COSMETIC TREATMENT PROCESS

专利摘要:
cosmetic treatment process. the present invention deals with a process for the cosmetic treatment of keratin fibers, preferably hair, which comprises at least the steps consisting of: ? a) applying, on said keratin fibers, a composition containing at least one substance chosen from fatty substances, non-silicone polymers and surfactants, ? b) apply a mechanical tension on said keratin fibers, and ? c) expose said keratin fibers under mechanical tension to microwaves, at a pressure ranging from 50,000 to 250,000 pa, in the presence of at least one solvent in vapor form in contact with the keratin fibers and without drying complete keratin fiber during the entire microwave exposure, ? the solvent(s) in vapor form are entirely generated by the evaporation of at least one compound present, before microwave emission, in contact with the keratin fibers, ? step a) takes place before step c).
公开号:BR112014030153B1
申请号:R112014030153-0
申请日:2013-06-06
公开日:2021-07-13
发明作者:Gabin Vic；Maryse Chaisy；Stefania NUZZO
申请人:L'oreal；
IPC主号:

专利说明:

[001] The present invention deals with the field of treatment processes for keratin fibers, preferably hair. BACKGROUND OF THE INVENTION
[002] Cosmetic treatments for long-lasting hair styling are mainly carried out using chemical products.
[003] Two techniques, both based on the rupture of the disulfide bonds -S-S- present in keratin (cystine), are generally used to obtain a permanent deformation of the hair.
[004] The first technique comprises a first step consisting in opening the disulfide bonds by means of a composition comprising a reducing agent, for example, of the thioglycolic acid type. This first reduction step is usually carried out at a pH between 8 and 9.
[005] This first technique comprises, then, preferably after rinsing the hair, a second step that consists of reconstituting the disulfide bonds by applying an oxidizing composition called fixative on the hair. The hair can, before applying the reducing composition, be tensioned by suitable devices such as rollers or straightened. The oxidation step, in particular, can be carried out at a pH of approximately 3 with hydrogen peroxide and can facilitate the formation of new disulfide bridges that allow the hair to be kept in the desired shape.
[006] The second technique comprises a lantionization step that uses a composition comprising a base belonging to the hydroxide family. The lanthionization step is generally carried out at a basic pH of approximately 13. Lanthionization is the transformation of disulfide bridges into monosulfide bridges. This type of treatment is mainly used for styling naturally frizzy hair.
[007] In order to obtain satisfactory performances in terms of modeling durability, the compositions used in treatments known from the state of the art can contain relatively high concentrations of chemical actives (reducing agents or hydroxy compounds, for example). Thus, thioglycolic acid can, for example, be used, in certain compositions, in mass concentrations comprised between 6 and 11% and 2% sodium hydroxide.
[008] Products that contain thioglycolic acid have an unpleasant odor, which may be present during application and may also remain in the hair after the treatment has been carried out.
[009] Furthermore, the treatments described above can lead to an irreversible hair degradation induced by modifications of the intrinsic properties of the hair fiber.
[010] These treatments can also irritate the scalp due to their relatively high concentration of chemical actives.
[011] It is, on the other hand, known practice to provide heat during treatment in order to activate the processes. These technologies can effectively improve cosmetic performance, but they always involve high concentrations of chemical actives and can, therefore, present the same drawbacks as the treatments described above.
[012] The documents WO 2002051281, US 20060042649, US 20050250830, WO 2002100210, US 2000680432, US 6079422, US 5988182, US 5819763, US 5773802, US 5676871, JP 09075 125, JP 09051813, AU 9664467, US 5494598, EP 197824 US 4710609, US 4743726, US 4952360, US 5030820, US 5286949 describe objects, for example rollers, which can be heated in a domestic microwave oven, and used on wet hair for drying and styling.
[013] The patent US 3958340 describes a process of fast drying wigs by means of air heated by microwave radiation.
[014] The application US 20070056960 describes a shaping tool that allows you to curl, straighten and dry locks of wet hair by means of microwaves.
[015] Patent DE 3148538 describes a cylindrical tool, protected by a wall, around which a lock of hair is wrapped. The wick is dried and shaped using microwaves applied in the space between the cylinder and the wall.
[016] They are known through FR 2 178 049 devices for releasing electromagnetic energy in various materials.
[017] In addition, heating and drying processes of hair by using an electromagnetic radiation are known from FR 2 114 540 and FR 2 118 945.
[018] Application FR 2 959 917 describes a hair treatment process in which a mechanical tension is applied to the hair, which is then exposed to microwaves.
[019] There is a need to have new processes, more effective and less aggressive, permanent deformation of hair.
[020] There is, in particular, an interest in having processes that allow to obtain improved lasting styling performances, and which at the same time minimize the impact of chemicals on the hair and scalp.
[021] There is also a need for new durable hair styling devices.
[022] The present invention proposes to meet all or part of the stated needs. According to a first aspect, the present invention deals with a process for the cosmetic treatment of keratin fibres, preferably hair, which comprises at least the steps consisting of: a) applying, on said keratin fibres, a composition containing at least one substance chosen from fatty substances, non-silicone polymers and surfactants, b) applying a mechanical stress to said keratin fibers, and c) exposing said keratin fibers under mechanical stress to microwaves, at a pressure ranging from 50 000 to 250 000 Pa, in the presence of at least one solvent in vapor form in contact with the keratin fibers and without complete drying of the keratin fibers during the entire exposure to microwaves, with the solvent(s) in Vapor form are entirely generated by the evaporation of at least one compound present, before microwave emission, in contact with the keratin fibers, and step a) occurs and before step c).
[023] In the present text, the expression solvent is used to designate indifferently a single solvent or a mixture of solvents.
[024] The process according to the present invention can be carried out in order to lead to a lasting less aggressive styling treatment for the scalp and hair. In fact, the process according to the present invention dispenses with the use of aggressive compounds for the scalp.
[025] In addition, the application to the hair of a composition that contains at least one substance chosen from fatty substances, non-silicone polymers and surfactants, preferably before the application of mechanical tension, in the presence of microwaves and of a solvent in the form of vapor allows to obtain a lasting and improved styling of the hair without the need to use reducing agents or alkaline or alkaline-earth hydroxides.
[026] In particular, the process according to the present invention can use in step a) a composition containing at least one fatty substance or a composition containing at least one non-silicone polymer or a composition containing at least one surfactant.
[027] Thus, according to an embodiment, the present invention aims at a process of cosmetic treatment of keratin fibers, preferably hair, which comprises at least the steps consisting of: c) applying, on said keratin fibers , a composition containing at least one grease substance, d) applying mechanical stress to said keratin fibers, and e) exposing said keratin fibers under mechanical stress to microwaves at a pressure ranging from 50,000 to 250,000 Pa, in the presence of at least one solvent in vapor form in contact with the keratin fibers and without complete drying of the keratin fibers during the entire exposure to microwaves, the solvent(s) in vapor form are entirely generated by the evaporation of at least one compound present, before microwave emission, in contact with the keratin fibers, and step a) occurs before step c).
[028] According to another embodiment, the present invention aims at a process of cosmetic treatment of keratin fibers, preferably hair, which comprises at least the steps consisting of: f) applying, on said keratin fibers, a composition containing at least one non-silicone polymer, g) applying mechanical stress to said keratin fibers, and h) exposing said keratin fibers under mechanical stress to microwaves at a pressure ranging from 50,000 to 250,000 Pa, in presence of at least one solvent in vapor form in contact with the keratin fibers and without complete drying of the keratin fibers during the entire exposure to microwaves, the solvent(s) in vapor form are entirely generated by the evaporation of hair less one compound is present, before microwave emission, in contact with the keratin fibers, and step a) occurs before step c).
[029] According to one more embodiment, the present invention aims at a process for the cosmetic treatment of keratin fibers, preferably hair, which comprises at least the steps consisting of: i) applying, on said keratin fibers, a composition containing at least one surfactant, j) applying mechanical stress to said keratin fibers, and c) exposing said keratin fibers under mechanical stress to microwaves at a pressure ranging from 50,000 to 250,000 Pa, in presence of at least one solvent in vapor form in contact with the keratin fibers and without complete drying of the keratin fibers during the entire exposure to microwaves, the solvent(s) in vapor form are entirely generated by the evaporation of at least a compound present, before microwave emission, in contact with the keratin fibers, and step a) occurs before step c).
[030] In a particular variant of the present invention, the process according to the present invention does not comprise a step of application on keratin fibers, of composition(s) comprising alkaline or alkaline earth hydroxides at a pH greater than 12 or reducing agents that allow the breakdown of disulfide bonds.
[031] The process according to the present invention allows to obtain the desired modeling: curling or smoothing. The effect is achieved lasting for several weeks. When the process according to the present invention is carried out to obtain a undulation, the undulation obtained is regular. A hairstyle (hair) volume gain is also observed.
[032] The expressions "which comprise a (a)", "which comprises a (a)", "which contains (has) a (a)" should be understood as "which includes a at least one", "which comprises at least one", "which contains at least one".
[033] The expression “at least one” is equivalent to the expression “one or more”.
[034] The expression “understood between” should be understood with the limits included. STEP A)
[035] The cosmetic hair treatment process according to the present invention comprises, in particular, a step a) which comprises the application of a composition containing at least one substance chosen from fatty substances, non-silicone polymers and the surfactants.
[036] Advantageously, the composition used in step a) is an aqueous composition, that is, it comprises at least 5% by weight of water relative to the total weight of the composition. Preferably the composition comprises from 20 to 99.9% by weight of water relative to the total weight of the composition.
[037] According to a particular preferred embodiment of the present invention, step a) is prior to step b).
[038] According to another particular embodiment of the present invention, step b) is prior to step a).
[039] According to a particularly preferred embodiment, the steps are carried out in the following steps: step a) then step b) then step c).
[040] In a particular variant of the present invention, the process according to the present invention does not comprise a step of application on keratin fibers, of composition(s) that comprise(s) alkaline or alkaline-earth hydroxides at a higher pH to 12 or reducing agents that allow the breakdown of disulfide bonds. In this variant, the composition of step a) is free of reducing agent(s) for breaking the disulfide bonds.
[041] In the sense of the present invention, by "reducing agent that allow the rupture of disulfide bonds", it is understood an agent chosen among thiols, alkaline sulfites, phosphines and hydrides.
[042] Likewise, in this variant, the composition of step a) is free of alkaline or alkaline-earth hydroxides at a pH greater than 12.
[043] By "exempt" is meant a composition comprising less than 0.5% by weight of the element considered, preferably less than 0.1% by weight relative to the total weight of the composition, more preferably the element considered is totally absent.” GREASE SUBSTANCES
[044] According to a first embodiment of the present invention, the composition of step a) is a composition containing at least one fatty substance. According to this first variant, the composition preferably comprises from 30 to 95% by weight of water relative to the total weight of the composition.
[045] Preferably said composition comprises at least one fatty substance in a content ranging from 0.1% to 95% by weight relative to the total weight of the composition.
[046] According to a particular embodiment, said fatty substance(s) are present in said composition in a content ranging from 1% to 50%, preferably from 5 to 30% by weight relative to the total weight of the composition.
[047] By "greasy substances" is meant an organic compound insoluble in water at ordinary temperature (25°C) and atmospheric pressure (760 mm Hg), that is, with a solubility of less than 5% and preferably at 1%, more preferably 0.1%. They have in their structure at least a sequence of at least two siloxanes groups or a hydrocarbon chain containing at least 6 carbon atoms. Furthermore, fatty substances are generally soluble in organic solvents under the same temperature and pressure conditions, such as, for example, chloroform, ethanol, benzene, petroleum jelly or odecamethylcyclopentasiloxane.
[048] In particular, the fatty substance(s) used in step a) are not (poly)oxyalkylenated or (poly)glycerolated(s).
[049] More particularly, the fatty substance(s) are chosen among hydrocarbons with C6-C16, hydrocarbons with more than 16 carbon atoms, non-silicone oils of animal origin, vegetable oils of the triglyceride type, synthetic triglycerides, fluorinated oils, fatty alcohols, non-salified fatty acids, fatty acid and/or fatty alcohol esters other than triglycerides and vegetable waxes, non-silicone waxes, silicones, and mixtures thereof.
[050] It is worth remembering that in the sense of the present invention, alcohols, esters and fatty acids have more particularly one or more hydrocarbon groups, linear or branched, saturated or unsaturated, comprising 6 to 30 carbon atoms, possibly substituted, in particular , by one or more hydroxyl groups (in particular, 1 to 4). If unsaturated, these compounds can comprise one to three carbon-carbon double bonds, whether conjugated or not.
[051] Preferably, the grease substance(s) used in step a) of the process according to the present invention is a non-silicone grease substance.
[052] With regard to hydrocarbons with C6-C16, they are linear, branched, eventually cyclic and preferably alkanes. By way of example, hexane, dodecane, isoparaffins such as isohexadecane, isodecane may be mentioned.
[053] As hydrocarbon oils of animal origin, perhydrosqualene can be cited.
[054] Triglyceride oils of vegetable or synthetic origin are preferably chosen from the liquid triglycerides of fatty acids that contain 6 to 30 carbon atoms such as the triglycerides of heptanoic or octanoic acids or, for example, the oils of sunflower, corn, soybean, pumpkin, grape seeds, sesame, hazelnut, apricot, macadamia, macaw, sunflower, castor, avocado, caprylic/capric acid triglycerides such as those are sold by Stearineries Dubois or those sold under the names Miglyol® 810, 812 and 818 by Dynamit Nobel, jojoba oil, shea butter oil.
[055] Linear or branched hydrocarbons, of mineral or synthetic origin, containing more than 16 carbon atoms, are preferably chosen among paraffin oils, vaseline, vaseline oil, polydecenes, hydrogenated polyisobutene such as Parleam®.
[056] Fluorinated oils can be chosen from perfluoromethylcyclopentane and perfluoro-1,3-dimethylcyclohexane, sold under the names "FLUTEC® PCI" and "FLUTEC® PC3" by BNFL Fluorochemicals; perfuoro-1,2-dimethylcyclobutane; perfluoroalkanes such as dodecafluoropentane and tetradecafluorohexane sold under the names "PF 5050®" and "PF 5060®" by 3M, or bromoperfluorooctyl sold under the name "FORALKYL®" by Atochem; nonafluoro-methoxybutane and nonafluoroethoxyisobutane; perfluoromorpholine derivatives such as 4-trifluoromethyl perfluoromorpholine sold under the name "PF 5052®" by 3M.
[057] Fatty alcohols likely to be used in the cosmetic composition of step a) are saturated or unsaturated alcohols, linear or branched, and which contain 6 to 30 carbon atoms and more particularly 8 to 30 carbon atoms, among which there may be mentioned, for example, cetyl alcohol, stearyl alcohol and its mixture (cetylstearyl alcohol or cetearyl alcohol), octyldodecanol, 2-butyloctanol, 2-hexyldecanol, 2-undecylpentadecanol, oleic alcohol or linoleic alcohol.
[058] The non-salified fatty acids likely to be used in the cosmetic composition of step a) can be saturated or unsaturated carboxylic acids and which contain from 6 to 30 carbon atoms, in particular, from 9 to 30 carbon atoms. They are chosen more particularly from myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, linoleic acid, linolenic acid and isostearic acid.
[059] These acids are not salified. This means that they are introduced in the form of free acids and that the composition does not contain an alkaline agent that causes their salification.
[060] The fatty acid and/or fatty alcohol esters, advantageously different from the triglycerides mentioned above that can be used in the cosmetic composition used in step a) are the esters of saturated or unsaturated aliphatic mono or polyacids, linear or branched with C1 -C26 and of saturated or unsaturated aliphatic mono or polyalcohols, linear or branched with C1-C26, and the total carbon number of the esters is more particularly greater than or equal to 10.
[061] Among the monoesters, dihydroabiethyl behenate can be mentioned; octyldodecyl behenate; isocetyl behenate; cetyl lactate; C12-C15 alkyl lactate; isostearyl lactate; lauryl lactate; linoleyl lactate; oleyl lactate; (iso)stearyl octanoate; isocetyl octanoate; octyl octanoate; cetyl octanoate; decyl oleate; isocetyl isostearate; isocetyl laurate; isocetyl stearate; isodecyl octanoate; isodecyl oleate; isononyl isononanoate; isostearyl palmitate; acetylmethyl ricinoleate; myristyl stearate; octyl isononanoate; 2-ethylhexyl isononate; octyl palmitate; octyl pelargonate; octyl stearate; octyldodecyl erucate; oleyla erucate; ethyl and isopropyl palmitates, ethyl-2-hexyl palmitate, 2-octyldecyl palmitate, alkyl myristates such as isopropyl, butyl, cetyl, 2-octyldodecyl, myristyl myristate, de stearyl, hexyl stearate, butyl stearate, isobutyl stearate; dioctyl malate, hexyl laurate, 2-hexyldecyl laurate.
[062] Still within the context of this variant, the esters of dicarboxylic acids or tricarboxylic acids with C4-C22 and alcohols with C1-C22 and the esters of monodicarboxylic or tricarboxylic acids and of di-, tri-, alcohols can also be used tetra- or pentahydroxy with C2-C26
[063] The following can be mentioned, in particular: diethyl sebacate; diisopropyl sebacate; diisopropyl adipate; din-propyl adipate; dioctyl adipate; diisostearyl adipate; dioctyl maleate; glyceryl undecylenate; octyldodecyl stearoyl stearate; pentaerythryl monoricinoleate; pentaerythryl tetraisononanoate; pentaerythryl tetrapelargonate; pentaerythryl tetraisostearate; pentaerythrityl tetraoctanoate; propylene glycol dicaprylate; propylene glycol dicaprate, tridecyl erucate; triisopropyl citrate; triisostearyl citrate; glyceryl trilactate; glyceryl trioctanoate; trioctyldodecyl citrate; trioleyl citrate, propylene glycol dioctanoate; neopentyl glycol diheptanoate; diethylene glycol diisanonate; and polyethylene glycol distearates.
[064] Among the esters mentioned above, preferably the palmitates of ethyl, isopropyl, myristyl, cetyl, stearyl, palmitate of ethyl-2-hexyl, palmitate of 2-octyldecyl, myristates are used. from alkyls such as isopropyl, butyl, cetyl, 2-octyldodecyl myristate, hexyl stearate, butyl stearate, isobutyl stearate; dioctyl malate, hexyl laurate, 2-hexyldecyl laurate and isononyl isononanoate, cetyl octanoate.
[065] The composition used in step a) of the process according to the present invention may also comprise, as fatty ester, esters and diesters of fatty acid sugars with C6-C30, preferably with C12-C22. It should be remembered that the term “sugar” designates oxygenated hydrocarbon compounds that have several alcohol functions, with or without an aldehyde or ketone function, and that contain at least 4 carbon atoms. These sugars can be monosaccharides, oligosaccharides or polysaccharides.
[066] As suitable sugars, there may be mentioned, for example, sucrose (or sucrose), glucose, galactose, ribose, fucose, maltose, fructose, mannose, arabinose, xylose, lactose , and particularly alkylated derivatives thereof, such as methylated derivatives such as methylglucose.
[067] The esters of sugars and fatty acids can be chosen, in particular, from the group comprising the esters or mixtures of esters of sugars described above and of fatty acids with C6-C30, preferably in C12-C22, linear or branched, saturated or unsaturated. If unsaturated, these compounds can comprise one to three carbon-carbon double bonds, whether conjugated or not.
[068] The esters according to this variant can be equally chosen among the mono-, di-, tri- and tetra-esters, the polyesters and their mixtures.
[069] These esters can be, for example, oleates, laurates, palmitate, myristate, behenate, cocoates, stearates, linoleates, linolenates, caprates, arachidonates, or their mixtures such as in particular the mixed esters oil-palmitate, oil-stearate , heart of palm stearate.
[070] More particularly, mono- and di-esters are used, and in particular, the mono- or di-oleate, -stearate, -behenate, -oleopalmitate, -linoleate, -linolenate, oleostearate of sucrose, glucose or methylglucose .
[071] As an example, the product sold under the name Glucate® DO by Amerchol can be cited, which is a methylglucose dioleate.
[072] Examples of esters or mixtures of fatty acid sugar esters can also be cited:- products sold under the names F160, F140, F110, F90, F70, SL40 by Crodesta, which respectively designate palmitostearates sucrose formed from 73% monoester and 27% di- and triester, 61% monoester and 39% di-, tri-, and tetraester, 52% monoester and 48% di-, tri, and tetraester, 45% monoester and 55% di-, tri-, and tetraester, 39% monoester and 61% di-, tri-, and tetraester, and sucrose monolaurate; name Ryoto Sugar Esters, for example, designated by reference B370 and corresponding to sucrose behenate formed from 20% monoester and 80% di-triester-polyester;- sucrose mono-dipalmitostearate marketed by Goldschmidt under the name Tegosoft® PSE.
[073] Esters of fatty acids and fatty alcohols can also be used. As an example, a product sold under the name CRODAMOL MS-PA (MH) by CRODA can be mentioned.
[074] The wax or non-silicone waxes likely to be used in the cosmetic composition used in step a) are chosen, in particular, among carnauba wax, Candelila wax, and wax and Alfa, the hydrocarbon waxes that include paraffin wax, ozokerite and microcrystalline wax, vegetable waxes such as olive wax, rice wax, hydrogenated jojoba wax or absolute flower waxes such as blackcurrant flower essential wax sold by BERTIN (France), animal waxes such as beeswax, or modified beeswax (kerabellin); other waxes or waxy raw materials usable according to the present invention are, in particular, marine waxes such as that sold by SOPHIM under the reference M82, polyethylene waxes or polyolefin waxes in general.
[075] Silicones that can be used in step a) according to the present invention can be in the form of oils, waxes, resins or gums.
[076] Preferably, silicones are chosen from polydialkylsiloxanes, in particular, polydimethylsiloxanes (PDMS), and organomodified polysiloxanes that have at least one functional group chosen from amino groups, aryl groups and alkoxy groups.
[077] Organopolysiloxanes are defined in more detail in Walter NOLL's "Chemistry and Technology of Silicones" (1968), Académie Press. They can be volatile or non-volatile.
[078] When volatile, silicones are more particularly chosen among those having a boiling point comprised between 60°C and 260°C, and more particularly among: (I) cyclic polydialkylsiloxanes having from 3 to 7, of preferably from 4 to 5 silicon atoms. This is, for example, octamethylcyclotetrasiloxane sold in private under the name VOLATILE SILICONE® 7207 by UNION CARBIDE or SILBIONE® 70045 V2 by RHODIA, decamethylcyclopentassiloxane sold under the name VOLATILE SILICONE® 7158 by UNION CARBIDE, and SILBIONE® 70045 V5 by RHODIA, as well as its blends.
[079] Cyclocopolymers of the dimethylsiloxanes/methylalkylsiloxane type can also be mentioned, such as SILICONE VOLATILE® FZ 3109 marketed by UNION CARBIDE, with the formula:

[080] Mixtures of cyclic polydialkylsiloxanes with organic compounds derived from silicon can also be mentioned, such as a mixture of octamethylcyclotetrasiloxane and tetratrimethylsilylpentaerythritol (50/50) and a mixture of octamethylcyclotetrasiloxane and oxy-1,1'-(hexa- 2,2,2',2',3,3'-trimethylsilyloxy) bis-neopentane; (II) linear volatile polydialkylsiloxanes having 2 to 9 silicon atoms and having a viscosity less than or equal to 5.10-6m2/sec 25° C. This is, for example, the decamethyltetrasiloxane sold in private under the name "SH 200" by TORAY SILICONE. Silicones that belong to this category are also described in the article published in Cosmetics and Toiletries, Vol. 91, Jan. 76, P. 27-32 - TODD & BYERS "Volatile Silicone fluids for cosmetics".
[081] Non-volatile polydialkylsiloxanes, polydialkylsiloxanes gums and resins, polyorganosiloxanes modified by the above organofunctional groups as well as their mixtures are preferably used.
[082] These silicones are more particularly chosen among polydialkylsiloxanes among which can be cited mainly polydimethylsiloxanes with trimethylsilyl end groups. The viscosity of silicones is measured at 25°C per ASTM 445 Appendix C.
[083] Among these polydialkylsiloxanes, the following commercial products may be mentioned, without limitation: - SILBIONE® oils of the 47 and 70 047 series or MIRASIL® oils marketed by RHODIA such as, for example, 70 047 V oil 500 000;- oils from the MIRASIL® series marketed by RHODIA;- oils from the 200 series from DOW CORNING such as DC200 which has a viscosity of 60 000 mm2/s;- VISCASIL® oils from GENERAL ELECTRIC and certain oils of the SF series (SF 96, SF 18) from GENERAL ELECTRIC.
[084] Polydimethylsiloxanes with terminal dimethylsilanol groups known by the name of dimethiconol (CTFA) may also be cited, such as the RHODIA series 48 oils.
[085] In this category of polydialkylsiloxanes, products marketed under the names "ABIL WAX® 9800 and 9801" by GOLD SCHMIDT which are polydialkyl(C1-C20)siloxanes can also be mentioned.
[086] The silicone gums that can be used according to the present invention are, in particular, polydialkylsiloxanes, preferably polydimethylsiloxanes having high number average molecular masses between 200 000 and 1 000 000 used alone or as a mixture in a solvent. This solvent can be chosen from volatile silicones, polydimethylsiloxanes (PDMS), polyphenylmethylsiloxanes (PPMS) oils, isoparaffins, polyisobutylenes, methylene chloride, pentane, dodecane, tridecane or mixtures thereof.
[087] Products that can be used more particularly according to the present invention are mixtures such that:- the mixtures are formed from a chain-end hydroxylated polydimethylsiloxane, or dimethiconol (CTFA) and a cyclic polydimethylsiloxane also called cyclomethicone ( CTFA) such as product Q2 1401 marketed by DOW CORNING; - mixtures of a polydimethylsiloxane gum and a cyclic silicone such as GENERAL ELECTRIC's SF 1214 Silicone Fluid product, such product is an SF 30 gum corresponding to a dimethicone, which has a number average molecular weight of 500 000, solubilized in SF 1202 Silicone Fluid oil corresponding to decamethylcyclopentasiloxane; - mixtures of two PDMS of different viscosities, and more particularly of a PDMS gum and a PDMS oil, such as the product SF 1236 of GENERAL ELECTRIC. The SF 1236 product is the mixture of an SE 30 gum defined above which has a viscosity of 20 m2/s and an SF 96 oil of a viscosity of 5.10-6 m2/s. This product preferably comprises 15% of SE 30 gum and 85% of an SF 96 oil.
[088] The organopolysiloxanes resins that can be used according to the present invention are crosslinked siloxanic systems that contain the units:
in which R represents an alkyl having 1 to 16 carbon atoms. Among these products, most particularly preferred are those in which R designates a lower alkyl group with C1-C4, more particularly methyl.
[089] These resins include the product marketed under the name "DOW CORNING 593" or those marketed under the names "SILICONE FLUID SS 4230 and SS 4267" by GENERAL ELECTRIC and which are silicones with a dimethyl/trimethylsiloxane structure.
[090] The trimethylsiloxysilicate type resins marketed, in particular, under the names X22-4914, X21-5034 and X21-5037 by SHIN-ETSU can also be mentioned.
[091] The organomodified silicones that can be used in step a) are silicones as defined above and that have in their structure one or more organofunctional groups fixed by means of a hydrocarbon group.
[092] Organomodified silicones can be polydiarylsiloxanes, in particular, polydiphenylsiloxanes, and polyalkylarylsiloxanes functionalized by the organofunctional groups mentioned above.
[093] Polyalkylarylsiloxanes are particularly chosen from polydimethyl/methylphenylsiloxanes, linear and/or branched polydimethyl/diphenylsiloxanes with a viscosity ranging from 1xiQ-5 to 5x10-2 m2/s at 25°C.
[094] Among these polyalkylarylsiloxanes, the products marketed under the following names can be mentioned, by way of example: - SILBIONE® oils of the series 70 641 from RHODIA; - oils from the series RHODORSIL® 70 633 and 763 from RHODIA; - o DOW CORNING 556 COSMETIC GRAD FLUID oil from DOW CORNING; - BAYER PK series silicones as PK20 product; - BAYER PN, PH series silicones as PN1000 and PH1000 products; - certain GENERAL ELECTRIC SF series oils such as SF 1023, SF 1154, SF 1250, SF 1265.
[095] Among the organomodified silicones, polyorganosiloxanes can also be mentioned that contain:- substituted or unsubstituted amino groups such as the products marketed under the name GP 4 Silicone Fluid and GP 7100 by GENESEE or the products marketed under the names Q2 8220 and DOW CORNING 929 or 939 by DOW CORNING. Substituted amino groups are, in particular, aminoalkyl groups with C1-C4;- alkoxylated groups, such as the product marketed under the name "SILICONE COPOLYMER F-755" by SWS SILICONES and ABIL WAX® 2428, 2434 and 2440 by GOLDSCHMIDT.
[096] Preferably, the greasy substance or substances used in the composition according to the present invention are non-silicone.
[097] In a variant of the present invention, the fatty substance or substances are chosen between liquid or pasty compounds at room temperature (25°C) and atmospheric pressure.
[098] In this variant, preferably, the fatty substance or substances are liquid compounds at room temperature (25°C) and atmospheric pressure.
[099] Even more preferably in this variant, the fatty substance(s) used in the composition used in step a) according to the present invention are liquid and non-silicone at a temperature of 25 °C and at atmospheric pressure.
[0100] Still in this variant, the fatty substance or substances are advantageously chosen from hydrocarbons with C6-C16, hydrocarbons with more than 16 carbon atoms, triglycerides, fatty alcohols, fatty acid and/or alcohol esters different fatty acids from triglycerides, or mixtures thereof.
[0101] Preferably in this variant, the fatty substance(s) are chosen from Vaseline oil, polydecenes, liquid fatty alcohols, esters of fatty acids and/or liquid fatty alcohols, or mixtures thereof.
[0102] In another variant of the present invention, the fatty substance or substances are chosen from solid compounds at room temperature (25°C) and at atmospheric pressure.
[0103] In this variant, the fatty substance or substances are advantageously chosen from hydrocarbon waxes, vegetable waxes, solid fatty alcohols, fatty acid esters and/or solid fatty alcohol esters, or mixtures thereof. NON-SILICON POLYMERS
[0104] According to a second embodiment of the present invention, the composition of step a) is a composition containing at least one non-silicone polymer.
[0105] According to this second variant, the composition preferably comprises from 25 to 95% by weight of water, in particular from 30 to 90% by weight of water relative to the total weight of the composition.
[0106] Preferably said composition comprises at least one non-silicone polymer in a content ranging from 0.01% to 95% by weight relative to the total weight of the composition.
[0107] According to a particular embodiment, said non-silicone polymer(s) are present in said composition in a content ranging from 0.1% to 50%, preferably from 1 to 30% by weight relative to the total weight of the composition.
[0108] In the sense of the present invention, the non-silicone polymer(s) used in step a) can be chosen from thickening, fixing or conditioning polymers.
[0109] By "thickening polymer", it is understood a polymer that, when introduced at 1% by weight into a composition that does not contain it, allows to increase the viscosity by at least 100 cps, preferably at least 500 cps, to 25°C and at a shear rate of 1 s-1. This viscosity can be measured using a cone/flat viscometer (Haake R600 Rheometer or similar).
[0110] Preferably, a polymer will be used that, when introduced at 1% by weight in an aqueous or hydroalcoholic solution at 30% of ethanol and at pH = 7 or in an oil chosen from petroleum jelly, myristate isopropyl or cyclopentadimethylsiloxane, makes it possible to achieve a viscosity of at least 100 cps, preferably at least 500 cps, at 25°C and at a shear rate of 1 s-1. This viscosity can be measured using a cone/flat viscometer (Haake R600 Rheometer or similar).
[0111] The thickening polymers can be thickeners of the aqueous phase and/or the grease phase, preferably the aqueous phase.
[0112] The thickening polymer(s) used in step a) can be chosen from cellulosic thickeners, in particular, hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylcellulose, guar gum and its derivatives, in particular, hydroxypropylguar, gums of microbial origin, in particular, xanthan gum, scleroglucan gum, cross-linked homopolymers of acrylic acid or of acrylamidopropanesulfonic acid, associative polymers.
[0113] As hydroxypropyl guar, the product will be mentioned, for example, by RHODIA with the trade name JAGUAR HP 105.
[0114] With regard to associative thickening agents, one or more polymers of non-ionic or ionic nature can be used. Preferably, the associative thickening agents are non-ionic, anionic or cationic.
[0115] The chemical structure associative polymers (or amphiphilic polymers) more particularly comprises at least one hydrophilic region and at least one hydrophobic region. By hydrophobic group is meant a hydrocarbon chain radical or polymer, saturated or not, straight or branched, comprising at least 8 carbon atoms, preferably 10 to 30 carbon atoms, in particular 12 to 30 atoms of carbon and more preferably from 18 to 30 carbon atoms.
[0116] Preferably, the hydrocarbon group comes from a monofunctional compound. By way of example, the hydrophobic group can come from a fatty alcohol such as stearyl alcohol, dodecyl alcohol, decyl alcohol. It can also designate a hydrocarbon polymer such as, for example, polybutadiene.
[0117] Among the anionic amphiphilic thickening polymers that have at least one fatty (hydrophobic) chain, the following can be mentioned: (I) polymers that have at least one hydrophilic unit, and at least one fatty chain allyl ether unit, more particularly those whose hydrophilic unit is constituted by an ethylenic unsaturated anionic monomer, advantageously by a vinylic carboxylic acid and more particularly by an acrylic acid or a methacrylic acid or their mixtures, and whose fatty chain allyl ether corresponds to the monomer of formula (A) Next:
in which R' denotes H or CH 3 , B denotes the ethyleneoxy radical, n is null or denotes an integer ranging from 1 to 100, R denotes a hydrocarbon radical chosen from alkyl, arylalkyl, aryl, alkylaryl, cycloalkyl radicals, which it comprises from 8 to 30 carbon atoms, preferably 10 to 24, and more particularly from 12 to 18 carbon atoms. A more particularly preferred unit of formula (A) is a unit in which R' designates H, n is equal to 10, and R designates a stearyl radical (C18).
[0118] Among these fatty chain anionic polymers, polymers formed from 20 to 60% by weight of acrylic acid and/or methacrylic acid, from 5 to 60%) by weight of alkyl (meth)acrylates are preferred lower, from 2 to 50% by weight of fatty chain allyl ether of formula (A), and from 0 to 1% by weight of a crosslinking agent which is a well-known copolymerizable polyethylenic unsaturated monomer such as diallyl phthalate, allyl (meth)acrylate, divinylbenzene, (poly)ethylene glycol dimethacrylate, and methylene-bis-acrylamide.
[0119] Among these latter polymers, more particularly preferred are the cross-linked terpolymers of methacrylic acid, ethyl acrylate, polyethylene glycol (10 OE) and stearyl alcohol ether (Steareth 10), in particular those sold by ALLIED COLLOIDS with the names SALCARE SC 80 and SALCARE SC90 which are 30% aqueous emulsions of a terpolymer of methacrylic acid, ethyl acrylate and steareth-10-allyl ether (40/50/10).(IV) the polymers that carry hair at least one hydrophilic unit of unsaturated olefinic carboxylic acid type, and at least one hydrophobic unit of unsaturated carboxylic acid (C10-C30) alkyl ester type.
[0120] Preferably, these polymers are chosen among those whose hydrophilic unit of unsaturated olefinic carboxylic acid type corresponds to the monomer of formula (B) below:
in which R1 designates H or CH3 or C2H5, that is, acrylic acid, methacrylic acid or ethacrylic acid units, and whose hydrophobic unit of the unsaturated carboxylic acid (C10-C30) alkyl ester corresponds to the monomer of formula (C) Next:
in which, R2 denotes H or CH3 or C2H5 (i.e. acrylate, methacrylate or ethacrylate units) and preferably H (acrylate unit) or CH3 (methacrylate unit), and R3 denotes an alkyl radical with C10-C30, and preferably in C12-C22.
[0121] Alkyl (C10-C30) esters of unsaturated carboxylic acids are, for example, lauryl acrylate, stearyl acrylate, decyl acrylate, isodecyl acrylate, dodecyl acrylate, and the corresponding methacrylates , lauryl methacrylate, stearyl methacrylate, decyl methacrylate, isodecyl methacrylate, and dodecyl methacrylate.
[0122] Among this type of anionic polymers, more particularly are used polymers formed from a mixture of monomers comprising: (V) essentially acrylic acid, (VI) an ester of formula (C) described above and in which R2 designates H or CH3, and R3 designates an alkyl radical having 12 to 22 carbon atoms, (VII) and a crosslinking agent, which is a well-known copolymerizable polyethylenic unsaturated monomer, such as diallyl phthalate, (meth)acrylate. allyl, divinylbenzene, (poly)ethylene glycol dimethacrylate, and methylene-bis-acrylamide.
[0123] Among this type of fatty chain anionic polymers, more particularly will be used those consisting of 95 to 60% by weight of acrylic acid (hydrophilic unit), 4 to 40% by weight of C10-C30 alkyl acrylate (hydrophobic unit), and 0 to 6% by weight of crosslinking polymerizable monomer, or those consisting of 98 to 96% by weight of acrylic acid (hydrophilic unit), 1 to 4% by weight of C10 alkyl acrylate -C30 (hydrophobic unit), and 0.1 to 0.6% by weight of crosslinking polymerizable monomer such as those described above.
[0124] Among the aforementioned polymers, the carbomer product sold by LUBRIZOL under the name CARBOPOL ULTREZ 10, as well as the products sold by GOODRICH under the trade names PEMULEN TR1, PEMULEN TR2, will be more particularly preferred according to the present invention. CARBOPOL 1382, and more preferably PEMULEN TRI, and the product sold by SEPPIC with the name COATEX SX.(III) the maleic anhydride/C30-C38 α-olefin/alkyl maleate terpolymers such as the product (C30-C38 α-olefin/Isopropyl maleate copolymer) sold with the name PERFORMA V 1608 by NEWPHASE TECHNOLOGIES.(IV) acrylic terpolymers comprising: (a) 20 to 70% by weight of a carboxylic acid with a,e-monoethylenic unsaturation, (b) 20 to 80% by weight of a monomer with α,β-monoethylenic unsaturation non-surfactant other than (a), (c) 0.5 to 60% by weight of a nonionic monourethane which is the reaction product of a monohydric surfactant with a monoisocyanate with monoethylenic unsaturation, such as those described in patent application EP-A-0173109 and more particularly a terpolymer of methacrylic acid/methyl acrylate/dimethyl metallopropenyl benzyl behenyl alcohol ethoxylated (40OE) isocyanate in 25% aqueous dispersion. (V) the copolymers comprising among its monomers a carboxylic acid with a,e-monoethylenic unsaturation and a carboxylic acid ester with α,β-monoethylenic unsaturation and an oxyalkylenated (C8-C30) fatty alcohol.
[0125] Preferably these compounds also comprise as a monomer a carboxylic acid ester with α, β-monoethylenic and alcohol unsaturation with C1-C4.
[0126] As an example of this type of compound, the ACULYN 22 sold by ROHM and HAAS can be cited, which is a terpolymer of methacrylic acid/ethyl acrylate/oxyalkylenated stearyl methacrylate.
[0127] The fatty-chain (hydrophobic) nonionic amphiphilic thickening polymer(s) used in step a) is preferably chosen from: (1) celluloses modified by groups that contain at least one fatty chain, such as in particular; hydroxyethylcelluloses modified by groups having at least one fatty chain such as alkyl, aryalkyl, alkylaryl groups, or mixtures thereof, and in which the alkyl groups are preferably with C8-C22, such as the product NATROSOL PLUS GRADE 330 CS (alkyls with C16) sold by AQUALON, or the product BERMOCOLL EHM 100 sold by BEROL NOBEL, - hydroxyethylcelluloses modified by polyalkylene glycol ether groups of alkyl phenol, such as the product AMERCELL POLYMER HM-1500 (polyethylene glycol (15) nonylphenol ether) sold by AMERCHOL.(2) hydroxypropyl guars modified by groups containing at least one fatty chain such as the product ESAFLOR HM 22 (alkyl chain with C22) sold by LAMBERTI, the RE products 210-18 (alkyl chain with C14) and RE205-1 (alkyl chain with C20) sold by RHONE POULENC.(3) chemically modified or unmodified starches, in particular, distarch phosphates and carboxymethyl starches.(4) copolymers vinylpyrrolidone and fatty chain hydrophobic monomers, with, for example: - ANTARON V216 or GANEX V216 (vinylpyrrolidone / hexadecene copolymer) products sold by ISP - ANTARON V220 or GANEX V220 (vinylpyrrolidone / eicosene copolymer) products sold by ISP(5 ) copolymers of C1-C6 alkyl methacrylates or acrylates and amphiphilic monomers having at least one fatty chain such as, for example, the methyl acrylate/oxyethylenated stearyl acrylate copolymer sold by GOLDSCHMIDT under the name ANTIL 208. (6) copolymers of hydrophilic methacrylates or acrylates and hydrophobic monomers having at least one fatty chain such as, for example, polyethylene glycol methacrylate/lau methacrylate copolymer. rila.(7) polymers with an aminoplast ether skeleton that have at least one fatty chain, such as the PURE THIX compounds proposed by SUD-CHEMIE.(8) polyether polyurethanes that have hydrophilic sequences in their chain at the same time. usually polyoxyethylene in nature and hydrophobic sequences which may be aliphatic sequences alone and/or cycloaliphatic and/or aromatic sequences.
[0128] Preferably, polyurethane polyethers comprise at least two fatty hydrocarbon chains having 8 to 30 carbon atoms, separated by a hydrophilic sequence, and the hydrocarbon chains can be pendant chains or chains at the end of the hydrophilic sequence.
[0129] As examples of nonionic polyurethane polyethers with a fatty chain that can be used in step a) of the present invention, Rheolate 205 which contains a urea function sold by RHEOX or Rheolates 208, 204 or 212 can be used , as well as Acrysol RM 184, Aculyn or Acrysol 44 and Aculyn or Acrysol 46 from ROHM & HAAS [1ACULYN 46 is a polycondensate of polyethylene glycol at 150 or 180 moles of ethylene oxide, stearyl alcohol and methylene bis(4 -cyclohexyl-isocyanate) (SMDI), 15% by weight in a matrix of maltodextrin (4%) and water (81%); 1ACULYN 44 is a polyethylene glycol polycondensate at 150 or 180 moles of ethylene oxide, decyl alcohol and methylene bis(4-cyclohexylisocyanate) (SMDI), 35% by weight in a mixture of propylene glycol (39%) and water (26%)].
[0130] The product ELFACOS T210 which contains an alkyl chain with C12-C 14 and the product ELFACOS T212 which contains an alkyl chain with C18 from AKZO can also be mentioned, as well as the product DW 1206B from ROHM & HAAS which contains a chain alkyl with C20 and a urethane bond, sold at 20% dry matter in water.
[0131] Solutions or dispersions of these polymers can also be used in particular, in water or in a hydroalcoholic medium. By way of example, of such polymers, Rheolate 255, Rheolate 278 and Rheolate 244 sold by RHEOX may be mentioned. DW 1206F and DW 1206J products sold by ROHM & HAAS can also be used.
