plasterboard having a core with at least one side covered with non-woven fabric

专利摘要:
PLASTER BOARD HAVING A CORE WITH AT LEAST ONE SIDE COVERED WITH NON-WOVEN FABRIC, PROCESS TO PRODUCE A PLASTER BOARD AND SYSTEM FOR USE INSIDE OR OUTDOOR OF A BUILDING Plasterboard having a core, having this core, by less, one side covered with a non-woven fabric, characterized in that the inner side of the non-woven fabric, which is in contact with the core of the plasterboard, has a surface roughness Ra of 25 to 60 micrometers, preferably from 25 to 50 micrometers, advantageously from 25 to 40 micrometers.
公开号:BR112014019015B1
申请号:R112014019015-1
申请日:2012-12-26
公开日:2021-05-25
发明作者:Emmanuel Faynot；Marc Berlioz；Samuel Merlet；Claude Leclercq
申请人:Siniat International；
IPC主号:

专利说明:

TECHNICAL FIELD OF THE INVENTION
[001] The invention relates to a building material comprising a plaster core layer between two mats or mats. In particular, the object of the invention is a plasterboard also known as plasterboard, which is especially suitable to be used as a building material in a bathroom, in a kitchen, in a laundry, in any room, which may be exposed to moisture, even outdoors. BACKGROUND OF THE INVENTION
[002] Gypsum board, partition walls or gypsum board consist of or comprise a fibrous mat (usually a cellulosic cardboard, or non-woven fabric) wrapped around a thicker layer of gypsum. Gypsum or plaster is a hydratable calcium sulphate, such as for example CaSO4-^H2O, which is hardened after being wetted and subsequently dried.
[003] Although the gypsum board core is mainly made of gypsum, its properties can be improved by the introduction of additives. For example, the gypsum composition can include water resistant additives such as poly(vinyl alcohol), wax, polysiloxanes or thermoplastic synthetic resins. Other additives include fire resistant glass fibers or mineral fillers such as clay. The properties of the plasterboard can therefore be adjusted according to the intended end use.
[004] Water resistant additives such as fluorocarbon resin or silicone derivatives can also be introduced into the fibrous mat to impart hydrophobicity to the final gypsum board.
[005] The water resistance of a gypsum board is typically characterized by the maximum allowable absorption of liquid water in the board, in accordance with any of the C-473 standards of ASTM or EN-520 or EN15 2831.
[006] Although it may be necessary to introduce additives into the interior of the plaster and/or the mat in order to ensure that the plasterboard can be used in a wet area, the bond between said mat and the plaster can significantly weaken. In fact, hydrophobic additives can prevent good surface contact and chemical interaction between the fibrous mat and the gypsum core.
[007] As a consequence, one of the main problems in the development of gypsum boards for applications in wet or wet areas concerns the compatibility between the specific composition of the gypsum and the carpet. An improvement in the bond between the mat or mat and the plaster is therefore of great concern.
[008] Examples of the state of the art of water-resistant gypsum boards include mats that have been adapted to the composition of the gypsum. For example, US 2006/0068186 describes a non-woven mat comprising two layers of different compositions, an inner layer and an outer layer, wherein the inner layer is in contact with the plaster core. The inner layer comprises a mixture of cellulose fibers, inorganic or mineral fibers and optionally other organic fibers. On the other hand, the outer layer essentially comprises cellulose fibers. The two layers are bonded together with a binder and mineral filler in the presence of a water resistant fluorocarbon agent. The inner and outer layers have, respectively, an inner and outer outer face, where the inner outer face comes in contact with the plasterboard. The inner and outer outer faces are relatively flat, as a result of the standard production process of wet-laid non-woven fabric to form the net. Although the boards according to this prior art document are satisfactory, the connection can still be improved.
[009] EP 2 230 075 refers to a non-woven mat applicable to a gypsum board to be used in damp or wet areas, wherein at least one surface of such mat is treated with a hydrophilic latex binder. In this gypsum board, the bond between the gypsum core and the mat is increased thanks to improved chemical compatibility.
[010] WO2004/055286 discloses a gypsum panel comprising a gypsum core facing each other with a fibrous mat. A thin coating of a curable formulation is applied to the fibrous sheet facing the plasterboard.
[011] WO2008/100777 discloses a plaster panel that is covered on at least one face with a fibrous mat of fabric or non-woven fabric. A finishing material is applied to the mat surface, which is in contact with the plasterboard. The objective is to reduce the permeability of the fibrous mat face in order to improve the panel's water resistance. Even though it is indicated that the mat surface, prior to applying the finish, is uneven, it is specified that the finish is applied as a layer that is thick enough to delay or prevent penetration of the cement paste through the fibrous mat. This means that after the finish is applied, the uneven surface no longer exists. Furthermore, the document does not give any information regarding the way of production of the mat.
[012] US6787486 discloses a backing sheet sheet having moisture resistant face layers secured to a porous concrete core. In a preferred embodiment, the moisture resistant face layers include a mesh of woven or woven fibers incorporated in a respective resin layer.
[013] In order to solve the technical problems mentioned above and despite the shortcomings related to the previous solutions, it is thus desirable to develop a plasterboard that can be applied to buildings and buildings in damp and/or wet conditions, while maintaining the others Relevant characteristics in this type of material.
[014] Therefore, the present invention relates to a new gypsum board, which exhibits better bonding properties between the gypsum core and the mat, when compared to the prior art gypsum boards. This new gypsum board comprises water resistant and/or repellent agents in the core and/or mat, thus making it especially suitable for application in wet or wet conditions. In fact, due to its surface roughness, mat is more closely bonded to gypsum regardless of gypsum composition and the presence of any additives specially used in wet or wet conditions. SUMMARY OF THE INVENTION
[015] The object of the invention relates to a plasterboard having an improvement in the connection between the fabric mat and the plaster, by modifying the structure of the mat surface on the inner side of said mat. In this way the plasterboard of the invention is particularly suitable for use in damp or wet conditions.
[016] Therefore, in a first aspect the present invention discloses a plasterboard having a core with at least one side covered by a non-woven fabric and wherein said non-woven fabric has 2 sides, an inner side, which is in contact with the plaster core, and an outer side, which is on the opposite side of the plaster core, characterized in that the inner side of the non-woven fabric has a surface roughness Ra of 25 to 60 micrometers, preferably 25 to 50 micrometers, advantageously from 25 to 40 micrometers, according to claim 1.
[017] According to another embodiment, the non-woven plaster of the plasterboard of the present invention has on its inner side surface a specific relief pattern that has a surface roughness Ra from 25 to 60 micrometers, preferably from 25 to 50 micrometers, ideally 25 to 40 micrometers, according to claim 2.
[018] According to another modality, said non-woven plaster board of the present invention also has on its outer surface a surface roughness less than 25 micrometers, preferably from 5 to 15 micrometers, according to claim 3.
[019] According to another embodiment, the plasterboard of the present invention contains water-resistant agents in its core and/or in its non-woven fabric, according to claim 4.
[020] According to another embodiment, said non-woven plasterboard of the present invention comprises fibers that are selected from the group consisting of cellulosic fibers, inorganic or mineral fibers, synthetic polymeric fibers and mixtures thereof, wherein preferably :
[021] - the cellulosic-based fibers represent at least 25% by weight, preferably at least 30% by weight, more preferably at least 40% by weight of the weight of the non-woven fabric and/or
[022] - inorganic or mineral fibers are glass fibers; and/or
[023] - Synthetic polymer fibers are polymer fibers that can be selected from the group consisting of polyamide, polyaramid, polyethylene, polypropylene, polyester and mixtures thereof, according to claim 5.
[024] According to another embodiment, said non-woven gypsum board of the present invention further comprises at least one binder and/or at least one class of mineral filler particles and said mineral filler particles of preferably have a d50 of from about 0.1 to about 10 µm, preferably from about 0.5 to about 5 µm, according to claim 6.
[025] According to another embodiment, said non-woven gypsum board of the present invention comprises a binder:filler weight ratio of from about 1:2 to about 8:1, preferably from about 1: 1 to about 4:1, according to claim 7.
[026] According to another embodiment, said non-woven plasterboard of the present invention comprises at least two layers which are the first an inner layer, which is in contact with the core of said plasterboard, and the second a outer layer, said non-woven preferably comprises two layers and more preferably said two layers have a different composition, according to claim 8.
[027] According to another embodiment, said non-woven plasterboard of the present invention comprises at least two layers wherein the inner layer comprises a mixture of cellulosic fibers, inorganic or mineral fibers and optionally organic fibers, and said outer layer essentially comprises cellulosic fibres, wherein said non-woven fabric further comprises at least one binder and at least mineral filler particles, said particles being at least partially distributed in the inner and/or outer layer of the non-woven fabric, in accordance with claim 9.
[028] According to another so-called non-woven embodiment of the plasterboard of the present invention comprises at least two layers, in which:
[029] - the inner layer comprises, by weight based on the total weight of the fibers, from 25 to 60% by weight of the cellulosic fibers, from 25 to 60% by weight of the glass fibers and from 0 to 30% by weight of organic fibers, preferably from 30 to 50% by weight of cellulosic fibers, from 30 to 50% by weight of glass fibers and from 10 to 20% by weight of organic fibers; and/or
[030] - the outer layer comprises cellulosic-based fibers, preferably is essentially made of cellulosic-based fibers, more preferably consists of cellulosic-based fibers and ideally has a surface roughness Ra less than 25 micrometers, preferably from 5 to 15 micrometers, and/or
[031] - the mineral filler particles are distributed at least partially or substantially in both of said inner layer and outer layer of the non-woven fabric, according to claim 10.
[032] According to another embodiment, said non-woven plasterboard of the present invention comprises at least two layers, wherein in the outer layer of said non-woven, the amount of fibers and/or particles is about 0, 5 to 20% by weight of the fibers in the inner layer of the non-woven fabric, and wherein the fibers and/or particles in the outer layer are sufficiently large so that more than 90%, preferably more than 95%, more preferably more than 99% of the particles and/or fibers are larger than the openings between the fibers in the inner layer, according to claim 11.
[033] According to another embodiment, said non-woven plasterboard of the present invention comprises at least two layers, wherein the inner and outer layers are joined with the same binder, preferably a resinous binder, more preferably with a self-crosslinkable binder and/or a hydrophobic binder according to claim 12.
[034] According to another embodiment, said non-woven plasterboard of the present invention comprises at least two layers, wherein the inner and/or outer layers further comprise a water resistant agent, according to claim 13.
[035] According to another embodiment, said plasterboard non-woven fabric of the present invention comprises at least two layers, based on the final weight of the non-woven fabric, the inner layer represents between about 30 to about 150 g /m 2 , the outer layer represents from about 10 to about 70 g/m 2 and the binder and filler together represent from about 20 to about 150 g/m 2 , according to claim 14.
[036] In a second aspect of the present invention a process is disclosed for producing a plasterboard comprising the step of depositing a plaster paste on at least one non-woven fabric on its inner layer, wherein said non-woven fabric has 2 sides, an inner side, which is in contact with the plaster core and an outer side, which is on the opposite side of the plaster core, characterized by the inner side of the non-woven fabric having a surface roughness Ra from 25 to 60 micrometers , preferably from 25 to 50 micrometers, ideally from 25 to 40 micrometers and optionally is covered with a second non-woven fabric wherein the plaster core side is not covered with the first non-woven fabric, according to claim 15.
[037] In a preferred embodiment of said process, there is at least one non-woven fabric that forms a network that has a surface roughness Ra of 25 to 60 micrometers and preferably an embossed pattern, according to claim 16.
[038] In another embodiment of said process, the non-woven net further comprises a second non-woven fabric on the underside of the net, which has a surface with a roughness Ra of 25 to 60 micrometers and preferably an embossed pattern which forms a screen frame consisting of a first base screen and a second screen superimposed over it, in which:
[039] - the first base fabric contains at least more than 4 times the amount of warp and weft fibers per cm than the second fabric, preferably the first base fabric comprises between 15 and 50 weft fibers per cm and between 15 and 50 warp fibers per cm, and the second base fabric comprises between 1 and 15 weft fibers per cm and between 1 and 15 warp fibers per cm, the ratio of openings per cm2 being between the first and second fabric , preferably at least 10, and
[040] - the diameter of the weft and warp fibers of the first base fabric is at least 4 times smaller than the diameter of the weft and warp fibers of the second fabric, preferably the first base fabric comprises weft fibers having a diameter of 0.1 to 0.4 mm, and warp fibers having a diameter of 0.1 to 0.4 mm, and the second fabric comprises weft fibers having a diameter of 0.3 to 1.2 mm and fibers warp lengths having a diameter of 0.3 to 1.2 mm, according to claim 17.
[041] In another modality of said process, the gypsum core comprises:
[042] - at least one water resistant additive, in a sufficient amount such that the core absorbs less than about 10%, preferably less than about 5%, more preferably less than about 3% of water, when it is tested in accordance with ASTM method C-473 and/or in accordance with method EM 520, section 5.9.2,
