smoke article, combustible thermal source, and process of reducing or eliminating increases in tempe

专利摘要:
SMOKE ARTICLE, COMBUSTIBLE THERMAL SOURCE, AND PROCESS TO REDUCE OR ELIMINATE TEMPERATURE INCREASES IN A SUBSTRATE AEROSOL FORMATOR OF A SMOKE ARTICLE. The present invention relates to a smoking article (2, 32, 34, 36, 38, 42, 56), comprising: a combustible thermal source (4, 40) with opposite front and rear faces; an aerosol-forming substrate (6) downstream of the rear face of the fuel thermal source (4, 40); an outer wrap (12) circumscribing the aerosol-forming substrate and at least one rear part of the combustible thermal source; and one or more air flow routes, along which air can be drawn by the smoke article (2, 32, 34, 36, 38, 42, 56) for inhalation by a user. The fuel thermal source (4, 40) is isolated from one or more airflow routes, the air drawn by the smoke article, along one or more airflow routes, does not come into direct contact with the thermal source fuel (4, 40).
公开号:BR112014018734B1
申请号:R112014018734-7
申请日:2013-02-12
公开日:2020-11-17
发明作者:Oleg Mironov；Laurent Edouard Poget
申请人:Philip Morris Products S.A.；
IPC主号:

专利说明:

