• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    Absorbent article comprising polymeric foam and intermediates Absorbent articles comprising an absorbent composite are described. The absorbent composite comprises a first absorbent layer comprising a polymeric foam having an average cell size of at least 100 microns. the polymeric foam has at least one property selected from (a) an indentation force deflection of less than 75 n to 50%; or (b) a constant deflection compression strain of less than 25% for a deflection of 50%; or a combination of a) and b); and a second absorbent layer in fluid communication with the fluid transport layer. In another embodiment, the second absorbent layer has an average absorption capacity of at least 20 g / g. In another embodiment, a polyurethane foam is described as having an average cell size of at least 100 microns. The polyurethane foam comprises the reaction product of at least one polyol component having poly (ethylene oxide) units and a polyisocyanate component comprising at least 75% by weight of at least one bond-free polymeric polyisocyanate. urethane. In some embodiments, the polyurethane foam is free of superabsorbent polymer. In some embodiments, polyurethane foam has an average cell size of up to 500 microns. In some embodiments, the polyurethane foam comprises at least 12% by weight of ethylene oxide units. Also described are various composites comprising the polyurethane foam described herein in combination with another substrate such as a second absorbent layer, a fluid impermeable bottom layer, and / or a fluid permeable top layer.
    公开号:BR112014029833B1
    申请号:R112014029833-5
    申请日:2013-04-05
    公开日:2019-10-01
    发明作者:Delton R. Thompson；Robert L. Rowan
    申请人:3M Innovative Properties Company；
    IPC主号:
    专利说明:

    “ABSORBENT ARTICLE THAT UNDERSTANDS POLYMERIC FOAM AND INTERMEDIARIES”
    Background of the invention [001] In the field of disposable absorbent articles, "superabsorbent polymers" (PSA - superabsorbent polymers) mixed with cellulose fibers provide a good storage medium for aqueous fluids. However, it has also been described that these materials do not accentuate fluid transport. When a phenomenon often called “gel block” occurs, a reduction in fluid transport can occur.
    [002] In this way, many absorbent core designs have been described that comprise components or layers with separate functionalities, that is, a liquid storage material and also a different material that provides the capture and distribution of the fluid ("ADF" - acquisition and distribution of the fluid).
    [003] Open cell polymeric foams for use in disposable absorbents have been described. A type of foam that has been described is produced from high internal phase emulsions (also called “HIPE” - high internai phase emulsions). Polyurethane foams for use in disposable absorbent articles have also been described.
    Summary [004] Although several absorbent articles have been described, it would be advantageous for the industry to produce alternative absorbent articles, particularly those that have improved properties.
    [005] In one embodiment, an absorbent article is described which comprises an absorbent composite disposed between a fluid-permeable top layer and a fluid-impermeable bottom layer. The absorbent composite comprises a first absorbent layer comprising a polymeric foam which has
    2/42 an average cell size of at least 100 microns. The polymeric foam has at least one property selected from a) an indentation force deflection of less than 75 N at 50%; or b) a compression deflection at constant deflection less than 25% for a deflection of 50%; or a combination of a) and b); and a second absorbent layer in fluid communication with the fluid transport layer.
    [006] In another embodiment, a polyurethane foam is described as having an average cell size of at least 100 microns. The polyurethane foam comprises the reaction product of at least one polyol component that has units of poly (ethylene oxide) and a polyisocyanate component that comprises at least 75% by weight of at least one polymeric polyisocyanate devoid of urethane connections. In some embodiments, the polyurethane foam is free of superabsorbent polymer. In some embodiments, the polyurethane foam has an average cell size of up to 500 microns. In some embodiments, the polyurethane foam comprises at least 12% by weight of ethylene oxide units.
    [007] In another embodiment, an absorbent article is described comprising an absorbent composite. The absorbent composite comprises a first absorbent layer comprising a polymeric foam, the polymeric foam being free of superabsorbent polymer and having a cell size of at least 100 microns. The absorbent composite additionally comprises a second absorbent layer that has an average absorption capacity of at least 20 g / g in fluid communication with the fluid transport layer.
    [008] Various composites are also described which comprise the polyurethane foam described herein in combination with another substrate such as a second absorbent layer, a fluid impermeable bottom layer, and / or a
    3/42 fluid-permeable top layer.
    Brief description of the drawings [009] Figures 1 to 4 are seen in cross-section of absorbent articles comprising an absorbent composite, the absorbent composite having several arrangements of first and second absorbent layers.
    Detailed description [010] Referring to Figure 1, a cross-sectional view of an absorbent article is shown which comprises an absorbent composite 10 disposed between the fluid-permeable top layer 40 and the fluid-impermeable bottom layer 50. The absorbent composite comprises a first absorbent layer 20 and a second absorbent layer 30 in fluid communication with each other. The first absorbent layer comprises a polymeric foam 21. The layers are close enough (i.e., close to) to each other so that the fluid from the first layer is readily transported to the second layer. In some modalities, the first and second layers are in direct contact with each other. In other embodiments, one or more additional layers are arranged between the first and the second layer. This additional layer or layers does not reduce the desired properties of the absorbent composite (for example, absorbency, penetration and re-humidification). In one embodiment, a layer of fabric is arranged between the first and second absorbent layers. Preferred absorbent items include feminine hygiene items, and adult incontinence items.
    [011] In a preferred embodiment, the first absorbent layer works as, and therefore will be called, "fluid transport layer". The fluid transport layers quickly absorb the liquid through the top layer of the absorbent article for temporary retention (for example, to act as a temporary reservoir), and to transfer that liquid to the
    4/42 second absorbent layer underlying a rate at which the second absorbent layer can absorb the liquid for permanent or final retention. Fluid transport typically optimizes the “capillary effect absorption” of the absorbent article by spreading the body fluid in the “x” and “y” plane over the area of the second absorbent layer covered by the fluid transport layer, also transporting the fluid in the direction “Z” for the second absorbent layer.
    [012] The absorbent composite comprises a first absorbent layer that comprises a polymeric foam material. The polymeric foam comprises a continuous phase of a hydrophilic polymer. The term "continuous" means that the cell structure is substantially continuous, free of discernible contours within the cell structure. In contrast, a layer formed from foam particles would be characterized in that it comprises a discontinuous layer, since a plurality of distinct contours would be evident between the neighboring foam particles. The foam of the absorbent composite optionally comprises separate pieces of superabsorbent polymer dispersed within the polymeric foam. When present, the distinct pieces of the superabsorbent polymer are typically distributed homogeneously within the polymeric foam.
    [013] The polymeric foams described here are predominantly open cell. This means that the individual foam cells are in complete and unobstructed communication with the adjacent cells. The cells in these substantially open cell foam structures have intercellular openings, or "windows" that are large enough to allow the transfer of fluids from one cell to another within the foam structure. Individual cells can be defined by a plurality of mutually connected and branched blankets in three dimensions. The wicks of polymeric material that form these branched blankets can be called "struts". The material of
    5/42 foam is typically “open cell” if at least 80% of the cells in the foam structure that are at least 1 micrometer in size are in fluid communication with at least one adjacent cell. In this way, a portion of the cells (up to 20%) of the foam can be closed. The minimum cell size is typically at least 5, 10, 15, 20, 25, or 30 micrometers.
    [014] In addition to being open cell, polymeric foams are sufficiently hydrophilic to allow the foam to absorb aqueous fluids. The internal surfaces of the foam structures can be rendered hydrophilic by selecting components (for example hydrophilic) during polymeric foam formation or by further treatment.
    [015] The average cell size of the total total foam structure is typically at least 100 microns. In some embodiments, the average cell size is at least 110, 120, 130, 140, or 150 microns. The average cell is typically no larger than 1000, 900, 800, or 700 microns. In some embodiments, the average cell size cannot be greater than 650 microns, 600 microns, 550 microns, 500 microns, 450 microns, 400 microns, 350 microns, or 300 microns. As used here, the average cell size refers to the size as determined using a scanning electron microscope at 50X magnification, as further described in the examples.
    [016] In some embodiments, the foam has a relatively uniform cell size. For example, the average cell size on a main surface can be around it or vary by no more than 10% compared to the opposite main surface. In other embodiments, the average cell size of a main foam surface may differ from the opposite surface. For example, in the foaming of a thermoset material it is not uncommon for a portion of the cells at the bottom of the cell structure to be flattened, resulting in a lower average cell size on a surface.
    6/42
    When the foam has a medium cell size gradient, it is preferred that the surface having the smallest average cell size is in fluid communication with the second (e.g., fluid storage) absorbent layer.
    [017] The foam is typically a non-compacted foam. Uncompacted foam does not expand substantially when it comes into contact with aqueous fluids, such as body fluids.
    [018] In preferred embodiments, the foam of the first absorbent layer (for example fluid transport) is a polyurethane foam. Polyurethane polymers are generally formed by the reaction of at least one polyisocyanate component and at least one polyol component. The polyisocyanate component can comprise one or more polyisocyanates. The polyol component can comprise one or more polyols. The concentration of a polyol can be expressed in relation to the total polyol component. The concentration of polyol or polyisocyanate can alternatively be expressed in relation to the total polyurethane concentration.
    [019] Various aliphatic or aromatic polyisocyanates have been described in the art. The polyisocyanate used to form the polyurethane foam typically has a functionality between 2 and 3. In some embodiments, the functionality is not greater than about 2.5.
    [020] In one embodiment, the foam is prepared from at least one aromatic polyisocyanate. Examples of aromatic polyisocyanates include those having a unique aromatic ring such as toluenes 2,4 and 2,6-diisocyanate (TDI) and naphthylene 1,5-diisocyanate; as well as those that have at least two aromatic rings like 4,4'-, 2,4'- and 2,2'-diisocyanate (MDI) diphenylmethane.
    [021] In preferred embodiments, the foam is prepared from one or more polymeric polyisocyanates (for example, aromatic). Polymeric polyisocyanates typically have an average molecular weight (weight average) greater than
    7/42 a monomeric polyisocyanate (without repetition units), even lower than a polyurethane prepolymer. Thus, the polyurethane foam is derived from at least one polymeric polyisocyanate free of urethane bonds. In other words, the polyurethane foam is derived from a polymeric isocyanate that is not a polyurethane prepolymer. Polymeric polyisocyanates comprise other linking groups between repeating units, such as isocyanurate groups, biuret groups, carbodiimide groups, uretonimine groups, uretidione groups, etc. as known in the art.
    [022] Some polymeric polyisocyanates can be called "modified monomeric isocyanate". For example, pure 4,4'-methylene diphenyl diisocyanate (MDI) is a solid having a melting point of 38 ° C and an equivalent weight of 125 g / equivalent. However, modified MDIs are liquid at 38 ° C and have a higher equivalent weight (eg 143 g / equivalent). It is believed that the difference in melting point and equivalent weight is the result of a small degree of polymerization, such as by the inclusion of linker groups, as described above.
    [023] Polymeric polyisocyanates, including modified monomeric isocyanate, may comprise a monomer mixture in combination with polymeric species including oligomeric species. For example, it is reported that the polymeric MDI contains 25 to 80% of 4,4'-methylene diphenyl monomeric diisocyanate as well as oligomers containing 3 to 6 rings and other smaller isomers, such as 2.2 'isomer.
