aluminum alloy material for heat exchanger fin, method of its manufacture and heat exchanger using t

专利摘要:
ALUMINUM ALLOY MATERIAL FOR HEAT EXCHANGE FIN, METHOD OF ITS MANUFACTURING AND HEAT EXCHANGE USING THE ABOVE ALUMINUM ALLOY MATERIAL. The problem addressed by the invention is to provide an aluminum alloy, which can be bonded in a monolayer state as a fin material for a heat exchanger and which does not change shape before and after bonding. problem is a heat exchanger fin material aluminum alloy which has a heat bonding function as a monolayer. The alloy contains 1.0-5.0% by mass of Si, 0.1-2.0% by mass of Fe and 0.1-2.0% by mass of Mn and the remainder is obtained from Al and unavoidable impurities. 250 pieces/mm2-7 × 104 pieces of Si intermetallic compounds with an equivalent circle radius of 0. 5-5 µm are present in an aluminum alloy cross section. 10 pcs/mm2-1000 pieces of Al-Fe-Mn-Si intermetallic compounds with an equivalent circle radius greater than 5 µm are present in an aluminum alloy cross section. aluminum. The alloy can also contain Mg, Cu, Zn, In, Sn, Ti, V, Zr, Cr, Ni, Be, Sr, Bi, Na or Ca as needed.
公开号:BR112014017965A2
申请号:R112014017965-4
申请日:2013-01-25
公开日:2021-06-08
发明作者:Kazuko Fujita；Akio Niikura；Takashi Murase
申请人:Uacj Corporation；
IPC主号:

专利说明:

[0001] [0001] The present invention relates to an aluminum alloy material used as a heat exchanger fin material, method of its manufacture and, more specifically, to an aluminum alloy material capable of being joined to another member with its own joining function without using a brazing filler metal and a method of fabrication of said aluminum alloy material. The present invention further relates to a heat exchanger which employs said aluminum alloy material and which can be efficiently manufactured. Background of the Technique
[0002] [0002] When fabricating a structural body, such as a heat exchanger, which employs an aluminum alloy material as a component member, it is necessary to join the aluminum alloy materials together or join the aluminum alloy material to another different kind of material. Several methods are known as joining methods for aluminum alloy material. Among the various methods, a brazing method (hard soldering method) is used in many cases. The brazing method is often used considering, for example, the advantage that strong bonding can be obtained in a short time without melting a base material. As manufacturing methods for heat exchangers etc. employing methods of joining the aluminum alloy material with brazing, for example, a method of using a brazing sheet on which a brazing filler metal made of Al-Si alloy is coated, is known. of using an extruded member coated with a powdered brazing filler metal and a method of mounting multiple members and then further applying a brazing filler metal to parts that are to be joined (Patent Documents 1 to 3) . In addition, Chapter 3.2 Brazing Alloys and Brazing Sheets in Non-Patent Document 1 explains in detail the coated brazing sheet and powder brazing filler metal.
[0003] [0003] To date, several brazing methods have been developed in the field of fabrication of structural bodies using an aluminum alloy material. With respect to vehicular heat exchangers, for example, when using a fin member in a single layer, a method of using a brazing sheet made of a sheet of tube material over which a metal is covered was employed. of brazing charge and an additional method of coating Si powder or metal brazing that contains Si onto the sheet of tube material. On the other hand, when using the tube member in a single layer, a method of using a brazing sheet made of a sheet of fin material over which a brazing filler metal is coated has been employed.
[0004] [0004] Patent Document 4 describes a method of employing a single-layer brazing sheet in place of the coated brazing sheet mentioned above. This method proposes to use the single layer brazing sheet for a heat exchanger such as fin member and a heat exchanger tank member. According to Patent Document 4, the desired shape is maintained by adjusting the amount of Si to be added and the brazing temperature. In the fin member which is thinner than the tube member and/or the tank member, however, the described method is not satisfactory as a method of maintaining the desired shape, although it guarantees sufficient brazing performance.
[0005] [0005] Patent Documents: Patent Document 1: JP 2008-303405 A. Patent Document 2: JP 2009-161835 A; Patent Document 3: JP 2008-308760 A; Patent Document 4: JP 2010-168613 A.
[0006] [0006] Non-Patent Documents: Non-Patent Document 1: Aluminum Erazing Handbook (revised edition), Japan Light Metal Welding & Construction Association, 2003. Summary of the Invention
[0007] [0007] Problems to be solved by the present invention: the manufacture of coated sheets, such as brazing sheets, requires steps of manufacturing individual layers separately and joining the individual layers to each other after their deposition in a layered state. Thus, the use of the brazing sheet is contrary to the demand for reducing the heat exchanger's production costs, etc. Coating the powdered brazing filler metal also increases the production cost corresponding to the cost of the brazing filler metal.
[0008] [0008] Meanwhile, it is proposed, as described above, to employ the single-layer brazing sheet in place of the coated brazing sheet. When the single-layer brazing sheet is used as a fin member having a small thickness, however, the problem arises that a fin is easily susceptible to bending deformation during brazing, even under light load. Furthermore, in the case of trying to increase the amount of Si in the composition and/or the brazing temperature to ensure brazing performance, the fin is more susceptible to deformation. It is, therefore, very difficult to adequately control the brazing performance and the degree of deformation during the brazing operation.
[0009] [0009] In this way, it can be stated that it would be preferable to join single-layer materials together without the use of brazing filler metal from the point of view of reducing the cost of the aluminum alloy structural body, such as the exchanger. heat. If single-layer brazing sheet is simply employed, however, it will be difficult to avoid the problem of deformation of component members. The present invention has been devised in view of the background described above and an object of the present invention is to provide an aluminum alloy material which is used as a material for a heat exchanger fin and does not cause the problem of deformation during joining, while avoiding the increased cost that can be attributed to using a member with multiple tiers.
[00010] [00010] As a result of conducting intensive studies, the inventors discovered an innovative bonding method, which improves the bonding method of an aluminum alloy material with the known brazing method and uses the bonding capacity exerted by the aluminum alloy material itself. be joined without the use of a brazing filler metal. The innovative joining method is characterized in that the members are joined and assembled under specific conditions, employing an aluminum alloy material described later for a heat exchanger fin, the members can be joined together under heating without using an auxiliary heat exchanger material. bonding such as a brazing filler metal (this capability is called "heat bonding function") and the deformation between before and after bonding can be kept very small.
[00011] [00011] According to a first aspect, the present invention provides an aluminum alloy material for a heat exchanger fin, in which the aluminum alloy material has superior bonding function by heating a single layer of the aluminum alloy material. aluminum containing Si: 1.0% by mass to 5.0% by mass, Fe: 0.1% by mass to 2.0% by mass and Mn: 0, 1% by mass to 2.0% by mass , where the balance is Ale unavoidable impurities , 250 pieces/mm 2 or more to 7 x 104 pieces/mm 2 or less of Si-based intermetallic compounds particles having equivalent circle diameters of O , 5 to 5 Jlm are present in a cross section of aluminum alloy material and 10 pieces/mm2 or more and 1000 pieces/mm2 or less of Al - Fe-Mn-Si based intermetallic compounds particles having diameters and circle equivalents of 5 Jlm or more are present in a cross section of aluminum alloy material.
[00012] [00012] According to a second aspect of the present invention, in the first aspect described above, the aluminum alloy material satisfies T/To 1, 40, where T indicates tensile strength of a material plate and To indicates tensile strength after heating at 450 °C for two hours.
[00013] [00013] According to a third aspect of the present invention, in the first or second aspect described above, the aluminum alloy material further contains one or two selected from Mg : 2.0% by mass or less and Cu : 1.5 % by mass or less. According to a fourth aspect of the present invention, in any of the first to third aspects described above, the aluminum alloy material further contains one, two or more selected from Zn: 6, 0% by mass or less, In: 0, 3% by mass or less and Sn : 0 , 3% by mass or less.
[00014] [00014] According to a fifth aspect of the present invention, in any of the first to four aspects described above, the aluminum alloy material further contains one, two or more selected from Ti: 0.3% by mass or less, V : 0.3 % by mass or less , Zr : 0.3 % by mass or less , Cr : 0.3 % by mass or less and Ni : 2.0 % by mass or less .
[00015] [00015] According to a sixth aspect of the present invention, in any of the first to fifth aspects described above, the aluminum alloy material further contains one, two or more selected from Be: 0.1% by mass or less, Sr : 0.1% by mass or less, Bi: 0.1% by mass or less, Na: 0.1% by mass or less, and Ca: 0.05 % by mass or less.
[00016] [00016] According to a seventh aspect of the present invention, in any one of the first to sixth aspects described above, the tensile strength before heating for joining is from 80 to 250 MPa. According to an eighth aspect, the present invention provides a method of manufacturing the aluminum alloy material for the heat heater fin in accordance with one of the first to seventh aspects described above, wherein the method comprises the steps of: an aluminum alloy to aluminum alloy material, heating a molded ingot before hot rolling, hot rolling the ingot after the heating step, cold rolling a hot rolled plate and combining a hot rolled plate cold halfway through the cold rolling step, where the shaping speed is set to be 20 to 100 mm/min in the shaping step and the hot rolling step includes a rough rolling stage in which the total ratio roll reduction ratio is defined as 92 to 97%, where the rough roll stage includes three or more passes, in each of which the roll reduction ratio is 15% or more. According to a ninth aspect, the present invention provides a heat exchanger manufactured by heating and joining a fin member which is made of the aluminum alloy material according to any one of the first to seventh aspects described above and another component member. of the heat exchanger together.
[00017] [00017] According to a tenth aspect of the present invention, in the ninth aspect described above, the grain size of an aluminum matrix in a microstructure in cross section of the fin member aluminum alloy material after heating for joining is 50 pm or more.
[00018] [00018] According to an eleventh aspect of the present invention, in the ninth or tenth aspect described above, when observing the microstructure in the cross section of the fin member aluminum alloy material after heating for the union, the number of triple points of grain boundaries where there are particles of intermetallic compounds that have equivalent circle diameters of 1 J.lm or more, is 50% or more of the total amount of triple points of all grain boundaries.
[00019] [00019] According to a twelfth aspect of the present invention, in any of the ninth to eleventh aspects described above, when observing the microstructure in the fin cross section of the fin member aluminum alloy material after heating for the union , 10 pieces/mm2 to 3000 pieces/mm2 of eutectic structures that have lengths of 3 J.lm or more are present within matrix grains.
[00020] [00020] The present invention will be described in detail below. The present invention is basically characterized in that a liquid phase generated when heating the aluminum alloy material containing the aforementioned composition is used for bonding. In view of this basic characteristic, the mechanism for generating that liquid phase is described first.
[00021] [00021] Fig. 1 illustrates a phase diagram of an alloy based on Al and Si that is a eutectic alloy with typical binary phase.
[00022] [00022] When an aluminum alloy material that has Si composition of c1 is heated, a liquid phase begins to be generated at temperature T1, close to but higher than the eutectic temperature (solid temperature) Te. At eutectic temperature Te or below, as illustrated in Fig. 2a, dispersoids are distributed in a matrix divided by grain boundaries. When the liquid phase begins to be generated in this state of the aluminum alloy material, as illustrated in Fig. 2b, the grain boundaries in which the dispersoids are distributed in greater quantity due to segregation are melted and become liquid phases. Then, as illustrated in Fig. 2c, the vicinity of the dispersoid particles of intermetallic compounds of Si, which is a major additive element component dispersed in the aluminum alloy material matrix, are fused into spherical shapes and become phases liquids. Furthermore, as illustrated in Fig. 2d, the spherical liquid phases generated in the matrix are again dissolved in the solid state matrix due to the energy of interface with the time lapse or temperature rise and move to the grain boundaries or surfaces. through solid phase diffusion. Then, when the temperature rises to T2 as shown in Fig. 1, the amount of liquid phases increases more than shown in the phase diagram.
[00023] [00023] When, in Fig. 1, the Si composition of the aluminum alloy material is c2, which is less than a maximum solids solubility limit composition, a liquid phase begins to be generated at a temperature close to but higher than the temperature of solid Ts2. Unlike the case of c1, however, in a structure just before the fusion, dispersoids do not always exist in the matrix as illustrated in Fig. 3a. In this case, the grain boundaries are first fused and become liquid phases as illustrated in Fig. 3b. In this way, as illustrated in Fig. 3c, a liquid phase begins to be generated from a location where a composition of solute elements is locally high in the matrix. As in the case of cl, the spherical liquid phases generated in the matrix are re-dissolved in the solid state matrix due to the interface energy with time lapse or temperature rise and move to grain boundaries or surfaces through diffusion in the solid phase, as illustrated in Fig. 3d. With the temperature rising to T3, the amount of liquid phase increases more than shown in the phase diagram.
[00024] [00024] A joining method using the aluminum alloy material for the heat exchanger fin, according to the present invention, uses the liquid phase generated with the local melting described above inside the aluminum alloy material. By keeping the mass of the liquid phase in a preferable range with adjustment of the heating temperature, bonding and fin shape maintenance can be accomplished. When a fin member is manufactured by molding the aluminum alloy material in accordance with the present invention and subjected to heat treatment at a temperature of about 600°C, a liquid phase is partially generated in the fin, which bleeds into the fin. material surface, in order to allow the fin to be joined. As a result, the heat exchanger can be manufactured without using a bonding material such as a brazing filler metal.