[043] - at least one fire-resistant or flame-retardant additive in a sufficient amount such that the board has a fire-resistance rating in accordance with ASTM E-119 and/or C36-95 of at least about an hour and/or
[044] - hydraulic fixation of hydratable calcium sulfate, where said hydratable calcium sulfate has a particle size distribution (by weight) such that, after being separated into water: - the d10 is 1 to 2 μm , e- the d50 is from 5 to 35 µm, preferably the d50 is from 5 to 20 µm, more preferably the d50 is from 5 to 10 µm, or the d50 is from 10 to 35 µm, preferably the d50 is 10 at 20μm or d50 is from 20 to 35μm, and/or
[045] - the d950 is from 35 to 85 μm, preferably the d90 is from 35 to 50 μm, or the d90 is from 50 to 85 μm, and
[046] Preferably said hydratable calcium sulfate has a particle size distribution by weight such that about 100% of the particles fit into pores smaller than 60 µm and at least about 90% of the plaster particles fit into pores less than 40 µm or about 90% of the particles fit in pores less than 60 µm and about 70% of the stucco particles fit in pores less than 40 µm according to claim 18.
[047] Another aspect of the present invention relates to a system to be used inside or outside a building, comprising plasterboard, as described above, comprising said plasterboard, in addition: - An insulating material, having an inner surface and an outer surface, the inner surface of which is adhered to the surface of the non-woven fabric of said plasterboard by means of an adhesive material and an outer finishing material above the outer surface of said material insulating, optionally including a reinforcing element sandwiched between said insulating material and said finishing material; or- An underlying structural support element, which is covered with an underlying finishing material; or- A metal or wooden structure or nails for supporting said plasterboard, as claimed in claim 19. Definitions:
[048] In the scope of the present invention, as "non-woven fabric" is meant a textile-like material comprising long fibers bonded together through chemical, mechanical, thermal or solvent treatment. It may also be referred to as "non-woven fabric", "non-woven mat", "non-woven face", "carpet face" or simply "mat" or "face". "Non-woven fabrics" can define network or layer structures bonded together by fibers or filaments bonded together. Thus, within the scope of the present invention, a "layer" may also be called a "sheet", "panel" or "net".
[049] The term “fabric” means a material manufactured with a certain defined class of fibers and meshes or nets.
[050] The term or expression “ply assembly” means a material that is the result of the superposition of a first base ply and a second ply on which the wet laminated non-woven substrate is formed. The inner layer of substrate is laminated directly onto the second ply, and the outer layer of substrate forms on top of the inner layer.
[051] The term “fiber” means a form of material characterized by an extremely high proportion of length to diameter (eg 50/1). In the context of the present invention, the suitable fiber length is ideally between about 0.1 cm and about 4 cm.
[052] Typically, non-woven fabric is a material that can be manufactured from fibers or filament, cut or uncut, oriented or not, in such a way that it forms a laminar support obtained from a random arrangement of individual fibers that are interspersed. These can be held together by means of adhesives, heat and pressure or, for example, needle sewing. Such non-woven supports can be prepared in accordance with well-known processes, such as melt blowing, spin laying, carding, air laying and water laying.
[053] The surface roughness parameter Ra corresponds to the arithmetic mean of the absolute values of the coordinates Z(x) along a base length (L), with x varying from 0 to L. This parameter is well known for the technical in the subject.
[054] In other words, the Ra parameter is obtained according to the following:
DETAILED DESCRIPTION OF A PREFERRED MODALITY
[055] The object of the present invention relates to a plasterboard having a core comprising at least one surface covered with a non-woven fabric and a process to obtain said plasterboard, an insulating system and a set of division which also comprises said plasterboard.Gypsum board:
[056] As mentioned above, the plasterboard of the present invention has a core comprising at least one surface covered with a non-woven fabric, wherein the inner side of the non-woven fabric, which is in contact with the core of the board of gypsum, has a surface roughness Ra between 25 and 60 micrometers.
[057] According to a preferred embodiment, said inner side of the non-woven fabric comprises an embossed pattern having a surface roughness Ra from 25 to 60 micrometers, ideally from 25 to 50, preferably from 25 to 40 micrometers.
[058] According to a particular embodiment, the mat, that is, the non-woven fabric of the present invention may be constituted by, or may comprise one or more layers. In a more preferred embodiment, the mat of the present invention comprises two layers, an inner layer and an outer layer, wherein the inner layer, which is in contact with the plaster core and corresponds to the inner side of the mat, and the outer layer which is in contact with the plaster core and corresponds to the inner side of the mat. is opposite the plaster core, that is, which is not in contact with the plaster core, corresponds to the outer side of the mat. The mat layers can have the same or different compositions.
[059] According to another aspect of the invention, plasterboard comprises a two-layer non-woven fabric, an inner layer and an outer layer, wherein the inner layer, which is in contact with the core of the plasterboard, it has a surface roughness Ra from 25 to 60 micrometers, preferably from 25 to 50 micrometers, more preferably from 25 to 40 micrometers.
[060] In another preferred aspect of the present invention, when the mat comprises at least two layers, the inner layer has an embossed pattern.
[061] In another preferred aspect of the present invention, when the mat comprises at least two layers (inner + outer layers), the inner layer has an embossed pattern that has a surface roughness Ra from 25 to 60 micrometers, preferably from 25 to 50 micrometers, more preferably 25 to 40 micrometers.
[062] Without wanting to be restricted by theory, it is believed that said roughness may arise from the reorientation of the mat fibers due to the relief pattern process.
[063] Therefore, the invention also relates to a non-woven mat having an inner side and an outer side, wherein said inner side comprises an embossed pattern that has a surface roughness Ra from 25 to 60 micrometers, preferably from 25 to 50 micrometers, more preferably from 25 to 40 micrometers.
[064] According to another aspect of the present invention, the outer side of the non-woven mat has a roughness similar to that of the inner side. However, in a preferred embodiment, said outer layer has a surface roughness lower than that of the inner layer.
[065] Therefore, in another embodiment of the present invention, the second side of the non-woven fabric, that is, the outer side, which is not in contact with the plaster core has a surface roughness Ra of less than 25 micrometers, preferably less 15 micrometers, and even more preferably 5 to 15 micrometers.
[066] In addition, the outer layer of the non-woven fabric is generally not printed, although it may be ideal to propose an embossed pattern, that is, in another embodiment of the present invention, both sides of the non-woven fabric (inner and outer sides ) are subjected to an embossed treatment, which allows to achieve a better bond, for example a good bond to adhesives applied in place on the outer layer of the board, as well as in a Finishing System with Exterior insulation - EIFS). Said outer layer is not in contact with the plaster core; it can, however, be in contact with air and can be painted or covered with other materials, such as tiles, for example.
[067] It was surprisingly observed that the roughness increased when the mat surface formed a relief, compared to an unrelieved surface. Therefore, the combination of an embossed pattern with a specific surface roughness results in a great improvement in the anchoring of the mat to the plasterboard.
[068] Without wanting to be bound by theory, it can be considered that the relief treatment changes the 3D structure of the substrate in 2 ways:
[069] - A clearly visible mesh design over the cladding and plate, for example with dots at a distance of 1.5 x 1.5 mm as shown in Figures 4 and 6, which is the result of the lamination process wet on the double screen. This mesh design results from the formation of the substrate at the intersection points of the 2nd ply threads;
[070] - An improved cross distribution of fibers through the inner layer of the substrate. Thanks to the combination of 2 sheets, thin and coarse (respectively, the 1st and 2nd screens), and the water drainage through this double screen, the arrangement of fibers (mainly glass fibers) creates greater roughness. The second effect is considered to have the greatest improvement on binding properties.
[071] Therefore, in a more preferred embodiment, the plasterboard of the present invention comprises a non-woven mat that has an inner side and an outer side, wherein the inner side of said mat comprises an embossed pattern that has a roughness of surface Ra from 25 to 60 micrometers, preferably from 25 to 50 micrometers, even more preferably from 25 to 40 micrometers, and the outer side of said mat comprises an unrelieved design having a surface roughness Ra of less than 25 micrometers , preferably less than 15 micrometers and more preferably 5 to 15 micrometers.2. Face or mat:
[072] The non-woven fabric, or any of its layers, preferably comprises fibers that can be selected from the group consisting of or comprising:- cellulose-based fibers, including wood pulp, fibers cotton, sisal and abaca, - man-made fibers derived from cellulose, including viscose, rayon and lyocell, - glass, - mineral fibers, - synthetic (polymeric) fibers, and - mixtures thereof.
[073] According to a preferred embodiment, said synthetic (polymeric) fibers include polymer fibers that can be selected from the group consisting of or comprises polyamide, polyaramid, polyethylene, polypropylene, polyester, poly(vinyl alcohol), and mixtures thereof. Polyester is the preferred synthetic fiber. Fiber size can vary within wide ranges, for example, from 2.0 to 40.0 micrometers in diameter and from 1.5 to 38 mm in length. A mixture of fibers with different lengths can be used.
[074] As already mentioned, the inner and outer layers of the mat can have different compositions. However, the outer layer is advantageously made essentially of cellulose-based fibers, in order to provide a plasterboard that can be handled more conveniently, as the outer layer does not cause itching or any other unpleasant sensation in case that inorganic fibers, such as, for example, glass fibers, have been used in the composition of the inner layer.
[075] According to another preferred embodiment, the cellulose-based fibers may represent at least 25% by weight of the non-woven mat, preferably 30% by weight, more preferably 40% by weight of the non-woven fabric. fabric.
[076] Preferably, the non-woven face comprises two layers, wherein the outer layer is essentially cellulose and the inner layer comprises, by weight, based on the total weight of the fibers, from 25 to 60% by weight of fibers. cellulose, from 25 to 60% by weight of glass fibers and from 0 to 30% by weight of organic fibers, and preferably from 30 to 50% by weight of cellulose fibers, from 30 to 50% by weight of fiber. glass and from 10 to 20% by weight of organic fibers.
[077] Cellulose can be obtained, for example, from paper, cardboard or wood.
[078] According to a preferred aspect of the invention, the non-woven fabric having one or two layers, may also comprise at least one binder and/or at least one kind of mineral filler particles. These additives can constitute from 20 to 50% by weight with respect to the weight of the non-woven fabric.
[079] The individual fibers can be held together by at least one binder that can be selected from the group consisting of or comprises urea formaldehyde, melamine formaldehyde, polyesters, acrylics, polyvinyl acetate, ethylene acetate copolymers of vinyl, styrene acrylic copolymers, styrene butadiene styrene copolymers, polyvinyl chloride, etc., and mixtures thereof. Preferably, said binder is a self-crosslinkable hydrophobic binder, such as a styrene acrylic copolymer, in order to show good wet strength.
[080] The mineral filler particles can be an organic or inorganic powder selected from the group consisting of calcium carbonate, calcium sulfate, clay, kaolin, sand, talc, mica, glass powder, titanium dioxide , magnesium oxide, alumina, alumina trihydrate, aluminum hydroxide, antimony oxide, silica, silicate, etc. The dimensions of the infill material are such that it substantially penetrates the fibrous mat. For example, the mineral filler material can be particles having a d50 of about 0.1 to about 10 micrometers, preferably about 0.5 to 5 micrometers.
[081] The mat can also comprise resistant or water repellent additives such as fluorinated polymers. The amount of fluorinated additive can range from 0.1 to 5% by weight (based on the dry weight of the mat), preferably from about 0.2 to 2% by weight.
[082] Fluorinated polymers can be, for example, emulsions of acrylic copolymers with perfluorinated acrylates.
[083] As already stated, the inner side of the mat that is in contact with the plaster core comprises an embossed pattern that has a surface roughness of 25 to 60 micrometers. This makes it possible to significantly improve the connection of the plaster to the mat.
[084] Regarding the additional characteristics of the treadmill, its overall weight can represent up to 200 g/m2, advantageously from 100 to 200 g/m2, preferably it is 160 g/m2.
[085] Furthermore, its porosity can range from 10 to 60 l/m2/s under a pressure of 196 Pa. This porosity represents the air flow that can pass through the sample under a certain pressure drop across the mat, according to TAPPI T251 cm-85 paper industry standard.
[086] Also, the average mat thickness can range from about 0.2 to about 0.5 mm.
[087] On the other hand, according to another embodiment, the plaster layer can have a thickness of 10 to 20 mm.
[088] As already mentioned, the gypsum core properties can be adjusted with respect to the intended use of the gypsum board. As a result, gypsum can consist of gypsum alone or a mixture of gypsum and additives that impart water resistant or fire resistant properties.
[089] Examples of water resistant additives include poly(vinyl alcohol), molten wax, emulsified wax/asphalt mixture, emulsified wax, asphalt, metallic soaps, resins, polysiloxanes, and synthetic thermoplastic synthetic materials such as polyvinyl chloride or polyvinyl acetate, to name a few. The amount of water resistant additives can range from 0.05% by weight to about 5% by weight, based on the total weight of the gypsum core.
