• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    method and system for purifying exhaust gases from an internal combustion engine. the invention provides a method for purifying exhaust gases from an internal combustion engine, which comprises reducing the soot content in the exhaust gases by passing the gas through a filter; subsequently reduce the content of nitrogen oxides in the presence of ammonia or a precursor thereof in contact with an active catalyst in the selective catalytic reduction of nitrogen oxides with ammonia as a reducer; periodically regenerating the filter by burning the soot captured on the filter and thus increasing the exhaust gas temperature up to 850°C and water vapor content up to 100% by volume; passing exhaust gas from the filter through the catalyst during filter regeneration, wherein the catalyst comprises a microporous hydrothermally stable zeolite and/or zeolite having the ae1 type structure and being promoted with copper.
    公开号:BR112014026909B1
    申请号:R112014026909-2
    申请日:2012-04-27
    公开日:2021-06-29
    发明作者:Joakim Reimer Th0Gersen；Arkady Kustov；Avelino Corma Canós；Manuel Moliner Marin；Peter N. R. Vennestr0M；Antonio Eduardo Palomares Gimeno；Cristina Franch Marti；Marie Grill
    申请人:Umicore Ag & Co. Kg；
    IPC主号:
    专利说明:

    [001] The present invention relates to after-treatment of exhaust gases from an internal combustion engine in terms of removing or reducing harmful compounds. More particularly, the invention focuses on removing particulate matter and reducing nitrogen oxides in the exhaust of lean-burn internal combustion engines, and in particular diesel engines.
    [002] Lean burn engines are known to be efficient, but have the disadvantage of particulate formation and nitrogen oxides, which must be removed or at least reduced in the engine exhaust.
    [003] To avoid environmental pollution and comply with various government requirements, modern diesel engines are provided with an exhaust gas purification system that comprises in series an oxidation catalyst for the removal of organic or volatile compounds, a particulate filter for particulate matter removal and a catalyst being active in the selective reduction of nitrogen oxides (NOx).
    [004] It is also known about the integration of the SCR catalyst in the particulate filter.
    [005] Selective catalytic reduction of NOx in the exhaust gases is generally performed by reaction with ammonia introduced as such or as a precursor thereof, which is injected into the exhaust gas upstream of the SCR catalyst for the selective reduction of oxide oxides. nitrogen, mainly nitrogen dioxide and nitrogen monoxide (NOx), for nitrogen.
    [006] For this purpose, numerous catalyst compositions are disclosed in the literature.
    [007] Lately, zeolites promoted with copper or iron have found great interest, in particular, for use in automobile application.
    [008] Copper-containing zeolite catalysts for NH3-SCR applications showed high activity at low temperature. However, in certain applications, the catalyst can be exposed to high temperature excursions from the exhaust gases. In addition, the exhaust gas contains high concentrations of water vapor from the combustion engine, which can deteriorate the performance of the zeolite catalyst. Hydrothermal stability is often a problem for Cu-based zeolite catalysts, as a possible catalyst deactivation mechanism is the degradation of the zeolite structure due to its instability to hydrothermal conditions, which is further enhanced by presence of copper.
    [009] The deactivation of copper-containing zeolite catalysts in NH3-SCR applications is generally caused by the degradation of the zeolite structure due to its instability with respect to hydrothermal conditions, which is, furthermore, increased by the presence of copper. However, stability is especially important for automotive applications where the catalyst will experience high temperature excursions in an exhaust stream containing water.
    [010] Catalyst deactivation is, in particular, a problem in exhaust gas scrubbing systems provided with a particulate filter, which has to be periodically actively regenerated to avoid pressure build-up on the soot loading filter .
    [011] Active regeneration is performed by burning captured soot. Regeneration can be initiated by injecting fuel into the exhaust gas upstream of the oxidation catalyst or by electrically heating the particulate filter.
    [012] During active regeneration the exhaust gas temperature at the filter outlet can reach more than 850°C and a water vapor content greater than 15% and up to 100% for time periods between 10 and 15 minutes, depending on the amount of soot captured in the filter.
    [013] It is the general objective of the invention to provide a method for the removal of harmful compounds in lean-burn internal combustion engines, such as particulate material by means of a particulate and nitrogen oxides filter by selective catalytic reduction of nitrogen oxides in contact with catalyst being hydrothermally stable when exposed to high temperatures and water vapor concentration during active regeneration of the particulate filter.
    [014] It was found that the object of the invention can be achieved using a zeolite or zeotype having hydrothermally stable structure type AEI, in which the structure is preserved under hydrothermal aging conditions even when copper is present in the zeolite or zeotype.
    [015] According to the above finding, this invention provides a method for purifying exhaust gases from an internal combustion engine, comprising: reducing the soot content in the exhaust gases by passing the exhaust gas through a particulate filter; further reduce the content of nitrogen oxides in the presence of ammonia or a precursor thereof in contact with a catalyst being active in NH3-SCR; periodically regenerating the filter by burning the soot captured on the filter and thus increasing the exhaust gas temperature up to 850°C and the water vapor content up to 100% by volume; and passing exhaust gas from the filter through the catalyst during filter regeneration, wherein the catalyst comprises a hydrothermally stable zeolite and/or zeotype having an AEI type structure and copper incorporated into the structure.
