optical effect layer, device and method to produce it, security document and use of an optical effec

专利摘要:
OPTICAL EFFECT LAYER, DEVICE AND METHOD TO PRODUCE THE SAME, DOCUMENT SECURITY AND USE OF AN OPTICAL EFFECT LAYER The invention concerns the field of graphic elements and is directed to an optical effect layer (OEL), a device and a method for produce the same. The invention solves the problem of providing an optical effect that is easy to detect as such and exhibits apparent motion depending on the viewing angle of image characteristics over an extended length, if the angle of view changes with respect to the OEL. This objective is achieved by providing an OEL comprising a binder material that is at least partially transparent and a plurality of particles dispersed within the layer. Each particle has a non-isotropic reflectivity and can be either magnetic or magnetizable. The orientation of the particles forms an orientation pattern extending over a length within an extended surface of the OEL, such that in a first cross section of said OEL, substantially perpendicular to said extended surface and along said first direction x , the local average of an angle between (i) a straight line along (...).
公开号:BR112014026974B1
申请号:R112014026974-2
申请日:2013-04-30
公开日:2020-12-08
发明作者:Pierre Degott；Mathieu Schmid；Claude-Alain Despland；Cédric Amerasinghe
申请人:Sicpa Holding Sa；
IPC主号:

专利说明:

Field of invention
[0001] The present invention concerns the field of graphic elements and is directed to an optical effect layer showing an angle-dependent optical effect and a device and method for producing the optical effect layer. In particular, an application of the optical effect layer is in the field of security elements for the protection of banknotes, passports and other documents and for brand protection. In addition to this or alternatively, the optical effect layer can also be used for decorative purposes. Fundamentals of the invention
[0002] Security features, for example, for document security, can be classified into "hidden" security features, on the one hand, and "explicit" security features, on the other hand. The protection provided by hidden security features depends on the concept that such features are difficult to detect, usually requiring specialized equipment and knowledge for detection, "explicit" security features depend on the concept of being easily detectable with helpless human senses, for example , such characteristics can be visible and / or detectable by means of tactile sense, while they are still difficult to produce and / or copy. However, the effectiveness of explicit security features depends to a large extent on its easy recognition as a security feature, due to the majority of users, and particularly those who have no prior knowledge of the security features of a document or insured item. for these, you will only then perform a security check based on said security feature if they have real knowledge of its existence and nature.
[0003] It is known in the art to use inks containing magnetically orientable pigments, also particularly optically magnetic variable pigments, for the production of explicit security elements, for example, in the field of security documents.
[0004] WO 2005/002866 A1, for example, discloses optically variable printed security elements comprising a high resolution image represented by optically variable magnetic pigment particles in a hardened coating layer. This high resolution image is produced in a printing process using a particular magnetic orientation device. The security document is first printed with a coating composition comprising magnetic or magnetizable particles, such as optically variable magnetic pigment flakes. The printed document is subsequently exposed, while the coating is still "wet", to the magnetic field of the magnetic guidance device, comprising a permanent magnetized magnetic plate engraved with clues. The magnetic or magnetizable particles of the coating are oriented under the influence of the magnetic field of the orientation device, thus forming an image of said recorded evidence. The coating is subsequently hardened in order to "freeze" the magnetic or magnetizable particles in their positions and orientations.
[0005] Optically variable magnetic pigments that can be used for this purpose have been disclosed, for example, in US 4,838,648 and EP 686,675 B1. Corresponding paint and coating compositions were disclosed in WO 2007/131833 A1.
[0006] WO 2008/046702 A1 discloses additional types of magnetically induced images produced by orienting optically variable magnetic pigment particles in a coating layer, as well as a device for producing said types of images. The device comprises the combination of a permanent magnetized magnetic plate etched with evidence with one or more additional magnets mounted with respect to the etched magnetic plate, such as holding them up against the inherent magnetic forces occurring between them.
[0007] WO 2004/007095 A2 discloses a device for orienting magnetic pigment flakes in a coating layer exposed to the magnetic field of one or more magnetic dipoles, to produce aesthetically attractive, optically luminous variable coatings, which, even if flat, show a smooth variation of color and reflectivity with the modification of the angle of view, which resembles a floating or mobile three-dimensional object. In particular, the remarkable device of WO 2004/007095 allows to orient flakes of magnetic pigment in a coating layer in order to produce a "scroll bar" effect in the resulting coating. A printed "scroll bar" type image shows a contrast band that appears to move ("roll") as the image is tilted and can be achieved with a single printing step and using a single ink formulation. Printed elements that exhibit a movement of evident image characteristics with angle of view modification, such as "scroll bar" effect, are copy protection means for security documents, which can be easily recognized and used for the authentication of a security document. The WO 2004/007095 device, however, may show the disadvantage that useful "scrollbar" type effects can only be produced over a relatively short length, and could therefore often be difficult to recognize as a safety feature.
[0008] This is illustrated in Figures 1a and 1b, each showing schematically a DM magnetic dipole generating a magnetic dipole field, and a substrate S positioned within said magnetic field on one side of and at a distance d from the DM magnet. and essentially parallel to its magnetic axis, that is, the virtual line between its north pole and magnetic south pole. The magnetic dipole in Figure 1a has a longer extension L along its magnetic axis than the magnetic dipole in Figure 1b along its respective magnetic axis. In both cases, reflective particles, for example, pigment particles, are provided dispersed within a layer of liquid binder material on top of the substrate S and are oriented by the magnetic field, usually in such a way that the respective longest extension of each particle is substantially aligned with the magnetic field lines at the particle's position. As can be seen when comparing Figures 1a and 1b, the magnetic dipole used in the device to orient the particles in a corresponding layer on a substrate S must have at least the length L along which the "scroll bar" effect is to be produced. The long magnetic dipole DM shown in Figure 1a has only slightly curved field lines at the location of the substrate S, whereas the short magnetic dipole DM shown in Figure 1b has field lines having a greater degree of curvature at the location of the substrates S. As a consequence, the resulting "scroll bar" impression, in the case of the long magnet in Figure 1a, shows a large luminous zone z, which only exhibits a slight evident movement with modification of the angle of view, that is, a dynamic effect poor and unattractive, considering that in comparison the resulting "scroll bar" impression in the case of the short magnet in Figure 1b shows only a small luminous zone z, which, however, exhibits a strong evident movement with modification of the angle of view . However, due to the relatively limited length corresponding to the short magnetic dipole, the safety feature is not attractive and is not easy to recognize, particularly if someone has no prior knowledge of its presence and / or optical effect. Therefore, a need for safety features remains, exposing an attractive dynamic optical effect over an extended length. Summary of the invention
[0009] It is therefore an object of the present invention to provide a layer of optical effect, for example, on a document or other item, which exhibits movement of evident image characteristics dependent on the angle of view over an extended length. It is particularly desirable to provide such an optical effect layer as an explicitly enhanced easy-to-detect security feature, or in addition or alternatively, as a hidden security feature, for example, in the field of document security. According to an additional object, such an optical effect layer is also suitable for decorative purposes.
[0010] The present invention, remarkable, provides a solution to the above objects by providing an optical effect layer (in the parts that follow abbreviated as "OEL"), a device and a method to produce the same, a security document comprising such an OEL and the use of such an OEL as a security feature, in accordance with the attached claims.
[0011] In a first aspect of the invention, an OEL is provided which comprises a binder material being at least partially transparent to electromagnetic radiation of one or more wavelengths in the range of 200 nm to 2500 nm, that is, within a portion of the electromagnetic spectrum which is commonly referred to as the "optical spectrum". A plurality of non-spherical particles having non-isotropic reflectivity is dispersed within said binder material and the particles are oriented according to a pattern extending along a length along a first direction within an extended surface of the effect layer optical. In a first cross section of the optical effect layer, substantially perpendicular to the extended surface and along the first direction at the local average of an angle between (i) a straight line along a longer dimension observed within the corresponding cross section of these particles non-spherical intersecting with said first cross section, and (ii) said first direction, varies according to a function θ of a position along said first direction, which is the sum of the first function monotonically increasing or decreasing θ-] of said position and a second alternating function θ2 from said position. Explicit safety features based on such an improved and extended OEL are significantly more remarkable, that is, eye-catching, than conventional or related optical "scrollbar" effects, such as those discussed above in connection with Figures 1a and 1b, where either the spatial extent of the attainable effect could be very limited or just a moving effect weak dynamic image could be attainable. As a document security feature is particularly effective if it is easily perceived and / or used, document security and / or protection against counterfeiting or illegal reproduction achievable with such an improved OEL can be significantly increased, since the likelihood that the security feature will actually be (i) recognized as such by a user, (ii) used to verify the authenticity of a document protected in this way or another article and (iii) safely distinguished from an inauthentic, that is, feature of false security, is greatly increased. Due to its nature, the optical effect provided by the present invention cannot be reproduced by mere copying, for example, by commercially available copying machines and, therefore, provides an increased level of security compared to other optical effects. The improved OEL can, for example, be used as an explicit security feature for security documents such as banknotes or passports, or in general, for any item or item such as valuable consumer products or spare parts, etc., where protection matters. In addition or alternatively, the effect can be employed as a hidden security feature, where the optical effect occurs (at least additionally) for wavelengths outside the visible range of the optical spectrum that can only be detected with appropriate authentication equipment, being sensitive to radiation in the respective non-visible portions of the spectrum. Furthermore, the optical effect, due to its dependence on the angle of view and its increased spatial extent, is also very suitable for decorative purposes, including in combination with its use as a safety feature.
[0012] In other words, and more in terms of function 0, the total shape of the function θ is such that it is undulating or fluctuating, with its total tendency either gradually decreasing or gradually increasing as a function of the position. By the total trend gradually decreasing or gradually increasing, it is understood that, when calculated over several fluctuations, the mean of the function θ either gradually increases or gradually decreases in relation to the position. The second alternating function θ2 ensures that the function θ displays a plurality of positions where the derivative of θ with respect to the position is zero, that is, where the function is, in simple language, "flat". Preferably, the function θ forms a plurality of local maximums and minimums (that is, highs and lows) in these "flat" positions, which lead to a standardized visual effect formed by a plurality of dark spots and a plurality of luminous spots. These points move through the optical effect layer in a directional way when the OEL is tilted. In other words, the function θ, varies in such a way that, if the angle of view of the optical effect layer changes, a pattern of light and dark areas on the extended surface of the optical effect layer will appear to move along the first direction. (x).
[0013] In a second aspect of the invention, a device for producing a layer of optical effect when orienting magnetic or magnetizable particles dispersed within a binder material is provided. The device comprises an arrangement of one or more magnets comprising a magnetized magnetic plate.
[0014] The arrangement of one or more magnets is thus configured so as to produce a combined magnetic field comprising (a) a first magnetic field component being substantially similar to a magnetic dipole field and having its North-South direction aligned substantially parallel to the said magnetized magnetic plate; and (b) a second magnetic field component which comprises an overlap of individual local dipole-type magnetic fields and thus corresponds to an alternation of the North and South magnetic poles along a first direction substantially parallel to said North-North direction. South. The first magnetic field component and the second magnetic field component overlap at least in an area adjacent to an extended surface of said magnetized magnetic plate, where the optical effect layer can be produced.
[0015] Therefore, the device is suitable for producing an OEL according to the first aspect in cases where the particles within the binder material are magnetic or magnetizable particles.
[0016] In a third aspect of the invention, a method for producing an optical effect layer is provided. The method comprises exposing a fluid, that is, not yet hardened, binder material comprising a plurality of magnetic or magnetizable non-spherical particles having a non-isotropic reflectivity and being dispersed within said binder material, to the magnetic field of a device according to the second aspect of the present invention in an area adjacent to an extended surface of the magnetized magnetic plate of the device. In this way, the non-spherical magnetic or magnetizable particles within the binder material are oriented. The method additionally comprises the concomitant or subsequent hardening of the binding material in order to fix the magnetic or magnetizable non-spherical particles in their adopted positions and orientations. The binding material is, at least in its hardened state, at least partially transparent to electromagnetic radiation of one or more wavelengths in the range 200 nm to 2500 nm.
[0017] The method, therefore, provides a layer of optical effect according to the first aspect of the invention in cases where the particles within the binder material are magnetic or magnetizable particles.
[0018] In a fourth aspect, a security document comprising an optical effect layer according to the first aspect is provided.
[0019] In a fifth aspect, a use of an optical effect layer according to the first aspect of the present invention as a security feature or security element in document security applications is provided.
[0020] Various preferred embodiments and variants of the invention, according to the above aspects, are provided in the dependent claims. Brief description of the figures
