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    • 专利摘要:
    AEROSOL FOAM FORMING PRODUCT. The purpose of the present invention is to provide a foaming aerosol product which can be applied with a high degree of safety regardless of the environment of use, which has excellent storage stability and which has the ability to easily form a satisfactory foam. This aerosol foaming product is characterized by having a double structure container with a discharge mechanism that has a propellant filling space and two stock liquid filling spaces, the discharge mechanism being to simultaneously discharge contents that fill the two stock liquid filling spaces, a propellant that comprises a compressed gas that fills the propellant filling space, a first stock liquid composition that contains 0.5 to 15.0% in mass of an organic acid being that it fills a first stock liquid filling space, a second stock liquid composition that contains from 0.5 to 15.0% by mass of a bicarbonate substance being that it fills a second space of filling filling liquid stock and a foam being formed by mixing the first composition (...).
    公开号:BR112014010853B1
    申请号:R112014010853-6
    申请日:2012-08-16
    公开日:2021-01-12
    发明作者:Yasutomo Nakajima
    申请人:Toyo Aerosol Industry Co., Ltd.；
    IPC主号:
    专利说明:

    [0001] [0001] The present invention relates to a foaming aerosol product. BACKGROUND OF THE INVENTION
    [0002] [0002] A type of aerosol product that has been known until then is configured to hold an aerosol composition that includes a liquid concentrate that contains active ingredients and a propellant in an aerosol container, which is a pressure-resistant container that has a sprinkling value. The aerosol product delivers a sparkling discharge as the evaporating propellant forms bubbles in the discharged liquid.
    [0003] [0003] In order to obtain favorable foaming capacity or stability of the discharged foam, a liquefied gas such as petroleum gas or liquefied dimethyl ether is used as the propellant in such a foaming aerosol product. Since these liquefied gases are combustible, there are problems with the danger of handling them depending on the environment in which they are used and the possibility of explosion risks when disposing the aerosol container. Although petroleum gas and liquefied dimethyl ether produce less airborne particulate matter or greenhouse gases as compared to other fossil fuels, they can, not enough, adversely affect the environment.
    [0004] [0004] A combination of compositions, such as, for example, an organic acid composition that contains an organic acid, for example, citric acid, for example, and a hydrogen carbide composition that contains a hydrogen carbide, for example For example, sodium hydrogen carbonate, for example, is known to form a foam since it generates carbon dioxide gas when mixed (see, for example, Patent Literature 1 to 3).
    [0005] [0005] However, since these compositions containing organic acid and hydrogen carbide need to be kept separately in tube or cup-shaped containers that are hermetically sealed with a lid, they need to be dispensed from the respective containers and mixed when used, which is a complicated process. In addition, they may not be mixtures at an appropriate mixing ratio due to the fact that the difficulty in adjusting the amount dispensed from the respective containers. Another problem is that the compositions in the containers are exposed to air each time they are dispensed, which can compromise their stability over long-term storage. LIST OF QUOTES PATENT LITERATURE
    [0006] [0006] Patent Literature 1: Japanese Patent Application Open to Public Inspection No. 2000-297007
    [0007] [0007] Patent Literature 2: Japanese Patent Application Open to Public Inspection No. 2000-297008
    [0008] [0008] Patent Literature 3: Japanese Patent Application Open to Public Inspection No. 2009-091365 SUMMARY OF THE INVENTION Technique Problem
    [0009] [0009] The present invention was made in view of the aforementioned circumstances and its objective is to provide a foaming aerosol product that can be used in a highly safe manner regardless of the environment in which it is used and which has excellent storage stability and is able to readily form a favorable foam. Solution to the Problem
    [0010] [0010] The foaming aerosol product of the present invention includes a double structure container that has a propellant fill space, two independent liquid concentrate fill spaces and a discharge mechanism to simultaneously discharge the contents filled in both liquid concentrate filling spaces, where:
    [0011] [0011] the propellant filling space in the double structure container is filled with a propellant composed of a compressed gas;
    [0012] [0012] a first liquid concentrate composition containing an organic acid, water, a surfactant and a higher alcohol is filled in a first liquid concentrate filling space of the double-structure container, in which the organic acid is contained in a ratio from 0.5 to 15.0% by weight;
    [0013] [0013] a second liquid concentrate composition containing a hydrogen carbide, water, a surfactant and a higher alcohol is filled in a second liquid concentrate filling space of the double structure container, in which the hydrogen carbide is contained in a content ratio of 0.5 to 15.0% by weight; and
    [0014] [0014] the first liquid concentrate composition discharged from the first liquid concentrate filling space and the second liquid concentrate composition discharged from the second liquid concentrate filling space are mixed to form a foam.
    [0015] [0015] In the foaming aerosol product of the present invention, the mixing ratio of the first liquid concentrate composition discharged from the first liquid concentrate filling space and the second liquid concentrate composition discharged from the second liquid concentrate filling space. (mass of the first liquid concentrate composition: mass of the second liquid concentrate composition) may preferably be 0.8: 1.2 to 1.2: 0.8.
    [0016] [0016] In the foaming aerosol product of the present invention, the first liquid concentrate composition may preferably have a viscosity of 10 to 15,000 mPa • s at a temperature of 20 ° C, the second liquid concentrate composition may preferably have a viscosity of 10 to 15,000 mPa • s at a temperature of 20 ° C and also each of the viscosity of the first liquid concentrate composition and the viscosity of the second liquid concentrate composition can preferably fall within a ± 20% range of an average viscosity of the first liquid concentrate composition and the second liquid concentrate composition.