[001] The present invention relates to a smoke article comprising a combustible thermal source and an aerosol-forming substrate, downstream of the combustible thermal source.
[002] Various smoking articles, in which the smoke is heated instead of burned, have been proposed in the art. One object of these "heated smoking articles" is to reduce the known harmful smoke constituents, of the type produced by combustion and pyrolytic degradation of smoke in conventional cigarettes. In a known type of heated smoke article, an aerosol is generated by transferring heat from a combustible thermal source to an aerosol-forming substrate. The aerosol-forming substrate can be located inside, around or downstream of the combustible thermal source. During smoking, volatile compounds are released from the aerosol-forming substrate by thermal transfer from the combustible thermal source and carried in the air drawn by the smoke article. As the released compounds cool, they condense to form an aerosol, which is inhaled by the user. Typically, air is drawn in these heated smoke articles known to one or more airflow channels by the combustible thermal source, and thermal transfer from the combustible thermal source to the aerosol-forming substrate occurs by convection and conduction.
[003] For example, international patent application W0-A2- 2009/022232 describes an article of smoke, which comprises a combustible thermal source, an aerosol-forming substrate downstream of the combustible thermal source, and a heat conducting element in around and in direct contact with a rear part of the fuel thermal source and an adjacent front part of the aerosol-forming substrate. To provide a controlled amount of convective heat from the aerosol-forming substrate, at least one longitudinal airflow channel is provided by the combustible thermal source. In the smoke article of international patent application WO-A2-2009 / 022232, the surface of the aerosol-forming substrate comes into contact with the combustible thermal source and, in use, the air drawn by the smoke article comes in direct contact with the rear end surface of the fuel thermal source.
[004] In known smoking articles, in which the transfer of heat from the combustible thermal source to the aerosol-forming substrate, basically occurs by convection, the convective heat transfer and, therefore, the temperature of the Aerosol can vary considerably, depending on the user's smoking behavior. Therefore, the composition and, therefore, the sensory properties of the main stream aerosol, inhaled by the user, can be highly disadvantageously sensitive to the user's smoke regimes.
[005] In known heated smoking articles, in which the air drawn by the heated smoking article comes in direct contact with the combustible thermal source of the heated smoking article, user smoke results in combustion activation of the combustible thermal source. Intense smoke regimes can therefore cause a convective thermal transfer high enough to cause temperature spikes in the aerosol-forming substrate, disadvantageously causing pyrolysis and, even potentially, local combustion of the aerosol-forming substrate. As used in this specification, the term "peak" is used to describe a short-lived increase in the temperature of the aerosol-forming substrate.
[006] The levels of undesirable pyrolytic by-products and combustion in mainstream aerosols, generated by these known heated smoke articles, can also disadvantageously vary significantly, depending on the particular smoke regime adopted by the user.
[007] It is known to include additives in the combustible thermal sources of heated smoke articles, to improve the ignition and combustion properties of combustible thermal sources. However, the inclusion of ignition and combustion additives can cause decomposition and reaction products, which disadvantageously enter the air drawn by the aerosol-forming substrates of the heated smoke articles, during their use.
[008] Several previous attempts have been made to reduce or eliminate undesirable constituents of smoke from the air drawn by the aerosol-forming substrates of smoke articles heated with a combustible thermal source, during their use. For example, several previous attempts have been made to reduce the amount of carbon monoxide, produced during combustion of carbonaceous thermal sources to heated smoke articles, by using catalysts in the carbonaceous thermal source, to convert the carbon monoxide, produced during combustion carbonaceous thermal source, in carbon dioxide.
[009] Patent application US-A-5,040,551 describes a process for reducing the amount of carbon monoxide produced during the combustion of a carbonaceous fuel element, for a heated smoke article comprising an aerosol generating means. The process comprises coating part or all of the exposed surfaces of the carbonaceous fuel element with a thin, microporous layer of solid particulate material, which is substantially non-combustible at the temperature at which the carbonaceous fuel element burns. The coating may additionally include catalytic ingredients. According to patent application US-A-5,040,551, the microporous layer must be sufficiently thin, and therefore permeable to air, so as not to unduly prevent the burning of carbonaceous fuel. Consequently, the air drawn by the smoke article from patent application US-A-5,040,551 is in direct contact with the surface of the carbonaceous fuel element, causing higher levels of undesirable constituents of the smoke.
[0010] Patent application US-A-5,060,667 describes a smoking article, comprising a fuel element, a hollow heat transfer tube circumscribing the fuel element, an aroma source material circumscribing the heat transfer tube, and a porous envelope circumscribing the smoking article. The heat transfer tube is opened at its upstream end and closed at its downstream end, and has an annular flange at its upstream end, having an outside diameter substantially equal to that of the smoke article, and an opening arranged in the center in alignment with the fuel end element. The closed downstream end of the heat transfer tube and the annular flange at the upstream end of the heat transfer tube prevent smoke from the fuel element from entering the smoker's mouth.
[0011] To facilitate aerosol formation, the aerosol-forming substrates of heated smoke articles typically comprise a polyhydric alcohol, such as glycerin, or other known aerosol builders. During storage and smoking, these aerosol builders can migrate from the aerosol forming substrates of known heated smoke articles to their combustible thermal sources. The migration of aerosol builders to the combustible thermal sources of known heated smoke articles can disadvantageously decompose the aerosol builders, particularly during the smoking of the heated smoke articles.
[0012] Several previous attempts have been made to inhibit the migration of aerosol builders from the aerosol forming substrates of heated smoke articles to their combustible thermal sources. Generally, these previous attempts involved enveloping the aerosol-forming substrate of a heated smoke article within an incombustible capsule, such as a metal cage, to reduce the migration of aerosol-forming substrates from the aerosol-forming substrate to the fuel thermal source, during storage and use. However, the fuel thermal source is still allowed to come in direct contact with the aerosol-forming substrate of the aerosol-forming substrate, during storage and use, and the air drawn by the aerosol-forming substrate, for inhalation by a user, can still come into contact with direct contact with the surface of the fuel thermal source. This disadvantageously allows the decomposition and combustion gases, generated from the combustible thermal source, to be drawn into the main stream aerosol of these known heated smoke articles.
[0013] There remains a need for a heated smoke article comprising a combustible thermal source, with opposite front and rear faces, and an aerosol forming substrate, downstream of the rear face of the combustible thermal source, where peaks in the temperature of the forming substrate Aerosol spray is avoided in heavy smoke regimes. In particular, there remains a need for a heated smoke article, comprising a combustible thermal source, with opposite front and rear faces, and an aerosol forming substrate, downstream of the rear face of the combustible thermal source, in which substantially no combustion or pyrolysis of the aerosol-forming substrate occurs under intense smoke regimes.
[0014] There is still a need for a heated smoke article, comprising a combustible thermal source, with opposite front and rear faces, and an aerosol forming substrate, downstream of the rear face of the combustible thermal source, in which the combustion products and decomposition, formed during the ignition and combustion of the fuel thermal source, are prevented or inhibited from entering the air drawn by the aerosol-forming substrate, during the use of the heated smoke article.
[0015] There is still a need for a heated smoke article, comprising a combustible thermal source, with opposite front and rear faces, and an aerosol-forming substrate, downstream of the rear face of the fuel thermal source, in which the formation migration of aerosol, from the aerosol-forming substrate to the fuel thermal source, is substantially prevented or inhibited.
[0016] According to the invention, an article of smoke is provided, comprising: a combustible thermal source with opposite front and rear faces; an aerosol-forming substrate downstream of the rear face of the fuel thermal source; an outer envelope circumscribing the aerosol-forming substrate and at least one rear part of the combustible thermal source; and one or more airflow routes, along which air can be drawn by the user's inhalation article of smoke. The fuel thermal source is isolated from one or more airflow routes, so that, in use, the air drawn by the smoke article, along one or more airflow routes, does not come in direct contact with the combustible thermal source.
[0017] According to the invention, a combustible thermal source is provided, with opposite front and rear walls, for use in a smoke article according to the invention, wherein the combustible thermal source has a substantially impermeable first barrier non-combustible air, provided at least substantially throughout the rear face of the fuel thermal source. In certain preferred embodiments, the first barrier comprises a first barrier coating provided on the rear face of the combustible thermal source. In these embodiments, preferably, the first barrier comprises a first barrier coating, provided at least substantially throughout the rear face of the combustible thermal source. In particular, the first barrier comprises a first barrier coating, provided across the rear face of the combustible thermal source.
[0018] In accordance with the invention, there is also provided a process for reducing or eliminating increases in temperature of an aerosol-forming substrate of a smoke article during smoking. The process comprises providing a smoke article, comprising: a combustible thermal source with opposite front and rear faces; an aerosol-forming substrate downstream of the rear face of the fuel thermal source; an outer envelope circumscribing the aerosol-forming substrate and at least one rear part of the combustible thermal source; and one or more airflow routes, along which air can be drawn by the user's inhalation smoke article, where the fuel thermal source is isolated from one or more airflow routes, so that , in use, the air drawn by the smoke article, along one or more air flow routes, does not come into direct contact with the combustible thermal source.
[0019] As used in this specification, the term "air flow route" is used to describe a route, along which air can be drawn by the user's inhalation article of smoke.
[0020] As used in this specification, the term "aerosol-forming substrate" is used to describe a substrate capable of releasing volatile compounds, which can form an aerosol, by heating. Aerosols generated from aerosol-forming substrates of smoke articles according to the invention may be visible or invisible and may include vapors (for example, fine particles of substances, which are in a gaseous state, which are commonly liquid or solid at room temperature), as well as gases and liquid droplets of condensed vapors.
[0021] As used in this specification, the terms "upstream" and "front" and "downstream" and "rear" are used to describe the relative positions of components, or parts of components, of the smoking article in relation to the direction in which a user pulls on the smoking article while using it. The smoking articles according to the invention comprise a mouth end and an opposite distal end. In use, a user pulls on the mouth end of the smoking article. The mouth end is downstream of the distal end, the fuel thermal source is located at or near the distal end.
[0022] The front face of the fuel thermal source is at the upstream end of the fuel thermal source. The upstream end of the combustible heat source is the end of the combustible heat source furthest from the mouth end of the smoke article. The rear face of the fuel thermal source is at the downstream end of the fuel thermal source. The downstream end of the combustible heat source is the end of the combustible heat source closest to the mouth end of the smoke article.
[0023] As used in this specification, the term "length" is used to describe the dimension in the longitudinal direction of the smoke article.
[0024] As used in this specification, the term "direct contact" is used to describe the contact between the air drawn by the smoke article, along one or more airflow routes, and a surface of the combustible thermal source .
[0025] As used in this specification, the term "isolated fuel thermal source" is used to describe a fuel thermal source, which does not come into direct contact with the air drawn by the smoke article, along one or more air routes. air flow.
[0026] As used in this specification, the term "coating" is used to describe a layer of material that covers and is adhered to the combustible thermal source.
[0027] As further described below, the smoking articles according to the invention may comprise combustible thermal sources that are blind or not blind.
[0028] As used in this specification, the term "blind" is used to describe a combustible thermal source of a smoking article, according to the invention, in which the air drawn by the smoking article, for inhalation by a user , does not pass through any airflow channels, along the fuel thermal source.
[0029] As used in this specification, the term "not blind" is used to describe a combustible thermal source of a smoking article, according to the invention, in which the air drawn by the smoking article, for inhalation by a user, passes through one or more airflow channels along the fuel thermal source.
[0030] As used in this specification, the term "airflow channel" is used to describe a channel extending along the length of a combustible thermal source, by which air can be drawn downstream for inhalation by a user.
[0031] The isolation of the combustible thermal source from one or more of the air flow routes, according to the invention, advantageously prevents or substantially inhibits the combustion activation of the combustible thermal source of tobacco articles, according to the invention. , during smoking by a user. This prevents or substantially inhibits spikes in the temperature of the aerosol-forming substrate during user smoke.
[0032] By preventing or inhibiting the activation of combustion of the fuel thermal source, and thereby preventing or inhibiting excessive temperature increases in the aerosol-forming substrate, combustion or pyrolysis of the aerosol-forming substrate of smoke articles, according to the invention, under intense smoke regimes, it can be advantageously avoided. In addition, the impact of a user smoke regime on the aerosol composition of the main stream of the smoking articles according to the invention can be advantageously minimized or reduced.
[0033] The isolation of the combustible thermal source from one or more of the air flow routes also substantially prevents or inhibits combustion and decomposition products and other materials, formed during ignition and combustion of the combustible thermal source of smoke articles, according to the invention, to enter the air drawn by the smoke articles, along one or more air flow routes. As further described below, this is particularly advantageous when the combustible thermal source comprises one or more additives to assist in the ignition or combustion of the combustible thermal source.
[0034] The isolation of the combustible thermal source from one or more of the air flow routes isolates the combustible thermal source from the aerosol-forming substrate. The isolation of the combustible thermal source from the aerosol-forming substrate can advantageously prevent or substantially inhibit the migration of components from the aerosol-forming substrate of tobacco articles according to the invention to the combustible thermal source during storage of the tobacco articles.
[0035] Alternatively or additionally, the isolation of the combustible thermal source prevents or substantially inhibits the migration of components of the aerosol-forming substrate of smoke articles, according to the invention, to the combustible thermal source, during use of the smoke articles .
[0036] As further described below, isolating the combustible thermal source from one or more of the airflow routes and the aerosol-forming substrate is particularly advantageous when the aerosol-forming substrate comprises at least one aerosol-forming substrate.
[0037] To isolate the combustible thermal source from one or more of the air flow routes, the smoke articles according to the invention may comprise a first substantially impermeable, non-combustible, air barrier between one end downstream of the source thermal fuel and an upstream end of the aerosol-forming substrate.
[0038] As used in this specification, the term "non-combustible" is used to describe a barrier, which is substantially non-combustible at the temperatures reached by the fuel thermal source, during combustion or ignition.
[0039] The first barrier may come into contact with one or both of the downstream end of the fuel thermal source and the upstream end of the aerosol-forming substrate.
[0040] The first barrier can be adhered to or otherwise affixed to one or both of the end downstream of the fuel thermal source and the end upstream of the aerosol-forming substrate.
[0041] In some embodiments, the first barrier comprises a first barrier coating, provided on the rear face of the fuel thermal source. In these embodiments, preferably, the first barrier comprises a first barrier coating provided at least substantially throughout the rear face of the combustible thermal source. In particular, the first barrier comprises a first barrier coating provided across the rear face of the combustible thermal source.
[0042] The first barrier can advantageously limit the temperature at which the aerosol-forming substrate is exposed, during ignition or combustion of the combustible thermal source, and thereby help or reduce the thermal degradation or combustion of the aerosol-forming substrate, during use of the smoking article. As further described below, this is particularly advantageous when the combustible thermal source comprises one or more additives to assist in igniting the combustible thermal source.
[0043] Depending on the desired characteristics and performance of the smoke article, the first barrier may have a low thermal conductivity or a high thermal conductivity. In certain embodiments, the first barrier can be formed of material having a mass thermal conductivity between about 0.1 W per meter Kelvin (W / (mK)) and about 200 W per meter Kelvin (W / (mK)) at 23 ° C and a relative humidity of 50%, measured using the modified transient plane source method (MTPS).
[0044] The thickness of the first barrier can be adjusted accordingly to obtain a good smoke performance. In certain embodiments, the first barrier can have a thickness between about 10 microns and about 500 microns.
[0045] The first barrier can be formed from one or more suitable materials, which are substantially thermally stable and non-combustible at temperatures obtained by the fuel thermal source, during ignition and combustion. Suitable materials are known in the art and include, but are not limited to, clays (such as, for example, bentonite and kaolinite), glass, minerals, ceramic materials, resin, metals and combinations thereof.
[0046] Preferred materials, from which the first barrier can be formed, include clays and glass. Particularly preferred materials, from which the first barrier can be formed, include copper, aluminum, stainless steel, alloys, alumina (AI2O3), resins and mineral glues.
