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    • 专利摘要:
    abstract patent of invention: "cold rolled steel sheet and method for producing cold rolled steel sheet". cold rolled steel sheet according to the present invention satisfies the expression of (5 × [si] + [mn]) / [c]> 11, when [c] represents the quantity of c in mass%, [si] represents the amount of si in,% by mass, and [mn] represents the amount of mn in% by mass, and the metallographic structure before hot stamping includes 40% to 90% ferrite and 10% to 60% martensite in fraction of area, the total of the fraction of ferrite area and the fraction of area of martensite is 60% or greater, the hardness of the martensite measured with a nanoindenter satisfies h2 / h1 <1.10 and shm <20 before hot stamping, and ts ×? what is the product of the tensile strength ts by the bore expansion ratio? is 50000mpa?% or greater.
    公开号:BR112014017020B1
    申请号:R112014017020
    申请日:2013-01-11
    公开日:2020-04-14
    发明作者:Kawasaki Kaoru；Kato Satoshi；Nonaka Toshiki；Tomokiyo Toshimasa
    申请人:Nippon Steel & Sumitomo Metal Corp；Nippon Steel Corp；
    IPC主号:
    专利说明:

    Descriptive Report of the Invention Patent for COLD LAMINATED STEEL SHEET AND METHOD FOR PRODUCING COLD LAMINATED STEEL SHEET.
    Technical Field of the Invention [001] The present invention relates to a cold rolled steel sheet having an excellent forming capacity before hot stamping and / or after hot stamping, and a method for producing it.
    [002] Priority is claimed over Japanese patent application No. 2012-004549, registered on January 13, 2012, and over Japanese patent application No. 2012-004864, registered on January 13, 2012, whose contents are incorporated here by reference.
    Relative technique [003] Currently, a steel plate for a vehicle needs to be improved in terms of crash safety and have a reduced weight. In such a situation, hot stamping (also called hot processing, hot stamping, die hardening, or the like) is drawing attention as a method to obtain high strength. Hot stamping refers to a forming method in which a steel plate is heated to a high temperature of, for example, 700 ° C or more, and then hot forming in order to improve the forming capacity of the plate. steel, and quenched by cooling after forming, thus obtaining the desired material qualities. As described above, the steel plate used for the chassis structure of a vehicle must have a high pressing work capacity and a high strength. A steel plate that has a ferrite and martensite structure, a steel plate that has a ferrite and bainite structure, a steel plate that contains austenite retained in the structure or similar, is known
    Petition 870180161107, of 10/12/2018, p. 11/77
    2/47 as a steel sheet that has both the ability to work presses and high strength. Among these steel sheets, a multi-stage steel sheet having martensite dispersed on a ferrite base has a low elasticity limit and a high tensile strength and, in addition, has excellent elongation characteristics. However, the multi-phase steel sheet has insufficient hole expansion capacity since stress is concentrated at the interface between ferrite and martensite, and the fracture is likely to start from the interface.
    [004] For example, Patent Documents 1 to 3 describe the multi-stage steel sheet. In addition, Patent Documents 4 to 6 describe relationships between the hardness and the forming ability of a steel sheet.
    [005] However, even with these techniques of relative technique, it is difficult to obtain a steel plate that meets the current requirements for a vehicle such as additional weight reduction and more complicated component shapes.
    Prior Art Documents [006] Patent Documents [007] [Patent Document 1] Unexamined Japanese Patent Application, First Publication No. H6-128688 [008] [Patent Document 2] Unexamined Japanese Patent Application publication n ° 2000-319756 [009] [Patent Document 3] Unexamined Japanese patent application, first publication n ° 2005-120436 [0010] [Patent Document 4] Unexamined Japanese patent application, first publication n ° 2005 -256141 [0011] [Patent Document 5] Japanese patent application not examined, first publication n ° 2001-355044
    Petition 870180161107, of 10/12/2018, p. 12/77
    3/47 [0012] [Patent Document 6] Japanese patent application not examined, first publication No. H11-189842
    Description of the Invention
    Problems to be solved by the invention [0013] An object of the present invention is to provide a cold-rolled steel sheet, a hot-dip galvanized cold-rolled steel sheet, a galvannealed cold-rolled steel sheet, a steel sheet cold rolled electrogalvanized and a cold rolled steel sheet aluminized, which are able to guarantee resistance before and after hot stamping and have a more favorable hole expansion capacity, and a method of production of the same.
    Means to solve the problems [0014] The present inventors carried out intensive studies in relation to a cold-rolled steel sheet, to a hot-dip galvanized cold-rolled steel sheet, to a galvannealed cold-rolled steel sheet, to an electrogalvanized cold-rolled steel sheet, and an aluminized cold-rolled steel sheet that guaranteed strength before hot stamping (before heating to perform the hot stamping process) and / or after hot stamping ( after quenching in a hot stamping process), and having an excellent forming capacity (hole expansion capacity). As a result, it was discovered that, in relation to the steel composition, when an adequate relationship is established between the amount of Si, the amount of Mn and the amount of C, the fraction of ferrite and the fraction of martensite in the steel plate are adjusted for predetermined fractions, and the hardness ratio (hardness difference) of the martensite between the surface part of the sheet thickness and the central part of the steel sheet thickness and the hardness distribution of the martensite in the central part of the sp
    Petition 870180161107, of 10/12/2018, p. 13/77
    4/47 plate thicknesses are adjusted in specific ranges, it is possible to industrially produce a cold rolled steel plate capable of guaranteeing, in the steel plate, a greater forming capacity than ever, that is, a characteristic of TS χ λ> 50000MPa-% which is the product of TS tensile strength and bore expansion capacity λ. In addition, it has been found that when this cold rolled steel sheet is used for hot stamping, a steel sheet having excellent forming capacity even after hot stamping can be obtained. In addition, it was also clarified that suppression of MnS segregation in the central part of the cold rolled steel sheet thickness is also effective in improving the forming capacity (hole expansion capacity) of the steel sheet before hot stamping and / or after hot stamping. In addition, it was also found that, in cold rolling, an adjustment in the fraction of the reduction of cold rolling to the total reduction of cold rolling (reduction of cumulative rolling) from a first chair to the third chair based on first chair within a specific range is effective in controlling the martensite hardness. In addition, the inventors have discovered a variety of aspects of the present invention as described below. In addition, it has been found that the effects are not impaired even when the hot-dip galvanized layer, the galvannealed layer, an electro-galvanized layer and an aluminized layer are formed on the cold-rolled steel sheet.
    [0015] That is, according to a first aspect of the present invention, the cold rolled steel sheet includes, in% by weight, C: 0.030% to 0.150%, Si: 0.010% to 1,000%, Mn: 1, 50% to 2.70%, P: 0.001% to 0.060%, S: 0.001% to 0.010%, N: 0.0005% to 0.0100%, Al: 0.010% to 0.050%, and optionally one or more elements between B: 0.0005% to 0.0020%, Mo: 0.01% to 0.50%, Cr: 0.01% to 0.50%, V:
    Petition 870180161107, of 10/12/2018, p. 14/77
    5/47
    0.001% to 0.100%, Ti: 0.001% to 0.100%, Nb: 0.001% to 0.050%, Ni: 0.01% to 1.00%, Cu: 0.01% to 1.00%, Ca: 0, 0005% to 0.0050%, REM: 0.0005% to 0.0050%, and the balance including Fe and the inevitable impurities, in which, when [C] represents the amount of C in mass%, [Si] represents the amount of Si in% by mass, and [Mn] represents the amount of Mn in% by mass, the expression (A) below is satisfied, the metallographic structure before a hot stamping includes 40% to 90% of ferrite and 10% to 60% martensite in a fraction of area, the total fraction of the area of ferrite and the fraction of area of martensite is 60% or more, the metallographic structure can optionally also include one or more between 10% or less than perlite in a fraction of area, 5% or less of an austenite retained in a volume ratio, and less than 40% of a bainite like the rest in a fraction of area, the hardness of martensite measured with a nanoindentator satisfies the expression (B) below and the expression (C) then before the hot stamping, TS x λ which is a product of a tensile strength TS for a bore expansion ratio λ is 50000MPa-% or more.
    (5 x [Si] + [Mn]) / [C]> 11 (A),
    H2 / H1 <1.10 (B), aHM <20 (C), and [0016] H1 is the average hardness of the martensite on the surface part of the sheet thickness before hot stamping, H2 is the average hardness of the martensite on a part of the surface in the central part of the sheet thickness which is an area having a width of 200 pm in the direction of the thickness in the center of the sheet thickness before hot stamping, and aHM is a variation of the hardness of the martensite in the central part the thickness of the plate before hot stamping.
    Petition 870180161107, of 10/12/2018, p. 15/77
    6/47 [0017] In the cold rolled steel sheet as per item (1) above, the fraction of MnS area that exists in the cold rolled steel sheet and which has an equivalent circle diameter of 0.1 pm at 10 pm can be 0.01% or less, and the expression (D) below can be satisfied.
    n2 / n1 <1.5 (D), and [0018] n1 is the average numerical density per 10,000 pm 2 of MnS that has an equivalent circle diameter of 0.1 pm to 10 pm in a part 1/4 of the plate thickness before hot stamping, and n2 is the average numerical density per 10,000 pm 2 of MnS which has an equivalent circle diameter of 0.1 pm to 10 pm in the central part of the plate thickness before hot stamping.
    [0019] In hot stamped steel according to item (1) or (2) above, a galvanization can be formed on its surface.
    [0020] In accordance with another aspect of the present invention, a method is provided to produce a cold-rolled steel sheet including ingot a molten steel having the chemical composition according to item (1) above and obtain a steel, heat the steel, laminating hot steel with a hot strip mill including a plurality of chairs, winding the steel after hot rolling, stripping the steel during coiling, cold rolling the steel with a hot strip laminator including a plurality of chairs after blasting under a condition that satisfies the expression (E) below, perform annealing in which the steel is annealed under 700 ° C to 850 ° C and cooled after cold rolling, perform hardening lamination on the steel after annealing.
    1.5 x r1 / r + 1.2 x r2 / r + r3 / r> 1.0 (E), and [0021] the ri (i = 1, 2, 3) represents the reduction of individual hot rolling desired in an i the chair (i = 1, 2, 3) based on the first chair in the plurality of chairs in cold rolling in unit%, and r represents the total reduction of cold rolling in unit%.
    Petition 870180161107, of 10/12/2018, p. 16/77
    7/47 [0022] The method for producing the cold rolled steel sheet as per item (4) above may also include galvanizing the steel between annealing and hardening lamination.
    [0023] In the method for producing the cold rolled steel sheet as per item (4) above, when CT represents the winding temperature in the winding in units of ° C, [C] represents the amount of C in mass%, [Mn] represents the amount of Mn in% by weight, [Cr] represents the amount of Cr in% by weight, and [Mo] represents the amount of Mo in% by weight on the steel plate, the expression (F) a following can be satisfied.
    560 - 474 χ [C] - 90 χ [Mn] - 20 χ [Cr] - 20 χ [Mo] <CT <830 - 270 χ [C] - 90 χ [Mn] - 70 χ [Cr] - 80 χ [Mo] (F).
    [0024] In the method for producing the cold-rolled steel sheet according to item (6) above, when T represents the heating temperature in heating in units of ° C, t represents the time in the heating oven in units of minutes, [Mn] represents the amount of Mn in% by mass, and [S] represents the amount of S in% by mass in the steel plate, the expression (G) below can be satisfied.
    T χ ln (t) / (1.7 [Mn] + [S])> 1500 (G).