    [0017] [0017] In the foaming aerosol product of the present invention, the discharge mechanism may preferably include a mixing space for mixing the first liquid concentrate composition discharged from the first liquid concentrate filling space and the second composition of liquid concentrate discharged from the second liquid concentrate filling space.
    [0018] [0018] The foaming aerosol product of the present invention may preferably be intended to be applied to the human body. ADVANTAGE EFFECTS OF THE INVENTION
    [0019] [0019] The foaming aerosol product of the present invention includes a double structure container that has a discharge mechanism to simultaneously discharge the contents filled in the two liquid concentrate filling spaces, wherein a first liquid concentrate composition that contains a specific ratio of an organic acid that is filled in one of the two liquid concentrate filling spaces, while a second liquid concentrate composition that contains a specific ratio of a hydrogen carbide is filled in the other liquid concentrate filling space. In this way, the first liquid concentrate composition and the second liquid concentrate composition can be discharged from the respective two liquid concentrate filling spaces of the double structure container in appropriate quantities at the same time. In this way, the first liquid concentrate composition and the second liquid concentrate composition are always mixed in a constant ratio, as a result of which a favorable foam is readily formed by carbon dioxide gas that is generated by the reaction between the organic acid and the hydrogen carbide. Since an incombustible compressed gas is used as the propellant for the first liquid concentrate composition and the second liquid concentrate composition, the product can be used in a highly safe manner regardless of the environment in which it is used. Furthermore, since neither the first liquid concentrate composition nor the second liquid concentrate composition is exposed to air outside the container when used, they can be kept stable through long-term storage.
    [0020] Consequently, the foaming aerosol product of the present invention can be used in a highly safe manner regardless of the environment in which it is used, has excellent storage stability and is capable of promptly forming a favorable foam. BRIEF DESCRIPTION OF THE DRAWINGS
    [0021] [0021] FIG. 1 is a diagram illustrating an example of the structure of the double-structure container used for the foaming aerosol product of the present invention.
    [0022] [0022] FIG. 2 is a cross-sectional view illustrating a section A-A 'of FIG. 1.
    [0023] [0023] FIG. 3 is a diagram illustrating another example of the structure of the double-structure container used for the foaming aerosol product of the present invention.
    [0024] [0024] FIG. 4 is a diagram illustrating yet another example of the structure of the double-structure container used for the foaming aerosol product of the present invention.
    [0025] [0025] FIG. 5 is a cross-sectional view illustrating a section A-A 'of FIG. 4.
    [0026] [0026] FIG. 6 is a diagram illustrating yet another example of the double-structure container structure used for the foaming aerosol product of the present invention. DESCRIPTION OF THE MODALITIES
    [0027] [0027] The foaming aerosol product of the present invention includes a double structure container that has a propellant fill space, two independent liquid concentrate fill spaces, and a discharge mechanism for simultaneously discharging the contents filled in both. liquid concentrate filling spaces, where In the double structure container, the propellant filling space is filled with a propellant composed of a compressed gas and a first liquid concentrate filling space is filled with a first liquid concentrate composition that contains an organic acid, while a second liquid concentrate fill space filled with a second liquid concentrate composition that contains a hydrogen carbide.
    [0028] [0028] The foaming aerosol product of the present invention forms a foam produced by means of carbon dioxide gas which is generated by the reaction between an organic acid and a hydrogen carbide under the mixture of the first and the second concentrate compositions liquid discharged simultaneously from the first and second liquid concentrate filling spaces, respectively. (First composition of liquid concentrate)
    [0029] [0029] The first liquid concentrate composition contains an organic acid, water, a surfactant and a higher alcohol as essential components, the organic acid being contained in a content ratio of 0.5 to 15.0% by weight.
    [0030] [0030] Examples of organic acids, as an essential component of the first liquid concentrate composition, include citric acid, lactic acid, fumaric acid and tartaric acid.
    [0031] [0031] These can be used either separately or in any combination of them.
    [0032] [0032] Organic acid can preferably be a citric acid from the point of view of its solubility for water and the ability to produce carbon dioxide.
    [0033] [0033] The organic acid content ratio needs to be 0.5 to 15.0% by weight and is preferably 2.0 to 10.0% by weight, more preferably 4.0 to 9% by weight, per 100 % by mass of the first liquid concentrate composition.
    [0034] [0034] If the organic acid content ratio is too high, the organic acid may not be fully dissolved in the first liquid concentrate composition or the viscosity of the first liquid concentrate composition may decrease, which may lead to dripping at the application. The production cost will be higher, too. On the other hand, if the organic acid content ratio is very low, sufficient foaming capacity may not be achieved.
    [0035] [0035] Water with an essential component of the first liquid concentrate composition can be purified water or ion exchange water.
    [0036] [0036] The water content ratio is preferably 70.0 to 99.0% by weight, more preferably 75.0 to 95.0% by weight, particularly preferably 80.0 to 90.0% by weight , per 100% by weight of the first liquid concentrate composition.
    [0037] [0037] If the water content ratio is too high, other ingredients may not be contained in a sufficient ratio. On the other hand, if the water content ratio is too low, sufficient foaming capacity may not be achieved and the cost of production may be increased.
    [0038] [0038] As a surfactant, which is an essential component of the first liquid concentrate composition, a nonionic surfactant can preferably be used, since it is hardly affected by an organic acid.
