• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    Multilayer aluminum brazing sheet for controlled atmosphere free flow brazing is described an aluminum brazing sheet comprising an interlayer aluminum alloy core material and an al-brazing alloy. The interlayer consists of an aluminum alloy comprising <-1.0% of itself and 0.1-2.5% mg. the al-si brazing alloy comprises 5-14% si and 0.01-1.0% bi. The core material and the interlayer have a melting temperature that is higher than that of the brazing alloy.
    公开号:BR112014029796B1
    申请号:R112014029796-7
    申请日:2013-05-28
    公开日:2019-04-02
    发明作者:Linda AHL；Richard Westergãrd；David Abrahamson
    申请人:Gränges Sweden Ab；
    IPC主号:
    专利说明:

    [0001] The present invention relates to a multilayer aluminum brazing sheet comprising core material covered by an interlayer, and an outer brazing layer to the brazing layer. The invention also relates to a heat exchanger comprising said improved multilayer aluminum brazing sheet.
    Background [0002] The present invention relates to sheet materials to be joined by brazing aluminum materials in an inert or reducing atmosphere, usually at atmospheric pressure, without the need to apply a flow to break, dissolve or displace the surface oxide layer.
    [0003] A challenge today is to design and manufacture materials and components for the heat exchanger industry at the lowest possible cost and with the highest possible quality.
    The technology most commonly used in the production of heat exchangers is brazing in a controlled atmosphere normally consisting of nitrogen with as low an amount of oxidizing impurities (mainly gaseous oxygen and water vapor) as possible. This process is known as controlled atmosphere brazing (CAB) and involves the application of a flux based on Al-K-F, for example, flux
    Nocolok, on the surfaces to be joined before brazing.
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    2/20
    The flow breaks, displaces or dissolves the surface oxide layer of the metal fill in order to facilitate the wetting between a flow fill and the surfaces of the individual components of the heat exchanger. The flow also prevents or reduces the formation of new oxides during the formation of the joint. The flux residues after brazing, however, are often considered harmful to the heat exchanger as they detach themselves from the brazed aluminum surfaces and clog the internal channels, thus preventing effective use of the heat exchanger. Sometimes arguments are heard that the use of flux in some cases promotes corrosion and erosion and leads to less effective units and sometimes premature failure of the unit. There are also some questions regarding the chemical reactions that occur between the waste stream and the corrosion inhibitors used in the middle of, for example, the radiator circuit which can cause damage to the system. In addition to the purely function-related disadvantages, the impact of the flow on, for example, the work environment, cost, brazing investments related to the equipment and its maintenance, energy and the natural environment is severe.
    [0004] In addition to the limitations mentioned above, the efficiency of removing oxide from a CAB flow is reduced by using Mg as an alloying element in the material to be brazed. This is due to the reaction between Mg and the flow-forming compounds which have a very high melting temperature and which prevents wetting, fillet formation and union growth. This incompatibility is problematic as Mg
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    3/20 is very efficient when it provides resistance to aluminum materials. Consequently, CAB has been restricted to non-heat-treatable alloys (NHT) and alloys that contain a low amount of Mg. It is well known that Mg starts to affect the result of the brazing already at trace levels and at levels of 0.2% most CAB users have major problems with the formation of the joint. The problem can be solved to some extent by increasing the flow additions or by using exclusive and expensive degrees of flow containing Cs. The problem is, however, not solved, but instead shifted towards marginally higher Mg levels.
    [0005] In order to be able to produce heat exchangers using CAB without the application of flow, it is then necessary to develop new concepts and material designs to make the formation of brazing joints possible.
    [0006] All temper and alloy designations used hereinafter refer to the Aluminum Association Designation Standards and Data and the Registration Records, as published by the Aluminum Association in 2007. All percentages relating to the chemical content in an alloy are to be understood hereinafter as indicating weight percentage.