[0021] The invention is described below in detail and with reference to the figures, in which: Figure 1 schematically illustrates two layers of optical OEL effect known as the "scroll bar effect" of the state of the art and the way in which they can be obtained: a) using a long magnetic dipole, and b) using a short magnetic dipole; Figure 2 schematically illustrates an optical effect coating (OEC) comprising two separate optical effect layer (OEL) components arranged on a substrate layer; 3a schematically illustrates an OEL having a flat surface and a cross section perpendicular to it and along a first direction within an extended OEL surface; Figure 3b schematically illustrates an OEL having a curved surface and a cross section perpendicular to it and the along a first direction within an extended OEL surface; Figure 4 illustrates the variation of the elevation angle of the plaque-shaped pigment particles with respect to the substrate plane in a cross section along the indicated line (R1-R2) of an exemplary OEL comprising said particles, on a substrate according to a modality of the present invention; Figure 5 illustrates the angle of elevation of the particles of platelet-shaped pigment in relation to the substrate plane, as seen in the three cross-sections WITHOUT coplanar taken at three points indicated A, B and C along the indicated line (R1-R2) in Figure 4; Figure 6 schematically illustrates the variation of the particle angle θ (in this document also referred to as "elevation angle") with respect to a first x direction within the surface of an OEL, along which the image appears to move, as a function θ of a position at along a length along the x-direction, for example, the indicated line (R1-R1) of Figure 5, as well as a corresponding first exemplary function θ1t according to an embodiment of the present invention; Figure 7 shows an OEL according to an example of the present invention, as seen from angled angles of view (aac, fah) and from almost orthogonal (dee) angles of view; Figure 8 schematically illustrates the structure of a device for producing an OEL , according to an exemplary embodiment of a first major set of embodiments of the present invention; Figure 9 schematically illustrates several exemplary magnetization patterns of a two-dimensional multipolar magnetization of a magnetic plate of the device of the present invention; Figure 10 schematically illustrates the structure of a device for producing an OEL, according to another exemplary embodiment of the first main set of modalities of the present invention; Figure 11 schematically illustrates magnetization patterns useful for incorporating the multipolar magnetization of one or more magnetic plates) of a device according to some modalities of the present invention. Figure 12 illustrates schematically the structure of a device for producing an OEL, according to yet another exemplary embodiment of a first main set of embodiments of the present invention; Figure 13 schematically illustrates the exemplary structure of a device for producing an OEL, according to a second main set of exemplary embodiments of the present invention; Figure 14 schematically illustrates a longitudinal cross-section through the magnetic plate of the device of Figure 13; Figure 15 shows the corresponding calculated magnetic field generated by the device of Figure 13.Figures 16 to 18 schematically illustrate several exemplary electromagnets, that can be used as part of the magnet arrangements of devices to produce an OEL, in accordance with various embodiments of the present invention; Figure 19 depicts a photo of an optical effect coating achieved by additionally using a permanent magnetic backing plate engraved in the orientation of particles within an OEL, in accordance with the modalities of the present invention; Figure 20 schematically illustrates an exemplary magnet arrangement specific to incorporate the present invention according to another exemplary embodiment of a first main set of modalities; Figure 21 shows the calculated magnetic field lines of the magnet arrangement of Figure 20. The magnetic pole designations are omitted here; Figure 22 illustrates schematically the orientation of platelet-shaped pigment particles (pigment flake) along the lines of the magnetic field from the magnetic arrangement of Figure 20 at the location of the backing plate (SP) (Figure 22b)), and the corresponding reflection of entry light into platelet-shaped pigment particles (Figure 22a)). Detailed description of the invention I. Optical effect layer (OEL)
[0022] An optical effect layer ("OEL") according to the present invention comprises a binder material and a plurality of non-randomly oriented non-spherical particles having a non-isotropic reflectivity and being dispersed within the binder material.
[0023] Throughout this description, the term "orientation" refers to the general relationship between the coordinate system of the oriented particle and the coordinate system of the optical effect layer. In the case of orthonormal coordinate systems, three angle values (rotations around particle axes z, y and x) are generally required to define the orientation of a particle.
[0024] In the following parts, the term "elevation angle" of a particle will refer, in a vertical cross-section through the effect layer along an x direction in the plane of the effect layer, to the easily observable angle between : (i) a straight line along a longer dimension observed within the corresponding cross-sectional shape of a cross particle, and (ii) said x direction.
[0025] The binding material is, at least in its hardened state (see the next paragraph), at least partially transparent to the electromagnetic radiation of one or more wavelengths in the range of 200 nm to 2500 nm, that is, within a range of wavelength which is commonly referred to as the "optical spectrum" and which comprises infrared, visible and UV portions of the electromagnetic spectrum. In particular, the binder material can be at least partially transparent in the visible spectrum range between 400 nm and 700 nm. In this way, incident electromagnetic radiation, for example, visible light, entering the OEL through its surface can reach the scattered particles within the OEL and be reflected there, and the reflected light can leave the OEL again to produce the desired optical effect. If the wavelengths are selected outside the visible range, for example, in the range close to UV, then the OEL can also serve as a hidden safety feature as then technical means will normally need to detect the (complete) optical effect generated by the OEL under respective lighting conditions comprising the selected non-visible wavelengths. The infrared, visible and UV portions of the electromagnetic spectrum correspond approximately to the wavelength ranges between 700 to 2500 nm, 400 to 700 nm and 200 to 400 nm, respectively.
[0026] Furthermore, the binder material has a first fluid state in which the particles dispersed in it are essentially free to rotate, said first fluid state can be converted into a second, hardened state, in which the particles are fixed in their positions and guidelines adopted and can no longer rotate. For example, the binder material can be a coating composition, more particularly an ink composition, such as those that are used in security applications, for example, printing banknotes. When the fluid binder material is hardened, for example, when drying or curing by irradiation with suitable light (for example, UV-VIS-light), said binder material becomes the second, hardened state where the particles are fixed in their positions current orientation and orientation and can no longer move or rotate within the binding material.
[0027] Figure 2 schematically illustrates a cross-section of an exemplary embodiment of OEL 202 having non-spherical non-reflective particles 300 dispersed therein, according to some embodiments of the present invention. OEL 202 comprises two separate layer portions 203 and 204 arranged on a substrate layer 205. Portions 203 and 204 may or may not be connected together in the third dimension perpendicular to the cross section, and form an optical effect coating ("OEC ") comprising the substrate and the OEL itself. OEL 202 can be arranged on substrate 205, at least temporarily. This is particularly useful in applications where the OEL corresponds to an ink, for example, a security ink, or some other coating material and is permanently placed on a substrate such as a banknote, passport or other document of value, for example, printing medium. However, the substrate can also, instead of being temporarily bonded to the OEL, for example, to facilitate the production of the OEL, particularly while the binder material is still in its fluid state. Thereafter the substrate can be removed from the OEL. Alternatively, the substrate can comprise an adhesive layer and, thus, the OEC comprising the OEL and the adhesive layer can be attached to all types of documents or other articles or items without printing or other processes involving machinery and very high effort. In particular, in some embodiments, the OEC is in the form of a transfer slide, which can be attached to a document or article in a separate transfer step. In such a case, the substrate carries a release liner, over which an OEC is laid out as previously described. An adhesive layer may additionally be present on the optical effect coatings.
[0028] The OEL described in this document is preferably a coating cured by radiation in the visible and / or UV ranges of the spectrum, more preferably in the wavelength range from 380 nm to 420 nm, where LED-based UV curing equipment is or it could be available.
[0029] The substrate 205 can be selected from the group consisting of non-woven materials, fabric materials, metals and plastic polymer materials and combinations thereof. Preferred non-woven materials are paper, cardboard and synthetic woven olefin fiber (spunbond), such as Tyvek®. Preferred woven materials are printable textiles. Preferred plastic polymer materials are polyethylene (PE), polypropylene (PP), in particular biaxially oriented PP, and polyethylene terephthalate (PET). Metals include without limitation those used for the preparation of metal coins and those used for the preparation of metallized plastic polymer materials, such as metallized safety wires. Particularly preferred substrates are banknote papers and polymer banknote substrates, as well as hybrid substrates including layers or parts or fibers of paper and polymer. Substrate 205 may additionally be selected from transparent materials and opaque materials, and may, moreover, carry printed, coated or laser-marked or laser-punched evidence. Additionally, substrate 205 may additionally carry additional coatings or layers (not shown), on top or below the OEL or on its face opposite to the OEL. In particular, the substrate can carry a first layer under the OEL of the present invention, which serves, for example, to enhance the quality of the magnetically transferred pigment orientation image, to promote adhesion, etc. The substrate can additionally carry a protective coating along the OEL, which serves, for example, to increase its wear and resistance to the soil, to modify its optical brightness, etc.
[0030] The substrate, OEL and / or any layers of additional coatings described above may also additionally comprise one or more marker substances, preferably selected from the group consisting of luminescent UV / visible / IR substances, absorbent substances of UV / visible / IR and magnetic substances and combinations thereof. Said substances can also additionally serve as security features allowing automatic authentication, for example, of a security document, by an authentication apparatus, such as a high-speed banknote processing machine.
[0031] Each of the plurality of non-spherical particles dispersed within the binder material has a non-isotropic reflectivity with respect to incident electromagnetic radiation by which the binder material is at least partially transparent, at least in its hardened state. Here, the term "non-isotropic reflectivity" refers to the variant fraction of incident radiation reflected by a particle in a direction of view as a function of particle orientation. Thus, if the binder material containing the oriented reflection particles, that is, the OEL, is inclined with respect to the direction of view under given lighting conditions, the reflected radiation fraction of each of the particles can change for each particle individually . In general, the particles in the binder material can be pigment particles, for example, pigment particles within a coating material, such as an ink.
[0032] The particles have a non-spherical shape and can, for example, be particles of prolate or oblate ellipsoid shape, platelet shape or needle shape or mixtures thereof. Thus, even if the intrinsic reflectivity per unit surface area (for example, per μm2) is uniform across the entire surface of such a particle, due to its non-spherical shape, the reflectivity is non-isotropic depending on the visible area of the particle. the direction from which it is viewed.
[0033] In some embodiments, the particles may comprise a magnetic or magnetizable material, which allows an external magnetic field to be used to orient the particles within the OEL binder material according to a desired orientation pattern. In this way, a permanent magnetic particle is oriented in such a way that its magnetic axis is aligned with the direction of the external magnetic field line at the location of the particle. A magnetizable particle without an intrinsic permanent magnetic field is oriented by the external magnetic field in such a way that the direction of its longest dimension (in the following parts also referred to as particle length or size) is aligned with a magnetic field line at the location of the particle.
[0034] To be oriented along the magnetic field lines, the magnetic or magnetizable particles must have a non-spherical shape, for example, a prolate or oblate shape. Magnetic or magnetizable particles can be of any type of magnetic pigment, preferably platelets (flakes) or needles or mixtures of these. Examples of useful magnetic particles include, without limitation, particles in the shape of platelets (for example, flakes) or in the shape of a needle comprising a ferromagnetic or ferrimagnetic material, such as cobalt, iron or nickel, or a magnetic alloy of manganese, cobalt, iron or nickel, or a chromium, manganese, cobalt oxide, pure or mixed magnetic iron or nickel or a mixture thereof. Examples of magnetic oxides include, without limitation, pure and mixed iron oxides, such as hematite (Fe2O3), acicular magnetite (Fe3O4), magnetic ferrites (MFe2O4), magnetic orthoferrites (RFeO3), magnetic hexaferrites (MFe12O19), magnetic grenades (R3Fe5O12) etc., M being a bivalent metal ion and R being a trivalent ion of the group comprising yttrium and rare earths; cobalt oxide (Co3O4) and chromium dioxide (CrO2).
[0035] Most of the preferred suitable magnetic or magnetizable particles are optically variable magnetic particles. The particles can be particularly optically variable pigment flakes. In some preferred particle embodiments, they may additionally comprise a color-generating thin film Fabry-Perot interference stack comprising a five-layer absorber / dielectric / magnetic / dielectric / absorber sequence, or a seven-layer absorber sequence / dielectric / reflective / magnetic / reflective / dielectric / absorbent, as disclosed in US 4,838,648, EP 686,675 B1, WO 02/732250 A2 or in WO 03/008001 A2. Compositions of paints and corresponding coatings were disclosed in WO 2007/131833 A1. The color of the optically noticeable variable magnetic particles depends on the angle of view with respect to the plane of the pigment flake, which results in a different color margin appearing around the luminous zones of the optical effect layer (OEL). For example, in the case of optically variable pigment flakes from green to blue, which appear green under orthogonal view and blue under refraction view, the luminous zones of the OEL appear green with a blue border on a dark background. The use of optically variable magnetic pigment in the OEL of the present invention thus intensifies the contrast of the luminous zones and improves the visual impact of the OEL on document security and decorative applications. Using optically variable magnetic particles also adds an additional layer of security to the OEL, as this type of material is reserved for the security printing industry and is not commercially available to the public. For visible radiation, the presence of both evident movement of zones and the change of color with a change in the angle of view is easily verified with the naked eye.