[0047] In one embodiment, the first barrier comprises a clay coating, comprising a 50 - 50 mixture of bentonite and kaolinite, provided on the rear face of the combustible thermal source. In a particularly preferred embodiment, the first barrier comprises an aluminum coating, provided on a rear face of the combustible thermal source. In another preferred embodiment, the first barrier comprises a glass coating, particularly a sintered glass coating, provided on a rear face of the combustible thermal source.
[0048] Preferably, the first barrier has a thickness of at least about 10 microns. Due to the slight permeability of clays in the air, in embodiments in which the first barrier comprises a clay coating, provided on the rear face of the combustible thermal source, the clay coating has, in particular, a thickness of at least about 50 microns, and , especially between about 50 microns and about 350 microns. In embodiments in which the first barrier is formed of one or more materials, which are more impermeable to air, such as aluminum, the first barrier may be thinner, and will generally preferably be less than about 3 mm thick. 100 microns, and particularly about 200 microns. In embodiments in which the first barrier comprises a glass coating, provided on the rear face of the combustible thermal source, the glass coating is preferably less than about 200 microns thick. The thickness of the first barrier can be measured using a microscope, a scanning electron microscope (SEM) or any other measurement methods known in the art.
[0049] When the first barrier comprises a first barrier coating, provided on the rear face of the fuel thermal source, the first barrier coating can be applied to cover and adhere to the rear face of the fuel thermal source by any processes known in the art, including , but not limited to, spray coating, vapor deposition, immersion, material transfer (for example, by brushing or bonding), electrostatic deposition or any combination thereof.
[0050] For example, the first barrier coating can be done by pre-forming a barrier in the approximate size and shape of the rear face of the fuel thermal source, and applying it on the rear face of the fuel thermal source, to cover and adhere to the less substantially across the rear face of the fuel thermal source. Alternatively, the first barrier coating can be cut, or otherwise machined, after being applied to the rear face of the fuel thermal source. In a preferred embodiment, aluminum foil is applied to the rear face of the combustible thermal source by gluing or compressing it to the combustible thermal source, and is cut, or otherwise machined, so that the aluminum foil covers and adheres at least substantially across the rear face of the fuel heat source, preferably across the rear face of the fuel heat source.
[0051] In another preferred embodiment, the first barrier coating is formed by applying a solution or suspension of one or more suitable coating materials to the rear face of the combustible thermal source. For example, the first barrier coating can be applied to the rear face of the fuel thermal source by immersing the rear face of the fuel thermal source in a solution or suspension of one or more suitable coating materials, or by brushing or spray coating a solution or suspension, or electrostatic deposition of a powder or mixture of powders of one or more suitable coating materials on the rear face of the combustible thermal source. When the first barrier coating is applied to the rear face of the combustible thermal source by electrostatic deposition of a powder or mixture of powders of one or more suitable coating materials on the rear face of the combustible thermal source, the rear face of the combustible thermal source is, preferably, pre-treated with soluble glass, before electrostatic deposition. Preferably, the first barrier coating is applied by spray coating.
[0052] The first barrier coating can be formed by a single application of a solution or suspension of one or more suitable coating materials on the rear face of the fuel thermal source. Alternatively, the first barrier coating can be formed by multiple applications of a solution or suspension of one or more suitable coating materials on the rear face of the fuel thermal source. For example, the first barrier coating may be formed by one, two, three, four, five, six, seven or eight successive applications of a solution or suspension of one or more suitable coating materials on the rear face of the fuel source.
[0053] Preferably, the first barrier coating is formed by one to ten applications of a solution or suspension of one or more suitable coating materials on the rear face of the combustible thermal source.
[0054] After applying the solution or suspension of one or more coating materials on its rear face, the fuel thermal source can be dried to form the first barrier coating.
[0055] When the first barrier coating is formed by multiple applications of a solution or suspension of one or more suitable coating materials on its rear face, the combustible thermal source may need to be dried between successive applications of the solution or suspension .
[0056] Alternatively or in addition to drying, after applying a solution or suspension of one or more coating materials to the rear face of the combustible thermal source, the coating material in the combustible thermal source can be sintered to form the first barrier coating. The sintering of the first barrier coating is particularly preferred when the first barrier coating is a glass or ceramic coating. Preferably, the first barrier coating is sintered at a temperature between about 500 ° C and about 900 ° C, and particularly at about 700 ° C.
[0057] The tobacco articles according to the invention comprise one or more air flow routes, along which air can be drawn by the tobacco article.
[0058] In certain embodiments, the one or more airflow routes of smoke articles, according to the invention, may comprise one or more airflow channels along the combustible thermal source. The combustible thermal sources of tobacco articles, according to these embodiments, are referred to in this specification as non-blind combustible thermal sources.
[0059] In tobacco articles, according to the invention, comprising non-blind combustible thermal sources, heating of the aerosol-forming substrate occurs by conduction and convection. In use, when a user smokes an article of smoke, according to the invention, comprising a non-blinded heat source, air is drawn downstream from one or more of the airflow channels, along the fuel source . The drawn air then passes through the aerosol-forming substrate, as it is drawn further downstream by one or more of the air flow routes of the smoking article for inhalation by the user.
[0060] The one or more of the airflow routes of smoking articles according to the invention, comprising a non-blinded fuel thermal source, may comprise one or more airflow channels encased along the fuel thermal source.
[0061] As used in this specification, the term "wrapped" is used to describe airflow channels that are surrounded by the fuel thermal source along their lengths.
[0062] For example, one or more of the airflow routes may comprise one or more airflow channels, which extend over the internal part of the fuel thermal source, along the entire length of the fuel thermal source. In these embodiments, the one or more of the airflow channels extend between the opposite front and rear faces of the combustible thermal sources.
[0063] Alternatively or in addition, one or more of the airflow routes may comprise one or more airflow channels not enveloped along the combustible thermal source. For example, one or more of the airflow routes may comprise one or more grooves or other uninvolved airflow channels, which extend along the outside of the fuel thermal source, along at least part of the downstream of the length of the fuel thermal source.
[0064] The one or more of the airflow routes may comprise one or more of the airflow channels enclosed, along the fuel thermal source, or one or more of the uninvolved airflow channels, along the source fuel thermal, or a combination of them.
[0065] In certain embodiments, one or more of the air flow routes may comprise one, two or three air flow channels. In a preferred embodiment, one or more of the airflow routes comprise a single airflow channel, extending through the internal part of the combustible thermal source. In a particularly preferred embodiment, the one or more of the airflow routes comprise a single axial or central airflow channel, extending through the interior of the combustible thermal source. The diameter of the single airflow channel is preferably between about 1.5 mm and about 3 mm.
[0066] When the smoking articles according to the invention comprise a first barrier, comprising a first barrier coating provided on the rear face of the combustible thermal source, and one or more air flow routes comprising one or more channels of airflow along the fuel thermal source, the first barrier coating must allow air to be drawn downstream by one or more of the airflow channels.
[0067] When one or more of the air flow routes comprise one or more of the air flow channels, along the combustible thermal source, the smoke articles according to the invention further comprise a second substantially impermeable barrier to non-combustible air between the combustible thermal source and one or more of the airflow channels, to isolate the combustible thermal source from one or more of the airflow routes.
[0068] In some embodiments, the second barrier may be adhered to or otherwise affixed to the combustible thermal source.
[0069] Preferably, the second barrier comprises a second barrier coating, provided on an internal surface of one or more of the air flow channels. In particular, the second barrier comprises a second barrier coating, provided at least substantially over the entire inner surface of one or more of the air flow channels. In particular, the second barrier comprises a second barrier coating, provided over the entire internal surface of one or more of the air flow channels.
[0070] Alternatively, the second barrier coating can be provided by inserting a jacket in one or more of the air flow channels. For example, when one or more of the airflow routes comprise one or more of the airflow channels, which extend along the inside of the combustible thermal source, a substantially airproof, non-combustible hollow tube can be inserted. in each of the one or more of the airflow channels.
[0071] The second barrier can advantageously prevent or substantially inhibit combustion and decomposition products, formed during ignition and combustion of the combustible thermal source of smoke articles, according to the invention, from entering the air drawn downstream along one or more of the airflow channels.
[0072] The second barrier can also advantageously prevent or substantially inhibit the activation of combustion of the combustible thermal source of tobacco articles, according to the invention, during smoking by a user.
[0073] Depending on the desired characteristics and performance of the smoke article, the second barrier may have a low thermal conductivity or a high thermal conductivity. Preferably, the second barrier has a low thermal conductivity.
[0074] The thickness of the second barrier can be adjusted accordingly to obtain good smoke performance. In certain embodiments, the second barrier can have a thickness between about 30 microns and about 200 microns. In a preferred embodiment, the second barrier has a thickness between about 30 microns and about 100 microns.
[0075] The second barrier may be formed from one or more suitable materials, which are substantially thermally stable and non-combustible at the temperatures reached by the fuel thermal source, during ignition and combustion. Suitable materials are known in the art and include, but are not limited to, for example: clays, metal oxides, such as iron oxide, alumina, titania, silica, silica-alumina, zirconia and ceria; zeolites; zirconium phosphate; and other ceramic materials or combinations thereof.
[0076] Preferred materials, from which the second barrier can be formed, include clays, glass, aluminum, iron oxide and their combinations. If desired, catalytic ingredients, such as ingredients that promote the oxidation of carbon monoxide to carbon dioxide, can be incorporated into the second barrier. Suitable catalytic ingredients include, but are not limited to, for example, platinum, palladium, transition metals and their oxides.
[0077] When smoke articles according to the invention comprise a first barrier, between an end downstream of the combustible thermal source and an end upstream of the aerosol-forming substrate, and a second barrier, between the combustible and thermal source one or more of the air flow channels, along the fuel thermal source, the second barrier may be formed from the same material or from materials other than those of the first barrier.
[0078] When the second barrier comprises a second barrier coating, provided on an internal surface of the one or more of the air flow channels, the second barrier coating can be applied to the internal surface of the one or more of the air flow channels air by any suitable process, such as the processes described in patent application US-A-5,040,551. For example, the inner surface of one or more of the airflow channels can be sprayed, wetted or painted with a solution or suspension of the second barrier coating. In a preferred embodiment, the second barrier coating is applied to the internal surface of one or more of the airflow channels by the process described in international patent application WO-A2-2009 / 074870, in which the combustible thermal source is extruded.
[0079] In other embodiments, the one or more of the airflow routes of smoke articles according to the invention may not comprise any airflow channels along the combustible thermal source.
[0080] The combustible thermal sources of tobacco articles, according to these embodiments, are referred to in this specification as blind combustible thermal sources.
[0081] In smoke articles according to the invention comprising blind combustible thermal sources, the thermal transfer from the combustible thermal source to the aerosol-forming substrate occurs, basically by conduction, and heating of the aerosol-forming substrate by convection is minimized or reduced. This advantageously helps to minimize the impact of a user's smoke regime on the aerosol composition of the main stream of tobacco articles according to the invention, comprising blind combustible thermal sources.
[0082] It will be appreciated that the smoking articles, according to the invention, may comprise blind combustible thermal sources, comprising one or more blocked or closed passages, through which the air can be pulled inhaled by a user. These closed passages do not form part of one or more of the airflow routes of the smoking articles according to the invention. It will also be considered that, in addition to one or more of the air flow channels, through which the air can be drawn for inhalation by a user, the non-blind combustible thermal sources of smoke articles, according to the invention, also they may comprise one or more closed passages, through which the air cannot be drawn for inhalation by a user.
[0083] For example, the smoking articles according to the invention may comprise combustible thermal sources, comprising one or more passages, which extend from the front face at the upstream end of the combustible thermal source only partially along the thermal source fuel.
[0084] The inclusion of one or more closed air passages increases the surface area of the fuel thermal source, which is exposed to oxygen in the air, and can advantageously facilitate the ignition and continuous combustion of the fuel thermal source.
[0085] The smoking articles according to the invention, comprising blind combustible thermal sources, comprise one or more air inlets, downstream of the rear face of the combustible thermal source, to draw air in one or more of the air flow routes air. The smoking articles according to the invention, comprising non-blind combustible thermal sources, comprise one or more air inlets, downstream of the rear face of the combustible thermal source, to draw air in one or more of the air flow routes.
[0086] During smoke by a user, the cold air drawn to one or more of the air flow routes through the air inlets, downstream from the rear face of the fuel thermal source, advantageously reduces the temperature of the aerosol-forming substrate. This prevents or substantially inhibits spikes in the temperature of the aerosol-forming substrate during user smoke.
[0087] As used in this specification, the term "cold air" is used to describe ambient air, which is not significantly heated by a user's smoke-combustible thermal source.
[0088] By preventing or inhibiting spikes in the temperature of the aerosol-forming substrate, the inclusion of one or more air inlets, downstream of the rear face of the fuel thermal source, advantageously helps to prevent or reduce the combustion or pyrolysis of the forming substrate of aerosol of tobacco articles according to the invention in intense smoke regimes. In addition, the inclusion of one or more air inlets, downstream from the rear face of the fuel thermal source, advantageously helps to minimize or reduce the impact of a user smoke regime on the aerosol composition of the main stream of smoking articles. according to the invention.
[0089] The smoke articles according to the invention comprise an external wrapper, which circumscribes at least one rear part of the combustible thermal source, the aerosol-forming substrate and any other components of the smoke-article, downstream of the aerosol-forming substrate . Agricultural conveyors according to the invention may comprise external casings, formed from any suitable material, or a combination of suitable materials. Suitable materials are well known in the art and include, but are not limited to, cigarette paper. The outer wrapper must hold the combustible thermal source and the aerosol-forming substrate of the smoke article when the smoke article is assembled.
[0090] When present, at one or more of the air inlets, downstream of the rear face of the fuel thermal source, to draw air in one or more of the air flow routes, they are provided in the outer wrap and in any other circumscribing materials the components of tobacco articles according to the invention, by which air can be drawn in one or more of the air flow routes. As used in this specification, the term "air inlet" is used to describe one or more holes, slits, notches or other openings in the outer wrap and any other materials circumscribing the components of the tobacco articles according to the invention, by which air can be drawn on one or more of the airflow routes.
[0091] The number, shape, size and location of the air intakes can be adjusted accordingly to obtain a good smoke performance.
[0092] The tobacco articles according to the invention may comprise one or more air inlets, between an end downstream of the combustible thermal source and an end upstream of the aerosol-forming substrate, to draw air on one or more of the routes air flow. The air intakes, located between a downstream end of the fuel thermal source and an upstream end of the aerosol-forming substrate, are referred to in this specification as primary air intakes.
[0093] In use, when a user smokes that article of smoke, air can be drawn into the article of smoke through one or more of the primary air inlets, between the downstream end of the combustible thermal source and the upstream end of the substrate aerosol former. The drawn air then passes through the aerosol-forming substrate, as it is drawn downstream by one or more of the airflow routes of the smoke article, for inhalation by the user.
[0094] When the smoke articles according to the invention comprise a first barrier, between the downstream end of the combustible thermal source and the upstream end of the aerosol-forming substrate, to one or more of the primary air inlets are located at downstream of the first barrier.
[0095] Alternatively or in addition to one or more primary air intakes, the smoke articles according to the invention may comprise one or more air intakes, around the periphery of the aerosol-forming substrate, to draw air into one or more airflow routes. The air intakes, located around the periphery of the aerosol-forming substrate, are referred to in this specification as secondary air intakes.
[0096] In use, when a user smokes this article of smoke, air can be drawn through the aerosol-forming substrate through one or more of the secondary air intakes. The drawn air then passes through the aerosol-forming substrate, as it is drawn downstream by one or more of the air flow routes of the smoke article, for inhalation by the user.
[0097] Alternatively or in addition to one or more primary air inlets or one or more secondary air inlets, the smoke articles according to the invention may comprise one or more air inlets, downstream of the aerosol-forming substrate, for draw air to one or more of the airflow routes. The air inlets, located downstream of the aerosol-forming substrate, are referred to in this specification as tertiary air intakes.