    [0025] That is, according to a first aspect of the present invention, a cold rolled steel sheet is provided for hot stamping including, in mass%, C: 0.030% to 0.150%, Si: 0.010% to 1,000 %, Mn: 1.50% to 2.70%, P: 0.001% to 0.060%, S: 0.001% to 0.010%, N: 0.0005% to 0.0100%, Al: 0.010% to 0.050%, and optionally one or more elements between B: 0.0005% to 0.0020%, Mo: 0.01% to 0.50%, Cr: 0.01% to 0.50%, V: 0.001% to 0.100% , Ti: 0.001% to 0.100%, Nb: 0.001% to 0.050%, Ni: 0.01% to 1.00%, Cu: 0.01% to 1.00%, Ca: 0.0005% to 0, 0050%, REM: 0.0005% to 0.0050%, and the balance including Fe and the inevitable impurities, in which,
    Petition 870180161107, of 10/12/2018, p. 17/77
    8/47 when [C] represents the amount of C in mass%, [Si] represents the amount of Si in mass%, and [Mn] represents the amount of Mn in mass%, the expression (H) a following is satisfied, the metallographic structure after hot stamping includes 40% to 90% of ferrite and 10% to 60% of martensite in fraction of area, the total fraction of ferrite area and fraction of area, is 60% or more, the metallographic structure may optionally also include one or more between 10% or less of perlite in fraction of area, 5% or less of austenite retained in fraction of volume, and less than 40% of bainite as remaining in the fraction of area , the martensite hardness measured with a nanoindentator satisfies the expression (I) below and the expression (J) following after the hot stamping, TS χ λ which is the product of the tensile strength TS by the bore expansion ratio λ is 50000MPa-% or more.
    (5 χ [Si] + [Mn]) / [C]> 11 (H),
    H21 / H11 <1.10 (I), oHM1 <20 (J), and [0026] H11 is the average hardness of the martensite on the surface part of the sheet thickness after hot stamping, H21 is the average hardness of the martensite on the part central thickness of the sheet which is an area having a width of 200 pm in the direction of the thickness in the center of the sheet thickness after hot stamping, and aHM1 is the variation in the average hardness of the martensite in the central part of the sheet thickness after hot stamping.
    [0027] In cold rolled steel sheet for hot stamping as per item (8) above, the fraction of MnS area that exists in cold rolled steel sheet and which has an equivalent circle diameter of 0.1 pm at 10 pm it can be 0.01% or less, and the expression (K) below can be satisfied.
    n21 / n11 <1.5 (K), and
    Petition 870180161107, of 10/12/2018, p. 18/77
    9/47 [0028] n11 is the average numerical density per 10,000 pm 2 of MnS that has an equivalent circle diameter of 0.1 pm to 10 pm in the 1/4 part of the plate thickness after hot stamping, and n21 is the average numerical density per 10,000 pm 2 of the MnS which has an equivalent circle diameter of 0.1 pm to 10 pm in the central part of the sheet thickness after hot stamping.
    [0029] In the cold rolled steel plate for hot stamping according to item (8) or (9) above, a hot dip galvanization can be formed on its surface.
    [0030] In the cold rolled steel plate for hot stamping as per item (10) above, a galvanizing annealing can be formed on the surface of the hot dip galvanizing.
    [0031] In the cold rolled steel plate for hot stamping according to item (8) or (9) above, an electroplating can be formed on its surface.
    [0032] In the cold rolled steel plate for hot stamping according to item (8) or (9) above, an aluminization can be formed on its surface.
    [0033] According to another aspect of the present invention, a method is provided for producing a cold rolled steel sheet for hot stamping including casting a molten steel having a chemical composition as per item (8) above and obtaining a steel , heating the steel, hot rolling the steel with a hot strip mill including a plurality of chairs, winding the steel after hot rolling, stripping the steel after winding, cold rolling the steel with a hot strip laminator cold including a plurality of chairs after blasting under a condition that meets the expression (L) below, perform annealing in which the steel is annealed under 700 ° C to 850 ° C and cooled after cold rolling, and perform hardening lamination on steel after annealing.
    Petition 870180161107, of 10/12/2018, p. 19/77
    10/47
    1.5 χ r1 / r + 1.2 χ r2 / r + r3 / r> 1 (L), and [0034] ri (i = 1, 2, 3) represents the reduction in individual cold rolling desired in i the chair (i = 1, 2, 3) based on the first chair in the plurality of chairs in cold rolling in units of%, er represents the total reduction in cold rolling in units of%.
    [0035] In the method for producing the cold rolled steel sheet for hot stamping according to item (14) above, when CT represents the winding temperature in units of ° C, [C] represents the amount of C in% in mass, [Mn] represents the amount of Mn in mass%, [Si] represents the amount of Si in mass%, and [Mo] represents the amount of Mo in mass% in the steel plate, the expression (M ) below can be satisfied.
    560 - 474 χ [C] - 90 χ [Mn] - 20 χ [Cr] - 20 χ [Mo] <CT <830 - 270 χ [C] - 90 χ [Mn] - 70 χ [Cr] - 80 χ [Mo] (M).
    [0036] In the method for producing the cold rolled steel plate for hot stamping according to item (15) above, when T represents the heating temperature in heating in ° C units, t represents the time in the oven in heating in units of minutes, [Mn] represents the amount of Mn in mass%, and [S] represents the amount of S in mass% in the steel plate, the expression (N) below can be satisfied.
    T χ ln (t) / (1.7 χ [Mn] + [S])> 1500 (N).
    [0037] The production method according to any of items (14) to (16) can also include galvanizing the steel between annealing and hardening lamination.
    [0038] The production method according to item (17) above can also include the steel connection between galvanizing and hardening lamination.
    Petition 870180161107, of 10/12/2018, p. 20/77
    11/47 [0039] The production method according to any of the items (14) and (15) above can also include electrogalvanizing the steel after hardening lamination.
    [0040] The production method according to any of items (14) to (16) above can also include aluminizing the steel between annealing and hardening lamination.
    [0041] The hot stamped steel obtained using the steel layer of any of the items (1) to (20) has excellent forming capacity.
    Effects of the invention [0042] According to the present invention, once a suitable relationship is established between the amount of C, the amount of Mn, and the amount of Si, and the hardness of the martensite measured with a nanoindentator is adjusted to a suitable value, it is possible to obtain a more favorable hole expansion capacity before hot stamping and / or after hot stamping on hot stamped steel.
    Brief description of the drawings [0043] FIG. 1 is a graph illustrating the relationship between (5 x [Si] + [Mn]) / [C] and TS x λ before hot stamping and after hot stamping.
    [0044] FIG. 2A is a graph illustrating the basis of an expression (B) and is a graph illustrating the relationship between H2 / H1 and σΗΜ before hot stamping and the relationship between H21 / H11 and σΗΜ1 after hot stamping.
    [0045] FIG. 2B is a graph illustrating the basis of an expression (C) and is a graph illustrating the relationship between σHM and TS x λ before hot stamping and the relationship between σHM1 and TS x λ after hot stamping.
    Petition 870180161107, of 10/12/2018, p. 21/77
    12/47 [0046] FIG. 3 is a graph illustrating the relationship between n2 / n1 and TS x λ before hot stamping and the relationship between n21 / n11 and TS x λ after hot stamping, and illustrating the basis of an expression (D).
    [0047] FIG. 4 is a graph illustrating the relationship between 1.5 x r1 / r + 1.2 x r2 / r + r3 / r H2 / H1 before hot stamping and the relationship between 1.5 x r1 / r + 1.2 x r2 / 2 + r3 / r H21 / H11 after hot stamping, and illustrating the basis of an expression (E).
    [0048] FIG. 5A is a graph illustrating the relationship between the expression (F) and the fraction of martensite.
    [0049] FIG. 5B is an illustrated graph of the relationship between expression (F) and fraction of perlite.
    [0050] FIG. 6 is a graph illustrating the relationship between T x ln (t) / (1.7 x [Mn] + [S]) and TS x λ, and illustrating the basis of an expression (G). [0051] FIG. 7 is a perspective view of a hot stamped steel used in an example.
    [0052] FIG. 8A is a flow chart illustrating the method of producing a cold-rolled steel sheet according to one embodiment of the present invention.
    [0053] FIG. 8B is a flow chart illustrating a method for producing a cold rolled steel sheet after hot stamping in accordance with another embodiment of the present invention.
    Modalities of the invention [0054] As described above, it is important to establish an adequate relationship between the amount of Si, the amount of Mn and the amount of C and provide an adequate hardness for the martensite in a predetermined position on a steel plate to improve conformability (hole expansion capacity). So far, there have been no studies regarding the relationship between the forming capacity and the hardness of martensite in a
    Petition 870180161107, of 10/12/2018, p. 22/77
    13/47 steel before hot stamping or after hot stamping.
    [0055] Here, the reasons for limiting the chemical composition of a cold-rolled steel sheet before hot stamping according to an embodiment of the present invention will be described (in some cases also referred to as cold-rolled steel sheet before stamping in accordance with the present embodiment), of a cold rolled steel sheet after hot stamping in accordance with one embodiment of the present invention (in some cases also referred to as cold rolled steel sheet after hot stamping in accordance with an embodiment of the present invention) ), and the steel used for its production. Henceforth,% which is the unit of quantity of an individual component indicates% by mass.
    C: 0.030% to 0.150% [0056] C is an important element to reinforce martensite and increase the strength of steel. When the amount of C is less than 0.030%, it is not possible to increase the strength of the steel sufficiently. On the other hand, when the amount of C exceeds 0.150%, the degradation of the ductility (elongation) of the steel becomes significant. Therefore, the C amount range is adjusted to 0.030% to 0.150%. In a case where there is a demand for high hole expansion capacity, the amount of C is desirably adjusted to 0.100% or less.
    Si: 0.010% to 1,000% [0057] Si is an important element to suppress the formation of a harmful carbide and obtain a multi-phase structure including mainly a ferrite structure and a balance of martensite. However, in a case where the amount of Si exceeds 1,000%, the elongation or bore expansion capacity of the steel degrades, and the chemical conversion treatment property also degrades.
    Petition 870180161107, of 10/12/2018, p. 23/77
    14/47
    Therefore, the amount of Si is adjusted to 1,000% or less. In addition, although Si is added for deoxidation, the deoxidation effect is not sufficient when the amount of Si is less than 0.010%. Therefore, the amount of Si is adjusted to 0.010% or more. Therefore, the amount of Si is set to 0.010% or more.
    Al: 0.010% to 0.050% [0058] Al is an important element as a deoxidizing agent. To obtain the deoxidation effect, the amount of Al is adjusted to 0.010% or more. On the other hand, even when Al is added excessively, the effect described above is saturated and, on the contrary, the steel becomes brittle. Therefore, the amount of Al is adjusted in a range of 0.010% to 0.050%.
    Mn: 1.50% to 2.70% [0059] Mn is an important element to increase the steel's hardening capacity and reinforce the steel. However, when the amount of Mn is less than 1.50%, it is not possible to sufficiently increase the strength of the steel. On the other hand, when the amount of Mn exceeds 2.70%, since the hardening capacity increases more than necessary, an increase in the strength of the steel is caused, and consequently the elongation or hole expansion capacity of the steel degrades . Therefore, the amount of Mn is adjusted in a range of 1.50% to 2.70%. In a case where there is a demand for high elongation, the amount of Mn is desirably 2.00% or less.
    P: 0.001% to 0.060% [0060] In a case where the quantity is large, P secretes at the grain edge, and deteriorates the local ductility and the weldability of the steel. Therefore, the amount of P is adjusted to 0.060% or less. On the other hand, since an unnecessary decrease in
    Petition 870180161107, of 10/12/2018, p. 24/77
    15/47 P content leads to an increase in refining cost, the amount of P is desirably adjusted to 0.001% or more.
    S: 0.001% to 0.010% [0061] S is an element that forms MnS and significantly deteriorates the local ductility or weldability of steel. Therefore, the upper limit on the amount of S is set to 0.010%. In addition, to reduce refining costs, the lower limit on the amount of S is desirably set to 0.001%.
    N: 0.0005% to 0., 100% [0062] N is an important element to precipitate AlN and the like and to reduce crystal grains. However, when the amount of N exceeds 0.0100%, a solid solution of N (Solid nitrogen solution) remains and the ductility of the steel is degraded. Therefore, the amount of N is adjusted to 0.0100% or less. Due to the problem of refining costs, the lower limit of the amount of N is desirably set to 0.0005%.