[00025] [00025] In the aluminum alloy material for the heat exchanger fin according to the present invention, the unfused matrix (ie a part of the aluminum material, except intermetallic compounds) and intermetallic compounds that do not contribute to generation of the liquid phase mainly develop the strength of the material. Therefore, although the aluminum alloy material according to the present invention enters a partially molten state during joining, it can maintain sufficient strength to retain shape. Consequently, the heat exchanger manufactured in accordance with the present invention is characterized in that changes in size and shape are hardly caused during joining. With that feature, the aluminum alloy material according to the present invention can preferably be used as a thin fin material, which otherwise may deform during joining. As described above, the present invention utilizes the liquid phase in the aluminum alloy material. The present invention has two specific characteristics, namely, (i) the aluminum alloy material is made of an alloy based on Ale Si that contains Si in composition from 1.0% by mass to 5.0% by mass and has a basic composition containing Fe: 0.1% to 2.0% and Mn: 0.1% to 2.0% and (ii) in a microstructure of aluminum alloy material, intermetallic compounds derived from component elements ( ie, particles of intermetallic compounds based on Si and particles of intermetallic compounds based on Al-Fe-Mn-Si) are present in corresponding predetermined ranges of surface density in cross-section of the aluminum alloy material. These features are described below. It should be noted that, in the following description, "% in bulk" is simply denoted by "%".
[00026] [00026] As for the composition of Si, Si is an element that generates a liquid phase based on Al-Si and contributes to the union. If the composition of Si is less than 1.0%,
[00027] [00027] In the aluminum alloy material according to the present invention, Fe and Mn are added as essential elements for the Al-Si alloy. At this point, Fe and Mn are additive elements that serve to strengthen the matrix to ensure strength that is effective as the fin member and to generate intermetallic compounds as described later.
[00028] [00028] Fe is effective not only to increase strength through slight dissolution in the solid state matrix, but also to avoid lowering strength at high temperatures, particularly through dispersion in the form of crystallized deposits. If the amount of Fe added is less than 0.1%, the effects mentioned above would be reduced and a higher purity ingot would need to be used in order to increase the cost. If the amount of Fe added is more than 2.0%, crude intermetallic compounds will be generated during modeling and fabrication capability will be problematic. Furthermore, when the fin made with the aluminum alloy material according to the present invention is exposed to a corrosive environment (particularly corrosive environment which includes liquid flow), the corrosion resistance of the fin will be reduced. Additionally, as the sizes of grains recrystallized due to heating during bonding are reduced and the grain boundary density increases, the size change between before and after bonding will increase. For this reason, the amount of Fe added is specified to be from 0.1% to 2.0%. A preferable amount of Fe added is from 0.2% to 1.0%.
[00029] [00029] Mn is an important additive element, which forms intermetallic compounds based on Al-Fe-Mn-Si together with Fe and Si and increases strength through the development of dispersion strengthening or dissolution action in the matrix of solid state aluminum and the development of solids solution strengthening action. If the amount of Mn added is less than 0.1%, the effects mentioned above will be insufficient. If the amount of Mn added is more than 2.0%, crude intermetallic compounds will be easily formed and corrosion resistance will be reduced. Consequently, the amount of Mn added is specified to be 0.1%
[00030] [00030] Si forms the intermetallic compounds based on Al-Fe-Mn-Si together with Fe and Mn. As Si that has these formed intermetallic compounds is, however, less effective in contributing to the generation of the liquid phase, there is a risk of impaired bonding performance. Consequently, in the aluminum alloy material for the heat exchanger fin according to the present invention, it is preferable to take care of the corresponding amounts of Si, Fe and Mn added. More specifically, considering that the content (% by mass) of Si, Fe and Mn is indicated by S, F and M, respectively, a ratio expression of 1.2 ≤ S - O, 3(F + M) ≤ 3 , 5 is preferably satisfied. If S - 0.3(F + M) is less than 1.2, the union will be insufficient. On the other hand, if S - 0.3(F + M) is more than 3.5, the shape will be better able to change between before and after the union.
[00031] [00031] Characteristics of a microstructure in the aluminum alloy material according to the present invention will be described below. In the aluminum alloy material according to the present invention, there are not only Si-based intermetallic compounds generated from its basic intermetallic (Al-Si) composition, but also Al-Fe-Mn-Si-derived compounds of the additive elements Fe and Mn. The present invention is characterized by the dispersed sizes and states of these intermetallic compounds.
[00032] [00032] The expression "Si-based intermetallic compounds" indicates (1) an isolated Si intermetallic compound and (2) Si intermetallic compounds and other elements, such as Ca and P, which are partially contained in Si. Si-based intermetallics are intermetallic compounds that contribute to liquid phase generation in the liquid phase generation process described above. The aluminum alloy material according to the present invention is characterized because 250 pieces/mm² or more to 7 x 10⁴ pieces/mm² or less of Si-based intermetallic compounds particles having equivalent circle diameters of O .5 to 5 µm are present in cross section of aluminum alloy material. Particles of Si-based intermetallic compounds, such as Si particles, which are dispersed in the aluminum alloy material, react with the surrounding matrix and generate a liquid phase during bonding.
[00033] [00033] Therefore, the finer the particles of intermetallic compounds based on Si, the greater the area in which the particles and matrix come into contact with each other. In this way, as Si-based intermetallic compounds are thinner, the liquid phase tends to be generated more quickly during bonding heating and satisfactory bonding performance is obtained. Furthermore, as Si-based intermetallic compounds are thinner, the shape of the aluminum alloy material can be maintained more reliably. These effects are most significant when the bond temperature is closer to the solid line or when the temperature rise rate is higher. In the present invention, therefore, it is necessary that preferable Si-based intermetallic compounds are specified as having equivalent circle diameters of 0.5 to 5 m and their presence rate is specified as being 250 pieces/rn 2 or more and 7 x 104 pieces/rnrn2 or less in cross section of aluminum alloy material.
[00034] [00034] On the other hand, intermetallic compounds based on 15 Al-Fe -Mn-Si do not contribute much with the generation of the liquid phase, unlike intermetallic compounds based on Si , but constitute a phase that develops the resistance of the material during heating for bonding together with the matrix. Considering that the aluminum alloy material according to the present invention is used as a thin member, that is, a thin member of a heat exchanger, the strength of the material is ensured with proper dispersion of intermetallic compounds based on Al-Fe- Mn-Si. As the dispersion of intermetallic compounds based on Al-Fe-Mn-Si has great influence on the grain size after heating for bonding, they are necessary for proper dispersion. It is required that 10 pieces lmm2 or more and 1000 pieceslmm2 or less of the Al-Fe-Mn-Si based intermetallic compounds having equivalent circle diameters of more than 5 Jlm are required to be present in the material cross-section. If the number is less than 10 pieces/mm 2 , the strength will be reduced, causing deformation. If the number is greater than 1000 pieces/mm2, the incidence of cores for recrystallization particles during heating for bonding will be higher and the grain sizes will be reduced. As the grains become smaller, the grains will be more able to slide with each other at grain boundaries and deformation will be more likely to occur, in a way that causes fin arching. In addition, liquid phases would be generated around the intermetallic compounds during heating for bonding and the ratio of a liquid phase area to plate thickness will increase, causing fin arching. There are also Al - Fe - Mn - Si based intermetallic compounds that have equivalent circle diameters of 5 µm or less and they contribute to increasing the strength of a material plate and strength during heating for joining and after heating for union. Al - Fe - Mn - Si based intermetallic compounds that have equivalent circle diameters of 5 µm or less , however , are easily dissolved in the matrix with grain boundary change during heating for bonding and hardly affect the ease of bonding . occurrence of deformation that can be attributed to the grain sizes after heating. In this way, lowercase Al - Fe-Mn - Si based intermetallic compounds are excluded from the specified preferable range. As there are hardly any Al-Fe-Mn-Si based intermetallic compounds that have equivalent circle diameters of 10 J.lm or more, they are also substantially excluded from the preferable specified range.
[00035] [00035] The equivalent circle diameters of the Si-based intermetallic compounds mentioned above can be determined with SEM observation (ie observation of an electron image reflected by the Scanning Electron Microscope) of the cross section. At this point, the expression "equivalent circle diameter" indicates nominal diameter. Preferably, the equivalent circle diameters of the intermetallic compounds prior to bonding are determined by performing image analysis of an SEM photo. The metallic substance of the internal and rmetallic compounds can be examined using, for example, EPMA (electron probe microanalyzer (X-ray).
[00036] [00036] Furthermore, intermetallic compounds based on Si and intermetallic compounds based on Al-Fe -Mn -Si can be discriminated against each other based on the contrast difference with the observation of SEM - reflected electronic image. Intermetallic compounds can be specified more precisely using, for example, EPMA.
[00037] [00037] The aluminum alloy material described above for the heat exchanger fin according to the present invention has the characteristics in the corresponding composition ranges of the component elements and the microstructure, which can perform the union with its own performance of union and can be used as fin member joined to other component members of the heat exchanger. At this point, the other component members of the heat exchanger indicate a tank, tube, side plate, and so on.
[00038] [00038] Depending on the structure of the heat exchanger, fin members, each made with the aluminum alloy material according to the present invention, can be joined together or a fin member made with the aluminum alloy material according to the present invention it can be joined to another type of fin member.
[00039] [00039] As discussed above, in the aluminum alloy material according to the present invention, Si, Fe and Mn are essential elements and their contents are specified to meet the basic function of developing the bonding performance and to ensure the necessary strength as fin member. In order to further increase the strength and corrosion resistance, elements other than the essential elements mentioned above can be additionally added singly or in combination of several elements. These other additive elements are described below.
[00040] [00040] At least one of Mg and Cu is preferably added as a selective additive element which is suitable to further increase strength.
[00041] [00041] Mg develops age hardening in the form of Mg2Si after heating for bonding, in order to increase strength with age hardening. In this way, Mg is an additive element to develop the resistance-increasing effect. If the amount of Mg added is more than 2.0%, Mg will react with the flux and form a high melting compound, significantly degrading the bonding performance. Consequently, the amount of Mg added is specified to be 2.0% or less. A preferable amount of Mg added is from 0.05% to 2.0%. In the present invention, not only for Mg, but also for other alloy components, when it is mentioned that the amount of added element is "a predetermined percentage or less", the amount includes 0%.
[00042] [00042] Cu is an additive element that dissolves in the solid state matrix and increases strength. If the amount of Cu added is more than 1.5%, however, corrosion resistance will be reduced. Consequently, the amount of Cu added is specified to be 1.5% or less.
[00043] [00043] A preferable amount of Cu added is from 0.05% to 1.5%. In the present invention, one or more of Ti, V, Zr, Cr and Ni are preferably added as selective additive elements to further increase strength.
[00044] [00044] Ti and V have the effects of not only increasing the strength when dissolved in the solid state matrix, but also preventing the corrosion progress towards the plate thickness when being distributed in a layered pattern. If the amount of each of Ti and V added is more than 0.3%, gigantic crystallized deposits will be generated, in a way that impairs the formation capacity and corrosion resistance. Consequently, the amount of each of Ti and V added is preferably specified to be 0.3% or less. A more preferred amount of Cu is from 0.05% to 0.3%.
[00045] [00045] Zr is precipitated in the form of intermetallic compounds based on Al and Zr and develops the effect of increasing strength after bonding with strengthening the dispersion. Furthermore, intermetallic compounds based on Al and Zr act to make the grains more coarse during heating. If the amount of Zr added is more than 0.3%, crude intermetallic compounds will be easily formed and the working capacity of the plastic will be reduced.
[00046] [00046] Consequently, the amount of Zr added is preferably specified to be 0.3% or less. A more preferred amount is from 0.05% to 0.3%. Cr increases strength with solid solution strengthening and acts to make the grains coarser after heating with precipitation of intermetallic compounds based on Al and Cr. If the amount of Cr added is more than 0.3%, crude intermetallic compounds will be easily formed and the working capacity of the plastic will be reduced. Consequently, the amount of Cr added is preferably specified to be 0.3% or less.
