the composite pane via the outer pane 1 is reflected by the infrared protective coating 3 before it can hit the active layer 5.
    [0065] The infrared protective coating 3 comprises four dielectric layers 15 and three functional layers 14, which are applied alternatively on the outer pane, so that each functional layer 14 is arranged between two dielectric layers 15 and the adjacent functional layers 14 are separated in each case by a dielectric layer 15. The functional layers 14 are made of silver (with possible production related impurities) and have, for example, a layer thickness of approximately 15 nm. The dielectric layers 15 contain, in the simplest embodiment, in each case, a single layer of a dielectric material, for example, silicon nitride. Those single layers of a dielectric material that are arranged between two functional layers 14 have, for example, in each case, a layer thickness of approximately 50 nm. The only top and bottom layers of a dielectric material have, for example, a layer thickness of 25 nm in each case. However, the dielectric layers 15 may also contain in each case two or more unique layers of different materials.
    [0066] The infrared protective coating 3, according to the present invention, with the three functional layers 14, has high transmittance in the visible spectral range. In the infrared range, the infrared protective coating 3 has high reflectance and low transmittance. In particular, in the near-infrared range, reflectance is significantly improved compared to a known infrared protective coating with only one or two functional layers. Thus, functional element 4 is significantly more effectively protected against aging.
    [0067] After application on the external glass 1, the infrared protective coating 3 was subjected to a temperature treatment. The outer pane 1, with the infrared protective coating 3, has been heated, for example, to at least 300 ° C. In particular, the crystallinity of the functional layers 14 is improved by the temperature treatment. Thus, the transmittance of visible light and the reflective properties related to infrared radiation are significantly improved.
    [0068] Fig. 3 represents a cross section through another embodiment of the composite glazing according to the present invention, with electrically switchable optical properties. The outer pane 1, the inner pane 2, the thermoplastic adhesive films 12, 13, the carrier films 9, 10 and the functional element 4 are configured as in Fig. 1. The infrared protective coating 3 is applied to the surface of the first film carrier 9 facing away from the functional element 4 and thus arranged in the composite glazing between the first thermoplastic adhesive layer 12 and the first carrier film 9. With an infrared protective coating thus positioned 3, the aging of the active layer 5 can also be effectively avoided.
    [0069] Alternatively, the infrared protective coating 3 can also be applied to the first thermoplastic adhesive film 12. It is also alternatively possible to apply the infrared protective coating 3 to another film that is inserted between the first thermoplastic adhesive layer 12 and the carrier film. 9 during production of the composite glazing.
    [0070] Fig. 4 represents a cross section through another embodiment of the composite glazing according to the present invention, with electrically switchable optical properties. The infrared protective coating 3 is applied to the surface of the first carrier film 9 facing the active layer 5. The infrared protective coating 3, which is itself electrically conductive, serves simultaneously as the outer plate electrode 6. This simplifies production of the composite glazing. For this reason, the infrared protective coating 3 is connected to the external power supply via a bus and a connection cable (not shown). In addition, the infrared protective coating 3 is advantageously protected against corrosion and other damage within the pre-laminated functional element 8. Consequently, the pre-laminated functional element 8, with the integrated infrared protective coating 3, can be prepared in relatively large quantities before the production of the composite glazing.
    [0071] Alternatively, of course, another layer made, for example, of tin indium oxide, can be applied to the protective infrared coating 3 as the outer plate electrode 6.
    [0072] Fig. 5 represents a diagram of transmittance through a composite pane with an infrared protective coating 3 according to the invention. The infrared protective coating 3 was applied to the inner surface of the external glass 1 and consisted of three functional layers 14 made of silver. The infrared protective coating 3 was hardened. The diagram also represents the transmittance through a composite pane with an infrared protective coating according to the prior art, which contained only two functional layers made of silver and which were applied to another thermoplastic film made of PET inserted in the intermediate layer. For a better comparison of the transmittance of the infrared protective coatings, composite glazing has no functional element 4. It is clearly discernible that the infrared protective coating 3, according to the invention, has a lower transmittance in the infrared radiation range, in particular even in the near infrared range. Consequently, a functional element 4 is better protected against aging due to infrared radiation by an infrared protective coating 3, according to the present invention.