[0036] The particles dispersed within the binder material are oriented according to a pattern extending along a length along a first direction (x) within an extended surface of the OEL, for example, in the example of Figure 2 this extended surface could be the top surface of OEL 202.
[0037] The orientation of the non-spherical particles within the OEL can be defined as illustrated in Figure 3a and Figure 3b.
[0038] Figure 3a, in general, shows an OEL 300 with exemplary particles 302 to 305 representing a plurality of particles dispersed within the OEL 300. In general, the non-spherical particles are dispersed throughout the entire volume of the OEL, while for the purpose of discussing your orientations within the OEL, the exemplary particles 302 to 305 are all located within the same cross section plane 308 (first) of the OEL, defined by a virtual plane 301, as described in more detail below. Since exemplary particles 302 to 305 are located within the plane 301, they intersect with the plane 301, respectively the cross section 308 (first), which thus defines a cross section for each of the particles 302 to 305 that are graphically depicted, each by a short line representing its longest diameter appearing within its cross-sectional shape. In an exemplary way, only for non-spherical particle 303, the cross-sectional shape of the particle is also depicted as an ellipse, the longest diameter of which corresponds to the short line representing particle 303. The total number of non-spherical reflective particles in the OEL can be appropriately chosen according to the desired application; however, in order to create a surface coverage pattern generating a visible effect, several thousand particles per square millimeter of OEL surface are, in general, required. The plurality of non-spherical particles, which together produce the optical effect, can correspond to all or just a subset of the total number of particles dispersed within the binder material. For example, the particles producing the optical effect can be combined into the binder material, which can be pigment particles of conventional or special color.
[0039] OEL as a physical object has, in general, three dimensions Dim1, Dim2 and Dim3, and its extension along at least one dimension, for example, as illustrated in Figure 3a its thickness along Dim2, is normally much smaller than its extension over other dimension (s), for example, the dimensions Dim1 and Dim3 in Figure 3a. Therefore, the extent of OEL across at least one of the dimensions, for example, along Dim1, can be dominant. For practical purposes, that is, to create an optical effect extending over a significant length, someone will generally select one or one of the larger surface portions, for example, faces, of the OEL to show the desired optical effect. Preferably a portion of the surface or face of the OEL is selected, which is covered in two of the dimensions of the OEL along which it shows its greatest extent. Thus, in the example in Figure 3a, the dimensions Dim1 and Dim3 encompass such surface 306 of the OEL 300. This portion or face of the selected surface can be designated as an extended surface 306 of the OEL 300, or equivalent of the binder material, and a first x direction within this extended surface 306 can be selected, along which an angle-dependent image appears to move at least along this first x direction and along a length 307 is produced, when the angle of view in relation to the first direction changes. The length can be the same or less than the length of the OEL along the first direction. The angle of view changes, for example, when the extended surface 306 of the OEL 300 is tilted with respect to the line of sight between the viewer's eyes and the OEL 300 such that the angle (view) between the first direction 306 and the line of sight varies. This effect is produced by the plurality of particles dispersed within the OEL, as will be explained in detail below. Preferably, the length 307 along the first x direction is at least 20 mm in order to provide an evident strikingly enhanced movement of an image when the angle of view is modified.
[0040] The particles have a non-random orientation within the OEL 300 that forms an orientation pattern extending along the length 307 along at least the first x direction within the extended surface 306 of the OEL 300. To express the orientation of the a cross-sectional plane 301 is defined, whose plane is covered by the first x direction within the extended surface and a perpendicular NM to the extended surface of the layer. In the example in Figure 3a, this NM perpendicular is along the Dim2 dimension of the OEL. The plane 301 thus defines a cross section 308 through the OEL. In Figure 3a, the exemplary particles 302 to 205 are each located within this cross section 308 and the short lines representing the particles depict their respective longest diameter within their cross section shape within the plane 301 defining the cross section 308 .
[0041] Figure 3b illustrates another exemplary OEL 310 with particles 312 dispersed in it, which has a curved extended surface 313, particularly cylindrical, extending over a first dimension Dim1 and a third dimension Dim3. Also in this example, a plane is defined and covered by a first x direction within the extended surface 313 and a perpendicular NM to the extended surface, for example, parallel to the second dimension Dim2. In the examples of Figures 3a and 3b the first direction along the first dimension Dim1, and the respective perpendicular NM is along the second dimension Dim2. The plane thus defines a cross section 311 through the curved OEL in which exemplary particles 312 are located.
[0042] The orientation of a particle can then be described by the easily measurable elevation angle θ between the first x direction and a line along the longest dimension of the particle's cross-sectional shape within the 301 plane. For each particle a position P can be defined as a coordinate along the first direction of a point on the particle's cross-sectional shape. In particular, the coordinate can correspond to a perpendicular projection of the point on the particle on said first direction. For example, the point on the particle's cross-sectional shape can be taken as the center of gravity of the particle's cross-sectional shape or as the center point of its longest dimension within the cross-sectional shape or as the point within the cross-sectional shape having the smallest (or largest) coordinate value along said first direction of any particle point in the cross-sectional shape. The latter case is illustrated in Figure 3a, where the respective leftmost point of the particle cross-section formats 302 and 305 is selected to define the position P as a corresponding coordinate along the first direction.
[0043] The mean value of the elevation angle θ (defined as described above) of the particles within the plurality of particles, whose position P (as defined above) covers an interval centered on a position P along the first direction, defines a function θ (P) from position P at least along a length along the first direction, for example, in Figure 3a along length 407. This mean angle is also referred to as "local mean elevation angle θ" or " local angle mean "and is thus taken as an average of the respective elevation angles over a local population of particles located in the perpendicular cross section (first) through the OEL. Thus, said local mean of the angles is performed only along these particles, which cross the cross section (for example, cross section 308 or 311 in Figure 2) within a delimited range [P-δ; P + δ] of length 2δ and assigned as the local mean angle to position P along the cross section. Said length 2δ is normally in the range of 50 to 1000 micrometers. The angle to be calculated is the angle between a straight line along a longer dimension observed within the corresponding cross section of a cross spherical particle and the first x direction in position P.
[0044] According to the present invention, the local average elevation angle of the particles within the plurality of non-spherical particles dispersed within the binding material satisfies a corresponding function θ (P), which is a function equal to the sum of a first function θi (P) and a second function θ2 (P). The first function θi (P) a first monotonically increasing or decreasing function of said position P and the second function 02 (P) is a second alternating function of said position P. In this document, an alternating function will mean any function that oscillates between positive values and negatives around an average value of zero.
[0045] Figure 4 illustrates a top view in an exemplary OEL and the corresponding orientation pattern of particles in it, according to an embodiment of the invention. The OEL image is produced through the reflection of incident light in an orthogonal manner by the non-spherical particles. In this example, the particles are in the form of particles in the form of flat platelets having a thickness much less than their extension in the other two dimensions. The first direction within the visible extended surface of the OEL is indicated as the line between points R1 and R2 and the variation of the average particle orientation with respect to the first direction is shown above the line (for illustration purposes the schematically illustrated particles are shown by a 90 degree rotation around the axis defined by the line between RT and R2) and copied again (for the sake of better visibility) below the image. The particle orientation is shown, therefore, in the form of a perpendicular cross-section of the flakes along the line R1 and R2, as obtained from electromicrographs of the polished ditch of vertical cuts along said line, similar to the micrographs in Figure 6. As the particles are platelet-shaped particles, their cross-sectional shape roughly corresponds to a thin line. Based on their shape, particles have their maximum reflectivity (maximum projection area) in a direction perpendicular to their extended surface, and therefore, in an orthogonal view, in the OEL image, the luminous areas correspond to particles whose orientation roughly matches that of the surface, that is, that it has a low angle θ with respect to the surface of the OEL in such a way that the incident light is substantially reflected back in the same direction (orthogonal). Dark areas of the OEL image, on the other hand, correspond to particles whose orientation is significantly tilted with respect to the extended surface of the OEL, such that they reflect the light falling on them away from the orthogonal direction. It should be noted that although the image in Figure 4 shows only the reflection image for incident light in an orthogonal shape and a 90 degree angle of view in relation to the image. Figure 4 does not show and cannot show the angle of view dependency of an OEL image and, therefore, the desired effect of a moving image, which can only be achieved by a real OEL according to the present invention and does not by a mere photo of her taken from a unique angle of view.
[0046] Figure 5 shows three electromicrographs of cross-sections of the OEL of Figure 4 that cut perpendicular to its extended surface (top). In this example, the OEL is arranged on a substrate and thus forms an OEC. The micrographs were obtained at locations A, B and C, respectively, which are identified in Figure 4 along the first direction, that is, along the indicated line (Ri and R2), and each shows the substrate (at the bottom ) covered by the OEL comprising 500 oriented platelet-shaped particles. The average orientation of the particles located along the first x direction within respective intervals [P-δ, P + δ] at positions P are shown reported for such locations A, B and C in Figure 4, as can be seen by comparison with the corresponding micrographs A, B and C in Figure 5.
[0047] Figure 6 depicts graphically the local average elevation angle θ (P) of the pigment particles ("Flake orientation") distributed within respective intervals [P-δ; P + δ] along the first x direction, that is, the orientation of the pigment flakes with respect to the OEL surface plane along the first x direction, that is, along the line (R1 and R2) of Figure 4 and Figure 5 as a function of their respective P positions on said line (see bold waveform curve). The area around the curve of θ (P) illustrates schematically (not to scale) a standard deviation o of the distribution of the angle of elevation of the flake 0 (P) of the particle (flakes) within the range [P- δ; P + δ], The flakes or particles are, notably, never perfectly aligned, and their orientation, thus, also their elevation angle, fluctuates around an average value according to a standard deviation.
[0048] The exemplary dashed line in Figure 6 corresponds to an average elevation angle of 10 °. All particles in these P positions, where the dashed line crosses the θ (P) waveform function, reflect electromagnetic radiation incident in the same direction, that is, along the same line of sight in the OEL at a corresponding angle of view. Therefore, if the OEL is viewed at an angle of view to its surface (in Figure 4 both the incident light direction and the line of sight are substantially vertical to the extended OEL portrayed surface), where these flakes having an angle of elevation around 10 ° inside the OEL are oriented in such a way that the incident electromagnetic radiation falling on its surface is reflected along a line of light towards the viewer, the OEL at the P position of these particles appears luminous (for example , at location B in Figure 4). On the other hand, these areas of the OEL, whose mean particle orientations differ substantially by 10 °, such that the particles will show much less reflectivity with respect to the direction of incident radiation and the line of sight, will appear darker (for example , in locations A and C in Figure 4). If the viewing angle changes, for example, when the OEL and its first direction are tilted in relation to the line of sight, then in Figure 6 this is equivalent to moving the dashed line from top to bottom respectively towards a larger one, respectively, at a lower local average elevation angle 0. Therefore, the intersections between the dashed line and the 0 (P) curve will also move to a different location P along the first direction and as a consequence, the pattern light and dark areas on the extended surface of the OEL will also appear to move along the first x direction. Particularly, when the dashed line reaches a point where it intersects with a local maximum or a local minimum of 0 (P) and the OEL is additionally sloped, then the luminous area corresponding to the local maximum or minimum disappears. Similarly, a new luminous area is produced when, when tilting the OEL, the moving dashed line approaches a local maximum from the top, respectively, a local minimum from the bottom and thus establishes a new intersection in a position P where previously there was no intersection.
[0049] An additional curve shown (straight) in Figure 6 represents an exemplary modality of a first function θ-i (P) that monotonously decreases along the length (that is, the position range from 0 to 25 nm in this example) from a maximum value 01rnax around 35 ° to a minimum value 01imjn around -35 ° and thus covers a range of values other than zero, in this example 70 °. Preferably the difference between the maximum value θi max and ° minimum value θ1min is at least 30 °, that is, the values of said first function of monotonically increasing or decreasing θ ^ P) cover a difference of at least 30 degrees along said length. Other selections of the first function, which may or may not be linear along the first direction are also possible.