    [0007] EP 1306207 B1 describes an aluminum brazing alloy suitable for brazing in an inert gas without the use of a flux. This invention is based on a multilayer brazing sheet, where the outer material is a thin layer that covers an Al-Si based alloy containing 0.1 to 0.5% Mg and 0.01 to 0.5% of Bi, and a
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    4/20 core material. During the temperature rise stage of a brazing cycle, the middle layer of Al-Si first will begin to melt and expand volumetrically in order to break the thin layer of cover allowing the molten metallic fill to penetrate the cracks and surface of the sheet brazing.
    [0008] In WO 2008/155067 A1 a method for brazing without flow is described. The invention is based on a multilayer aluminum foil comprising a thin covering layer, an Al-Si brazing material as an intermediate layer between the covering layer and the core. The cover alloy and the core alloy have a solidification temperature above the liquefaction temperature of the brazing material. The Al-Si brazing alloy contains 0.01-0.09% Mg and 0.01-0.5% Bi. The Mg content of the core is preferably <0.015%. In this document, brazing without flow is made possible by maintaining a total Mg content of the brazing sheet below 0.06%.
    [0009] The configuration of the brazing sheet of the prior art documents identified above is similar. Both are based on a core, an intermediate brazing metal that contains Mg and Bi, covered by a thin layer of coverage. There is a potential risk with such a brazing sheet structure. There must be a period of time between melting the filling and moistening it. The influence of gravity on the melt can cause the filling flow under the surface oxide, resulting in an inhomogeneous joint size and large localized accumulations of melt filling.
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    5/20 [0010] The methods for brazing without flow available in the state of the art present a restriction in that they require either an external cover with a higher melting temperature than the underlying brazing, or it is a combination of two layers of different brazing which were both intended to melt during the brazing process. This does not allow for a sophisticated potential corrosion gradient design, high strength sheet design and flow-free joining.
    There is also a desire to improve the brazing process.
    [0011] The demands mainly from the automotive industry are increasing with respect to the amount of residual flow that is allowed in a heat exchanger system.
    It is difficult and expensive to apply small and repeated amounts of flux to areas located on the internal surfaces of a heat exchanger in order to repeatedly form high quality internal joints and this invention provides a clear advantage in this aspect of heat exchanger production.
    [0012] Thus, there is still a need to provide a brazing sheet that overcomes the problems identified above.
    [0013] Other examples of previously known aluminum alloy brazing sheets are known from US patent 6,627,330 B1 and WO 2010/052231, which describe both outer layers with a high or intentionally added Mg content.
    Summary of the invention [0014] The purpose of the present invention is to provide an aluminum alloy brazing sheet that can be brazed
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    6/20 in an inert or reducing atmosphere, without the need to apply a flux, which results in improved brazing connections, and which allows for a sophisticated sophisticated corrosion design.
    [0015] The objective is achieved by the aluminum alloy brazing sheet according to independent claim 1. Achievements are defined in the dependent claims.
    [0016] The aluminum alloy brazing sheet according to the present invention is especially suitable for brazing for one or more components other than the brazing sheet itself, in particular the brazing of fins or indents on the outer surface of a tube made from aluminum foil brazing.
    [0017] The aluminum alloy brazing sheet comprises an aluminum alloy core material covered by an aluminum alloy interlayer, which in turn is covered by an Al-Si brazing alloy. The aluminum alloy of the interlayer comprises <1.0% Si and 0.1-2.5% Mg, preferably> 0.2% Mg, more preferably> 0.3% Mg, even more preferably> 0 , 5% Mg. The Al-Si brazing alloy comprises 5-14% Si and 0.011.0% Bi, preferably 0.05-0.5% Bi, most preferably 0.07-0.2% Bi, < 0.8% Fe, <6% Zn, <0.1% Sn, <0.1% In, <0.3% Cu, <0.15% Mn, <0.05% of Sr, and unavoidable impurities each in amounts below 0.05% by weight and a total impurity content below 0.2% by weight, the remainder consisting of aluminum. The core and interlayer material have a melting temperature that is higher than that of the brazing alloy.