[00047] [00047] A most preferred amount is from 0.05% to 0.3%. Ni is crystallized or precipitated as an intermetallic compound and develops the effect of increasing strength after bonding with strengthening the dispersion. The amount of Ni added is preferably specified to be 2.0% or less. A most preferred amount is from 0.05% to 2.0%. If the Ni content is more than 2.0%, crude intermetallic compounds will be easily formed, in a way that impairs the working capacity and the resistance to self-corrosion.
[00048] [00048] In addition to the selective elements mentioned above to increase strength, other selective additive elements intended to increase corrosion resistance can also be added. Selective additive elements intended to increase corrosion resistance are, for example, Zn, In and Sn.
[00049] [00049] Addition of Zn is effective in increasing corrosion resistance with sacrificial anticorrosion action. Zn is substantially uniformly dissolved in the solid state matrix.
[00050] [00050] When generating a liquid phase, however, Zn is dissolved in the liquid phase to increase the composition of Zn in the liquid phase. Upon bleed from the liquid phase to the surface, the Zn composition in a region that has bled from the liquid phase increases, so as to increase the corrosion resistance due to the action of sacrificial anodes. Furthermore, when the aluminum alloy material according to the present invention is applied to heat exchangers, the anti-corrosion action sacrifices for the protection of pipes etc. Anti-corrosion can be developed using the aluminum alloy material according to the present invention in the form of fins. If the amount of Zn added is more than 6.0%, the corrosion rate will increase and the resistance to self-corrosion will be reduced.
[00051] [00051] Consequently, the amount of Zn added is preferably specified to be 6.0% or less. A most preferred amount of Zn added is from 0.05% to 6.0%.
[00052] [00052] Sn and In have the effect of developing the sacrificial anode action. If the amount of each of Sn and In added is more than 0.3%, the corrosion rate will increase and the resistance to self-corrosion will be reduced. Consequently, the amount of each of Sn and In added is preferably specified to be 0.3% or less. A more preferred amount is from 0.05% to 0.3%.
[00053] [00053] In the aluminum alloy material according to the present invention, selective elements can also be added to improve the liquid phase characteristics and further increase the bonding performance. In more detail, these elements are preferably Be : O , 1% or less , Sr : O , 1% or less , Bi : 0 , 1% or less , Na : 0 , 1% or less , Ca : 0 , 05% or any less . One, two or more of these elements are added as needed.
[00054] [00054] If the amount of each trace element is less than the most preferred specific range mentioned above, the effects of causing finer dispersion of Si particles and increasing the fluidity of the liquid phase will be insufficient in some cases. If the amount of each trace element is greater than the most preferred specific range mentioned above, a disadvantage such as reduced corrosion resistance may be caused in some cases. Regardless of whether any one or more of Be , Sr , Bi , Na and Ca are added, each element is aggregated in the preferable or most preferred composition range mentioned above.
[00055] [00055] The aluminum alloy material for the heat exchanger fin according to the present invention satisfies a ratio of T/To 1.4O, where T indicates tensile strength of a material plate and To indicates resistance to tension after heating at 450 °C for two hours. With heating at 450 °C for two hours, the aluminum alloy material for the heat exchanger fin according to the present invention is sufficiently combined and becomes O-quench material. T/To represents the rate of increase in strength from the strength of the O quench material. In the present aluminum alloy material, it is effective to reduce the final cold bearing reduction ratio after blending in a manufacturing process from the viewpoint of increasing grain size after heating for union. If the final reduction ratio is large, the driving forces in recrystallization would be increased and the grains during heating for bonding would become finer. As the final reduction ratio increases, the resistance also increases and T/To takes on a higher value. Keeping T/To, which is an index representing the final reduction ratio, at 1.40 or less is effective in increasing grain size and preventing fin deformation after heating for bonding.
[00056] [00056] In the aluminum alloy material for the heat exchanger fin according to the present invention, the tensile strength before heating for joining is preferably from 80 to 250 MPa. If the tensile strength before heating for bonding is less than 80 MPa, sufficient strength required to form the fin-shaped sheet of material will not be obtained and the fin shape cannot be formed. If it is more than 250 MPa, the sustainability of the form after molding on the fin will be lower and a gap will be generated between the fin and another component member when they are assembled together with a heat exchanger, in order to impair the bonding performance. Furthermore, in the aluminum alloy material for the heat exchanger fin according to the present invention, the tensile strength after heating for bonding is also preferably from 80 to 250 MPa. If the resistance to tension after heating for the union is less than 80 MPa, the resistance required for the fin will be insufficient and deformation will occur upon application of tension to the heat exchanger. If it is more than 250 MPa, the resistance of the fin will be higher than that of another component member of the heat exchanger so as to cause a risk of breakage in a joining part between the fin and the other component member during use.
[00057] [00057] The aluminum alloy material for the heat exchanger fin according to the present invention has, after heating for the union, a microstructure in which the grain size of the aluminum matrix is preferably 20 of 50 lm or more in a cross section of the fin. Boundary pieces of grain are fused during heating for bonding. If the grains are small, therefore, they are more likely to slip together, in a way that causes deformation. As it is very difficult to observe the grains during heating for bonding, the grain size of the aluminum matrix after bonding is taken into account for determination. If the grain size after heating for bonding is less than 50 µlm, the fin member will be susceptible to deformation during bonding. The grain size of the aluminum matrix is measured according to the grain measurement method of ASTM E112-96 and the average grain size is calculated. Although the aluminum alloy material for the heat exchanger fin according to the present invention has the microstructure characteristics described above in the state before heating for bonding, microstructure characteristics are further developed even after heating for bonding. The inventors have found that the microstructure described below that appears after heating can also be considered characteristic of the aluminum alloy material according to the present invention and that these characteristics are effective in developing the material strength and bond strength that are appropriate as fin member of the heat exchanger.
[00058] [00058] More in detail, in the microstructure of the aluminum alloy material according to the present invention after heating for the union, there are many intermetallic compounds etc at the grain boundaries.
[00059] [00059] As seen from the liquid phase generation mechanism illustrated in Fig. 2, in a process where the liquid phase is generated and flows outward, the grain boundaries serve as one of the outward flow paths of the liquid phase.
[00060] [00060] There are therefore liquid phases at grain boundaries during heating for union. Consequently, with subsequent cooling, the liquid phases are solidified to generate the intermetallic compounds at the grain boundaries. The inventors have found that, in the joined member in which the bonding performance and material strength during bonding are satisfactorily balanced, the amount of grain boundary triple points in which Si-based intermetallic compounds and Si-based intermetallic compounds exist emAl-Fe-Mn-Si having equivalent circle diameters of 1 pm or more is 50% or more of the total amount of triple points of all grain boundaries. At this point, the expression "triple grain boundary point" indicates a point (triple point) at which at least three or more grain boundaries in the matrix intersect when observing a cross-section of the aluminum alloy material.
[00061] [00061] The intermetallic compounds mentioned above that exist at the triple points of the grain boundaries function as dispersed particles in the second phase that have dispersion strengthening action and develop the function of strengthening the fin member of the heat exchanger. Furthermore, intermetallic compounds exhibit the effect of suppressing grain growth during cooling after heating to join the limb. Furthermore, when heating the fin together again, the intermetallic compounds exhibit the effect of suppressing grain coarseness in the fin. These effects would be insufficiently obtained if the rate of the number of triple points of the grain boundaries where the intermetallic compounds exist is less than 50%.
[00062] [00062] For this reason, the amount of triple points of grain boundaries where there are intermetallic compounds that have equivalent circle diameters of 1 pm or more is preferably specified as being 50% or more of the amount of triple points of all grain borders. This rate is most preferably 80% or more. An upper limit value of that rate is 100%.
[00063] [00063] Existing intermetallic compounds at the triple points of grain boundaries include intermetallic compounds based on Al-Fe-Mn-Si and intermetallic compounds based on Si. Intermetallic compounds based on Si include an isolated Si intermetallic compound and intermetallic compounds of Si and other elements, such as Ca and P, which are partially contained in Si.
[00064] [00064] Intermetallic compounds based on Al-Fe-Mn-Si are intermetallic compounds made of Ale one or more additive elements, such as compounds based on Al-Fe, based on Al-Mn, based on Al- Fe-Si, based on Al-Mn-Si, based on Al-Fe-Mn and based on Al-Fe-Mn-Si.
[00065] [00065] The presence of intermetallic compounds at the triple points of grain boundaries can be identified by several methods. With a method using an optical microscope, for example, a cross section of the fin member after bonding is mechanically polished and eroded using Keller's reagent. Positions of the intermetallic compounds are then identified. In addition, grain boundaries in the relevant cross section become clearer with the anodic oxidation method and the positions of triple point grain boundaries are identified.
[00066] [00066] Comparing the two identification results, the rate of the number of triple points of grain boundaries where there are intermetallic compounds that have equivalent circle diameters of 1 m or more is determined with respect to the amount of triple points of all the grain borders.
[00067] [00067] When the liquid phase that leaves the grain boundaries is solidified and transformed into a eutectic structure, there is a possibility that the intermetallic compounds are formed discontinuously at the grain boundaries or that a eutectic structure is formed in which they are alternately an Ale phase and an intermetallic compound phase are arranged. In this case, as the grain boundaries are not clear, the grain boundaries are often observed as broken lines and the positions of the triple points of the grain boundaries are not clear. In this case, the intermetallic compounds and the eutectic structure are considered part of the grain boundaries and the triple points of the grain boundaries are discriminated by drawing continuous imaginary lines along the grain boundaries. When a Si phase (not shown) and the eutectic structure is large and the triple point of the grain boundaries is not clear as shown in Fig.5, the entire area of that portion is considered to represent the grain boundaries as shown in Fig. 6. As indicated by a dotted line in Fig. 6, a region in which three grain boundaries imaginary intersect is considered a triple point. The triple point in the case mentioned above is given as an area resulting from combining parts of corresponding grain boundaries in a region in which the three grain boundaries intersect. It is only necessary that the intermetallic compounds are formed even in a part of the above mentioned triple point area.
[00068] [00068] The triple point can also be identified by means of a method that uses an EPMA (Micro Analyzer of Electron Probes (X-ray)). This method is intended to analyze surface components of elements, such as Si and Fe, in fin member cross section employing EPMA. As the composition of Si is reduced near the grain boundaries, the grain boundaries can be identified.
[00069] [00069] Intermetallic compounds can be identified from parts in which the composition of elements, such as Si and Fe, are high. Corresponding positions of grain boundaries and intermetallic compounds can also be identified with SEM (observation of an electron image reflected by the Scanning Electron Microscope) observation of the cross section.
[00070] [00070] The aluminum alloy material for the heat exchanger fin according to the present invention has another microstructure feature after heating for union. In more detail, a joining joint of the aluminum alloy material according to the present invention has a microstructure that, by means of the liquid phase generation mechanism described above, the vicinity s of the Si particles s are fused in the form of a sphere , remaining in the matrix to some extent at the same time, and many eutectic structures, illustrated in Fig. 2d, are dispersed within each grain of the matrix (hereinafter simply referred to as "inside the grain"). The inventors have found that, in the aluminum alloy material according to the present invention in which the bonding performance and the material strength during bonding are satisfactorily balanced, it is preferable to have 10 pieces/mm 2 to 3000 pieces/mm 2 of eutectic structures that have lengths of 3 m or more within the grains in the microstructure after joining in terms of surface density in cross-section of the fin member. Regarding the preferable condition of the microstructure mentioned above, if the surface density of the eutectic structures within the grains is less than 10 pieces/mm 2, the amount of the liquid phase that forms part of the union will be too large, in order to cause difficulty maintenance of resistance during heating for joining in some cases. On the other hand, if the surface density of the eutectic structures within the grains is more than 3000 pieces/mm 2, the amount of the liquid phase that is part of the bond will be too small, in order to reduce the bonding performance in some cases .