[090] Examples of fire resistance additives include mineral fibers such as glass fibers, basalt fibers, and mineral fillers such as clay, vermiculite, silica, alumina. The amount of fire resistance additives can be from about 0.03% by weight to about 10% by weight.
[091] Other additives, such as a biocide, needed particularly for gypsum board in wet area may be used. A foaming agent is also typically used in the gypsum slurry core in order to lessen the overall weight of the core. Typical gypsum core weight density ranges from 700 to 1000 kg/m3. Thickening additives or thinners are also typically used to control the rheology of the gypsum slurry. These can be, respectively, carboxymethylcellulose (CMC), hydroxymethylcellulose (HMC), hydroxyethylcellulose (HEC), starch, guar gums, as thickening agents, and polycarboxylate ether as thinning agent. Starch, CMC, HMC or HEC are also used to provide a better bond between the gypsum core and the mat face.
[092] According to the invention, the specific characteristics of the roughness and the design of the non-woven mat are obtained through a process that comprises the wet lamination of a suspension of fibers on a set of fabric that form a net and draining the water from the mains to produce the embossed pattern that presents a surface with a roughness Ra of 25 to 60 micrometers.
[093] The fabric assembly comprises a first base fabric and a second fabric superimposed thereon, wherein the inner substrate layer is strung directly on the second fabric, and the outer substrate layer is formed on the inner layer. This first web comprises fine filaments and a fine mesh, while the second web comprises thicker filaments and a coarser mesh. Overlapping screens change fiber orientation when water is drained through openings in the thicker mesh.
[094] The invention also relates to a process for the manufacture of a plasterboard, as described above, and its use as a building material, especially in humid environments, such as for example a bathroom, a kitchen or a laundry. Said plasterboard can be used in any wet area, indoors or outdoors.
[095] It is assumed that the use of the double ply assembly not only forms an embossed pattern on the lower substrate of the non-woven fabric but that it is also responsible for a certain reorientation of the fibers on the surface of the embossed pattern leading to specific roughness.
[096] Ideally, the amount of cm of the warp and weft fibers of the first base fabric is greater than that of the second fabric. Preferably, the first base fabric contains at least more than 4 times the amount of warp and weft fibers per cm as the second fabric.
[097] Therefore, in a preferred embodiment, the first base fabric comprises from 15 to 50 weft fibers per cm, preferably from 20 to 35 weft fibers per cm, more preferably 32 weft fibers per cm, and from 15 at 50 warp fibers per cm, preferably from 20 to 35 warp fibers per cm, more preferably 32 warp fibers per cm. weft per cm, and from 1 to 15 warp fibers per cm, preferably 6.3 warp fibers per cm. The ratio of openings per cm2 between the first and second fabric is at least 10, preferably equal to 23 ,two.
[098] According to another embodiment, the diameter of the warp and weft fibers of the first base fabric is at least less than 4 times, preferably less than 3 times the diameter of the warp and weft fibers of the second fabric. Ideally, the diameter of the weft fibers of the first base fabric is less than the diameter of the warp fibers of the first base fabric.
[099] Therefore, in a preferred embodiment of the present invention, the first base fabric comprises weft fibers having a diameter of 0.1 to 0.4 mm, ideally equal to 0.18 mm, and warp fibers having a diameter from 0.1 to 0.4 ideally equal to 0.22 mm. The second base fabric comprises weft fibers having a diameter of 0.3 to 1.2, ideally equal to 0.7 mm, and warp fibers which have a diameter of 0.3 to 1.2 ideally equal to 0.75 mm. PROCESS FOR PREPARING A PLASTER PLATE
[0100] The invention also relates to a process for manufacturing a plasterboard as described above and its use as a building material especially in wet areas such as bathrooms, kitchens or laundries, for example. This gypsum board can be used in any damp area indoors or outdoors.
[0101] The manufacturing process of the board of the invention can be very simple, since it can be performed on a conventional wall board production line. Especially, compared to previously known techniques, there is no need to specifically control the viscosity of the gypsum slurry, as the layers generally have a porosity blocked with the filler material, so that the gypsum does not substantially penetrate the face. of the mat.
[0102] Briefly, the process for manufacturing a gypsum board comprises the following steps: (i) preparation of a gypsum paste, by mixing the various components of the composition with water, in a mixer; (ii) deposition of the pulp thus prepared on at least one face of the mat of the invention, in its inner layer; (iii) molding and coating the upper face of the pulp, using a second reinforcing material, preferably a second face of the mat of the invention, in the its inner layer; (iv) where appropriate, molding the edges of the slab previously obtained by molding fresh plaster into profiled bands, this molding especially comprising the adjustment of the edges of the slab; (v) hydraulic adjustment of the hydratable calcium sulfate in a line of production, while the tape of the hydratable calcium sulfate plate runs along a belt conveyor; (vi) cutting the tape at the end of the line to predetermined lengths; and (vii) drying the plates obtained.
[0103] Between steps (ii) and (iii) there may be a sub step (iia) comprising the folding of the face of the mat of the invention in a U-shape for the formation of edges. The mat face of the present invention has the additional advantage of ease of folding.
[0104] This process of manufacturing a gypsum board may further include, immediately before the drying step, an optional step comprising coating with a second non-woven fabric (mat) on the side of the gypsum that is not already covered with the first non-woven fabric. PROCESS TO PRODUCE A NON-WOVEN FABRIC
[0105] The non-woven fabric is manufactured according to a process comprising wet lamination of a fiber suspension onto a web assembly to form a net and draining water from the net to produce the embossed pattern with a surface roughness Ra of 25 to 60 micrometers.
[0106] In more detail, the process for producing the non-woven mat typically comprises:
[0107] - wet laminating a fiber suspension over a screen assembly to form a net;
[0108] - drain the mains water to produce the relief pattern having a surface with a roughness Ra from 25 to 60 micrometers;
[0109] - dry the net that has the embossed dicta-pattern;
[0110] - optionally, impregnating the network with a solution that contains at least one binder; and
[0111] - dry the impregnated net.
[0112] The impregnation step is advantageously done in a size press.
[0113] Filler particles can be added to the size press composition. The penetration of particles into the network(s) can be adjusted by regulating the viscosity and/or particle size distribution.
[0114] The second mat, when present, may also have an inner side, this inner side being in contact with the plaster core and comprising an embossed pattern and has a roughness Ra from 25 to 60 micrometers, with that side being interior in contact with the plaster. The first and second mats can overlap each other as the first mat can be wrapped around the plaster core. This is a well known technique in the plasterboard manufacturing industry. The inner sides of the first and second non-woven fabrics may also comprise the same embossed pattern, which has the same surface roughness Ra from 25 to 60 micrometers. According to a preferred embodiment of the invention, the first and second non-woven fabrics have the same chemical composition. Furthermore, the gypsum paste is such that it can penetrate the carpet. Typically, it will not penetrate completely.
[0115] Without wishing to be bound by theory, it is believed that the gypsum slurry penetrates the "valleys" of the rough side (inner side) of the carpet, and may possibly also (partially) penetrate the carpet. However, the outer side of the mat, i.e. the side that does not face the plaster core, is essentially plaster-free, and advantageously entirely plaster-free.
[0116] According to a preferred embodiment, the mat is a non-woven, which has two layers, in which the gypsum paste can penetrate into the first layer, while the second layer is essentially gypsum-free. In this case, the carpet manufacturing process may comprise: - wet laminating a first fiber suspension on a set of mesh to form a net; - then wet laminating a second suspension on the upper side of the net and, simultaneously, drain the mains water to produce; on the underside of the net, the embossed pattern that has a surface of Ra roughness of 25 to 60 micrometers; - dry the net; - optionally, impregnate the net with a solution containing at least one binder; - dry the impregnated net.
[0117] The impregnation step is advantageously done in a size press. This process advantageously involves the use of the screen assembly as disclosed above.
[0118] The invention also relates to the non-woven fabric to be used in the manufacture of a plasterboard, as described above. More specifically, it concerns a non-woven fabric, which has an inner side comprising an embossed pattern, which has a surface roughness Ra of 25 to 60 micrometers, for the manufacture of a plasterboard having a core, having said core has at least one side covered with said non-woven fabric, the inner side of said non-woven fabric being in contact with the core.
[0119] Such non-woven fabric can be prepared as previously disclosed. Further disclosure of the process can be found in US3 322 617.
[0120] According to a preferred embodiment, the gypsum board contains water-resistant agents in the core and/or in the non-woven fabric. In addition, the outer side of the non-woven fabric, which may be in contact with air but not in contact with the plaster core, may have a surface roughness Ra of less than 25 micrometers. The surface roughness Ra on the outer side is preferably less than 15 micrometers, and even more preferably 5 to 15 micrometers. The outer side may or may not have an embossed pattern.
[0121] As already mentioned, the non-woven fabric can have more than one layer, that is, it can be a single-layer fabric or a multi-layer fabric. Preferably it is a two-layer fabric, in which its outer side, which is in contact with air but not in contact with the gypsum core, essentially comprises cellulose-based fibers and has a surface roughness Ra less than 15 micrometers, more preferably 5 to 15 micrometers. Advantageously, the outer side of the non-woven fabric is not embossed.
[0122] By "essentially cellulose-based fibers" is meant a content of at least 90% by weight of cellulose in relation to the weight of fibers comprised in the non-woven fabric, regardless of the weight of other additives such as a binder and/or a filler material.
[0123] According to another embodiment of the present invention, the non-woven fabric comprises a material with two layers, in which its outer side, which is in contact with the air, consists of cellulose-based fibers and has a surface roughness Ra less than 15 micrometers and advantageously 5 to 15 micrometers.
[0124] The use of this non-woven mat, for the manufacture of a plasterboard suitable for wet areas, is another aspect of the present invention. The board can be used in a variety of applications, both indoors and outdoors. As an example of an indoor application, we can mention axis wall sets, tile support, as well as partitions and ceilings in wet rooms.
[0125] A gypsum board as described herein can be used to particular advantage as a component of a partition or shaft wall assembly, or a similar assembly within a building. In the present invention, carpet face board can be used, with particular advantage, in place of conventional paper face gypsum core board or shaft facing panels, the core of which can include fire resistant additives. Assemblies of this type generally comprise metal or wooden structure or nails to support the plaster panels, which form the partitions in bathrooms and other wet or damp areas, in the walls of elevator shafts, in stairs and the like. Carpet face gypsum board, as described herein, can be used, for example, as the well cladding panel. For use in such an application, the core of the board may include fire resistant additives.
[0126] Refer to US-P-4047355, incorporated herein by reference, for more details on a shaft wall assembly. The present plate can also be used to advantage in air ducts, in a manner similar to WO-A-02/06605.
[0127] The present board can also be used, with advantage, as a support for tiles in bathrooms. Usual construction of bathroom walls includes the tiles adhering to an underlying base member, for example a plasterboard panel according to the invention. This panel is known in the industry as a "tile support plate" or "tile support". Generally speaking, tile backing sheets are secured by rust resistant nails or rivets. The plate joints and screw heads are then treated, in a conventional way, with a water resistant compound before the surface is finished, for example by painting or tiling. Wall-to-wall and floor-to-wall joints can be further treated with conventional sealants or buffering compounds before the surface is finished. The tile pieces adhere to the tile backing sheets through a water resistant adhesive (eg muck) or by a Portland cement-based adhesive (eg laying mortar), the latter case being mainly used for floor applications. After that, the spaces between tiles and between tiles and other adjacent surfaces are filled with a water-resistant material (mortar).
[0128] The present boards are also useful in any application on partitions and ceilings in rooms with wet or humid areas. Furthermore, the boards of the invention can be used in any application for which wall boards are known to be useful, including stucco wall.
[0129] As outdoor applications one can especially mention the metal platform roof system and EIS (exterior insulation system) and EFS (exterior finishing system), the latter systems being disclosed in greater detail below.
[0130] A typical metal deck roofing system incorporating the plasterboards of the invention is as follows. In this construction, the spaced parallel beams extending between the support members of the building generally support a metal (corrugated) platform that is secured to the beams. Layers of insulating sheet material (eg, expanded polystyrene) are laid out on the corrugated metal platform. A plasterboard of the invention is fixed to the corrugated platform by means of fasteners. The board joints are sealed in a conventional way by applying tape. A waterproof coating membrane is placed on top of the plasterboard. Typically, this membrane comprises alternating layers of asphalt and felt coating. An asphalt topcoat can be covered with a top coat.