[0050] The second function θ2 (P) (not shown in Figure 6) is then equal to the difference in functions θ2 (P) = θ (P) - θi (P). It is an alternate function, that is, it oscillates between positive and negative values around an average value of zero. Preferably, its amplitude is half or less than the range covered by the values of the first function θ-i (P). In this way, the second function θ2 (P) can be interpreted with a modulation of the first function θi (P). Therefore, the first function can be considered a main component and the second function an auxiliary component of the function θ (P) = θi (P) + θ2 (P).
[0051] The main component θi (P), substantially determines the local average elevation angle of the particles along the length along the first direction, while the alternating auxiliary component causes a modulation of the local average particle elevation angle determined by the component main. Again with reference to Figures 4 and 5, the particles in region A point their face up-left, particles in region B point their face up, and particles in region C point their face up-right. The main component can be monotonously increasing or decreasing along the length along the first direction. In particular, the main component can be a linear function θ ^ P) = aP + b, corresponding to the linear gradient of a magnetic field line of parabolic shape of a magnetic dipole (DM) as in Figure 1. The main component can also follow a more sophisticated function of the P position along the length along the first x direction, for example, on the line (R1-R2) in the examples above.
[0052] The alternate function serving as the auxiliary component can either be a periodic function θ2 (P + K) = θ2 (P) of period K, such as a sine function, or even a more general, non-periodic function. Particularly, in some modalities the second function has a large enough amplitude to make the sum θ (P) of the first function θ-i (P) and the second function θ2 (p) is a non-monotonous function, whose first derived modifications sign at least twice along the length along the first direction. Preferably, the amplitude of the auxiliary component, that is, the modulation of the local average particle elevation angle, causing the positive or negative excursion of said average particle elevation angle, is in the range of 5 ° to 30 °, more preferably in the range of 10 ° to 20 °, corresponding to a range of values for the first component at least twice as high. Thus, the length of a "stroke" in Figure 5 between a minimum and a subsequent maximum of θ (or vice versa) then corresponds approximately to twice the modulation, that is, preferably from 10 ° to 60 °, more preferably 20 ° to 40 °, which is less than the range of values from -35 ° to + 35 °, that is, a total of 70 °, covered by the main component. In this way, the main component can dominate despite a variation of the auxiliary component. In general, the predominance (in terms of amplitude) of the main component over the auxiliary component is desirable to achieve that the desired optical effect provides an image that seems to move in a striking way along the length as the angle of view varies.
[0053] In some embodiments, the orientation pattern also extends along a second y direction within the extended surface of the OEL respectively to the binding material, the second y direction being different from the first x direction. Then, in a second cross section of said OEL substantially perpendicular to said extended surface and along the second y direction, the local mean angle between (i) a straight line along a longer dimension observed within the corresponding cross section shape of those non-spherical particles that intersect with said second cross-section, and (ii) said second direction y varies according to a third function (θ3) of a position along said second direction y. In this way, the third function is similarly defined as the first and second functions 0! and θ2, however, along the different y direction. Particularly, in some embodiments of these third function 03, it can be an alternate function of said position along said second y direction.
[0054] In additional modalities, said local average angle along the second y direction can vary according to a fourth function 04 of a position along said second y direction. This fourth function 04 is the sum of a function being equal to said first function Of said position, but along said second direction y (and not as the first function itself along the x direction) and a fifth alternating function 05 of said position along said second y direction. In this way, the image produced by the non-spherical particles oriented on the extended surface of the optical effect of OEL shows a structure not only along the first direction, but at least along the second y direction as well.
[0055] In a particular embodiment, function 0 (P) shows substantially rotational symmetry with respect to rotations of the first direction within said extended surface of the binder material and around a particular point on the surface extended by an angle of rotation , at least for selected rotation angles. In other words, if the first direction is rotated within the extended surface of the OEL by an angle of rotation of the OEL by an angle of rotation for which such rotating symmetry occurs then the function θ (P) is unchanged by this rotation. Consequently, the optical effect defined by the function θ (P) also remains unchanged under such rotation.
[0056] For example, in some modalities both the first function θi (P) and the second function θ2 (x) are constant with respect to the rotations of the first direction within the extended surface of the OEL, then also the sum function θ (P ) shows this constancy. Therefore, the thus obtained OEL has no preferred direction, but instead shows the same optical effect along any direction for a given angle of view and direction of incident radiation in relation to the extended surface of the OEL.
[0057] In yet another particularly preferred modality, only one of the main and auxiliary components show such rotational symmetry with respect to the rotations of the first direction, at least for selected angles of rotation.
[0058] In a particular OEL modality, a small slice of image elements, orthogonal to the said first direction, is used to incorporate a security element. Said image elements have the property of "appearing" and "disappearing" depending on the angle of view as described above, and can be used to incorporate a "latent image" on a document, that is, an image that is only visible under certain angles of view, and that is therefore difficult to copy.
[0059] In an additionally particular mode of OEL, a slice or slices of orthogonal image elements in said first direction is either absent or hidden, resulting in an "on-off" appearance of these image elements that are present, instead of in a dynamic motion appearance, of image elements of the OEC optical effect coating with angle of view modification. This can usually be achieved with a discontinuous OEC created from several elements of OEL.
[0060] Figure 7 illustrates an exemplary embodiment of an image of an OEL according to the present invention at eight different inclination angles along said first direction. A large border denotes the side of the image, which is close to the observer; a small border denotes the side of the image that is far from the viewer. In other words, the observer's position for Figure 7a is on the top side of the OEL, while it is on the bottom side for Figure 7h. The corresponding tilt angles, that is, angles of view in relation to the OEL surface, are as follows: Figure 7a: -60 °; Figure 7b: - 45 °; Figure 7c: -30 °; Figure 7d: -15 °; Figure 7e: + 15 °; Figure 7f: + 30 °; Figure 7g: + 45 °; Figure 7h: + 60 °. The impressive progression or evident regression that is incapable of copying from perceived light and dark image elements is immediately evident to the naked eye when leaning towards OEL.
[0061] Finally, in some modalities the OEL may comprise, in addition to said plurality of non-spherical particles, at least one among: magnetic particles that do not change color, colorless magnetic particles, non-magnetic particles that change color, non-magnetic particles that do not change color and colorless non-magnetic particles. In this way, additional properties of the OEL, for example, its color and / or color change with angle of view can be checked or changed in addition to the dynamic optical effect described above. In particular, such additional particles can be pigment particles. II. Guidance device
[0062] The present invention also discloses a device for orienting magnetic or magnetizable particles within a binder material. In this way, the device can be used to produce an OEL as described above, in cases where the particles are magnetic or magnetizable particles.
[0063] The device comprises an arrangement of one or more magnets comprising a magnetized magnetic plate and being thus configured to produce a combined magnetic field. The combined magnetic field comprises a first magnetic field component and a second magnetic field component. The first magnetic field component is substantially similar to a magnetic dipole field and has its North-South direction aligned substantially parallel to said magnetized magnetic plate. The second magnetic field component comprises an overlap of individual local dipole-type magnetic fields and thus corresponds to an alternation of North and South magnetic poles along a first direction substantially parallel to said North-South direction. The first magnetic field component and the second magnetic field component overlap at least in a region adjacent to an extended surface of said magnetized magnetic plate, that is, in a region close to the surface of the magnetized magnetic plate which the plate forms a limit. This region defines an orientation region in which the OEL must be placed to orient magnetic or magnetizable non-spherical particles having a non-isotropic reflectivity dispersed in it. In this orientation region, the magnetic field field lines of the magnet array have a desired shape according to the desired particle orientation specified above in this document.
[0064] Depending on whether the magnetic or magnetizable particles within the binder material, when it is in a fluid state and the particles are rotating in it, align themselves along the field lines as described above in this document, the respective orientation reached from the particles (that is, their magnetic axis in the case of magnetic particles or their largest diameter in the case of magnetizable particles) coincides, at least on average, with the local direction of the magnetic field lines at the positions of the particles. Thus, the device is suitable for producing an OEL according to the first aspect of the present invention.
[0065] In a first set of main modalities described below in this document, the magnet arrangement of one or more magnets comprises one or more magnets (in the parts that follow "first magnet (s) / magnets) configured to produce the first component of magnetic field and an MP magnetized magnetic plate configured to produce the second magnetic field component, so in the first set of main modes, the two magnetic field components are generated separately, that is, by separate magnets.
[0066] In some of the modalities, the first magnets comprise a DM magnetic dipole that is configured in such a way that its magnetic axis, defined by the line connecting its North and South magnetic poles, is aligned substantially parallel to the first direction or its tangent. Figures 1a and 1b show examples of such a configuration, where the magnetic dipole DM shown represents the first magnet. Note that in Figures 1a and 1b, which refer to the state of the art, the magnetic plate generating the second magnetic field component is absent.
[0067] Additionally, at least one of the first magnets can be mounted so as to be rotatable in a plane substantially parallel to the plane of said magnetized magnetic plate MP. In this way, an effective magnetic field component corresponding to the first function can be generated to show, at least to some approximate degree, a rotational symmetry. In addition to the fact that the magnetic plate can be rotatable, for example, in combination with the first magnets around the same axis, such that an effective magnetic field can be generated by rotating the magnet arrangement, which is rotationally symmetrical at least to the over a range of angles of rotation thereby causing the corresponding rotational symmetry within the OEL, whose magnetic or magnetizable non-spherical particles are thus oriented during the rotation of the magnet array.
[0068] Particularly, if the rotation is around a complete revolution of 360 degrees or more, a magnetic field calculated in a circular form is produced by the production of an OEL that has no preferential direction, but shows the optical effect of the invention to the along any direction, under an arbitrary tilt axis in the OEL plane.
[0069] The magnetized magnetic plate MP may have a first and a second opposite extended surface, where the first surface is located closer to the orientation region than the second extended surface, and a multipolar magnetization at least throughout its first surface. In particular, this multipolar magnetization of the magnetic plate MP can be a two-dimensional alternating multipolar magnetization.
[0070] By comparison with the above description of the OEL it is recognized that the one or more first magnets are responsible for orienting the magnetic or magnetizable particles within the OEL according to the main component 0-, of the orientation function 0. The magnetic plate magnetized MP is responsible for orienting the magnetic or magnetizable particles within the OEL according to the auxiliary component θ2 of the orientation function. Therefore, the first magnets are responsible for generating the basic effect of a moving image dependent on angle of view, while the magnetized magnetic plate MP is responsible for generating modulations of the main component, which are in addition necessary to achieve the improved optical effect provided by the present invention.
[0071] An exemplary modality of a device according to the first set of main modalities is now explained with reference to Figure 8. In this example a magnetic plate MP has a multipolar magnetization of alternating north and south poles over at least its entire surface . A magnetic dipole DM is disposed below the bottom surface of said magnetic plate MP, its north-south direction D1 being substantially parallel to the plane of said magnetic plate MP. A support means in the form of a support plate SP can be provided on top of the magnetic plate, preferably substantially parallel to it. Furthermore, the top surface of the backing plate can be located at a distance d from the magnetic plate MP, depending on the shape of the magnetic field lines, such that the desired shape of the field lines occurs in the above orientation region the top surface of the support means. This distance d is normally in the range of 0.1 to 5 millimeters. In a preferred embodiment, the thickness of the support plate SP equals this distance d, which allows a mechanically solid assembly of the device, without intermediate voids. The support plate SP can be made of a non-magnetic or magnetic material.