[0098] In use, when a user smokes this article of smoke, air can be drawn through the aerosol-forming substrate through one or more of the tertiary air inlets, downstream of the aerosol-forming substrate.
[0099] In certain preferred embodiments, the smoke articles according to the invention may comprise an air flow path, extending between one or more of the tertiary air inlets, downstream of the aerosol-forming substrate, and an end at the mouth of the smoke article, in which the air flow route comprises a first part, extending longitudinally from one or more of the tertiary air inlets towards the aerosol-forming substrate, and a second part, extending longitudinally , downstream of the first part, towards the mouth end of the smoke article.
[00100] In use, when a user smokes this article of smoke, the air can be drawn by the article of smoke through one or more of the tertiary air inlets, downstream of the aerosol-forming substrate, and passes upstream, for the first part of the air flow route, towards the aerosol-forming substrate. The drawn air then passes down the second part of the air flow route, towards the mouth end of the smoke article, for inhalation by the user.
[00101] Preferably, the first part of the air flow route extends upstream from one or more of the tertiary air inlets, to the aerosol forming substrate, and the second part of the air flow route extends downstream aerosol-forming substrate towards the mouth end of the smoke article.
[00102] The tobacco articles according to the invention may comprise an air flow directing element, downstream of the aerosol forming substrate. The air flow guiding element defines the first and second part of the air flow route, extending between one or more of the tertiary air inlets, downstream of the aerosol-forming substrate and the mouth end of the article of smoke. One or more of the tertiary air inlets are provided between an end downstream of the aerosol-forming substrate and an end downstream of the airflow directing element. The air flow directing element can come in contact with the aerosol forming substrate. Alternatively, the airflow directing element can extend into the aerosol forming substrate. For example, in certain embodiments, the airflow directing member can extend up to a distance of up to 0.5 L to the aerosol-forming substrate, where L is the length of the aerosol-forming substrate.
[00103] The air flow guiding element can be between about 7 mm and about 50 mm in length, for example, between about 10 mm and about 45 mm in length or between about 15 mm and about 30 mm mm. The airflow directing element may have other lengths depending on the desired total length of the smoke article, and the presence and length of other components within the smoke article.
[00104] The air flow guiding element may comprise a hollow body substantially impermeable to air, with an open end. In these embodiments, the outer part of the hollow body substantially impermeable to air, the open end defines one of the first part of the airflow route and the second part of the airflow route, and the inner part of the hollow body substantially impermeable to open end air defines the other part of the first part of the air flow route and the second part of the air flow route.
[00105] The hollow body substantially impermeable to air may be formed from one or more suitable air-impermeable materials, which are substantially thermally stable at the rising pipe temperature, generated by the transfer of heat from the combustible thermal source to the forming substrate. aerosol. Suitable materials are known in the art and include, but are not limited to, cardboard, plastic, ceramics and combinations thereof.
[00106] Preferably, the outer part of the hollow body substantially impermeable to air, the open end defines the first part of the airflow route, and the inner part of the hollow body substantially impermeable to air, the open end defines the second part of the airflow route.
[00107] In a preferred embodiment, the hollow body substantially impermeable to air, with an open end, is a cylinder, preferably a straight circular cylinder.
[00108] In another preferred embodiment, the hollow body substantially impermeable to air, with an open end, is a cone trunk, preferably a straight circular cone trunk.
[00109] The hollow body substantially impermeable to air, with an open end, can have a length between about 7 mm and about 50 mm, for example, a length between about 10 mm and about 45 mm, or between about 15 mm and about 30 mm. The hollow body substantially impermeable to air, with an open end, may have other lengths, depending on the desired total length of the smoking article and the presence and height of the other components within the smoking article.
[00110] When the hollow body substantially impermeable to air, with an open end is a cylinder, the cylinder may have a diameter between about 2 mm and about 5 mm, for example, a diameter between about 2.5 mm and about 4.5 mm. The cylinder may have other diameters, depending on the desired total diameter of the smoke article.
[00111] When the hollow body substantially impermeable to air, with an open end is a cone trunk, the upstream end of the cone trunk can have a diameter between about 2 mm and about 5 mm, for example, a diameter between about 2.5 mm and about 4.5 mm. The upstream end of the cone trunk may have other diameters, depending on the desired total diameter of the smoking article.
[00112] When the hollow body substantially impermeable to air, with an open end is a cone trunk, the downstream end of the cone trunk can have a diameter between about 5 mm and about 9 mm, for example, a diameter between about 7 mm and about 8 mm. The downstream end of the cone trunk may have other diameters, depending on the desired total diameter of the smoke article. Preferably, the downstream end of the cone trunk is substantially the same diameter as that of the aerosol-forming substrate.
[00113] The hollow body substantially impermeable to air, with an open end, can come into contact with the aerosol-forming substrate. Alternatively, the substantially open-air hollow body substantially open-ended may extend into the aerosol-forming substrate. For example, in certain embodiments, the substantially air-impermeable, open-ended body may extend a distance of up to 0.5 L to the aerosol-forming substrate, where L is the length of the aerosol-forming substrate.
[00114] The upstream end of the hollow body substantially impermeable to air is of a reduced diameter, compared to that of the aerosol-forming substrate.
[00115] In certain embodiments, the downstream end of the hollow body substantially impermeable to air is of a reduced diameter, compared to that of the aerosol-forming substrate.
[00116] In other embodiments, the downstream end of the hollow body substantially impermeable to air is of a diameter substantially equal to that of the aerosol-forming substrate.
[00117] When the downstream end of the substantially air-impermeable hollow body is of a reduced diameter, compared to that of the aerosol-forming substrate, the substantially air-impermeable hollow body may be circumscribed by a substantially impermeable seal. air. In these embodiments, the substantially airtight seal is located downstream of one or more of the tertiary entrances. The substantially air-tight seal may be substantially the same diameter as that of the aerosol-forming substrate. For example, in some embodiments, the downstream end of the hollow body substantially impermeable to air may be circumscribed by a plug or washer of substantially the same diameter as that of the aerosol-forming substrate.
[00118] The substantially air-impermeable seal may be formed from one or more suitable air-impermeable materials, which are substantially thermally stable at the aerosol temperature, generated by the transfer of heat from the combustible thermal source to the aerosol-forming substrate. Suitable materials are known in the art and include, but are not limited to, cardboard, plastic, wax, silicone, ceramics and combinations thereof.
[00119] At least a portion of the hollow body substantially impermeable to air, with an open end, may be circumscribed by an air-permeable diffuser. The air-permeable diffuser may be of a diameter substantially equal to that of the aerosol-forming substrate. The air-permeable diffuser may be formed from one or more suitable air-impermeable materials, which are substantially thermally stable at the temperature of the aerosol, generated by the transfer of heat from the combustible thermal source to the aerosol-forming substrate. Suitable materials are known in the art and include, but are not limited to, porous materials, such as, for example, cellulose acetate tow, cotton, polymeric foams and open cell ceramics, smoke material and combinations thereof. In certain preferred embodiments, the air-permeable diffuser comprises a substantially homogeneous, air-permeable porous material.
[00120] In a preferred embodiment, the airflow directing element comprises a hollow tube substantially impermeable to air, an open end of a reduced diameter, compared to that of the aerosol-forming substrate, and a seal substantially impermeable to annular air. substantially the same diameter as that of the aerosol-forming substrate, which circumscribes the hollow tube downstream of one or more of the tertiary air intakes.
[00121] In this embodiment, the volume radially connected by the outer part of the hollow tube, and an outer wrap of the smoke article defines the first part of the air flow route, which extends longitudinally upstream of one or more of the air intakes tertiary, towards the aerosol-forming substrate, and the volume radially connected by the inner part of the hollow tube defines the second part of the air flow route, which extends longitudinally towards the mouth end of the smoke article.
[00122] The air flow guiding element may further comprise an external envelope, which circumscribes the hollow tube and the seal substantially impermeable to annular air.
[00123] In this embodiment, the volume radially connected by the external part of the hollow tube and the internal envelope of the air flow directing element defines the first part of the air flow route, which extends longitudinally upstream of one or more of the inlets of tertiary air in the direction of the aerosol-forming substrate, and the volume radially connected by the inner part of the hollow tube defines the second part of the air flow path, which extends longitudinally downstream of the mouth end of the smoke article.
[00124] The open upstream end of the hollow tube may come into contact with an end downstream of the aerosol-forming substrate. Alternatively, the open downstream end of the hollow tube can be inserted or otherwise extend to the downstream end of the aerosol-forming substrate.
[00125] The air flow directing element may further comprise an annular air-permeable diffuser with a diameter substantially equal to that of the aerosol-forming substrate, which circumscribes at least part of the length of the hollow tube, upstream of the substantially impermeable seal. annular air. For example, the hollow tube can be at least partially embedded in a cellulose acetate tow plug.
[00126] When the air flow directing element further comprises an inner wrap, the inner wrap can circumscribe the hollow tube, the seal substantially impermeable to annular air and the diffuser permeable to annular air.
[00127] In use, when a user pulls on the mouth end of the smoke article, cold air is drawn into the smoke article by one or more of the tertiary air inlets, downstream of the aerosol-forming substrate. The drawn air passes upstream to the aerosol-forming substrate, along the first part of the airflow route between the outer part of the hollow tube and the outer wrap of the smoke article, or inner wrap of the outer wrap. The drawn air passes through the aerosol-forming substrate and then passes downstream along the second part of the air flow route through the inside of the hollow tube, towards the mouth end of the smoke article, for inhalation by the user.
[00128] When the airflow directing element comprises an annular air-permeable diffuser, the pulled air passes through the annular air-permeable diffuser as it passes upstream along the first part of the airflow route, towards the aerosol-forming substrate.
[00129] In another preferred embodiment, the airflow directing element comprises a hollow cone trunk substantially impermeable to air, with an open end, having an upstream end of reduced diameter, compared to that of the aerosol-forming substrate, and a downstream end of diameter substantially equal to that of the aerosol-forming substrate.
[00130] In this embodiment, the volume radially connected by the external part of the hollow cone trunk and an external wrap of the smoke article defines the first part of the air flow route, which extends longitudinally downstream of one or more of the air inlets. tertiary air towards the aerosol-forming substrate, and the volume radially connected by the inner part of the hollow cone trunk defines the second part of the air flow route, which extends longitudinally upstream of the mouth end of the smoke article.
[00131] The open downstream end of the hollow cone trunk can come in contact with an downstream end of the aerosol-forming substrate. Alternatively, the open upstream end of the hollow cone trunk can be inserted or otherwise extend to the downstream end of the aerosol forming substrate.
[00132] The air flow directing element may further comprise an annular air-permeable diffuser of a diameter substantially equal to that of the aerosol-forming substrate, which circumscribes at least a part of the length of the hollow cone trunk. For example, the hollow cone trunk can be at least partially embedded in a cellulose acetate tow buffer.
[00133] In use, when a user pulls on the mouth end of the smoke article, cold air is drawn into the smoke article by one or more of the tertiary air inlets, downstream of the aerosol-forming substrate. The drawn air passes upstream to the aerosol forming substrate, along the first part of the air flow path between the outer wrap of the smoke article and the outer part of the hollow cone trunk of the air flow directing element. The drawn air passes through the aerosol-forming substrate and then passes downstream along the second part of the air flow route through the inside of the hollow tube, towards the mouth end of the smoke article, for inhalation by the user.
[00134] When the airflow directing element comprises an annular air-permeable diffuser, the pulled air passes through the annular air-permeable diffuser as it passes upstream along the first part of the airflow route, towards the aerosol-forming substrate.
[00135] It will be appreciated that the smoking articles according to the invention may comprise one or more of the primary air intakes, between an end downstream of the combustible thermal source and an end upstream of the aerosol-forming substrate, or one or more of the secondary air inlets around the periphery of the aerosol-forming substrate, or one or more of the tertiary air inlets downstream of the aerosol-forming substrate, or any combination thereof.
[00136] Preferably, the fuel thermal source is a carbonaceous thermal source. As used in this specification, the term "carbonaceous" is used to describe a combustible thermal source comprising carbon.
[00137] Preferably, combustible carbonaceous thermal sources, for use in tobacco articles according to the invention, have a carbon content of at least about 35 percent, particularly at least about 40 percent, especially at least about 45 percent dry weight of the fuel thermal source.
[00138] In some embodiments, the combustible thermal sources according to the invention are carbon based combustible thermal sources. As used in this specification, the term "carbon-based fuel source" is used to describe a thermal source, basically comprised of carbon.
[00139] Carbon-based combustible thermal sources, for use in tobacco articles according to the invention, have a carbon content of at least about 50 percent, preferably at least about 60 percent, particularly, at least about 70 percent, especially at least about 80 percent dry weight of the fuel thermal source.
[00140] The smoking articles according to the invention may comprise combustible carbonaceous thermal sources formed from one or more suitable carbon-containing materials.
[00141] If desired, one or more binders can be combined with one or more of the carbon-containing materials. Preferably, the one or more binders are organic binders. Suitable known organic binders include, but are not limited to, gums (e.g., guar gum), modified celluloses and cellulose derivatives (e.g., methylcellulose, carboxymethylcellulose, hydroxypropylcellulose and hydroxypropylmethylcellulose), wheat flour, starches, sugars, oils vegetables and their combinations.
[00142] In a preferred embodiment, the combustible thermal source is formed of a mixture of powdered carbon, modified cellulose, wheat flour and sugar.
[00143] Instead of or in addition to one or more binders, the combustible thermal sources for use in tobacco articles according to the invention may comprise one or more additives, to improve the properties of the combustible thermal source. Suitable additives include, but are not limited to, additives to promote consolidation of the combustible thermal source (for example, sintering aids), additives to promote ignition of the combustible thermal source (for example, oxidants, such as perchlorates, chlorates, nitrates , peroxides, permanganates, zirconium and combinations thereof), additives to promote combustion of the fuel thermal source (for example, potassium and potassium salts, such as potassium citrate), and additives to promote the decomposition of one or more gases produced by combustion from the combustible thermal source (eg catalysts, such as CuO, Fβ2θ3 and AI2O3).
[00144] When the smoking articles according to the invention comprise a first barrier, comprising a first barrier coating on the rear face of the fuel thermal source, these additives can be incorporated into the fuel thermal source, before or after application of the first barrier coating on the rear face of the fuel source.
[00145] In a preferred embodiment, the combustible thermal source is a cylindrical combustible thermal source, comprising carbon and at least one ignition aid, the cylindrical combustible thermal source having a front end face (i.e., the upstream end face) ) and an opposite rear face (that is, the downstream end face), in which at least part of the cylindrical combustible heat source, between the front face and the rear face, is wound in a combustion-resistant winder, and where by ignition of the front face of the cylindrical fuel thermal source, the rear face of the cylindrical fuel thermal source increases in temperature, at a first temperature, and in which, during the subsequent combustion of the cylindrical fuel thermal source, the rear face of the cylindrical fuel thermal source maintains a second temperature, lower than the first temperature.
[00146] As used in this specification, the term "ignition aid" is used to denote a material that releases one or both of energy and oxygen, during ignition of the combustible thermal source, in which the release rate of one or both energy and oxygen, by the material, is not limited by the diffusion of environmental oxygen. In other words, the rate of release of one or both of energy and oxygen by the material, during ignition of the fuel thermal source, is quite independent of the rate at which environmental oxygen can reach the material. As used in this specification, the term "ignition aid" is also used to denote an elementary metal, which releases energy during the ignition of the combustible thermal source, where the ignition temperature of the elemental metal is below about 500 ° C and the combustion heat of the elemental metal is at least about 5 kJ / g.
[00147] As used in this specification, the term "ignition aid" does not include alkali metal salts of carboxylic acids (such as alkali metal citrate salts, alkali metal acetate salts and alkali metal succinate salts) , alkali metal halide salts (such as alkali metal chloride salts), alkali metal carbonate salts or alkali metal phosphate salts, which are believed to modify carbon combustion. Even when present in a high content relative to the total weight of the combustible thermal source, these burnt alkali metal salts do not release enough energy, during ignition from a combustible thermal source, to produce an acceptable aerosol during previous puffs.