[0131] Refer to US-P-4783942, incorporated herein by reference, for further details on a metal deck roof system. Exterior insulation systems and exterior finishing systems. An EIS system typically comprises insulation material that is located between an underlying support surface and an exterior trim material, which may be an integral part of the insulation material, but which is typically applied to the insulation material at the installation site. From one EIS system to the next there are variations in structural details and components. For example, although the exterior trim material can be attached directly to the insulation material, several systems include a reinforcement component sandwiched between the exterior trim material and the insulation material. The reinforcing component generally comprises one or more layers of fiberglass or mesh reinforcing fabric, which are adhered by the appropriate mortar to the surface of the insulating material. In some systems, the support surface is attached to a wooden frame attached to the outer surface of a building's exterior wall, while in other systems a metal frame is used. In certain applications, the bearing surface may be attached directly to the outer surface of an exterior wall, such as to an exterior wall comprising cement blocks or concrete blocks. Adhesives or mortars for adhesion of system components tend to vary from one system to another and are known. They normally comprise specially formulated proprietary compositions. Mechanically fixed insulation is also suitable. The support surface, improved in the present invention, can be used satisfactorily and to advantage in EIS systems, which include overlapping layers of insulating and exterior finishing materials and other optional components. The insulating material is generally substantially free of penetration channels therethrough.
[0132] An insulating material useful in EIS systems is foamed or expanded polystyrene, a material that has good moisture resistance properties. Although it has a desirably low water to vapor transmission, it is not a vapor barrier, but rather capable of breathing. Expanded polystyrene rigid panels are most widely used in EIS systems. These panels have satisfactory compressive strength and resilience and are currently available in different thicknesses and lengths. Other thermal insulation materials can also be used in EIS systems. Examples of these materials include extruded polystyrene, polyurethane, polyisocyanurate, cement-based insulating plasters and phenolic foam. Insulating materials generally have low thermal conductivity and low density. As mentioned above, various EIS systems include a reinforcing component, for example in the form of fabric sandwiched between the insulation material and the outer trim material. Glass fabric can be used in a conventional way to reinforce the system, that is to improve the impact strength of the system. The particular type or types of glass fabric as well as the number of layers to be used depend on the impact strength that is desired. Examples of fabric or fabric that can be used in the system are woven glass, strong fiberglass fabric, and fiberglass mesh. A coating can also be applied to the reinforcing cloth or fabric to protect it from alkaline attack on the adhesive. Installation of the reinforcing fabric generally involves applying a suitable adhesive to the surface of the insulation material and then applying the fabric to it. If desired, additional layers of fabric can be applied. An example of an adhesive that can be used is a cement/acrylic resin. The outer finishing material can be attached directly to the insulation material or to an intermediate surface, such as, for example, the surface of a reinforcement element, as described above. The exterior finishing material has climatic characteristics and is preferably attractive in appearance. Generally, an exterior finish that can be used is a conventional dry product, which is mixed with water and then spread over the underlying substrate. Alternatively, an acrylic resin-based composition, which is available in a paste-like form, can be used. After application, the resin sets to form a hard, weather-resistant solid material that adheres strongly to the underlying substrate. These resin compositions are commercially available in a variety of colors. They generally include aggregates that can vary in size. This allows the person applying it to choose a certain composition that allows them to apply a finish that can vary in texture from fine to coarse. Examples of other materials, which can be used as an exterior finish, are Portland cement, including, for example, sand and larger aggregates.
[0133] The exterior finish can vary in thickness over a wide range, as is known in the art, with a coating or layer thickness of about 2 to 6 mm being an example.
[0134] Different systems can have a different number of layers applied to the system. A typical example in commercial applications is as follows: steel rivets, construction or building wrapping material (such as tyvek®), plasterboard, spatula in adhesive, EPS insulation, spatula in Portland cement-based adhesive, glass screen reinforcement, Portland cement based adhesive “brown” backing coating and finally mortar based on a Portland cement color coating or a coat of paint.
[0135] The gypsum board of the present invention can also be used advantageously in addition to conventional gypsum board in applications other than EIS systems, that is, in systems that do not have any insulation material. Thus, the board can be used as an underlying support surface, which is covered with superimposed finishing materials such as aluminium, wood coatings, plaster and Portland cement.
[0136] Numerous advantages arise from the use of the present invention: An EIS system, which includes a support surface of the face of the plaster mat, which has an insulating material attached to it, through adhesive only, i.e. without other fastening means extending through the insulating material. This system exhibits greater tension or cohesive strength than a similar system that includes conventional gypsum paper faceplate. The mat face of the plaster support element is water resistant. This improved water resistance allows for greater flexibility, during application, in selecting adhesives that can be used to adhere the insulation directly to the mat face surface of the plaster support element, as no adverse effects are encountered in the use of water-based adhesives. The mat face of the plaster support element is nailable and therefore can be easily attached to an underlying structure or other substrate. The improved support surface of the present invention improves rigidity and strength uniformity in both the length and width dimensions of the system. In a preferred embodiment of the invention, which includes the use of a water resistant core, the support surface provides a substantially improved weather resistant product that better resists degradation both inside and outside the system. Reference may be made to documents US-P-4647496, US-P-5319900 and US-P5552187, all incorporated herein by reference, for further details on exterior insulation systems and exterior trim systems.
[0137] The invention also offers an additional advantage: it is known that the plaster, generally used in the manufacture of plasterboard, has different qualities depending on the supply and origin of this plaster. For example, it could be natural or it could be FGD. Thus, it is desirable to find a face that allows to eliminate any consequence of the variation between different plasters and that provides high-level properties regardless of the plaster type. The present invention provides such a face which is effective with both thin and thick plasters. Without wishing to be bound by any theory, it is believed that the roughness of the face is such as to allow for at least partial (eg 70%) intermeshing of stucco particles within the face fibers (inner face/inner layer ).
[0138] The following figures and examples illustrate the invention without limiting its scope. BRIEF DESCRIPTION OF THE FIGURES
[0139] Figure 1 shows the Ra vs. the sample length of a rough surface. The mat's roughness is illustrated in the diagram by means of the upper and lower peaks in a cross-section of a sample. The roughness parameter is calculated as the arithmetic mean of the absolute values of the ordinates (x) along a given length of a fixed sample length.
[0140] Figure 2 is a schematic view of a method that allows the measurement of the Ra parameter of a rough surface. A vertically scanning white light interferometry microscope tool takes the surface topography through a 2-ray white light interferometry, where: A represents a camera, B represents a mirror, C represents paper, and D represents a light source.
[0141] Figure 3 is a photograph of the surface of the inner layer of the F1 non-woven mat, where it is possible to see the random orientation of the glass fibers. The analyzed area of the treadmill corresponds to 3.5 mm x 3.5 mm.
[0142] Figure 4 is a photograph of the surface of the inner layer of the F2 non-woven mat, where it is possible to see the glass fibers plus the mat design obtained by the superimposed screens (illustrated by the dot line screen). The analyzed area of the treadmill corresponds to 3.5 mm x 3.5 mm. Comparing the images in Figure 3 and Figure 4, the roughness differences between the inner layer of mats F1 and F2, respectively, can be highlighted.
[0143] Figure 5 is a photograph of the surface of the outer layer of the F1 non-woven mat, where it is possible to see that the surface is smoother than the inner layer, and the glass fibers do not protrude as in the inner layer. You can also see essentially cellulosic fibers. The analyzed area of the treadmill corresponds to 3.5 mm x 3.5 mm.
[0144] Figure 6 is a photograph of the surface of the outer layer of the F2 non-woven mat. Comparing the images in Figure 5 and Figure 6, it is possible to observe that the roughness of the outer layer of F1 and F2 is quite similar. The analyzed area of the treadmill corresponds to 3.5 mm x 3.5 mm.
[0145] Figures 7 and 8 schematically represent the equipment and the delamination test method.
[0146] Wherein:1. Represents the sample;2. represents the extreme of the sample to be delaminated;3. represents the bearings;4. represents the mandible;5. represents the charging device.
[0147] Figures 9 and 10 are the same as Figures 3 and 4, respectively representing the surfaces of the inner layer of the non-woven mat F1 and F2 but amplified about 10 times. The arrow points to the drawing mesh clearly visible at this image size in F2. EXAMPLESExample 1: Non-woven rugs
[0148] Two mats or two non-woven fabrics, F1 and F2, were produced on an industrial paper manufacturing line according to the process mentioned above. Each mat comprises two layers (interior + exterior).
[0149] The inner layer comprised, in % weight on the total weight of the fibers: - 45% of cellulose fibers (length of about 2.5 to 5 mm and diameter of about 30 micrometers); - 14% of cellulose fibers polyester (length about 3 to 12 mm and diameter about 12 to 13 micrometers); e- 41% glass fibers, (length about 6 to 12 mm and diameter about 23 micrometers).
[0150] The dry weight of the inner layer surface was about 73 g/m2.
[0151] On the other hand, the outer layer comprised 100% cellulose fibers, with a length of about 2.5 to 5 mm and a diameter of about 15 to 30 micrometers. The dry weight of the outer layer surface was about 26 g/m2.
[0152] Both the inner and outer layers were impregnated with a mixture comprising (in parts by weight of the impregnation mixture): - 67 parts of a binder (self-crosslinkable styrene deacrylic polymer dispersion); - 0, 6 parts of a fungicide (iodine-based organic dispersion);- 1.5 parts of a water-repellent fluorocarbon (perfluoroacrylate copolymer dispersion); and - optionally 27 parts of a filler material.
[0153] The additional dry weight, due to the impregnation mixture, was about 38 g/m2, when the mixture does not comprise any filler material. However, it was about 56 g/m2 when the mixture comprises a filler material.
[0154] The filler material can be either calcium sulfate anhydride or kaolin (median particle diameter was such that the D50 ranged from about 1 micrometer to about 5 micrometers).
[0155] The F1 mat was manufactured by a common wet lamination process, according to this process, the mats were manufactured on an industrial paper production line, which comprised a primary head box and a secondary head box, where the first and second fiber dispersions are respectively prepared, corresponding respectively to the inner layer and the outer layer of the mat. The first dispersion of fibers was wet-rolled and placed onto a fabric comprising 32 warp threads/cm with a diameter equal to 0.18 mm and 32 weft threads/cm with a diameter equal to 0.22 mm so as to form a network. Then, the second suspension was wet rolled and placed on the upper side of the net. The process consisted of draining the water from the network simultaneously to produce, on the underside of the network, the relief pattern with a surface of specific roughness. Then, the net is dried and impregnated using a size press with the aforementioned mixture. The face is finally dry.
[0156] The mat F2 differed from F1 in that the set of screens comprises a first base screen and a second screen, superimposed on the first, instead of a single screen.
[0157] In this modality: - the first base fabric comprised 32 weft threads/cm and 32 warp threads/cm; - the second fabric comprised 7 weft threads/cm and 6.3 warp threads/cm; - the ratio of openings per cm2 between the first and second fabric was equal to 23.2;- the first base fabric comprised weft threads with a diameter equal to 0.18 mm and warp threads having a diameter equal to 0.22 mm;- the second fabric comprised threads of common weft diameter equal to 0.7 mm and warp threads having a diameter equal to 0.75 mm.
[0158] Therefore, two different mats were prepared, F1 and F2. They have a different internal and external surface roughness, as shown below in Table 1. Example 2: Measuring surface roughness
[0159] As described above, each of the mats F1 and F2 comprised an inner layer and an outer layer, as well as a respective inner and outer side. These two sides are characterized by their inner surface roughness (inner side in contact with the gypsum core) and by their outer surface roughness (outer side not in contact with the gypsum core).
[0160] The surface roughness can be characterized by the roughness parameter Ra, which results from the arithmetic mean of the absolute values of the coordinates (x) along a fixed length (L) (Figure 1), which defines the roughness profile . The Ra parameter was determined from at least 6 different roughness profiles within the working image and corresponds to the average of at least 6 of these unique Ra values. This Ra parameter is commonly used by a person skilled in the art in order to determine the surface roughness of a substrate, especially in the paper and non-woven carpet industry, as well as in other types of materials industry (plastics, metals, etc. .).
[0161] The Ra parameter was obtained as follows (figure 1): RaPa Deviation of the arithmetic meanWaEm where the arithmetic mean of the absolute values of the Z(x) coordinates over a sampling length