    [024] Polymeric polyisocyanates typically have a low viscosity compared to prepolymers. The polymeric isocyanates used in the present invention typically have a viscosity not greater than about 300 cps at 25 ° C and in some embodiments not greater than 200 cps or 100 cps at 25 ° C. Viscosity is typically at least about 10, 15, 20 or 25 cps at 25 ° C.
    [025] The equivalent weight of polymeric polyisocyanates is also
    8/42 typically lower than that of prepolymers. The polymeric isocyanates used in the present invention typically have an equivalent weight not greater than about 250 g / equivalent and in some embodiments not greater than 200 g / equivalent or 175 g / equivalent. In some embodiments, the equivalent weight is at least 130 g / equivalent.
    [026] The average molecular weight (Mw) of polymeric polyisocyanates is also typically lower than that of polyurethane prepolymers. The polymeric isocyanates used in the present invention typically have an average molecular weight (Mw) not greater than about 500 Da and in some embodiments not greater than 450, 400, or 350 Da.
    [027] In some embodiments, polyurethane is derived from a simple polymeric isocyanate or a blend of polymeric isocyanates. Thus, 100% of the isocyanate component consists of polymeric isocyanate (s). In other embodiments, a major portion of the isocyanate component is a simple polymeric isocyanate or a blend of polymeric isocyanates. In these embodiments, at least 50, 60, 70, 75, 80, 85 or 90%, by weight, of the isocyanate component is formed of polymeric isocyanate (s).
    [028] Some illustrative polyisocyanates include, for example, polymeric MDI diisocyanate available from Huntsman Chemical Company, The Woodlands, TX, USA, under the trade name “RUBINATE 1245”; and modified MDI isocyanate available from Huntsman Chemical Company under the trade name “SUPRASEC 9561”.
    [029] The aforementioned isocyanates are reacted with a polyol to prepare a polyurethane foam material. Polyurethane foams are hydrophilic, so the foam absorbs aqueous liquids, particularly body fluids. The hydrophilic capacity of polyurethane foams is typically provided by the use of an isocyanate-reactive component, such as a polyether polyol, having a
    9/42 high content of ethylene oxide. Examples of useful polyols include adductors [for example, poly (ethylene oxide), polypropylene oxide, and poly (ethylene oxide-propylene oxide) copolymer] of dihydric or trihydric alcohols (for example, ethylene glycol, propylene glycol, glycerol, hexane triol, and triethanolamine) and alkylene oxides (for example, ethylene oxide, propylene oxide, and butylene oxide). Polyols having a high ethylene oxide content can also be prepared by other techniques, as known in the art. Suitable polyols typically have a molecular weight (MW) of 100 to 5,000 Da and contain an average functionality of 2 to 3.
    [030] Polyurethane foam is typically derived (or in other words is the reaction product of) at least one polyether polyol having (for example, repeated) units of ethylene oxide. The polyether polyol typically has an ethylene oxide content of at least 10, 15, 20 or 25% by weight, and typically not more than 75% by weight. This polyether polyol has a higher functionality than the polyisocyanate. In some embodiments, the average functionality is about 3. The polyether polyol typically has a viscosity not greater than 1000cps at 25 ° C and in some embodiments not greater than 900, 800, or 700 cps. The molecular weight of the polyether polyol is typically at least 500 or 1000 Da and in some embodiments no greater than 4000 or 3500, or 3000 Da. This polyether polyol typically has a hydroxyl number of at least 125, 130, or 140. One Illustrative polyol includes, for example, a polyether polyol product obtained from Carpenter Company, Richmond, VA, USA, under the designations “CDB-33142 POLYETHER POLYOL”, “CARPOL GP-5171” and EB-PO-11034-1 ” [031] In some embodiments, one or more polyether polyols having a high ethylene oxide content and a molecular weight (PM) of not more than 5500, or 5000, or 4500, or 4000, or 3500, or 3000 Da, as exactly described, are the primary or unique polyether polyols of the polyurethane foam. For example, these polyols
    10/42 polyethers make up at least 50, 60, 70, 80, 90, 95 or 100%, by weight) of the total polyol component. Accordingly, the polyurethane foam may comprise at least 25, 30, 35, 40, 45 or 50%, by weight, of polymerized units derived from such polyether polyols.
    [032] In other embodiments, one or more polyether polyols having a high ethylene oxide content are used in combination with other polyols. In some embodiments, the other polyols make up at least 1,2,3, 4, or 5%, of the total polyol component. The concentration of these other polyols typically does not exceed 40, or 35, or 30, or 25, or 20, or 15, or 10%, by weight, of the total polyol component, that is, it does not exceed 20%, by weight, or 17.5% by weight or 15% or 12.5% by weight or 10% by weight or 7.5% by weight or 5% by weight of the polyurethane. Other illustrative polyols include a polyether polyol product (Chemical Abstracts Number 25791-96-2) that can be obtained from the Carpenter Company, Richmond, VA, USA, under the designation “CARPOL GP-700 POLYETHER POLYOL” and a polyether polyol product (Chemical Abstracts Number 9082-00-2) which can be obtained from Bayer Material Science, Pittsburgh, VA, USA, under the trade name “ARCOL E-434”. In some embodiments, these other optional polyols may comprise polypropylene (for example, repetitive) units.
    [033] Polyurethane foam generally has an ethylene oxide content of at least 10, 11, or 12% by weight, and not more than 20, 19, or 18% by weight. In some embodiments, the polyurethane foam has an ethylene oxide content of no more than 17 or 16% by weight.
    [034] The types and amounts of polyisocyanate and polyol components are selected so that the polyurethane foam is relatively soft, yet resilient. These properties can be characterized, for example, by an indentation force deflection and compression deflection at constant deflection, as measured according to the test methods described in
    11/42 examples. In some embodiments, the polyurethane foam has an indentation force deflection of less than 75 N at 50%. The 50% indentation force deflection can be less than 70 N, or 65 N, or 60 N. In some embodiments, polyurethane foam has an indentation force deflection of less than 100 N at 65%. The indentation force deflection at 65% can be less than 90 N, or 80 N, or 70 N, or 65 N, or 60 N. In some embodiments, the indentation force deflection at 50% or 65% is typically at least 30 N or 35 N. The constant deflection compression strain at 50% deflection can be zero and is typically at least 0.5, 1 or 2% and generally not greater than 35%. In some embodiments, the compression deflection from constant deflection to 50% deflection is not greater than 30%, or 25%, or 20%, or 15%, or 10%.
    [035] The polyurethane foam may comprise known and customary polyurethane forming catalysts such as organic tin compounds and / or an amine type catalyst. The catalysts are preferably used in an amount of about 0.01 to 5%, by weight, of the polyurethane. The amine type catalyst is typically a tertiary amine. Examples of suitable tertiary amine include monoamines such as triethylamine, and dimethyl cyclohexylamine; diamines such as tetramethylethylenediamine, and tetramethylhexanediamine; triamines such as tetramethylguanidine; cyclic amines such as triethylenediamine, dimethylpiperadine, and methylmorphorin; alcohololamines such as dimethyl amino ethanol, trimethyl aminoethyl ethanolamine, and hydroxyethylmorphine; Ether amines such as bisdimethyl aminoethyl ethanol; diazabicycloalkenes such as 1,5-diazabicyclo (5,4,0) undecene-7 (DBU), and 1,5 diazabicyclo (4,3,0) nonene-5; and organic acid salts of diazabicycloalkenes such as phenol salt, 2-ethylhexanoate and DBU formate. These amines can be used alone or in combination. The amine type catalyst can be used in an amount not greater than 4, 3, 2, 1 or 0.5%, by weight, of the polyurethane.
    [036] Polyurethane typically comprises a surfactant to stabilize the
    12/42 foam. Several surfactants have been described in the art. In one embodiment, a silicone surfactant is used which comprises (for example, repeats) ethylene oxide units, optionally in combination with propylene oxide units (for example, repeats), as is commercially available from Air Products under the trade name “DABCO DC-198”. In some embodiments, the concentration of hydrophilic surfactant is typically in the range of about 0.05 to 1 or 2%, by weight of the polyurethane.
    [037] Polyurethane foam can comprise various additives such as surface active substances, foam stabilizers, cell regulators, blocking agents to delay catalytic reactions, flame retardants, chain extenders, crosslinking agents, internal mold release agents and external, fillers, pigments (titanium dioxide), dyes, optical brighteners, antioxidants, stabilizers, hydrolysis inhibitors, as well as antifungal and antibacterial substances. Such other additives are typically and collectively used in concentrations ranging from 0.05 to 10%, by weight of polyurethane.
    [038] In some embodiments, the absorbent foam is white in color. Certain hindered amine stabilizers can contribute to the discoloration, such as fading, of the absorbent foam. In some embodiments, the absorbent foam is free of diphenylamine stabilizer and / or phenothiazine stabilizer.
    [039] In other modalities, the absorbent foam can be colored (that is, another color besides white). White or colored absorbent foam can include a pigment in at least one of the components. In preferred embodiments, the pigment is combined with a polyol-based vehicle and is added to the liquid polyol stream during the manufacture of the polyurethane foam. Commercially available pigments include, for example, DispersiTech ™ 2226 White, DispersiTech ™ 2401 Violet, DispersiTech ™ 2425 Blue, DispersiTech ™ 2660 Yellow,
    13/42 and DispersiTech ™ 28000 Red, available from Milliken in Spartansburg, South Carolina, USA and Pdi® 34-68020 Orange, from Ferro in Cleveland, Ohio, USA.
    [040] In the production of polyurethane foams, the polyisocyanate component and polyol component are reacted so that an equivalence ratio between isocyanate groups and the sum of hydroxyl groups is not greater than 1 to 1. In some embodiments, the components are reacted so that there is an excess of hydroxyl groups (eg excess of polyol). In these modalities, the equivalence ratio between isocyanate groups and the sum of the hydroxyl groups is at least 0.7 to 1. For example, the ratio can be at least 0.75: 1, or at least 0.8: 1.
    [041] Polyurethane foams can be prepared by mixing the reagents in liquid form with an appropriate amount of water or chemical blowing agent, suitable catalyst and other optional components, and allowing the mixture to foam and remain firm. It is preferable to use water to produce polyurethane foams, because the water reacts with the isocyanate groups to release carbon dioxide. The amount of water is preferably in the range of 0.5 to 5% by weight of polyurethane. In some embodiments, the amount of water is not more than 4 or 3 or 2 or 1%, by weight, of polyurethane.
    [042] Polyurethane foam can be prepared by various methods as described in the art. In one embodiment, polyurethane foams are prepared, in general, by continuously molding a thin layer of foam onto a substrate, as described in US patent 2,957,207. Although US Patent 2,957,207 emphasizes the importance of introducing a limited delay after the polyol component and polyisocyanate component are mixed, this delay is not typically used when the foam is transported between a pair of measuring cylinders, so the established span of the measuring cylinder controls the thickness of the foam. The foam is typically cured at an excess temperature in the range of about 38 ° C to 135 Ό (100 ° F to 275 ° F). Alternatively to
    14/42 foam can be produced as pads that are cut to the desired thickness or by molding foam into an open or closed metal mold.