[00148] Examples of suitable oxidizing agents include, but are not limited to: nitrates, such as, for example, potassium nitrate, calcium nitrate, strontium nitrate, sodium nitrate, barium nitrate, lithium nitrate, nitrate aluminum and iron nitrate; nitrites; other organic and inorganic nitrogen compounds; chlorates, such as, for example, sodium chlorate and potassium chlorate; perchlorates, such as, for example, sodium perchlorate; chlorites; bromates, such as, for example, sodium bromate and potassium bromate; perbromates; bromites; borates, such as, for example, sodium borate and potassium borate; ferrates, such as, for example, barium ferrate; ferrites; manganates, such as, for example, potassium manganate; permanganates, such as, for example, potassium permanganate; organic peroxides, such as, for example, benzoyl peroxide and acetone peroxide; inorganic peroxides, such as, for example, hydrogen peroxide, strontium peroxide, magnesium peroxide, calcium peroxide, barium peroxide, zinc peroxide and lithium peroxide; superperoxides, such as, for example, potassium superperoxide and sodium superperoxide; iodates; periodates; iodides; sulfates; sulfites; other sulfoxides; phosphates; phosphinates; phosphites; and phosphatites.
[00149] While improving the ignition and combustion properties of the combustible thermal source, the inclusion of ignition and combustion additives can lead to undesirable decomposition and reaction products during the use of the smoke article. For example, the decomposition of nitrates included in the fuel thermal source, to aid in ignition, can result in the formation of nitrogen oxides. The isolation of the combustible thermal source from one or more of the air flow routes, by the smoke article, advantageously prevents or inhibits these decomposition and reaction products from entering the air drawn by the smoke article during its use.
[00150] In addition, the inclusion of oxidants, such as nitrates or other additives, to aid in ignition, can result in the generation of hot gases and high temperatures in the fuel thermal source, during ignition of the fuel thermal source. The isolation of the combustible thermal source from one or more of the air flow routes, by the smoke article, advantageously limits the temperature at which the aerosol-forming substrate is exposed, and thereby helps to prevent or reduce thermal degradation or combustion of the aerosol-forming substrate during ignition of the fuel thermal source.
[00151] Combustible carbonaceous thermal sources for use in tobacco articles, according to the invention, are preferably formed by mixing one or more carbon-containing materials with one or more binders and other additives, when included, and pre - forming the mixture in a desired shape. The mixture of one or more carbon-containing materials, one or more binders and other optional additives can be preformed into a desired shape, using any suitable known ceramic forming processes, such as, for example, slip casting, extrusion, molding by matrix injection and compaction. In certain preferred embodiments, the mixture is preformed to a desired shape by extrusion.
[00152] Preferably, the mixture of one or more materials containing carbon, one or more binders and other additives is preformed on an elongated stick. However, it will be appreciated that the mixture of one or more carbon-containing materials, one or more binders and other additives can be preformed in other desired forms.
[00153] After forming, particularly after extrusion, the elongated rod or other desired elongated shape is preferably dry, to reduce its moisture content and then thermally decomposed in a non-oxidizing atmosphere, at a temperature sufficient to carbonize o one or more binders, when present, and substantially eliminate any volatiles in the elongated stick or other elongated shape. The elongated rod or other elongated form is thermally decomposed in an atmosphere of nitrogen, at a temperature between about 700 ° C and about 900 ° C.
[00154] In one embodiment, at least one metal nitrate salt is incorporated into the combustible thermal source by including at least one metal nitrate precursor in the mixture of one or more carbon-containing materials, one or more binders and other additives. The at least one metal nitrate precursor is then subsequently converted in situ to at least one metal nitrate salt, by treating the elongated cylindrical rod or other elongated form with an aqueous solution of nitric acid. In one embodiment, the combustible thermal source comprises at least one metal nitrate salt, having a thermal decomposition temperature of less than about 600 ° C, particularly less than about 400 ° C. Preferably, the at least one metal nitrate salt has a decomposition temperature between about 150 ° C and about 160 ° C, particularly between about 200 ° C and about 400 ° C.
[00155] In preferred embodiments, exposure of the combustible thermal source to a conventional yellow flame igniter, or to another means of ignition, can cause at least one metal nitrate salt to decompose and release oxygen and energy. This decomposition causes an initial increase in the temperature of the fuel thermal source and also assists in igniting the fuel thermal source. Following the decomposition of at least one metal nitrate salt, the fuel thermal source preferably continues to burn at a lower temperature.
[00156] The inclusion of at least one metal nitrate salt advantageously results in ignition of the fuel thermal source being initiated internally, and not just at a point on its surface. Preferably, the at least one metal nitrate salt is present in the fuel thermal source in a content between about 20 weight percent dry and about 50 weight percent dry fuel source.
[00157] In another embodiment, the fuel thermal source comprises at least one peroxide or superperoxide, which actively releases oxygen at a temperature below about 600 ° C, particularly at a temperature below about 400 ° C.
[00158] Preferably, the at least one peroxide or superperoxide actively releases oxygen at a temperature between about 150 ° C and about 160 ° C, particularly at a temperature between about 200 ° C and about 400 ° C, especially at a temperature of about 350 ° C.
[00159] In use, the exposure of the combustible thermal source to a conventional yellow flame igniter, or to another means of ignition, can cause at least one metallic nitrate salt to decompose and release oxygen and energy. This causes an initial boost in the temperature of the fuel source and also assists in igniting the fuel source. Following the decomposition of at least one metal nitrate salt, the fuel thermal source preferably continues to burn at a lower temperature.
[00160] The inclusion of at least one peroxide or superperoxide advantageously results in the ignition of the fuel thermal source being initiated internally, and not just at a point on its surface.
[00161] The fuel thermal source preferably has a porosity between about 20 percent and about 80 percent, particularly between about 20 percent and 60 percent. When the fuel thermal source comprises at least one metal nitrate salt, it advantageously allows the diffusion of oxygen in the mass of the fuel thermal source at a rate sufficient to maintain combustion, since at least one metal nitrate salt decomposes and combustion proceeds. Still more particularly, the fuel thermal source has a porosity between about 50 percent and about 70 percent, particularly between about 50 percent and about 60 percent, measured, for example, by mercury porosimetry or pycnometry of helium. The necessary porosity can be easily obtained during the production of the fuel thermal source, using conventional processes and technology.
[00162] Advantageously, combustible carbonaceous thermal sources, for use in smoke articles according to the invention, have an apparent density between about 0.6 g / cm3 and about 1 g / cm3.
[00163] Preferably, the fuel thermal source has a mass between about 300 mg and about 500 mg, particularly between about 400 mg and about 450 mg.
[00164] Preferably, the fuel thermal source is between about 7 mm and about 17 mm in length, particularly between about 7 mm and about 15 mm, especially between about 7 mm and about 13 mm.
[00165] Preferably, the fuel source has a diameter between about 5 mm and about 9 mm, particularly between about 7 mm and about 8 mm.
[00166] Preferably, the fuel thermal source is of a substantially uniform diameter. However, the fuel source can alternatively be tapered, so that the diameter of the rear part of the fuel source is greater than the diameter of its front part. Particularly preferred combustible thermal sources are those that are substantially cylindrical. The fuel thermal source can be, for example, a cylinder or a tapered cylinder of a substantially circular cross section, or a cylinder or a tapered cylinder of a substantially elliptical cross section.
[00167] The tobacco articles according to the invention preferably comprise an aerosol forming substrate, which comprises at least one aerosol former. In such embodiments, the isolation of the combustible thermal source from the aerosol forming substrate advantageously prevents or inhibits the migration of at least one aerosol former from the aerosol forming substrate to the combustible thermal source, during storage of the smoke articles. In such embodiments, the isolation of the combustible thermal source from one or more of the air flow routes may also advantageously prevent or inhibit the migration of at least one aerosol former from the aerosol former to the combustible thermal source, during use of the articles. smoke. The decomposition of the at least one riser tube, during use of the smoking articles, is thus substantially avoided or reduced.
[00168] The at least one aerosol former can be any suitable known compound, or a mixture thereof, which, in use, facilitates the formation of a dense and stable aerosol and which is substantially resistant to thermal degradation, at the operating temperature of the smoking article. Suitable aerosol builders are well known in the art and include, for example, polyhydric alcohols, polyhydric alcohol esters, such as glycerol mono-, di- and triacetate, and aliphatic esters of mono-, di- and polycarboxylic acids, such such as dimethyl dodecanedioate and dimethyl tetradecanedioate. The preferred aerosol builders, for use in tobacco articles according to the invention, are polyhydric alcohols, or mixtures thereof, such as triethylene glycol, 1,3-butanediol and, particularly, glycerin.
[00169] The combustible thermal source and the aerosol forming substrate of smoke articles according to the invention can substantially come into contact with each other. Alternatively, the combustible thermal source and the aerosol-forming substrate of smoke articles according to the invention can be spaced longitudinally between them.
[00170] Preferably, the smoke articles according to the invention further comprise a heat conducting element, around and in direct contact with a rear part of the combustible thermal source and an adjacent front part of the aerosol-forming substrate. The heat conducting element is preferably resistant to combustion and oxygen limiting.
[00171] The heat conducting element is around and in direct contact with the peripheries of both the rear of the fuel thermal source and the front of the aerosol-forming substrate. The heat conducting element provides a thermal connection between these two components of tobacco articles according to the invention.
[00172] Suitable heat conducting elements for use in smoke articles according to the invention include, but are not limited to: foil wrappers, such as, for example, aluminum foil wrappers, steel wrappers , wraps of iron sheets and wraps of copper sheets; and metal alloy sheet wraps.
[00173] Preferably, the rear part of the fuel thermal source, surrounded by the heat conducting element, is between 2 mm and 8 mm long, particularly between 3 mm and 5 mm in length .
[00174] Preferably, the front part of the fuel thermal source not surrounded by the heat conducting element is between about 4 mm and about 15 mm in length, particularly between about 4 mm and about 8 mm in length.
[00175] Preferably, the aerosol forming substrate is between about 5 mm and about 20 mm in length, particularly between about 8 mm and about 12 mm.
[00176] In certain preferred embodiments, the aerosol-forming substrate extends at least about 3 mm downstream beyond the heat conducting element.
[00177] Preferably, the front part of the aerosol-forming substrate, surrounded by the heat conducting element, is between 2 mm and 10 mm long, particularly between 3 mm and 8 mm in length. especially between about 4 mm and about 6 mm in length. Preferably, the rear part of the aerosol forming substrate, not surrounded by the heat conducting element, is between about 3 mm and about 10 mm in length. In other words, the aerosol-forming substrate preferably extends between about 3 mm and about 10 mm downstream beyond the heat conducting element. In particular, the aerosol-forming substrate extends at least about 4 mm downstream beyond the heat conducting element.
[00178] In other embodiments, the aerosol-forming substrate may extend less than 3 mm downstream beyond the heat-conducting element.
[00179] In more other embodiments, the entire length of the aerosol-forming substrate can be surrounded by the heat conducting element.
[00180] Preferably, the tobacco articles according to the invention comprise aerosol forming substrates, comprising at least one aerosol former and a material capable of emitting volatile compounds in response to heating. Preferably, the material capable of emitting volatile compounds in response to heating is a charge of plant material, particularly a charge of homogenized plant material. For example, the aerosol-forming substrate may comprise one or more plant-derived materials, including, but not limited to: smoke; tea, for example, green tea; pepper mint; blond; eucalyptus; basil; saves; verbena; and tarragon. The plant material may comprise additives, including, but not limited to, humectants, flavors, binders and mixtures thereof. Preferably, the plant material essentially consists of smoke material, particularly, homogenized smoke material.
[00181] The tobacco articles according to the invention preferably further comprise an expansion chamber, downstream of the aerosol-forming substrate, and, when present, downstream of the airflow directing element. The inclusion of an expansion chamber advantageously allows additional cooling of the aerosol generated by the thermal transfer from the fuel thermal source to the aerosol-forming substrate. The expansion chamber can also advantageously allow the total length of the tobacco articles according to the invention to be adjusted to a desired value, for example, to a length similar to that of conventional cigarettes, by means of the appropriate selection of the length of the smoking chamber. expansion. Preferably, the expansion chamber is an elongated hollow tube.
[00182] The tobacco articles according to the invention may also comprise a nozzle, downstream of the aerosol-forming substrate, and, when present, downstream of the airflow directing element and the expansion chamber. Preferably, the nozzle has a low filtration efficiency, particularly a very low filtration efficiency. The nozzle can be a single segment or component.
[00183] The nozzle may comprise, for example, a filter made of cellulose acetate, paper or other suitable known filter materials. Alternatively or additionally, the nozzle may comprise one or more segments comprising absorbents, adsorbents, flavorings and other aerosol modifiers and additives, or combinations thereof.
[00184] The features described in relation to one aspect of the invention can also be applicable to other aspects of the invention. In particular, the characteristics described in relation to articles of smoke and combustible thermal sources, according to the invention, can also be applicable to the processes according to the invention.
[00185] The invention will be described further, only by way of example, with reference to the attached drawings, in which:
[00186] Figure 1a) shows a detailed view of a smoke article, according to a first embodiment of the invention, comprising a non-blind combustible thermal source;
[00187] Figure 1b) shows a detailed view of a smoke article, according to a second embodiment of the invention, comprising a non-blind combustible thermal source;
[00188] Figure 1c) shows a detailed view of a smoke article, according to a third embodiment of the invention, comprising a non-blind combustible thermal source;
[00189] Figure 1d) shows a detailed view of a smoking article, according to a fourth embodiment of the invention, comprising a blind combustible thermal source;
[00190] Figure 2 shows a schematic longitudinal cross section of the smoking article, according to the first embodiment of the invention shown in Figure 1a);
[00191] Figure 3 shows a schematic longitudinal cross-section of a smoking article, according to a sixth embodiment of the invention, comprising a blind combustible thermal source; and
[00192] Figure 4 shows a schematic longitudinal cross section of a smoke article, according to a seventh embodiment of the invention, comprising a blind fuel thermal source.
[00193] Smoke article 2, according to the first embodiment of the invention, shown in Figures 1a) and 2, comprises a combustible carbonaceous thermal source 4, an aerosol forming substrate 6, an elongated expansion chamber 8 and a nozzle 10 in contact coaxial alignment. The combustible carbonaceous thermal source 4, the aerosol-forming substrate 6, the elongated expansion chamber 8 and the nozzle 10 are super-wrapped in an outer wrapper of cigarette paper 12 of low air permeability.
[00194] As shown in Figure 2, a substantially air-impermeable, non-combustible first barrier coating 14 is provided across the rear face of the combustible carbonaceous thermal source 4.
[00195] The carbonaceous thermal heat source 4 comprises a central airflow channel 16, which extends longitudinally through the carbonaceous thermal heat source 4 and a substantially impermeable, non-combustible first barrier coating 14. A substantially impermeable second barrier coating non-combustible air 18 is provided over the entire internal surface of the central air flow channel 16.
[00196] The aerosol-forming substrate 6 is located immediately downstream of the rear face of the fuel carbonaceous thermal source 4 and comprises a cylindrical plug 20 of smoke material, comprising glycerin as an aerosol former and circumscribed by the filter cap wrap 22 .
[00197] A heat conducting element 24, consisting of an aluminum foil tube, surrounds and is in direct contact with a rear part 4b of the combustible carbonaceous thermal source 4 and a front part in contact 6a of the aerosol-forming substrate 6. As shown in Figure 2, a rear part of the aerosol forming substrate 6 is not surrounded by the heat conducting element 24.
[00198] The elongated expansion chamber 8 is located downstream of the aerosol forming substrate 6 and comprises a hollow cylindrical open end tube 26 of cardboard, which is substantially the same diameter as the aerosol forming substrate 6. The nozzle 10 of the article smoke screen 2 is located downstream of the expansion chamber 8 and comprises a cylindrical plug 28 of cellulose acetate tow of a very low filtration efficiency, circumscribed by the filter plug wrap 30. The nozzle 10 can be circumscribed by forming paper edge (not shown).
[00199] In use, the user turns on the carbonaceous thermal heat source 4 and then pulls on the nozzle 10, to draw air downstream through the central airflow channel 16 of the carbonaceous thermal source 4. The front part 6a of the forming substrate aerosol 6 is heated basically by conduction by the contacting rear part 4b of the carbonaceous thermal heat source 4 and by the heat conducting element 24. The drawn air is heated as it passes through the central airflow channel 16 of the carbonaceous thermal heat source 4 and then heat the aerosol forming substrate 6 by convection. Heating of the aerosol-forming substrate 6, by conduction and convection, releases volatile and semi-volatile compounds and the glycerin from the smoke material buffer 20, which are carried in the heated drawn air as it flows through the aerosol-forming substrate 6. The heated air and the carried compounds pass downstream through the expansion chamber 8, cool and condense, to form an aerosol, which passes through the nozzle 10 to the user's mouth.
[00200] The air flow route through the smoke article 2, according to the first embodiment of the invention, is illustrated by the dotted arrow in Figure 1a). The non-combustible, substantially impermeable first barrier coating 14 provided on the rear face of the combustible carbonaceous thermal source 4, and the substantially non-combustible, substantially air-impermeable second barrier coating 18 provided in the central airflow channel 16, isolate the combustible carbonaceous thermal source 4 of the airflow route, so that, in use, the air drawn by the smoke article 2, along the airflow route, does not come into direct contact with the combustible carbonaceous thermal source 4.
[00201] The smoking articles, according to the first embodiment of the invention, shown in Figures 1a) and 2, having the dimensions shown in Table 1, were assembled using combustible carbonaceous thermal sources, produced according to Examples 1 and 6 below.