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    7/20 [0018] The present invention is thus based on a completely different brazing sheet configuration from that described, for example, in EP 1306207 B1 and WO 2008/155067 A1 to obtain good weldability without flow in a controlled atmosphere and increased corrosion protection, and circumvents possible limitations of the state of the art.
    [0019] According to one embodiment, the aluminum alloy of the interlayer comprises at least 0.9% Mg.
    [0020] According to yet another embodiment, the aluminum alloy of the interlayer comprises a maximum of 2.2% Mg.
    [0021] According to one embodiment, the interlayer is directly adjacent to the core material, that is, without any intermediate layer between the interlayer and the core material. According to another embodiment, the brazing layer is directly adjacent to the interlayer, that is, without any intermediate layer between the brazing layer and the interlayer. According to yet another embodiment, the interlayer is sandwiched between the core layer and the brazing alloy without any additional layers between the core layer and the brazing alloy.
    [0022] The aluminum alloy brazing sheet is used to produce brazed products such as heat exchangers.
    [0023] Since there is no flow present on the external surfaces of the heat exchanger produced from the brazing sheet according to the invention, any difficulties in loosening the flow residue that may enter, for example, the passenger compartment of the vehicle, is avoided. This also increases the visual appearance
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    8/20 of the heat exchanger. Since there is no flow present on the internal surfaces of the heat exchanger, any difficulties related to clogging, erosion and chemical reactions between the flow and the cooling medium and other perceived disadvantages with the flow residue are avoided.
    [0024] There is also a clear cost advantage with respect to the heat exchanger units without the use of flow as it eliminates not only the cost of the flow itself, but also shortens the passage time across the line brazing, allows for lower labor costs, frees up space on the factory floor, reduces the demand for maintenance of the brazing equipment and reduces the demand for cleaning service. Also, important benefits must be attributed to a better working environment for workers, less disposal of solid waste and wastewater from the fluid system and lesser amounts of harmful gaseous effluents from the brazing process.
    Detailed description of the invention [0025] The aluminum alloy brazing sheet of the present invention consists of an aluminum-based core, covered on one or both sides by an Mg-rich aluminum alloy as an interlayer, which in turn is covered by an Al-Si brazing alloy, where said brazing contains an addition of Bi. The liquid temperature of the Al-Si brazing alloy is lower than the solid temperature of the core and interlayer, which has a higher liquid temperature than the highest permissible brazing temperature. The interlayer Mg must diffuse to the
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    9/20 outer surface of the braze during heating to the brazing temperature. If a correct amount of Mg reaches its destination and at the right time, the oxide will be broken to make it possible for the molten metal filling to moisten any counter-surface and form a bond,
    While that presenting an interlayer intact what Assists in providing a gradient in potential in corrosion through the thickness of leaf powder brazing. At
    of the present invention, the Mg content in the filler material, i.e. the brazing material, is preferably <0.01%. The present invention shows that optimal weldability is achieved with Mg in an interlayer between the core and the metallic fill.
    [0026] The invention is hereinafter described as a three-layer aluminum alloy brazing sheet where brazing occurs on one side of the sheet. However, the invention can be used to create brazing joints on both sides of the core, in which case the brazing sheet will be formed by five layers. It can also be covered by a sacrificial edge on one side and be a sheet or edge of four layers with an interlayer between the core and an edge coating that will provide a sheet of five layers.
    [0027] The present invention provides an aluminum alloy brazing sheet product comprising: a core material covered by an Mg-rich interlayer which in turn is covered by an Al-Si alloy containing Bi to improve the performance of the brazing, where the core and interlayer material have a higher melting temperature than that of the brazing alloy and in fact higher melting temperatures
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    10/20 higher than the desired brazing temperature. The Mg of the interlayer diffuses through the brazing layer to the outer surface of the braze during heating to the brazing temperature. If a correct amount of Mg reaches its destination and at the correct time, the surface oxide will be broken, making it possible for the molten metal filling to moisten any counter-surface and form a bond, while maintaining an intact interlayer that helps to provide a potential gradient of corrosion through the sheet thickness after brazing. To allow a good union to be formed in a heat exchanger, the braze must melt at around 577 ° C and the heating can reach temperatures in the range of 585-610 ° C. There is usually a tendency to target the 595-605 ° C range.