    [016] "Hydrothermally stable" means that the zeolite and zeotype catalyst has the ability to retain at least 80 to 90% of the initial surface area and 80 to 90% of the microporous volume after exposure to temperatures of at least , 600°C and water vapor content up to 100% by volume for 13 hours, and at least 30 to 40% of the initial surface area and micropore volume after exposure to temperatures of at least one water and 750° C a vapor content of up to 100% by volume for 13 hours.
    [017] Preferably, the hydrothermally stable zeolite or zeotype with an AEI-type structure has an atomic ratio of silicon to aluminum, between 5 and 50 for the zeolite or between 0.02 and 0.5 for the zeotype.
    [018] The most preferred zeolite or zeotype catalysts for use in the invention are SSZ-39 zeolite and SAPO-18 zeotype, both having "AEI" frame structures, in which copper is introduced by impregnation, liquid ion exchange or ion exchange solid.
    [019] The atomic ratio of copper to aluminum is preferred to be between about 0.01 and about 1 for the zeolite. For the zeotype, the preferential atomic ratio of copper to silicon corresponds to between 0.01 and about 1.
    [020] By means of the above catalysts used in the present invention, 80% of the initial NOx reduction is kept at 250°C after aging at 750°C, compared to 20% for a 20 Cu-CHA catalyst.
    [021] Thus, in one embodiment of the invention, 80% of the initial reduction of nitrogen oxides at 250°C is maintained after the catalyst has been exposed to a temperature of 750°C and a water vapor content of 100% in the exhaust gas for 13 hours.
    [022] The invention provides, in addition to an exhaust gas scrubbing system, comprising an active regenerable particulate filter and an SCR catalyst comprising a hydrothermally stable microporous zeolite and/or zeotype having AEI-type structure and being promoted with copper .
    [023] In an embodiment of the exhaust gas scrubbing system according to the invention, the SCR catalyst is integrated into the particulate filter.
    [024] In yet another embodiment, the copper to aluminum atomic ratio is between about 0.01 and about 1 for the zeolite and the copper to silicon atomic ratio is between 0.01 and about 1 for the zeotype.
    [025] In yet one modality, the atomic ratio of silicon to aluminum in the SCR catalyst is between 5 and 50 for the zeolite and between 0.02 and 0.5 for the zeotype.
    [026] In another embodiment, the SCR catalyst retains 80% initial reduction of nitrogen oxides at 250°C after the catalyst has been exposed to a temperature of 750°C and a water vapor content of 100% in the exhaust gas for 13 hours.
    [027] In another embodiment, the SCR catalyst retains 80 to 90% of the initial microporosity after aging at 600 °C, and 30 to 40% of the initial microporosity after aging at 750 °C.
    [028] In yet one embodiment, the SCR catalyst is a SSZ-39 aluminum silicate zeolite and/or SAPO-18 silicoaluminum phosphate.
    [029] In the above embodiments, the SCR catalyst can be deposited on a monolithic support structure.
    [030] The Cu-SSZ-39 catalyst system showed better performance compared to the typical "state of the art" Cu-SSZ-13 when similar Si/Al ratios are compared. Example 1: Preparation of Cu-SSZ-39 Catalyst
    [031] The SSZ-39 zeolite with the AEI code-type structure was synthesized in a manner similar to that indicated in US patent 5,958,370 using 1,1,3,5-tetramethyl piperidinium as the ganic model. A gel with the following composition: 30 Si: 1.0 Al: 0.51 NaOH: 5.1 OSDA: 600 H2O, was autoclaved at 135°C for 7 days, the product filtered, washed with water, dried and calcined in air. The final SSZ-39 had a Si/Al ratio = 9.1 measured by ICP-AES.
    [032] To obtain Cu-SSZ-39, the calcined zeolite was exchanged ionically with Cu(CH3COO)2 to obtain the final catalyst with a ratio of Cu/Al = 0.52 after calcination.
    [033] The X-ray powder diffraction pattern (PXRD) of Cu-SSZ-39 after calcination is shown in Fig. 1. Example 2: Catalytic Test
    [034] The activity of samples for selective catalytic reduction of NOx was tested in a fixed bed reactor to simulate an engine exhaust gas flow, using a total flow rate of 300 mL/min consisting of 500 ppm of NO, 533 ppm NH3, 7% O2, 5% H2O, in N2 atmosphere, where 40 mg of the catalyst were tested.
    [035] The NOx present in the exit gases of the reactor was analyzed continuously and the conversion is shown in Fig. 2. Example 3: Hydrothermal durability test
    [036] In order to test the hydrothermal stability of the zeolites, steam treatments were made with the samples. They were exposed to a water feed (2.2 mL/min) at 600 or 750°C for 13 hours in a conventional oven and then tested similarly to Example 2.
    [037] The catalytic results can also be seen in fig. 2. Samples that were subjected to a hydrothermal treatment were labeled with 600 or 700°C, depending on the temperature used during the hydrothermal treatment.