    [043] The polymeric foam (eg, polyurethane) of the first absorbent layer (eg, fluid transport) may optionally comprise a superabsorbent polymer (PSA), also called "hydrogels" and "hydrocolloids", as described in US patent application serial number 61 / 652,408, filed May 29, 2012. PSA is substantially insoluble in water, but swellable in water and capable of absorbing large amounts of liquids (for example 10 to 100 times its weight) . Various PSA materials have been described in the art. (See, for example, 4,410,571; US 6,271,277; and US 6,570,057; incorporated herein by reference.) These include superabsorbents with low gel strength, high gel strength, cross-linked surface superabsorbent, superabsorbents uniformly cross-linked, or superabsorbent with varying cross-linking density throughout the structure. Superabsorbents can be based on chemicals that include poly (acrylic acid), poly (iso-butylene-maleic coanhydride), poly (ethylene oxide), carboxy-methyl cellulose, poly (-vinyl pyrrolidone), and poly (-alcohol) vinyl). Superabsorbents can vary in expansion rate from slow to fast. Superabsorbents can be in varying degrees of neutralization. Counterions are typically Li, Na, K, Ca.
    [044] Preferred PSA materials can be slightly cross-linked polymers of partially neutralized polyacrylic acids or starch derivatives thereof. For example, PSA can comprise from about 50 to about 95%, preferably about 75%, neutralized, slightly cross-linked, polyacrylic acid (i.e., poly (sodium acrylate / acrylic acid)). As described in the art, the network crosslinking serves to make the polymer substantially insoluble in water and, in part, determines the characteristics of absorptive capacity and extractable polymer content of the precursor particles and the
    15/42 resulting macrostructures.
    [045] For modalities in which the foam comprises PSA, PSA is generally present within the foam as separate pieces. These can have different shapes such as spherical, rounded, angular, or irregular pieces as well as fibers. The particles generally comprise a size distribution ranging from about 1 micron to 500 microns in diameter or cross section (the largest dimension when not spherical). The particles are preferably a finely divided powder of a maximum particle size less than 400, 300, or 200 microns.
    [046] When present, the concentration of PSA in the polymeric foam is typically at least 1, 2, 3, 4, or 5%, weight, of the polymeric composition (e.g. polyurethane) and typically not greater than 30, 25, or 20 % by weight of the polymeric composition (for example polyurethane). The minimum amount of PSA that can provide the desired properties (for example, absorption capacity, penetration, rehumidification) is used. In some embodiments, the PSA concentration is not greater than 17.5, or 15, or 12.5 or 10%, by weight, of the polymeric composition (for example polyurethane). In some embodiments, the inclusion of PSA in the foam has little or no effect on the absorption capacity of the foam, and even surprisingly improves the times for pouring and rehumidifying the foam and specifically the absorbent composite.
    [047] PSAs can be incorporated into the polymeric foam by mixing PSA with the ingredients used to foam. In the direct addition of PSA during the production of polymeric foams (for example, polyurethane), PSA is typically added to the polyol component. However, other methods for incorporating PSA into polymeric foams have also been described, as in US 6,271,277.
    [048] For modalities in which the foam comprises PSA, the PSA is
    16/42 typically distributed homogeneously within the polymeric material of the first absorbent layer. However, the first absorbent layer may comprise more than one layer, the layers having a different concentration of PSA. For example, a layer of polymeric foam that has a lower concentration of PSA may be adjacent to the top layer and a layer of polymeric foam that has a higher concentration may be adjacent to the second absorbent layer.
    [049] The hydrophilic polymeric foam (eg polyol (s)) component (s) (eg polyurethane) provides the desired absorbency of the foam. In this way, the foam can be free of the superabsorbent polymer. Additionally, the polyurethane foam is free of amine or imine complexing agent such as ethylenimine, polyethyleneimine, polyvinylamine, carboxymethylated polyethylenimines, phosphono-methylated polyethylenimines, quaternized polyethylenimines and / or dithiocarbamitized polyethylenimines; as described for example in US patents 6,852,905 and U.S. 6,855,739.
    [050] Polymeric foam (for example, polyurethane) typically has an average base weight of at least 100, 150, 200, or 250 g / m 2 and typically not greater than 500 g / m 2 . In some modalities the average base weight is not greater than 450, or 400 g / m 2 . The average density of the polymeric foam (for example polyurethane) is typically at least 0.048, 0.056 or 0.064 g / cm 3 (3, 3.5 or 4 lbs / ft 3 ) and not greater than 0.11 g / cm 3 (7 lbs / ft 3).
    [051] The thickness (i.e., non-compressed) of the first absorbent layer (for example fluid transport) containing foam is at least 0.1 mm and typically not greater than about 10 mm. In some embodiments, the thickness is between about 1 mm and about 5 mm. The person skilled in the art will recognize that that preferred thickness may vary depending on the specific size of the absorbent garment, and its intended use. For example, for babies
    17/42 larger adults, a higher absorbency material is typically required.
    [052] The first and second absorbent layers and absorbent composite can have several shapes including symmetrical (having a point, line, or plane of symmetry) or asymmetric shapes. The shapes that are idealized include, but are not limited to, circles, ovals, squares, rectangles, pentagons, hexagons, octagons, trapezoids, truncated pyramids, hourglasses, dumbbells, dog bones, etc. Edges and corners can be straight or rounded. The sides can be curved (convex or concave), tapered, widened, or angled. In some embodiments, the absorbent composite has an hourglass or trapezoid shape.
    [053] The second absorbent layer can be the same size and shape as the first absorbent layer. In this embodiment, substantially an entire main surface of the first absorbent layer (for example polymeric foam) is in contact with or in fluid communication with the second absorbent layer. Alternatively, the second absorbent layer may be of a different size and / or shape than the first absorbent layer. In some embodiments, the second absorbent layer has a length and / or width that is less than the length and / or width of the first absorbent layer (for example, polymeric foam). Thus, a portion of the first absorbent layer (for example, polymeric foam) is not in contact with or in fluid communication with the second absorbent layer. Typically, the second absorbent layer is arranged so that it is in contact with or in fluid communication with the central region of the first absorbent layer (for example polymeric foam). Thus, when the second absorbent layer has a length and / or width that is less than the first absorbent layer (for example, polymeric foam), opposite perimeter regions or the entire perimeter region of the first absorbent layer (for example, foam polymeric) is not in contact
    18/42 with or in fluid communication with the second absorbent layer. In some embodiments, the surface area of the main surface of the second absorbent layer that faces and is in fluid communication with the first absorbent layer (for example, polymeric foam) is in the range of about one-half to three-quarters (for example, the about two thirds) of the total surface area of the main surface of the first absorbent layer (e.g., polymeric foam) facing the second absorbent layer. In one embodiment, the first absorbent layer (for example, polymeric foam) has an hourglass shape and the second absorbent layer is a rectangular strip that crosses the central longitudinal axis of the hourglass, the rectangular strip having a slightly smaller width than the narrower (middle) portion of the hourglass.
    [054] The foam can contain clipping regions to create voids, cavities, depressions, channels, or grooves. In one embodiment, at least the central region of the foam comprises a plurality of circular perforations that have a diameter of about 1 mm, spaced around 3 mm apart.
    [055] The first and / or second absorbent layers and / or the absorbent composite may comprise various functional additives including, for example, antimicrobial coatings, ion capture coatings, desiccants, fragrances, and odor control particles.
    [056] Regardless of the shape, the first and second absorbent layers and absorbent composite can generally be defined as having a first main face, a second main face opposite substantially parallel to the first main face, and a thickness in a direction orthogonal to the first face and opposite main face.
    [057] In some preferred embodiments, the functions of the first absorbent layer, such as a fluid transport layer and the second absorbent layer, function as the fluid storage layer. Others
    19/42 layers, like a fabric layer, can be arranged between the first absorbent layer (for example, of fluid transport) and the second absorbent layer (for example, of fluid storage). The presence of these other layers is not harmful and typically has little effect on the properties of the absorbent composite. In these embodiments, the second absorbent layer has at least the same and typically a higher absorbency than the first absorbent layer. For example, the second absorbent layer typically has an average absorption capacity of at least 20, 21, 22, 23, 24 g / g or at least about 25 to 30 g / g (i.e., at least 25, 26, 27, 28, 29, or 30 g / g) or at least 8 g / cm 3 . In some embodiments, the second absorbent layer has an average absorption capacity of no more than 60 or 55 or 50 or 45 or 40 g / g. The first absorbent layer has an average absorption capacity of at least 10 g / g; still typically less than 20 or 15 g / g. In addition, the first absorbent layer has an average absorption capacity of at least 1 g / cm 3 , but typically less than or equal to 2 g / cm 3 .
    [058] The second absorbent material can be produced from a variety of materials. In some embodiments, the second absorbent material is the same polymeric foam (for example, polyurethane) or similar which has more PSA than the first absorbent layer. In another embodiment, the second absorbent layer comprises fibrous materials, typically in the form of a fibrous mat.
    [059] Although the fluid transport layer and fluid storage layer are both absorbent, the fluid storage layer has a considerably greater absorption capacity than the fluid transport layer. In one embodiment, the absorption capacity (g / g or g / cm 3 ) of the second layer is at least 1.5X, 2X, 2.5X, or even 3X the absorption capacity of the first absorbent layer (i.e., X ). In some
    20/42 modalities, the absorption capacity of the second layer is typically not greater than 5X or 4.5X or 4X.
    [060] The fibers of the second layer (for example, fluid storage) are hydrophilic, or can be a combination of both hydrophilic and hydrophobic. Suitable fibers include those that are naturally occurring fibers (modified or unmodified), as well as synthetically produced fibers. Examples of suitable naturally occurring unmodified / modified fibers include cotton, esparto, cane bagasse, hemp, linen, silk, wool, wood pulp, chemically modified wood pulp, jute, rayon, ethyl cellulose, and cellulose acetate.
    [061] Suitable wood pulp fibers can be obtained by chemical processes known as, but not limited to, brown paper and sulfite processes. A further suitable type of fiber is cellulose chemically cured by chemical means to increase the hardness of the fibers under both dry and aqueous conditions. Such means may include the addition of a chemical curing agent which, for example, coats or impregnates the fibers or by hardening the fibers by altering the chemical structure, for example, by crosslinking polymer chains, as known in the art. The fibers can be curled by methods that include chemical treatment or mechanical torsion. The ripple is typically checked before crosslinking or twisting.
    [062] Hydrophilic fibers, particularly (optionally modified) cellulosic fibers are typically preferred. However, hydrophilic fibers can also be obtained by hydrophilizing hydrophobic fibers, such as thermoplastic fibers treated with surfactant or silica. Surfactant-treated fibers can be produced by spraying the fiber with a surfactant, immersing the fiber in a surfactant or including the surfactant as part of the melt in the
    21/42 production of thermoplastic fiber. Through fusion and resolidification, the surfactant will tend to remain on the surfaces of the thermoplastic fiber.