    This requires the interlayer liquid and the core layer to be higher and must both have liquid temperatures above 615 ° C.
    The brazing alloy [0028] The Al-Si brazing alloy preferably does not contain a maximum of 0.02% Mg, more preferably <0.01% Mg in order to obtain a good brazing. It is important that the Mg content in the thin brazing layer is kept low in order to avoid excessive growth of oxides on the surface during heating before brazing. The addition of Bi in the brazing layer according to the present invention improves the formation of the joint, in such a way that the joint is formed more quickly and has a larger size. It can also contain Zn, Sn and In which reduce the corrosion potential of aluminum alloys or Cu and Mn which increase the corrosion potential. Sr is a
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    11/20 powerful modifier to obtain a small particle size of Si and can also be present in technologically motivated quantities of up to 500 ppm.
    [0029] The amount of Si in the Al-Si brazing alloy can be chosen to suit the desired special brazing process and is usually between 5 and 14% Si, but is preferably 7 to 13% Si.
    [0030] A preferred AlSi brazing alloy composition thus contains:
    Si from 5 to 14%, preferably from 7 to 13%,
    Mg <0.02%, preferably <0.01%,
    Bi from 0.01 to 1.0%, preferably from 0.05 to 0.5%, most preferably from 0.07 to 0.2%,
    Fe <0.8%
    Cu <0.3%,
    Mn <0.15%,
    Zn <6%,
    Sn <0.1%
    In <0.1%
    Sr <0.05%, and unavoidable impurities each in quantities below 0.05% and a total impurity content below 0.2%, the rest being made up of aluminum.
    The core material [0031] The brazing foil of the present invention can be used with any aluminum brazing foil core material. A suitable core material can be any alloy in the AA3xxx series. It was found in the present invention that the formation of brazing joints works well also with Mg added to the core alloy, which means that the
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    12/20 core can exhibit greater resistance. The core may also contain Mn for resistance, weldability and corrosion performance and Cu to modify the corrosion performance and for post-brazing resistance. It can also contain Si for strength and dispersion formation, as well as Ti for strength, corrosion and grain refining in machining. The elements Zr, Cr, V and Sc can be present for resistance modification and as dispersion-forming.
    [0032] Thus, the core alloy preferably contains:
    Mn <2, 0%,Ass *1, 2%,Faith *1, 0%,Si *1, 0%,You * 0, 2%,Mg *2, 5%, preferably 0.03-2.0% Zr, Cr , V and / or Sc * 0.2% in total, and
    unavoidable impurities each in quantities below 0.05% and a total impurity content below 0.2%, the remainder being made up of aluminum.
    The interlayer [0033] The thin interlayer consists of an aluminum alloy, having a melting point above the melting point of the Al-Si brazing metal, it will need to contain a substantial amount of Mg to allow diffusion through the surface brazing of way to break the oxide on the surface.
    The interlayer, for this reason, must have a Mg content above 0.1%, more preferably above 0.2%.
    The most preferred case with Mg being added to the alloy in amounts of
    0.3% or
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    13/20 more, most preferably being above 0.5%.
    bonding is feasible with 0.5% interlayer, as shown in the examples.
    However, significantly better with at least
    0.9% Mg in the interlayer.
    lamination capacity of the material may be impaired Mg content when that of the interlayer exceeds 2.5%.
    Preferably, the maximum content of Mg at interlayer not exceeds 2.2%. In this way, the content in Mg of the interlayer is 0.1-2.5%, preferably in0.2-2.5% more preferably 0.3-2.5%, still more preferably from
    THE
    0.5-2.5%, and most preferably 0.9-2.2%.
    interlayer can also contain Si,
    Mn, Fe, Ti, Cu, Zn,
    Cr,
    Zr, V and
    Sc for the same reasons as the core material.