[0132] The polyurethane polyethers that can be used according to the present invention are, in particular, those described in the article by G. Fonnum, J. Bakke and Fk. Hansen - Colloid Polym. Sci 271, 380,389 (1993).
[0133] Cationic amphiphilic polymers that have at least one fatty chain (hydrophobic) used in step a) can, in particular, be chosen from quaternized cellulose derivatives, cationic polyurethanes, cationic polyvinyl lactams, and preferably, among quaternized cellulose derivatives.
[0134] By way of example of polymers of this type, the following may be mentioned, in particular:- quaternized celluloses modified by groups having at least one fatty chain, such as alkyl, arylalkyl, alkylaryl groups having at least 8 atoms of carbon, or mixtures thereof, quaternized hydroxyethylcelluloses modified by groups having at least one fatty chain, such as alkyl, aryalkyl, alkylaryl groups having at least 8 carbon atoms, or mixtures thereof.
[0135] The alkyl radicals carried by the celluloses or the quaternized hydroxyethylcelluloses above which preferably contain from 8 to 30 carbon atoms. Aryl radicals preferably denote phenyl, benzyl, naphthyl or anthryl groups.
[0136] The products QUATRISOFT LM 200, QUATRISOFT LM-X 529-18-A, QUATRISOFT LM-X 529-18B (alkyl with C12) and QUATRISOFT LM can also be indicated as examples of quaternized alkylhydroxyethylcelluloses containing fatty chains with C8C30 -X 529-8 (alkyl with C18) sold by AMERCHOL and the products CRODACEL QM, CRODACEL QL (alkyl with C12) and CRODACEL QS (alkyl with C18) sold by CRODA.
[0137] All anionic, cationic, amphoteric, non-ionic fixative polymers and their mixtures used in the technique can be used in the composition of step a) according to the present application.
[0138] Fixative polymer is understood as any polymer able to give a shape to a hair or to maintain a hair in a given shape.
[0139] The fixative polymers can be soluble in the cosmetically acceptable medium or insoluble in the same medium and used, in this case, in the form of dispersions of solid or liquid polymer particles (latex or pseudolatex).
[0140] The generally used anionic fixative polymer(s) are polymers that carry groups derived from carboxylic, sulfonic or phosphoric acid and have a number average molecular weight comprised between approximately 500 and 5 000 000.
[0141] Carboxylic groups are provided by unsaturated monomers or dicarboxylic acids such as those corresponding to formula (I):
where n is an integer from 0 to 10, Al designates a methylene group, optionally attached to the carbon atom of the unsaturated group or to the neighboring methylene group when n is greater than 1, by means of a heteroatom such as oxygen or sulfur, R7 designates a hydrogen atom, a phenyl or benzyl group, R8 designates a hydrogen atom, a lower alkyl or carboxyl group, R9 designates a hydrogen atom, a lower alkyl group, a -CH2-COOH, phenyl or benzyl group.
[0142] In the above formula, a lower alkyl group preferably designates a group having 1 to 4 carbon atoms and, in particular, the methyl and ethyl groups.
[0143] The anionic fixative polymers comprising preferred carboxylic groups according to the present invention are: A) Copolymers of acrylic or methacrylic acid or its salts and acrylamide sold in the form of its sodium salts under the names RETEN 421, 423 or 425 by HERCULES,B) Copolymers of acrylic or methacrylic acid with a monoethylenic monomer such as ethylene, styrene, vinyl esters, acrylic or methacrylic acid esters, optionally grafted onto a polyalkylene glycol such as polyethylene glycol , and possibly crosslinked. Such polymers are described, in particular, in French Patent No. 1 222 944 and in German Application No. 2 330 956, copolymers of this type which contain in their chain an optionally N-alkylated and/or hydroxyalkylated acrylamide unit as described. , in particular, in Luxembourg patent applications Nos. 75370 and 75371 or sold under the name QUADRAMER by AMERICAN CYANAMID. Copolymers of acrylic acid and alkyl methacrylate with C1-C4 and terpolymers of vinylpyrrolidone, acrylic acid and alkyl methacrylate with C1-C20, for example, lauryl, such as the product marketed by ISP, may also be mentioned. under the name ACRYLIDONE® LM and methacrylic acid/ethyl acrylate/tertiobutyl acrylate terpolymers such as the product marketed under the name LUVIMER® 100 P by BASF.
[0144] The copolymers of methacrylic acid/acrylic acid/ethyl acrylate/methyl methacrylate in aqueous dispersion, marketed under the name AMERHOLD® DR 25 by AMERCHOL.C) Crotonic acid copolymers, such as those contain in their chain units vinyl acetate or propionate, and eventually other monomers such as allylic or methyl esters, vinyl ether or vinyl ester of a saturated carboxylic acid, linear or branched, with a long hydrocarbon chain, such as those containing at least 5 carbon atoms, and these polymers can optionally be grafted or cross-linked, or another vinyl, allylic or methyl ester monomer of an α- or β-cyclic carboxylic acid. Such polymers are described among others in French Patent Nos. 1 222 944, 1 580 545, 2 265 782, 2 265 781, 1 564 110 and 2 439 798. Commercial products that fall into this category are resins 28-29-30 , 26-13-14 and 2813-10 marketed by National Starch;D) Copolymers of C4-C8 monounsaturated carboxylic acids or anhydrides chosen from:- copolymers comprising (i) one or more maleic, fumaric acids or anhydrides , itaconic and (ii) at least one monomer chosen from vinyl esters, vinyl ethers, vinyl halides, phenylvinyl derivatives, acrylic acid and its esters, and the anhydride functions of these copolymers are eventually monoesterified or monoamidified. Such polymers are described in particular in US Patent Nos. 2,047,398, 2 723 248, 2 102 113, GB Patent No. 839 805.
[0145] Commercial products are, in particular, those sold under the names GANTREZ® AN or ES by ISP; - copolymers comprising (i) one or more maleic, citraconic, itaconic anhydride units and (ii) one or more monomers chosen from allylic or methyl esters that may contain one or more acrylamide, methacrylamide, α-olefin, acrylic or methacrylic esters, acrylic or methacrylic acid or vinylpyrrolidone in their chain, and the anhydride functions of these copolymers are optionally monoesterified or monoamidified .
[0146] These polymers are, for example, described in French patents Nos. 2 350 384 and 2 357 241 of the Applicant. (1) Polyacrylamides that carry carboxylate groups.
[0147] Homopolymers and copolymers comprise sulfonic groups are polymers that carry vinylsulfonic units, styrene-sulfonic, naphthalene-sulfonic or acrylamido-alkylsulfonic units.
[0148] These polymers can be, in particular, chosen from: - salts of polyvinylsulfonic acid that have a molecular weight of between approximately 1 000 and 100 000, as well as copolymers with an unsaturated comonomer such as acrylic or methacrylic acids and its esters, as well as acrylamide or its derivatives, vinyl ethers and vinylpyrrolidone; polystyrenesulfonic acid salts such as sodium salts sold for example under the names Flexan® 500 and Flexan® 130 by National Starch. Such compounds are described in FR 2 198 719; salts of polyacrylamide-sulfonic acids such as those mentioned in US patent 4,128,631, and more particularly polyacrylamidoethylpropanesulfonic acid sold under the name COSMEDIA POLIMER HSP 1180 by HENKEL.
[0149] As another anionic fixative polymer usable according to the present invention, the branched sequenced anionic polymer sold under the name Fixate G-100 by NOVEON can be cited.
[0150] According to the present invention, the polymer(s) fixative(s) used in step a) is (are) preferably chosen among the copolymers of acrylic acid such as the acrylic acid/ethyl acrylate/N-tertiobutylacrylamide terpolymers sold privately under the name ULTRAHOLD® STRONG by BASF, the copolymers derived from crotonic acid such as the vinyl acetate/vinyl tertiarybutylbenzoate/crotonic acid terpolymers and the crotonic acid/vinyl acetate/vinyl neododecanoate terpolymers sold privately under the name Résine 28-29-30 by NATIONAL STARCH, the polymers derived from maleic, fumaric, itaconic acids or anhydrides with vinyl esters, vinyl ethers, vinyl halides, phenyl vinyl derivatives, acrylic acid and its esters such as the monoesterified methylvinyl ether/maleic anhydride copolymers sold, for example, under the name GANTREZ® by ISP, the copolymers of methacrylic acid and methacrylate of methyl products sold under the name EUDRAGIT® L by ROHM PHARMA, the copolymers of methacrylic acid and ethyl acrylate sold under the name LUVIMER® MAEX or MAE by BASF and the vinyl acetate/crotonic acid copolymers sold under the name LUVISET CA 66 by BASF and the polyethylene glycol grafted vinyl acetate/crotonic acid copolymers sold under the name ARISTOFLEX® A by BASF, the polymer sold under the name Fixate G-100 by NOVEON.
[0151] Among the above-mentioned anionic fixative polymers, it is more particularly preferred to use in the context of the present invention, the monoesterified methylvinyl ether/maleic anhydride copolymers sold under the name GANTREZ® ES 425 by ISP, the terpolymers of acrylic acid/ethyl acrylate/ N- tertiarybutylacrylamide sold under the name ULTRAHOLD® STRONG by BASF, the copolymers of methacrylic acid and methyl methacrylate sold under the name EUDRAGIT® L by ROHM PHARMA, the terpolymers of vinyl acetate/tertio-butyl vinylbenzoate/crotonic acid and the crotonic acid/vinyl acetate/vinyl neododecanoate terpolymers sold under the name Résine 28-29-30 by NATIONAL STARCH, the copolymers of methacrylic acid and ethyl acrylate sold under the name LUVIMER® MAEX OR MAE by BASF, the terpolymers vinylpyrrolidone/acrylic acid/lauryl methacrylate sold under the name ACRYLIDONE® LM by ISP, the polymer sold under the name and Fixate G-100 by NOVEON.
[0152] The cationic fixative film-forming polymer(s) usable in step a) is preferably chosen among polymers that carry primary, secondary, tertiary and/or quaternary amino groups that are part of the polymer chain or directly linked to it, and that have a molecular weight of between 500 and approximately 5,000,000 and preferably between 1,000 and 3,000,000.
[0153] Among these polymers, the following cationic polymers can be more particularly mentioned: (1) homopolymers or copolymers derived from acrylic or methacrylic esters or deamides and which contain at least one of the units with the following formulas:
R3 designates a hydrogen atom or a CH3 radical; A is a linear or branched alkyl group having 1 to 6 carbon atoms or a hydroxyalkyl group having 1 to 4 carbon atoms; R4, R5, R6, identical or different, represent an alkyl group having 1 to 18 carbon atoms or a benzyl radical; R 1 and R 2 , identical or different, each represent a hydrogen atom or an alkyl group having from 1 to 6 carbon atoms; X designates a methosulfate anion or a halide such as chloride or bromide.
[0154] The family (1) copolymers also contain one or more units derived from comonomers that can be chosen from the family of acrylamides, methacrylamides, diaketone-acrylamides, acrylamides and methacrylamides substituted on nitrogen by lower alkyl groups (C1-C4 ), groups derived from acrylic or methacrylic acids or their esters, vinyl lactams such as vinylpyrrolidone or vinylcaprolactam, from vinyl esters.
[0155] Thus, among these family (1) copolymers, the following may be mentioned: - the copolymers of acrylamide and dimethylaminoethyl methacrylate quaternized with dimethyl sulfate or with a dimethyl halide, such as the product sold under the name HERCOFLOC® by HERCULES, - the copolymers of acrylamide and methacryloyloxyethyl-trimethylammonium chloride described, for example, in patent application EP-A-080976 and sold under the name BINA QUAT P 100 by CIBA GEIGY, - the copolymer of acrylamide and methosulfate of methacryloyloxy-ethyl-trimethyl-ammonium such as that sold under the name RETEN by HERCULES,- quaternized or non-quaternized vinylpyrrolidone/acrylate or dialkyl-amino-alkyl methacrylate copolymers, such as products sold under the name "GAFQUAT ®" by ISP such as "GAFQUAT® 734" or "GAFQUAT® 755" or the products called "COPOLYMER® 845, 958 and 937". These polymers are described in detail in French patents 2,077,143 and 2,393,573, - the terpolymers of dimethylaminoethyl/vinylcaprolactam/vinylpyrrolidone methacrylate such as the product marketed under the name GAFFIX VC 713 by ISP, e- and the vinylpyrrolidone/methacrylamide copolymers of quaternized dimethylamino-propyl such as the products marketed under the name "GAFQUAT® HS 100" by ISP. (3) the quaternary copolymers of vinylpyrrolidone and vinylimidazole; (4) chitosans or their salts; salts which can be used are, in particular, chitosan acetate, lactate, glutamate, gluconate or pyrrolidone carboxylate.
[0156] Among these compounds, chitosan which has a deacetylation rate of 90.5% by weight sold under the name KYTAN BRUT STANDARD by ABER TECHNOLOGIES, the chitosan pyrrolidone carboxylate sold under the name KYTAMER® PC by AMERCHOL.
[0157] The products marketed which meet this definition are more particularly those sold under the names "CELQUAT L 200" and "CELQUAT H 100" by National Starch.
[0158] The amphoteric fixative polymer(s) used in step a) according to the present invention may be chosen among polymers that carry units B and C statistically distributed in the polymer chain where B designates a unit that derives from a monomer that carries at least one basic nitrogen atom and C designates a unit derived from an acidic monomer bearing one or more carboxylic or sulphonic groups, or else B and C may designate groups derived from zwitterionic monomers of carboxybetaines or sulphobetaines;
[0159] B and C can also designate a cationic polymeric chain that bear primary, secondary, tertiary or quaternary amine groups, in which at least one of the amine groups carries a carboxylic or sulfonic group linked by means of a hydrocarbon group, or else B and C, the α,β ethylene-dicarboxylic unit is part of a polymer chain, in which two carboxylic groups have been reacted with a polyamine that has one or more primary or secondary amine groups.
[0160] The most particularly preferred amphoteric fixative polymers corresponding to the definition given above are chosen from the following polymers: (1) copolymers containing acidic vinyl units and basic vinyl units, such as those resulting from the copolymerization of a monomer derived from a vinyl compound bearing a carboxylic group such as more particularly acrylic acid, methacrylic acid, maleic acid, alpha-chloroacrylic acid, and a basic monomer derived from a substituted vinyl compound that contains at least one basic atom, such as as more particularly the dialkyl-amino-alkyl methacrylate and acrylate, the dialkyl-amino-alkyl-methacrylamide and acrylamide. Such compounds are described in U.S. Patent No. 3,836,537. (2) polymers containing units derived from: a) at least one monomer chosen from acrylamides or methacrylamides substituted on the nitrogen atom by an alkyl group, b) of at least one acidic comonomer which contains one or more reactive carboxylic groups, and c) of at least one basic comonomer such as primary, secondary, tertiary and quaternary amine substituted esters of acrylic and methacrylic acids, and the quaternization product of dimethyl methacrylate - amino-ethyl with dimethyl or diethyl sulphate.
The most particularly preferred N-substituted acrylamides or methacrylamides according to the present invention are compounds whose alkyl groups contain from 2 to 12 carbon atoms, and more particularly N-ethylacrylamide, N-tertiarybutylacrylamide, N- tertiooctylacrylamide, N-octylacrylamide, N-decylacrylamide, N-dodecylacrylamide as well as the corresponding methacrylamides.
[0162] The acidic comonomers are chosen more particularly among acrylic, methacrylic, crotonic, itaconic, maleic, fumaric acids as well as the alkyl monoesters having 1 to 4 carbon atoms of the maleic or fumaric acids or anhydrides.
Preferred basic comonomers are aminoethyl, butylaminoethyl, N,N'-dimethylaminoethyl, N-tertiarybutylaminoethyl, methacrylates.
[0164] Copolymer whose CTFA name (4th Ed., 1991) is “octylacrylamide/acrylates/butylaminoethyl methacrylate copolymer” is particularly used, such as products sold under the name AMPHOMER® or LOVOCRYL® 47 by NATIONAL STARCH.(3) the partially or totally acylated crosslinked polyaminoamides deriving from polyaminoamides of the general formula:
in which R1O represents a divalent group derived from a saturated dicarboxylic acid, an aliphatic mono- or dicarboxylic acid with an ethylenic double bond, an ester of a lower alkanol having 1 to 6 carbon atoms of these acids, or a group deriving from the addition of any of said acids with a bis-primary or bis-secondary amine, and Z designates a group deriving from a bis-primary, mono- or bis-secondary polyalkylene-polyamine and preferably represents: a) in the proportions of 60 to 100% molar, the group
where x=2 and p=2 or 3, or x=3 and p=2 and this group derives from diethylene-triamine, triethylene-tetraamine or dipropylene-triamine; b) in proportions from 0 to 40% molar, the group (III) above, in which x=2 and p=1 and which is derived from ethylenediamine, or the group which is derived from piperazine:
c) in proportions of 0 to 20% molar, the group -NH-(CH2)6-NH- which derives from hexamethylenediamine, and these polyaminoamides are crosslinked by addition reaction of a bifunctional crosslinking agent chosen among the epihalohydrins, the diepoxides, dianhydrides, bis-unsaturated derivatives, by means of 0.025 to 0.35 mol of crosslinking agent per amine group of the polyaminoamide, and acylated by the action of acrylic acid, chloracetic acid or an alkane sultone or their salts.
[0165] Saturated carboxylic acids are preferably chosen from acids having 6 to 10 carbon atoms such as adipic, trimethyl-2,2,4-adipic and trimethyl-2,4,4-adipic, terephthalic acids, acids with an ethylenic double bond, such as acrylic, methacrylic, itaconic acids.
[0166] The alkane sultones used in the acylation are preferably the propane- or the butane-sultone, the salts of the acylating agents are preferably the sodium or potassium salts.
[0167] (4) polymers that carry zwitterionic units of the formula:
in which R11 designates an unsaturated polymerizable group such as an acrylate, methacrylate, acrylamide or methacrylamide group, y and z represent an integer from 1 to 3, R12 and R13 represent a hydrogen atom, a methyl, ethyl or propyl group, R14 and R15 represent a hydrogen atom or an alkyl group such that the sum of the carbon atoms in R14 and R15 does not exceed 10.
[0168] Polymers comprising such units may also comprise units derived from non-zwitterionic monomers such as dimethyl- or diethylaminoethyl acrylate or methacrylate or alkyl acrylates or methacrylates, acrylamides or methacrylamides, or vinyl acetate.
[0169] By way of example, methyl methacrylate/dimethyl-carboxymethylammonium-ethyl methyl methacrylate copolymers can be cited, such as the product sold under the name DIAFORMER Z301 by SANDOZ.(5) the polymers derived from chitosan that carry corresponding monomeric units to the following formulas:
unit (D) is present in proportions between 0 and 30%, unit (E) in proportions between 5 and 50% and unit (F) in proportions between 30 and 90%, it should be clear that in this unit (F), R16 represents a formula group:
in which if q=0, R17, R18 and R19, identical or different, each represent a hydrogen atom, a methyl, hydroxyl, acetoxy or amino residue, a monoalkylamine or a dialkylamine residue, optionally interrupted by one or more nitrogen atoms and/or optionally substituted by one or more amino, hydroxyl, carboxyl, alkylthio, sulfonic groups, an alkylthio residue whose alkyl group bears an amino residue, and at least one of the groups R17, R18 and R19 is, in this case, a hydrogen atom; or if q=1, R17, R18 and R19 each represent a hydrogen atom, as well as the salts formed by these compounds with bases or acids. (6) Polymers comprising units corresponding to the formula general (V) are, for example, described in French patent 1 400 366:
in which R20 represents a hydrogen atom, a CH3O,CH3CH2O or phenyl group, R21 denotes a hydrogen atom or a lower alkyl group such as methyl, ethyl, R22 denotes a hydrogen atom or a lower alkyl group with C1-C6 such as as methyl, ethyl, R23 denotes a lower alkyl group with C1-C6 such as methyl, ethyl or a group corresponding to the formula: -R24-N(R22)2, wherein R24 represents a group -CH2-CH2-, - CH2-CH2-CH2- or -CH2-CH(CH3)-, and R22 has the meanings mentioned above. (7) Polymers derived from the N-carboxyalkylation of chitosan such as N-carboxymethyl-chitosan or N-carboxybutyl-chitosan , sold under the name “EVALSAN” by JAN DEKKER.(8) Amphoteric polymers of the -DXDX type chosen from: a) polymers obtained by the action of chloracetic acid or sodium chloracetate on compounds containing at least one unit of formula: -DXDXD- (VI) where D designates a group