    [0063] The cold rolled steel sheet according to the modality has a basic composition including the components described above, Fe as balance and the inevitable impurities, but it can also contain any one or more elements between Nb, Ti, V, Mo, Cr , Ca, REM (rare earth metals), Cu, Ni and B as elements that have so far been used in amounts that are equal to or less than the upper limits described above to improve strength, control the shape of a sulfide or an oxide, etc. Since these chemical elements are not necessarily added to the steel sheet, their lower limits are 0%.
    [0064] Nb, Ti and V are elements that precipitate a fine carbonitride and reinforce steel. In addition, Mo and Cr are elements that increase the hardening capacity and reinforce the steel. To obtain these effects, it is desirable to contain Nb: 0.001% or more, Ti: 0.001% or
    Petition 870180161107, of 10/12/2018, p. 25/77
    16/47 more, V: 0.01% or more, Mo: 0.01% or more, and Cr: 0.01% or more. However, when Nb: more than 0.050%, Ti: more than 0.100%, V: more than 0.100%, Mo: more than 0.50%, and Cr: more than 0.50% are contained, the effect of increasing the resistance is saturated, and there is a concern that degradation of elongation or bore expansion capacity may be caused.
    [0065] Steel may also contain Ca in the range of 0.0005% to 0.0050%. Ca controls the shape of the sulfide or oxide and improves local ductility or the ability to expand the hole. To achieve this effect using Ca, it is preferable to add 0.0005% or more of Ca. However, since there is a concern that an excessive addition may deteriorate the work capacity, the upper limit on the amount of Ca is set to 0 , 0050%. For the same reasons, also for rare earth metals (REM), it is preferable to adjust the lower limit of the quantity to 0.0005% and the upper limit of the quantity to 0.0050%.
    [0066] Steel may also contain Cu: 0.01% to 1.00%, Ni: 0.01% to 1.00% and B: 0.0005% to 0.0020%. These elements can also improve the hardening capacity and increase the strength of the steel. However, to obtain this effect, it is preferable to contain Cu: 0.01% or more, Ni: 0.01% or more and B: 0.0005% or more. In a case where the amounts are equal to or less than the values described above, the effect that reinforces the steel is small. On the other hand, even when Cu: more than 1.00%, Ni: more than 1.00% and B: more than 0.0020% are added, the effect of increasing resistance is saturated, and there is a concern that ductility can degrade.
    [0067] In one case and that the steel contains B, Mo, Cr, V, Ti, Nb, Ni, Cu, Ca and REM, one or more elements are contained. The steel balance is made up of Fe and the inevitable impurities. Elements other than the elements described above (for example, Sn, As and the like) can
    Petition 870180161107, of 10/12/2018, p. 26/77
    17/47 may also be contained as unavoidable impurities as long as these elements do not impair the characteristics. In addition, when B, Mo, Cr, V, Ti, Nb, Ni, Cu, Ca and REM are contained in quantities that are less than the lower limits described above, the elements are treated as unavoidable impurities.
    [0068] In addition, in cold rolled steel plate according to the modality, as illustrated in FIG. 1, when the amount of C (% by mass), the amount of Si (% by mass) and the amount of Mn (% by mass) are represented by [C], [Si] and [Mn] respectively, it is important satisfy the expression (A) below (as well as (H)).
    (5 χ [Si] + [Mn]) / [C]> 11 (A) [0069] When the expression (A) above is satisfied before hot stamping and / or after hot stamping, it is possible to satisfy the TS condition χ λ> 50000MPa-%. When the value of (5 χ [Si] + [Mn]) / [C] is 11 or less, it is not possible to obtain sufficient hole expansion capacity. This is because, when the amount of C is large, the hardness of the hard phase becomes very high, the difference in hardness (hardness ratio) between the hard phase and the soft phase becomes large, and therefore the λ value deteriorates, and when the amount of Si or the amount of Mn is small, the TS becomes low.
    [0070] Generally, it is martensite instead of ferrite that dominates the forming capacity (hole expansion capacity) in a two-phase steel (DP steel). As a result of intensive studies by the inventors regarding the hardness of martensite, it was clarified that, when the difference in hardness (the ratio of hardness) of martensite between the part of the surface of the sheet thickness and the central part of the sheet thickness, and the hardness distribution of the martensite in the central part of the sheet thickness are in a predetermined state in a phase before the hot stamping, the state is almost maintained even the tempering in a hot stamping process with
    Petition 870180161107, of 10/12/2018, p. 27/77
    18/47 as shown in FIGS. 2A and 2B, and then the forming capacity such as elongation and bore expansion capacity are favorable. This is considered to be because the hardness distribution of the martensite formed before hot stamping still has a significant effect even after hot stamping, and connecting elements concentrated in the central part of the sheet thickness even after hot stamping. That is, on the steel sheet before hot stamping, in a case where the hardness ratio between the martensite on the surface part of the sheet thickness and the martensite on the central part of the sheet thickness is large, the same trend is displayed even after hot stamping. As illustrated in FIGS. 2A and 2B, the hardness ratio between the part of the sheet thickness surface and the central part of the sheet thickness on the cold rolled steel sheet according to the mode before hot stamping, and the hardness ratio between the part of the sheet the sheet thickness surface and the central part of the sheet thickness on the steel sheet obtained by hot stamping the cold rolled steel sheet according to the modality, are almost the same. In addition, similarly, the variation in the hardness of the martensite in the central part of the plate thickness in the cold-rolled steel sheet according to the modality before the hot stamping, and the variation in the hardness of the martensite in the central part of the thickness of the plate and steel. obtained by hot stamping the cold rolled steel sheet according to the modality, are almost the same. Therefore, the forming capacity of the steel sheet obtained by hot stamping the cold rolled steel sheet according to the modality is similarly excellent for the forming capacity of the cold rolled steel sheet according to the modality before the hot stamping. [0071] In addition, in relation to the martensite hardness measured with a nanoindentator produced by Hysitron Corporation at a wide range
    Petition 870180161107, of 10/12/2018, p. 28/77
    19/47 1000 times, it is discovered, the present invention, that the expression (B) to follow and the expression (C) to follow (also (I) and (J)) being satisfied before the hot stamping and / or after hot stamping are advantageous for the forming capacity of the steel sheet. Here, H1 is the average hardness of the martensite on the part of the sheet thickness surface that is within the area that is 200 pm wide in the thickness direction from the outermost layer of the steel sheet in the thickness direction before stamping hot, H2 is the average hardness of martensite in an area that has a width of ± 100 pm in the thickness direction from the central part of the sheet thickness to the central part of the sheet thickness on the steel sheet before hot stamping , and σΗΜ is the variation in martensite hardness in an area having a width of ± 100 pm in the thickness direction from the central part of the plate thickness before hot stamping. In addition, H11 is the hardness of the martensite on the surface part of the thickness of the cold-rolled steel sheet for hot stamping after hot stamping, H21 is the hardness of the martensite in the central part of the sheet thickness, that is, in an area that is 200 pm wide in the direction of thickness in the center of the plate thickness after hot stamping, and σΗΜ1 is the variation in martensite hardness in the central part of the plate thickness after hot stamping. H1, H11, H2, H21, σΗΜ and σΗΜ1 are obtained respectively from measurements at 300 points for each one. An area having a width of ± 100 pm in the thickness direction from the central part of the plate thickness refers to an area having its center in the center of the plate thickness and having a dimension 200 pm in the direction of the thickness.
    H2 / H1 <1.10 (B) σHM <20 (C)
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    20/47
    H21 / H11 <1.10 (I) σΗΜ1 <20 (J) [0072] In addition, here, the variation is a value obtained using the expression (O) below and indicating the distribution of martensite hardness.
    [Expression 1] σΗΜ n = 2 - £ (αν χ, -χ /) ··· (θ)
    Xave represents the average hardness value, ie, you represent the hardness there.
    [0073] An H2 / H1 value of 1.10 or more represents that the hardness of the martensite in the central part of the sheet thickness is 1.1 or more times the hardness of the martensite in the part of the steel sheet surface, and in this case , the HM becomes 20 or more as illustrated in FIG. 2A. When the H2 / H1 value is 1.10 or more, the hardness of the central part of the sheet thickness becomes very high, TS χ λ becomes less than 50000MPa-% as illustrated in FIG. 2B, and sufficient forming capacity cannot be achieved before tempering (i.e., before hot stamping) and after tempering (i.e., after hot stamping). In addition, theoretically, there is a case where the lower limit of H2 / H1 becomes the same in the central part of the sheet thickness and in the part of the surface of the sheet thickness unless a special heat treatment is carried out; however, in a current production process, when productivity is considered, the lower the limit, for example, up to approximately 1,005. What was described above in relation to the H2 / H1 value should also apply in a similar way to the H21 / H11 value.
    [0074] In addition, the variation of oHM being 20 or more indicates that the spread of martensite hardness is large, and there are parts where the hardness is very high locally. In this case, TS χ λ is
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    21/47 makes it less than 50000MPa-% as illustrated in FIG. 2B, and sufficient forming capacity cannot be achieved. What was described above in relation to the oHM value should also apply in a similar way to the oHM1 value.
    [0075] In cold rolled steel plate according to the modality, the fraction of the ferrite area in a metallographic structure before hot stamping and / or after hot stamping is 40% to 90%. When the ferrite area fraction is less than 40%, sufficient elongation or sufficient bore expansion capacity cannot be achieved. On the other hand, when the ferrite area fraction exceeds 90%, the martensite becomes insufficient, and sufficient strength cannot be achieved. Therefore, the fraction of the ferrite area before hot stamping and / or after hot stamping is adjusted to 40% to 90%. In addition, the metallographic structure of the steel plate before hot stamping and / or after hot stamping also includes martensite, the area fraction of the martensite is 10% to 60%, and the total area fraction of the ferrite and the fraction of martensite area is 60% or more. All or the main parts of the steel plate metallographic structure before hot stamping and / or after hot stamping are occupied by ferrite and martensite, and, in addition, one or more between perlite, bainite as a remainder and retained austenite can be included in the metallographic structure. However, when the retained austenite remains in the metallographic structure, the weakening of secondary work and the delayed fracture characteristic are liable to degrade. Therefore, it is preferable that the retained austenite is not substantially included; however, inevitably, 5% or less of austenite retained in a volume ratio can be included. Since the perlite is a hard and fragile structure, it is preferable not to include the perlite in the metallographic structure before hot stamping and / or after hot stamping; however, inevitable
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    22/47, up to 10% of the perlite in the area fraction can be included. In addition, the amount of bainite as a remainder is preferably 40% or less in a fraction of the area in relation to the region that excludes ferrite and martensite. Here, the metallographic structures of ferrite, bainite as a remnant and perlite were observed through caustication with Nital, and the metallographic structure of martensite was observed through Le pera caustication. In both cases, a portion 1/4 of the thickness of the plate was observed at a magnification of 1000 times. The volume ratio of the retained austenite was measured with x-ray diffraction equipment after polishing the steel sheet to a part 1/4 of the thickness of the sheet. The 1/4 part of the plate thickness refers to the 1/4 part of the steel plate thickness from the steel plate surface in the direction of the steel plate thickness on the steel plate.
    [0076] In the modality, the martensite hardness measured at 1000 times magnification is specified using a nanoindentator. Since a concavity formed in a common Vickers hardness test is greater than martensite, according to the Vickers hardness test, while the macroscopic hardness of martensite and its peripheral structures (ferrite and the like) cannot be obtained, it is not possible to obtain the hardness of the martensite itself. Since the forming capacity (hole expansion capacity) is significantly affected by the hardness of the martensite itself, it is difficult to sufficiently assess the forming capacity with only a Vickers hardness. On the contrary, in the present invention, since an adequate ratio of the martensite hardness is provided before the hot stamping and / or after the hot stamping measured with the nanoindentator, it is possible to obtain an extremely favorable forming capacity.