    Zn,
    Sn and In can be included to reduce the corrosion potential of the alloy and assist in creating an appropriate post-brazing corrosion potential gradient across the thickness of the sheet.
    [0034] The interlayer alloy, in this way, preferably
    0.1-2.5% Mg, preferably ^ 0.2%, more preferably> 0.3%, even more preferably ^ 0.5%, most preferably 0.9-2.2%
    Mn <2.0%,
    Cu <1.2%,
    Fe <1.0%,
    Si <1.0%,
    Ti <0.2%,
    Zn <6%,
    Sn <0.1%,
    In <0.1%,
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    14/20
    Zr, Cr, V and / or Sc ^ 0.2% in total, and unavoidable impurities each in amounts less than 0.05%, and a total impurity content below 0.2%, the remainder being made up of aluminum.
    The composite brazing sheet [0035] By providing an aluminum alloy brazing sheet product comprising: a core material covered by an interlayer containing Mg, which in turn is covered by an Al-Si alloy containing Bi for improve brazing performance, where said core material and interlayer have a melting temperature that is higher than that of the brazing alloy and in fact melting temperatures higher than the desired brazing temperature. The brazing sheet can be effectively brazed in a controlled atmosphere without the use of flux. The opposite side may be uncoated, arranged in a similar configuration, coated with a sacrificial coating, or an Al-Si brazing coating. However, brazing sheets that can be used in the present invention are not limited to the above configurations.
    [0036] The total thickness of the aluminum brazing sheet is between 0.1 and 4 mm, which is suitable in the manufacture of heat exchangers. The interlayer thickness is preferably from 5 to 200pm, in order to provide an effective rupture of the oxide during brazing. The thickness of the brazing layer can be between 5 and 100 pm. The total thickness of the coating layer in relation to the total thickness of the multilayer brazing sheet is preferably 3 to 30%. The thickness of the brazier is chosen in such a way that sufficient filling is
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    15/20 available to provide a suitable size after brazing connection.
    Also, the thickness must be chosen in such a way that a sufficient amount of Mg is diffused through the brazing layer to the external oxide during the brazing heating, thus providing an adequate breakdown of the oxide and good wetting. The thickness of the interlayer in relation to the brazing alloy layer is between 25% and
    250%, with most applications requiring a thickness ratio in the range of 50% to 150%.
    suitable temperature range in which the brazing is conducted is in the range of
    580 ° C to 610 ° C, and preferably from 590 ° C to 605 ° C.
    [0037] Chemistry da and cores should be chosen of such so that after the brazing provide a gradient in corrosion potential appropriate. This means what The interlayer should to be properly sacrificial for O
    core.
    [0038] The leaf design is ideally such that a sufficient amount of
    Mg reaches the oxide / metal interface in order to break down the oxide at the correct time during the brazing heating cycle.
    If too much Mg reaches the oxide / metal interface too early during the brazing heating cycle, excess Mg can cause the production of a thick oxide and prevent wetting and bond formation. If too little Mg reaches the oxide / metal interface or if it arrives too late during the brazing heating cycle, wetting and bonding will be incomplete or absent.
    This is because the filler can flow under the unbroken oxide layer.
    In this way, the brazing heating cycle is very
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    16/20 important and should be considered in conjunction with the sheet design, thermomechanical production route, oven characteristics and the assembly design of the rest of the heat exchanger to provide a successful flow-free brazing result.
    [0039] The invention further provides a heat exchanger comprising the aluminum alloy brazing sheet as described above.
    Production of the brazing sheet [0040] Each of the alloys described above can be machined using machining by vertical casting (direct chill - DC) or machining by continuous double laminator or continuous machining on a belt machining machine. the choice of machining technique is decided by technical, economic and capacity considerations. The core alloy is machined like a plate using a DC machining route, while the middle layer and the outer thin layer are machined using either DC machining or continuous machining techniques.