TABLE 1
[00202] The smoking article 32, according to the second embodiment of the invention, shown in Figure 1b) is of a construction quite identical to the smoking article, according to the first embodiment of the invention, shown in Figures 1a) and 2 However, the smoke article 32, according to the second embodiment of the invention, the combustible carbonaceous heat source 4 and the aerosol forming substrate 6 are spaced apart, along the length of the smoke article. A circumferential arrangement of primary air inlets is provided on the cigarette paper 12 and the heat conducting element 24 between the downstream end of the combustible carbonaceous thermal source 4 and the downstream end of the aerosol forming substrate 6, to admit wire air in the space between the fuel carbonaceous thermal source 4 and the aerosol-forming substrate 6.
[00203] In use, when a user pulls on the nozzle 10 of the smoke article 32, according to the second embodiment of the invention, the air is drawn downstream by the central airflow channel 16 of the combustible carbonaceous thermal source 4, and the air is also drawn into the space between the fuel carbonaceous thermal source 4 and the aerosol-forming substrate 6 through the primary air inlet channels in the cigarette paper 12 and in the heat conducting element 24. The cold air mixture, drawn through the inlets of primary air, with the heated air drawn by the central airflow channel 16 of the carbonaceous thermal fuel source 4, reduces the temperature of the air drawn by the aerosol-forming substrate 6 of the smoke article 32, according to the second embodiment of invention, during smoking by a user.
[00204] The air flow routes through the smoke article 32, according to the second embodiment of the invention, are illustrated by dotted arrows in Figure 1b). The substantially air-resistant, non-combustible first barrier coating 14 provided on the rear face of the combustible carbonaceous thermal source and the substantially non-combustible air-resistant second barrier coating 18 provided on the inner surface of the central airflow channel 16, isolate the combustible carbonaceous thermal source 4 from the air flow routes, so that, in use, the air drawn by the smoke article 32, along the air flow route, does not come into direct contact with the thermal source combustible carbonaceous 4.
[00205] The smoking article 34, according to the third embodiment of the invention, shown in Figure 1c), is also of construction quite identical to that of the smoking article according to the first embodiment of the invention, shown in Figures 1a) and 2. However, in the smoke article 34, according to the third embodiment of the invention, a circumferential arrangement of secondary air inlets is provided in the cigarette paper 12 and in the filter plug wrap 22 circumscribing the aerosol-forming substrate 6 , to admit cold air in the aerosol-forming substrate 6.
[00206] In use when a user pulls on the nozzle 10 of the smoke article 34, according to the third embodiment of the invention, the air is pulled downstream by the central air flow channel 16 of the carbonaceous thermal heat source 4, and air it is also pulled into the aerosol-forming substrate 6 by the secondary air inlets in the cigarette paper 12 and in the filter buffer wrap 22. Cold air, drawn in by the secondary air inlets, reduces the temperature of the aerosol-forming substrate 6 of the smoking article 34, according to the third embodiment of the invention, during smoking by a user.
[00207] The air flow routes through the smoke article 34, according to the third embodiment of the invention, are illustrated by the dotted arrows in Figure 1c). The substantially non-combustible, substantially air-impermeable first barrier coating 14 provided on the rear face of the combustible carbonaceous thermal source 4, and the substantially non-combustible, substantially air-impermeable second barrier coating 18 provided on the inner surface of the airflow channel. central 16, isolate the fuel carbonaceous thermal source 4 from the air flow routes, so that, in use, the air drawn by the smoke article 34, along the air flow routes, does not come into direct contact with the source carbonaceous thermal fuel 4.
[00208] The smoking articles 36, 38, according to the fourth and fifth embodiments of the invention, shown in Figure 1d) and 1e), are of construction quite identical to the smoking articles, according to the second and third embodiments of invention, shown in Figures 1b) and 1c), respectively, and can be mounted analogously. However, smoke articles 36, 38, according to the fourth and fifth embodiments of the invention, comprise combustible carbonaceous thermal sources 40, which do not comprise a central air flow channel 16. A first barrier coating substantially impermeable to air , incombustible 14 is provided across the rear face of the combustible carbonaceous thermal sources 40 of the smoking articles 36, 38, according to the fourth and fifth embodiments of the invention.
[00209] In use, when a user pulls on the nozzle 10 of the smoking articles 36, 38, according to the fourth and fifth embodiments of the invention, no air is pulled by the combustible carbonaceous thermal sources 40. Consequently, the aerosol forming substrate 6 is heated exclusively by driving from the rear in contact 4b of the combustible carbonaceous thermal source 40 and the heat conducting element 24.
[00210] The air flow routes through the smoking articles 36, 38, according to the fourth and fifth embodiments of the invention, are illustrated by the dotted arrows in Figures 1d) and 1e). The substantially air-impermeable, non-combustible first barrier coating 14 provided across the rear face of the combustible carbonaceous thermal sources 40 of the smoking articles 36, 38, in accordance with the fourth and fifth embodiments of the invention, isolates the combustible carbonaceous thermal sources 40 airflow routes, so that, in use, the air drawn by the smoke articles 36, 38, along the airflow routes, does not come into direct contact with combustible carbonaceous thermal sources 40.
[00211] Smoke article 42, according to the sixth embodiment of the invention, shown in Figure 3, comprises a combustible carbonaceous thermal source 40, an aerosol-forming substrate 6, an air flow directing element 44, an air chamber elongated expansion 8 and a nozzle 10 in coaxial contact alignment. The combustible carbonaceous thermal source 40, the aerosol forming substrate 6, the airflow directing element 44, the elongated expansion chamber 8 and the nozzle 10 are super-wrapped in an outer wrapper of low permeability cigarette paper 12 air.
[00212] As shown in Figure 3, a substantially air-impermeable, non-combustible first barrier coating 14 is provided across the rear face of the combustible carbonaceous thermal source 40.
[00213] The aerosol-forming substrate 6 is located immediately downstream of the rear face of the fuel carbonaceous thermal source 40 and comprises a cylindrical plug 20 of smoke material, comprising glycerin as an aerosol former and circumscribed by the filter cap wrap 22 .
[00214] A heat conducting element 24, consisting of an aluminum foil tube, surrounds and is in direct contact with a rear part 4b of the combustible carbonaceous thermal source 40 and a front part in contact 6a of the aerosol forming substrate 6. As shown in Figure 3, a rear part of the aerosol forming substrate 6 is not surrounded by the heat conducting element 24.
[00215] The air flow directing element 44 is located downstream of the aerosol-forming substrate 6 and comprises a hollow cone trunk substantially impermeable to air, with an open end 46 made of, for example, cardboard. The downstream end of the open-ended hollow cone trunk 46 is substantially the same diameter as that of the aerosol-forming substrate 6, and the upstream end of the open-ended hollow cone trunk 46 is of a reduced diameter compared to that of the aerosol-forming substrate 6.
[00216] The upstream end of the open-ended hollow cone trunk 46 comes into contact with the aerosol-forming substrate 6 and is embedded in an air-permeable cylindrical plug 48 of cellulose acetate tow, circumscribed by the wrapper cap. filter 50, which is substantially the same diameter as that of the aerosol forming substrate 6. It will be considered that in alternative embodiments (not shown), the upstream end of the open-ended hollow cone trunk 46 may extend towards the rear of the aerosol-forming substrate 6. It will also be considered that, in alternative embodiments (not shown), the cylindrical plug 48 of cellulose acetate tow may be omitted.
[00217] As shown in Figure 3, the part of the open-ended hollow cone trunk 46, which is not embedded in the cylindrical plug 48 of cellulose acetate tow, is circumscribed by an inner wrap 52 of low air permeability, made of, for example, cardboard. It will be considered that, in alternative embodiments (not shown), the inner wrap 52 can be omitted.
[00218] As also shown in Figure 3, a circumferential arrangement of tertiary air intakes 54 is provided in the outer wrapper 12 and the inner wrapper 52, circumscribing the hollow cone trunk of the open end 46 of the cylindrical plug 48 of the acetate tow cellulose.
[00219] The elongated expansion chamber 8 is located downstream of the airflow directing element 44 and comprises an open-ended hollow tube 26, made of, for example, cardboard, which is substantially the same diameter as that of the substrate aerosol former 6. The nozzle 10 of the smoke article 42 is located downstream of the expansion chamber 8 and comprises a cylindrical plug 28 of cellulose acetate tow of very low filtration efficiency, circumscribed by the filter plug wrap 30. The nozzle 10 can be circumscribed by tip forming paper (not shown).
[00220] The smoking article 42, according to the sixth embodiment of the invention, comprises an air flow path extending between the tertiary air intakes 54 and the mouth end of the smoking article 42. The volume connected by the the outer part of the open-ended hollow cone trunk 46 and the inner casing 52 forms a first part of the air flow path between the tertiary air intakes 54 and the aerosol-forming substrate 6, and the volume bound from the inside of the open-ended hollow cone trunk 46 forms a second part of the air flow path between the aerosol forming substrate 6 and the expansion chamber 8.
[00221] In use, when a user pulls on the nozzle 10, the cold air is drawn into the smoke article 42, according to the sixth embodiment of the invention, through the tertiary air intakes 54. The drawn air passes upstream to the substrate aerosol former 6, along the first part of the air flow path, between the outside of the open-ended hollow cone trunk 46 and the inner casing 52 and by the cylindrical plug 48 of cellulose acetate tow.
[00222] The front part 6a of the aerosol-forming substrate 6 is heated by conduction by the back in contact 4b of the fuel carbonaceous thermal source 40 and of the heat conducting element 24. Heating of the aerosol-forming substrate 6 releases volatile and semi-volatile compounds and the glycerin of the smoke material buffer 20, which is carried in the drawn air, as it flows through the aerosol-forming substrate 6. The drawn air and the carried compounds pass downstream, along the second part of the flow path. of air through the inner part of the open-ended hollow cone trunk 46 to the expansion chamber 8, in which they cool and condense, to form an aerosol, which passes through the nozzle 10 to the user's mouth.
[00223] The substantially air-impermeable, non-combustible first barrier coating 14 provided on the rear face of the combustible carbonaceous thermal source 40, isolates the combustible carbonaceous thermal source 40 from the airflow route by the smoke article 42, so that, in use, the air drawn by the smoke article 42, along the first part of the air flow route and the second part of the air flow route, does not come into direct contact with the combustible carbonaceous thermal source 40.
[00224] Smoke article 56, according to the seventh embodiment of the invention, shown in Figure 4, also comprises a combustible carbonaceous thermal source 40, an aerosol-forming substrate 6, an airflow directing element 44, a chamber of elongated expansion 8 and a nozzle 10 in contact coaxial alignment. The combustible carbonaceous thermal source 40, the aerosol forming substrate 6, the airflow directing element 44, the elongated expansion chamber 8 and the nozzle 10 are super-wrapped in an outer wrapper of low permeability cigarette paper 12 air.
[00225] As shown in Figure 4, a substantially air-impermeable, non-combustible first barrier coating 14 is provided across the rear face of the combustible carbonaceous thermal source 40.
[00226] The aerosol-forming substrate 6 is located immediately downstream of the rear face of the fuel carbonaceous thermal source 40 and comprises a cylindrical plug 20 of smoke material, comprising glycerin as an aerosol former and circumscribed by the filter cap wrap 22 .
[00227] A heat conducting element 24, consisting of an aluminum foil tube, surrounds and is in direct contact with a rear part 4b of the combustible carbonaceous thermal source 40 and a front part in contact 6a of the aerosol forming substrate 6. As shown in Figure 4, a rear part of the aerosol forming substrate 6 is not surrounded by the heat conducting element 24.
[00228] The airflow directing element 44 is located downstream of the aerosol forming substrate 6 and comprises a hollow tube substantially impermeable to air, open end 58 made of, for example, cardboard, which is of a reduced size compared with that of the aerosol forming substrate 6. The downstream end of the open-ended hollow tube 58 comes in contact with the aerosol-forming substrate 6. The downstream end of the open-ended hollow tube 58 is surrounded by an air-tight seal substantially annular 60 in diameter substantially equal to that of the aerosol-forming substrate 6. The remainder of the hollow open-ended tube 58 is embedded in an air-permeable cylindrical plug 62 of cellulose acetate tow of substantially the same diameter as that of the aerosol-forming substrate 6.
[00229] The hollow tube with open end 58 and the cylindrical plug 62 of cellulose acetate tow are circumscribed by an internal air-permeable wrap 64.
[00230] As also shown in Figure 4, a circumferential arrangement of tertiary air intakes 54 is provided in the outer shell 12, circumscribing the inner shell 64.
[00231] The elongated expansion chamber 8 is located downstream of the airflow directing element 44 and comprises an open-ended hollow tube 26, made of, for example, cardboard, which is substantially the same diameter as that of the substrate aerosol former 6. The nozzle 10 of the smoke article 56 is located downstream of the expansion chamber 8 and comprises a cylindrical plug 28 of cellulose acetate tow of very low filtration efficiency, circumscribed by the filter plug wrap 30. The nozzle 10 can be circumscribed by tip forming paper (not shown).
[00232] The smoking article 56, according to the seventh embodiment of the invention, comprises an air flow path extending between the tertiary air intakes 54 and the mouth end of the smoking article 56. The volume bound by the the outer part of the open-ended hollow tube 58 and the inner casing 64 forms a first part of the air flow path between the tertiary air intakes 54 and the aerosol-forming substrate 6, and the volume bound by the inner part of the hollow tube open-ended 58 forms a second part of the air flow path between the aerosol forming substrate 6 and the expansion chamber 8.
[00233] In use, when a user pulls on the nozzle 10, cold air is drawn on the smoke article 56, according to the seventh embodiment of the invention, through the tertiary air intakes 54 and internal air-permeable envelope 64. The air pulled upstream to the aerosol-forming substrate 6, along the first part of the airflow route, between the outside of the open-ended hollow tube 58 and the inner envelope 64 and through the cylindrical plug 62 of acetate tow cellulose.
[00234] The front part 6a of the aerosol-forming substrate 6 is heated by conduction by the back in contact 4b of the fuel carbonaceous thermal source 40 and of the heat conducting element 24. Heating of the aerosol-forming substrate 6 releases volatile and semi-volatile compounds and the glycerin of the smoke material buffer 20, which is carried in the drawn air, as it flows through the aerosol-forming substrate 6. The drawn air and the carried compounds pass downstream, along the second part of the flow path. of air through the inner part of the open-ended hollow tube 58 to the expansion chamber 8, in which they cool and condense, to form an aerosol, which passes through the nozzle 10 to the user's mouth.
[00235] The substantially non-combustible 14 substantially impermeable air barrier coating provided on the rear face of the combustible carbonaceous thermal source 40, isolates the combustible carbonaceous thermal source 40 from the air flow route through the smoke article 56, so that, in use, the air drawn by the smoke article 56, along the first part of the airflow route and the second part of the airflow route, does not come into direct contact with the combustible carbonaceous thermal source 40.
[00236] The smoking articles, according to the sixth and seventh embodiments of the invention, shown in Figures 3 and 4, having the dimensions shown in Table 2, were assembled using combustible carbonaceous thermal sources, produced according to the Examples 1 and 6 shown below, but without any longitudinal airflow channels.