[00071] [00071] The eutectic structures within the aforementioned grains are formed by means of a process in which the liquid phase that was generated during heating from the molten vicinity of sphere-shaped Si particles is solidified during cooling. Each of the eutectic structures therefore often takes on a shape close to a sphere. Thus, as illustrated in Fig. 2, these eutectic structures are observed as circular eutectic structures when observed in their cross section. Furthermore, when the liquid phase is generated with intermetallic compounds based on Al-Fe-Mn - Si that serve as nuclei generation sites and remain within the grains, eutectic structures can sometimes be formed that have the following forms. intermetallic compounds based on Al-Fe-Mn-Si.
[00072] [00072] The surface density of the eutectic structures within the grains in the cross section of the eutectic structure can be measured by several methods. With a method using an optical microscope, for example, a cross section of the member constituting the structural body according to the present invention is mechanically polished and eroded using Keller's reagent. The positions of the eutectic structures are then identified. The eutectic structures can be discriminated because the Si-based intermetallic compound phase and the Al phase are finely arranged alternately in the eutectic structures. Furthermore, the positions of the grain boundaries in the relevant cross section are identified with the aid of the anodic oxidation method. Comparing the two identification results, the amount of the eutectic structure that has a length of 3 pm or more existing inside the grains is measured and converted into the surface density.
[00073] [00073] The surface density can also be measured by a method that uses EPMA. This method is intended to analyze surface components of elements, such as Si and Fe, in the cross section of the member that constitutes the structural body using EPMA. Eutectic structures can be identified because a part where the composition of Si is high and another part where it is low are finely arranged alternately in the eutectic structures. Furthermore, grain boundaries can be identified because the Si composition is reduced near the grain boundaries. Eutectic structures can also be identified with SEM observation of the cross section. In this case, grain boundaries are identified using the SEM/EBSB method.
[00074] [00074] The microstructure described above and developed in the aluminum alloy material after heating for the union can be obtained by adjusting its composition and adjusting the heating conditions considering the composition. When the temperature during bonding is high, for example, the liquid phase can be generated in sufficient quantity even with the amount of Si defined as relatively low. More specifically, in the case of a fin member having a plate thickness of 30 m to 100 m, it is preferable that the amount of Si added is from about 1.5% to 3.5% and the heating temperature is about from 580°C to 620°C. In this case, the amount of eutectic structures within the grains is from 20 to 500/mm2 • In this way, satisfactory bonding performance can be obtained by pre-adjusting the amount of Si added to the aluminum alloy material that constitutes a member to be joined in the range of 1.5% to 5.0%, such that the surface density of the eutectic structures within the grains in the cross section of the eutectic structures is in the range of 10/mm2 to 3000/mm2, with observation of the structure after union. Furthermore, the addition of 0.3% or more of Mn is effective in reducing eutectic structures within the grains.
[00075] [00075] A method of manufacturing the aluminum alloy material for the heat exchanger fin according to the present invention will be described below. The aluminum alloy material according to the present invention is molded by means of a DC (direct cooling) molding method and the molding speed of a slab during molding is controlled as follows. As the shaping speed affects the cooling speed, the shaping speed is set to 20 to 100 mm/min. If the modeling speed is less than 20 mm/min, sufficient cooling speed and crystallized intermetallic compounds such as Si-based intermetallic compounds and Al-Fe-Mn-Si-based intermetallic compounds will not be obtained , will become rough. On the other hand, if the shaping speed is more than 100 mm/min, the aluminum material will not solidify sufficiently during shaping and a normal ingot cannot be obtained. Most preferred modeling speed is from 30 to 80 mm/min. Furthermore, in order to obtain the microstructure as one of the features of the present invention, the shaping speed can be adjusted depending on the composition of the alloy material to be manufactured. Although depending on the cross-sectional shape of the slab, including its thickness and width, the cooling speed can be achieved at 0.1 up to 2 °C/sec in a central part of an ingot by setting the shaping speed to 20 to 100 mm/min as described above.
[00076] [00076] The ingot thickness (slab) in the case of using the DC modeling method is preferably of 600 mm or less. If the slab thickness is more than 600 mm, sufficient cooling speed will not be achieved and the intermetallic compounds will become rough. Most preferred slab thickness is 500 mm or less. The slab that has been manufactured using the DC modeling method undergoes a heating step before hot rolling, a hot rolling step, a cold rolling step, and a blending step. After modeling, the slab can be subjected to a homogenization process before hot rolling.
[00077] [00077] The slab that was manufactured using the DC modeling method is subjected to the heating step before hot rolling after the homogenization process or without being subjected to the homogenization process. The heating step is preferably carried out as long as the heating hold temperature is set at 400 to 570°C and the hold time is set at 0 to 15 hours. If the holding temperature is less than 400 °C, the resistance of the slab to deformation during hot rolling will be increased, so as to cause a risk of cracking. If the holding temperature is more than 570 °C, there is a risk of local melting. If the retention time is more than fifteen hours, the precipitation of intermetallic compounds based on Al-Fe-Mn-Si will progress, so that the precipitated deposits will become rough and will be loosely distributed. The incidence of cores for recrystallizing particles during heating for bonding will be higher and grain sizes will be reduced. The expression "where the hold time is 0 hour" indicates that heating ends immediately after reaching the heating hold temperature.
[00078] [00078] Following the heating step, the slab is subjected to a hot rolling step. The hot roll step includes a rough roll stage and a finish roll stage. At this point, the total reduction ratio in the hot rolling rough stage is set at 92 to 97% and the hot rolling stage includes three or more rough rolling passes, in each of which the reduction ratio is 15% or more.
[00079] [00079] In the slab manufactured by the DC modeling method, crude crystallized deposits are generated in a finally solidified part. As the crystallized deposits undergo shear that can be attributed to the roll and are fragmented into smaller pieces in a step of plate rolling, the crystallized deposits are observed in particulate form after the roll. The hot-rolling step includes the hot-rough-rolling stage to roll the slab into a slab that has a certain thickness and a hot-finish rolling stage to roll the slab so that it is about several millimeters thick. Controlling the reduction ratio in the rough hot roll stage to roll the slab is important for the fragmentation of crystallized deposits. More specifically, in the rough hot rolling stage, the slab is rolled from a thickness of 300 to 7 O mm up to a thickness of 15 to 40 mm. Crude crystallized powders can be finely comminuted by setting conditions such that the total reduction ratio in the hot rough-rolling stage is 92 to 97% and the hot-rolling stage includes three or more passes , in each of which the reduction ratio is 15% or more. Under these conditions, Si-based intermetallic compounds and Al-Fe-Mn-Si-based intermetallic compounds, ie crystallized deposits, can become finer and the proper distribution state specified in the present invention.
[00080] [00080] If the total reduction ratio in the rough hot rolling stage is less than 92%, the effect of making the crystallized deposits finer cannot be sufficiently obtained. On the other hand, if it is more than 97%, the slab thickness will be substantially excessive, the cooling speed during modeling will be reduced, and therefore crystallized deposits will become rough. Crystallized deposits cannot, therefore, be sufficiently broken down into finer pieces, even with rough hot rolling. The reduction ratio in each of the passes in the rough hot roll stage also affects the distribution of the intermetallic compounds.
[00081] [00081] Increasing the reduction ratio in each pass, the crystallized deposits are fragmented.
[00082] [00082] After the hot rolling stage, the hot rolled plate is subjected to a cold rolling step. The cold roll step conditions are not limited to specific conditions. Halfway through the cold-rolling step, a blending step is performed to sufficiently combine the cold-rolled slab to obtain a recrystallized structure. After the blending step, the rolled slab is subjected to final cold rolling to have final slab thickness. If the reduction ratio, ie {(plate thickness before roll-plate thickness after roll) I plate thickness before roll} x 100 (%) , in a final cold rolling stage, the forces direction in the recrystallization during heating for the bond will increase and the grains will become smaller, so as to increase the deformation during the heating for the bond. For this reason, as described above, the reduction ratio in the final cold roll stage is defined such that T/To is kept at 1, 40 or less. The reduction ratio in the final cold rolling stage is preferably defined as being from about 10 to 30%.
[00083] [00083] A method of joining the aluminum alloy material according to the present invention will be described below. The present invention utilizes the bonding capability developed by the aluminum alloy material itself without the use of the brazing filler metal. Considering the case where aluminum alloy material is employed as the fin member of a heat exchanger, deformation of the fin member is a serious problem. Consequently, it is also important to control the heating conditions for the union. In more detail, the aluminum alloy material is heated for the time necessary for bonding at a temperature that is in the range of no less than the temperature of the solid and no more than the temperature of liquid at which a liquid phase is generated within the aluminum alloy material according to the present invention and which is no higher than the temperature at which the strength is reduced and the shape cannot be maintained due to the generation of the liquid phase in the aluminum alloy material.
[00084] [00084] As a more specific heating condition, the union needs to be carried out under temperature at which the ratio (hereinafter referred to as "liquid phase ratio") between a liquid phase mass generated in the aluminum alloy material that constitutes the member of fin and a total mass of the relevant aluminum alloy material is more than 0 % and 35 % or less. As bonding cannot be performed unless the liquid phase is generated, the liquid phase ratio needs to be greater than 0%. If the amount of the liquid phase is small, however, the union is difficult in some cases. For this reason,
[00085] [00085] In order to ensure that the liquid phase is sufficiently filled between the fin and another limb, it is also preferable to take into account the time required for filling. From this point of view, the time during which the liquid phase ratio is 5% or more is preferably specified to be 30 seconds or more and 3600 seconds or less. More preferably, the time during which the liquid phase ratio is 5% or more is 60 seconds or more and 1800 seconds or less. With this condition, a more sufficient filling of the liquid phase is ensured and a more reliable union takes place.
[00086] [00086] If the time during which the liquid phase ratio is 5% or more is less than 30 seconds, the liquid phase will not be sufficiently filled in a joining part in some cases. On the other hand, if it is too long than 360 seconds, the deformation of the aluminum material will progress in some cases. It should be noted that, in the joining method according to the present invention, as the liquid phase is moved only in the very close vicinity of the joining part, the time required for filling does not depend on the size of the joining part.
[00087] [00087] As a practical example of the desired heating conditions, in the case of the aluminum alloy material according to the present invention, the union temperature is defined as being from 580 °C to 640 °C and the retention time at the temperature of union is defined to be about O mine 10 min. At this point, 0 mm indicates that cooling begins immediately after the limb temperature reaches the previously determined bonding temperature. The most preferred retention time is from 30 seconds to 5 minutes. With respect to the bonding temperature, in case the Si content is about 1 to 1.5%, for example, the heating temperature for bonding is desirably set in a slightly higher range, ie, 610 to 640 °C. On the other hand, in case the Si content is about 4 to 5%, for example, the heating temperature for the union is desirably set in a slightly higher range, ie 580 to 590 °C. Furthermore, in order for the microstructure of the joining part to enter an appropriate state described later, the heating conditions can be adjusted depending on the composition.
[00088] [00088] It is very difficult to measure the actual liquid phase ratio during heating. The liquid phase ratio specified in the present invention, therefore, is normally determined based on the general rule of thumb of an alloy composition and maximum temperature that can be reached using an equilibrium diagram. In an alloy system for which an equilibrium diagram is already clarified, the liquid phase ratio can be determined based on the general rule using that equilibrium diagram. On the other hand, with reference to an alloy system for which the equilibrium diagram is not published, the liquid phase ratio can be determined using equilibrium phase diagram calculation software.