    [0041] The predominant technique currently used is DC machining and then the plates of the brazing alloy ingot and the interlayer alloy are both scalped and then heated in an oven to a temperature between 350 and 550 ° C and the duration at temperature of soaking varies from 0 to 20 hours. Subsequently both alloys are hot rolled to the desired thickness and cut to the appropriate lengths. The interlayer plate is then placed on the scaled surface of the core ingot and the brazing alloy plate is then placed on the surface of the interlayer. The plates are kept in the
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    17/20 place on the core plate by means of seam welds along two opposite sides by means of MIG welding, or by means of steel strips or by other suitable techniques to obtain a manageable ingot package. The package is then placed in a preheating oven. The package is
    heated for a temperature between 350 ° C and 550 ° C and duration soak temperature is between 0 and 20 hours. After that the coating package is laminated to hot, cold rolled to the final dimension, stretched
    to increase leveling and cut to the delivery width. The intermediate and final heat treatments to obtain an easier production and the correct release tempering are carried out as needed.
    Examples [0042] All the alloys in the examples were machined using laboratory machining equipment in the so-called book molds producing small plates with a length of 150 mm, a width of 90 mm and a thickness of 20 mm. The chemical compositions of the alloys tested for weldability can be seen in table 1.
    [0043] Each plate was scalped, heated from room temperature to 450 ° C for 8 hours, soaked at 450 ° C for 2 hours and cooled to room air. Then the materials were laminated to a suitable thickness and annealed between steps when necessary to facilitate easy lamination. Then the materials of the core, the brazing intermediate layer and the outer layer were combined to obtain three layer coating packages where the layers were fixed together by means of cold lamination. The materials were
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    18/20 cold rolled to a thickness of 0.25 mm, which produced a single-sided coating with 10% interlayer and 10% brazing layer, with mild intermediate annealing when needed to produce easy lamination and final annealing for a H24 temper to provide large grains of recrystallization in the core during the subsequent brazing procedure. Instead of annealing annealing, it is possible to provide worked anneals, for example, H12, H14 or H112, in order to provide large recrystallization grains.
    Table 1 Chemical compositions in% by weight of the alloys tested from the analysis of the castings with OES.
    turns on Type Si Faith Ass Mn Mg You Zr Bi THE Core 0.14 0.50 0.12 1.09 <0.01 0.02 <0.01 <0.01 B Core 0.07 0.22 0.81 1.70 <0.01 0.05 0.14 <0.01 Ç Core / interlayer 0.75 0.22 0.29 0.60 0.31 0.15 <0.01 <0.01 D Core 0.68 0.25 0.30 0.03 0.42 0.14 <0.01 <0.01 AND Core / interlayer 0.05 0.20 0.28 1.30 0.22 0.02 <0.01 <0.01 F Core / interlayer 0.50 0.22 <0.01 0.06 0.67 0.01 <0.01 <0.01 G Interlayer 0.05 0.17 <0.01 <0.01 0.51 <0.01 <0.01 <0.01 H Interlayer 0.03 0.15 <0.01 <0.01 0.96 <0.01 <0.01 <0.01 I Interlayer 0.03 0.15 <0.01 <0.01 1.9 <0.01 <0.01 <0.01 J Interlayer 0.07 0.28 <0.01 0.80 1.1 <0.01 <0.01 <0.01 K Interlayer 0.09 0.33 <0.01 1.7 1.0 <0.01 <0.01 <0.01 L Interlayer 0.05 0.17 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 M Brazing 10.0 0.23 <0.01 0.01 1.26 <0.01 <0.01 0.09 N Brazing 10.2 0.17 <0.01 <0.01 0.11 <0.01 <0.01 0.12 O Brazing 8.0 0.18 <0.01 <0.01 <0.01 <0.01 <0.01 0.11 P Brazing 8.0 0.18 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 Q Brazing 10.2 0.17 <0.01 <0.01 <0.01 <0.01 <0.01 0.12
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    19/20 [0044] The brazing was carried out in a laboratory glass oven with approximately 3 dm 3 of brazing chamber. The furnace was flushed with nitrogen throughout the brazing cycle at a rate of 10 standard liters per minute. The brazing cycle was a linear heating from room temperature to 600 ° C in 10 minutes, soaking for 3 minutes at 600 ° C followed by cooling to air at room temperature. The sample establishment was a simple uncoated beaded corner on a bead where the lining materials were used as a bead and an uncoated AA3003 with a 0.5 mm gauge was used as the corner. All brazing was carried out without flow. The samples were examined visually for brazing joints and a representative selection of some of the results is provided below.