    Petition 870180161107, of 10/12/2018, p. 32/77
    23/47 [0077] In addition, on the cold-rolled steel plate before hot stamping and / or after hot stamping, as a result of observing MnS in the 1/4 part of the plate thickness and in the central part of the plate thickness, it has been found that it is preferable that a fraction of the MnS area having an equivalent circle diameter from 0.1 pm to 10 pm is 0.01% or less, and, as illustrated in FIG. 3, the expression (D) (as well as the expression (K)) below is satisfied to favorably and stably satisfy the condition of TS x λ> 50000MPa-% before hot stamping and / or after hot stamping. When MnS having an equivalent circle diameter of 0.1 pm or more exists during the hole expansion capability test, since stress is concentrated in its vicinity, the fracture is likely to occur. One reason for not counting MnS that has an equivalent circle diameter of less than 0.1 pm is that MnS that has an equivalent circle diameter of less than 0.1 pm has little effect on stress concentration. In addition, the reason for not counting the MnS that has an equivalent circle diameter of more than 10 pm is that the MnS that has the grain size described above is included in the steel plate, the grain size is very large, and the steel sheet becomes unsuitable for the job. In addition, when the fraction of MnS area having an equivalent circle diameter of 0.1 pm or more exceeds 0.01%, since it is easy to propagate fine fractures generated due to the concentration of stress, the ability to bore expansion also deteriorates, and there is a case where the condition of TS x λ> 50000MPa-% is not met. Here, n1 and n11 are numerical densities of the MnS that have the equivalent circle diameter of 0.1 pm to 10 pm in the 1/4 part of the plate thickness before hot stamping and after hot stamping respectively, and n2 and n21 are numerical densities
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    24/47 cas of the MnS which has the equivalent circle diameter from 0.1 pm to 10 pm in the central part of the sheet thickness before hot stamping and after hot stamping respectively.
    n2 / n1 <1.5 (D) n21 / n11 <1.5 (K) [0078] These ratios are all identical for the steel plate before hot stamping and for the steel plate after hot stamping.
    [0079] When the fraction of area of the MnS that has the equivalent circle diameter from 0.1 pm to 10 pm is greater than 0.01%, the forming capacity is liable to degrade. The lower limit of the MnS area fraction is not particularly specified, however, 0.0001% or more of MnS is present due to a measurement method described below, the limitation of magnification and a visual field, and the amount of Mn or S. In addition, the value of n2 / n1 (or n21 / n11) being 1.5 or more represents that the numerical density of MnS which has an equivalent circle diameter of 0.1 pm to 10 pm on the part The central thickness of the plate is 1.5 or more times the numerical density of the MnS which has the equivalent circle diameter from 0.1 pm to 10 pm in the 1/4 part of the plate thickness. In this case, the forming capacity is liable to degrade due to the segregation of the MnS in the central part of the plate thickness. In the modality, the equivalent circle diameter and the numerical density of the MnS that has the equivalent circle diameter from 0.1 pm to 10 pm were measured with a field emission scanning electron microscope (Fe-SEM) produced by JEOL Ltd At one measurement, the magnification was 1000 times, and the measurement area of the visual field was adjusted to 0.12 x 0.09 mm 2 (= 10800 pm 2 ~ 10000 pm 2 ). Ten visual fields were observed in the 1/4 part of the plate thickness, and ten visual fields were observed in the central part of the plate thickness.
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    25/47 plate. The fraction of MnS area having the equivalent circle diameter from 0.1 pm to 10 pm was computed with particle analysis software. In cold rolled steel sheet according to the modality, the shape (a shape and a number) of the MnS formed before the hot stamping is the same before and after the hot stamping. FIG. 3 is a view illustrating the relationship between n2 / n1 and TS χ λ before hot stamping and the relationship between n21 / n11 and TS χ λ after hot stamping and, according to FIG. 3, n2 / n1 before hot stamping and n21 / n11 after hot stamping are almost the same. This is because, generally, the shape of the MnS does not change at the heating temperature of a hot stamping.
    [0080] According to the steel sheet that has the configuration described above, it is possible to achieve a tensile strength of 500 MPa to 1200 MPa, and a significant effect of improving the forming capacity is obtained in the steel sheet that has a tensile strength of approximately 550 MPa to 850 MPa.
    [0081] In addition, a cold rolled steel sheet with galvanization on which the galvanization is formed on the steel sheet of the present invention indicates the steel sheet on which a galvanization, a hot dip galvanized annealing, an electro-galvanization, an aluminization, or a mixture of them, is formed on the surface of the cold-rolled steel sheet, which is preferable in terms of rust prevention. The formation of the coatings described above does not affect the effects of the modality. The coatings described above can be carried out with a known method.
    [0082] Hereinafter, a method will be described for the production of the steel sheet (a cold-rolled steel sheet, a hot-dip galvanized cold-rolled steel sheet, a laminated steel sheet
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    26/47 nothing cold galvannealed, an electrogalvanized cold rolled steel sheet, and an aluminized cold rolled steel sheet).
    [0083] When the steel plate is produced according to the modality, as a common condition, a steel cast in a converter is cast continuously, thus producing a plate. In continuous casting, when the casting rate is fast, a Ti precipitate or similar becomes very fine, and when the casting rate is slow, the productivity deteriorates, and consequently the precipitate described above becomes stale, and the number of particles decreases. , and so there is a case where other features such as delayed fracture cannot be controlled. Therefore, the casting rate is desirably 1.0 m / min to 2.5 m / min.
    [0084] The slab after casting can be subjected to hot rolling in the state it is in. Alternatively, in a case where the plate after cooling has been cooled to below 1100 ° C, it is possible to reheat the plate after cooling to 1100 ° C to 1300 ° C in a tunnel oven or similar and subject the plate to lamination the hot. When the plate temperature is below 1100 ° C, it is difficult to guarantee the finishing temperature in the hot rolling, which causes the elongation to degrade. In addition, on the steel plate to which Ti and Nb are added, since the dissolution of the precipitates becomes insufficient during heating, which causes a decrease in resistance. On the other hand, when the heating temperature is higher than 1300 ° C, the generation of scale becomes large, and there is a case in which it is not possible to favor the property of the steel sheet surface.
    [0085] In addition, to decrease the fraction of area of MnS having the equivalent circle diameter from 0.1 pm to 10 pm, when the amount of Mn and the amount of S in the steel are respectively represented by [Mn] and [ S] in% by mass, it is preferable that the temperature
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    27/47 ra T (° C) of a heating furnace before hot rolling, and the time in the furnace t (minutes), [Mn] and [S] to satisfy the expression (G) below (so as the expression (N)) as illustrated in FIG. 6.
    T x ln (t) / (1.7 x [Mn] + [S])> 1500 (G) [0086] When T x ln (t) / (1.7 x [Mn] + [S]) is equal to or less than 1500, the fraction of MnS area that has the equivalent circle diameter from 0.1 pm to 10 pm becomes large, and there is the case that the difference between the numerical density of MnS that has a diameter equivalent circle of 0.1 pm to 10 pm in the 1/4 part of the plate thickness and the numerical density of the MnS which has an equivalent circle diameter of 0.1 pm to 10 pm in the central part of the plate thickness if makes it great. The temperature of the heating oven before the hot lamination is performed refers to the extraction temperature on one outlet side of the heating oven, and the time in the oven refers to the time elapsed from the insertion of the plate in the heating oven to the heating plate extraction. Since MnS does not change even after hot stamping as described above, it is preferable to satisfy the expression (G) or the expression (N) in a heating process before the hot lamination.
    [0087] Next, the hot rolling is performed according to a conventional method. At that time, it is desirable to perform the hot lamination on the plate at the finishing temperature (final temperature of the hot lamination) which is adjusted in a range of an Ara temperature up to 970 ° C. When the finishing temperature is lower than the Ara temperature, the hot rolling becomes a rolling in the two-phase region (α + γ) (two-phase region of ferrite + martensite), and there is a concern that the stretching may degrade. On the other hand, when the finishing temperature exceeds
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    28/47
    At 970 ° C, the grain size of the austenite becomes stale, and the fraction of the ferrite becomes small, so there is a concern that the elongation may degrade. The hot rolling equipment can have a plurality of chairs.
    [0088] Here, the Ar3 temperature was estimated from an inflection point of a specimen length after the thermal expansion test was performed.
    [0089] After hot rolling, the steel is cooled at an average cooling rate of 20 ° C / s to 500 ° C / s, and is wound at a predetermined winding temperature CT. In a case where the average cooling rate is less than 20 ° C / s, the perlite that causes the degradation of ductility is likely to be formed. On the other hand, the upper limit of the cooling rate is not particularly specified and is adjusted to approximately 500 ° C / s in consideration of the equipment specification, but is not limited to this.
    [0090] After winding, pickling is carried out and cold rolling is carried out. At that time, to obtain a range that satisfies the expression (C) described above as illustrated in FIG. 4, cold rolling is performed under a condition in which the following expression (E) (as well as the expression (L)) is satisfied. When the conditions for annealing, cooling and the like described below are also satisfied after the lamination described above, TS χ λ> 50000 MPa-% is guaranteed before hot stamping and / or after hot stamping. Cold rolling is desirably carried out with an in-line rolling mill in which the plurality of rolling mills are arranged linearly, and the steel sheet is rolled continuously in a single direction, thus obtaining a predetermined thickness.
    1.5 r1 χ / χ + 1.2 r r2 / r3 + r / R> 1.0 (E) [0091] Here, ri represents the reduction objectified individual cold lamination (%) i in a chair ( i = 1, 2, 3) from the first
    Petition 870180161107, of 10/12/2018, p. 38/77
    29/47 chair in cold rolling, and r represents the objective reduction of total cold rolling (%) in cold rolling. The total reduction in cold rolling is a so-called cumulative reduction, and based on the thickness of the plate at the entrance of the first chair, it is the percentage of the cumulative reduction (the difference between the thickness of the plate at the entrance before the first pass and the thickness of the plate at the exit after the final pass) in relation to the base described above.
    [0092] When cold rolling is performed under the conditions in which the expression (E) is satisfied, it is possible to sufficiently divide the perlite in the cold lamination even when a large perlite phase exists before the cold lamination. As a result, it is possible to burn the perlite or suppress the fraction of the perlite's area to a minimum through annealing performed after cold rolling, and therefore it is easy to obtain a structure in which expression (B) and expression (C ) are satisfied. On the other hand, in a case where the expression (E) is not satisfied, the reductions in cold rolling in the upper chain chairs are not enough, the large perlite phase is liable to remain, and it is not possible to form the desired martensite in the following annealing. In addition, the inventors found that when the expression (E) is satisfied, the shape obtained from the martensite structure after annealing is kept in almost the same state even after hot stamping is performed, and therefore the steel sheet is cold depending on the modality becomes advantageous in terms of elongation or the ability to expand the hole even after hot stamping. In a case where the hot-stamped steel for which the hot-rolled steel sheet for hot stamping as the mode is used is heated up to the two-stage region in the hot-stamping, a hard phase including the martensite before the hot stamping becomes an austenite structure, and the ferrite before hot stamping remains as it is. The car
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    30/47 bono (C) on austenite does not move to the peripheral ferrite. After that, when cooled, austenite turns into a hard phase including martensite. That is, when the expression (E) is satisfied and the H2 / H1 ratio described above is in a predetermined range, H2 / H1 is maintained, even after hot stamping and the forming capacity becomes excellent after hot stamping .
    [0093] In the modality, r, r1, r2 and r3 are the desired reductions of cold rolling. Generally, cold rolling is performed while controlling the desired reduction of cold rolling and the actual reduction of cold rolling to become substantially the same value. It is not preferable to perform cold rolling in a state in which the actual reduction of cold rolling is unnecessarily made to be different from the desired reduction of cold rolling. However, in a case where there is a big difference between the desired reduction in lamination and the actual reduction in lamination, it is possible to consider that the modality is performed when the actual reduction in cold rolling meets the expression (E). In addition, the actual reduction in cold rolling is preferably within ± 10% of the desired reduction in cold rolling.