[0072] When a layer of the non-hardened binder material containing the non-spherical magnetic or magnetizable particles dispersed in it is placed on the backing plate above the magnet arrangement, the magnetic or magnetizable particles within the (fluid) layer are oriented towards each other. align with the field lines of the combined magnetic field of the DM magnetic dipole and the MP magnetic plate at the locations of the particles.
[0073] Said multipolar magnetization of said magnetic plate MP being any alternation between the north and south poles, like a regular linear band pattern in a given D1 direction, a pattern of irregular linear bands (Figure 9a) or a pattern of curved bands (Figure 9b) or a pattern of bands of arbitrary shapes. The alternating multipolar magnetization of the MP magnetic plate can, moreover, be a circular pattern (Figure 9c), an elliptical pattern or more generally any closed circuit pattern.
[0074] The multipolar magnetization may additionally be present only on a single surface (for example, the upper one) of the MP magnetic plate, or it can cross the entire thickness of the plate, appearing with equal force on both opposite extended surfaces (for example top and bottom) of the plate.
[0075] The north-south direction D1 of the DM magnetic dipole can be chosen according to the design requirements and, notably, defines the first x direction, along which the produced OEL exhibits the evident movement of perceived image elements with modification of the angle of view, for example, when tilting it around an orthogonal axis in said first x direction.
[0076] An exemplary alternating modality of the device is explained with reference to Figure 10. The magnetic plate MP, in this document, has a two-dimensional multipolar magnetization, which can be any alternation of surface coverage of north and south magnetic poles, such as a square pattern (Figure 11a), a rectangular pattern, a triangular pattern (Figure 11b), a pattern derived from hexagonal symmetry (Figure 11c) or any arbitrary pattern of regular or irregular surface tile with alternating N / S magnetic poles. On the other hand, this modality is similar to that of Figure 9.
[0077] Yet another exemplary alternate embodiment of the device is explained with reference to Figure 12. The magnetic plate MP, in this document, is incorporated as a combination of first and second overlapping magnetic plates MP1, respectively MP2, in which the first magnetic plate MP1 has a one-dimensional multipolar magnetization with alternating magnetic polarity along a first direction D2, which can be equal to the D1 direction of the definitive magnetic axis between the North and South pole effective of the first magnets (for example, of the DM magnetic dipole) in the plane of said first magnetic plate, and said second magnetic plate MP2 has a one-dimensional multipolar magnetization with alternating magnetic polarity along a second direction D3 in the plane of said second magnetic plate, and said first and second plates are arranged substantially parallel to each other.
[0078] The alpha rotation angle α between the alternating magnetic polarity D2 direction of said first MP1 plate and the alternating magnetic polarity D3 direction of said second MP2 plate is not restricted and may correspond to the particular design needs.
[0079] Said first and second magnetic plates MP1 and MP2 are arranged in relation to each other in such a way that the first plate MP1 is arranged with its surface extended firmly or at some distance, for example, separated by a spacer, on the extended surface of the second MP2 plate, in such a way that its magnetic fields have a combined action in the location of the OEL.
[0080] In general, in some embodiments, this magnetic plate MP can also be implemented as a combination of two or more magnetic plates MP1, MP2, ..., MPi having one-dimensional or two-dimensional multipolar magnetizations with alternating magnetic polarity throughout at least an extended surface of said magnetic plates. Said one-dimensional multipolar magnetization of said first and second plates MP1, MP2, ..., MPi can again be any alternation between the north and south magnetic pole bands, such as a regular linear band pattern, a pattern of irregular linear bands ( Figure 9a), or a pattern of curved bands (Figure 9b) or bands of arbitrary shape, or they can, moreover, be circular patterns (Figure 9c), elliptical patterns or, more generally, any circuit patterns Closed. The required multipolar magnetization can additionally be present only on a single surface (for example, the upper one) of said magnetic plates MP, MP1, MP2, ..., MPi, or can span the entire thickness of the plates MP, MP1, MP2, MPi appearing with equal force on both the upper and lower surfaces of the MP, MP1, MP2, .... MPi plates.
[0081] The magnetic dipole DM can be oriented in such a way that its north-south direction D1, defined as the first x direction of the OEL, is substantially parallel to the plane of said magnetic plate MP or said combined magnetic plates MP1, MP2, MPi. In turn, individual magnetic plates MP1, MP2, MPi can be substantially parallel to each other.
[0082] In a second set of main modalities of the device of the invention, described below with reference to Figures 13, 14 and 15, the magnet arrangement of one or more magnets comprises a magnetized magnetic plate MP containing a plurality of individual magnetic elements ME configured to produce the first magnetic field component together, as well as generate an overlap of individual local dipole-type magnetic fields as the second magnetic field component. In this way, in the second set of main modalities, the two magnetic field components are generated together, that is, by the same magnets.
[0083] The magnetized magnetic plate MP contains or consists of a plurality of individual magnetic elements that are arranged within a magnetic plate MP along at least one direction within the magnetic plate, the direction being substantially parallel to said first direction, and which has its magnetic axes, that is, its north-south directions, substantially in the plane of the magnetic plate and are separated from their respective neighboring magnetic elements by spans. The spans generate an overlap of individual local dipole-type magnetic fields, corresponding to an alternation of North and South magnetic poles along a first direction D1, as the second alternating field component. The magnetic elements together also produce this first monotonous magnetic field component along said first direction, which implies that its magnetic axes are not randomly oriented in the plane of the magnetic plate, but oriented so as to produce the total magnetic field together. the plate.
[0084] In a preferred variant, the individual magnets are also arranged inside the magnetized magnetic plate MP along a second direction inside the magnetized magnetic plate MP. The second direction is different from the first direction and in such a way that along the second direction each individual magnet is separated from its respective neighboring individual magnets by a gap and the individual magnets have their magnetic axes oriented in order to produce the magnetic field total plate. In some modalities this arrangement shows an analogy to a "check box" where only the black fields (or alternatively the white ones) carry the magnetic elements, while the white fields (respectively the black fields) represent the gaps.
[0085] Except for these differences, the modalities of the second set of main modalities are similar to the first set of main modalities and, therefore, the respective portions of the description relating to the first set of main modalities, which are not strictly based on these differences , also apply to the second set of main modalities.
[0086] An example of the second set of main modalities is now described in more detail with reference to Figures 13, 14 and 15.
[0087] Figure 13 shows a device where the MP magnetic plate itself is defined, such as additionally assuming the function of the DM magnetic dipole. In such a modality, a number of ME magnetic elements, being preferably permanent magnetic, create the plane of said magnetic plate MP, and are arranged and fixed, as for i) resulting in cracks (magnetic spans) between north and south magnetic poles and for ii) result in a definitive total dipole field of the magnetic plate in a D1 direction that is substantially parallel to the plane of said magnetic plate MP. Said cracks (magnetic gaps) can be empty spaces. The ME magnetic elements can be fixed on a non-magnetic base plate. Alternatively, said cracks (magnetic gaps) can be filled with non-magnetic material. In both cases this has the advantage of resulting in a more mechanically sound construction. Preferably, the ratio of the size of a gap and the size of a magnetic element ME is at least 0.1.
[0088] Figure 14 schematically depicts a longitudinal section through an exemplary modality of such a magnetic plate with the north poles N and the south poles S identified.
[0089] Figure 15 shows the corresponding calculated magnetic field. In the location of a schematically drawn two-dimensional area, incorporated here by an optional support plate SP, the angle of elevation of the magnetic field lines in relation to the plane of the support plate SP and along the section shown on the support plate SP is the sum of a first function θ-i as described above, which can be monotonically decreasing, as the main component (that is, the effect of the macroscopic dipole field along the D1 direction) and an alternating function θ2 as the auxiliary component (that is, the effect of magnetic spans), thus reflecting the conditions above with reference to and depicted in Figure 6.
[0090] The following explanations are again, in general, applicable and the first and second main modalities are therefore not specific: The magnetic plate MP, respectively the combined magnetic plates MP1, MP2, MPi are preferably more extended than the OEL to be produced, in order to avoid edge effects due to the deviation of the magnetic fields at the edges of the plate.
[0091] Any of the magnets of the magnet arrangement, including said magnetic plate MP, respectively in the case of the first set of main modalities said combined magnetic plates MP1, MP2, MPi, as well as any of the first magnets, for example, said dipole magnetic DM, it can additionally comprise a permanent magnet, an electromagnet or a combination of these. Permanent magnets have the advantage of fixed magnetic fields, which allows to mount and adjust the orientation device in one for all the ways to facilitate use. Electromagnets have the advantage of allowing variable magnetic fields and reverse poles, which is useful in more flexible operation, where more than one coating of different effect must be accomplished using one and the same device. Thus, to allow flexible operation, one or more of the magnets in the device can be incorporated as electromagnets. Electromagnets are incorporated as iron cores having the required shape and magnetic poles, and taking appropriate wire coils, usually insulated copper or aluminum wire ("magnetic wire"), into which an electric current can be launched to produce a corresponding magnetic field .
[0092] For example, in the modalities of Figures 16, 17 and 18, either the magnetic plate MP or the magnetic dipole DM, or an additional vertical magnet VM, or any combination of these, can be incorporated with electromagnets to allow for variable magnetic fields (cf. Figure 16). Figure 17 and Figure 18 schematically illustrate exemplary modalities of iron cores with magnetic poles and wire windings for a one-dimensional multipolar magnetic plate and a two-dimensional multipolar magnetic plate, respectively. It is also possible to incorporate devices for even more differentiated variable magnetic fields, in which each pole of the iron core is provided with its own individual winding. In the case of permanent magnets, any type of permanent magnetic material can be used to incorporate the magnets, for example, in related modalities described above, the magnetic plates MP, MP1, MP2, MPi and the magnetic dipole DM. Permanent magnets can be, for example, Alnico, barium or strontium hexaferrite, cobalt alloys or rare earth iron alloys, such as neodymium-iron-boron alloy. Particularly preferred, however, are easily-used magnetic compound materials, which comprise a permanent magnetic fill, such as strontium hexaferrite (SrFe12O19) or neodymium-iron-boron powder (Nd2Fe14B), in a plastic or rubber-type matrix . Such materials have been described in the art as "Plastoferritas".
[0093] The magnetic plate MP, respectively the magnetic plates MP1, MP2, ..., MPi can, in addition, carry surface relief, engravings or cutouts on their respective surfaces, thus causing additional modulation of the first component magnetic, for example, of the DM magnetic dipole in some modalities, which has an effect of the image provided by the OEL to be produced and additionally and simultaneously allows the transfer of graphic evidence in the OEL, as shown in Example 2 described below in Figure 19.
[0094] According to a general principle, for all the modalities of the present invention, the distance d between the location of the OEL, for example, the location of the two-dimensional area, and the magnetic arrangement is preferably chosen, such as to obtain an appropriate balance of first magnetic field component, corresponding to the first function θ! and an alternating modulation due to the second magnetic field component corresponding to the second function θ2 (x). On the other hand, for a short distance d, the second alternating magnetic field component can dominate and the first macroscopic magnetic field component can be very negligible in comparison. On the other hand, for a long distance d, the second component of the magnetic field can be rendered negligible, and the first component of the macroscopic magnetic field can dominate (which yields an effect similar to a pure "scroll bar" effect). Thus, in preferred embodiments of the present invention a distance d is selected, where both the first and the second components are present in appropriate lengths at the position of the OEL, when the particles are oriented, in order to achieve an optimized desired optical effect of the OEL .
[0095] For similar reasons, preferably the ratio (i) of the length of the magnetized magnetic plate MP measured along a direction being parallel to said first direction, and (ii) said distance d, exceeds a value of 5.0.
[0096] The device can additionally comprise a support means having a surface to support the binding material during the orientation of the magnetic or magnetizable particles in it, such that the orientation region is defined as the space adjacent to a surface of the means of support. In particular, the support can be a plate or rotating unit of a printing apparatus. Alternatively, the support means can be a separate component of the device, such as a separate plate for carrying the OEL within the orientation region or its proximity. In an additional variant, the support means may comprise a component for generating an air cushion that supports the OEL within the orientation region. In a variant of the invention, the backing plate SP comprises a magnetic material, in particular permanent magnetic material, preferably an easily usable magnetic compound, "plastoferrite" type material, comprising a permanent magnetic fill, such as strontium hexaferrite (SrFe12O19 ) or neodymium-iron-boron powder (Nd2Fe14B), in a plastic or rubber type matrix. Particularly, in a preferred embodiment of this variant, the support plate SP of the magnetic material can be permanently magnetized and can carry signs in the form of surface relief, engravings or cutouts. As in the case of the magnetic plate carrying clues, (as described above) this modality additionally and simultaneously allows the transfer of graphic clues in the OEL, as shown in Example 2, described below in Figure 19.