    [0039] [0039] Examples of non-ionic surfactants that are preferred from the point of view of foaming capacity include those that have a BHL value of 10 to 18 that includes polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbitol fatty acid ester , polyoxyethylene hardened castor oil, hydrogenated sterol / sterol, polyoxyethylene alkyl ether, polyoxypropylene polyoxyethylene alkyl ether and lecithin derivatives.
    [0040] [0040] These can be used either separately or in any combination of them.
    [0041] [0041] Surfactants other than nonionic surfactants, such as, for example, anionic surfactants, cationic surfactants and amphoteric surfactants, can also be used in the first liquid concentrate composition.
    [0042] [0042] The content ratio of the surfactant is preferably 0.1 to 10% by weight, more preferably 0.5 to 8.0% by weight, particularly preferably 1.0 to 4.0% by weight, per 100% by weight of the first liquid concentrate composition.
    [0043] [0043] If the content ratio of the surfactant is too high, the cost of production will become high and for human body applications in particular, the composition may not give a favorable feeling when applied, since the surfactant adds a sensation sticky. On the other hand, if the surfactant content ratio is too low, sufficient foaming capacity may not be achieved and the first liquid concentrate composition may not have sufficient emulsification stability.
    [0044] [0044] Examples of higher alcohols, as an essential component of the first liquid concentrate composition, include lauryl alcohol, myristyl alcohol, cetyl alcohol, cetostearyl alcohol, arachyl alcohol, beenyl alcohol, oleyl alcohol, jojoba alcohol, stearyl alcohol, cholesterol , phytosterol, lanolin alcohol, octyldodecanol, hexildecanol and isostearyl alcohol.
    [0045] [0045] These can be used either separately or in any combination of them.
    [0046] [0046] Cetyl alcohol or ceto-stearyl alcohol, particularly cetyl alcohol, can preferably be used as superior alcohol in the first liquid concentrate composition.
    [0047] [0047] The higher alcohol content ratio is preferably 0.1 to 10.0% by weight, more preferably 1.0 to 5.0% by weight, particularly preferably 2.0 to 4.0% by weight, by 100% by weight of the first liquid concentrate composition.
    [0048] [0048] If the higher alcohol content ratio is too high, the viscosity of the first liquid concentrate composition will increase, due to the fact that sufficient foaming capacity may not be achieved. On the other hand, if the higher alcohol content ratio is very low, the viscosity of the first liquid concentrate composition will decrease, which can lead to dripping at the application site. Also, the first liquid concentrate composition may not have sufficient emulsification stability. In addition, for human body applications, the composition may not feel favorable when applied.
    [0049] [0049] The first liquid concentrate composition may contain other optional components as required in addition to the essential components of organic acid, water, surfactant and higher alcohol.
    [0050] [0050] Examples of optional components include esters, oil-based materials, polyhydric alcohols, waxes, film-forming agents, other base conditioning agents (such as a humectant, a thickener and a pigment) , medicinal agents and fragrance ingredients. Esters are preferred among these.
    [0051] [0051] Esters can be used in the first liquid concentrate composition related to the foaming aerosol product of the present invention as a viscosity adjusting agent for the first liquid concentrate composition, for example, or, for body applications in particular, as a humectant or an emollient ingredient to enhance sensation when used.
    [0052] [0052] Examples of esters include higher fatty acid esters which include ethyl linoleate, isopropyl myristate, isopropyl palmitate, isopropyl isostearate, lanolin fatty acid isopropyl ester, lanolin acid hexyl ester, myristylmiristate, octyl myristate , cetyl lactate, ethyl oleate, decyl oleate, octyldodecyl oleate, cetyl octanoate, dioctyl succinate, glyceryl tricaprilate, glyceryl triisoestearate, propylene glycol tipprate, cetyl palmitate and glycyl trilate and caprate. These can be used either separately or in any combination of them.
    [0053] [0053] The ratio of esters content may be different depending on the purpose of use of the foaming aerosol product or the types and content ratios of other constituent components of the first liquid concentrate composition. However, the content ratio may be preferably 0.1 to 2.0% by weight, more preferably 0.2 to 1.0% by weight, particularly preferably 0.3 to 0.7% by weight, per 100% by weight of the first liquid concentrate composition.
    [0054] [0054] If the ester content ratio is too high, sufficient foaming capacity may not be achieved. For human body applications, in particular, a problem may arise as the ester adds a sticky sensation, due to the fact that the product may not give a favorable feeling when applied. On the other hand, if the ratio of esters content is very low, the expected effects of the esters on the foaming aerosol product may not be fully explored.
    [0055] [0055] The first liquid concentrate composition composed of the essential and optional components as described above may preferably have a viscosity of 10 to 15,000 mPa • s and a temperature of 20 ° C, more preferably 10 to 10,000 mPa • s, particularly preferably 1,000 to 5,000 mPa • s.
    [0056] [0056] If the viscosity of the first liquid concentrate composition is too high, the first liquid concentrate composition may not be sufficiently mixed with the second liquid concentrate composition, due to the fact that sufficient foaming capacity may not be achieved. On the other hand, if the viscosity of the first liquid concentrate composition is very low, the product may tend to drip at the application site.
    [0057] [0057] The viscosity of the first liquid concentrate composition can preferably be within a range of ± 20%, more preferably ± 15%, of an average of the viscosities of the first liquid concentrate composition and the second liquid concentrate composition ( hereinafter also referred to as "average viscosity value"), taking into account the relationship with the viscosity of the second liquid concentrate composition to be described later.