    [0094] After cold rolling, recrystallization is caused on the steel plate by the annealing process. In addition, in a case where hot dip galvanizing or galvanizing annealing is formed to improve the rust prevention ability, hot dip galvanizing, and bonding treatment is performed on the steel plate, and then , the steel sheet is cooled with a conventional method. Annealing and cooling form the desired martensite. In addition, in relation to the annealing temperature, it is preferable to perform annealing by heating the steel sheet to 700 ° C to 850 ° C, and to cool the steel sheet to room temperature or to a temperature at which the treatment of
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    31/47 surface as galvanizing is performed. When annealing is carried out in the range described above, it is possible to stably guarantee the fraction of the predetermined area of the ferrite and the fraction of the predetermined area of the martensite, to stably adjust the total fraction of the ferrite area and the fraction of the area of the martensite to 60 % or more, and to contribute to an improvement in TS χ λ. Other annealing conditions are not particularly specified, but the retention time at 700 ° C to 850 ° C is preferably 1 second or longer as long as productivity is not hindered to safely obtain a predetermined structure, and it is also preferable to properly determine the rate of temperature increase in a range of 1 ° C / s to the upper limit of the equipment's capacity, and properly determine the cooling rate in a range of 1 ° C / s to the upper limit of the equipment's capacity. In a hardening lamination process, hardening lamination is performed with a conventional method. The elongation ratio of the hardening lamination is generally approximately 0.2% to 5%, and is preferably within a range in which the limit of elasticity in elongation is avoided and the shape of the steel sheet can be corrected. [0095] As a condition is more preferable of the present invention, when the amount of C (% by mass), the amount of Mn (% by mass), the amount of Cr (% by mass) and the amount of Mo (% in mass) of the steel are represented by [C], [Mn], [Cr] and [Mo] respectively, in relation to the winding temperature CT, and it is preferable to satisfy the following expression (F) (as well as the expression (M )).
    560 - 474 χ [C] - 90 χ [Mn] - 20 χ [Cr] - 20 χ [Mo] <CT <830 - 270 χ [C] - 90 χ [Mn] - 70 χ [Cr] - 80 χ [Mo] (F) [0096] As illustrated in FIG. 5A, when the CT winding temperature is less than 560 - 474 χ [C] - 90 χ [Mn] - 20 χ [Cr] - 20 χ
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    32/47 [Mo], the martensite is excessively formed, the steel sheet becomes very hard, and there is a case in which the next cold rolling becomes difficult. On the other hand, as illustrated in FIG. 5B, when the CT winding temperature exceeds 830 - 270 χ [C] - 90 χ [Mn] - 70 χ [Cr] - 80 χ [Mo], a bonded ferrite and pearlite structure can be formed and, in addition Furthermore, the fraction of perlite in the central part of the plate thickness is liable to increase. Therefore, the uniformity of a distribution of martensite formed at the next annealing degrades, and it becomes difficult to satisfy the expression (C) described above. In addition, there is the case where it becomes difficult for the martensite to be formed in a sufficient amount.
    [0097] When the expression (F) is satisfied, the ferrite and the hard phase have an ideal distribution form as described above. In this case, when the heating of the two-phase region is carried out in hot stamping, the form of distribution is maintained as described above. If it is possible to more safely guarantee the metallographic structure described above by satisfying the expression (F), the metallographic structure is maintained even after hot stamping, and the forming capacity becomes excellent after hot stamping.
    [0098] In addition, to improve the rust prevention capacity, it is also preferable to include a hot dip galvanizing process in which a hot dip galvanizing is formed between the annealing process and the hardening lamination process, and to form hot dip galvanizing on the surface of the cold rolled steel sheet. In addition, it is also preferable to include a bonding process in which bonding treatment is carried out after hot dip galvanizing. In a case in which the bonding treatment is carried out, the treatment in which the galvannealed surface is brought into contact with the substance
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    33/47 which oxidizes the surface of the plate such as water vapor, thereby thickening the oxidized film, can also be carried out on the surface. [0099] It is also preferable to include, for example, an electrogalvanization process in which electrogalvanization is formed after the good hardening lamination process such as hot dip galvanizing and galvanizing annealing and to form an electrogalvanization on the plate surface cold rolled steel. In addition, it is also preferable to include, instead of hot dip galvanizing, an aluminization process in which an aluminization is formed between the annealing process and the hardening lamination process, and to form the aluminization on the surface of the steel sheet. cold rolled. Aluminization is generally hot-dip aluminization, which is preferable.
    [00100] After the series of treatments mentioned above, hot stamping is performed as needed. In the hot stamping process, hot stamping is desirably carried out, for example, under the following condition. The steel plate is initially heated to 700 ° C to 1000 ° C at a temperature increase rate of 5 ° C / s to 500 ° C / s, and the hot stamping (hot stamping process) is carried out after the retention time from 1 second to 120 seconds. In order to improve the forming capacity, the heating temperature is preferably A3 or lower. The Ac3 temperature was estimated from the point of inflection of the specimen after the execution of the formator test. Subsequently, the steel sheet is cooled, for example, to room temperature at 300 ° C at a cooling rate of 10 ° C / s to 1000 ° C / s (hot stamping quench).
    [00101] When the heating temperature in the hot stamping process is less than 700 ° C, the quenching is not sufficient, and consequently the resistance cannot be guaranteed, which is not
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    34/47 preferable. When the heating temperature is greater than 1000 ° C, the steel sheet becomes very soft, and in a case where a coating, particularly a zinc coating, is formed on the surface of the steel sheet, there is a concern that zinc can be evaporated and burned, which is not preferable. Therefore, the heating temperature in the hot stamping is preferably 700 ° C to 1000 ° C. When the rate of temperature increase is less than 5 ° C / s, since it is difficult to control the heating in the hot stamping, and the productivity degrades significantly, it is preferable to perform the heating at a temperature increase rate of 5 ° C / s or more. On the other hand, the upper limit of the 500 ° C / s temperature rise rate depends on the current heating capacity, but it is not necessary to limit it to that value. When the cooling rate is less than 10 ° C / s, since controlling the cooling rate after hot stamping is difficult, and productivity also degrades significantly, it is preferable to perform the cooling at a cooling rate of 10 ° C / s or more. The upper limit of the cooling rate of 1000 ° C / s depends on the current cooling capacity, but it is not necessary to limit it to this value. The reason for adjusting the time until hot stamping after an increase in temperature to 1 second or more is the ability to control the current process (the lower limit of the capacity of the equipment), and the reason for adjusting the time until stamping a hot after the temperature rise to 120 seconds or less is to prevent evaporation of zinc or the like in a case where galvanizing or the like is formed on the surface of the steel sheet. The reason for adjusting the cooling temperature to room temperature at 300 ° C is to ensure enough martensite and to guarantee resistance after hot stamping.
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    35/47 [00102] FIG. 8A and FIG. 8B are flowcharts that illustrate the method for producing the cold rolled steel sheet according to the embodiment of the present invention. The reference signals S1 to S13 in the drawing correspond respectively to the individual processes described above.
    [00103] In the cold rolled steel sheet of the modality, the expression (B) and the expression (C) are satisfied even after the hot stamping is performed under the condition described above. In addition, consequently, it is possible to satisfy the condition of TS χ λ> 50000MPa% even after hot stamping is performed.
    [00104] As described above, when the conditions described above are satisfied, it is possible to produce the steel sheet in which the distribution of the structure's hardness is maintained even after hot stamping, and consequently the resistance is guaranteed and an expansion capacity more favorable borehole before hot stamping and / or after hot stamping can be obtained.
    Examples [00105] A steel having the composition described in Table 1 was cast continuously at a casting rate of 1.0 m / minute to 2.5 m / minute, the plate was heated in a heating oven under the conditions shown in Table 2 with a conventional method in the state or after cooling the steel once, and the hot rolling was carried out at a finishing temperature of 910 ° C to 930 ° C, thus producing a hot-rolled steel plate. After that, the hot rolled steel sheet was wound at a CT winding temperature described in Table 1. After this, the pickling was carried out in order to remove the scale on the surface of the steel sheet, and the thickness of the steel sheet. it was made to be 1.2 mm to 1.4 mm through cold rolling. At that time, cold rolling was performed so that the value of the expression (E) or the expression (L)
    Petition 870180161107, of 10/12/2018, p. 45/77
    36/47 becomes the value described in Table 5. After cold rolling, annealing was carried out in a continuous annealing furnace at the annealing temperature described in Table 2. In a part of the steel sheets a galvanization was also formed in the middle of cooling after soaking in the continuous annealing furnace, and then a bonding treatment was also carried out on part of the steel sheets, thus forming a galvanizing annealing. In addition, electrogalvanization or aluminization was formed in part of the steel sheets. In addition, the hardening lamination was carried out at an elongation ratio of 1% according to a conventional method. In this state, a sample was taken to assess the qualities of the material and the like before hot stamping, and a quality test of the material or similar was performed. Thereafter, to obtain a hot-stamped steel sheet having the shape shown in FIG. 7, a hot stamping was performed in which the temperature was increased at a rate of temperature increase from 10 ° C / s to 100 ° C / s, the steel sheet was kept at 780 ° C for 10 seconds, and the sheet steel was cooled at a cooling rate of 100 ° C / s to 200 ° C or less. A sample was cut from the location of FIG. 7 on the hot stamped steel obtained, the material quality test and the like were performed, and the tensile strength (TS), the elongation (El), the hole expansion ratio (λ) and the like were obtained. The results are described in Table 2, Table 3 (continuation of Table 2), Table 4 and Table 5 (continuation of Table 4). The expansion ratios for hole λ in the tables were obtained from the expression (P) below.
    λ (%) = {(d '- d) / d} x 100 (P) d': diameter of the hole when the fracture penetrates the thickness of the plate d: initial diameter of the hole
    Petition 870180161107, of 10/12/2018, p. 46/77
    37/47 [00106] In addition, in relation to the types of coating in Table 2, CR represents an uncoated plate, that is, a cold rolled steel plate, GI represents that hot dip galvanizing was formed on the plate of cold rolled steel, GA represents that the galvanizing annealing is formed in the cold rolled steel sheet, EG represents that the electrogalvanization is formed in the cold rolled steel sheet.
    [00107] In addition, the determinations of G and B in the tables have the following meanings:
    G: the expression of the desired condition is satisfied. B: expression of the desired condition is not satisfied.
    [00108] In addition, since the expression (H), the expression (I), the expression (J), the expression (K), the expression (L), the expression (M), and the expression (N ) are substantially the same as expression (A), expression (B), expression (C), expression (D), expression (E), expression (F), expression (G), respectively, in the headings of the respective tables, the expression (A), the expression (B), the expression (C), the expression (D), the expression (E), the expression (F), and the expression (G), are described as representative.