[0097] In some preferred embodiments of the device, the magnet arrangement can generally be configured as a component of a printing apparatus. In particular, the magnet arrangement can be configured as an insert being adapted to be inserted into a recess within a plate or a rotating unit of a printing apparatus. The orientation region can then be defined, at least partially, as the space adjacent to the outer surface of the plate or rotary unit or it can be defined as a region at a given distance from the plate or rotary unit or it can be defined as a region at a given distance from said surface. In some specific embodiments, the magnet arrangement is particularly adapted to be inserted in the recess of the plate or in the cylindrical rotating unit of a printing apparatus, such that when it is inserted, its remaining external surface is aligned with the surface of the plate respectively. rotating unit. In such a case, the magnetic plate MP or the combined magnetic plates MP1, MP2, ..., MPi, as well as an optional support plate SP are correspondingly designed and adapted to the cylindrical surface of the rotating unit in order to ensure good contact with the substrate.
[0098] Finally, referring to Figures 20 to 22 and, for the purpose of illustration, again to the first set of main modalities and, the working principle of the combination of a multipolar MP magnetic plate with a DM magnetic dipole is corroborated by a calculating the magnetic field of a device according to such modalities of the present invention using the Vizimag 2.5 program (J. Beeteson, 2003). The magnet arrangement used in the calculation is shown in Figure 20. In this example, the magnetic plate MP is composed of six magnets arranged in parallel of relative length 20, with north and south poles alternating in a vertical direction. A DM magnetic dipole, arranged horizontally under the MP magnetic plate, has a relative strength of 100. The calculated magnetic field pattern based on this magnet arrangement is depicted in Figure 21. The evolution of the magnetic field vector across the SP support plate is approximately provided by the FL field line drawn in bold. Figure 22a depicts the specular reflection of light incident vertically on plate-like particles that are aligned along said FL field line drawn in bold. Figure 22b depicts a pigment flake orientation pattern in an OEL corresponding to said FL field line drawn in bold.
[0099] Referring now to Figure 22a, it can be seen that: i) within each of the zones "1", "2 '," 3 ", the positions of the mirror reflection, that is, the luminous parts of the image , seem to move with a change in the angle of view: looking from the top of the image, the positions marked with "a" are in a condition of specular reflection; changing the angle of view now to top-left, the positions marked with "b" are in a condition of specular reflection, that is, the luminous parts of the image appear to move to the left. Similarly, by changing the viewing angle to top-right, the positions marked with "c" are in a condition of specular reflection, that is, the luminous parts of the image appear to move to the right.ii) The evident movement of the luminous zones with changing the angles of view inverts the direction when looking from the other side, that is, for coatings obtained by applying the magnetic guidance device from the top instead of from the bottom, and for coating on a transparent substrate, allowing look at them from the straight side and from the back.iii) Some zones "disappear" completely from sight at a limiting angle of view: Zone "1" looks luminous at angles of view ranging from the left-side refraction view to around orthogonal view (position "c" of zone 1), but it looks dark ("disappears") at smaller right-side view angles, because there is no more pigment flake in the specular reflection condition at said angles of vis smaller for zone "1". Zone "2" looks luminous at viewing angles ranging from a 30 ° left side view to a 30 ° right side view, and "disappears" in a refractive view on either side. Zone "3" looks luminous at viewing angles ranging from right-side refractive view to around orthogonal view, and "disappears" at smaller left-side view angles.III. Method for producing an OEL
[00100] The present invention additionally discloses a method for producing an OEL and an OEL obtainable therefrom. The method of producing an optical effect layer, comprises a step of exposing a fluid binder material, being at least partially transparent to electromagnetic radiation of one or more wavelengths in the range 200 nm to 2500 nm and comprising a plurality of magnetic or magnetizable non-spherical particles having a non-isotropic reflectivity and being dispersed within said binder material, that is, an OEL as described in section I above, to the magnetic field of a device described in section II above. The OEL is exposed in said region adjacent to an extended surface of the magnetized magnetic plate MP of the device, thereby orienting the magnetic or magnetizable non-spherical particles within the binder material. The method, additionally, comprises a step of hardening concomitantly or subsequently of the binder material, in order to fix the magnetic or magnetizable non-spherical particles in their adopted positions and orientation.
[00101] During exposure to the combined magnetic field of the guidance device, the OEL is preferably maintained at a distance d from the magnetic plate MP of the guidance device. The distance d can be particularly in the range of 0.1 to 5 millimeters.
[00102] The binder material is preferably cured by radiation curing, which has the advantage of producing an instantaneous increase in viscosity of the coating composition after exposure to curing radiation, thereby avoiding any further movement of the particles and consequently any loss information after the magnetic orientation step.
[00103] Curing by radiation by photopolymerization is preferable, under the influence of actinic light having a wavelength component in the UV or blue part of the electromagnetic spectrum (normally from 300 nm to 500 nm; more preferable from 380 nm to 420 nm; "UV-visible cure"). The binder material for UV-visible curing must be correspondingly formulated, comprising at least one photoinitiator. UV-visible curing equipment may comprise a high power light-emitting diode (LED) lamp as obtainable from PHOSEON Technology, or an arc discharge lamp, such as a medium pressure mercury arc lamp (MPMA) or metal vapor arc, as the source of the actinic radiation.
[00104] In the case of an OEC comprising a substrate and at least one OEL, the magnetic field of the guidance device can additionally be applied either from the side of the substrate leading to at least one OEL, or from the side of the substrate opposite the OEL. Preferably, the substrate S is disposed on a support plate SP of the device during the orientation of the particles within the OEL.
[00105] In a particular embodiment of the method, the arrangement of magnets, or at least the portion of this generating the first magnetic field component, is rotated in a plane substantially parallel to the OEL and / or to the plane of the magnetized magnetic plate MP of the device during the orientation step, so as to produce an average magnetic field at least approximately circular. The thus obtained OEL has substantially no preferred direction, but shows the effect of the invention along any direction, under an arbitrary inclination axis in the plane of the OEL.
[00106] In a particular mode of the method in the case of an OEC, the substrate is a transparent substrate enabling a view of the OEL from both the straight side and the back side. The OEL of the present invention has the remarkable peculiarity that the direction of its movement is evident with modification of reverse angles of view if seen from the straight side or from the back side, respectively. Whereas dark image elements apparently progress with an increased angle of view on the straight side of the OEL, these dark image elements apparently regress with an increased angle of view on the back side of the same OEL.
[00107] Still according to another modality of the process, at least a first and a second OEL are combined on the same surface of a substrate S, the first OEL being oriented and cured when applying the magnetic field of the present orientation device invention described above from the substrate side leading to OEL (straight side), and the second OEL being oriented and cured by applying the magnetic field of said same device determined from the substrate side opposite the OEL (back side ), in which said first direction dir1 within the extended surface of the first OEL and the second OEL, is the same in said first and said second application.
[00108] In an additional variant of the above modality, said first and said second OELs are arranged at least in part on top of each other. When viewed in such a way that the direction of the OELs corresponding to said first direction, for example, D1 direction of a magnetic dipole DM generating the first magnetic field component of the combined magnetic field of the guidance device, is along the line between the two the observer's eyes, the combined OELs exhibit a three-dimensional depth effect, which is useful as a security element or as a decorative feature.
[00109] Furthermore, additional variants of the above modality are obtained if said first directions D1 are different in said first and said second application of the device, or if a first device is used in said first application, and a second different device in said second application .
[00110] It is also possible to provide one or more additional coatings or layers on the surface of said OEL or on the substrate of an OEC or on parts thereof. In the case of an OEC, additional coatings or layers can be added either before or after applying the OEL of the present invention to the substrate. In particular, a first layer can be applied to the substrate prior to the OEL of the present invention, in order to enhance the quality of a magnetically transferred pigment orientation image or to promote adhesion, and / or a protective coating can be applied along of the OEL of the present invention, serving, for example, to increase its wear and resistance to the ground or to improve its optical appearance, for example, to make it shiny or matte depending on the particular needs.
[00111] Still in an additional modality, the OEL is produced in the form of a transfer blade, which can be applied to a document or an article in a separate transfer step. For this purpose, the substrate is provided with a release coating, on which an OEL optical effect coating is produced as previously described. An adhesive layer can be applied over the OEL thus produced.
[00112] An OEL according to the invention can, for example, be used for decorative purposes, as well as to protect and authenticate a security document, such as a banknote, a document of value, an identity document and an identity document. access, a financial transaction card, a transport ticket or a product tag. Therefore, a decorative object or a security document can carry an OEL according to the present invention. IV. Specific exemplary modalities
[00113] The invention is now further illustrated with the help of two specific exemplary modalities: Example 1:
[00114] An exemplary device according to the present invention consists of: - a polymeric support with a convex top surface (50 x 50 mm), cylindrically curved around an D2 axis (surface curvature diameter: 275 mm) , the lower surface of the support being flat and the maximum thickness of the support in its center measuring 2.7 mm; - a magnetic dipole grouped DM (30 x 30 x 6 mm), magnetized through the thickness of 30 mm, located in contact with the flat bottom surface of the support, the magnetization axis of the magnetic dipole DM being along a direction D1 parallel to the bottom surface of said support and perpendicular to the cylindrical axis D2 of the upper curved surface of the support; - a flexible composite MP2 magnetic plate (NdFeB in polymeric binder; 40 x 40 mm, thickness 1.5 mm) located on top of and parallel to said upper convex surface of said polymeric support, said magnetic plate MP2 being magnetized through its thickness with a succession of strips of magnetic pole N and S alternating along the axial direction D2. The alternation of strips of magnetic pole N and S pointing away from the surface of MP2 forms a repetitive structure with a 6 mm periodicity along the D2 direction. A magnetic plate MP1 made of ferrite compound in flexible rubber alloy (SrFe12O19 in rubber nitrile, 40 x 40 mm, 1.5 mm thick) placed in contact with and directly on the top of said magnetic plate MP2. Said magnetic plate MP1 is magnetized through its thickness of 1.5 mm with a repetitive succession of strips of pole N and S alternating along a direction essentially parallel to an axis D1 parallel to D3. D1 forms an alpha angle of 90 degrees with D2 and an angle of 0 degrees with D3. The alternation of strips of pole N and S pointing away from the surface of MP1 forms a repetitive structure with a 6 mm periodicity along the perimeter of the curved surface of MP1.a magnetic plate (SP) of flexible compound in rubber alloy ( SrFei2O19 in nitrile rubber, 40 x 40 mm, thickness 1 mm) located directly in contact with the magnetic plate MP1 and uniformly magnetized across its 1 mm thick surface, with a single N pole pointing radially towards the magnetic plate MP1 .
[00115] A solid rectangular area (17 x 27 mm) was printed on the obverse surface of a paper substrate using a silkscreen UV curing coating composition according to WO 2007/131833 A1. The printed paper substrate was placed in contact with the device while the ink was still "wet", with the reverse side of the substrate facing the surface of the SP support plate. The contact was maintained between the printed paper and the device for about 1 second, to allow the orientation of the magnetic particles contained in the printed coating composition. The substrate carrying the oriented coating composition was subsequently removed from the device and the coating composition was cured by UV irradiation to produce a solid coating containing optically oriented variable particles. Figure 7 depicts the resulting visual effect when the print is tilted backwards a) to d) and forward e) to h). Example 2:
[00116] The device described in Example 1 is modified by rotating the grouped magnetic dipole DM around its main axis perpendicular to the surface, so as to form an angle of + 45 ° between D3 and D2, and an angle of -45 ° with D1, and the surface of the SP magnetic support plate was engraved with the image of a seahorse (engraving depth: 0.5 mm).
[00117] A solid rectangular area (17 x 27 mm) surrounded with two decorative edges was printed on the obverse surface of a paper substrate using a UV curing coating composition by silkscreen according to WO 2007/131833 A1. The printed paper substrate was brought into contact with the modified device of Example 2 while the ink was still "wet", with the reverse side of the substrate facing the backing plate (SP) surface. The contact was maintained between the printed paper and the device for about 1 second, to allow the orientation of the magnetic particles contained in the printed coating composition. The substrate carrying the oriented coating composition was subsequently removed from the device and the coating composition was cured by UV irradiation to produce a solid coating containing optically oriented variable particles.
[00118] The resulting solid coating containing oriented particles exhibits an intensely dynamic and color changing pattern depending on the angle of view, in combination with a distinct image of the seahorse recorded in Figure 19. This example illustrates the combination of a pattern geometric color change produced by the combination of magnets (DM, MP1, MP2) with essentially static evidence5 produced by the engraved magnetic support plate SP.