and X designates the symbol E or E', E or E' identical or different designates a bivalent group which is a straight or branched chain alkylene group having up to 7 carbon atoms in the main chain unsubstituted or substituted by hydroxyl groups and which can also contain oxygen, nitrogen, sulfur atoms, 1 to 3 aromatic and/or heterocyclic cycles; and the oxygen, nitrogen and sulfur atoms are present in the form of ether, thioether, sulfoxide, sulfone, sulfonium, alkylamine, alkenylamine, hydroxyl groups, benzylamine, amine oxide, quaternary ammonium, amide, imide, alcohol, ester groups and/or urethane.b) Polymers of the formula: -DXDX- (VI*)where D designates a group
and X designates the symbol E or E' and at least once E'; and E has the meaning indicated above and E' is a bivalent group which is a straight or branched chain alkylene group having up to 7 carbon atoms in the main chain, whether or not substituted by one or more hydroxyl groups and having one or more nitrogen atoms, and the nitrogen atom is replaced by an alkyl chain eventually interrupted by an oxygen atom and which mandatorily has one or more carboxyl functions or one or more hydroxyl functions and beta-tainized by reaction with chloracetic acid or chloracetate of soda.(9) (C 1 -C 5 )alkyl vinyl ether/maleic anhydride copolymers partially modified by semi-amidification with an N,N-dialkylaminoalkylamine such as N,N-dimethylaminopropylamine or by semiesterification with an N,N-dialkylaminoalkanol. These copolymers can also contain other vinyl comonomers such as avinylcaprolactam.
[0170] Among the amphoteric fixative polymers mentioned above, the most particularly used in step a) according to the present invention are those of the family (3) such as copolymers whose CTFA name is "Octylacrylamide/acrylates/butylaminoethyl methacrylate copolymer", such such as products sold under the names AMPHOMER®, AMPHOMER® LV 71 or LOVOCRYL® 47 by NATIONAL STARCH and those of the family (4) such as the methyl methacrylate/dimethyl-carboxymethylammonio-ethyl-methyl methacrylate copolymers sold for example with the name DIAFORMER Z301 by SANDOZ.
[0171] The non-ionic fixative polymer(s) usable in step a) according to the present invention are chosen, for example, among: - polyalkyloxazolines; - vinyl acetate homopolymers; - vinyl acetate copolymers such as , for example, copolymers of vinyl acetate and acrylic ester, copolymers of vinyl acetate and ethylene, or copolymers of vinyl acetate and maleic ester, for example, of dibutyl maleate; of acrylic esters such as, for example, copolymers of alkyl acrylates and alkyl methacrylates such as the products sold by ROHM & HAAS under the names PRIMAL® AC-261 K and EUDRAGIT® NE 30 D, by BASF under the name 8845, by HOECHST under the name APPRETAN® N9212;- copolymers of acrylonitrile and a non-ionic monomer chosen, for example, between butadiene and alkyl (meth)acrylates; products sold under the name CJ 0601 B by ROHM & HAAS may be mentioned; - styrene homopolymers; - styrene copolymers such as, for example, styrene and alkyl (meth)acrylate copolymers such as MOWILITH products ® LDM 6911, MOWILITH® DM 611 and MOWILITH® LDM 6070 sold by HOECHST, RHODOPAS® SD 215 and RHODOPAS® DS 910 products sold by RHONE POULENC; copolymers of styrene, alkyl methacrylate and alkyl acrylate; styrene and butadiene copolymers; or copolymers of styrene, butadiene and vinylpyridine; - polyamides; - vinyl lactam homopolymers, such as vinylpyrrolidone homopolymers, polyvinylcaprolactam marketed under the name Luviskol® PLUS by BASF; e- vinyl lactam copolymers such as a poly(vinylpyrrolidone/vinyl lactam) copolymer sold under the trade name Luvitec® VPC 55K65W by BASF, poly(vinylpyrrolidone/vinyl acetate) copolymers such as those sold under the trade name PVPVA® S630L by ISP, Luviskol® VA 73, VA 64, VA 55, VA 37 and VA 28 by BASF; and poly(vinylpyrrolidone/vinyl acetate/vinyl propionate) terpolymers such as the one marketed under the name Luviskol® VAP 343 by BASF.
[0172] The alkyl groups of the nonionic polymers mentioned above preferably have from 1 to 6 carbon atoms.
[0173] They can also be used in step a) as fixative polymers, functionalized or non-functionalized polyurethanes, cationic, non-ionic, anionic or amphoteric, or their mixtures.
[0174] The polyurethanes particularly intended for the present invention are those described in the applications EP 0 751 162, EP 0 637 600, EP 0 648 485 and FR 2 743 297 to which the Depositor is the holder, as well as in the applications EP 0 656 021 and WO 94/03510 by BASF, and EP 0 619 111 by National Starch.
[0175] As polyurethanes that are particularly suitable in the present invention, the products marketed under the name LUVISET PUR® by BASF can be cited.
[0176] By conditioning polymer, it is understood in the sense of the present invention a polymer capable of giving the keratin fibers and, in particular, the hair an improvement of at least one of the following properties: soft to the touch, smoothing effect, ease of disentanglement.
[0177] Preferably the conditioning polymer(s) are cationic polymers or amphoteric polymer or polymers, in particular, Polyquaternium-22.
[0178] Preferably, the conditioning polymer(s) are chosen from: (1) cyclopolymers of alkyl dialkyl amine salts or of dialkyl diallyl ammonium salts such as homopolymers or copolymers that have units corresponding to the formulas as the main constituent of the chain (VII ) or (VIII):
where ket equals 0 or 1, and the sum k + t equals 1, R 2 denotes a hydrogen atom or a methyl group, R10 and R11 independently of one another designate an alkyl group having 1 to 6 carbon atoms, a hydroxyalkyl group in which the alkyl group preferably has 1 to 5 carbon atoms, a lower amidoalkyl group (C1-C4), or R10 and R11 may denote together with the nitrogen atom to which they are attached , heterocyclic groups, such as piperidinyl or morpholinyl, Y- is an anion such as bromide, chloride, acetate, borate, citrate, tartrate, bisulfate, bisulfite, sulfate, phosphate. These polymers are, in particular, described in French patent 2 080 759 and its certificate of addition 2 190 406. R10 and R11, independently of one another, preferably designate an alkyl group having from 1 to 4 carbon atoms.
[0179] Among the polymers defined above, mention may be made more particularly of the homopolymer of dimethyldiallylammonium chloride sold under the name "Merquat 100" by NALCO, its low weight average molecular weight counterparts, and the copolymers of diallyldimethylammonium chloride and of acrylamide marketed under the name "MERQUAT 550".(2) Quaternary diammonium polymers that contain, in particular, the repeating units corresponding to formula (IX):
in which: R13, R14, R15 and R16, identical or different, represent aliphatic, alicyclic or arylaliphatic groups containing from 1 to 20 carbon atoms or lower aliphatic hydroxyalkyl radicals, or else R13, R14, R15 and R16, together or separately, constitute with the nitrogen atoms to which they are attached heterocycles that optionally contain a second heteroatom other than nitrogen, or else R13, R14, R15 and R16 represent a linear or branched C1-C6 alkyl group substituted by a nitrile group, ester, acyl, amide or CO-O-R17-D or CO-NH-R17-D where R17 is an alkylene and D a quaternary ammonium group, A1 and B1 represent polymethylene groups containing from 2 to 20 carbon atoms which they can be linear or branched, saturated or unsaturated, and they can contain, linked or interspersed in the main chain, one or more aromatic cycles, or one or more oxygen, sulfur or sulfoxide, sulfone, disulfide, amino, alkylamino atoms, hydroxyl, the quaternary ammonium, ureido, amide or ester, eX- designates an anion derived from a mineral or organic acid, A1, R13 and R15 can form with the two nitrogen atoms to which they are attached a piperazine cycle. Furthermore, if A1 designates a linear or branched, saturated or unsaturated alkylene or hydroxyalkylene radical, B1 may also designate a group (CH2)n-CO-D-OC-(CH2)p-, n and p are integers ranging from 2 to 20 approximately, in which D denotes: a) a glycol residue of the formula: -OZO-, in which Z denotes a hydrocarbon radical, linear or branched, or a group corresponding to one of the following formulas:-(CH2- CH2-O)x -CH2-CH2-,-[CH2-CH(CH3)-O]y-CH2-CH(CH3)-, where x and y designate an integer from 1 to 4, which represents a degree of polymerization defined and unique or any number from 1 to 4 representing an average degree of polymerization, b) a bis-secondary diamine residue such as a piperazine derivative, c) a bis-primary diamine residue of formula: -NH- Y-NH-, where Y denotes a linear or branched hydrocarbon radical, or the bivalent radical --CH2-CH2-SS-CH2-CH2-,d) a ureylene group of the formula -NH-CO-NH-.
[0180] Preferably, X- is an anion such as chloride or bromide.
[0181] These polymers have a number average molecular mass generally between 1 000 and 100 000.
[0182] Polymers of this type are described, in particular, in French patents 2 320 330, 2 270 846, 2 316 271, 2 336 434 and 2 413 907 and in US patents 2 273 780, 2 375 853, 2 388 614, 2 454 547, 3 206 462, 2 261 002, 2 271 378, 3 874 870, 4 001 432, 3 929 990, 3 966 904, 4,005 193, 4,025 617, 4,025 627, 4,025 653, 4,026 945 and 4,027,020.
[0183] Polymers that are made up of repeating units corresponding to the formula (X) can be used more particularly:
in which R18, R19, R20 and R21, which are identical or different, designate an alkyl or hydroxyalkyl group having approximately 1 to 4 carbon atoms, rs are integers ranging from approximately 2 to 20, and X- is a anion derived from a mineral or organic acid.
[0184] A particularly preferred compound of formula (X) is one for which R18, R19, R20 and R21 represent a methyl radical, r = 3, s = 6 and X = Cl, called "Hexadimethrine chloride" according to nomenclatureINCI (CTFA).
[0185] Quaternary diammonium polymers can also be constituted, in particular, of units of formula (XI):
in which: R22, R23, R24 and R25, identical or different, represent a hydrogen atom or a methyl, ethyl, propyl, β-hydroxyethyl, β-hydroxypropyl or -CH2CH2(OCH2CH2)pOH group, where p is equal to 0 or an integer comprised between 1 and 6, provided that R22, R23, R24 and R25 do not simultaneously represent a hydrogen atom, t and u, identical or different, are integers comprised between 1 and 6, v is equal to 0 or a an integer comprised between 1 and 34, X- designates an anion such as a halide, A designates a dihalide radical or preferably represents. -CH2-CH2-O-CH2-CH2-.
[0186] Such compounds are, in particular, described in patent application EP-A-122324.
[0187] Among them, we can mention, for example, the products "Mirapol® A 15", "Mirapol® AD1", "Mirapol® AZ1" and "Mirapol® 175" sold by MIRANOL.(3) cationic polysaccharides, in particular, cationic celluloses and galactomannan gums.
[0188] For celluloses, copolymers of cellulose or cellulose derivatives grafted with a water-soluble monomer containing a quaternary ammonium can be cited, and described, in particular, in patent US 4 131 576, such as hydroxyalkyl celluloses, such as ashydroxymethyl-, hydroxyethyl- or hydroxypropyl celluloses grafted, in particular, with a salt of methacryloyloxyethyl trimethylammonium, of methacrylamidopropyl trimethylammonium, of dimethyldiallylammonium.
[0189] The marketed products that meet this definition are more particularly the products sold under the names "CELQUAT L 200", "CELQUAT LOR" and "CELQUAT H 100" by AKZO NOBEL (Polyquaternium-4). The product sold under the name MERQUAT 280 (Polyquaternium-22) by LUBRIZOL.TENSOATIVOS can also be mentioned.
[0190] According to a third embodiment of the present invention, the composition of step a) is a composition that contains at least one surfactant.
[0191] According to this third variant, the composition preferably comprises from 30 to 70% by weight of water with respect to the total weight of the composition.
[0192] Preferably said composition comprises at least one surfactant in a content ranging from 0.01% to 95%, preferably from 0.1% to 60%, more preferably from 1 to 50%, by weight in relation to the total weight of the composition.
[0193] In the sense of the present invention, the surfactant(s) used in step a) can be chosen between nonionic surfactants, anionic surfactants, cationic surfactants and amphoteric or zwitterionic surfactants.
[0194] The surfactant(s) according to the present invention can be silicone or not.
[0195] It is understood by "anionic surface-active agent", a surfactant that comprises, as ionic or ionizable groups, only anionic groups. These anionic groups are preferably chosen from the groups — C(O)OH, -C(O)O-, -SO3H, -S(O)2O-, -OS(O)2OH, -OS(O) 2O-, -P(O)OH2, -P(O)2O-, -P(O)O2-, -P(OH)2, =P(O)OH, -P(OH)O-, =P (O)O-, =POH, =PO-; and the anionic parts comprise a cationic counterion such as an alkali metal, an alkaline earth metal, or an ammonium.
[0196] As examples of anionic surfactants that can be used in step a) according to the present invention, there can be cited the alkyl sulfates, the alkyl ether sulfates, the alkylamidoether sulfates, the alkylarylpolyethersulfates, the monoglyceride-sulfates, the alkylsulfonates, alkylamide sulfonates, alkylarylsulfonates, alpha-olefin sulfonates, paraffin sulfonates, alkylsulfosuccinates, alkylethersulfosuccinates, alkylamidesulfosuccinates, alkylsulfoacetates, acylsarcosinates, acylglutamates, alkylsulfosuccinates -acyltaurates, salts of alkyl monoesters and polyglycoside-polycarboxylic acids, acyl lactylates, salts of D-galactoside-uronic acids, salts of alkyl ether-carboxylic acids, salts of alkyl aryl ether-carboxylic acids, salts of alkyl amidoether carboxylic acids, and the corresponding unsalified forms of all such compounds, the alkyl and ac. 1 of all these compounds having 6 to 40 carbon atoms and the aryl group designates a phenyl group.
[0197] These compounds can be oxyethylenated and contain, then, preferably from 1 to 50 ethylene oxide units.
[0198] The salts of alkyl monoesters with C6-C24 and polyglycoside-polycarboxylic acids can be chosen from polyglycoside-alkyl citrates with C6-C24, polyglycoside-alkyl tartrates with C6-C24 and polyglycoside-sulfosuccinates of alkyl with C6-C24.
[0199] When the anionic surfactant or agents are in salt form, they can be chosen from alkali metal salts such as sodium or potassium salt and preferably sodium, ammonium salts, salts of amines and in particular amino alcohols or alkaline earth metal salts such as magnesium salts.
[0200] As an example of salts of amino alcohols, there may be mentioned in particular, salts of mono-, di- and triethanolamine, salts of mono-, di- or triisopropanolamine, salts of 2-amino-2-methyl-1 -propanol, 2-amino-2-methyl-1,3-propanediol and tris(hydroxymethyl)amino methane.
[0201] Are used, preferably. alkali metal or alkaline earth metal salts and in particular sodium or magnesium salts.
[0202] Among the cited anionic surfactants that can be used, alkyl(C6-C24)sulfates are preferred, alkyl(C6-C24)ethersulfates comprising from 2 to 50 ethylene oxide units, in particular, in the form of alkali metal, ammonium, amino alcohol, and alkaline earth metal salts, or a mixture of these compounds.
[0203] In particular, it is preferred to use alkyl(C12-C2o) sulfates, alkyl(C12-C2o) ether sulfates comprising from 2 to 20 ethylene oxide units, in particular, in the form of alkali metal salts, of ammonium, amino alcohols, and alkaline earth metals, or a mixture of these compounds. Most preferably, the use of sodium lauryl ether sulfate at 2.2 moles of ethylene oxide is preferred.
[0204] Examples of nonionic surfactants usable in step a) according to the present invention are described, for example, in "Handbook of Surfactants" by MR PORTER, Blackie & Son editions (Glasgow and London), 1991, pp 116-178. They are chosen, in particular, from alcohols, alpha-diols, alkyl(C1-C2o)phenols, and these compounds are polyethoxylated, polypropoxylated and/or polyglycerolated, and have at least one fatty chain that has, for example, 8 to 40 carbon atoms, and the number of ethylene oxide and/or propylene oxide groups may in particular vary from 1 to 200 and the number of glycerol groups may vary in particular from 1 to 30.
[0205] Mention may also be made of copolymers of ethylene oxide and propylene oxide, esters of optionally oxyethylenated fatty acids and sorbitan, esters of fatty acids and sucrose, polyoxyalkylenated fatty acid esters, optionally oxyalkylenated alkylpolyglycosides, esters of alkyl glucosides, mono- or di-alkanolamides, derivatives of N-alkylglucamine and N-acyl-methylglucamine, aldobionamides, oxyethylenated and/or oxypropylenated silicones and amine oxides.
[0206] The nonionic surfactant(s) used in step a) are more particularly chosen from mono- or poly-oxyalkylenated, mono- or polyglycerolated non-ionic surfactants. Oxyalkylenated units are more particularly oxyethylenated, oxypropylenated, or combinations thereof, preferably oxyethylenated.
[0207] By way of examples of nonionic oxyalkylenated surfactants, the following may be mentioned: - alkyl(C8-C24) oxyalkylenated phenols, - alcohols with C8-C30, saturated or not, linear or branched, oxyalkylenated, as in particular, deceth-3 or deceth-5, - amides, with C8-C30, saturated or not, linear or branched, oxyalkylenated, - esters of acids with C8-C30, saturated or not, linear or branched, and of polyethylene glycols,- esters of acids with C8-C30, saturated or not, linear or branched, and of polyoxyethylenated sorbitol, - oxyethylenated vegetable oils, saturated or not, - ethylene oxide and/or propylene oxide condensates, among others, alone or in mixtures, - oxyethylenated and/or oxypropylenated silicones.
[0208] The surfactant(s) have a number of moles of ethylene oxide and/or propylene oxide that preferably ranges from 1 to 100, more preferably from 2 to 50. Advantageously, the nonionic surfactant(s) do not comprise oxypropylenated units.
[0209] According to a preferred embodiment of the present invention, the nonionic surfactant(s) used in step a) are chosen from alcohols with C8-C30, oxyethylenated, esters of acids with C8-C30, saturated or non, linear or branched, and polyoxyethylenated sorbitol.
[0210] As an example of non-ionic surfactants mono- or poly-glycerolated, are used in step a), preferably, alcohols with C8-C40, mono- or polyglycerolate.
[0211] In particular, alcohols with C8-C40 mono- or polyglycerols correspond to the formula (A1) below: RO-[CH2-CH(CH2OH)-0]mH (A1)in which R represents an alkyl or alkenyl radical, linear or branched, with C8-C40, preferably with C8-C30, m represents a number ranging from 1 to 30 and preferably from 1 to 10.
[0212] As examples of compounds usable in step a) in the context of the present invention, lauric alcohol with 4 moles of glycerol (INCI name: POLIGLYCERYL-4 LAURYL ETHER), lauric alcohol with 1.5 moles of glycerol, oleic alcohol with 4 moles of glycerol (INCI name: POLIGLYCERYL-4 OLEYL ETHER), oleic alcohol with 2 moles of glycerol (INCI name: POLIGLYCERYL-2 OLEYL ETHER), cetearyl alcohol with 2 moles of glycerol, o cetearyl alcohol with 6 moles of glycerol, oleocetyl alcohol with 6 moles of glycerol, and octadecanol with 6 moles of glycerol.
[0213] Alcohol can represent a mixture of alcohols in the same way that the value of m represents a statistical value, which means that in a commercial product several species of polyglycerol fatty alcohols can coexist in the form of a mixture.
[0214] Among the mono- or polyglycerolated alcohols, it is more particularly preferred to use the alcohol with C8/C10 that contains one mole of glycerol, the alcohol with C10/C12 that contains 1 mole of glycerol and the alcohol with C12 that contains 1, 5 mol of glycerol.
[0215] Preferably the nonionic surfactant(s) are chosen from oxyethylenated or not alkanolamides and oxyethylenated fatty alcohols.
[0216] The cationic surfactant(s) that can be used in step a) comprise, for example, salts of primary, secondary or tertiary fatty amines, optionally polyoxyalkylenated, quaternary ammonium salts, and mixtures thereof.
[0217] As quaternary ammonium salts, it can be cited, in particular, for example: - those corresponding to the general formula (A2) below:

[0218] Formula (A2) in which: R8 to R11, which may be identical or different, represent an aliphatic group, linear or branched, having 1 to 30 carbon atoms, or an aromatic group such as aryl or alkylaryl, it should be clear that at least one of the groups R8 to R11 has from 8 to 30 carbon atoms, and preferably from 12 to 24 carbon atoms; eX" represents an organic or inorganic anionic counterion, such as that chosen from halides, acetates, phosphates, nitrates, (C1-C4)alkyl sulfates, (C1-C4)-alkyl or (C1-C4)alkylaryl- sulphonates, in particular methyl sulphate and ethyl sulphate.
[0219] The aliphatic groups from R8 to R11 can also contain heteroatoms such as, in particular, oxygen, nitrogen, sulfur and halogens.
[0220] The aliphatic groups from R8 to R11 are, for example, chosen from alkyl with C1-C30 or alkenyl, alkoxy with C1-C30, polyoxyalkylene (C2-C6), alkylamide with C1-C30, alkyl(C12- C22)amidoalkyl(C2-C6), alkyl(C12-C22)acetate, and hydroxyalkyl with C1-C30, X" is an anionic counterion chosen among halides, phosphates, acetates, lactates, alkyl(C1-C4) sulfates, alkyl (C1-C4)- or (C1-C4)alkylaryl-sulfonates.
[0221] Among the quaternary ammonium salts of formula (A2), preferred are, on the one hand, tetraalkylammonium chlorides such as, for example, dialkyldimethylammonium or alkyltrimethylammonium chlorides in which the alkyl group has approximately 12 to 22 atoms of carbon, in particular, beheyl trimethylammonium, distearyldimethylammonium, cetyltrimethylammonium, benzyldimethylstearylammonium chlorides or, on the other hand, distearoylethylhydroxyethylmethylammonium methosulphate, dipalmitoylethylhydroxyethylammonium methosulphate or finally distearate methomonium or hydroxyethylsulphate palmitylamidopropyltrimethylammonium chloride or stearamidopropyldimethyl-(myristyl acetate)ammonium chloride marketed under the name CERAPHYL® 70 by VAN DYK; - imidazoline quaternary ammonium salts such as those of formula (A3) shown below:

[0222] Formula (A3) in which: R12 represents an alkenyl or alkyl group having from 8 to 30 carbon atoms, for example derived from fatty acids of tallow; R13 represents a hydrogen atom, an alkyl group with C1-C4 or an alkenyl or alkyl group having from 8 to 30 carbon atoms; R14 represents an alkyl group with C1-C4; R15 represents a hydrogen atom, an alkyl group with C1-C4; X- represents an anionic organic or inorganic counterion , such as that chosen from halides, phosphates, acetates, lactates, (C1-C4)alkyl sulphates, (C1-C4)alkyl- or (C1-C4)alkylarylsulphonates.
[0223] Preferably, R12 and R13 designate a mixture of alkenyl or alkyl groups having 12 to 21 carbon atoms, for example derived from fatty acids from tallow, R14 designates a methyl group, R15 designates a hydrogen atom. Such a product is, for example, marketed under the name REWOQUAT® W 75 by REWO; - the di- or quaternary triammonium salts, in particular, of formula (A4) below:

[0224] Formula (A4) in which: R16 designates an alkyl group having approximately 16 to 30 carbon atoms, optionally hydroxylated and/or interrupted by one or more oxygen atoms; R17 is chosen from hydrogen, an alkyl group that comprises 1 to 4 carbon atoms or a group -(CH2)3-N+(R16a)(R17a)(R18a), X-;R16a, R17a, R18a, R18, R19, R20 and R21, which are identical or different , are chosen from hydrogen and an alkyl group having 1 to 4 carbon atoms; and X-, identical or different, represent an organic or inorganic anionic counterion, such as the one chosen from halides, acetates, phosphates, nitrates, (C1-C4) alkyl sulfates, (C1-C4)-alkyl or (C1 -alkyl) - C4) aryl sulphonates, in particular methyl sulphate and ethyl sulphate.
[0225] Such compounds are, for example, Finquat CT-P sold by FINETEX (Quaternium 89), Finquat CT sold by FINETEX (Quaternium 75);-quaternary ammonium salts that contain one or more ester functions, such as of formula (A5) below:

[0226] Formula (A5) in which: R22 is chosen from C1-C6 alkyl groups and C1-C6 hydroxyalkyl or dihydroxyalkyl groups, R23 is chosen from:- the group
- R27 hydrocarbon groups in C1-C22, linear or branched, saturated or unsaturated, - the hydrogen atom, R25 is chosen from: - the group
- the linear or branched, saturated or unsaturated C1-C6 hydrocarbon groups R29, - the hydrogen atom, - 24, R26 and R28, which are identical or different, are chosen from the linear or C7-C21 hydrocarbon groups branched, saturated or unsaturated; r, set, which are identical or different, are integers ranging from 2 to 6, r1 and t1, which are identical or different, are equal to 0 or 1 with r2+r1=2r and t1+ t2=2t,y is an integer ranging from 1 to 10.x and z, identical or different, are integers that have values from 0 to 10.X- represents an anionic, organic or inorganic counterion, as long as the sum x + y + z is from 1 to 15, that when x is 0 then R23 designates R27 and when z is 0 then R25 designates R29.
[0227] Alkyl groups R22 can be linear or branched, and more particularly linear.
[0228] Preferably, R22 designates a methyl, ethyl, hydroxyethyl or dihydroxypropyl group, and more particularly a methyl or ethyl group.
[0229] Advantageously, the sum x + y + z ranges from 1 to 10.
[0230] When R23 is a hydrocarbon group R27, it can be long and have 12 to 22 carbon atoms, or short and have 1 to 3 carbon atoms.
[0231] When R25 is a hydrocarbon group R29, it preferably has 1 to 3 carbon atoms.
[0232] Advantageously, R24, R26 and R28', identical or different, are chosen from hydrocarbon groups with C11-C21, linear or branched, saturated or unsaturated, and more particularly between alkyl and alkenyl groups with C11-C21, linear or branched, saturated or unsaturated.
[0233] Preferably, x and z, which are identical or different, are worth 0 or 1.
[0234] Advantageously, y is equal to 1.
[0235] Preferably, r, s and t, which are identical or different, are equal to 2 or 3, and more particularly are equal to 2.
[0236] The anionic counterion X- is preferably a halide, such as chloride, bromide or iodide; a (C 1 -C 4 )alkyl sulfate; (C 1 -C 4 )alkyl- or (C 1 -C 4 )alkyl aryl sulfonate. However, it is possible to use methanesulfonate, phosphate, nitrate, tosylate, an anion derived from organic acid such as acetate or lactate, or any other anion compatible with ammonium that contains an ester function.
[0237] The anionic counterion X" is more particularly the chloride, methylsulfate or ethylsulfate.
[0238] It is used more particularly in the composition according to the present invention, the ammonium salts of formula (A5) in which: - R22 designates a methyl or ethyl group, - x and y are equal to 1, - z is equal to 0 or 1,- r, set are equal to 2,- R23 is chosen from: the group
methyl, ethyl or hydrocarbon groups with C14-C22, the hydrogen atom, - R25 is chosen from: the group
the hydrogen atom, - R24, R26 and R28, which are identical or different, are chosen from hydrocarbon groups with C13-C17, linear or branched, saturated or unsaturated, and preferably between alkyl and alkenyl groups with C13-C17 , linear or branched, saturated or unsaturated.
[0239] Advantageously, hydrocarbon radicals are linear.
[0240] There may be mentioned, for example, among the compounds of formula (A5) the salts, in particular, the chloride or methylsulfate, of diacyloxyethyldimethylammonium, of diacyloxyethylhydroxyethylmethylammonium, demonoacyloxyethyldihydroxyethyl methylammonium, of triacyloxyethylmethylammonium, demonoacyloxy ethylhydroxyethyl dimethylammonium, and Mistura. The acyl groups preferably have 14 to 18 carbon atoms and are more particularly derived from a vegetable oil such as palm or sunflower oil. When the compound contains several acyl groups, they can be identical or different.
[0241] These products are obtained, for example, by direct esterification of triethanolamine, triisopropanolamine, alkyldiethanolamine or alkyldiisopropane amine possibly oxyalkylenated with fatty acids or mixtures of fatty acids of vegetable or animal origin, or by transesterification of their methyl esters . This esterification is followed by a quaternization by means of an alkylation agent such as an alkyl halide, preferably of methyl or ethyl, a dialkyl sulfate, preferably of methyl or ethyl, methyl methanesulfonate, paratoluenesulfonate. methyl, the chlorhydrin of glycol or glycerol.
[0242] Such compounds are, for example, marketed under the names DEHYQUART® by HENKEL, STEPANQUAT® by STEPAN, NOXAMIUM® by CECA, REWOQUAT® WE 18 by REWO-WITCO.
[0243] The composition according to the present invention may contain, for example, a mixture of mono-, di- and triester quaternary ammonium salts with a predominance by weight of diester salts.
[0244] Ammonium salts containing at least one ester function described in US-A-4874554 and US-A-4137180 can also be used.
[0245] Behenoylhydroxypropyltrimethylammonium chloride sold by KAO under the name Quatarmin BTC 131 may also be used.
[0246] Preferably the ammonium salts contain at least one ester function which contain two ester functions.
[0247] Among the cationic surfactants that may be present in the composition according to the present invention, more particularly are chosen the salts of cetyltrimethylammonium, behenyltrimethylammonium, dipalmitoylethyl-hydroxyethylmethylammonium, and their mixtures, and more particularly beheyltrimethylammonium chloride, cetyltrimethylammonium chloride, dipalmitoylethylhydroxyethylammonium methosulfate, and mixtures thereof.
[0248] The amphoteric or zwitterionic surfactant(s) used in step a) are preferably non-silicone. They can be, in particular, derived from secondary or tertiary aliphatic amines, in which the aliphatic group is a straight or branched chain containing 8 to 22 carbon atoms and containing at least one anionic water solubilizing group such as, for example, a carboxylate, sulfonate, sulfate, phosphate or phosphonate group; further mention may be made of (C8-C20)alkyl betaines, sulphobetaines, (C8-C20)alkylamido(C6-C8)alkyl-betaines or (C8-C20)alkylamido(C6-C8)alkylsulfobetaines; and its mixtures.
[0249] Among the derivatives of aliphatic secondary or tertiary amines, possibly quaternized, usable, as defined above, may also be mentioned the compounds of respective structures (A6) and (A7) below: Ra-C(O)-NH- CH2-CH2-N+(Rb)(Rc)-CH2C(O)O-, M+, X- (A6)
[0250] Formula (A6) in which: Ra represents an alkyl or alkenyl group with C10-C30 derived from an acid RaCOOH, preferably present in hydrolyzed copra oil, a heptyl, nonyl or undecyl group; Rb represents a beta- group hydroxyethyl; eRc represents a carboxymethyl group; M+ represents a cationic counterion from an alkaline earth metal such as sodium, an ammonium ion or an ion from an organic amine, eX" represents an organic or inorganic anionic counterion such as which is chosen from halides, acetates, phosphates, nitrates, (C 1 -C 4 )alkyl sulphates, (C 1 -C 4 )alkyl- or (C 1 -C 4 )alkyl aryl sulphonates, in particular methyl sulphate and ethyl sulphate; or else M+ and X" are absent; Ra'-C(O)-NH-CH 2 -CH 2 -N(B)(B') (A7)
[0251] Formula (A7) in which: B represents the group -CH2-CH2-0-X;B' represents the group -(CH2)ZY', with z = 1 or 2;X' represents the group -CH2- C(O)OH, -CH2-C(O)OZ', -CH2-CH2-C(O)OH or -CH2-CH2-C(O)OZ', or a hydrogen atom; Y' represents the group -C(O)OH, -C(O)OZ', -CH2-CH(OH)-SO3H or the group -CH2-CH(OH)-SO3-Z';Z' represents a cationic counterion from a metal alkaline or alkaline earth, such as sodium, an ammonium ion or an ion derived from an organic amine; Ra' represents a C10-C30 alkyl or alkenyl group of an acid Ra'-C(O)OH preferably present in the copra oil or in hydrolyzed linseed oil, an alkyl group, in particular, with C17 and its iso form, a group with unsaturated C17.
[0252] These compounds of formula (A6) and (A7) are classified in the CTFA dictionary, 5th edition, 1993, under the names cocoamphodiacetate
[0253] As an example, the cocoamphodiacetate marketed by RHODIA under the trade name MIRANOL® C2M concentrate can be mentioned.
[0254] Compounds of formula (A'2);Ra''-NH-CH(Y'')-(CH2)nC(O)-NH-(CH2)n'-N(R(Re) )) (A'2)
[0255] Formula in which:Y" represents the group -C(O)OH, -C(O)OZ'', -CH2-CH(OH)-SOaH or the group -CH2-CH(OH)-SO3- Z'';Rd and Re, independently of one another, represent an alkyl or hydroxyalkyl radical with C1-C4Z" represents a cationic counterion originating from an alkali or alkaline earth metal, such as sodium, an ammonium ion or an ion originating of an organic amine; Ra" represents an alkyl or alkenyl group with C10 -C30 of an acid Ra'-C(O)OH preferably present in copra oil or hydrolyzed linseed oil. n and n' independently of one another , designate an integer ranging from 1 to 3.
[0256] Among the compounds of formula (A'2), the compound classified in the CTFA dictionary with the name "sodium diethylaminopropyl cocoaspartamide" and marketed by CHIMEX under the name CHIMEXANE HB can be mentioned.
[0257] Among the aforementioned amphoteric or zwitterionic surfactants, alkyl(C8-C2o) betaines such as cocobetaine, alkyl(C8-C2o)amidoalkyl(C3-C8)betaines such as cocamidopropylbetaine are preferably used. compounds of formula (B'2) such as diethylaminopropyl lauryl amino succinamate sodium salt (INCI name) sodium diethylaminopropyl cocoaspartamide) and mixtures thereof.
[0258] Preferably, the surfactant(s) can be chosen between nonionic surfactants, amphoteric or zwitterionic surfactants and cationic surfactants, silicone or not. STEPS B) AND C)
[0259] The process of cosmetic treatment of keratin fibers according to the present invention, comprises in particular steps b) and c) which consist respectively of applying a mechanical stress on these keratin fibers and exposing them under mechanical stress to microwaves at a pressure ranging from 50,000 to 250,000 Pa, more preferably from 75,000 to 150,000 Pa, most preferably at atmospheric pressure in the presence of at least one solvent in vapor form in contact with said keratin fibers and without there is complete drying of the keratin fibers during the entire exposure to the microwave.
[0260] In case of complete drying in step c), the modeling is not obtained.
[0261] Consequently, in particular, when steps a), b) and c) are carried out in that order, a step consisting in re-applying a certain amount of the composition from step a) or a certain amount of solvent may be performed somewhat before step c) (in order to ensure that the keratin fibers are kept moist).
[0262] It should be clear that when such step of applying a composition of step a) is performed again before step c), said composition contains the same substance as that which had been applied during step a), that is: - that it contains at least one grease substance when the composition of step a) contains at least one grease substance, - that it contains at least one non-silicone polymer when the composition of step a) contains at least one non-silicone polymer, and- that it contains at least one surfactant when the composition of step a) contains at least one surfactant.
[0263] During step b) the microwave radiation may or may not already exist, as does the solvent in vapor form. In other words, step b) is prior to or simultaneous with step c).
[0264] By "mechanical tension applied to these hairs", it is understood a mechanical tension applied to at least a portion of the length of said hairs.
[0265] "Microwave" means electromagnetic radiation with a frequency between 500 MHz and 300 GHz.
[0266] The microwave frequency used during step c) is preferably comprised between 500 MHz and 300 GHz, ranging, for example, from 500 MHz to 10 GHz, in particular, from 915 MHz to 2.45 GHz.
[0267] The power of the microwaves used during step c) can vary from 100 to 2000 W, preferably from 100 to 500 W, and more particularly from 180 to 450W.
[0268] Microwaves can be generated by a microwave generator, for example, a solid state generator such as a magnetron.
[0269] The expression “without complete drying of the hair” means that after step c) the hair has a damp touch. The hair can thus retain at least 1%, in particular at least 2%, and even 5% of the weight of the liquid compounds (solvents) present before step c), in contact with them, these liquid compounds add up to the hair's natural moisture before treatment.
[0270] The application of mechanical stress can be by a device for applying a mechanical stress, and this device can be configured to induce on the hair a bending, a traction, a twist and / or a compression, for example. The mechanical tension application device can exert mechanical tensions simultaneously on one or more locks of hair.
[0271] The mechanical tension device can be, for example, a roller.
[0272] The solvent in vapor form is entirely generated by the evaporation of a compound present, before the emission of microwaves, in contact with the treated hair.
[0273] Treated hair should never be completely dry during the entire period of microwave action. In other words, the hair must always be impregnated with the solvent during said exposure.
[0274] To facilitate impregnation, the solvent can be sprayed first.
[0275] Step c) of the process according to the present invention can occur inside a chamber possibly together with step b), in addition, steps b) and c) can be carried out in the same, single chamber. The chamber can form a microwave barrier.
[0276] The chamber can, during the process according to the present invention, in particular, during step c), contain the hair to be treated and the device for applying a mechanical tension.
[0277] By "containing the hair", it is understood to contain the hair in all or part of its length.
[0278] The camera can cover the hair over a length, for example, greater than or equal to 5 cm. Thus, a length of at least 5 cm of hair can be treated in the chamber.
[0279] The chamber can be immobile in relation to the treated hair during microwave emission or mobile in relation to the hair, being, for example, moved along the hair to be treated.
[0280] Microwaves can be emitted, if applicable, from an antenna.
[0281] As indicated above, the chamber can be configured not to release the solvent in the external environment in the form of vapor, or release only a small amount of it, thanks, for example, to a recycling of the solvent, and the recycling occurs, by example, in vapor or liquid form, after solvent condensation.
[0282] The chamber can contain a material configured to absorb the solvent in the form of vapor. The chamber may have a cold wall on which the solvent condenses and/or a suction port for the solvent in the form of vapor.
[0283] Thus, the process according to the present invention may comprise, during and/or after step c), a solvent collection step, for example, in the form of vapor and/or liquid and/or absorbed onto a material.
[0284] The chamber is advantageously substantially microwave-proof. In other words, the chamber can be configured to contain the microwaves emitted. Step c) can therefore take place inside a microwave-tight chamber.
[0285] The chamber can comprise at least one gasket of an electrically conductive material, for example, elastically deformable, which allows blocking the microwaves used during step c) while allowing the hair to leave the chamber if necessary. The joint can comprise, for example, a foam charged with electrically conductive particles, a brush made of electrically conductive bristles, or a comb comprising metal teeth.
[0286] When the chamber is in the form of a helmet, the chamber may contain an electromagnetic shield through which treated hair can pass. Such shielding allows you to treat the user's hair while protecting his/her skull from the microwaves emitted.
[0287] The electromagnetic shield can be formed, for example, by a grid or a metallic grid.
[0288] The treatment device that serves to carry out the process may include an audible and/or light warning system, for example to warn the user of a microwave leakage outside the chamber and/or an excessive temperature inside of the camera. The treatment device advantageously includes a safety system which prevents the emission of microwaves while the chamber is not closed and/or in case of abnormal operation, for example, with excessive temperature and/or in the absence of solvent.
[0289] The treatment device can be configured to control the emission duration of the microwaves, in order not to reach a treatment duration susceptible to damage the hair.
[0290] The process according to the present invention may comprise, before step c), a step of detecting the closure of the chamber. For example, a contactor is triggered when the chamber is closed.
[0291] The sending of the microwaves can be conditioned to the detection of the closing of the chamber.
[0292] The process according to the present invention can also include a step of detecting the placement of hair to be treated, before step c). This detection step can be carried out, for example, by an optical sensor and/or a mechanical probe.
[0293] The process according to the present invention can comprise, for example, during step c), a step of measuring the temperature to which the treated hair is subjected. This step of measuring the temperature can be performed by a thermometer without contact with the hair.
[0294] The chamber, for example, when it is defined by a clamp, can include all or part of the device for applying mechanical stress.
[0295] The mechanical tension application device may comprise one or more roller(s) or other winding device, which are, for example, electrically insulating and compatible with exposure to microwaves, jaws (jaws) and/or one or more combs.
[0296] The treatment device can be configured to allow using several different tension application devices, which serve, for example, to curl the hair or, conversely, to straighten them. Devices can be user-interchangeable.
[0297] The treatment device can be configured to automatically recognize the voltage application device used, if applicable, for example, thanks to electrical contacts or one or more switches.
[0298] The device for applying mechanical tension can be configured in order to place the treated hair horizontally during exposure to microwaves.
[0299] Whatever the embodiments considered, the hair treated during step b) can be subjected to one or a plurality of mechanical stresses. The mechanical stress(s) can be chosen from bending, grinding, compressive, torsional and/or tensile stresses. The applied tensions can aim to curl the hair or, on the contrary, to straighten it. The applied tensions can also aim to curl the hair over a portion of its length and curl it over another portion of its length.
[0300] According to a particular embodiment of the present invention, step b) is carried out by applying at least a torsional, traction or compression tension on the keratin materials.
[0301] The treatment device can include, inside the same handpiece, the microwave generator as well as the device for applying mechanical tension. By “hand piece”, it is understood a piece manipulated by the user in (with) one hand during the hair treatment.
[0302] When the treatment device includes a forceps, microwaves can be emitted by only one of the arms of the forceps or by all arms of the forceps.
[0303] As conducting means that can be used to drive the microwaves from the generator to the chamber, waveguides can be cited, for example, a flexible coaxial cable with a length of less than 10 m, preferably less than 5 m, with a diameter of less than 5 cm, preferably less than 2 cm, and the sets comprise at least one antenna emitting electromagnetic radiation and at least one antenna receiving electromagnetic radiation.
[0304] The microwave generator and/or the chamber can be configured to subject the hair treated during step c) to a microwave radiation variable in its spatial distribution inside the chamber, for example, rotating. A rotating microwave radiation can advantageously allow the treated hair to be exposed to such radiation in a more homogeneous way and thus reduce the risk of local overexposure to radiation.
[0305] The solvent(s) are, for example, liquids that have a boiling point lower than 200°C.
[0306] Said solvent can, for example, be and is preferably contained in the composition comprising at least one fatty substance from step a).
[0307] Said solvent may comprise, in particular, consist of a polar protic liquid medium having a dielectric constant at 20°C which is greater than or equal to 8, preferably greater than or equal to 10 and in particular greater than or equal to to 15.
[0308] According to a preferred embodiment, the solvents used comprise water. Most preferably, the solvent used is water.
[0309] According to another preferred embodiment, this solvent is propanol or isopropanol.
[0310] According to another preferred embodiment, the solvents are constituted by a mixture of water and propanol or isopropanol.
[0311] In an embodiment example, the solvent in vapor form can be generated by direct heating of the solvent in the liquid state by microwaves.
[0312] The solvent in vapor form may have in the vicinity and/or in contact with the hair, during step c), a temperature between 80 and 200°C, preferably between 100 and 150°C, for example between 120 and 150 °C.
[0313] The pressure to which the treated hair is subjected, during step c), is close to atmospheric pressure, it can vary from 50,000 to 250,000 Pa, more preferably from 75,000 to 150,000 Pa.
[0314] Hair may, during part or all of step c), be present in a volume defined by at least one wall of a material, which material allows microwaves to pass through the wall and limit evaporation of the present compound, before microwave emission, in contact with the treated hair.
[0315] The use of such material can advantageously limit the drying of hair during the treatment according to the present invention.
[0316] Said material can comprise and, in particular, consist of cellophane and/or have low porosity. In a variant, the material can be porous and in particular be a mesh.
[0317] Whatever the examples of realization considered, the duration of step c) may vary from 1 second to 60 minutes, preferably from 1 second to 30 minutes, more preferably from 30 seconds to 20 minutes, more particularly from 3 to 15 minutes.
[0318] Whatever the examples of realization considered, step c) can be repeated, for example between 0 and 10 times, preferably between 0 and 5 times. DESCRIPTION OF THE FIGURES
[0319] The present invention may be better understood by reading the detailed description below, non-limiting examples of the realization of said invention, and by examining the attached drawing, in which:- figures 1 to 5 represent, of schematically and partially, examples of embodiments of treatment devices according to the present invention, and figures 6, 7 and 9 to 13 represent locks of hair that have been subjected to various cosmetic treatments according to the process of the present invention. - figure 8 represents, in a schematic and partial way, an example of embodiment according to the present invention.
[0320] A treatment device 100 comprising a handpiece 3 which has a chamber in which the hair to be treated is received, connected by a hose 2 to a base station 1 which includes a micro generator is represented in Figure 1 . -waves.
[0321] Hose 2 can have a waveguide.
[0322] Figure 2 represents a detail of Figure 1.
[0323] The microwaves 70 led into the handpiece 3 by the waveguide 2 allow to heat the liquid solvent present on the hair to be treated and make it pass to the solvent state in the form of vapor. In this exemplary embodiment, a mechanical tensioning device as well as a lock of hair (not shown) are present in the handpiece 3 and the hairs are exposed at the same time to the microwave and the solvent in the form of a vapor 80. A temperature detector 150 can be present in order to measure the temperature of the treated lock of hair and a control system, for example, with a microprocessor, can allow to interrupt or modulate the microwave emission in case of a detected temperature higher than one predefined threshold.
[0324] In Figure 3, an example of embodiment is shown in which the treatment chamber is formed by closing a gripper that constitutes all or part of the handpiece 3. The gripper allows, when open, to introduce one or more between the arms locks of hair to be treated. Each arm defines, for example, the half of the chamber.
[0325] Microwaves can be emitted by only one or both arms of the clamp.
[0326] A sensor (not shown) can inform the treatment device of the fact that the gripper is closed and the microwave sending can be conditioned to the detection of this closure.
[0327] The mechanical tension applied to the hair can be a traction in order to straighten them.
[0328] In all the above examples, the microwave conducting means can comprise a transmitter antenna 10 and a receiver antenna 15, as illustrated in figure 4.
[0329] Figure 5 also shows a lock of hair M present in a treatment chamber of the handpiece 3. The chamber is microwave-tight and includes, for this purpose, for example, electrically foam gaskets 200 that reflects microwave radiation where the hair leaves the chamber.
[0330] In a variant not illustrated, the microwave generator 1 can, for example, be present in the chamber and/or in the device for applying a mechanical stress.
[0331] Figure 8 represents an example of an embodiment in which a lock of hair M is present in a volume delimited by a wall 300 of a material, which material allows the microwaves 70 to pass through the wall, and contains the 80 steam generated.
[0332] The levels of steam 80 advantageously allow to moisten the hair M during the treatment.
[0333] Said material comprises, and in particular, consists of a cellophane film. In a variant, the material can be porous and in particular be a mesh. STEPS D) AND E)
[0334] The process according to the present invention may also comprise at least one additional pre-treatment step d) and/or an additional post-treatment step e), and these steps consist of performing on the keratin materials at least one classic treatment chosen from oxidation coloration, direct coloration, discoloration, permanent deformation based on one or more reducing agents, for example thiolates or based on one or more alkali or alkaline earth hydroxides, a care, a mask and/or shampoo.
[0335] Advantageously, when the composition of step a) is a composition containing at least one fatty substance, the composition(s) applied during the additional step(s) d) are free of fatty substances.
[0336] Advantageously, when the composition of step a) is a composition containing at least one fatty substance, the composition(s) applied during the additional step(s) e) are free of grease substances.
[0337] Advantageously, when the composition of step a) is a composition containing at least one non-silicone polymer, the composition(s) applied during the additional step(s) d) are free of non-silicone polymer.
[0338] Advantageously, when the composition of step a) is a composition containing at least one non-silicone polymer, the composition(s) applied during the additional step(s) e) are free of non-silicone polymer.
[0339] Advantageously, when the composition of step a) is a composition containing at least one surfactant, the composition(s) applied during the additional step(s) d) are free of surfactant.
[0340] Advantageously, when the composition of step a) is a composition containing at least one surfactant, the composition(s) applied during the additional step(s) e) are free of surfactant.
[0341] Step d) occurs before steps a), b) and c).
[0342] Step e) occurs after steps a), b) and c).
[0343] When an additional pre-treatment step d) and an additional post-treatment step e) are performed, these steps may be identical or different, preferably they are different.
[0344] According to a preferred embodiment of the present invention, the additional step is a pre-treatment step d).
[0345] When the additional step is a step comprising a permanent deformation based on one or more reducers, then this step can be followed by a step comprising applying to the hair at least one fixing composition comprising one or more oxidizing agents.
[0346] Advantageously, the composition(s) applied during the additional step(s) d) are free of alkaline or alkaline-earth hydroxides at a pH greater than 12 or of reducing agents that allow the rupture of the disulfide bonds.
[0347] Advantageously, the composition(s) applied during the additional step(s) e) are free of alkali or alkaline-earth hydroxides at a pH greater than 12 or of reducing agents that allow the rupture of the disulfide bonds.
[0348] The duration of step d) may vary according to the desired styling performances and the nature of the hair, for example.
[0349] The composition used in step a) as well as any compositions used in additional steps d) and e) can be applied while the hair is present in the chamber, for example thanks to an appropriate application system. The application system comprises, for example, a plug, a comb, one or more dispensing orifices or a spray nozzle, disposed in or outside the chamber, for example, in the path of the hair leaving the chamber or entering it.
[0350] The composition used in step d) can be subjected to microwave radiation.
[0351] The treatment device can have a sensor sensitive to a hair characteristic, for example, color, mechanical strength, surface condition, moisture, and the treatment device can control at least one treatment parameter in a function of the characteristic thus detected, for example microwave energy, solvent temperature, duration of treatment and/or mechanical stress exerted.
[0352] According to another of its aspects, the present invention deals with a hair treatment device for carrying out the process as defined above, which comprises: - a device for applying a mechanical tension to the hair, - a generator microwave oven, - at least one composition comprising at least one substance chosen from fatty substances, silicone polymers and surfactants.
[0353] All characteristics specified in relation to the above process apply to the treatment device.
[0354] Thus, the treatment device can, for example, define a treatment chamber that forms a barrier to microwaves.
[0355] All the compositions used in the process according to the present invention can be presented independently of one another in the form of a lotion, thickened or not, a cream, a gel or a foam.
[0356] The following examples are given for illustrative and non-limiting purposes of the present invention. EXAMPLESEXAMPLE 1PROCESS FOR LASTING CURLING OF HAIR THROUGH A COMPOSITION THAT CONTAINS AT LEAST ONE GREASE SUBSTANCE
[0357] A moistened 1 g, 20 cm lock of natural straight hair was treated as follows.
[0358] The swab is washed with shampoo and drained, and an aqueous composition according to the present invention comprising at least one grease substance is applied with a bath ratio 2 to 1 at least regularly along the swab.
[0359] The roving is then wound and secured around a roll.
[0360] The wick is then placed in a confined medium (cellophane type) or not, and is treated by microwave emission with a household microwave (SAMSUNG Combi CE 137nem; 2.45GHz) for 15 minutes with a power of 300W.
[0361] The end of treatment is followed by a rinse or shampoo wash depending on the case.
[0362] The table below indicates the aqueous composition applied.