    Petition 870180161107, of 10/12/2018, p. 47/77 [Table 1]
    S 'ir a-po type reference balloonç Si Mn P s IN Al Cr Mo V You Nb Ni Ass Here B REM Expression(THE) THE EXAMPLE 0.042 0.145 1.55 0.003 0.008 0.0035 0.035 0 0 0 0 0 0 0 0 0 0 54.2 B EXAMPLE 0.062 0.231 1.61 0.023 0.006 0.0064 0.021 0 0 0 0 0 0.3 0 0 0 0 44.6 Ç EXAMPLE 0.144 0.950 2.03 0.008 0.009 0.0034 0.042 0.12 0 0 0 0 0 0 0 0 0 47.1 D EXAMPLE 0.072 0.342 1.62 0.007 0.007 0.0035 0.042 0 0.15 0 0 0 0 0 0 0 0 46.3 AND EXAMPLE 0.074 0.058 1.54 0.008 0.008 0.0045 0.034 0.21 0 0 0 0 0 0 0 0 0 24.7 F EXAMPLE 0.081 0 256 1.71 0006 0 009 0.0087 0041 0 0 0 0 0 0 04 0.004 0 ç 36.9 G EXAMPLE 0.095 0 321 1.51 0 012 0 008 0.0041 0 038 0 0 0 0 0 0 0 0 0 0 32.8 H EXAMPLE 0090 0 465 1.51 0051 0 001 0 0035 0 032 032 005 0 0 □ 0 0 0003 0 0 42 6 I EXAMPLE 0.084 0 512 1.54 0008 0002 0.0065 0 041 0 0 003 0 0 0 0 0 0 0 48.8 J EXAMPLE 0.075 0 785 1.62 0007 0 009 0.0014 0 025 0 0.31 0 0 0 0 0 0 0 0 73.9 K EXAMPLE 0.089 0 145 1.52 0006 0 008 0.0026 0 034 □ 0 0 0 0 0 0 0 0 0 25.2 L EXAMPLE 0.098 0 624 2.11 0 012 0 006 0.0035 0 012 □ 0.21 0 0.05 0 0 0 0 0 0 53.4 M EXAMPLE 0.103 0325 1.58 0 011 0 005 0.0032 0025 0 0 0 0 0 0 0 0 0 0 31.1 N EXAMPLE 0.101 0265 2.61 0009 0008 0.0035 0041 0 0.31 0 0 0 0 0 0 0.0015 0 38.9 O EXAMPLE 0.142 0.955 1.74 0.007 0.007 0.0041 0.037 0 0.25 0 0 0 0 0 0 0 0 45.9 P EXAMPLE 0.097 0.210 2.45 0.005 0.008 0.0022 0.045 0.42 0 0 0 0 0 0 0 0 0 36.1 Q EXAMPLE 0.123 0.325 1.84 0.011 0.003 0.0037 0.035 0 0.11 0 0 0.01 0 0 0 0.0010 0 28.2 R EXAMPLE 0.113 0.120 2.06 0.008 0.004 0.0047 0.035 0 0 0 0 0.03 0 0 0 0 0 23.5 s EXAMPLE 0.134 0.562 1.86 0.013 0.007 0.0034 0.034 0 0.12 0 0 0 0 0 0 0 0 34.9 T EXAMPLE 0.141 0.150 2.35 0.018 0.003 0.0029 0.031 0 0.21 0 0.03 0 0 0 0 0 0 22.0 u EXAMPLE 0.128 0.115 2.41 0.011 0.003 0.0064 0.021 0 0.31 0 0 0 0 0 0 0.0008 0 23.3 w EXAMPLE 0.142 0.562 2.03 0.012 0.007 0.0012 0.036 0 0 0 0 0 0 0 0.002 0 0 34.1 X EXAMPLE 0.118 0.921 1.54 0.013 0.003 0.0087 0.026 0.15 0.11 0 0.05 0 0 0 0 0.0014 0.0005 52.1 Y EXAMPLE 0.125 0.150 2.44 0.009 0.007 0.0087 0.034 0.32 0 0 0 0 0 0 0 0.0015 0 25.5 z EXAMPLE 0.145 0.110 2.31 0.008 0.004 0.0069 0.035 0 0.15 0.05 0 0 0 0 0 0 0 19.7 AA EXAMPLE 0.075 0.210 1.85 0.010 0.005 0.0025 0.025 0 0 0 0 0 0 0 0 0 0 38.7 AB EXAMPLE 0.085 0.210 1.84 0.011 0.005 0.0032 0.032 0 0 0 0 0 0 0 0 0 0 34.0 AG EXAMPLE 0.092 0.150 1.95 0.008 0.003 0.0035 0.035 0 0 0 0 0 0 0 0 0 0 29.3 AD EXAMPLE 0.075 0 325 1.95 0008 0 004 0.0034 0 031 □ 0 0 0 0 0 0 0 0 ç 47.7 AE EXAMPLE 0.087 0 256 1.99 0008 0 002 0.0030 0 031 □ 0 0 0 0 0 0 0 0 0 37.6 AF EXAMPLE 0.092 0 263 1.85 0008 0002 0.0030 0 031 0 0 0 0 0 0 0 0 0 0 344 AG Ex. Comparative 0.111 0 526 1.85 0007 0003 0.0034 0 030 0 0 0 0 0 0 0 0 0 0 40.4 AH Ex. Comparative 0.028 0 321 1.55 0007 0 003 0.0035 0 035 □ 0 0 0 0 0 0 0 0 0.0006 1 12.7 THERE Comparative Example Õ.252 0 512 2.15 0003 0 006 0.0009 0 041 □ 0 0 0 0 0 0 0 0 0 18.7 AJ Comparative Example 0.075 0.005 2.12 0007 0 009 0.0035 0 035 □ 0.15 0 0 0 0 0 0 0.0012 0 28.6 AK Comparative Example 0.081 1,521 1.50 0008 0 005 0.0034 0026 0.28 0.32 0 0 0 0 0 0 0.0015 0 1 12.4 AL Ex. Comparative 0.099 Õ66Õ 0.08 0009 0003 0.0032 0029 0 0 0 0 0 0 0 0 0 0 34 1 AM Comparative Example 0.125 0.050 2.81 0.007 0.004 0.0034 0.036 0 0 0 0 0 0 0 0 0 0 24.5 AN Comparative Example 0.131 0.321 2.05 0.091 0.003 0.0021 0.034 0.26 0.15 0 0 0.03 0 0 0 0 0 27.9 TO Comparative Example 0.064 0.125 2.50 Õ.002 0.022 0.0059 0.034 0 0 0 0 0 0.2 0 0 0 0 48.8 AP Comparative Example 0.039 0.265 1.52 0.011 Õ.009 0.0152 0.026 0 0 0 0 0.02 0 0 0.003 0 0 72.9 AQ Ex. Comparative 0.144 0.012 2.39 0.007 0.004 Õ.0065 0.003 0 0.20 0 0 0 0 0 0 0 0 17.0 AIR Ex. Comparative 0.142 0.150 2.35 0.005 0.003 0.0035 0.060 0 0.22 0 0 0 0 0 0 0 0 21.8 AT Ex. Comparative 0.149 0.020 1.50 0.005 0.003 0.0020 0.025 0 0 0 0 0 0 0 0 0.001 0 10.7 AT Comparative Example 0.132 0.090 2.05 0.005 0.003 0.0020 0.025 0 0 0 0 0.01 0 0 0 0 0 18.9 ’ AU Ex. Comparative 0.135 0.220 2.06 0.005 0.003 0.0020 0.025 0 0 0 0.01 0 0 0 0 0 0 23.4
    38/47
    Petition 870180161107, of 10/12/2018, p. 48/77 [Table 2]
    Steel type reference symbol Test reference symbol Annealing temperature co After annealing and hardening lamination and before hot stamping Fraction of perlite area before cold rolling (%) TS (Mpa) EL (%) λ (%) TS x EL TSX Λ Ferrite area fraction(%) Fraction of martensite area (%) Fraction of martensite + ferrite area (%) Fraction of residual austenite area (%) Bainite area fraction (%) Fraction of perlite area (%) THE 1 750 485 32.5 111 15763 53835 88 11 99 1 0 0 35 B 2 750 402 33.2 107 16334 52644 78 15 93 3 4 0 25 Ç 3 720 524 30.5 90 15982 51876 75 10 85 4 5 6 34 D 4 745 562 34.2 95 19220 53300 74 15 80 3 8 0 25 AND 5 775 501 20.8 90 17612 53100 70 15 85 4 11 0 56 F 6 780 601 25.5 84 15326 50484 74 10 84 3 5 8 62 G 7 741 603 26.1 83 15738 50049 70 10 80 5 6 0 75 H 8 756 612 32.1 88 19645 53856 71 15 86 3 8 3 35 I 9 773 614 28.1 90 17258 55260 75 12 87 4 5 4 42 J 10 762 615 30.5 91 18758 55965 78 12 90 3 7 0 25 K 11 761 621 24.2 81 15028 50301 71 10 81 4 7 8 35 L 12 745 633 31.6 84 20003 53172 81 12 93 2 5 0 15 M 13 738 634 32.4 85 20542 53800 51 35 86 3 5 6 8 N 14 780 642 28.6 84 18361 53928 50 34 84 4 5 7 42 0 15 756 653 20.8 81 19459 52803 72 19 91 3 6 0 33 P 16 785 666 27.5 70 18315 52614 68 28 96 3 1 0 25 Q 17 777 671 26.5 80 17782 53680 52 41 93 3 4 0 34 R 18 746 684 21.5 80 14706 54720 51 35 86 4 10 0 52 Ξ 10 780 712 24.1 74 17159 52688 48 38 86 4 10 0 46 T 20 785 745 28.5 71 21233 52805 44 41 85 3 12 0 18 u 21 746 781 20.2 60 15776 53889 41 42 83 5 12 0 22 w 22 845 812 17.4 65 14129 52780 45 39 84 4 12 0 15 X 23 800 988 17.5 55 17290 54340 42 46 88 2 5 5 45 Y 24 820 1012 17.4 54 17609 54648 41 41 82 2 16 0 42 z 25 836 1252 13 5 45 16902 56340 41 48 80 2 9 0 10
    39/47
    Petition 870180161107, of 10/12/2018, p. 49/77 [Table 3]
    Steel type reference symbol Test reference symbol Annealing temperature(° C) After annealing and hardening lamination and before hot stamping Fraction of perlite area before cold rolling (%) TS (Mpa) EL (%) A t%) TS x EL TS * λ Ferrite area fraction (%) Fraction of martensite area (%) Fraction of ferrite + martensite area (%) Fraction of residual austenite area (%) Bainite area fraction (%) Fraction of perlite area (%) AA 26 794 625 24.4 72 15250 45000 59 10 69 2 16 13 27 AB 27 777 626 27.1 64 16965 40064 56 15 71 1 11 17 30 B.C 28 754 594 28.0 78 16632 46332 58 12 70 2 14 14 24 AD 29 749 627 21.6 62 13543 38874 37 19 56 1 24 li 36 AE 30 783 627 24.9 71 15612 44517 66 10 76 2 10 12 21 AF 31 748 683 24.3 72 16597 49176 59 21 BO 2 8 10 46 AG 32 766 632 28.6 58 18075 36656 69 20 89 2 9 0 25 AH 33 768 326 41.9 112 13659 36512 95 0 95 3 2 0 2 THERE 34 781 1512 8.9 25 13457 37800 5 90 95 4 1 0 3 AJ 35 739 635 22 5 72 14288 45720 74 22 96 2 2 0 42 AK 36 789 625 31.2 55 19500 34375 75 22 97 2 1 0 15 AL 37 784 705 26.0 48 18330 33840 42 25 67 1 25 7 2 AM 38 746 795 15 6 36 12402 28620 30 52 82 3 10 5 14 AN 39 812 784 19.1 42 14974 32928 51 37 88 3 9 0 16 TO 40 826 602 305 35 18361 21070 68 21 89 4 7 0 22 AP 41 785 586 27.4 66 16056 38676 69 21 90 4 6 0 32 AQ 42 845 1254 7.5 25 9405 31350 11 68 79 4 11 6 22 AIR 43 775 1480 9.6 26 14208 38480 12 69 81 3 16 0 5 AT 45 778 1152 12.0 42 13824 48384 41 35 76 0 23 1 5 AT 46 688 855 15.9 53 13595 45315 30 20 50 1 19 30 40 AU 47 893 1349 6 3 35 8499 47215 5 51 56 1 41 2 5
    40/47
    Petition 870180161107, of 10/12/2018, p. 50/77 [Table 4]
    Steel type reference symbol Test reference symbol After hot stamping Type of coating *) TS (Mpa) EL (%) ÀÍW TSXEL TSX A Ferrite area fraction (%) Fraction of martensite area f%) Fraction of ferrite area + marten sita {%} Fraction of residual austenite area (%) Bainite area fraction (%) Fraction of perlite area W THE 1 445 41.2 125 18334 55625 87 11 98 1 0 1 CR B 2 457 40.5 118 18509 53926 76 15 91 3 4 2 GA Ç 3 532 35.2 101 18726 53732 75 IO 85 1 5 9 Gl D 4 574 33 3 96 19114 55104 74 15 89 3 8 0 EG AND 5 591 30.9 86 18262 50826 69 15 84 1 11 4 Al F 6 605 30.1 88 18211 53240 82 10 92 3 5 0 CR G 1 611 30.8 87 18819 53157 75 15 90 1 6 3 CR H 8 612 32.0 85 19584 52020 80 15 95 3 0 2 GA I 9 785 25.3 65 19861 51025 56 15 71 4 23 2 GA J 10 795 23.5 65 18683 51675 55 25 80 1 19 0 GA K 11 815 23.5 71 19153 57865 50 32 82 1 17 0 GA L 12 912 22 5 63 20520 57456 45 33 78 2 20 0 Gl M 13 975 20.6 60 20085 58500 50 41 91 3 5 1 GA N 14 992 19.2 52 19046 51584 52 34 86 4 5 5 GA 0 15 1005 18 6 51 18693 51255 48 40 88 3 6 3 Gl P 16 1012 17.8 52 18014 52624 42 28 70 1 29 0 GA Q 17 1023 18 2 50 18619 51150 46 41 87 3 4 6 GA R 18 1031 18.0 55 18558 56705 51 35 86 4 10 0 CR s 19 1042 20.5 48 21361 50016 52 38 90 4 0 6 GA T 20 1125 18 5 48 20813 54000 41 41 82 3 12 3 Gl u 21 1185 16.0 45 18960 53325 42 42 84 1 12 3 EG w 22 1201 15.6 46 18736 55246 43 39 82 4 12 2 GA X 23 1224 14.9 41 18238 50184 41 46 87 2 10 1 Al Y 24 1342 13.5 40 18117 53680 41 41 82 1 16 1 GA z 25 1482 12 5 40 18525 59280 41 48 89 1 9 1 CR