    [0058] [0058] If the viscosity of the first liquid concentrate composition falls outside the range of the average viscosity value noted above, that is, if it is higher than + 20% or lower than -20% of the average viscosity value, there will be a big difference in the amount of the first liquid concentrate composition discharged from the first liquid concentrate filling space and that of the second liquid concentrate composition discharged from the second liquid concentrate filling space. As a result, the foam produced by the first and second mixtures of liquid concentrate mixtures may not exhibit sufficient foamability. (Second composition of liquid concentrate)
    [0059] [0059] The second composition of liquid concentrate contains a hydrogen carbide, water, a surfactant and an alcohol superior to the essential components, in which the hydrogen carbide is contained in a content ratio of 0.5 to 15.0% in pasta.
    [0060] [0060] Examples of hydrogen carbide, as an essential component of the second liquid concentrate composition, include sodium hydrogen carbonate, calcium hydrogen carbide and potassium hydrogen carbide.
    [0061] [0061] These can be used either separately or in any combination of them.
    [0062] [0062] Like hydrogen carbide, sodium hydrogen carbonate can preferably be used from the point of view of the fact that it is highly safe and versatile and widely used in a variety of fields such as cosmetics , drugs, household products, food and so on, just as it is cheap.
    [0063] [0063] The hydrogen carbide content ratio needs to be 0.5 to 15.0% by weight, preferably 3.0 to 12.0% by weight, more preferably 5.0 to 11.0% by weight, per 100% by weight of the second liquid concentrate composition.
    [0064] [0064] If the hydrogen carbide content ratio is too high, the hydrogen carbide may not be fully dissolved in the second liquid concentrate composition. The production cost will be higher, too. On the other hand, if the hydrogen carbide content ratio is too low, sufficient foaming capacity may not be achieved.
    [0065] [0065] Water as an essential component of the second liquid concentrate composition can be any of these data as examples of water that constitute the first liquid concentrate composition.
    [0066] [0066] The water content ratio is preferably 70.0 to 99.0% by weight, more preferably 75.0 to 95.0% by weight, particularly preferably 80.0 to 90.0% by weight. mass, per 100% by mass of the second liquid concentrate composition.
    [0067] [0067] If the water content ratio is too high, other ingredients may not be contained in a sufficient ratio in the second liquid concentrate composition. On the other hand, if the water content ratio is too low, sufficient foaming capacity may not be achieved and the cost of production may be increased.
    [0068] [0068] As a surfactant, which is an essential component of the second liquid concentrate composition, a nonionic surfactant can preferably be used, since it is hardly affected by a hydrogen carbonate.
    [0069] [0069] The non-ionic surfactant as an essential component of the second liquid concentrate composition can be any of these data as examples of the non-ionic surfactant that constitutes the first liquid concentrate composition.
    [0070] [0070] These can be used either separately or in any combination of them,
    [0071] [0071] Surfactants other than non-ionic surfactants, such as, for example, anionic surfactants, cationic surfactants and amphoteric surfactants, can also be used in the second liquid concentrate composition
    [0072] [0072] The content ratio of the surfactant is preferably 0.1 to 10% by weight, more preferably 0.5 to 8.0% by weight, particularly preferably 1.0 to 4.0% by weight, per 100% by weight of the second liquid concentrate composition.
    [0073] [0073] If the content ratio of the surfactant is too high, the production cost will become high and for human body applications in particular, the composition may not give a favorable feeling when applied, since the surfactant adds a sensation sticky. On the other hand, if the surfactant content ratio is too low, sufficient foaming capacity may not have sufficient emulsification stability.
    [0074] [0074] Higher alcohol as an essential component of the second liquid concentrate composition can be any of these data as examples of the higher alcohol that constitutes the first liquid concentrate composition.
    [0075] [0075] These can be used either separately or in any combination of them.
    [0076] [0076] Cetyl alcohol or ceto-stearyl alcohol, particularly cetyl alcohol, can preferably be used as superior alcohol in the second liquid concentrate composition.
    [0077] [0077] The higher alcohol which constitutes the second liquid concentrate composition may be different from, or the same as, the higher alcohol which constitutes the first liquid concentrate composition, which depends on the purpose of using the foaming aerosol product or ease and cost of production.
    [0078] [0078] The higher alcohol content ratio is preferably 0.1 to 10.0% by weight, more preferably 1.0 to 5.0% by weight, particularly preferably 2.0 to 4.0% by weight, by 100% by weight of the second liquid concentrate composition.
    [0079] [0079] If the higher alcohol content ratio is too high, the viscosity of the second liquid concentrate composition will increase, due to the fact that sufficient foaming capacity may not be achieved. On the other hand, if the ratio of the higher alcohol content is very low, the viscosity of the second liquid concentrate composition will decrease, which can lead to dripping at the application site. Also, the second liquid concentrate composition may lack emulsification stability. In addition, for human body applications, the composition may not feel favorable when applied.
    [0080] [0080] The second liquid concentrate composition may contain other optional components as required in addition to the essential components of hydrogen carbonate, water, surfactant and higher alcohol. The optional components can be any of these data as examples of the optional components that constitute the first liquid concentrate composition, for example, among which esters are preferred.