权利要求:
Claims (28)
[0001]
1. Optical effect layer (202; 300; 310; OEL), comprising: a binding material that is at least partially transparent to electromagnetic radiation of one or more wavelengths in the range 200 nm to 2500 nm; a plurality of non-spherical particles (200; 302 to 305; 312) having a non-isotropic reflectivity and being dispersed within said binder material and oriented according to a pattern extending along a length (307) along a first direction (x) within an extended surface (306; 313) of the optical effect layer, characterized by the fact that they have a first cross section (308; 311) of said optical effect layer perpendicular to said extended surface (306; 313) and along said first direction (x), the local average of an angle between (i) a straight line along a longer dimension observed within the corresponding cross-sectional shape of these non-spherical particles (200; 302 to 305; 312) that intersect with said first crosscut (308; 311) and (ii) said first direction (x) varies according to a function (θ) of a position (P) along said first direction (x), whose function is the sum of a first function (ΘI) monotone increasing or decreasing from said position (P) and a second alternating function (θ2) from said position (P), such that if the angle of view of the optical effect layer changes a pattern of light and dark areas on the The extended surface of the optical effect layer will appear to move along the first direction (x).
[0002]
2. Optical effect layer according to claim 1, characterized by the fact that the binding material is at least partially transparent to the electromagnetic radiation of one or more wavelengths in the range of the visible spectrum between 400 nm and 700 nm.
[0003]
Optical effect layer according to claim 1 or 2, characterized in that the optical effect layer (202) is arranged on a substrate (205) to form an optical effect coating (OEC) comprising the substrate ( 205) and the optical effect layer (202; 300; 310; OEL).
[0004]
Optical effect layer according to any one of claims 1 to 3, characterized in that said non-spherical particles (200; 302 to 305; 312) comprise a magnetic or magnetizable material.
[0005]
Optical effect layer according to any one of claims 1 to 4, characterized in that said non-spherical particles (200; 302 to 305; 312) are selected from the group consisting of platelet-shaped particles, particles in the shape of a needle and mixtures of these.
[0006]
Optical effect layer according to any one of claims 1 to 5, characterized in that said non-spherical particles (200; 302 to 305; 312) are optically variable magnetic particles.
[0007]
7. Optical effect layer according to claim 6, characterized in that said optically variable non-spherical magnetic particles comprise a thin film Fabry-Perot interference stack.
[0008]
8. Optical effect layer according to any one of claims 1 to 7, characterized by the fact that the values of said first function (θi) monotonically increasing or decreasing include a difference of at least 30 degrees along said length (307 ).
[0009]
Optical effect layer according to any one of claims ia 8, characterized in that in a second cross-section of said optical effect layer (202; 300; 310; OEL) perpendicular to said extended surface (306; 313 ) and along a second direction (y) within the extended surface (306; 313), which is different from the first direction (x), the local mean angle between (i) a straight line along a longer observed dimension within the corresponding cross-sectional shape of these non-spherical particles (200; 302 to 305; 312) that intersects with said second cross-section and (ii) said second direction (y) varies according to a third function (θs) of a position along said second direction (y), whose function (θs) is an alternate function of said position along said second direction (y).
[0010]
Optical effect layer according to any one of claims 1 to 8, characterized in that in a second cross-section of said optical effect layer (202; s00; s10, OEL) perpendicular to said extended surface (s06; s1s) and along a second direction (y) within the extended surface (s06; s1s), which is different from the first direction (x), the local mean angle between (i) a straight line along a longer observed dimension within the corresponding cross-sectional shape of these non-spherical particles (200; s02 to s05; s12) that intersect with this second cross-section and (ii) said second direction (y) varies according to a fourth function (θ4) from a position to the along said second direction (y), whose fourth function (θ4) is the sum of a function being equal to said first function (θ1) of said position along said second direction (y) and a fifth alternating function (θ5) from said position along said second direction (y).
[0011]
Optical effect layer according to any one of claims 1 to 10, characterized in that the optical effect layer (202; 300; 310; OEL) comprises, in addition to said plurality of non-spherical particles, at least one among: - magnetic particles that do not change color; - colorless magnetic particles; - non-magnetic particles that change color; - non-magnetic particles that do not change color; - colorless non-magnetic particles.
[0012]
12. Device for producing the optical effect layer (202; 300; 310; OEL), defined in any one of claims 1 to 11, by the orientation of magnetic or magnetizable particles (200; 302 to 305; 312) dispersed within a binding material, the device characterized by the fact that it comprises: an arrangement of one or more magnets (MP, MPi, ..., MPi, DM) comprising one or more first magnets and a magnetized magnetic plate (MP, MP1, .. ., MPi) and being thus configured to produce a combined magnetic field comprising: a) a first magnetic field component being similar to a magnetic dipole field and having its North-South direction (Di) aligned parallel to said magnetized magnetic plate (MP); and b) a second magnetic field component that comprises an overlap of individual local dipole-type magnetic fields and thus corresponds to an alternation of North and South magnetic poles along a first direction parallel to said North-South direction (Di ); wherein the first magnetic field component and the second magnetic field component overlap at least in a region adjacent to an extended surface of said magnetized magnetic plate (MP), the one or more first magnets being arranged to orient magnetic or magnetizable particles within the optical effect layer according to a main component θ1 of an θ orientation function, the magnetized magnetic plate being arranged to orient the magnetic or magnetizable particles within the optical effect layer according to an auxiliary component θ2 of the orientation function θ, the orientation function θ being a function of a position (P) along a first direction (x), the main component θ1 being a first monotonically increasing or decreasing function of the position, the auxiliary component θ2 being a second alternating function position, where the orientation function coincides with the local direction of the magnetic field lines in the respective positions, if n the general form of the function θ, such that it is wavy or fluctuating, with its general tendency gradually decreasing or gradually increasing as a function of the position, the second alternating function θ2 ensuring that the function θ displays a plurality of positions in which the derived from θ in relation to the position is zero, so as to form a plurality of local maximums and minimums in those positions.
[0013]
13. Device according to claim 12, characterized by the fact that the arrangement of one or more magnets (MP, MPi, ..., MPi, DM) comprises: a) one or more magnets configured to produce the first field component magnetic; and b) a magnetized magnetic plate (MP) configured to produce the second magnetic field component.
[0014]
Device according to claim 13, characterized by the fact that said one or more magnets configured to produce the first magnetic field component comprise a magnetic dipole (DM) having its North-South Di direction aligned parallel to said magnetized magnetic plate (MP).
[0015]
15. Device according to claim 13 or 14, characterized by the fact that at least one of said one or more magnets configured to produce the first magnetic field component is mounted so as to be rotatable in a plane parallel to the plane of said magnetized magnetic plate (MP).
[0016]
16. Device according to claim 12, characterized in that the arrangement of one or more magnets (MP, MP1, ..., MPi, DM) comprises a magnetized magnetic plate (MP) containing a plurality of individual magnetic elements arranged within the magnetized magnetic plate and along at least one dimension of the magnetized magnetic plate, the dimension being parallel to said first direction, such that along said dimension the magnetic elements: - form a row, - are separated from their respective magnetic elements neighboring by a gap e- have their magnetic axes aligned and pointing in the same alignment direction, in which said magnetized magnetic plate (MP) containing said magnetic elements (ME) is configured, in this way, to produce the field combined magnetic field comprising both the first and the second magnetic field component.
[0017]
17. Device according to claim 16, characterized in that the magnetized magnetic plate (MP) comprises additional magnetic elements (ME) arranged along a second dimension of the magnetized magnetic plate, the second dimension being different from the first dimension, in such a way that along the second dimension the magnetic elements (ME) are separated from their respective neighboring magnetic elements (ME) by a span and have their magnetic axes aligned and pointing in said alignment direction.
[0018]
18. Device according to claim 16 or 17, characterized in that the ratio of the span size and the size of the magnetic element (ME) is at least 0.1.
[0019]
19. Device according to any one of claims 12 to 18, characterized in that said magnetized magnetic plate (MP) is composed of two or more magnetic plates (MP1, MP2, ..., MPi).
[0020]
20. Device according to any one of claims 12 to 19, characterized by the fact that said magnetized magnetic plate (MP) carries signs in the form of surface relief, engravings or cutouts.
[0021]
21. Device according to any one of claims 12 to 20, characterized in that the device additionally comprises a support means (SP) for supporting the optical effect layer at a distance (d) from said magnetized magnetic plate (MP).
[0022]
22. Device according to claim 21, characterized by the fact that the ratio (i) of the length of the magnetized magnetic plate (MP) measured along a direction being parallel to said first direction (Di) and (ii) of said distance (d) exceeds a value of 5.0.
[0023]
23. Device according to claim 21 or 22, characterized in that said support means (SP) comprises a permanent magnetized magnetic material.
[0024]
24. Device according to claim 23, characterized by the fact that said support means (SP) carries indications in the form of surface relief, engraving or cutouts.
[0025]
25. Device according to any one of claims 12 to 24, characterized in that the device is configured as a component of a printing apparatus and adapted to be inserted into a recess of a printing plate or a rotating unit of the apparatus Printing.
[0026]
26. Method for producing the optical effect layer defined in any one of claims 1 to 11, characterized in that it comprises the steps of: exposing a fluid binder material comprising a plurality of magnetic or magnetizable non-spherical particles (200; 302 to 305; 312) having a non-isotropic reflectivity and being dispersed within said material binding to the magnetic field of a device defined in any one of claims 12 to 25, in said region adjacent to an extended surface of the magnetized magnetic plate (MP) of the device , thereby orienting the magnetic or magnetizable non-spherical particles (200; 302 to 305; 312) within a binder material; harden the bonding material in order to fix magnetic or magnetizable non-spherical particles (200; 302 to 305; 312) in their adopted positions and orientations, in which at least in their hardened state the bonding material is at least partially transparent to electromagnetic radiation of one or more wavelengths in the range 200 nm to 2500 nm.
[0027]
27. Security document, characterized by the fact that it comprises an optical effect layer defined in any one of claims 1 to 11.
[0028]
28. Use of an optical effect layer defined in any of claims 1 to 11, characterized by the fact that it is as a security feature or security element in document security applications.

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法律状态:
2018-03-06| B06F| Objections, documents and/or translations needed after an examination request according art. 34 industrial property law|

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2018-03-13| B06F| Objections, documents and/or translations needed after an examination request according art. 34 industrial property law|

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2018-03-20| B06I| Technical and formal requirements: publication cancelled|Free format text: ANULADA A PUBLICACAO CODIGO 6.6.1 NA RPI NO 2462 DE 13/03/2018 POR TER SIDO INDEVIDA. |

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2019-09-17| B06U| Preliminary requirement: requests with searches performed by other patent offices: suspension of the patent application procedure|

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2020-09-29| B09A| Decision: intention to grant|

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2020-12-08| B16A| Patent or certificate of addition of invention granted|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 30/04/2013, OBSERVADAS AS CONDICOES LEGAIS. |

优先权:

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申请号 | 申请日 | 专利标题

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EP12003551|2012-05-07|

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EP12003551.4|2012-05-07|

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PCT/EP2013/058986|WO2013167425A1|2012-05-07|2013-04-30|Optical effect layer|

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