    41/47
    Petition 870180161107, of 10/12/2018, p. 51/77 [Table 5]
    Steel type reference symbol Test reference symbol After hot stamping Type of coating *) TS(Mpa) EL 00 λ® TSxEL TSX Λ Ferrite area fraction (%) Fraction of martensite area {%} Fraction of ferrite area + martens ita (%) Fraction of residual austenite area(%) Bainite area fraction{%) Fraction of perlite area{%) AA 26 814 18.9 61 15385 49654 39 44 83 2 4 n GA AB 27 991 17.1 47 16946 46577 37 47 84 1 3 12 CR B.C 28 1004 16 5 47 16566 47188 36 44 80 2 7 n GA AD 29 1018 15.9 43 16186 43774 31 42 73 1 8 18 EG AE 30 1018 16 3 48 16593 48864 43 40 83 2 3 12 GI AF 31 1184 14 2 42 16813 49728 33 46 79 2 9 10 Al AG 32 715 18.5 55 13228 39325 69 18 87 2 9 2 CR AH 33 440 42.5 105 18700 46200 95 0 95 3 2 0 GA Al 34 1812 85 26 15402 47112 5 90 95 4 1 0 GA AJ 35 812 18.5 50 15022 40600 60 22 82 2 15 1 GA AK 36 1012 17 2 41 17406 41492 55 42 97 2 1 0 GA AL 37 1005 16 5 35 16583 35175 45 41 86 3 10 1 GI AM 38 1002 15.0 41 15030 41082 45 41 86 3 10 1 GI AN 39 1015 18 2 41 18473 41615 51 37 88 3 9 0 GI TO 40 1111 17.0 36 18887 39996 50 30 80 4 7 9 GI AP 41 566 31.0 71 17546 40186 48 40 88 4 6 2 EG AQ 42 1312 11.1 31 14563 40672 n 68 79 4 11 6 Al AIR 43 1512 10 2 31 15422 46872 12 69 81 3 16 0 GA AT 45 1242 10 0 39 12420 48438 41 32 73 3 21 3 GA AT 46 991 13.1 40 12982 39640 24 34 58 1 14 27 GA AL) 47 1326 S.9 31 11801 41106 6 69 75 3 21 1 GA
    42/47
    Petition 870180161107, of 10/12/2018, p. 52/77
    43/47 [Table 6]
    Steel type reference symbol Left side of expression (B) Determination Left side of expression (B) after hot stamping Determination Left side of expression (C) Determination Left side of expression (C) after hot stamping Determination MnS area fraction of 0.1 pm or more before hot stamping (%) MnS area fraction of 0.1 μπι or more after hot stamping (%) THE 1 02 G 1.03 G 15 G 16 G 0.005 0.005 B 1 03 G 1.03 G 19 G 17 G 0.006 0.006 Ç 1.09 G 1.09 G 2 G 3 G 0.014 0.013 D 1.04 G 1.04 G 19 G 18 G 0.006 0.006 AND 1 06 G 1.05 G 14 G 14 G 0.008 0.008 F 1 09 G 1.09 G 13 G 13 G 0.013 0.013 G 1 09 G 1.09 G 10 G 9 G 0.009 0.008 H 1 06 G 1.06 G 8 G 8 G 0.005 0.005 1 1.04 G 1.04 G 7 G 8 G 0.006 0.006 J 1.03 G 1.02 G 12 G 11 G 0.007 0.007 K 1 02 G 1.03 G 16 G 16 G 0.006 0.006 L 1 02 G 1.03 G 15 G 16 G 0.008 0.008 M 1 09 G 1.09 G 12 G 12 G 0.01 1 0.011 N 1 07 G 1.07 G 13 G 14 G 0.003 0.003 0 1 08 G 1.08 G 11 G 11 G 0002 0.002 P 1.06 G 1.06 G 10 G 10 G 0.005 0.005 Q 1 05 G 1.06 G 11 G 11 G 0.006 0.006 R 1 03 G 1.03 G 17 G 16 G 0.007 0.007 s 1 07 G I.07 G 19 G 18 G 0.008 0.009 T 1.09 G 1.08 G 10 G 10 G 0.004 0.004 u 1.09 G 1.09 G 5 G 6 G 0.012 0.012 w 1 08 G 1.09 G 6 G 6 G 0.006 0.006 X 1 07 G 1.06 G 12 G 8 G 0.007 0.007 Y 1 06 G 1.06 G 10 G 10 G 0.005 0.005 z 1.04 G 1.03 G 15 G 17 G 0.006 0.006
    Petition 870180161107, of 10/12/2018, p. 53/77
    44/47 [Table 7]
    Steel type reference symbol Left side of expression (B) Determination Left side of expression (B) after hot stamping Determination Left side of expression (C) Determination Left side of expression (C) after hot stamping Determination MnS area fraction of 0.1 pm or more before hot stamping (%) MnS area fraction of 0.1 pm or more after hot stamping (%) AA 1.12 B 1.12 B 21 B 21 B 0.010 0.010 AB 1.14 B 1.13 B 23 B 22 B 0.008 0.008 B.C 1.11 B 1.11 B 20 B 20 B 0.006 0.006 AD 1.17 B 1.16 B 25 B 25 B 0.007 0.007 AE 1.13 B 1.13 B 22 B 21 B 0.009 0.009 AF 1.10 B 1.09 G 20 B 19 G 0.002 0.002 AG 1.12 B 1.13 B 22 B 23 B 0.003 0.003 AH 1.15 B 1.15 B 21 B 21 B 0.004 0.004 THERE 1.23 B 1.18 B 25 B 25 B 0.006 0.006 AJ 1.21 B 1.21 B 22 B 22 B 0.007 0.007 AK 1.14 B 1.14 B 21 B 21 B 0.008 0.007 AL 0.36 B 0.37 B 31 B 30 B 0.006 0.006 AM 1.36 B 1.37 B 32 B 31 B 0.006 0.006 AN 1.23 B 1.25 B 25 B 28 B 0.009 0.008 TO 1.35 B 1.33 B 30 B 35 B 0.004 0.004 AP 1.05 G 1.04 G 12 G 11 G 0.006 0.006 AQ 1.15 B 1.16 B 21 B 25 B 0.003 0.003 AIR 1.08 G 1.08 G 18 G 18 G 0.002 0.002 AT 1.19 B 1.17 B 24 B 23 B 0.005 0.005 AT 1.29 B 1.28 B 28 B 27 B 0.004 0.005 AU 1.09 G 1.09 G 19 G 19 G 0.005 0.005
    Petition 870180161107, of 10/12/2018, p. 54/77 [Table 8]
    Steel type reference symbol Before hot stamping After hot stamping Left side of expression (E) OIB5«ΓAND(The d Left side of expression (F) CT Right side of expression (F) The Iff)rcc E jstD O Ro heating oven temperature Heating oven time (minutes) Left side of expression (G) HI COANDscu Q n1 n2 Left side of expression (DJ Determination n11 n21 Left side of expression (D) Determination THE 9 13 1.4 G 9 12 1.3 G 1.4 G 401 550 679 G 1200 85 1918 G B 3 4 1.3 G 3 4 1.3 G 1.2 G 386 620 668 G 1250 102 1948 G Ç 2 3 1.5 B 2 3 1.5 B 1.1 G 307 542 600 G 1154 152 1317 B D 6 7 1.2 G 5 6 1.2 G 1.4 G 377 553 653 G 1123 124 1748 G AND 2 2 1.0 G 2 2 1.0 G 1.6 G 382 632 657 G 1215 136 2231 G F 2 2 1.0 G 2 2 1.0 G 1.2 G 368 664 654 B 1223 127 1873 G G 1 1 1.0 G 1 1 1.0 G 1.3 G 379 701 668 B 1123 111 1831 G H 5 5 1.0 G 5 6 1.2 G 1.2 G 374 631 643 G 1156 106 1778 G 1 4 5 1.3 G 4 5 1.3 G 1.7 G 382 558 669 G 1148 95 1670 G J 3 4 1.3 G 3 4 1.3 G 1.4 G 372 559 639 G 1206 87 1522 G K 7 7 1.0 G 7 8 1.1 G 1.1 G 381 674 669 B 1214 152 2235 G L 5 6 1.2 G 5 6 1.2 G 1.3 G 319 452 597 G 1233 182 1524 G M 11 19 1.7 B 11 18 1.6 B 1.3 G 369 442 660 G 1112 47 1422 B N 6 7 1.2 G 6 8 1.3 G 1.2 G 271 512 543 G 1287 252 1513 G O 2 2 1.0 G 2 2 1.0 G 1.6 G 331 612 615 G 1250 122 1535 G P 4 5 1.3 G 4 5 1.3 G 1.7 G 285 487 554 G 1285 222 1587 G Q 7 8 1.1 G 7 9 1.3 G 1.9 G 334 566 622 G 1156 135 1642 G R 16 19 1.2 G 15 18 1.2 G 1.4 G 321 567 614 G 1222 185 1761 G s 11 12 1.1 G 10 12 1.2 G 1.3 G 327 554 617 G 1232 122 1589 G T 6 7 1.2 G 6 7 1.2 G 1.1 G 277 512 564 G 1256 152 1522 G u 7 14 2.0 B 7 13 1.9 B 1.2 G 277 521 554 G 1256 138 1472 B w 17 21 1.2 G 15 20 1.3 G 1.1 G 310 571 609 G 1250 145 1550 G X 23 27 1.2 G 22 25 1.1 G 1.2 G 360 656 640 B 1150 138 1600 G Y 21 28 1.3 G 20 28 1.4 G 1.4 G 275 522 554 G 1260 182 1526 G z 26 33 1.3 G 25 32 1.3 G 1.5 G 280 504 571 G 1250 151 1554 G
    45/47
    Petition 870180161107, of 10/12/2018, p. 55/77 [Table 9]
    Steel type reference symbol Before hot stamping After hot stamping Left side of expression (E) Determination Left side of expression (F) CT Right side of expression (F) Determination Heating oven temperature’C) Heating oven time (minutes) Left side of expression (G) Determination n1 n2 Left side of expression (D) Determination n11 n21 Left side of expression (□) Determination AA 12 14 1.2 G 12 15 1.3 G 09 B 358 602 643 G 1200 132 1746 G AB 9 13 1.4 G 9 13 1.4 G 08 B 354 505 641 G 1200 126 1739 G B.C 14 18 1.3 G 14 19 1.4 G 08 B 341 506 630 G 1188 133 1677 G AD 5 7 1.4 G 5 7 1.4 G 06 B 349 443 634 G 1165 145 1593 G AE 12 16 1.3 G 12 15 1.3 G 07 B 340 611 627 G 1152 152 1590 G AF 17 23 1.4 G 16 22 1.4 G 1Ό B 350 352 639 G 1187 89 1563 G AG 5 6 1.2 G 5 7 1.4 G 09 B 341 555 634 G 1201 152 1644 G AH 3 4 1.3 G 3 4 1.3 G 1.1 G 407 436 683 G 1203 125 1965 G THERE 12 16 1.3 G 12 15 1.3 G 1.1 G 247 541 568 G 1250 175 1549 G AJ 16 21 1.3 G 15 20 1.3 G 1.3 G 331 577 607 G 1200 96 1518 G AK 11 13 1.2 G 11 12 1.1 G 1.2 G 375 578 628 G 1201 166 1508 G AL 12 18 1.5 G 12 17 1.4 G 1.1 G 506 578 796 G 1285 205 8593 G AM 15 20 1.3 G 14 20 1.4 G 1.2 G 248 533 543 G 1285 312 1529 G AN 10 11 1.1 G 10 12 1.2 G 1.1 G 305 580 580 G 1212 125 1538 G TO 9 11 1.2 G 8 11 1.4 G 1.2 G 302 564 578 G 1285 185 1535 G AP 6 8 1.3 G 6 8 1.3 G 1.1 G 405 582 683 G 1200 135 2066 G AQ 12 14 1.2 G 12 15 1.3 G 1.1 G 273 477 560 G 1250 166 1568 G AIR 21 24 1.1 G 22 25 1.1 G 1.5 G 277 504 563 G 1254 222 1634 G AT 17 19 1.1 G 15 18 1.2 G 1.3 G 354 620 655 G 1224 201 2526 G AT 16 16 1.0 G 15 17 1.1 G 1.3 G 313 550 610 G 1199 201 1779 G AU 16 19 1.2 G 15 18 1.2 G 1.6 G 311 552 608 G 1184 201 1687 G
    46/47
    Petition 870180161107, of 10/12/2018, p. 56/77
    47/47 [00109] Based on the examples described above, as long as the conditions of the present invention are met, it is possible to obtain an excellent cold-rolled steel sheet, an excellent hot-dip galvanized cold-rolled steel sheet, an excellent galvanealed cold rolled steel plate, all of which satisfy TS x λ> 50000 MPa-%, before hot stamping and / or after hot stamping.