    [0081] [0081] The ratio of esters content may be different depending on the purpose of use of the foaming aerosol product or the types and content ratios of other constituent components of the second liquid concentrate composition. However, the content ratio may be preferably 0.1 to 2.0% by weight, more preferably 0.2 to 1.0% by weight, particularly preferably 0.3 to 0.7% by weight, per 100% by weight of the second liquid concentrate composition.
    [0082] [0082] If the ratio of esters content is too high, sufficient foaming capacity may not be achieved and for human body applications in particular, a problem may arise as the ester adds a sticky sensation due to the fact that the product may not give a favorable feeling when applied. On the other hand, if the ratio of esters content is very low, the expected effects of the esters on the foaming aerosol product may not be fully explored.
    [0083] [0083] The second liquid concentrate composition composed of the essential and optional components as described above may preferably have a viscosity of 10 to 15,000 mPa • s at a temperature of 20 ° C, more preferably 10 • to 10,000 mPa • s , particularly preferably 1,000 to 5,000 mPa • s.
    [0084] [0084] If the viscosity of the second liquid concentrate composition is too high, the second liquid concentrate composition may not be sufficiently mixed with the first liquid concentrate composition, due to the fact that sufficient foaming capacity may not be achieved. On the other hand, if the viscosity of the second liquid concentrate composition is very low, the product may tend to drip at the application site.
    [0085] [0085] The viscosity of the second liquid concentrate composition may preferably be within a range of ± 20%, more preferably ± 15%, of an average of the viscosities of the first liquid concentrate composition and the second liquid concentrate composition ( average viscosity value), taking into account the relationship with the viscosity of the first liquid concentrate composition.
    [0086] [0086] If the viscosity of the second liquid concentrate composition falls outside the range of the average viscosity value noted above, that is, if it is higher than + 20% or lower than - 20% of the average viscosity value, there will be a big difference in the amount of the first liquid concentrate composition discharged from the first liquid concentrate filling space and that of the second liquid concentrate composition discharged from the second liquid concentrate filling space. As a result, the foam produced by the first and second mixtures of liquid concentrate mixtures may not exhibit sufficient foamability. (Propellant)
    [0087] [0087] A compressed gas is used as the propellant.
    [0088] [0088] Examples of compressed gases include nitrous oxide gas, nitrogen gas, carbon dioxide and a mixture of these.
    [0089] [0089] Nitrogen gas is preferred since the propellant of the first liquid concentrate composition.
    [0090] [0090] The propellant can preferably be sealed in the double-structure container at a pressure of 0.3 to 0.8 MPa at 25 ° C.
    [0091] [0091] If the filling pressure of the propellant (internal pressure of the product) is too high or too low, the product may not be sprayed in a favorable way in any case. (Double structure container)
    [0092] [0092] The double-structure container that constitutes the foaming aerosol product of the present invention includes a propellant filling space to be filled with a propellant, a first liquid concentrate filling space to be filled with a first composition liquid concentrate and a second liquid concentrate filling space to be filled with a second liquid concentrate composition. The double-structure container additionally includes a discharge mechanism for discharging the first and second liquid concentrate compositions simultaneously from the respective first and second liquid concentrate filling spaces.
    [0093] [0093] The following four containers to be described below and shown in FIG. 1 to FIG. 6 are specific examples of the double-structure container according to the present invention.
    [0094] [0094] FIG. 1 is a diagram illustrating an example of the structure of the double-structure container used for the foaming aerosol product of the present invention and FIG. 2 is a cross-sectional view illustrating a section A-A 'of FIG. 1.
    [0095] [0095] This double-structure container 10 includes a pressure-resistant container 11 made of metal and equipped with an aerosol valve 12. Inside the pressure-resistant container 11, a first inner bag 15A is provided which is made of laminated aluminum film. , for example, and defines the first liquid concentrate filling space to be filled with the first liquid concentrate composition and a second inner bag 15B that is made of laminated aluminum film, for example, and defines the second concentrate filling space liquid to be filled with the second liquid concentrate composition. A gap surrounded by this pressure-resistant container 11, this first inner bag 15A and this second inner bag 15B forms a propellant filling space to be filled with a propellant. The aerosol valve 12 is provided with a first pipe 14A and a second pipe 14B which have an internal pipe passage and are movable up and down inside a first housing 13A and a second housing 13B, respectively. A shared actuator 21 is provided for the upper ends of these first and second pipes 14A and 14B.
    [0096] [0096] In the illustrated example, the reference symbol 16A denotes a submerged pipe that communicates with the pipe passage in the first pipe 14A at the lower end of the first housing 13A that forms the aerosol valve 12. The first submerged pipe 16A extends towards the bottom of the pressure-resistant container 11 inside the first inner bag 15A. The reference symbol 16B denotes a submerged pipe that communicates with the pipe passage in the second pipe 14B at the lower end of the second housing 13B that forms the aerosol valve 12. The second submerged pipe 16B extends towards the bottom of the resistant container pressure 11 inside the second inner bag 15B.
    [0097] [0097] In FIG. 1, the constituent elements disposed within the pressure-resistant container 11 and the actuator 21 are desired with the dotted lines.
    [0098] [0098] The shared actuator 21 is provided with a first passage for actuator 22A that communicates with the passage for pipe of the first pipe 14A, a second passage for actuator 22B that communicates with the passage for pipe of the second pipe 14B and a space mixture 23 which communicates with the first and second passages for actuator 22A and 22B at one end and forms a discharge port 24 at the other end.