TABLE 2 EXAMPLE 1 - Preparation of combustible thermal source
[00237] Cylindrical combustible carbonaceous thermal sources, for use in smoke articles according to the invention, can be prepared as described in international patent application WO- 2009/074870 A2, or in any prior art, which is known to those skilled in the art in the technique. An aqueous paste, as described in international patent application WO-2009/074870 A2, is extruded by means of a die, having a central die orifice of circular cross section, to produce the combustible thermal source. The matrix hole has a diameter of 8.7 mm, so as to form cylindrical rods, having a length between about 20 cm and about 22 cm and a diameter between about 9.1 cm and about 9.2 mm . A single longitudinal airflow channel is formed on the cylindrical rods by a mandrel mounted in the central part of the die hole. The mandrel preferably has a circular cross section with an outside diameter of approximately 2 mm, or approximately 3.4 mm. Alternatively, three airflow channels are formed on the cylindrical rods using three circular cross-section mandrels, with an outside diameter of approximately 2 mm, mounted at uniform angles in the die hole. During the extrusion of cylindrical rods, a clay-based coating paste (made using clay, such as natural green clay) is pumped through a feed passage, extending through the center of the mandrel or mandrels, to form a coating second fine barrier of about 150 microns to about 300 microns on the inner surface of the channel or airflow channels. The cylindrical rods are dried at a temperature of about 20 ° C to about 25 ° C, from about 40% to about 50% relative humidity, for approximately 12 hours to approximately 72 hours, and then thermally decomposed, in a nitrogen atmosphere, at about 750 ° C for approximately 240 minutes. After pyrolysis, the cylindrical rods are cut and shaped to a defined diameter, using a grinding machine, to form individual combustible carbonaceous thermal sources. The sticks, after cutting and molding, have a length of about 11 mm, a diameter of about 7.8 mm and a dry mass of about 400 mg. The individual combustible carbonaceous thermal sources are subsequently dried at about 130 ° C for approximately 1 hour. EXAMPLE 2 - Coating of carbonaceous thermal source with bentonite / kaolinite
[00238] A substantially air-impermeable, non-combustible bentonite / kaolinite first barrier coating is provided on the rear face of a combustible carbonaceous thermal source, prepared as described in Example 1 by dipping, brushing or spray coating. Immersion involves inserting the back face of the combustible carbonaceous thermal source in a concentrated solution of bentonite / kaolinite. The bentonite / kaolinite solution for immersion contains 3.8% bentonite, 12.5% kaolinite and 83.7% H2O [m / m]. The rear face of the combustible carbonaceous thermal source is immersed in the bentonite / kaolinite solution for about 1 second, and the meniscus left to disappear as a result of the solution penetrating into the carbon pores on the surface of the rear face of the combustible carbonaceous thermal source. Brushing involves immersing a brush in a concentrated bentonite / kaolinite solution and applying the concentrated bentonite / kaolinite solution on the brush on the surface of the rear face of the combustible carbonaceous thermal source, until it is covered. The bentonite / kaolinite solution for brushing contains 3.8% bentonite, 12.5% kaolinite and 83.7% H2O [m / m].
[00239] After applying a first barrier coating substantially impermeable to air, incombustible by immersion or brushing, the combustible carbonaceous thermal source is dried in an oven at about 130 ° C for approximately 30 minutes and placed in a desiccator, at about 5% relative humidity, overnight.
[00240] The spray coating involves a suspension solution, preferably containing 3.6% bentonite, 18.0% kaolinite and 78.4% H2O [m / m], and having a viscosity around 50 mPa.sa a shear rate of about 100 s1, measured with a rheometer (Physica MCR 300, coaxial cylinder arrangement). The spray coating with a Sata MiniJet 3000 spray gun, using 0.5 mm, 0.8 mm or 1 mm spray nozzles on an SMC E-MY2B linear actuator, at a speed of about 10 mm / about 100 mm / s. The following spray parameters are used: sample distance - gun -15 cm; sample speed -10 mm / s; spray nozzle - 0.5 mm; and spray pressure with a uniform spray jet - 2.5 bar. In a single spray coating event, a coating thickness of about 11 microns is typically obtained. Sprinkling is repeated three times. Between each spray coating, the combustible carbonaceous thermal source is dried at room temperature for approximately 10 minutes. After applying the substantially air-impermeable, non-combustible first barrier coating, the combustible carbonaceous thermal source is thermally decomposed at about 700 ° C for approximately 1 hour. EXAMPLE 3 - Coating of thermal fuel source with sintered glass
[00241] A substantially air-impermeable, non-combustible glass first barrier coating is provided on the rear face of a combustible carbonaceous thermal source, prepared as described in Example 1, by spray coating. The glass spray coating is done with a suspension of ground glass, using a fine powder of the same. For example, a spray coating suspension containing 37.5% powdered glass (3 pm), 2.5% methylcellulose and 60% water, with a viscosity of 120 mPa.s, or 37.5% powdered glass (3 pm), 3.0% powdered bentonite and 59.5% water, with a viscosity of 60-100 mPa.s, is used. Powdered glass, having the compositions and physical properties corresponding to Glasses 1, 2, 3, and 4 in Table 3, can be used.
[00242] The spray coating is made with a Sata MiniJet 3000 spray gun, or using 0.5 mm, 0.8 mm or 1 mm spray nozzles on an SMC E-MY2B linear actuator, at a speed of about 10 mm / s to about 100 mm / s. The spraying is preferably repeated several times. After the sprinkling is completed, the combustible carbonaceous thermal source is thermally decomposed at about 700 ° C for approximately 1 hour.
TABLE 3: Glass composition in percentage by weight, transformation temperature Tg, thermal expansion coefficient A20- 300 and Kl value calculated from the composition. EXAMPLE 4 - Coating of thermal fuel source with aluminum
[00243] A substantially air-resistant, non-combustible aluminum first barrier coating is provided on the rear face of a combustible carbonaceous thermal source, prepared as described in Example 1 by laser cutting an aluminum barrier from aluminum coil strips, having a thickness of about 20 microns. The aluminum barrier has a diameter of about 7.8 mm and a single hole, having an outside diameter of about 1.8 mm, in its center, to replicate the cross section of the fuel carbonaceous thermal source of Example 1. In an alternative embodiment, the aluminum barrier has three holes, which are positioned to be aligned with the air flow channels provided in the combustible carbonaceous thermal source. The aluminum barrier coating is formed by fixing the aluminum barrier on the rear face of the combustible carbonaceous thermal source using any suitable adhesive. EXAMPLE 5 - Methods for measuring smoke compounds Conditions for smoke production
[00244] The conditions for smoking and the specifications for a smoking machine are presented in the ISO 3308 standard (ISO 3308: 2000). The atmospheres for conditioning and testing are presented in the ISO 3402 standard. Phenols are retained using Cambridge filter pads. Quantitative determination of carbonyls in aerosols, including formaldehyde, acrolein, acetaldehyde and propionaldehyde, is done by UPLC-MSMS. The quantitative measurement of phenolic substances, such as catechol, hydroquinone and phenol, is done by LC fluorescence. Carbon monoxide in smoke is retained by using gas sampling bags, by using a non-dispersive infrared analyzer, as shown in the ISO 8454 standard (ISO 8454: 2007). Smoking regimes
[00245] Cigarettes tested according to the Health Canada smoking regimen are smoked over 12 puffs, with a puff volume of 55 mL, a puff duration of 2 seconds and an interval between puffs of 30 seconds. The cigarettes tested under an intense smoke regime are smoked over 20 puffs, with a puff volume of 80 mL, a puff duration of 3.5 seconds and an interval between puffs of 23 seconds. EXAMPLE 6 - Preparation of combustible thermal source with ignition aid
[00246] A combustible carbonaceous thermal source comprising an ignition aid is prepared by mixing 525 g of powdered coal, 225 of calcium carbonate (CaCOs), 51.75 g of potassium citrate, 84 g of modified cellulose, 276 g of wheat flour, 141.75 sugar and 21 g of corn oil with 579 g of deionized water, to form an aqueous paste, essentially as described in international patent application WO-2009/074870 A2. The aqueous paste is then extruded by a die having a central die hole of circular cross section, with a diameter of about 8.7 mm, to form cylindrical rods having a length between about 20 cm and about 22 cm, and a diameter between about 9.1 mm and about 9.2 mm. A single longitudinal airflow channel is formed on the cylindrical rods by a mandrel, mounted in the central part of the die orifice. The mandrel has a circular cross section, with an outside diameter of approximately 2 mm or approximately 3.5 mm. Alternatively, three airflow channels are formed on the cylindrical rods using three circular cross-section mandrels, with an outside diameter of approximately 2 mm, mounted at uniform angles in the die hole. During extrusion of the cylindrical rods, a coating paste based on green clay is pumped through a feed passage, which extends through the center of the mandrel, to form a thin second barrier coating, having a thickness between about 150 microns and about 300 microns, on the inner surface of the single longitudinal airflow channel. The cylindrical rods are dried between about 20 ° C and about 25 ° C, at a relative humidity of about 40% to about 50%, for between approximately 12 hours and approximately 72 hours, and then thermally decomposed in an atmosphere nitrogen, at about 750 ° C for approximately 240 minutes. After pyrolysis, the cylindrical rods are cut and shaped to a defined diameter, using a grinding machine, to form individual combustible carbonaceous thermal sources, having a length of about 11 mm, a diameter of about 7.8 mm and a mass about 400 mg. The individual combustible carbonaceous thermal sources are dried at approximately 130 ° C for approximately 1 hour and then placed in an aqueous solution of nitric acid, having a concentration of 38 weight percent and saturated with potassium nitrate (KNO3). After approximately 5 minutes, the individual combustible carbonaceous thermal sources are removed from the solution and dried at approximately 130 ° C for approximately 1 hour. After drying, the individual combustible carbonaceous thermal sources are again placed in an aqueous solution of nitric acid, having a concentration of 38 weight percent and saturated with potassium nitrate (KNO3). After approximately 5 minutes, the individual combustible carbonaceous thermal sources are removed from the solution and dried at approximately 130 ° C for approximately 1 hour, followed by drying at approximately 160 ° C for approximately 1 hour, and finally drying at approximately 200 ° C for approximately 1 hour. EXAMPLE 7 - Smoke compounds from smoke articles with combustible thermal sources with a first barrier coating substantially impermeable to air, non-combustible from clay or glass
[00247] Cylindrical combustible carbonaceous thermal sources comprising an ignition aid are prepared as described in Example 6, with a single longitudinal airflow channel, having a diameter of 1.85 mm, and a bentonite / second barrier coating kaolinite. Cylindrical combustible carbonaceous thermal sources are provided with a substantially air-impermeable, non-combustible clay first barrier coating, as described in Example 2. In addition, combustible carbonaceous thermal sources comprising an ignition aid, as described in Example 6, with a single longitudinal airflow channel, having a diameter of 1.85 mm, and a second barrier coating are provided with a substantially air-impermeable, non-combustible sintered glass first barrier coating, as described in Example 3. In both in all cases, the length of cylindrical combustible carbonaceous thermal sources is 11 mm. The substantially air-resistant, non-combustible clay first barrier coating has a thickness of between about 50 microns and about 100 microns, and the substantially air-resistant, non-combustible glass first barrier coating has a thickness of about 20 microns , about 50 microns or about 100 microns. The smoking articles, according to the first embodiment of the invention, shown in Figures 1a) and 2, having a total length of 70 mm, comprising cylindrical combustible carbonaceous thermal sources, are assembled manually. The aerosol-forming substrate of the tobacco articles is 10 mm long and comprises approximately 60% by weight of smoke cured in gas ducts, approximately 10% by weight of oriental smoke and approximately 20% by weight of sun-cured smoke. . The heat conducting element of the smoking articles is 9 mm long, of which 4 mm cover the rear part of the fuel thermal source and 5 mm cover the adjacent front part of the aerosol-forming substrate. Except as indicated in the preceding description in this example, the properties of the tobacco articles conform to those listed in Table 1 presented above. Smoke articles of the same construction, but without a substantially air-impermeable, non-combustible first barrier coating are also assembled by hand for comparison.
[00248] The resulting tobacco articles are smoked as described in Example 5, according to a Health Canada smoking regime. Before smoking, the combustible thermal sources of the smoking articles are lit by using a common yellow flame igniter. Formaldehyde, acetaldehyde, acrolein and propionaldehyde in the main stream aerosol are measured, as described in Example 5. The results are summarized in Table 4, shown below, and show that carbonyls, such as acetaldehyde and especially formaldehyde, are significantly reduced in aerosols of the mainstream of smoking articles comprising a combustible thermal source with a substantially air-impermeable, non-combustible first barrier coating compared to aerosols of the mainstream of smoking articles comprising a combustible thermal source without a first barrier coating substantially impermeable to air, non-combustible.
TABLE 4: Carbonyl content (micrograms per sample) measured in a main stream aerosol, according to the Health Canada smoke regime, for smoke articles comprising a combustible carbonaceous thermal source: (a) without a substantial first barrier coating impermeable to air, non-combustible; b) with a first barrier coating substantially impermeable to air, non-combustible from clay; and c) with a first barrier coating substantially impermeable to air, non-combustible from sintered glass. EXAMPLE 8 - Smoke compounds from smoke articles with combustible thermal sources with a substantially air-impermeable, non-combustible aluminum first barrier coating
[00249] Cylindrical combustible carbonaceous thermal sources, prepared as described in Example 7 (but not treated with nitric acid), having a length of 11 mm, a single longitudinal airflow channel having a diameter of 1.85 mm and a second barrier coatings of micaceous iron oxide coating (Miox, Kãrntner Montanindustrie, Wolfsberg, Austria) are provided with a substantially air-resistant, non-combustible aluminum first barrier coating having a thickness of about 20 microns, as described in Example 4. The tobacco articles, according to the first embodiment of the invention, shown in Figures 1a) and 2, having a total length of 70 mm, comprising the carbonaceous thermal heat source mentioned above, are assembled manually. The aerosol-forming substrate of the tobacco articles is 10 mm long and contains approximately 60% by weight of smoke cured in gas ducts, approximately 10% by weight of oriental smoke and approximately 20% by weight of sun-cured smoke. . The heat conducting element of the smoking articles is 9 mm long, of which 4 mm cover the rear part of the fuel thermal source and 5 mm cover the adjacent front part of the aerosol-forming substrate. Except as indicated in the preceding description in this example, the properties of the tobacco articles conform to those listed in Table 1 presented above. Smoke articles of the same construction, but without a substantially air-impermeable, non-combustible first barrier coating are also assembled by hand for comparison.
[00250] The resulting tobacco articles are smoked as described in Example 5, according to a Health Canada smoking regime and an intense smoking regime. Before smoking, the combustible thermal sources of the smoking articles are lit by using a common yellow flame igniter. The formaldehyde, acetaldehyde, acrolein, propionaldehyde, phenol, catechol and hydroquinone in the main stream aerosol are measured, as described in Example 5. The results are summarized in Table 5. As can be seen from Table 5, according to the regimens of Health Canada smoke and intense smoke, the inclusion of a substantially air-impermeable, non-combustible aluminum first barrier coating on the rear face of the fuel thermal source causes a significant reduction in phenolic and carbonyl substances, such as formaldehyde and acetaldehyde in the aerosol main current.
TABLE 5: Content of compounds (micrograms per sample) measured in main stream aerosol, according to: (i) Health Canada's smoking regime; and (ii) intense smoke regime, for smoke articles comprising a combustible carbonaceous thermal source: (a) without a substantially air-impermeable, non-combustible first barrier coating; and b) with a substantially air-resistant, non-combustible aluminum first barrier coating.
[00251] As can be seen from Examples 7 and 8, the isolation of the combustible thermal source of smoke articles, according to the invention, from one or more of the air flow routes through the smoke article, providing a coating of first substantially impermeable, non-combustible air barrier on at least substantially the entire rear face of the fuel thermal source, and a substantially non-combustible second, substantially air-impermeable barrier coating on at least substantially the entire internal surface of the airflow channel , by the fuel thermal source, results in a significantly reduced formation of carbonyl compounds, such as formaldehyde, acetaldehyde, propionaldehyde and phenolic substances, in the main stream aerosol.
[00252] The embodiments and examples described above illustrate, but do not limit the invention. Other embodiments of the invention can be made without departing from the spirit and scope of it, and it should be understood that the specific embodiments, described in this specification, are not limiting.