[0162] The roughness profiles of the mats or mats were obtained through an optical measurement method based on the reinforcement of vertical white light scanning interferometry. The principle of this optically based measurement method is as follows (Figure 2): a vertical white light scanning interferometry microscopy tool leads the process to surface topography by means of white light interferometry with two light beams. The first beam is reflected by a perfectly flat mirror, which forms the reference surface, the second beam being reflected by the sample which has a certain topography. The two beams interfere and form a figure consisting of alternating dark and light fringes: the interferogram pattern. When the distances traveled by light from the sample surface and the mirror are identical, the intensity of light in the detector is maximum. The two waves are then said to be in phase or in order of chromatic zero. On the other hand, when the 2 distances are becoming different, the intensity fluctuates for a short period of time and then decreases very quickly. The principle involves changing the reference mirror and finding the highest intensity while scanning.
[0163] Experimental data were collected in the TOPO3D instrument at the CTP (Centre Technique du Papier, Grenoble, France).
[0164] The area of the carpet analyzed corresponds to 3.5 mm by 3.5 mm.
[0165] The Ra values of the F1 and F2 mats are listed in Table 1.Table 1: Surface roughness of the F1 and F2 mats


[0166] Figures 3 and 4 clearly show the differences in roughness between the inner layer of mats F1 and F2, which are in accordance with the values shown in Table 1. It is assumed that the difference in roughness of the inner layer is due to use of a double ply on the F2 mat, which not only gives a specific embossed design to the surface, but also rearranges the fibers on the design surface.
[0167] The roughness of the outer layer, as shown in figures 5 and 6, is similar since the second dispersion of the fibers that form the outer layer is applied under the same conditions on the inner layer of both F1 and F2. Example 3: Joining tape - preparation of mini-bands
[0168] The following materials were prepared in order to determine the adhesion of the non-woven belt joined with the binding compound that is applied on a standard plasterboard.
[0169] The mini-bands were prepared in a laboratory at 20°C +/- 3°C and a relative humidity (RH) higher than 40%.
[0170] With a blade, strips (50mm wide and 297mm long) are cut from each non-woven mat F1 and F2 along the machine direction.
[0171] As substrate for the preparation of the bonding tape, a standard gypsum board (cellulose-based cardboard) 150 mm wide by 350 mm long was used. This plasterboard includes PREGYPLAC BA13 available from LAFARGE.
[0172] Then, a layer of bonding compound, 80 mm wide and 1 mm thick, was applied over the plasterboard. This 1 mm thick layer is prepared with a blade and two 1 mm thick gauges.
[0173] The strip of mat was then placed in the middle of the bonding compound, with the inner side of the mat in contact with the bonding compound. When passing over the mat with the blade (on its two indicators) it is possible to ensure total and even contact between the mat and the joining compound.
[0174] The resulting mini-bands were left to dry for 7 days in an acclimatized room at 25°C with a relative humidity of 50%.
[0175] The mini-bands were then tested directly (dry bond strength) or conditioned (wet bond test).
[0176] Two different bonding compounds were used, as shown in Table 2.Table 2: Compositions of bonding compounds C1 and C2