    [0099] [0099] The shared actuator 21 provided in this way with the first barrel 14A associated with the first inner bag 15A that forms the first liquid concentrate filling space and the second tube 14B associated with the second inner bag 15B that forms the second filling space of liquid concentrate constitute the discharge mechanism for discharging the first liquid concentrate composition filled in the first inner pouch 15A and the second liquid concentrate composition filled in the second inner pouch 15B simultaneously with the first inner pouch 15A and the second inner pouch 15B, respectively.
    [0100] [00100] In that double-structure container 10 configured as described above, the first liquid concentrate composition is filled into the first inner pouch 15A while the second liquid concentrate composition is filled into the second inner pouch 15B in the pressure resistant container 11. Furthermore, the propellant filling space formed by the gap surrounded by the pressure-resistant container 11, the first inner bag 15A and the second inner bag 15B are filled with a propellant, so that the interior of the pressure-resistant container 11 is always pressurized by the propellant . When the actuator 21 is operated (pressed), the propellant pressure squeezes the first inner bag 15A and the second inner bag 15B, whereby the first and second liquid concentrate compositions are simultaneously discharged from the first and second inner bags 15A and 15B and then from the discharge port 24 of the actuator 21 as a mixture.
    [0101] [00101] More specifically, in the double structure container 10 that holds the first and second liquid concentrate compositions and the propellant filled in it, when the actuator 21 is not operated, or not pressed, the first pipe 14A and the second pipe 143 are pushed upwards to terminate their pipe passages from the inside of the pressure-resistant container 11. When actuator 21 is operated (pressed), the first pipe 14A and the second pipe 143 are pressed down, whereby their pipe passages they are simultaneously communicated with the interior of the pressure resistant container 11. The first liquid concentrate composition inside the first inner bag 15A and the second liquid concentrate composition inside the second inner bag 15B in the pressure resistant container 11 flows through the passages. of fluid formed by the first immersed tube 16A and the second immersed tube 16B, respectively. The first and second liquid concentrate compositions, thus flowing out simultaneously, travel through the pipe passages in the first pipe 14A and the second pipe 14B of the aerosol valve 12 and the first and second passages for actuator 22A and 22B in the actuator 21 and arrive in the mixing space 23, where they are mixed to form a foam, which is then discharged from the discharge port 24 as a sparkling discharge.
    [0102] [00102] FIG. 3 is a diagram illustrating another example of the structure of the double-structure container used for the foaming aerosol product of the present invention. More specifically, the drawing is a cross-sectional view to describe the structure of the actuator for the double-structure container.
    [0103] [00103] This double-structure container is configured similarly to the double-structure container 10 shown in FIG. 1 and FIG. 2 except that it has an actuator 31 instead of the actuator 21 of the double frame container 10 of FIG. 1 and FIG. 2. Specifically, actuator 31 has two discharge ports (more specifically, a first discharge port 34A and a second discharge port 34B) and is configured to separately discharge the first and second liquid concentrate compositions from the respective discharge port. .
    [0104] [00104] That is, the double-structure container associated with FIG. 3 includes the actuator 31 and a pressure-resistant container that is configured similarly to the pressure-resistant container 11 that constitutes the double-structure container 10 shown in FIG. 1 and FIG. two.
    [0105] [00105] Actuator 31 is configured to include a first passage for actuator 32A that is in communication with the passage for pipe of a first pipe at one end and forms a first discharge port 34A at the other end and a second passage for actuator 32B which communicates with the passage of a second pipe at one end and forms a second discharge port 34B at the other end.
    [0106] [00106] The actuator 31 is shared by both the first and second pipes and supplied to the upper ends of the first and second pipes, similarly to the actuator 21 of the double frame container 10 shown in FIG. 1 and FIG. two.
    [0107] [00107] In that double structure container configured as described above, when it is filled with the first and second liquid concentrate compositions and a propellant and when the actuator 31 is operated (pressed), the first and second concentrate compositions liquid are discharged simultaneously from the first and the second internal pouch into the pressure-resistant container, respectively. The first liquid concentrate composition is ejected from the first discharge port 34A through the pipe passage in the first aerosol valve pipe and the first actuator passage 32A from the actuator 31, while the second liquid concentrate composition is ejected from the second discharge port. discharge 34B through the pipe passage in the second pipe of the aerosol valve and the second passage for actuator 32B of the actuator 31. The first and second liquid concentrate compositions discharged from the first and second discharge ports 34A and 34B, respectively, are then mixed, for example, with a finger, to form a foam, at the point where they are applied.
    [0108] [00108] FIG. 4 is a diagram illustrating yet another example of the structure of the double-structure container used for the foaming aerosol product of the present invention and FIG. 5 is a cross-sectional view illustrating a section A-A 'of FIG. 4.
    [0109] [00109] This double structure container 40 is configured to have a first pressure resistant container 41A made of metal and provided with a first aerosol valve 42A and a second pressure resistant container 41B made of metal and provided with a second aerosol valve 42B, these containers are joined with a container retainer 48.
    [0110] [00110] Inside the first pressure-resistant container 41A that constitutes the double-structure container 40, a first inner bag 45A is formed which is made of polyethylene sheet, for example, and defines a first liquid concentrate filling space to be filled with a first liquid concentrate composition and a propellant filling space to be filled with a propellant, which is formed by a gap surrounded by the first pressure resistant container 41A and the first internal bag 45A. The first aerosol valve 42A is provided with a first pipe 44A which has an internal pipe passage and is movable up and down inside a first housing 43A.