权利要求:
Claims (21)
[0001]
1. Smoke article (2, 32, 34, 36,38), characterized by the fact that it comprises: a combustible thermal source (4, 40) having a front end and a rear end; an aerosol-forming substrate (6) downstream of the rear end of the fuel thermal source; a first barrier (14) substantially impermeable to non-combustible air between an end downstream of the fuel thermal source (4, 40) and an end upstream of the aerosol-forming substrate (6), wherein the first barrier is adhered to or fixed at the end downstream of the fuel thermal source; an outer wrap (12) circumscribing the aerosol-forming substrate and at least one rear part of the combustible thermal source; and one or more airflow routes, along which air can be drawn by the user's inhalation smoke article, where the fuel thermal source is isolated from one or more airflow routes, so that , in use, the air drawn by the smoke article, along one or more air flow routes, do not come into direct contact with the combustible thermal source.
[0002]
2. Smoke article (2, 42, 56), according to claim 1, characterized by the fact that the first barrier has a thickness between 10 microns and 500 microns.
[0003]
Smoke article (2, 42, 56), according to claim 1 or 2, characterized by the fact that the first barrier is formed from a material having a gross thermal conductivity between about 0.1 W per meter Kelvin (W / (mK)) and about 200 W per meter Kelvin (W / (mK)) at 23 ° C and a relative humidity of 50%, measured using the modified transient plane source (MTPS) method.
[0004]
4. Smoke article (2, 42, 56), according to claim 1 or 2, characterized by the fact that the first barrier is formed from one or more materials selected from the group consisting of copper, aluminum , stainless steel, alloys, alumina (AI2O3), resins and mineral glues.
[0005]
Smoke article (2, 42, 56) according to any one of claims 1 to 4, characterized in that the first barrier (14) comprises a first barrier coating provided on the rear face of the fuel thermal source ( 4, 40).
[0006]
6. Smoke article (2, 42, 56), according to claim 5, characterized by the fact that the first barrier coating (14) is applied to the rear face of the fuel thermal source (4, 40) by deposition of steam.
[0007]
Smoke article (2) according to any one of claims 1 to 6, characterized in that the one or more of the air flow routes comprise or more air flow channels (16) along the source fuel thermal (4).
[0008]
Smoke article (2) according to claim 7, characterized in that it comprises a second substantially impermeable barrier to non-combustible air (18) between the combustible thermal source (4) and the one or more flow channels of air (16).
[0009]
Smoke article (2) according to claim 8, characterized in that the second barrier comprises a second barrier coating (18) provided on an internal surface of the one or more airflow channels (16) .
[0010]
10. Smoke article (2, 32, 34, 36, 38,42, 56), according to any one of claims 1 to 9, characterized by the fact that it comprises one or more air inlets, downstream of the rear face from the fuel thermal source (4, 40), to draw air on one or more airflow routes.
[0011]
11. Smoke article (2, 32, 34, 36, 38,42, 56), according to claim 10, characterized by the fact that it comprises one or more primary air inlets, between one end downstream of the thermal source fuel and an upstream end of the aerosol-forming substrate (6).
[0012]
12. Smoke article (2, 32, 34, 36, 38,42, 56), according to claim 10 or 11, characterized by the fact that it comprises one or more secondary air inlets, around the periphery of the substrate aerosol former to draw air through one or more airflow routes.
[0013]
13. Smoke article (42,56) according to any one of claims 10 to 12, characterized by the fact that it comprises one or more tertiary air inlets (54), downstream from the periphery of the aerosol-forming substrate, for draw air through one or more airflow routes.
[0014]
14. Smoke article (42, 56) according to claim 13, characterized in that the one or more air flow routes comprise a first part that extends from the tertiary air inlets (54) to the aerosol-forming substrate, and a second part extending from the aerosol-forming substrate to a mouth end of the smoke article.
[0015]
15. Smoke article (2, 42, 56) according to any one of claims 1 to 14, characterized by the fact that it also comprises: a heat conducting element (24) around and in direct contact with a rear part the fuel thermal source (4.40) and a front part (6a) of the aerosol-forming substrate (6).
[0016]
16. Smoke article (2, 32, 34, 36, 38, 42, 56) according to any one of claims 1 to 15, characterized in that it further comprises an expansion chamber (8) downstream of the substrate aerosol former.
[0017]
17. Smoke article (2, 32, 34, 36, 38, 42, 56) according to any one of claims 1 to 16, characterized in that the combustible thermal source is a substantially cylindrical carbonaceous thermal source.
[0018]
18. Fuel thermal source (4, 40) with opposite front and rear faces, for use in a smoke article as defined in any of claims 1 to 17, characterized in that the fuel thermal source has a substantially first barrier impermeable to non-combustible air provided at least substantially across the rear face of the fuel thermal source, and the first barrier is adhered to, or otherwise affixed to, the rear face of the fuel thermal source.
[0019]
19. Fuel thermal source (4, 40) according to claim 18, characterized in that the first barrier comprises a first barrier coating on the rear face of the fuel thermal source.
[0020]
20. Fuel thermal source (4, 40) according to claim 19, characterized in that the first barrier coating is applied to the rear face of the fuel thermal source (4, 40) by vapor deposition.
[0021]
21. Process of reducing or eliminating increases in temperature of an aerosol-forming substrate (6) of a smoke article (2, 32, 34, 36, 38, 42, 56), during smoking, the process characterized by the fact comprising comprising a smoke article comprising: a combustible thermal source (4, 40) with opposite front and rear faces; an aerosol-forming substrate (6) downstream of the rear face of the fuel thermal source; a first barrier (14) substantially impermeable to non-combustible air between an end downstream of the fuel thermal source (4, 40) and an end upstream of the aerosol-forming substrate (6), wherein the first barrier is adhered to or fixed at the end downstream of the fuel thermal source; an outer wrap (12) circumscribing the aerosol-forming substrate and at least one rear part of the combustible thermal source; and one or more airflow routes, along which air can be drawn by the user's inhalation smoke article, where the fuel thermal source is isolated from one or more airflow routes, so that , in use, the air drawn by the smoke article, along one or more airflow routes, do not come in direct contact with the combustible thermal source.

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US10667554B2|2017-09-18|2020-06-02|Rai Strategic Holdings, Inc.|Smoking articles|

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US10555558B2|2017-12-29|2020-02-11|Rai Strategic Holdings, Inc.|Aerosol delivery device providing flavor control|

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KR20200061072A|2018-11-23|2020-06-02|주식회사 케이티앤지|Cigarette and aerosol generating apparatus thereof|

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KR20200061070A|2018-11-23|2020-06-02|주식회사 케이티앤지|Cigarette and aerosol generating apparatus therefor|

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WO2020115151A1|2018-12-06|2020-06-11|Philip Morris Products S.A.|Aerosol-generating article with high aerosol former content|

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EP3937681A1|2019-03-11|2022-01-19|Selby, Ryan Daniel|Improved smoking article|

法律状态:
2018-12-04| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|

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2019-12-03| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|

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2020-06-16| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|

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2020-11-17| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 12/02/2013, OBSERVADAS AS CONDICOES LEGAIS. |

优先权:

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申请号 | 申请日 | 专利标题

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EP12155239|2012-02-13|

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EP12155239.2|2012-02-13|

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PCT/EP2013/052794|WO2013120855A1|2012-02-13|2013-02-12|Smoking article comprising an isolated combustible heat source|

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