Example 4: Plates and mini-plate preparation
[0177] Mini-plates were prepared in the laboratory at a temperature of 20°C +/- 3°C and a relative humidity greater than 40%.
[0178] With a blade, strips (126 mm wide, 176 mm long) are cut from the F1 and F2 non-woven mats in the machine direction.
[0179] The four edges of the inner side of the strips were then bent so as to obtain four defined bend lines, 13 mm into the strip.
[0180] The four bend lines were therefore 100mm apart along the transverse direction and 150mm along the machine direction.
[0181] The four corners of the fold lines were then stapled to form an open mold shape for the strip with the inner side of the strip facing the interior of the mold.
[0182] Meanwhile, the gypsum core mixture was prepared as follows. The appropriate amount of water is poured into a plastic container so as to obtain a given solid/liquid ratio of 1.67.
[0183] Then, all liquid additives were added into a beaker and the mixture is homogenized under gentle agitation. The hydratable calcium sulfate is then added to the cup. The resulting slurry was left to rest for 2 minutes and then the mixture is homogenized under mechanical stirring for 5 minutes at 200 rpm.
[0184] After 5 minutes of stirring, the paste was poured into the molded non-woven mat as described above.
[0185] Excess gypsum slurry was removed from 13 mm high in order to leave a flat surface on the mat.
[0186] The mini-plate was then left to stand at ambient conditions for 53 hours.
[0187] After that, the mini-plate was dried at 70°C in a ventilated oven for 6 hours.
[0188] The resulting mini-plate was then conditioned at 25°C and 50% relative humidity for 24 hours, before measuring the dry bond strength.
[0189] The different compositions of the gypsum core tested are listed in Table 3.Table 3: Gypsum core compositions B1-B3
(a) CaSO4.1/2H2O (b) RediFILM 5400 from National Starch(c) Methylhydrogenpolysiloxane, MH1107 Fluid from Dow Corning Example 5: Connection Tests
[0190] This test consisted of measuring the force required to remove layers of a 50 mm wide strip of non-woven mat (in these examples, F1 or F2 non-woven mats), in order to peel them from the plaster core or the union compound. Furthermore, in order to ensure the accuracy of the test, the peeling force or the peeling force was measured at a constant speed of 100 mm/min and perpendicular to the surface.
[0191] In the case of mini-plates, the 50 mm strip of non-woven mat (in these examples, F1 or F2 non-woven mats) was cut along the machine direction from the dorsal part of the mini-plate .
[0192] In the case of mini-plates, being removed, manually, between 5 to 10 mm of this strip, the plaster core and from one of the two ends of said strip. This free part was then attached to the upper jaws of a dynamometer.
[0193] In the case of mini-bands, a 5 to 10 mm end of non-woven strip was attached to the upper jaws of a dynamometer in a similar manner.
[0194] The mini-plate was then fixed to a horizontal plate, which can move horizontally with the same linear speed as the crosshead (100 mm/min). The delamination force was registered by the dynamometer as a function of the crosshead position.
[0195] Bond strength represents the average of 3 measurements and is expressed in grams.
[0196] For the dry bonding test: before the test the samples were conditioned for 24 hours in an acclimatized room with a relative humidity of 50% and a temperature of 25°C. The dry bond test is carried out just after this 24-hour period.
[0197] For the wet bond test: before the test the samples were conditioned for 24 hours in an acclimatized room with a relative humidity adjusted to 90% and at a temperature of 30°C. The wet bond test is carried out just after this 24-hour period.
[0198] In addition to measuring the peel strength, the weight of the strip was measured after it was peeled from the plasterboard. In this way, it was possible to compare the initial and final weights, in order to calculate the total weight difference. This typically corresponds to the amount of gypsum core or bonding compound that is removed by the non-woven mat.
[0199] These results refer to the tests where the mini-bands were put in contact with the joint compound in dry and wet conditions, as shown in table 4, and to the contact of non-woven fabrics F1 and F2 with the gypsum core of the mini-bands as shown in table 5. Bonding tape: mini-bandsTable 4: Connecting the mini-bands to the bonding compound