    Table 2 Selected experimental results
    Comment Core Interlayer Brazing Result Ex 1Standard CAB sheet Comparative B - P No union between the coated bead and the uncoated corner. Ex 2Standard vacuum brazing sheet. Comparative THE - M No union between coated bead and uncoated corner. Ex 3 Inventive B G O Union formed between coated bead and uncoated corner. Small. Ex 4 Inventive Ç H Q Union formed between coated bead and uncoated corner. Ex 5 Inventive D I O Union formed between coated bead and uncoated corner.
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    20/20
    Ex 6 Inventive AND J Q Union formed between coated bead and corner uncoated. Ex 7 Inventive F K O Union formed between coated bead and uncoated corner. Ex 8 Comparative B G N No union, too muchMg on brazing Ex 9 Inventive B Ç O Union formed between coated bead and uncoated corner, very slightly slow. Ex 10 Inventive B AND O UNION, but reluctant Ex 11 Inventive B F O Union formed between coated bead and uncoated corner. Ex 12 Comparative F K P No joining, no Bi on brazing Ex 13 Comparative B L O No union, noMg in the interlayer
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    权利要求:
    Claims (15)
    [1]
    1. Aluminum alloy brazing sheet for free flowing brazing suitable for brazing for other components, characterized by comprising an aluminum alloy core material covered by an aluminum alloy interlayer consisting of:
    Mg from 0.2% to 2.5% by weight, preferably> 0.2% by weight, more preferably> 0.3% by weight, most preferably between 0.5% and 2.5% by weight,
    Mn
    Ass
    Faith
    Si
    You
    Zn
    Sn
    In
    <2.0% in Weight, <1.2% in Weight, <1.0% in Weight, <1.0% in Weight, <0.2% in Weight, <6% by weight, <0.1% in Weight, <0.1% in Weight,
    and
    Cr, V and / or Sc
    Zr, <0.2% in total, and unavoidable impurities each in amounts below 0.05% by weight, and a total impurity content below 0.2% by weight, the remainder consisting of aluminum, the interlayer being covered by an Al-Si brazing alloy consisting of 5% to 14% by weight of Si, <0.02% by weight of Mg, 0.05% to 0.2% by weight, of Bi, <0.8% by weight of Fe, <6% by weight of Zn, <0.1% by weight of Sn, <0.1% by weight of In, < 0.3% by weight of Cu, <0.15% by weight of Mn, <0.05% by weight of Sr, and unavoidable impurities each in amounts below 0.05% by weight and a total impurity content below 0.2% by weight, the remainder consisting of aluminum, and in which said core material and the interlayer
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    [2]
    2/4 have a melting temperature that is higher than that of the brazing alloy and in which the interlayer is sacrifice in relation to the core.
    2. Aluminum alloy brazing sheet, according to claim 1, characterized in that the core material is a 3XXX alloy, preferably containing:
    Mn <2, 0% in Weight, Ass <1, 2% in Weight, Faith <1, 0% in Weight, Si <1, 0% in Weight, You <0, 2% in Weight, Mg <2, 5% in weight, preferably 0.03% to 2.0% by weight
    Zr, Cr, V and / or Sc <0.2% by weight in total, and unavoidable impurities each in quantities below 0.05% by weight and a total impurity content below 0.2% by weight , the rest consisting of aluminum.
    [3]
    Aluminum alloy brazing sheet according to any one of claims 1 and 2, characterized in that the Al-Si brazing alloy contains from 0.07% to 0.2% by weight of Bi .