    [063] Suitable synthetic fibers can be produced from polyvinyl chloride, polyvinyl fluoride, polytetrafluoroethylene, polyvinylidene chloride, polyacrylics, poly (vinyl acetate), polyethyl vinyl acetate, non-soluble or soluble polyvinyl alcohol, polyethylene and polyethylene such as polyethylene and polyethylene such as polyethylene and polyolefins. polypropylene, polyamides such as nylon, polyesters, polyurethanes, polystyrenes, and the like. In some embodiments, synthetic fibers are thermoplastic fibers, for example, which have a melting point of at least less than 50 ° C to 75 ° C and not greater than 190 or 175 ° C.
    [064] In general, synthetic fibers (for example thermoplastic) have an average width, diameter, or cross-sectional dimension of at least 5, 10, 15, or 20 microns. The average diameter can be in the range of up to 1,000 microns (1 mm), yet it is typically not greater than 800 microns or 700 microns or 600 microns and, in some modalities, not greater than 500 microns or 400 microns. In some embodiments, the average diameter of the blanket fibers is not greater than 300, 250, 200, 150, 100, 75 or 50 microns. Smaller diameters of textile fiber blankets can provide improved flexibility (for example, lower compression work). The cross-sectional dimension of the filament (and the shape of the cross-section) is preferably substantially or essentially uniform throughout the length of the filament, for example, uniformly round. The surface of the filament is typically smooth. The fibers can be in the shape or form of fibers, strips, or other narrow and long shapes. Aggregations composed of a plurality of fibers with plastic compositions, geometric shapes, sizes and / or diameters may be created or the same or different. The fibers are typically solid. The fibers may have a circular or round cross-section or non-circular cross-section, for example, lobal, elliptical, rectangular, triangular, and
    22/42 formats with radial arms like “shaped in x”. For modalities in which the thermoplastic fiber is formed from casting-extrusion processes (for example, continuous spinning or meltblown) the length of the fibers is continuous. The length of textile fibers (that is, fibers) is typically at least 1.2, or 3 cm, and commonly not more than 15 cm. In some embodiments, the fiber length is no more than 10, 9, 8, or 7 cm.
    [065] The fluid storage layer can be a preformed fibrous mat. There are a variety of mat formation processes such as "dry-laid" and "produced by wet deposition" described in the art. Various second layers (for example, fluid storage) and methods for producing them have been described in the art. (See, for example, US 4,610,678 and US 6,896,669) [066] In some embodiments, the second layer (for example fluid storage) typically has a highly absorbent material that comprises a superabsorbent polymer. In some embodiment, the second layer comprises different pieces of superabsorbent polymer, such as the different pieces of PSA previously described, optionally included in the polymeric foam. The second absorbent layer can be substantially free of superabsorbent fiber or rayon fiber / superabsorbent fiber. The second layer (for example fluid storage) may comprise a blend of cellulosic fibers and superabsorbent material. A second illustrative layer (for example, fluid storage) has a weight of about 100 g / m 2 to about 700 g / m 2 that was produced by air deposition (airlaid) as a pulp bottom layer, a intermediate layer of pulp and superabsorbent polymer disposed between the pulp, and a top layer that contains at least some pulp. The second layer or absorbent material can have a density of 0.25 or 0.3 g / cm 3 to about 0.5 g / cm 3 .
    23/42 [067] The second layer (for example, fluid storage) typically comprises at least 5 or 10% by weight, and preferably at least 15, 20, 25 or 30%, by weight of superabsorbent polymer. The superabsorbent polymer is typically not more than 75% by weight of the second layer (e.g., fluid storage) and in some embodiments, not more than 55, 50, 45, or 40% by weight. The second layer (for example, fluid storage) can have a weight of at least 150 to 200 g / m 2 and typically not more than 500 g / m 2 .
    [068] The second absorbent layer has a weight less than, equal to, or greater than foam (for example, polyurethane). The average weight of the composite can be at least 150, 200, 250, or 300 g / m 2 and typically not greater than 1000 g / m 2 . In some modalities the average weight of the composite is not greater than 900, or 800 g / m 2 , or 600 g / m 2 .
    [069] The first absorbent layer (for example, fluid transport) and the second layer (for example, fluid storage) can be grouped by any suitable technique. In one embodiment, the layers are grouped with an adhesive. Examples of suitable adhesives include emulsion, hot melt, curable, or solvent based adhesives. Suitable pressure sensitive adhesives include (meth) acrylate-based adhesives, such as those described in US Patent No. Re 24,906 (Ulrich), polyurethane adhesives, synthetic or natural rubber-based adhesives, epoxy adhesives, curable adhesives, adhesives phenolic and similar.
    [070] There are several ways in which the first absorbent layer can be used (for example as a fluid transport element) adjacent to a second absorbent layer, some of which are shown in Figures 1 to 4. Figures 1 to 4, represent cross-sectional views of an absorbent article comprising the absorbent composite 10 disposed between a layer
    Fluid-permeable upper 40/42 and a fluid-impermeable lower layer 50. The absorbent composite comprises several arrangements of a first absorbent layer 20 and a second absorbent layer 30 in fluid communication with each other. The first absorbent layer comprises a polymeric foam 21.
    [071] In some embodiments, as shown in Figure 1 the first absorbent layer 20 comprises a continuous layer of the polymeric foam and the second absorbent layer 30 comprises a continuous layer of a fluid storage material, such as cellulosic fiber and PSA. In this embodiment, the first absorbent layer has almost the same width in cross section as the second absorbent layer.
    [072] In other embodiments, the width of the cross section of the first absorbent layer is less than the width of the second absorbent layer. For example, Figure 2 represents a polymeric foam 21 inserted within the second absorbent layer 30 so that substantially all of the side edges 23 (i.e., faces orthogonal to the main surfaces that define a thickness of the polymeric foam) of foam 21 are in communication fluid with the second absorbent layer 30.
    [073] Figure 3 represents a first multi-component absorbent layer comprising polymer foam 21 in a central region 20 and a different fluid transport material 25 disposed on opposite sides of the central region. In one embodiment, the fluid carrier material 25 may comprise a foam having a different (for example, higher) PSA content of 20. Alternatively, the fluid carrier material 25 may comprise a commercially available material used for layers of capture in disposable absorbent articles such as air-bonded textile fibers, adhesive-bonded textile fibers, and thermally bonded textile fibers.
    25/42
    In yet another embodiment, the central region 20 may comprise a different fluid transport material, with the fluid transport material on the opposite sides 25 comprising the polymeric foam as described herein.
    [074] Figure 4 represents a second multi-component absorbent layer in which a PSA containing a cellulosic fiber mat 30 is present in a central region and a different fluid storage material 35, disposed on opposite sides of the central region. In one embodiment, the fluid storage material 35 may comprise an absorbent foam.
    [075] In yet other embodiments, (not shown), both the first absorbent layer 20 and the second absorbent layer can both comprise multiple components.
    [076] The absorbent composite typically has an absorption capacity of at least 10, 11, 12, 13, 14, 15, 16, 17, 18, 19 or 20 g / g. The absorbent composite typically has an absorption capacity of at least 1, 1.1, 1.2,
    1.3, 1.4, 1.5, 1.6, 1.7, 1.8, 1.9, 2.0, 2.1, or 2.2 g / cm 3 . The absorbency of the absorbent composite is typically not greater than the second layer. The absorbent composite can exhibit a leak time in less than 20, 15, or 10, 9, 8, 7, 6 and in some embodiments 5 seconds. In preferred modes, the time to leak is not greater than 4.5, or 4, or 3.5, or 3.0, or 2.5, or 2.0 seconds. In some preferred embodiments, the time to leak is less than 2.0 seconds. The composite can exhibit less than 2 or 1.5 or 1.0 grams of rehumidification. In some modalities, rehumidification is less than 0.9, 0.8, 0.7, and in some modalities 0.6 or 0.5 or 0.4, or 0.3 grams. The composite can exhibit various combinations of absorption capacity, time to pour, and rehumidification properties already described. The various numerical values expressed for absorption capacity, time for
    26/42 leakage, and rehumidification described herein refer to the average absorption capacity, time to average leakage, and average rehumidification, unless otherwise specified.
    [077] The composite typically has a greater absorption capacity than polymeric foam. In addition, the composite typically has a lower absorbency than the second absorbent layer. The pouring time of the composite is less than that of the (better than) second absorbent layer. In some embodiments, the time to leak is less than the polymeric foam. In this way, the composite can have a lower pour time than each individual layer. The rehumidification of the composite is significantly less (better) than that of the polymeric foam. In some embodiments, the rehumidification of the composite is less than that of the second absorbent layer. The composite can exhibit good absorption capacity in combination with an optimized pour time and / or an optimized rehumidification.
    [078] The absorbent composite of the first absorbent layer (eg foam) and the second absorbent layer (eg fibrous) can be used as an absorbent article, as it is suitable for use in spill containment or medical uses, such as wound bandages . In other embodiments, such as in the case of a disposable diaper, feminine hygiene article, or adult incontinence article, the absorbent composite may additionally comprise another substrate, such as a fluid-permeable top layer and / or fluid-impermeable bottom layer. .
    [079] The top layer 40 is typically the surface facing the body of the absorbent article. In this way, the top layer comes into contact with the user's skin when using the absorbent article. The top layer is typically malleable, soft to the touch, and non-irritating to the wearer's skin. Additionally, the top layer is permeable to liquids, allowing liquids to penetrate
    27/42 readily through its thickness. Suitable upper layers can be manufactured from a wide range of materials, such as porous foams, reticulated foams, plastic films with openings, natural fibers (for example, wood or cotton fibers), synthetic fibers (for example, polyester or polypropylene) or a combination of natural and synthetic fibers. The top layer is typically a hydrophobic material to isolate the wearer's skin from liquids in the absorbent material. Thus, the top layer is typically of a different material than the first layer of underlying absorbent foam.
    [080] There are several manufacturing techniques that can be used to manufacture the top layer. The top layer may have woven, non-woven, continuous spinning, carded, or the like. An illustrative top layer is carded, and thermally bonded (1.5 denier polypropylene textile fibers). The top layer can have a weight of about 18 to about 25 grams per square meter. In addition, the top layer typically has a minimum dry tensile strength of about at least 400 grams per centimeter in the machine direction and a wet tensile strength of about at least 55 grams per centimeter in the transverse direction of the machine.
    [081] The bottom layer 50 is impermeable to liquids and is typically a thin plastic film, although other liquid impermeable materials can also be used. The bottom layer is typically flexible, meaning it is malleable and will readily adapt to the overall shape and contours of the user's body. The bottom layer prevents the exudates absorbed and contained in the absorbent material to moisten articles that come in contact with the absorbent article such as sheets and underwear. An illustrative bottom layer is a polyethylene film that has a thickness of about 0.012 mm (0.5 mil) to about 0.051 centimeters (2.0 mils). The bottom layer can be embossed and or have a matte finish to provide a more fabric-like appearance.
    28/42
    In addition, the bottom layer may allow vapors to escape from the absorbent member while still preventing exudates from passing through the bottom layer.
    [082] In a typical disposable absorbent article, the top layer and the bottom layer are combined in any suitable way. Typically, the top layer and the bottom layer are affixed directly to each other at the periphery of the article by a fixation means such as an adhesive or any other fixation means as known in the art.