[0363] This process allows a modeling of the roving (initially smooth), the roving obtained is wavy in a lasting way, and a gain in roving volume was also observed.
[0364] The result is reported in Figure 6. EXAMPLE 2PROCESS FOR LASTING CURLING OF HAIR THROUGH A COMPOSITION THAT CONTAINS AT LEAST ONE GREASE SUBSTANCE
[0365] A lock of natural straight hair of 1 g of 20 cm moistened was treated in a similar way to example 1, with the difference that the aqueous composition applied here is the one detailed in the table below.


[0366] This process allows a strand shaping, the strand obtained is wavy in a lasting way, and a gain in roving volume was also observed.
[0367] The result is reported in Figure 7. EXAMPLE 3PROCESS FOR LONG-LASTING HAIR CURLING THROUGH A COMPOSITION CONTAINING AT LEAST ONE NON-SILICONATE POLYMER
[0368] A damp, 1 g, 20 cm lock of natural straight hair was treated as follows.
[0369] The lock is washed with shampoo and drained and an aqueous composition according to the present invention comprising at least one non-silicone polymer is applied with a bath ratio 2 to 1 at least regularly along the lock.
[0370] The roving is then wound and secured around a roll.
[0371] The wick is then placed in a confined medium (cellophane type) and is microwaved with a household microwave (SAMSUNG Combi CE 137nem; 2.45GHz) for 5 minutes at a power of 450 W.
[0372] The end of treatment is followed by a rinse or shampoo wash depending on the case.
[0373] The table below indicates the aqueous composition applied.


[0374] This process allows a modeling of the roving (initially smooth), the roving obtained is wavy in a lasting way, and a gain in roving volume was also observed.
[0375] The result is reported in Figure 9. EXAMPLE 4 PROCESS FOR LONG-LASTING HAIR CURLING THROUGH A COMPOSITION CONTAINING AT LEAST ONE NON-SILICONATE POLYMER
[0376] A lock of natural straight hair of 1 g of 20 cm moistened was treated similarly to example 1, with the aqueous composition detailed in the table below.

[0377] This process allows a strand shaping, the strand obtained is wavy in a lasting way, and a gain in strand volume was also observed.
[0378] The result is reported in figure 10. EXAMPLE 5PROCESS FOR LONG-LASTING HAIR CURLING THROUGH A COMPOSITION CONTAINING AT LEAST ONE NON-SILICONATE POLYMER
[0379] A lock of natural straight hair of 1 g of 20 cm moistened was treated similarly to example 1, with the aqueous composition detailed in the table below.

[0380] This process allows a strand shaping, the strand obtained is wavy in a lasting way, and a gain in strand volume was also observed.
[0381] The result is reported in Figure 11. EXAMPLE 6PROCESS FOR LASTING CURLING THE HAIR THROUGH A COMPOSITION THAT CONTAINS AT LEAST ONE SURFACE-ACTIVE
[0382] A moistened 1 g, 20 cm lock of natural straight hair was treated as follows.
[0383] The lock is washed with shampoo and drained and an aqueous composition according to the present invention which comprises at least one surfactant is applied with a bath ratio 2 to 1 at least regularly along the lock.
[0384] The roving is then wound and secured around a roll.
[0385] The wick is then placed in a confined medium (cellophane film type), and is microwaved with a household microwave (SAMSUNG Combi CE 137nem, 2.5GHz) for 5 minutes with a power of 450 W.
[0386] The end of treatment is followed by a rinse or shampoo wash depending on the case.
[0387] The table below indicates the aqueous composition applied.


[0388] This process allows a strand shaping (initially anionic), the strand obtained is wavy in a lasting way, and a gain in strand volume was also observed.
[0389] The result is reported in Figure 12. EXAMPLE 7PROCESS FOR LASTING CURLING THE HAIR THROUGH A COMPOSITION THAT CONTAINS AT LEAST ONE SURFACE-ACTIVE
[0390] A lock of natural straight hair of 1 g of 20 cm moistened was treated in a similar way to example 1, with the difference that the aqueous composition applied here is the one detailed in the table below.


[0391] This process allows a strand shaping, the strand obtained is wavy in a lasting way, and a gain in roving volume was also observed.
[0392] The result is reported in Figure 13.

权利要求:
Claims (15)
[0001]
1. COSMETIC TREATMENT PROCESS of keratin fibers, preferably hair, characterized in that it comprises at least the steps consisting of: a) applying, on said keratin fibers, an aqueous composition containing at least one substance chosen from among fatty substances , and non-silicone polymers, said composition being free of hydroxides of alkali metals or alkaline earth metals at a pH greater than 12, or being free of reducing agents that allow the rupture of the disulfide bonds; b) applying mechanical stress to the said keratin fibers, and c) exposing said keratin fibers under mechanical tension to microwaves, at a pressure ranging from 50,000 to 250,000 Pa, in the presence of at least one solvent comprising water in the form of steam in contact with the keratin fibers and without complete drying of the keratin fibers during the entire exposure to the microwave, in which the duration of step c) varies from 1 second o to 60 minutes, the solvent(s) that comprise(s) water in the form of vapor are entirely generated by the evaporation of water in the present liquid form, before the emission of the microwaves, in contact with the keratin fibers, step a) occurring before step c).
[0002]
Process according to claim 1, characterized in that the pressure varies from 75,000 to 150,000 Pa, preferably the pressure is atmospheric pressure.
[0003]
Process according to any one of claims 1 to 2, characterized in that the composition of step a) contains at least one fatty substance.
[0004]
4. Process according to claim 3, characterized in that said grease substance(s) is chosen among hydrocarbons with C6-C16, hydrocarbons with more than 16 atoms of carbon, non-silicone oils of animal origin, vegetable oils of the triglyceride type, synthetic triglycerides, fluorinated oils, fatty alcohols, non-salified fatty acids, fatty acid and/or fatty alcohol esters other than triglycerides and vegetable waxes, non-silicone waxes , silicones, and mixtures thereof.
[0005]
5. Process according to any one of claims 1 to 2, characterized in that the grease substance(s) is (are) advantageously chosen from hydrocarbon waxes, vegetable waxes, solid fatty alcohols, esters of solid fatty acid and/or fatty alcohol, or mixtures thereof.
[0006]
Process according to any one of claims 1 to 2, characterized in that the composition of step a) contains at least one non-silicone polymer.
[0007]
Process according to claim 6, characterized in that the non-silicone polymer(s) is(are) one of the thickening polymers chosen among cellulosic thickeners, in particular, hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylcellulose, gum guar and its derivatives, in particular, hydroxypropylguar, gums of microbial origin, in particular, xanthan gum, scleroglucan gum, crosslinked homopolymers of acrylic acid or of acrylamidopropanesulfonic acid, and associative polymers.
[0008]
Process according to claim 6, characterized in that said non-silicone polymer(s) is (are) one or more fixative polymers chosen from: 9. the monoesterified methylvinylether/maleic anhydride copolymers;10. acrylic acid/ethyl acrylate/N-tertiobutylacrylamide terpolymers; 11. copolymers of methacrylic acid and methyl methacrylate;12. vinyl acetate/vinyl tertiary butylbenzoate/crotonic acid terpolymers;13. the crotonic acid/vinyl acetate/vinyl neododecanoate terpolymers;14. copolymers of methacrylic acid and ethyl acrylate;15. acrylamide and dimethylaminoethyl methacrylate copolymers quaternized with dimethyl sulfate or with a dimethyl halide; acrylamide and methacryloyloxy-ethyl-trimethyl-ammonium chloride copolymers;17. acrylamide and methacryloyloxy-ethyl-trimethyl-ammonium methosulfate copolymers;18. the copolymers of vinylpyrrolidone/acrylate or dialkyl-amino-alkyl methacrylate quaternized or not;19. dimethylaminoethyl methacrylate/vinyl-caprolactam/vinylpyrrolidone terpolymers; the quaternized vinylpyrrolidone/dimethylaminopropyl methacrylamide copolymers;21. the quaternary copolymers of vinylpyrrolidone and devinylimidazole;22. chitosans or their salts;23. polymers containing units deriving: a) from at least one monomer chosen from among acrylamides or methacrylamides substituted on the nitrogen atom by an alkyl group, b) from at least one acidic comonomer containing one or more reactive carboxylic groups, and c ) of at least one basic comonomer such as primary, secondary, tertiary and quaternary amine substituted esters of acrylic and methacrylic acids, and the quaternization product of dimethylaminoethyl methacrylate with dimethyl or diethyl sulfate, - the copolymers methyl methacrylate/dimethyl-carboxy-methyl-ammonium-ethyl-methyl methacrylate;- polyalkyloxazolines;- vinyl acetate homopolymers;- vinyl acetate copolymers;- nonionic acrylic ester homopolymers and copolymers;- copolymers of acrylonitrile and a nonionic monomer; - homo and copolymers of styrene; - polyamides; - homopolymers of vinyl lactam, such as homopolymers of vinylpyrro lidone, polyvinylcaprolactam, and vinyl lactam copolymers such as poly(vinylpyrrolidone/vinyl acetate) copolymers.
[0009]
Process according to claim 6, characterized in that said non-silicone polymer(s) is (are) one or more conditioning polymers chosen from: - the cyclopolymers of alkyl diallyl amine salts or of dialkyl diallyl ammonium;- quaternary diammonium polymers, and- cationic polysaccharides, in particular cationic celluloses and galactomannan gums.
[0010]
Process according to any one of Claims 1 to 9, characterized in that the composition of step a) comprises from 20 to 99.9% by weight of water, relative to the total weight of said composition.
[0011]
11. Process according to any one of claims 1 to 10, characterized in that step a) is prior to step b).
[0012]
Process according to any one of claims 1 to 11, characterized in that step b) is carried out by applying at least a torsional, traction or compression tension on the keratin materials.
[0013]
Process according to any one of claims 1 to 12, characterized in that the duration of step c) varies from 1 second to 30 minutes, more preferably from 30 seconds to 20 minutes, more particularly from 3 to 15 minutes.
[0014]
Process according to any one of claims 1 to 13, characterized in that the solvent used is water.
[0015]
15. Process according to any one of claims 1 to 14, characterized in that it comprises at least one additional pre-treatment step d) and/or an additional post-treatment step e), and these steps consist of performing on the keratin materials at least one classic treatment chosen from oxidation coloration, direct coloration, discoloration, permanent deformation based on one or more reducing agents, for example thiols and/or based on one or more alkali or alkaline-earth hydroxides , a care, a mask and/or a shampoo wash.

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法律状态:
2018-12-04| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|

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2020-05-19| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|

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2021-06-01| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|

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2021-07-13| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 06/06/2013, OBSERVADAS AS CONDICOES LEGAIS. |

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2021-07-27| B16C| Correction of notification of the grant [chapter 16.3 patent gazette]|Free format text: REF. RPI 2636 DE 13/07/2021 QUANTO A PRIORIDADE UNIONISTA. |

优先权:

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申请号 | 申请日 | 专利标题

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FR1255307|2012-06-07|

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FR1255310|2012-06-07|

---

FR1255309|2012-06-07|

---

FR1255310A|FR2991559B1|2012-06-07|2012-06-07|CAPILLARY SHAPING METHOD USING FAT BODIES|

---

FR1255309A|FR2991558B1|2012-06-07|2012-06-07|CAPILLARY FORMING METHOD USING POLYMERS|

---

FR1255307A|FR2991557B1|2012-06-07|2012-06-07|CAPILLARY FORMING METHOD USING SURFACTANTS|

---

US201261701648P| true| 2012-09-15|2012-09-15|

---

US201261701650P| true| 2012-09-15|2012-09-15|

---

US201261701649P| true| 2012-09-15|2012-09-15|

---

US61/701,649|2012-09-15|

---

US61/701,648|2012-09-15|

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PCT/IB2013/054655|WO2013183021A1|2012-06-07|2013-06-06|Method of shaping hair using fatty bodies, non-silicone polymers or surfactants|

---