[00089] [00089] A general rule-based liquid phase ratio determination method employing an alloy and temperature composition is incorporated into the equilibrium phase diagram calculation software. An example of equilibrium phase diagram calculation software is Thermo-Calc, developed by Thermo-Calc Software AB. Even for the alloy system for which the equilibrium diagram is clarified, the equilibrium phase diagram calculation software can also be used for simplification, as the result obtained by calculating the liquid phase ratio with the calculation software The equilibrium phase diagram is the same as obtained by determining the net phase ratio based on the general rule using the equilibrium diagram.
[00090] [00090] Heating atmosphere in heat treatment is preferably a non-oxidizing atmosphere in which air is replaced by nitrogen or argon, for example. More satisfactory bonding performance can be achieved by employing non-corrosive flux. Furthermore, the union can be carried out with vacuum heating or reduced pressure.
[00091] [00091] The non-corrosive flux mentioned above can be applied, for example, by a method of, after assembling the joined members, dusting flux powder on them or a method of suspending flux powder in water and spraying of the suspension solution. In the case of pre-coating the non-corrosive flux onto a material board, the adhesion of a coating can be increased by mixing a binder, such as an acrylic resin, with the flux powder and then coating the mixture. Examples of the non-corrosive flux that is used to obtain the ordinary flux function include fluoride-based fluxes such as KAlF 4 , K z AlFs , K z AlFs · H z O , K 3AlF6 , AlF 3 , KZnF3 and K 2 SiF 6 , and cesium - based fluxes such as Cs 3AlF 6 , CsAlF4 · 2H2 0 and Cs 2 AlF5 ·H2 0 .
[00092] [00092] The aluminum alloy material for the heat exchanger fin according to the present invention can be satisfactorily joined by means of the above-described control of the heat treatment and the heating atmosphere. As the fin member is in the form of a thin plate, however, if the tension generated inside the fin member is too high, the fin form cannot be maintained in some cases. Particularly, when the liquid phase ratio increases during bonding, the shape can be satisfactorily maintained by keeping the tension generated within the fin member comparatively small. When one wishes to take the voltage inside the fin member into account as in the case mentioned above, very stable union can be obtained by satisfying a condition of P 460 - 12 V, where P (kPa) is the maximum value of voltages generated within the fin member and V (%) is the liquid phase ratio. A value indicated by the right side (460 - 12 V) of the above expression represents threshold voltage. If a stress above the threshold stress is generated on the aluminum alloy material in which the liquid phase is generated, there is a risk that great deformation may occur. The tension generated in the fin member can be determined from the shape and the load. Stress can be calculated, for example, using, for example, a structural calculation program.
[00093] [00093] As described above, the aluminum alloy material for the heat exchanger fin according to the present invention is joined by means of a joining method different from the known joining method, such as the brazing method, and can exert a bonding function by heating a single layer of aluminum alloy material. Furthermore, the aluminum alloy material hardly causes changes in size or shape between before and after joining and can satisfy the needs in terms of strength.
[00094] [00094] A heat exchanger constituted by joining a fin member made of the aluminum alloy material according to the present invention with another component member, including another fin member, can be manufactured without the use of a joining material , such as a brazing filler metal, in order to satisfy the cost reduction demand of the equipment.
[00095] [00095] In addition, the heat exchanger obtained by heating and joining the fin member made of aluminum alloy material according to the present invention has the characteristics in microstructure in a fin cross section. More specifically, the amount of triple grain boundary points where Si-based intermetallic compounds and Al-Fe-Mn-Si-based intermetallic compounds that have equivalent circle diameters of 1 m or more exist is 50% or more of the amount of triple points of all grain boundaries. Furthermore, in the fin cross-sectional microstructure, eutectic structures with lengths of 3 m or more exist in quantities from 10/mm2 or more to 3000/mm2 or less within the grains. The heat exchanger according to the present invention is superior in terms of strength, as well as because the fin has the aforementioned characteristics in the microstructure. Brief Description of Figures
[00096] [00096] Fig. 1 illustrates a phase diagram of an Al-Si alloy which is a binary eutectic alloy.
[00097] [00097] Fig. 2 is an explanatory view to explain a mechanism for generating liquid phases in an aluminum alloy material according to the present invention, which is developed with a joining method using the aluminum alloy material.
[00098] [00098] Fig. 3 is an explanatory view to explain a mechanism for generating liquid phases in the aluminum alloy material according to the present invention, which is developed with the joining method using the aluminum alloy material.
[00099] [00099] Fig. 4 is an external view of a laminated test piece in three stages (mini-core) used in the first to third embodiments.
[000100] [000100] Fig. 5 is a diagram illustrating grain boundaries and their triple point.
[000101] [000101] Fig. 6 is an explanatory view illustrating a triple point discrimination method of grain boundaries. Mode of Conducting the Present Invention
[000102] [000102] The present invention will be described in detail below with respect to Examples according to the present invention and Comparative Examples.
[000103] [000103] First realization: Test plates having the compositions A1 to A56 and B1 in Tables 1 and 2 were first molded in sizes 400 mm thick, 1000 mm wide and 3000 mm long by the method of DC modeling.
[000104] [000104] The test plates mentioned above were evaluated to determine the manufacturability in the manufacturing process. The manufacturability was evaluated by a method, in the fabrication of each slab or slab, evaluating the test plate so that it is O (acceptable) when the suitable slab or slab was obtained without causing any problems during the manufacturing process and evaluation of the test plate to be x (unacceptable) when any problem occurs during the manufacturing process, such as the occurrence of cracks during modeling or difficulty in continuing to roll due to the generation of giant intermetallic compounds during modeling.
[000105] [000105] The surface density of the intermetallic compounds in the fabricated plate (material plate) was measured with SEM (observation of a reflected electronic image) observation of a cross section of the plate taken in the direction of the plate thickness. The intermetallic compounds based on Si and the intermetallic compounds based on Al-Fe-Mn-Si were discriminated on the basis of difference, as opposed to the observation of SEM-reflected electronic image. The observation was carried out over three observation fields for each sample.
[000106] [000106] The corresponding surface densities of the Si-based intermetallic compounds that have the equivalent circle diameters from 0.5 prn to 5 prn and the ernAl-Fe-Mn-Si-based intermetallic compounds that have the equivalent circle diameters of 5 prn or more in the sample were measured by image analysis of an SEM photograph in each observation field. Tensile tests were performed on the material before and after heating to join each manufactured plate and after heating at 450 °C for two hours. Tension tests were conducted on each sample at room temperature under conditions of tension velocity of 10 mm/min and measured length of 50 mm according to JIS Z2241. In the tension test after bonding heating, the sample was evaluated by heating it under the same bonding heating conditions defined for a mini-core described below.
[000107] [000107] Then, as illustrated in Fig. 4, each test plate was formed into a fin member that has a width of 16 mm, a crest height of 7 mm and a slope of 2.5 mm. The fin member was combined with a tube member having a thickness of 0.4 mm, which was obtained by electrically soldering a combined plate having the composition B1 in Table 2. A three-stage laminated test piece ( mini-core), illustrated in Fig. 4, was manufactured by assembling the combination of fin members and tube members with the aid of a stainless steel jig.
[000108] [000108] The above mentioned mini-core was dipped in a suspension solution containing 10% flux based on non-corrosive fluoride. After drying, the mini-core was heated in a nitrogen atmosphere under the heating conditions for the union, listed in Table 3, in order to join the tube and fin members together. For Example 16 in accordance with the present invention, the tube and fin members were joined by heating them in a vacuum without applying flow. In addition, the retention time at each specified temperature during bonding was set to three minutes. In the case of the above mentioned mini core, due to the difference in thermal expansion coefficients between the stainless steel template and the aluminum material, a compression load of about 4 N was generated between the stainless steel template and the mini core during heating for union. This indicates that, with calculation based on a joint area, a voltage of about 10 kPa is generated at the joint interface between the fin and tube members.
[000109] [000109] After heating and joining the fin and tube members together, the fin was peeled from the tube and a rate (join rate) of fully joined parts was measured by examining 40 parts of join between the tube and the mini-core fin. The measurement result was determined to be ® (excellent) when the bond rate was 90% or more, O (good) when it was 80% or more and less than 90%, C::. (reasonable) when it was 70% or more and less than 80% and x (poor) when it was less than 70%.
[000110] [000110] Deformation rate attributable to fin bowing was also evaluated by measuring fin height on the mini-core before and after union. The strain rate was determined to be ® (excellent) when the rate of change in fin height between before and after union with respect to fin height before union was 5% or less, O (good) when it was of more than 5% and 10% or less, C::.(reasonable) when it was more than 10% and 15% or less ex (poor) when it was more than 15%.
[000111] [000111] The material structure of each sample after heating for bonding was also examined in the first run. The study was carried out by embedding the mini-core after bonding it in a resin, polishing it and observing the structure in cross section of the limb with an optical microscope. In more detail, grain sizes were first measured by observing a cross section of the limb, taken in the direction of the plate thickness, after polishing and etching with an optical microscope. As a measurement method, the mean grain length was measured in the center of the plate thickness direction according to ASTME112-96.
[000112] [000112] In addition, the surface density of eutectic structures within the grains, which have lengths of 3 m or more, was measured. The measurement was carried out by polishing and etching a cross section of the member, where the cross section is perpendicular to the direction of the plate thickness, and by observing the structure in the cross section of the member with an optical microscope. Furthermore, after milling the member cross section in a similar way, the cross section was eroded using Keller's reagent, for example, and the positions of the intermetallic compounds were identified.
[000113] [000113] Furthermore, the grain boundaries in the relevant cross section became clearer with the anodic oxidation method and the positions of the triple points of the grain boundaries were identified. By comparing the positions of the intermetallic compounds and the positions of the triple grain boundary points, the rate of the number of triple grain boundary points where there are intermetallic compounds having equivalent circle diameters of 1 pm or more was determined with respect to the amount of triple points of all grain boundaries. For unclear region, the surface components of elements such as Si, Fe and Mn were analyzed using EPMA. As a result, parts where the Si composition was reduced in a linear fashion were identified as grain boundaries and parts where the compositions of other elements such as Si and Fe were high were identified as intermetallic compounds. From the amount of triple points of all grain boundaries, the rate of the number of triple points of grain boundaries where there are intermetallic compounds that have the equivalent circle diameters of 1 pm or more was determined. The observation was carried out using an isolated plate sample that was heated under heating conditions for union identical to those of the mini-core and the measurement was carried out for five observation fields at a magnification of 200.
[000114] [000114] Tables 3 and 4 list the corresponding evaluation results of the manufacturability, the surface density of the intermetallic compounds, the tensile strength and the material structure after heating for joining for each test piece, as well as the mini-core union test. Tables 3 and 4 further list the equilibrium liquid phase rates under the bonding conditions (ie, heating temperature) for each sample. The equilibrium net phase rate is a calculated value obtained using the equilibrium phase diagram calculation software. It should be noted that E+ in Tables 3 and 4 indicates exponential notation. 1, 2 . E+03, for example, indicates 1, 2x103 •
[000115] [000115] As noted in Tables 3 and 4, the manufacturability was acceptable in the samples that satisfied the conditions specified in the present invention with respect to the composition of the aluminum alloy material and the heating conditions. On the other hand, in the sample roll which has the A55 alloy composition, the relevant sample cannot be rolled to the final plate thickness because Fe exceeded the specified amount and giant intermetallic compounds were generated during packaging.