    [083] The disposable absorbent article may comprise a variety of other resources, as known in the art. For example, when the disposable absorbent article is an absorbent for feminine hygiene or for adult incontinence (also called a "pillow"), the article may further comprise flaps or wings as described for example in US5472437 (3M, Akiyama); US5730739 (P&G, Lavash); and US5201727 (Kao Corp., Nakanishi). Absorbents for feminine hygiene or adult incontinence also typically comprise a pressure sensitive adhesive on the outer surface of the liquid impermeable bottom layer to attach the absorbent to underwear. Additionally, when the disposable absorbent article is a disposable diaper, the article may additionally comprise elasticized leg openings. Disposable diapers also typically comprise a means of fixing the front and rear regions such as using an adhesive tape or hook and loop fasteners that fit mechanically.
    Test methods [084] Sample thickness: The sample thickness was measured in millimeters by placing a metric ruler or gauge along the sample's z-axis and recording the thickness. When a gauge was used, care was taken to ensure that the sample was not compressed. For measurements
    29/42 more accurate, the sample was placed on a platform and a Keyence stereo digital microscope model VHX-600E (Keyence Corporation, Itasca, IL, USA) was rotated 90 degrees in line and centered with the z plane of the sample. A metric ruler was attached to the platform and adjacent to the z plane of the foam as a reference. A scale was calibrated using the reference and the sample thickness was measured using the ImageJ software (a public domain image training program). Sample measurements were made in triplicate with the average value being reported.
    [085] Cell Size (Micra): The average cell diameter in a standard polyurethane foam was determined using an Environmental Scanning Electron Microscope (ESEM) FEI XL30, operating in high vacuum mode (available from the FEI Company, Hillsboro, OR, USA). The standard foam was sectioned transversely (in the direction perpendicular to the first digital surface of the foam sheet) by cutting with a scalpel while the sample was placed on dry ice and the cross-sectional face had its image formed with a 50X magnification. The images were analyzed using the ImageJ software. A total of 60 to 75 cell diameters were measured at random points throughout the cross sectioned sample with the average value being reported. For each cell, the longest dimension was measured. However, holes in cell walls have not been measured. The average cell diameter for the standard polyurethane foam was 233 microns.
    [086] By comparing other foams exemplified with standard foam using a microscope (30X magnification), it was found that these other foams had average cell diameters about the same size as in standard foam.
    [087] Weight (g / m 2 ): A rule matrix measuring 5.08 cm x 5.08 cm
    30/42 (2 inches x 2 inches) was used to cut the sample for weight measurement. The sample was weighed and the weight was subsequently calculated. Sample measurements were made in triplicate with the reported mean value.
    [088] Absorption Capacity: A saline solution (90 mL of 0.9% NaCI in deionized water) was poured into a disposable 100 ml Petri dish. A sample of 5.08 cm x 5.08 cm (2 inches x 2 inches) was weighed and recorded as "dry weight". The sample was immersed inside the Petri dish and left to saturate for 5 minutes. The sample was removed using tweezers to hold a corner of the sample. The wet sample was suspended vertically to dry without kneading for 2 minutes. The wet weight was recorded and the absorption capacity was calculated using the following equations:
    [089] Absorption Capacity (g / g) = [(weight of wet sample - weight of dry sample) / weight of dry sample] [090] The absorption capacity per unit volume of a dry sample was calculated using following formula:
    [091] Absorption Capacity (g / cm 3 ) = [(wet sample weight - dry sample weight) / dry sample volume] [092] All sample measurements were made in triplicate and reported as the average value.
    [093] Leakage Time (sec): Leakage time was measured using saline and a test guide standard. The guide pattern was made of Plexiglass with the dimensions of 10.16 cm x 10.16 cm x 2.54 cm (4 inches x 4 inches x 1 inch). A 2.54 cm (1 inch) hole was cut in the center of the Plexiglass guide pattern. The test guide pattern weighed about 284 grams. Unless otherwise specified, the test sample was at least 10.16 cm x 10.16 cm in size. The test sample was placed under the test guide pattern and positioned so that the hole in the plexiglass was
    31/42 directly above the sample center. The saline solution (10 mL of 0.9% NaCI in deionized water) was poured into the orifice and the time (in seconds) required for the saline solution to penetrate into the test sample was recorded. To accentuate the visualization, the saline solution was dyed with red food coloring. The test samples were oriented so that the polyurethane foam layer was in direct contact with the plexiglass surface of the test guide pattern. In this orientation, the polyurethane foam layer was the first surface of the test sample to come into contact with the saline solution. Sample measurements were made in triplicate and reported as the mean value.
    [094] Rehumidification (g): The measurement of rehumidification was determined using the same test guide standard as described for the measurement of time to leak. Unless otherwise specified, the test sample was at least 10.16 cm x 10.16 cm in size. The test sample was placed under the test guide pattern and positioned so that the hole in the plexiglass was directly above the center of the sample. The test samples were oriented so that the polyurethane foam layer was in direct contact with the plexiglass surface of the test guide pattern. In this orientation, the polyurethane foam layer was the first surface of the test sample to come into contact with the saline solution. A saline solution (10 mL of 0.9% NaCI in deionized water) was poured into the orifice and the sample was kept in the test guide pattern for 5 minutes. The test guide pattern was removed and a stack of ten sheets of 90 mm WHATMAN # 4 filter paper was placed on top of the test sample. Before being placed in the sample, the filter paper stack was weighed to obtain the initial weight. The test guide pattern was reapplied to the sample and a weight of 2200 grams was placed and centered on top of the plexiglass test guide pattern (providing a load of 3827 Pa (0.56 psi) for 15 seconds. The set was removed and the filter paper stack was weighed again
    32/42 to obtain the final weight. The rehumidification measurement was calculated using the following equation: Rehumidification (g) = final filter paper weight - initial filter paper weight. All sample measurements were made in triplicate and reported as the mean value.
    Indentation Force Deflection (N):
    [095] The indentation force deflection test (DFI) was conducted according to ASTM D3574-08 with the following modifications. The sample size was 160 mm by 160 mm and the dimensions of the presses were 150 mm by 150 mm. A contact force of 2.5 N was used.
    [096] DFI was measured at deflections of 25%, 50%, and 65%. All sample measurements were made in triplicate and reported as the mean value. A digital gauge was used to measure the thickness of the foam.
    Deformation by Constant Deflection Compression (%):
    [097] A constant deflection compression strain test was conducted according to ASTM D3574-08 for deflection of 50% of the initial thickness. The sample size was 50.8 mm by 50.8 mm and multiple foam sheets were stacked to achieve a total sample thickness of about 25 mm. The metal plates of the tester were 250 mm by 250 mm by 10 mm and were secured with the inclusion of a spacer element so that the base surface of the upper plate was positioned 12.5 mm from the top surface of the plate bottom. The sample was held in the apparatus and kept in an oven at 37.8 ° C (100 ° F) for 22 hours.
    [098] Compression strain measurements (Ct) were made in triplicate and reported as the mean value. A digital gauge was used to measure the thickness of the foam.
    Materials [099] Polymeric diphenylmethane diisocyanate (polymeric MDI) was obtained
    33/42 with Huntsman Chemical Company, The Woodlands, TX, under the trade name “RUBINATE 1245”. The material “RUBINATE 1245” has been reported to have the following properties: average PM of 283 Da, equivalent weight of 128 g / equivalent, functionality of 2.21, content of 32.8% isocyanate, specific gravity at 25 ° C of 1.23, and viscosity at 25 ° C of 25 cps.
    [0100] Modified diphenylmethane-diisocyanate (MDI) was obtained from Huntsman Chemical Company, The Woodlands, TX, USA, under the trade name “SUPRASEC 9561”. The “SUPRASEC 9561” material has been reported to have the following properties: equivalent weight of 143 g / equivalent, 2.10 functionality, 29.3% isocyanate content, 1.21 specific gravity at 25 ° C, and viscosity at 25 ° C of 36 cps.
    [0101] The first polyether polyol product was obtained from the Carpenter Company, Richmond, VA, USA, under the designation “CDB-33142”. The polymer was a blend made from glycerin, propylene oxide, and ethylene oxide. “CDB-33142” was reported to have the following properties: average Mw of 2300 Da, average Mn of 1200 Da, hydroxyl number of 142, functionality of 3, ethylene oxide content of 26%, and a viscosity at 25 ° C of 500 cps.
    [0102] The second polyester polyol product was obtained from the Carpenter Company, Richmond, VA, USA, under the trade name “CARPOL GP-700”. The polymer was prepared from glycerin and propylene oxide. The “CARPOL GP-700” was reported to have the following properties: mean PM of 730-770 Da, mean Mn of 700 Da, hydroxyl number of 240, functionality of 3, ethylene oxide content of 0, and a 250 cps viscosity at 25 ° C.
    [0103] The third polyether polyol product was obtained from Bayer MateriaIScience, Pittsburgh, VA, USA, under the trade name “ARCOL E-434”. The polymer was prepared as a polyoxypropylene triol modified with ethylene oxide. The “ARCOL E-434” was reported to have the following properties: PM
    34/42 4800 Da mean, hydroxyl number 33.8 to 37.2, 15% ethylene oxide content, and a viscosity at 25 ° C of 820 cps.
    [0104] The fourth polyether polyol product was obtained from the Carpenter Company, Richmond, VA, USA, under the trade name “CARPOL GP-5171”. The polymer was a polyether polyol initiated by glycerin polymerized with propylene oxide and ethylene oxide and then finished with 15% ethylene oxide. “CARPOL GP-5171” has been reported to have the following properties: average PM from 5100 to 5500 Da, hydroxyl number of 35, functionality of 3, ethylene oxide content of 71%, and a viscosity at 25 ° C 1.2 cps.
    [0105] The fifth polyether polyol product was obtained from the Carpenter Company, Richmond, VA, USA, under the designation “EB-PO-11034-1”. EB-PO11034-1 was reported to have the following properties: average MW of 3000 Da, average Mn of 1300 Da, hydroxyl number of 133, and an ethylene oxide content of 49%.
    [0106] Triethanolamine LFG (low freeze grade, in Portuguese, low freezing degree), 85% triethanolamine and 15% water was obtained from Quaker Chemica, Conshohocken, PA, USA, under the trade name “TEA99LFG”. The solution of triethylene diamine (33 weight percent) in dipropylene glycol was obtained from Air Products Company, Allentown, PA, USA, under the trade name “DABCO 33-LV”. The tertiary amine catalyst used to catalyze the urea formation reaction (water with isocyanate) was obtained from the Air Products Company, under the trade name “DABCO BL-17”.
    [0107] Compounds with the trade name "DABCO DC-198, a silicone glycol copolymer surfactant, and" DABCO BA-100 ", a polymeric acid blocking agent used to delay the catalytic reaction, were obtained from Products Company.
    [0108] Gelok 5040-72, a core component of absorbent fabric composed of a layer of superabsorbent polymer (about 60% by weight)
    35/42 placed between two layers of cellulosic fiber fabric (about 40% by weight), was obtained from Gelok International, Dunbridge, OH, USA. Gelok 5040-72 had a thickness of 0.3 mm and an average base weight of 86 g / m 2 .