    [0111] [00111] The second pressure-resistant container 41B that constitutes the double-structure container 40 is configured Similar to the first pressure-resistant container 41A. More specifically, inside the second pressure-resistant container 41B, a second inner pocket 45B is formed which is made of polyethylene sheet, for example, and defines a second liquid concentrate filling space to be filled with a second liquid concentrate composition. and a propellant filling space to be filled with a propellant, which is formed by a gap surrounded by the second pressure-resistant container 41B and the second internal pocket 45B. The second aerosol valve 42B is provided with a second pipe 44B that has an internal pipe passage and is movable up and down inside a second housing 43B.
    [0112] [00112] In the illustrated example, the container retainer 48 has an external appearance in the shape of an oval column. On one side (bottom side in FIG. 4) of the container retainer 48, cavities are formed which have diameters corresponding to those of the first and second housings 43A and 43B that form the first and second aerosol dispensing valves 42A and 42B, respectively . The first housing 43A and the second housing 43B are fitted in the respective cavities so that the first and second pressure-resistant containers 41A and 41B are retained. The first pipe 44A and the second pipe 44B protrude from the first and the second pressure-resistant containers 41A and 41B fixed to the container retainer 48 through holes formed in the center of the cavities of the container retainer 48 with diameters that correspond to those of the first and of the second pipes 44A and 44B.
    [0113] [00113] In FIG. 4, the constituent elements disposed within the first pressure-resistant container 41A, the second pressure-resistant container 41B and the actuator 51 are desired with dashed lines.
    [0114] [00114] A shared actuator 51 is provided for the upper ends of the first pipe 44A of the first aerosol valve 42A and the second pipe 44B of the second aerosol valve 42B.
    [0115] [00115] The shared actuator 51 is provided with a first passage for actuator 52A that is in communication with the passage for pipe of the first pipe 44A, a second passage for actuator 52B that is in communication with the passage for pipe of the second pipe 44B and a mixing space 53 which is in communication with these first and second passages for actuator 52A and 52B at one end and forms a discharge port 54 at the other end.
    [0116] [00116] The shared actuator supplied in this way with the first pipe 44A and the second pipe 44B constitutes the discharge mechanism for discharging the first liquid concentrate composition filled in the first inner pouch 45A and the second liquid concentrate composition filled in the second inner pouch 45B simultaneously from the first inner bag 45A and the second inner bag 45B, respectively.
    [0117] [00117] In this double-structure container 40 configured as described above, the first liquid concentrate composition is filled in the first internal bag 45A in the first pressure-resistant container 41A and the propellant filling space formed by the gap surrounded by the pressure-resistant container 41A and the first pocket 45A is filled with a propellant, so that the inside of the first pressure-resistant container 41A is always pressurized by the propellant. In the second pressure-resistant container 4113, the second liquid concentrate composition is filled in the second inner bag 45B and the propellant filling space formed by the gap surrounded by the second pressure-resistant container 41B and the second bag 45B is filled with a propellant, so that the interior of the second pressure-resistant container 41B is always pressurized by the propellant. When actuator 51 is operated (pressed), the propellant pressure squeezes the first inner bag 45A and the second inner bag 45B, whereby the first and second liquid concentrate compositions are discharged simultaneously from the first and second inner bags 45A and 45B and then discharge port 54 of actuator 51 as a mixture.
    [0118] [00118] More specifically, in the double structure container 40 that holds the first and second liquid concentrate compositions and the propellant filled in it, when the actuator 51 is not operated, or not pressed, the first pipe 44A and the second pipe 44B are pushed upward to terminate their pipe passages from the inside of the first pressure-resistant container 41A and the second pressure-resistant container 41B. When actuator 51 is operated (pressed), the first pipe 44A and the second pipe 44B are pressed downwards, whereby their pipe passages are simultaneously communicated with the interior of the first pressure-resistant container 41A and the second pressure-resistant container 41B. As a result, the first liquid concentrate composition inside the first inner pouch 45A in the first pressure resistant container 41A and the second liquid concentrate composition inside the second inner pouch 45B in the second pressure resistant container 41B flow out simultaneously. The first and second liquid concentrate compositions, which thus flow outward simultaneously travel through the pipe passages in the first pipe 44A and in the second pipe 44B and in the first and second passages for actuator 52A and 52B in actuator 51 and they arrive at the mixing space 53, where they are mixed to form a foam, which is then discharged from the discharge port 54 as a foamy discharge.
    [0119] [00119] FIG. 6 is a diagram illustrating a further example of the structure of the double-structure container used for the foaming aerosol product of the present invention. More specifically, it is a cross-sectional view to explain the structure of the actuator for the double-structure container.
    [0120] [00120] This double-structure container is configured similarly to the double-structure container 40 shown in FIG. 4 and FIG. 5 except that it has an actuator 61 instead of actuator 51 of the double frame container 40 of FIG. 4 and FIG. 5. Specifically, actuator 61 has two discharge ports (more specifically, a first discharge port 64A and a second discharge port 64B) and is configured to separately discharge the first and second concentrated liquid compositions from the respective discharge ports. discharge.
    [0121] [00121] Namely, the double structure container associated with FIG. 6 includes actuator 61, and a container body that is configured similarly to the container body that forms the double-structure container 40 shown in FIG. 5 and FIG. 6 and includes the first pressure resistant container 41A, the second pressure resistant container 41B and the container retainer 48.