[000116] [000116] Comparing, as for the results of the bonding tests, the evaluation results of the individual mini-core samples with the compositions (Tables 1 and 2) of the aluminum alloy materials of the fin members, the bonding rate, fin arching and tension length were all acceptable in the samples (Examples 1 to 37 according to the present invention), which satisfied the conditions specified in the present invention with reference to aluminum alloy material and heating conditions. For Examples 15 to 27 according to the present invention that samples were made of alloys containing, as additive elements, Mg, Ni, Ti, V, Zr and Cr in addition to Si, Fe and Mn as essential elements, it was confirmed that the results of the evaluation of the strain rate were more satisfactory and that these elements had the effect of increasing strength.
[000117] [000117] On the other hand, in Comparative Example 1, as the Si component did not reach the specified amount and the surface density of the Si-based intermetallic compounds in the material plate also did not reach the specified value, the generation speed of liquid phase was up to less than 5%, even with the heating temperature set to relatively high. In this way, the join rate was reduced and the joining performance was lower.
[000118] [000118] In Comparative Example 2, as the Si component exceeded the specified amount and the surface density of intermetallic compounds based on Al-Fe-Mn-Si in the material plate also exceeded the specified value, the liquid phase rate during bonding it increased, even with the heating temperature set to be relatively low. Also, the grain sizes after heating were small. In this way, the fin bent and the strain rate was unacceptable.
[000119] [000119] In Comparative Example 3, as the Fe component did not reach the specified amount and the surface density of intermetallic compounds based on Al-Fe-Mn-Si in the material plate also did not reach the specified value, the resistances before and after heating were low and unacceptable. Furthermore, the fin curled and the strain rate was also unacceptable.
[000120] [000120] In Comparative Example 4, as the Mn component did not reach the specified amount and the surface density of intermetallic compounds based on Al-Fe-Mn-Si in the material plate also did not reach the specified value, the resistances before and after heating were low and unacceptable. Furthermore, the fin curled and the strain rate was also unacceptable.
[000121] [000121] In Comparative Example 5, as the Fe component exceeded the specified amount, there was a problem in the manufacturability and the evaluation by the bond test could not be performed.
[000122] [000122] In Comparative Example 6, as the Mn component exceeded the specified amount and the surface density of intermetallic compounds based on Al-Fe -Mn -Si in the material plate did not reach the specified value, the resistances before and after the heating were low and unacceptable. Furthermore, the fin bent and the strain rate was also unacceptable.
[000123] [000123] In Comparative Examples 7 to 9, as the reduction ratio in the final cold rolling stage was higher and T /To exceeded the specified value, the grains became too fine during heating for bonding and the rate of deformation was unacceptable. Second Embodiment: In a second embodiment, the influences of heating temperature as one of the bonding conditions were examined. The material plates manufactured in the first embodiment were optionally selected as listed in Table 3 and were molded into fins similar to those in the first embodiment. In addition, as in the first embodiment, three-stage laminated test pieces (mini cores (Fig. 4) were fabricated, each of the mini cores was dipped in a suspension solution containing 10% flux based on non-corrosive fluoride.
[000124] [000124] After drying, the mini cores were heated to various heating temperatures and kept there for previously determined times, listed in Table 3, in a nitrogen atmosphere, in order to join the tube and fin members together. The bond rate and deformation rate that can be attributed to fin bowing were evaluated in the same way as in the first embodiment by measuring the bond rate and the dimensional change after bonding. Furthermore, as in the first embodiment, the cross-sectional structure of each member was observed to determine the surface density of the intermetallic compounds, the grain sizes after heating for bonding, the surface density of the eutectic structures that have lengths of 3 µlm or more inside the grains and the ratio of the amount of triple stitches of the grain boundaries in which intermetallic compounds having the equivalent circle diameters of 1 µm or more exist with respect to the amount of triple stitches of all grain boundaries Evaluation results are listed in Table 5 . It should be noted that , in Table 5 , 3 , 1E+03 , for example , indicates 3 , lxl0 3 •
[000125] [000125] As described above, when joining the aluminum alloy material according to the present invention, it is preferable that the heating temperature is set to the temperature at which the liquid phase rate is 5 to 30% and the time during which the liquid phase rate is 5% or more is 30 seconds or more and 3600 seconds or less. As seen in Table 3, in Examples 38 to 46 according to the present invention, all these conditions are satisfied and the bond rate and strain rate were both acceptable.
[000126] [000126] On the other hand, in Reference Examples 1 and 3, as the heating temperature was high and the liquid phase rate was too high, the shape could not be maintained, so as to cause great deformation. In Reference Example 2, as the heating temperature was low and the liquid phase rate was also low, the binding was insufficient.
[000127] [000127] In Reference Example 4, as the retention time during which the liquid phase rate was 5% or more was short, the bond rate was insufficient. In Reference Example 5, as the retention time during which the liquid phase rate was 5% or more was too long, large deformation occurred.
[000128] [000128] Third achievement:
[000129] [000129] In a third embodiment, the influences of additive elements upon corrosion resistance were examined. The material plates fabricated in the first embodiment were optionally selected as listed in Table 6 and were molded into fins similar to those in the first embodiment. In addition, as in the first realization, test pieces laminated in three stages (mini cores) were manufactured (Fig. 4). Each of the mini cores was dipped in a suspension solution containing 10% non-corrosive fluoride-based flux. After drying, the mini cores were heated to various heating temperatures and kept there for previously determined times, listed in Table 3, in a nitrogen atmosphere, in order to join the fins and the tubes together.
[000130] [000130] The bond rate and the deformation rate were evaluated in the same way as in the first embodiment by measuring the bond rate and the dimensional change after bonding. Also, as in the first embodiment, the cross-sectional structure of each member was observed to determine the surface density of the intermetallic compounds, in which the surface density of eutectic structures that have lengths of 3 µm or more inside the grains and the rate of the amount of triple points of grain boundaries at which there are the intermetallic compounds that have the equivalent circle diameters of 1 µlm or more with respect to the amount of triple points of all grain boundaries.
[000131] [000131] In addition, to evaluate the corrosion resistance of the fin itself, the CASS test was conducted for five hundred hours and the fin corrosion status was confirmed. Observing a cross section of the fin with an optical microscope, it was determined that the corrosion state is ® (excellent) when the rate of the remaining fin was 70% or more, O (good) when it was 50% or more and less than 70%, t, (reasonable) when it was 30% or more and less than 50% and ex (poor) when it was less than 30%.
[000132] [000132] The evaluation results are listed in Table 6 . It should be noted that , in Table 6 , for example ,2 , 3 . E+03 indicates 2,3x10 3 •
[000133] [000133] In Examples 48 to 60 according to the third embodiment of the present invention, aluminum alloys containing, as additive elements, Cu, Zn, In, Sn, Ti and V in addition to the essential elements, i.e., Si, Fe and Mn were used as samples. In these Examples according to the present invention, as seen in Table 6, the corrosion resistance was improved compared to an alloy used in Example 47 according to the present invention which does not contain Zn etc. In this way, the usefulness of the additive elements mentioned above was confirmed.
[000134] [000134] In fourth embodiment, the influences of changes in the distribution of intermetallic compounds in the aluminum alloy material on the bonding performance due to the manufacturing process were examined. The material plates fabricated in the first embodiment were optionally selected as listed in Table 7 and were molded into fins similar to those in the first embodiment under fabrication conditions listed in Table 7. In addition, as in the first embodiment, test pieces were fabricated in laminated three stages (mininuclei) (Fig. 4). Each of the micronuclei was immersed in a suspension solution containing 10% non-corrosive fluoride-based flux. After drying, the mininuclei were heated to 600 °C and kept in them for a three-minute maintenance time in a nitrogen atmosphere, in order to join the fins and tubes together. Manufacturability was also assessed as in the first run (Table 7).
[000135] [000135] The bond rate and the strain rate that can be attributed to the fin's bow were evaluated in the same way as in the first realization by measuring the bond rate and the dimensional change after bonding. In addition, as in the first embodiment, the cross-sectional structure of each member was observed to determine the surface density of the intermetallic compounds, the grain sizes after heating for bonding, the surface density of the eutectic structures having lengths of 3 pm or more inside the grains and the rate of the amount of triple stitches of the grain boundaries in which intermetallic compounds having the equivalent circle diameters of lpm or more exist with respect to the amount of triple stitches of all grain boundaries . The evaluation results are listed in Table 8.
[000136] [000136] Table 8 further lists the measurement results with respect to measuring the surface density of the intermetallic compounds before heating for bonding, not just corresponding surface densities of the Si-based intermetallic compounds having the equivalent circle diameters from 0.5 pm to 5 pm and the Al-Fe-Mn-Si based intermetallic compounds which have the equivalent circle diameters of 5 pm or more, but also the Si-based intermetallic compounds which have the equivalent circle diameters of 5 pm or more and the Al - Fe - Mn - Si based intermetallic compounds having the equivalent circle diameters of 0.5 pm or more and 5 pm or less and 10 pm or more . It should be noted that, in Table 8, for example, 3 , 1.
[000137] [000137] In samples (Examples 61 to 74 according to the present invention) manufactured according to the method according to the present invention, both the bond rate and the strain rate were acceptable.
[000138] [000138] On the other hand, in Comparative Example 1O, as the modeling speed was too low, the surface density of the Si-based intermetallic compounds in the material plate did not reach the specified value and the surface density of the intermetallic compounds with base on Al-Fe-Mn-Si in the material plate has exceeded the specified value.
[000139] [000139] In this way, due to the roughness of the intermetallic compounds based on Si and the intermetallic compounds based on Al - Fe -Mn - Si, the grain sizes after heating were reduced, so that the fin bent and the strain rate was unacceptable. Furthermore, as the amount of Si-based intermetallic compounds satisfying the specified surface density was reduced, the bond rate was unacceptable.
[000140] [000140] In Comparative Example 11, as the forming speed was too high, cracks occurred due to ingot fabrication and the sample plate could not be fabricated. In Comparative Example 12, the total reduction ratio in the hot rough rolling stage was less than the specified value and the Si-based intermetallic compounds and the Al-Fe-Mn-Si-based intermetallic compounds in the material plate did not have become thin enough. Therefore, the surface density of the Si-based intermetallic compounds in the material plate did not reach the specified value and the bond rate was unacceptable. Furthermore,
[000141] [000141] In Comparative Example 13, as the thickness of the slab after the front position was too large, the total reduction ratio in the rough hot rolling stage was greater than the specified value. As the ingot thickness was too great, the cooling speed during ingot manufacture was reduced and crude precipitated deposits were generated. The crude precipitated deposits were not sufficiently fragmented in the rough hot rolling stage, so that the surface density of the Si-based intermetallic compounds in the material plate did not reach the specified value and the surface density of the Si-based intermetallic compounds Al-Fe-Mn-Si in the material plate has exceeded the specified value. Grain sizes after heating were reduced due to the coarseness of the intermetallic compounds. As a result, the fin bent and the rate of deformation was unacceptable. As the surface density of the Si-based intermetallic compounds in the material plate did not reach the specified value, the bond rate was low and unacceptable.
[000142] [000142] In Comparative Example 14, the number of passes in which the reduction ratio was 15% or more was less than three in the rough hot roll stage. Intermetallic compounds based on Al-Fe-Mn-Si, therefore, did not become sufficiently finer and the surface density of these intermetallic compounds exceeded the specified value. Liquid phases were generated around intermetallic compounds based on crude Al-Fe-Mn-Si and the rate of sets of liquid phases occupying the plate thickness increased. As a result, the fin wrinkled and the rate of deformation was unacceptable. industrial applicability
[000143] [000143] The aluminum alloy material according to the present invention is useful as a heat exchanger fin member and can be joined to another heat exchanger component member, including another fin member, without the use of a material such as a brazing filler metal or a brazing material. The heat exchanger, therefore, can be efficiently manufactured. Size and shape changes hardly occur due to the joining of the aluminum alloy material. In this way, the aluminum alloy material and the joining method using the aluminum alloy material according to the present invention are remarkably effective from an industrial point of view.