    Control (Second Absorbent Layer (Gelok 5040-72) without Foam) [0109] The Gelok 5040-72 absorbent core was evaluated excluding all other components. The core had an average of 0.3 mm and an average thickness and base weight of 90 g / m 2 . The absorption capacity was 27.97 g / g (8.37 g / cm 3 ); the time to leak was 36.9 seconds; and rehumidification was 0.11 grams.
    Example 1 [0110] The open cell polyurethane foam layer was prepared by adding MDI SUPRASEC 9561 (58.2 parts) to a mixture of CDB-33142 (100 parts), CARPOL GP-700 (3.0 parts) , water (1.0 parts), triethanolamine LFG (3.7 parts), DABCO DC-198 (2.0 parts), ARCOL E-434 (4.0 parts), DABCO 33-LV (0.45 parts) , DABCO BA-100 (0.12 parts), and DABCO BL-17 (0.10 parts). All components were at an ambient temperature of 21 ° C (70 ° F) with the exception of CDB-33142 which was at 4.4 ° C (40 ° F). The polyol components were premixed for about 15 seconds and then mixed with the MDI for an additional 10 to 12 seconds. The mixture was poured immediately onto the removable polypropylene coated paper (0.36 mm (14mils) thick). A second sheet of removable polypropylene coated paper came into contact with the opposite surface of the foam as it was transported between a pair of measuring cylinders. After the thin sheet was cast and cured at 100 ° C for 5 minutes, the resulting open cell foam polyurethane sheet was measured to be an average of 3.5 mm thick, with an average density of 0.090 g / cm 3 (5.64 Ibs / feet 3 ). The average foam base weight was 316 g / m 2 . The results of the Indentation Force Deflection and the Constant Deflection Compression Deformation Test for Example 1 are reported in Table A and
    36/42
    Β.
    Control - Example 1 [0111] A layer of thin cell molded open cell polyurethane foam was prepared, as described in Example 1, by adding MDI SUPRASEC 9561 (72.7 parts) to a mixture of CDB-33142 (100 parts), CARPOL GP-700 (3.0 parts), water (1.0 parts), LFG triethanolamine (3.7 parts), DABCO DC198 (2.0 parts), ARCOL E-434 (4.0 part) , DABCO 33-LV (0.45 parts), DABCO BA-100 (0.12 parts), and DABCO BL-17 (0.10 parts). The resulting sheet of open cell polyurethane foam was measured to have an average thickness of 3.1 mm, with an average density of 0.071 g / cm 3 (4.43 Ibs / feet 3 ). The average base weight of the foam was 249 g / m 2 . The results of the Indentation Force Deflection and Compression Deformation Tests in Constant Deflection for the Control Example are reported in Tables A and B.
    _________Table A - Indentation strength deflection test _______________
    Example number Sample Thickness (mm) Force at 25% Deflection(N) Force at 50% Deflection(N) Force at 65% Deflection(N) Example 1 3.6 48.6 50.5 54.4 Control Example 1 3.1 52.0 108.3 160.1
    Table B - Compression strain test at constant deflection in
    50% deflection
    Example number Thickness ofOriginal Sample(mm) Thickness ofSample at the end ofTest (mm) Compression strain (Cf) (%) Example 1 25.0 24.0 4 ControlExample 1 25.0 13.5 46
    Absorbent composite example 1 [0112] The open cell polyurethane foam layer of Example 1
    37/42 was laminated adhesive to form Gelok 5040-72 using Spray 77 adhesive, available from 3M Company, St. Paul, MN, USA. The bilayer construction was on average 3.8 mm thick, and had an average base weight of 413 g / m 2 . The absorption capacity was 14.50 g / g (1.71 g / cm 3 ); and the time to leak was 5.4 seconds; and rehumidification was 0.78 grams.
    Control absorbent composite 1 [0113] The open cell polyurethane foam layer of Control Example 1 was adhesively laminated to form Gelok 5040-72 using adhesive Spray 77. The bi-layer construction was on average 3.4 mm thick, and had an average base weight of 371 g / m 2 . The absorption capacity was 15.10 g / g (1.81 g / cm 3 ); The time to leak was 13.0 seconds; and rehumidification was 0.27 grams.
    Table C
    Example number Absorption Capacity (g / g) Absorption Capacity (g / cm 3 ) Time to Leak (second) Rehumidification (grams) Absorbent Composite Example 1 14.50 1.71 5.4 0.78 Compositecontrol pad 1 15.10 1.81 13.0 0.27
    Absorbent composite example 2 [0114] A layer of open cell polyurethane foam molded on a thin foil was prepared as described in Example 1 by adding polymeric MDI RUBINATE 1245 (54.5 parts) to a mixture of CDB-33142 (100 parts), CARPOL GP-700 (2.4 parts), water (1.2 parts), triethanolamine LFG (3.7 parts), DABCO DC-198 (2.0 parts), ARCOL E-434 (4 , 0 parts), DABCO 33-LV (0.45 parts), DABCO BA-100 (0.12 parts), and DABCO BL-17 (0.10 parts). The resulting open cell polyurethane mold foam was measured to have an average thickness of 3.0 mm, with an average density of 0.094 g / cm 3 (5.85 Ibs / feet 3 ). The average base weight of the foam was 280 g / m 2 .
    38/42 [0115] A sample of polyurethane foam (alone - without Second Absorbent Layer) was measured to have an absorption capacity of 11.00 g / g (1.03 g / cm 3 ); leak time of 6.3 seconds; and re-humidification of 7.99 grams.
    [0116] The foam layer was laminated adhesive to Gelok 5040-72 using Spray 77 adhesive. The bilayer construction was 3.3 mm thick on average, with an average base weight of 388 g / m 2 . The absorption capacity was 13.03 g / g (1.54 g / cm 3 ); the time to leak was 4.6 seconds; and the rewetting was 0.60 grams.
    Comparative example of absorbent composite 1 (foam with an average cell diameter of 22 microns) [0117] The two-layer foam absorbent core with high internal phase emulsion (HIPEs, High Internai Phase Emulsion) of a feminine hygiene pad ALWAYS INFINITY HEAVY FLOW, available for sale (Proctor & Gamble Co., Cincinnati, OH, USA) was removed from the top layer and the bottom layer of the cushion and evaluated independently of any adjacent layer component. The HIPEs foam layers each had a different cell diameter. The HIPEs foam layer of the absorbent core component had an average cell diameter of 22 microns. The bottom layer of HIPEs foam of the absorbent core component had an average cell diameter of 6 microns. The HIPEs foam core was measured to have an average of 2.5 mm foam, with an average density of 0.080 g / cm 3 (5.01 Ibs / feet 3 ). The average base weight was 201 g / m 2 . The absorption capacity was 20.26 g / g (1.63 g / cm 3 ).
    [0118] The HIPEs foam on the cushion contained cutouts to facilitate the performance of time for fluid leakage. To determine the foam performance independent of the cutouts, these cutouts were covered with a minimum amount of masking tape (with the use of sufficient tape only
    39/42 to block the openings). A 7.62 cm x 15.24 cm (3 inch x 6 inch) sample was prepared to perform the leak and rehumidification time test by splicing two 7.62 cm x 7.62 cm (3 inch x 3) masking tapes. inch) with absorbent core sections cut from the back half of the two pads. For leakage and rehumidification time measurements, the core of the HIPEs foam was oriented in the test guide pattern so that the top layer of HIPEs foam was in direct contact with the surface of the Plexiglass test guide pattern. The time to leak was 24.3 seconds, and the rehumidification was 2.19 grams.
    Control absorbent composite example 2 (Comparative example foam 1 with second absorbent layer of Examples of absorbent composite examples 1 & 2) [0119] HIPEs foam absorbent cores in two layers were removed from ALWAYS INFINITY HEAVY FLOW feminine hygiene pads . A 7.62 cm x 15.24 cm sample was prepared by splitting with two masking tapes 7.62 cm by 7.62 cm sections of absorbent core cut from the back half of the two pads (as described in Comparative Example 1) · [0120] The HIPEs foam sample constructed was laminated adhesive to Gelok 5040-72 using Spray 77 adhesive. The orientation of the two-layer HIPEs foam as found in the commercial article was preserved by laminating the surface facing the lower layer of the HIPEs foam to Gelok 5040-72. The finished construction product had an average thickness of 2.8 mm and an average base weight of 322 g / m 2 . The absorption capacity was 18.73 g / g (2.15 g / cm 3 ).
    [0121] For time measurements for leakage and rehumidification, the cutouts in the HIPEs foam were covered with a minimum amount of tape to
    40/42 masking (as described in Comparative Example 1). The finished construction product was oriented so that the HIPE foam was in direct contact with the plexiglass surface of the test guide pattern. In this orientation, the HIPEs foam was the first surface of the test sample to come into contact with the saline solution. The time to leak was 21.4 seconds; and rehumidification was 1.43 grams.
    Wound dressing comparison [0122] Samples of Tegaderm ™ High Performance Foam Adhesive Dressing, Product No. 90612 were obtained. A cross section of such a product consists of a layer of absorbent foam that has a thickness of
    3.2 mm, a second absorbent layer that has a thickness of 2 mm consisting of rayon / superabsorbent fibers, and a conformable barrier film coated with adhesive. The conformable barrier coated with adhesive was left intact for testing the absorption capacity and removed to test the time for leakage and rehumidification.
    [0123] The absorbent foam is a polyurethane foam containing 3.16 to 3.21% by weight of superabsorbent particles. The absorbent foam had an average base weight of 350 g / m 2 and a cell diameter of 1057 microns +/- 341. The second absorbent layer had an absorption capacity of 18.6 g / g and 2.2 g / cm 3 . The construction of the bilayer composite had an average base weight of 619 g / m 2 .
    Table D - Absorbent Composites with a Second Layer
    Absorbent A
    Example number Absorption Capacity (g / g) Absorption Capacity (g / cm 3 ) Time to Leak (second) Rehumidification (grams) Absorbent Composite Example 1 14.50 1.71 5.4 0.78 Absorbent Composite Example 2 13.02 1.54 4.6 0.60 Comparative Example of CompositeAbsorbent 1 20.26 1.63 24.3 2.19
    41/42
    CompositeAbsorbentControl Example 2 18.73 2.15 21.4 1.43 Dressing forComparative Injury 9.49 1.23 9.7 0.94
    [0124] By comparing Examples of Absorbent Composites 1-2 to Comparative Example 1 (a commercially available product), it is evident that Examples of Absorbent Composites 1-2 reduced the time to pour and rehumidify. By comparing the Examples of Absorbent Composite 1-2 with Control Example 2 (using the same second absorbent layer), it is evident that the polyurethane foam layer provides reduced leakage and rehumidification time.