    [0073] Fig. 6 represents an exemplary embodiment of the method according to the invention, to produce a composite glazing with electrically switchable optical properties. The exemplary embodiment results in a composite glazing according to the invention according to Fig. 1. First, an infrared protective coating 3 is applied on the inner surface of the outer glazing 1. Then, the coated outer glazing 1 is subjected to a temperature treatment at 300 ° C. The switchable functional element 4 contains an active layer 5 between an outer plate electrode 6 and an inner plate electrode 7. The switchable functional element 4 is provided as a pre-laminated functional element 8 between a first carrier film 9 and a second film carrier 10. An internal glazing 2, a second thermoplastic adhesive film 13, the pre-laminated functional element 8, a first thermoplastic adhesive film 12 and the outer glazing 1 are laminated on top of each other in the indicated order and then laminated under the action temperature, pressure and / or vacuum to form the composite glazing.
    [0074] Fig. 7 represents an exemplary embodiment of the method according to the present invention for producing a composite glazing with electrically switchable optical properties. The exemplary embodiment results in a composite glazing according to the present invention according to Fig. 3. The switchable functional element 4 contains an active layer 5 between an outer plate electrode 6 and an inner plate electrode 7. O switchable functional element 4 is provided as a pre-laminated functional element 8 between a first carrier film 9 and a second carrier film 10. An infrared protective coating 3 is applied to the surface of the first carrier film 9 facing away from the functional element 4. An internal pane 2, a second thermoplastic adhesive film 13, the pre-laminated functional element 8, a first thermoplastic adhesive film 12 and an external pane 1 are laminated on top of each other in the indicated order and then laminated under the action of temperature, pressure and / or vacuum to form the composite glazing.
    [0075] Fig. 8 represents an exemplary embodiment of the method according to the present invention, to produce a composite glazing with electrically switchable optical properties. The exemplary embodiment results in a composite glazing according to the invention, according to Fig. 4. First, an infrared protective coating 3 is applied to the surface of a first carrier film 9. The first carrier film 9, a layer active 5, an inner plate electrode 7 and a second carrier film 10 are laminarly arranged on top of each other in the order indicated, so that the infrared protective coating 3 faces the active layer 5. The infrared protective coating 3 serves as the external plate electrode 6 and is suitably electrically contacted for this purpose. The first carrier film 9 as an infrared protective coating 3, the active layer 5, the inner plate electrode 7 and the second carrier film 10 are connected under the action of temperature, pressure and / or vacuum to form a pre-laminated functional element 8. Then, an internal pane 2, a second thermoplastic adhesive film 13, the pre-laminated functional element 8, a second thermoplastic adhesive film 12 and an external pane 1 are laminated on top of each other in the indicated order and then laminated under action of temperature, pressure and / or vacuum to form the composite glazing. Example
    [0076] A composite glazing, according to the present invention, with electrically switchable optical properties according to Fig. 1, has been produced. The infrared protective coating 3 was subjected, after application to the internal surface of the external glass 1, to a temperature treatment. For this purpose, the coated outer pane 1 was heated for 7 minutes at a temperature of 640 ° C. Then, the outer pane 1 with the infrared protective coating 3, the pre-laminated functional element 8 and the inner pane 2 were laminated, via the first thermoplastic adhesive film 12 and the second thermoplastic adhesive film 13, at a temperature of approximately 120 ° C and a pressure of approximately 0.2 MPa (2 bar), to form the composite glazing.