    [038] Additional characterization was also performed for all treated samples. PXRD patterns after hydrothermal treatments are shown in Fig. 1, and BET surface areas, micropore areas, and volumes of treated microporous samples are summarized in Table 1 below. Example 4: Comparative example with Cu-CHA (Cu-SSZ-13)
    [039] A Cu-CHA zeolite was prepared from a gel with the molar composition: SiO2: Al2O3 0.033: 0.50 OSDA: 0.50 HF: 3 H2O, where the OSDA is N,N,N hydroxide - trimethyl-1-adamantamonium.
    [040] The gel was autoclaved at 150°C for 3 days under falling to obtain a final product with a Si/Al zeolite = 12.7 after washing, drying and calcining.
    [041] To obtain the Cu-CHA the calcined zeolite was ionically exchanged with Cu(CH3COO)2 to obtain the final catalyst with Cu/Al = 0.54.
    [042] The X-ray powder diffraction (PXRD) pattern of Cu-CHA after calcination is shown in Fig. 1.
    [043] This catalyst was also tested according to example 2, and the hydrothermal durability evaluated similarly to example 3. The catalytic results are summarized in Fig. 2 of the drawings. The PXRD Patterns of the CHA treated samples are shown in Fig. 1, and the textural properties (BET surface area, micropore volume and micropore area) are summarized in Table 1.
    Example 5: Cu- SAPO-18
    [044] Silicoaluminophosphate SAPO-18 with the AEI type code structure was synthesized according to [J. Chen, J.M. Thomas, P.A. Wright, R.P. Townsend, Catal. Letter 28 (1994) [241-248] and impregnated with 2% by weight of Cu. The final catalyst, Cu-180-SAPO was hydrothermally treated in 10% H2O and 10% O2 at 750°C and tested under the same conditions indicated in Example 2. The results are shown in Fig. 2 of the drawings.
    权利要求:
    Claims (10)
    [0001]
    1. A method for purifying exhaust gases from an internal combustion engine comprising: reducing the soot content in the exhaust gases by passing the gas through a filter; further reduce the content of nitrogen oxides in the presence of ammonia or a precursor thereof in contact with a catalyst being active in NH3-SCR; periodically regenerating the filter by burning the soot captured on the filter and thus increasing the exhaust gas temperature up to 850°C and the water vapor content up to 100% by volume; and passing exhaust gas from the filter through the catalyst during filter regeneration, characterized by the fact that the catalyst consists of a copper-promoted SSZ-39 hydrothermally stable microporous zeolite.
    [0002]
    2. Method according to claim 1, characterized in that the atomic ratio of copper to aluminum is between 0.01 and 1 for the SSZ-39 zeolite.
    [0003]
    3. Method according to claim 1 or 2, characterized in that 80% of the initial reduction of nitrogen oxides at 250°C is maintained after the catalyst has been exposed to a temperature of 750°C and a content of 100% water vapor in the exhaust gas for 13 hours.
    [0004]
    4. Method according to any one of claims 1 to 3, characterized in that at least 80 to 90% of the initial microporosity is maintained after aging at 600°C, and at least 30 to 40% is maintained after aging aging at 750°C.
    [0005]
    5. Exhaust gas scrubbing system comprising an active regenerable particulate filter and an SCR catalyst, characterized in that the SCR catalyst comprises a copper promoted SSZ-39 hydrothermally stable microporous zeolite.
    [0006]
    6. Exhaust gas scrubbing system, according to claim 5, characterized in that the SCR catalyst is integrated in the particulate filter.
    [0007]
    7. Exhaust gas scrubbing system, according to claim 5 or 6, characterized in that the atomic ratio of copper to aluminum is between 0.01 and 1 for the SSZ-39 zeolite.
    [0008]
    8. Exhaust gas scrubbing system according to any one of claims 5 to 7, characterized in that the SCR catalyst retains 80% of the initial reduction of nitrogen oxides at 250°C after the catalyst has been exposed at a temperature of 750°C and a water vapor content of 100% in the exhaust gas for 13 hours.
    [0009]
    9. Exhaust gas scrubbing system according to any one of claims 5 to 8, characterized in that the SCR catalyst retains at least 80 to 90% of the initial microporosity after aging at 600°C, and less than 30 to 40% of the initial microporosity after aging at 750°C.
    [0010]
    10. Exhaust gas scrubbing system, according to any one of claims 5 to 9, characterized in that the SCR catalyst is deposited on a monolithic support structure.
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    法律状态:
    2018-05-22| B25A| Requested transfer of rights approved|Owner name: UMICORE AG AND CO. KG (DE) |
    2018-12-11| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|
    2020-02-04| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|
    2021-02-09| B06A| Patent application procedure suspended [chapter 6.1 patent gazette]|
    2021-06-08| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|
    2021-06-29| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 27/04/2012, OBSERVADAS AS CONDICOES LEGAIS. |
    优先权:
    申请号 | 申请日 | 专利标题
    PCT/EP2012/057795|WO2013159825A1|2012-04-27|2012-04-27|Method and system for the purification of exhaust gas from an internal combustion engine|
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