[0200] The dry and wet bonding strengths between the bonding tape and the gypsum core are significantly improved when mat F2 is used, regardless of the bonding compound C1 or C2.
[0201] Furthermore, without intending to limit to any theory, the absorption of weight, in the case of the non-woven face F2, can be explained by the higher surface roughness. This certainly leads to greater penetration of the bonding compound into the fibrous structure. Table 5 presents the results of dry bonding and respective weight absorption as a function of the mini-plates tested (F1 and F2) and their composition of the gypsum core.Mini-platesTable 5: Binding of non-woven fabric F1 and F2 to the plaster core

[0202] Regardless of the composition of the example gypsum core, the bond with the non-woven mat, with a higher surface roughness (F2), is stronger than that with the non-woven mat and with a lower roughness.
[0203] This trend is also confirmed when considering the amount of plaster that is removed by the non-woven strip (weight absorption in the table). The F2 non-woven mat (with the superior surface roughness) removes a greater weight of gypsum per square meter, which may be due to a greater interpenetration of the gypsum/core paste on the surface of the fibrous layer of the non-woven mat. Example 6: Plasterboard
[0204] The following plaster boards were produced in a standard line: The composition of the core paste was a standard formulation for wetland boards and had the same composition as the core composition of the PREGYWAB boards marketed by the company SINIAT and is in agreement with the described in US 2006/0068186. The face that was used for the manufacture of plasterboard was face F2. The plates thus obtained were subjected to the following tests. Bonding or contact force
[0205] The delamination test aims to measure the load required to remove the layers or coatings from the core, along the length of 50 mm.
[0206] The equipment comprised the following, with the general description given in figure 7:- Clamp + bucket + glass balls (0 2 mm) + feeding system for glass balls with automatic stop in case of failure or end of the round;- Sample support;- 0.1 g precision scale;- Air-conditioned room: 23°C, 50% relative humidity (RH) and 30°C, 90% RH;- Cutter.
[0207] And the procedure was as follows:- 6 samples of 300 x 300 mm (12 x12 inches) were cut along the sample plate, as shown in the drawing (away from any end): 3 samples for the test of ambient layer removal (23°C, 50% relative humidity (RH) and another 3 for wet layer removal (24 hours at 30°C, 90% RH).
[0208] Two conditioning modes were used:- Ambient mode: 24 hours at 23°C, 50% relative humidity (RH) or, by definition, in the laboratory room at 23°C, if there is no humidity control; - Humidity conditions: 24 hours in a humid cabinet ventilated at 30°C, 90% relative humidity (RH). In order to achieve consistent plate wetting, the number of samples was limited, for example, to a maximum of 30 samples placed on trays in a 190L cabinet.
[0209] The installation procedure was as follows (see figure 8):
[0210] - In the central part of the plate, and along the machine direction, draw 2 lines parallel to centers of 50 mm. The coating or face was cut along these lines.
[0211] - A strip of this coating, 50 mm wide, was pulled out over a distance of 50 mm and at the 2 ends of the sample; - Using a cutter, the delamination of the face was started, cautiously, on the said 50 mm (2 inches); - The sample was placed in the holder with the face to be tested facing downwards; - The tweezers and the bucket were attached to the strip and it was ensured that the clamp and the bucket are perfectly centered and aligned ;- The bucket was started to be filled with the glass balls until a delamination was obtained along 50 mm (2 inches). The charge rate should be about 1 kg/min. The feeding system was automatically interrupted when the coating broke or delaminated along the 50 mm; - The total weight was noted: tweezers + bucket + glass spheres and the failure mode; - The test was repeated in the other end of the sample, then the sample is turned over and 2 more tests are performed on the opposite side.
[0212] The wet delamination procedure was as follows: - The sample was weighed, before and after conditioning, in order to determine moisture recovery; - He removed the samples one by one from the humid chamber and tested them immediately. Alternatively, three to three samples were removed, but were placed in a closed plastic bag right after weighing; - The coating was cut along the 2 lines and delamination started after the sample was weighed; - The delamination test was started, first on the face side and then on the dorsal side. The test time on each side was less than 4 minutes in order to avoid surface drying.
[0213] The results are expressed as follows:
[0214] For conditioning in ambient and wet conditions: - The load necessary to remove the face along 50 mm (2 inches) in each sample was recorded; - The average value for the plate is calculated (based on 6 measurements ); - The failure mode was noted (loss of connection to the core - face, lack of cohesion on the face or rupture of the face) mentioning the test conditions for each result (dry or wet conditions); - If it was not measurable due to to the strength of the link being raised, it was noted;
[0215] For wet delamination:
[0216] - Moisture recovery was recorded after 24 hours of conditioning.
[0217] Cobb 2H and immersion tests were performed in accordance with EN520. This was the standard procedure followed, unless otherwise specified.
[0218] The following results (Table 6) were obtained from two industrial trials. The given value results from an average of 8 different measurements. In delamination tests the results are so good that most samples are not measurable (delamination at the start).
[0219] Table 6: Contact tests on laminated industrial WAB boards with F2 non-woven faces