    [0077] The composite glazing was subjected to a standardized WeatherOmeter (WOM) Test. The composite pane was irradiated for 800 hours with a xenon arc lamp, whose radiation simulates the solar spectrum. The outer pane 1 was arranged facing the light source. After irradiation, the ΔE value indicates the changes in brightness and color of the composite glazing, due to the WOM Test. It is calculated using the following formula:
    L * is the brightness value, a * and b * are the color coordinates in the Color Space L * a * b *. Δ refers to the difference of the respective variable before and after the WOM Test. COMPARATIVE EXAMPLE 1
    [0078] Comparative Example 1 was performed exactly like the Example. The difference was in the infrared protective coating 3. The infrared protective coating 3 consisted, according to the prior art, of only two functional layers made of silver. The infrared protective coating 3 was also not applied to the outer glazing 1, but instead to the other thermoplastic film made of PET, which was inserted between the first thermoplastic adhesive layer 12 and the pre-laminated functional element 8 of the compound ( Southwall XIR-75 PET). The composite glazing was subjected to the same WOM Test. The ΔE value determined below is shown in Table 1. COMPARATIVE EXAMPLE 2
    [0079] Comparative Example 2 was performed exactly like the Example. However, unlike the Example, the composite glazing had no protective infrared coating 3. The composite glazing was subjected to the same WOM Test. The ΔE value determined below is shown in Table 1.

    [0080] It can be discerned from Table 1 that the infrared protective coating 3, according to the present invention, results in substantially reduced aging of the functional element 4. The protection of the functional element 4 is substantially improved compared to a common composite glazing infrared protective coating, according to the prior art. This result was unexpected and surprising for the person skilled in the art. List of Reference Characters (1) outer pane (2) inner pane (3) infrared protective coating (4) switchable functional element (5) active layer of functional element 4 (6) outer plate electrode of functional element 4 (7 ) inner plate electrode of functional element 4 (8) pre-laminated functional element (9) first film bearing the pre-laminated functional element 8 (10) second film carrying the pre-laminated functional element 8 (11) intermediate layer (12 ) first thermoplastic adhesive film (13) second thermoplastic adhesive film (14) functional layer with reflective properties in the infrared range (15) dielectric layer (16) Z detail of composite glazing
    权利要求:
    Claims (16)
    [0001]
    1. Composite glazing with electrically switchable optical properties, characterized by the fact that it comprises an external glazing (1) and an internal glazing (2), which are laminarly connected to each other via an intermediate layer (11), and within the intermediate layer ( 11), a pre-laminated functional element (8) including, a) a switchable functional element (4) containing a1) at least one active layer (5), a2) an infrared protective coating (3) containing at least three functional layers (14) with reflective properties for the infrared band, the infrared protective coating (3) being an outer plate electrode (6), and a3) an inner plate electrode (7), b) a first film carrier (9), and c) a second carrier film (10), in which the protective infrared coating (3) is laminarly disposed between the outer pane (1) and the active layer (5), in which the switchable functional element ( 4) is laminarly disposed between the first film p carrier (9) and the second carrier film (10), and wherein the first carrier film (9) is attached to the outer pane (1) at least via a first thermoplastic adhesive film (12) and the second carrier film (10) it is connected to the internal pane (2) at least via a second thermoplastic adhesive film (13), in which the protective infrared coating (3) is laminarly disposed on the surface of the first carrier film (9) facing at least one active layer, wherein the at least one active layer is laminarly disposed between the outer plate electrode (6) and the inner plate electrode (7), where the pre-laminated functional element (8) is a pre-laminated functional element previously prepared with integrated infrared protective coating (3), and in which the composite glazing has an edge region that is devoid of the infrared protective coating.
    [0002]
    2. Composite glazing according to claim 1, characterized by the fact that the switchable functional element (4) is a suspended particle device (SPD) functional element.
    [0003]
    3. Composite glazing according to claim 1, characterized by the fact that the functional layers (14) contain at least one metal.
    [0004]
    4. Composite glazing according to claim 1, characterized by the fact that each functional layer (14) has a thickness of 5 nm to 50 nm.