    [0125] Other polyurethane foams that can be melted into a thin sheet as described in Example 1, having about the same cell size as standard foam, and are believed to have Indentation Force Deflection and Compression Deformation in Constant deflection at 50% with deflection properties as in Example 1, are described as follows:
    Example 3 [0126] The open cell polyurethane foam layer can be prepared by adding MDI SUPRASEC 9561 (60.7 parts) to a mixture of polyether polyol CDB-33142 (100 parts), CARPOL GP-5171 (5, 4 parts), Arcol E-434 (4.0 parts), water (1.2 parts), triethanolamine LFG (3.7 parts), DABCO DC-198 (0.2 parts), DABCO 33-LV (0, 45 parts), DABCO BA-100 (0.12 parts), and DABCO BL-17 (0.10 parts).
    Example 4 [0127] A layer of open cell polyurethane foam can be prepared by adding MDI SUPRASEC 9561 (61.0 parts) to a mixture of CDB-33142 (100 parts), CARPOL GP-700 (3.6 parts ), ARCOL E-434 (4.0 parts), water (1.2 parts), LFG triethanolamine (3.7 parts), DABCO DC-198 (2.0 parts), DABCO 33-LV (0.45 parts) ), DABCO BA-100 (0.12 parts), and DABCO BL-17 (0.10
    42/42 pieces).
    Example 5 [0128] The open cell polyurethane foam layer can be prepared by adding MDI SUPRASEC 9561 (60.5 parts) to a mixture of CDB-33142 (75 parts), EB-PO-11034-1 (25 parts), CARPOL GP-700 (3.6 parts), Arcol E-434 (4.00 parts), water (1.2 parts), triethanolamine LFG (3.7 parts), DABCO DC-198 (2.0 parts), DABCO 33-LV (0.45 parts), DABCO BA-100 (0.12 parts), and DABCO BL-17 (0.10 parts).
    权利要求:
    Claims (19)
    [1]
    1. Absorbent article CHARACTERIZED by the fact that it comprises:
    an absorbent composite disposed between a fluid-permeable top layer and a fluid-impermeable bottom layer, wherein the absorbent composite comprises:
    a first absorbent layer comprising a polyurethane foam having an average cell size of at least 100 microns in which the polymeric foam has:
    a) an indentation force deflection of less than 75 N at 50% for an area of 150 mm by 150 mm; and
    b) a compression deflection at constant deflection of less than 25% for a deflection of 50%; and a second absorbent layer in fluid communication with the first absorbent layer.
    [2]
    2. Absorbent article, according to claim 1, CHARACTERIZED by the fact that the article is a disposable diaper, a feminine hygiene article or an adult incontinence article.
    [3]
    3. Absorbent article, according to claim 1, CHARACTERIZED by the fact that the average cell size of the polyurethane foam is not greater than 500 microns.
    [4]
    4. Absorbent article, according to claim 1, CHARACTERIZED by the fact that the polyurethane foam is free from the superabsorbent polymer.
    [5]
    5. Absorbent article according to claim 1, CHARACTERIZED by the fact that the first absorbent layer is a fluid transport layer and the second absorbent layer has a higher absorption capacity than the first absorbent layer.
    [6]
    6. Absorbent article, according to claim 1, CHARACTERIZED
    Petition 870190082562, of 23/08/2019, p. 13/17
    2/3 due to the fact that the second absorbent layer is selected from a fibrous layer, a foam layer or a combination thereof.
    [7]
    7. Absorbent article, according to claim 6, CHARACTERIZED by the fact that the fibrous layer comprises cellulosic fiber.
    [8]
    8. Absorbent article according to claim 7, CHARACTERIZED by the fact that the second absorbent layer comprises a superabsorbent polymer.
    [9]
    Absorbent article according to claim 1, CHARACTERIZED by the fact that the article additionally comprises a layer of fabric between the first and second absorbent layers.
    [10]
    10. Absorbent article according to claim 1, CHARACTERIZED by the fact that the composite has an absorption capacity of at least 10 g / g
    [11]
    11. Absorbent article, according to claim 1, CHARACTERIZED by the fact that the composite has an absorption capacity of at least 1 g / cm 3 .
    [12]
    12. Absorbent article, according to claim 1, CHARACTERIZED by the fact that the composite has a penetration of no more than 15 seconds.
    [13]
    13. Absorbent article, according to claim 1, CHARACTERIZED by the fact that the composite has a rehumidification no greater than 1 gram.
    [14]
    14. Absorbent article, according to claim 1, CHARACTERIZED by the fact that the polyurethane foam is derived from a silicone surfactant that has ethylene oxide units.
    [15]
    15. Absorbent article according to claim 1, CHARACTERIZED by the fact that the polyurethane foam is free of amine or imine complexing agent.
    Petition 870190082562, of 23/08/2019, p. 14/17
    3/3
    [16]
    16. Absorbent article according to claim 1, CHARACTERIZED by the fact that the polyurethane foam comprises the reaction product of at least one polyol that has polyethylene oxide units and a polyisocyanate component, at least 75% by weight the polyisocyanate component comprises polymeric polyisocyanate with a lack of urethane bonds.
    [17]
    17. Absorbent article according to claim 1, CHARACTERIZED by the fact that the polyurethane foam comprises at least 12% by weight of ethylene oxide units.
    [18]
    18. Absorbent article according to claim 1, CHARACTERIZED by the fact that the second absorbent layer has an average absorption capacity of at least 20 g / g.
    [19]
    19. Absorbent article according to claim 1, CHARACTERIZED by the fact that the second absorbent layer has an average absorption capacity of at least 30 g / g.
    类似技术:
    公开号 | 公开日 | 专利标题
    BR112014029833B1|2019-10-01|ABSORBENT ARTICLE UNDERSTANDING POLYMERIC AND INTERMEDIATE FOAM
    US20140295134A1|2014-10-02|Absorbent foam composites
    US20150119837A1|2015-04-30|Absorbent article comprising polymeric foam with superabsorbent and intermediates
    US9744755B2|2017-08-29|Method of making absorbent foam composites
    JP2016521218A5|2017-04-27|
    US6852905B2|2005-02-08|Fluid handling layers made from foam and absorbent articles containing same
    PL171302B1|1997-03-28|Method of obtaining polymeric foamed material
    US10918537B2|2021-02-16|Absorbent article comprising flexible polymeric foam and intermediates
    EP3437610A1|2019-02-06|Absorbent article
    JPH05200064A|1993-08-10|Absorbent article
    同族专利:
    公开号 | 公开日
    BR112014029833A2|2017-06-27|
    CN104640576B|2017-04-19|
    CN107158445A|2017-09-15|
    EP2854880B1|2019-03-13|
    JP2015521079A|2015-07-27|
    JP6382800B2|2018-08-29|
    CN104640576A|2015-05-20|
    US20150080823A1|2015-03-19|
    US20190255211A1|2019-08-22|
    EP2854880A1|2015-04-08|
    WO2013180832A1|2013-12-05|
    CN107158445B|2021-01-15|
    US10357588B2|2019-07-23|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    USRE24906E|1955-11-18|1960-12-13|Pressure-sensitive adhesive sheet material |
    US2957207A|1958-08-28|1960-10-25|B B Chem Co|Manufacture of thin sheet foam|
    US3900030A|1974-06-10|1975-08-19|Dow Chemical Co|Catamenial tampons|
    US4239043A|1978-11-29|1980-12-16|The Procter & Gamble Company|Absorbent means for catamenial devices|
    US4410571A|1980-08-25|1983-10-18|Johnson & Johnson|Absorbent products, process and compositions for immobilization of particulate absorbents|
    US4394930A|1981-03-27|1983-07-26|Johnson & Johnson|Absorbent foam products|
    US4610678A|1983-06-24|1986-09-09|Weisman Paul T|High-density absorbent structures|
    PH23956A|1985-05-15|1990-01-23|Procter & Gamble|Absorbent articles with dual layered cores|
    JP2858660B2|1989-03-14|1999-02-17|花王株式会社|Liquid holding structure and absorbent article provided with the liquid holding structure|
    US4985467A|1989-04-12|1991-01-15|Scotfoam Corporation|Highly absorbent polyurethane foam|
    US5730739A|1991-10-01|1998-03-24|The Procter & Gamble Company|Absorbent article having a unitary release material joined to each side flap|
    CA2039241A1|1990-04-18|1991-10-19|Bi Le-Khac|Superabsorbent foam composition|
    US5250581A|1990-09-26|1993-10-05|Arco Chemical Technology, L.P.|Polymer polyols containing halogenated aromatic monomers|
    JP3181626B2|1990-09-27|2001-07-03|花王株式会社|Absorbent articles|
    JPH0595975A|1991-04-15|1993-04-20|Minnesota Mining & Mfg Co <3M>|Sanitary napkin having flap part|
    US5147345A|1991-08-12|1992-09-15|The Procter & Gamble Company|High efficiency absorbent articles for incontinence management|
    US5260345A|1991-08-12|1993-11-09|The Procter & Gamble Company|Absorbent foam materials for aqueous body fluids and absorbent articles containing such materials|
    US5387207A|1991-08-12|1995-02-07|The Procter & Gamble Company|Thin-unit-wet absorbent foam materials for aqueous body fluids and process for making same|
    US5229427A|1992-06-02|1993-07-20|Miles Inc.|Flexible, combustion-modified, polyurethane foams|
    MX213505B|1993-02-24|2003-04-03|
    US6685682B1|1993-03-22|2004-02-03|3M Innovative Properties Company|Carrier delivered dressing and method of manufacture|
    GB9311838D0|1993-06-08|1993-07-28|Ici Plc|Process for making flexible foams|
    US5591779A|1994-11-22|1997-01-07|Imperial Chemical Industries Plc|Process for making flexible foams|
    JPH10509365A|1994-11-23|1998-09-14|キンバリークラークワールドワイドインコーポレイテッド|Absorbent article having a composite absorbent core|
    US6107538A|1995-01-10|2000-08-22|The Procter & Gamble Company|Absorbent members for absorbing body liquids|
    HU9801765A3|1995-01-23|1999-05-28|Stockhausen Chem Fab Gmbh|Substrate with super-absorbent material, method for manufacture thereof and use|
    DE19505709A1|1995-02-20|1996-08-22|Stockhausen Chem Fab Gmbh|Layered body for the absorption of liquids and its production and use|
    US5719201A|1995-03-30|1998-02-17|Woodbridge Foam Corporation|Superabsorbent hydrophilic isocyanate-based foam and process for production thereof|
    JP3060095B2|1995-05-31|2000-07-04|三洋化成工業株式会社|Urethane resin composition, water absorbent and moisture absorbent|
    US5859031A|1995-06-07|1999-01-12|Gpi Nil Holdings, Inc.|Small molecule inhibitors of rotamase enzyme activity|
    SE509841C2|1995-10-04|1999-03-15|Sca Hygiene Prod Ab|Absorbent product such as an absorbent pants, diaper, incontinence cover, sanitary napkin, panty protection, dressing or the like|