    Industrial Applicability [00110] Since the cold-rolled steel sheet, the hot-dip galvanized cold-rolled steel sheet, and the galvannealed cold-rolled steel sheet that are obtained in the present invention and satisfy TS x λ> 50000 MPa-% before hot stamping and after hot stamping, hot stamped steel has a high pressing work capacity and high strength, and meets current vehicle requirements such as additional weight reduction and a more complicated form of a component.
    Brief description of reference symbols
    S1: CASTING PROCESS
    S2: CASTING PROCESS
    S3: HEATING PROCESS
    S4: HOT LAMINATION PROCESS
    S5: COILING PROCESS
    S6: STRIPPING PROCESS
    S7: COLD LAMINATION PROCESS
    S8: RECOVERY PROCESS
    S9: CRUISE LAMINATION PROCESS
    S10: GALVANIZATION PROCESS
    S11: CONNECTION PROCESS
    S12: ALUMINIZATION PROCESS
    S13: ELECTROGALVANIZATION PROCESS.
    Petition 870180161107, of 10/12/2018, p. 57/77
    权利要求:
    Claims (15)
    [1]
    1. Cold rolled steel sheet, characterized by the fact that it consists of, in% by mass,
    C: 0.030% to 0.150%;
    Si: 0.010% to 1,000%;
    Mn: 1.50% to 2.70%;
    P: 0.001% to 0.060%;
    S: 0.001% to 0.010%;
    N: 0.0005% to 0.0100%;
    Al: 0.010% to 0.050%, and optionally one or more between
    B: 0.0005% to 0.0020%;
    Mo: 0.01% to 0.50%;
    Cr: 0.01% to 0.12%;
    V: 0.001% to 0.100%;
    Ti: 0.001% to 0.100%;
    Nb: 0.001% to 0.050%;
    Ni: 0.01% to 1.00%;
    Cu: 0.01% to 1.00%;
    Ca: 0.0005% to 0.0050%;
    REM: 0.0005% to 0.0050%, and the balance of Fe and the inevitable impurities, where when [C] represents a quantity of C in mass%, [Si] represents a quantity of Si in mass% , and [Mn] represents an amount of Mn in% by mass, an expression (A) is satisfied below, a metallographic structure consists of 40% to 90% of a ferrite, 10% to 60% of a martensite in a fraction of area, and optionally one or more than 10% or less of a perlite in a fraction of area, 5% or less of an austenite retained in a ratio of
    Petition 870190051060, of 05/31/2019, p. 5/13
    [2]
    2/5 volume, and less than 40% of a bainite as a remainder in a fraction of area, a total of a fraction of the ferrite area and a fraction of the area of the martensite is 60% or greater, a hardness of the martensite measured with a nanoindentator satisfies an expression (B) to follow and an expression (C) to follow,
    TS x λ, which is a product of TS tensile strength and bore expansion ratio λ, is 50000MPa-% or greater, (5 x [Si] + [Mn]) / [C]> 11 (A) ,
    H2 / H1 <1.10 (B), and σΗΜ <20 (C), where H1 is an average hardness of martensite on a part of the surface of a sheet thickness that is within an area with a width of 200 pm in a thickness direction of an outer layer of the steel sheet before hot stamping, H2 is an average hardness of martensite in a central part of the sheet thickness, which is an area having a width of 200 pm in one direction the thickness in one center of the plate thickness, and σΗΜ is a variation of the martensite hardness in the central part of the plate thickness before hot stamping.
    2. Cold-rolled steel sheet according to claim 1, characterized by the fact that a fraction of the MnS area that exists in the cold-rolled steel sheet and that has a circle diameter equivalent to 0.1 pm to 10 pm is 0.01% or less, an expression (D) below is satisfied, n2 / n1 <1.5 (D), where n1 is an average numerical density per 10,000 pm 2 of MnS, having a diameter of circle equivalent to 0.1 pm to 10 pm in% of part of the sheet thickness before stamping to
    Petition 870190051060, of 05/31/2019, p. 6/13
    [3]
    3/5 hot, and n2 is an average numerical density per 10,000 pm 2 of MnS having a circle diameter equivalent to 0.1 pm to 10 pm in the central part of the sheet thickness before hot stamping.
    3. Cold rolled steel sheet according to claim 1 or 2, characterized by the fact that a galvanization is formed on a surface thereof.
    [4]
    4. Cold rolled steel sheet according to claim 1 or 2, characterized by the fact that a hot dip galvanization is formed on a surface thereof.
    [5]
    5. Cold rolled steel sheet according to claim 4, characterized by the fact that a galvanizing annealing is formed on a surface of the cold rolled steel sheet on which hot dip galvanizing is formed on a surface of the same.
    [6]
    6. Cold rolled steel sheet according to claim 1 or 2, characterized by the fact that an electrogalvanization is formed on a surface thereof.
    [7]
    7. Cold-rolled steel sheet according to claim 1 or 2, characterized by the fact that an aluminization is formed on a surface thereof.
    [8]
    Cold rolled steel sheet according to any one of claims 1 to 7, characterized in that the cold rolled steel sheet is used for hot stamping.
    [9]
    9. Method for producing a cold rolled steel sheet, as defined in claim 1 or 2, the method being characterized by the fact that it comprises:
    ingot a molten steel having a chemical composition as defined in claim 1 and obtaining a steel;
    heat the steel;
    Petition 870190051060, of 05/31/2019, p. 7/13
    4/5 hot rolling steel with a hot rolling mill including a plurality of supports;
    winding steel after hot rolling;
    stripping the steel after winding;
    cold rolling the steel with a cold rolling mill including a plurality of supports after blasting under a condition that satisfies an expression (E) below;
    perform annealing in which the steel is annealed under 700 ° C to 850 ° C and cooled after cold rolling;
    perform hardening lamination on steel after annealing;
    I, 5 χ r1 / r + 1.2 χ r2 / r + r3 / r> 1.0 (E), and the ri (i = 1, 2, 3) represents an individual target reduction of cold rolling in one i the support (i = 1,2,3) counted from a first support among the plurality of supports in cold rolling in units of%, and r represents a total reduction of cold rolling in units of%.
    [10]
    10. Method for producing cold-rolled steel sheet according to claim 9, characterized by the fact that it also comprises:
    galvanize the steel between annealing and hardening lamination.
    II. Method for the production of cold rolled steel sheet according to claim 9, characterized by the fact that when CT represents a winding temperature in the winding in the ° C unit, [C] represents the amount of C in mass%, [Mn] represents the amount of Mn in% by mass, [Cr] represents the amount of Cr in% by mass, and [Mo] represents the amount of Mo in% by mass, an expression (F) below is satisfied,
    Petition 870190051060, of 05/31/2019, p. 8/13
    5/5
    560 - 474 χ [C] - 90 χ [Mn] - 20 χ [Cr] - 20 χ [Mo] <CT <830 - 270 χ [C] - 90 χ [Mn] - 70 χ [Cr] - 80 χ [Mo] (F).
    [11]
    12. Method for producing the cold rolled steel sheet according to claim 11, characterized by the fact that when T represents a heating temperature in units of ° C, t represents a time in the oven for heating in units of minutes, [Mn] represents the amount of Mn in% by mass, and [S] represents an amount of S in% by mass, an expression (G) below is satisfied
    T χ ln (t) / (1.7 χ [Mn] + [S])> 1500 (G).
    [12]
    13. Method for producing cold rolled steel sheet according to any of claims 9 to 12, characterized by the fact that it also comprises:
    galvanize the steel between annealing and hardening lamination.
    [13]
    14. Method for producing cold-rolled steel sheet according to claim 13, characterized by the fact that it also comprises:
    connect the steel between galvanizing and hardening lamination.
    [14]
    15. Method for producing cold-rolled steel sheet according to any of claims 9, 11 and 12, characterized by the fact that it also comprises:
    electrogalvanize steel after hardening lamination.
    [15]
    16. Method for producing cold rolled steel sheet according to any of claims 9, 15 and 16, characterized by the fact that it also comprises:
    aluminize the steel between annealing and hardening lamination.
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    同族专利:
    公开号 | 公开日
    US9920407B2|2018-03-20|
    KR101660607B1|2016-09-27|
    WO2013105638A1|2013-07-18|
    BR112014017020A8|2017-07-04|
    RU2586387C2|2016-06-10|
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    CA2862257A1|2013-07-18|
    PL2803747T3|2019-09-30|
    CN104040010A|2014-09-10|
    CA2862257C|2018-04-10|
    JPWO2013105638A1|2015-05-11|
    TWI524953B|2016-03-11|
    CN104040010B|2016-06-15|
    EP2803747A1|2014-11-19|
    ZA201404813B|2015-08-26|
    US20140342185A1|2014-11-20|
    RU2014129323A|2016-03-10|
    JP5545414B2|2014-07-09|
    KR20140102755A|2014-08-22|
    EP2803747B1|2019-03-27|
    MX2014008428A|2014-10-06|
    TW201345627A|2013-11-16|
    ES2727684T3|2019-10-17|
    BR112014017020A2|2017-06-13|
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    法律状态:
    2018-03-13| B06T| Formal requirements before examination [chapter 6.20 patent gazette]|
    2018-09-11| B07A| Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]|
    2019-03-06| B06A| Patent application procedure suspended [chapter 6.1 patent gazette]|
    2019-08-20| B25D| Requested change of name of applicant approved|Owner name: NIPPON STEEL CORPORATION (JP) |
    2020-02-27| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|
    2020-04-14| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 11/01/2013, OBSERVADAS AS CONDICOES LEGAIS. |
    2021-11-03| B21F| Lapse acc. art. 78, item iv - on non-payment of the annual fees in time|Free format text: REFERENTE A 9A ANUIDADE. |
    2022-02-22| B24J| Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)|Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2652 DE 03-11-2021 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |
    优先权:
    申请号 | 申请日 | 专利标题
    JP2012004549|2012-01-13|
    JP2012004864|2012-01-13|
    PCT/JP2013/050405|WO2013105638A1|2012-01-13|2013-01-11|Cold-rolled steel sheet and method for producing cold-rolled steel sheet|
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