    [4]
    Aluminum alloy brazing sheet according to any one of claims 1 to 3, characterized in that the Al-Si brazing alloy contains <0.01% by weight of Mg.
    [5]
    Aluminum alloy brazing sheet according to any one of claims 1 to 4, characterized in that the Al-Si brazing alloy contains from 7% to 13% by weight of Si.
    Petition 870190006304, of 01/21/2019, p. 34/36
    3/4
    [6]
    Aluminum alloy brazing sheet according to any one of claims 1 to 5, characterized in that the melting point of the interlayer and that of the core is> 615 ° C.
    [7]
    Aluminum alloy brazing sheet according to any one of claims 1 to 6, characterized in that the melting point of the brazing alloy is from 550 ° C to 590 ° C.
    [8]
    Aluminum alloy brazing sheet according to any one of claims 1 to 7, characterized in that the ratio of the thickness of the interlayer to the thickness of the brazing alloy layer is 25% to 250%, preferably 50% to 150%.
    [9]
    Aluminum alloy brazing sheet according to any one of claims 1 to 8, characterized in that the thickness of the interlayer is from 5 pm to 200 pm.
    [10]
    Aluminum alloy brazing sheet according to any one of claims 1 to 9, characterized in that the brazing sheet has a brazing coating layer or a sacrificial coating layer on the opposite side of the core. comprising interlayer and brazing alloy.
    [11]
    11. Aluminum alloy brazing sheet according to claim 10, characterized in that the sacrificial coating on the opposite side of the core is covered by a sacrificial or brazing layer.
    [12]
    12. Brazed product characterized by the fact that it comprises an aluminum alloy brazing sheet as defined in any one of the claims
    Petition 870190006304, of 01/21/2019, p. 35/36
    4/4, in which the interlayer is sacrifice in relation to the nucleus.
    [13]
    13. Brazing method of a heat exchanger characterized by the fact that it is at a temperature in the range of 580 ° C to 610 ° C and in a controlled atmosphere without the use of flux, using an aluminum alloy brazing sheet as defined in any one of claims 1 to 11, for fins, tubes or upper plates.
    [14]
    14. Heat exchanger characterized by the fact that it comprises an aluminum alloy brazing sheet as defined in any one of claims 1 to 11.
    [15]
    15. Use of an aluminum alloy brazing sheet as defined in any of claims 1 to 11, characterized by the fact that it is for the production of heat exchangers.
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    同族专利:
    公开号 | 公开日
    WO2013180630A1|2013-12-05|
    JP6415429B2|2018-10-31|
    KR102131153B1|2020-07-07|
    CN104395028A|2015-03-04|
    BR112014029796A2|2017-08-08|
    KR20150021085A|2015-02-27|
    EP2855063B2|2022-01-19|
    RU2014153559A|2016-07-27|
    JP2015528852A|2015-10-01|
    HUE028924T2|2017-01-30|
    PL2855063T3|2016-10-31|
    US20150165564A1|2015-06-18|
    MX2014014444A|2015-09-08|
    EP2855063B1|2016-03-23|
    CN104395028B|2018-01-02|
    IN2014DN09944A|2015-08-14|
    RU2642245C2|2018-01-24|
    EP2855063A1|2015-04-08|
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    法律状态:
    2018-10-23| B07A| Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]|
    2019-02-26| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|
    2019-04-02| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 28/05/2013, OBSERVADAS AS CONDICOES LEGAIS. (CO) 20 (VINTE) ANOS CONTADOS A PARTIR DE 28/05/2013, OBSERVADAS AS CONDICOES LEGAIS |
    优先权:
    申请号 | 申请日 | 专利标题
    SE1250566|2012-05-31|
    SE1250566-5|2012-05-31|
    PCT/SE2013/050606|WO2013180630A1|2012-05-31|2013-05-28|Multilayer aluminium brazing sheet for fluxfree brazing in controlled atmosphere|
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