[0221] Compared to existing boards, especially boards manufactured according to US 2006/0068186, the boards of the present invention exhibit a marked improvement in bond strength, at least 30% compared to unrelieved face.
[0222] Another test was carried out with a core composition (unchanged face F2), which differs relatively with respect to the stucco. In tests 1 and 2, the plaster had the following dimension (PSD “Particle Size Distribution” - Distribution of Particles by Dimension) and based on weight, after fractionation in water: with d10 from 1 to 2 μm; with the d50 from 10 to 20 µm; and with the d90 from 35 to 50 µm. 100% of stucco particles fit in pores or openings less than 60 µm and about 90% or more particles fit in pores or openings less than 40 µm.
[0223] In test 3 the plaster had the following PSD:
[0224] PSD (weight) after fractionation in water: with d10 from 1 to 2 μm; with a d50 from 20 to 35 µm; and with the d90 from 50 to 85 µm. About 90% or less of stucco particles fit in pores or openings less than 60 µm and about 70% of particles fit in pores or openings less than 40 µm. The results obtained are shown in Table 7. Again, the results obtained are so good that most samples are not measurable (delamination at the beginning). Table 7: Delamination tests on industrial boards

[0225] Thus, it is possible to conclude that a change in the supply of stucco has little influence on the result in the effect of delamination of face 2, which is advantageous for industrial production.

权利要求:
Claims (13)
[0001]
1. PLASTER PLATE HAVING A CORE WITH AT LEAST ONE SIDE COVERED WITH NON-WOVEN FABRIC, wherein the non-woven fabric has 2 sides, an interior, which is in contact with the plaster core, and an exterior side, which is on the opposite side of the plaster core, characterized in that the inner side of the non-woven fabric comprises an embossed pattern having a surface roughness Ra of 25 to 60 micrometers, obtained through an optical measurement method based on enhanced scanning interferometry vertical white light, as detailed in the descriptive report.
[0002]
2. GYPSUM BOARD, according to claim 1, characterized in that the outer side of the non-woven fabric has surface roughness Ra less than 25 micrometers.
[0003]
GYPSUM BOARD according to any one of claims 1 or 2, characterized in that the plaster board contains water-resistant and/or fire-resistant agents in its core and/or water-resistant agents in its non-woven fabric.
[0004]
4. GYPSUM BOARD according to any one of claims 1 to 3, characterized in that the non-woven fabric comprises fibers that are selected from the group consisting of cellulose fibers, inorganic or mineral fibers, synthetic polymer fibers and/ or mixtures thereof, wherein:- the cellulose-based fibers represent at least 25% by weight of the non-woven fabric and/or- the inorganic or mineral fibers are glass fibers and/or- the synthetic polymer fibers are polymer fibers selected from the group consisting of polyamide, polyaramid, polyethylene, polypropylene, polyester and mixtures thereof.
[0005]
GYPSUM BOARD according to any one of claims 1 to 4, characterized in that the non-woven fabric comprises at least one binder and/or at least one type of mineral filler particles wherein the filler particles mineral have a d50 of 0.1 to 10 µm.
[0006]
6. GYPSUM BOARD, according to claim 5, characterized in that the weight ratio between the binder and the filling material is from 1:2 to 8:1.
[0007]
GYPSUM BOARD according to any one of claims 1 to 6, characterized in that the non-woven fabric comprises at least two layers, the first being an inner layer, which is in contact with the core of said plasterboard, and the second an outer layer, said non-woven comprises two layers.
[0008]
8. GYPSUM BOARD according to claim 7, characterized in that the inner layer comprises a mixture of cellulose fibers, inorganic or mineral fibers and organic fibers, and the outer layer comprises essentially cellulose fibers and in which the non-woven fabric it further comprises at least one binder and at least mineral filler particles, these particles being distributed at least partially in said inner and/or outer layer of the non-woven fabric.
[0009]
GYPSUM BOARD according to any one of claims 7 or 8, characterized in that:- the inner layer comprises, by weight, based on the total weight of the fibers, from 25 to 60% by weight of cellulose fibers of 25 to 60% by weight of glass fibers and 0 to 30% by weight of organic fibers and/or the outer layer comprises cellulosic based fibers and/or the mineral filler particles are distributed at least partially or substantially both of said inner layer and said outer layer of non-woven fabric.
[0010]
GYPSUM BOARD according to any one of claims 7 to 9, characterized in that in the outer layer of the non-woven fabric, the amount of fibers and/or particles is from 0.5 to 20% by weight of the fibers in the inner layer of the non-woven fabric and in which the fibers and/or particles in the outer layer are sufficiently large such that more than 90% of the fibers and/or particles in the outer layer are larger than the openings between the fibers in the inner layer.
[0011]
GYPSUM BOARD according to any one of claims 7 to 10, characterized in that the inner and outer layers are joined with the same binder.
[0012]
Plaster board according to any one of claims 7 to 11, characterized in that the inner and/or outer layers further comprise a water resistant agent.
[0013]
13. PLASTER BOARD according to any one of claims 7 to 12, characterized in that, based on the final weight of the non-woven fabric, the inner layer of this represents from 30 to 150 g/m2, the outer layer represents from 10 at 70 g/m2 and the binder and filler together represent from 20 to 150 g/m2.

类似技术:

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同族专利:

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公开号 | 公开日

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PE20142426A1|2015-02-13|

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AR090406A1|2014-11-12|

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AR089473A1|2014-08-27|

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ES2879936T3|2021-11-23|

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PL2809514T3|2021-12-27|

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EP2809517B1|2021-05-12|

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KR102150734B1|2020-09-02|

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RU2593773C2|2016-08-10|

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UA111771C2|2016-06-10|

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DK2809514T3|2021-10-18|

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ES2888098T3|2021-12-30|

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KR20140130109A|2014-11-07|

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WO2013113458A1|2013-08-08|

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JP6275050B2|2018-02-07|

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US10662648B2|2020-05-26|

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EP2809517A1|2014-12-10|

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US20150010730A1|2015-01-08|

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CL2014002046A1|2015-01-23|

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US20200284035A1|2020-09-10|

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CN104245305A|2014-12-24|

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AU2016202942A1|2016-05-26|

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WO2013113459A1|2013-08-08|

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CN111439013A|2020-07-24|

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EP2809514B1|2021-07-21|

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RU2014131898A|2016-02-20|

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EP2809514A1|2014-12-10|

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AU2012367940A1|2014-08-21|

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EP2623310A1|2013-08-07|

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JP2015508719A|2015-03-23|

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CO7111310A2|2014-11-10|

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CN104245305B|2020-04-24|

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WO2013113457A1|2013-08-08|

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PL2809517T3|2021-11-15|

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PT2809514T|2021-09-21|

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AU2016202942B2|2017-04-13|

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法律状态:
2018-03-27| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|

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2019-11-12| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|

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2020-12-08| B06A| Patent application procedure suspended [chapter 6.1 patent gazette]|

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2021-04-06| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|

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2021-05-25| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 26/12/2012, OBSERVADAS AS CONDICOES LEGAIS. |

优先权:

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申请号 | 申请日 | 专利标题

---

EP12153936.5|2012-02-03|

---

EP12153936.5A|EP2623310A1|2012-02-03|2012-02-03|Gypsum board suitable for wet or humid areas|

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PCT/EP2012/076908|WO2013113459A1|2012-02-03|2012-12-26|Gypsum board suitable for wet or humid areas|

---