    DE19607551A1|1996-02-28|1997-09-04|Basf Ag|Water-absorbent, foam-like, crosslinked polymers, processes for their preparation and their use|
    US5763335A|1996-05-21|1998-06-09|H.H. Brown Shoe Technologies, Inc.|Composite material for absorbing and dissipating body fluids and moisture|
    US6989005B1|1997-03-27|2006-01-24|The Procter & Gamble Company|Absorbent articles having removable components|
    AU7917298A|1997-07-09|1999-02-08|Huntsman Ici Chemicals Llc|Compressed hydrophilic polyurethane foams|
    US5948829A|1997-11-25|1999-09-07|Kimberly-Clark Worldwide, Inc.|Process for preparing an absorbent foam|
    US6121509A|1998-01-07|2000-09-19|The Procter & Gamble Company|Absorbent polymer compositions having high sorption capacities under an applied pressure and improved integrity when wet|
    US6570057B1|1998-03-13|2003-05-27|The Procter & Gamble Company|Absorbent articles with improved distribution properties under sur-saturation|
    IL138231D0|1998-03-13|2001-10-31|Procter & Gamble|Absorbent structures comprising fluid storage members with improved ability to dewater distribution members|
    US6013596A|1998-05-18|2000-01-11|Arco Chemical Technology, L.P.|Double metal cyanide catalysts containing cyclic, bidentate complexing agents|
    TW568921B|1998-08-07|2004-01-01|Huntsman Int Llc|Process for preparing a moulded flexible polyurethane foam|
    SE513964C2|1999-03-01|2000-12-04|Moelnlycke Health Care Ab|Wound dressing comprising a layer of a hydrophilic foam|
    US6515195B1|1999-08-16|2003-02-04|Johnson & Johnson Inc.|Sanitary napkin with improved liquid retention capability|
    CA2316006A1|1999-08-16|2001-02-16|Johnson & Johnson Inc.|Absorbent structure suitable for use in a sanitary absorbent article|
    US6723892B1|1999-10-14|2004-04-20|Kimberly-Clark Worldwide, Inc.|Personal care products having reduced leakage|
    JP2003512498A|1999-10-21|2003-04-02|ダウグローバルテクノロジーズインコーポレイティド|Inorganic / organic composition|
    AU1452301A|1999-11-02|2001-05-14|Procter & Gamble Company, The|Method of making shaped foam|
    US6406648B1|1999-11-02|2002-06-18|The Procter & Gamble Company|Method of making shaped foam implements|
    JP4700250B2|2000-01-26|2011-06-15|ビーエーエスエフソシエタス・ヨーロピア|Modified polyurethane foam used as adsorbent|
    JP3348283B2|2000-01-28|2002-11-20|住友重機械工業株式会社|Laser processing apparatus, laser processing mask, and method of manufacturing the same|
    US6977323B1|2000-02-17|2005-12-20|3M Innovative Properties Company|Foam-on-film medical articles|
    US6548727B1|2000-02-17|2003-04-15|3M Innovative Properties Company|Foam/film composite medical articles|
    US6620493B2|2000-03-07|2003-09-16|Fukuvi Chemcial Industry Co Ltd|Reflection-reducing film|
    US6506959B2|2000-04-11|2003-01-14|Kao Corporation|Absorbent article|
    US20020090453A1|2000-10-25|2002-07-11|Synergistic Ventures, Inc.|Highly absorbent products and process of making such products|
    US6852905B2|2001-11-15|2005-02-08|Paragon Trade Brands, Inc.|Fluid handling layers made from foam and absorbent articles containing same|
    US6689934B2|2001-12-14|2004-02-10|Kimberly-Clark Worldwide, Inc.|Absorbent materials having improved fluid intake and lock-up properties|
    US6896669B2|2001-12-21|2005-05-24|Kimberly-Clark Worldwide, Inc.|Composite absorbent members|
    US20060148907A1|2002-07-24|2006-07-06|Nicholson David M|Topical antinflammatory preparations of y-terpinene|
    US7189768B2|2003-11-25|2007-03-13|3M Innovative Properties Company|Solution containing surface-modified nanoparticles|
    US7358282B2|2003-12-05|2008-04-15|Kimberly-Clark Worldwide, Inc.|Low-density, open-cell, soft, flexible, thermoplastic, absorbent foam and method of making foam|
    US8182456B2|2004-03-29|2012-05-22|The Procter & Gamble Company|Disposable absorbent articles with components having both plastic and elastic properties|
    US8470417B2|2004-04-02|2013-06-25|Curwood, Inc.|Packaging inserts with myoglobin blooming agents, packages and methods for packaging|
    US8207286B2|2004-09-01|2012-06-26|Ppg Industries Ohio, Inc|Methods for preparing polyurethanes|
    JP5179060B2|2004-12-28|2013-04-10|株式会社カネカ|Curable composition|
    US7329715B2|2005-04-18|2008-02-12|Yazaki Corporation|Abrasion resistant coatings by siloxane oligomers|
    CA2637173C|2006-01-31|2015-12-01|Tyco Healthcare Group Lp|Super soft foams|
    DE102007061883A1|2007-12-20|2009-06-25|Bayer Materialscience Ag|Viscoelastic polyurethane foam|
    US8044109B2|2008-04-03|2011-10-25|Momentive Performance Materials Inc.|Polyurethane foams containing silicone surfactants|
    CN101250329A|2008-04-14|2008-08-27|东北林业大学|Crop straw-polyurethane foam composite material and method for preparing same|
    EP2140888A1|2008-07-04|2010-01-06|Bayer MaterialScience AG|Layered compound, intended as wound dressing, containing a polyurethane foam layer, an absorbent layer and a covering layer|
    US8735460B2|2009-01-09|2014-05-27|DuPont Nutrition BioScience ApS|Foamed isocyanate-based polymer, a mix and process for production thereof|
    GB2467554A|2009-02-04|2010-08-11|Systagenix Wound Man Ip Co Bv|A wound dressing material featuring polyurethane foam integrated into a solid substrate|
    EP2226047B1|2009-03-06|2019-06-26|The Procter and Gamble Company|Absorbent core|
    CN102355878B|2009-03-19|2013-10-16|尤妮佳股份有限公司|Absorbent article|
    US20120175556A1|2009-09-18|2012-07-12|Basf Se|Open-Cell Foams Having Superabsorbers|
    CN102740818B|2009-12-09|2015-01-28|花王株式会社|Absorbent article|
    US20120053547A1|2010-08-31|2012-03-01|Karyn Clare Schroeder|Absorbent Composite With A Resilient Coform Layer|
    US8946820B2|2011-06-30|2015-02-03|Sharp Kabushiki Kaisha|Method for manufacturing semiconductor substrate, substrate for forming semiconductor substrate, stacked substrate, semiconductor substrate, and electronic device|
    US20130171393A1|2011-12-28|2013-07-04|Sealed Air Corporation |Foam and methods of making the same|
    US20130274349A1|2012-04-12|2013-10-17|Jian Qin|Open-celled foam with superabsorbent material and process for making the same|
    WO2013180937A1|2012-05-29|2013-12-05|3M Innovative Properties Company|Absorbent article comprising polymeric foam with superabsorbent and intermediates|
    CN107158445B|2012-05-29|2021-01-15|3M创新有限公司|Absorbent article comprising polymeric foam and intermediate|
    EP2674449A1|2012-06-11|2013-12-18|3M Innovative Properties Company|Nanosilica coating assembly with enhanced durability|CN107158445B|2012-05-29|2021-01-15|3M创新有限公司|Absorbent article comprising polymeric foam and intermediate|
    US9744755B2|2013-04-01|2017-08-29|3M Innovative Properties Company|Method of making absorbent foam composites|
    GB2528004A|2013-05-08|2016-01-06|Procter & Gamble|Absorbent article with dual core|
    RU2662631C2|2014-05-05|2018-07-26|Дзе Проктер Энд Гэмбл Компани|Heterogeneous mass containing foam|
    EP2952166A1|2014-06-03|2015-12-09|The Procter and Gamble Company|Absorbent element for disposable absorbent articles having an integrated acquisition layer|
    EP2952164A1|2014-06-03|2015-12-09|The Procter and Gamble Company|Method for making an absorbent element for disposable absorbent articles having an integrated acquisition layer|
    EP2952165A1|2014-06-03|2015-12-09|The Procter and Gamble Company|Absorbent element for disposable absorbent articles having an integrated acquisition layer|
    US11173070B2|2015-04-28|2021-11-16|The Procter & Gamble Company|Heterogeneous foam materials having a graphic printed thereon|
    TWI597075B|2015-05-12|2017-09-01|Hydrophilic polyurethane, hydrophilic polyurethane foam and its preparation Wet wound dressing|
    US20160331860A1|2015-05-12|2016-11-17|Taicend Technology Co., Ltd|Wet wound dressing|
    CN106310497A|2015-07-01|2017-01-11|泰升国际科技股份有限公司|Negative pressure therapeutic apparatus|
    EP3359207A4|2015-10-05|2019-05-08|3M Innovative Properties Company|Absorbent article comprising flexible polymeric foam and intermediates|
    EP3370673A1|2015-11-04|2018-09-12|The Procter and Gamble Company|Absorbent structure|
    CN108348378B|2015-11-04|2021-07-20|宝洁公司|Thin and flexible absorbent article|
    US20170119597A1|2015-11-04|2017-05-04|The Procter & Gamble Company|Thin and flexible absorbent articles|
    EP3370666A1|2015-11-04|2018-09-12|The Procter and Gamble Company|Thin and flexible absorbent articles|
    JP6868964B2|2016-03-17|2021-05-12|株式会社リブドゥコーポレーション|Absorbent article|
    EP3228330A1|2016-04-08|2017-10-11|Mölnlycke Health Care AB|Composite materials in wound treatment|
    EP3323398B1|2016-11-22|2020-10-28|The Procter and Gamble Company|Unitary storage layer for disposable absorbent articles|
    JP2020529246A|2017-08-02|2020-10-08|ケーシーアイ ライセンシング インコーポレイテッド|Systems and methods for wound wound resection|
    GB2582508B|2017-11-29|2022-02-16|Kimberly Clark Co|Fibrous sheet with improved properties|
    CN113301875A|2019-01-23|2021-08-24|宝洁公司|Packaged feminine sanitary pad product suitable for concealed carrying and taking and method of manufacture|
    EP3711736A1|2019-03-18|2020-09-23|Ontex BVBA|Absorbent articles having an anisotropic foam acquisition layer|
    CN110577627A|2019-09-09|2019-12-17|上海万华科聚化工科技发展有限公司|Preparation method and application of absorbing material with high absorption capacity|
    法律状态:
    2018-03-27| B06F| Objections, documents and/or translations needed after an examination request according art. 34 industrial property law|
    2019-05-28| B07A| Technical examination (opinion): publication of technical examination (opinion)|
    2019-09-10| B09A| Decision: intention to grant|
    2019-10-01| B16A| Patent or certificate of addition of invention granted|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 05/04/2013, OBSERVADAS AS CONDICOES LEGAIS. (CO) 20 (VINTE) ANOS CONTADOS A PARTIR DE 05/04/2013, OBSERVADAS AS CONDICOES LEGAIS |
    优先权:
    申请号 | 申请日 | 专利标题
    US201261652388P| true| 2012-05-29|2012-05-29|
    US61/652.388|2012-05-29|
    US201361787888P| true| 2013-03-15|2013-03-15|
    US61/787.888|2013-03-15|
    PCT/US2013/035390|WO2013180832A1|2012-05-29|2013-04-05|Absorbent article comprising polymeric foam and intermediates|
    [返回顶部]