权利要求:
Claims (12)
[1]
1. Aluminum alloy material for a heat exchanger fin, characterized in that it has superior bonding function by heating a single layer of aluminum alloy material containing Si: 1.0 to 5.0% in mass, Fe: O, 1 to 2.0% by mass and Mn: 0.1 to 2.0% by mass, where the balance is Ale unavoidable impurities; where 250 pieces/mm2 or more to 7 x 104 pieces/mm2 or less of Si-based intermetallic compounds particles having equivalent circle diameters of 0.5 to 5 J.lm are present in cross section of the alloy material aluminum; and where 10 pieces/mm2 or more and 1000 pieces/mm2 or less of the Al-Fe-Mn-Si based intermetallic compounds having equivalent circle diameters of more than 5 J.lm are present in a material cross section of aluminum alloy.
[2]
2. Aluminum alloy material for the heat exchanger fin according to claim 1, characterized in that the aluminum alloy material is configured to satisfy T/To 1.40, where T indicates tensile strength of a plate of material and To indicates tensile strength after heating at 450 °C for two hours.
[3]
3. Aluminum alloy material for the heat exchanger fin according to any of claims 1 or 2, characterized in that it additionally contains one or two selected from Mg: 2.0% by mass or less and Cu : 1.5% by mass or less.
[4]
An aluminum alloy material for the heat exchanger fin according to any of the claims
1 to 3, characterized in that it additionally contains one, two or more selected from Zn: 6.0% by mass or less, In: 0.3% by mass or less and Sn: 0.3% by mass or less .
[5]
5. Aluminum alloy material for the heat exchanger fin according to any of claims 1 to 4, characterized in that it additionally contains one, two or more selected from Ti: 0.3% by mass or less , V : 0.3 % by mass or less , Zr : 0.3 % by mass or less , Cr : 0.3 % by mass or less and Ni : 2.0 % by mass or less .
[6]
6. Aluminum alloy material for the heat exchanger fin according to any of claims 1 to 5, characterized in that it additionally contains one, two or more selected from Be: 0.1% by mass or less , Sr : 0.1% by mass or less , Bi : 0.1% by mass or less , Na : 0.1 % by mass or less and Ca : 0.05 % by mass or less.
[7]
7. Aluminum alloy material for the heat exchanger fin according to any of claims 1 to 6, characterized in that the tensile strength of the aluminum alloy material before heating for joining is 80 to 250 MPa .
[8]
8. Method of manufacturing the aluminum alloy material for the heat exchanger fin according to any of claims 1 to 7, characterized in that the method comprises a step of modeling an aluminum alloy for the material. aluminum alloy, a step of heating a molded ingot before hot rolling, a step of hot rolling the ingot after the heating step, a step of cold rolling a hot rolled plate and a step of combining a cold rolled plate halfway through the cold roll step; where the modeling speed is defined to be from 20 to 100 mm/min in the modeling step; and wherein, although the hot rolling step includes a rough rolling stage and a finishing rolling stage, the total reduction ratio in the rough rolling stage is defined as 92 to 97% and the rough rolling stage includes three or more passes, in each of which the reduction ratio is 15% or more.
[9]
9. Heat exchanger manufactured by heating and joining a fin member, characterized in that it is made with the aluminum alloy material as defined in any of claims 1 to 7 and another component member of the heat exchanger together .
[10]
10. Heat exchanger according to claim 9, characterized in that the aluminum alloy material for the fin member has, after heating for the union, a microstructure in which the grain size of the aluminum matrix is preferably 50 µlm or more in a cross section of the fin.
[11]
11. Heat exchanger according to any of claims 9 or 10, characterized in that in the microstructure in the cross section of the fin member aluminum alloy material after heating for the union, the number of triple points of boundaries of grains in which there are intermetallic compounds that have equivalent circle diameters of 1 J.lm or more, is 50% or more of the total amount of triple points of all grain boundaries.
[12]
12. Heat exchanger according to any of claims 9 to 11, characterized in that the microstructure in a cross section of the aluminum alloy material for the fin member after heating for the union has 10 pieces/mm2 to 3000 pieces/mm2 of eutectic structures that have lengths of 3 m or more inside matrix grains.

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同族专利:

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公开号 | 公开日

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IN2014MN01665A|2015-05-29|

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JPWO2013111884A1|2015-05-11|

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KR101581609B1|2015-12-30|

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KR20140116941A|2014-10-06|

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US10024611B2|2018-07-17|

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CN103906852A|2014-07-02|

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EP2808410B1|2019-07-03|

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EP2808410A4|2016-01-20|

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MY164145A|2017-11-30|

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EP2808410A1|2014-12-03|

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法律状态:
2021-06-29| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|

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2021-07-06| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|

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2021-12-28| B06A| Patent application procedure suspended [chapter 6.1 patent gazette]|

优先权:

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申请号 | 申请日 | 专利标题

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JPJP2012-014939|2012-01-27|

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JP2012014939|2012-01-27|

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PCT/JP2013/051664|WO2013111884A1|2012-01-27|2013-01-25|Aluminum alloy for heat exchanger fin and manufacturing method therefor, as well as heat exchanger using said aluminum alloy|

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