    [0005]
    5. Composite glazing according to claim 1, characterized by the fact that each functional layer (14) is arranged between two dielectric layers (15), which contain at least one oxide or nitride.
    [0006]
    6. Composite glazing according to claim 1, characterized by the fact that the outer glazing (1) and / or the inner glazing (2) contains non-prestressed, partially prestressed or intended glass.
    [0007]
    7. Composite glazing according to claim 1, characterized by the fact that the average transmittance of the infrared protective coating (3) in the spectral range from 800 nm to 900 nm is less than or equal to 15%.
    [0008]
    8. Method for producing a composite glazing as defined in claim 1, characterized by the fact that it comprises: a) providing the pre-laminated functional element (8) previously prepared, b) arranging the intermediate layer (11) with the switchable functional element pre-laminated previously prepared laminarly between the outer pane (1) and the inner pane (2), and c) connect the outer pane (1) to the inner pane (2) via the intermediate layer (11), in which the element supply pre-laminated functional (8) previously prepared includes applying the protective infrared coating (3) to a surface of the first carrier film (9) during the preparation of the pre-laminated functional element (8) previously prepared.
    [0009]
    9. Method according to claim 8, characterized in that the preparation of the pre-laminated functional element (8) previously prepared also includes heating the infrared protective coating (3) after the application of the infrared protective coating (3) to a temperature of at least 200 ° C.
    [0010]
    10. Composite glazing according to claim 3, characterized by the fact that the functional layers contain silver.
    [0011]
    11. Composite glazing according to claim 4, characterized by the fact that each functional layer has a thickness from 8 nm to 25 nm.
    [0012]
    12. Composite glazing according to claim 5, characterized by the fact that each functional layer is disposed between two dielectric layers, containing silicon nitride.
    [0013]
    13. Composite glazing according to claim 6, characterized by the fact that the outer glazing (1) and / or the inner glazing (2) contains flat glass, float glass, quartz glass, borosilicate glass, sodium-calcium glass , polyethylene, polypropylene, polycarbonate, polymethyl methacrylate, polystyrene, polyamide, polyester or polyvinyl chloride
    [0014]
    14. Composite glazing according to claim 6, characterized in that the outer glazing (1) and / or the inner glazing (2) has a thickness of 0.5 mm to 15 mm.
    [0015]
    15. Composite glazing according to claim 6, characterized in that the outer glazing (1) and / or the inner glazing (2) have a thickness of 1 mm to 5 mm.
    [0016]
    16. Composite glazing according to claim 7, characterized by the fact that the average transmittance of the infrared protective coating (3) in the spectral range from 800 nm to 900 nm is less than or equal to 10%.
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    同族专利:
    公开号 | 公开日
    EA201590418A1|2015-06-30|
    EP2888106B1|2021-10-27|
    CN104582956A|2015-04-29|
    KR20150043428A|2015-04-22|
    JP6157623B2|2017-07-05|
    PL2888106T3|2022-01-24|
    CA2881175A1|2014-02-27|
    CA2881175C|2019-06-25|
    JP2015529183A|2015-10-05|
    EA028935B1|2018-01-31|
    WO2014029536A1|2014-02-27|
    EP2888106A1|2015-07-01|
    MX2015002193A|2015-04-10|
    CN104582956B|2018-12-28|
    US20150331296A1|2015-11-19|
    US10082716B2|2018-09-25|
    BR112015002977A2|2018-06-12|
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    法律状态:
    2018-06-26| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|
    2019-11-26| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|
    2020-08-04| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|
    2020-11-10| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 28/06/2013, OBSERVADAS AS CONDICOES LEGAIS. |
    优先权:
    申请号 | 申请日 | 专利标题
    EP12181122|2012-08-21|
    EP12181122.8|2012-08-21|
    PCT/EP2013/063629|WO2014029536A1|2012-08-21|2013-06-28|Composite panel with electrically switchable optical properties|
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