    [0122] [00122] Actuator 61 is configured to include a first actuator passage 62A that is in communication with the pipe passage of a first pipe at one end and forms a first discharge port 64A at the other end, and a second actuator passage 62B which is in communication with the passage of a second pipe at one end and forms a second discharge port 64B at the other end.
    [0123] [00123] Actuator 61 is shared by both the first and second pipe and is provided to the upper ends of the first and second pipes, similarly to actuator 51 of the double-structure container 40 shown in FIG. 4 and FIG. 5.
    [0124] [00124] In this double structure container configured as described above, when it is filled with first and second concentrated liquid compositions and a propellant, and when the actuator 61 is operated (pressed), the first and second concentrated liquid compositions are discharged simultaneously from the first and second inner bags inside the first and second pressure-resistant containers, respectively. The first liquid concentrated composition is ejected from the first discharge port 64A through the pipe passage in the first pipe of the first aerosol valve and the first actuator passage 62A from the actuator 61. The second concentrated liquid composition is ejected from the second discharge port 64B through the pipe passage in the second pipe of the second aerosol valve and the second actuator passage 62B of the actuator 61. The first and second concentrated compositions of liquid discharged from the first and second discharge ports 64A and 64B respectively are then mixed, for example, with a finger, to form foam, at the mark on which they are applied.
    [0125] [00125] With the double frame container having the configuration described above, the first liquid concentrated composition that fills the first liquid concentrate filling space and the second liquid concentrated composition that fills the second liquid concentrate filling space can be discharged simultaneously by means of the discharge mechanism and, in addition, the quantity of the first liquid concentrated composition discharged from the first liquid concentrate filling space and the quantity of the second liquid concentrated composition discharged from the second liquid concentrate filling space can be adjusted to achieve an appropriate mass ratio according to the relationship between the organic acid concentration of the first concentrated liquid composition and the hydrogen carbonate concentration of the second concentrated liquid composition or other factors.
    [0126] [00126] In the foaming aerosol product of the present invention, the mixing ratio of the first concentrated liquid composition discharged from the first liquid concentrate filling space and the second concentrated liquid composition discharged from the second liquid space. filling of liquid concentrate (mass of the first concentrated liquid composition: mass of the second concentrated liquid composition) can be preferably 0.8: 1.2 to 1.2: 0.8.
    [0127] [00127] That is, each of the quantity of the first concentrated liquid composition discharged from the first liquid concentrate filling space and the quantity of the second liquid concentrated composition discharged from the second liquid concentrate filling space can preferably be within a range of ± 20% of an average of the discharge amounts of the first concentrated liquid composition and the second concentrated liquid composition.
    [0128] [00128] The mixing ratio (mass of the first concentrated liquid composition: mass of the second concentrated liquid composition) can be made to be within the range noted above, for example, by preparing the first concentrated liquid composition to have a viscosity of 10 to 15,000 mPa • sa at a temperature of 20 ° C, and the second concentrated liquid composition to have a viscosity of 10 to 15,000 mPa • sa at a temperature of 20 ° C, and additionally preparing the two concentrated liquid compositions to have a viscosity at a temperature of 20 ° C which is within the range of ± 20% of a median viscosity value.
    [0129] [00129] If the mixing ratio (mass of the first concentrated liquid composition: mass of the second concentrated liquid composition) is in the range noted above, there will be a big difference in the amount of the first concentrated liquid composition discharged from the first space liquid concentrate filling and that of the second concentrated liquid composition discharged from the second liquid concentrate filling space. As a result, the foam produced by the first and the second mixed concentrated liquid compositions may not exhibit sufficient foamability.
    [0130] [00130] The foaming aerosol product of the present invention described above is produced by filling the first and second liquid concentrate filling spaces in the double-structure container with a first concentrated liquid composition and a second concentrated liquid composition, respectively , and filling the thruster fill space with a thruster.
    [0131] [00131] The foaming aerosol product of the present invention includes a double structure container that has a discharge mechanism for simultaneously discharging contents that fill two liquid concentrate filling spaces. A first concentrated liquid composition containing an organic acid in a specific ratio fills one of the two liquid concentrate filling spaces, while a second concentrated liquid composition containing a hydrogen carbonate in a specific ratio fills the other liquid filling space. liquid concentrate. Thus, the first concentrated liquid composition and the second concentrated liquid composition can be discharged from the respective two liquid concentrate filling spaces of the double-structure container in an appropriate amount at the same time. Therefore, the first concentrated liquid composition and the second concentrated liquid composition can always be mixed in a constant amount ratio, so that one concentrated liquid composition is never discharged excessively relative to the discharge amount of the other concentrated liquid composition. Thus, a simple operation of the discharge mechanism, more specifically, for example, pressing down on an actuator once (a squeeze), expels the first concentrated liquid composition and the second concentrated liquid composition, thus a favorable foam is always formed readily by the carbon dioxide gas that is generated by the reaction between organic acid and hydrogen carbonate.
    [0132] [00132] As an incombustible compressed gas is used as the propellant of the first concentrated liquid composition and the second concentrated liquid composition, the product can be used in a highly safe manner regardless of the environment in which it is used, and there is no risk explosion hazards when disposing of the aerosol container. Furthermore, since none of the first concentrated liquid composition and the second concentrated liquid composition is exposed to air outside the container when used, they can be kept stable over prolonged storage.
    [0133] Thus, the foaming aerosol product of the present invention can be used in a highly safe manner regardless of the environment in which it is used, has excellent storage stability, and has the ability to promptly dispense a favorable foam.
    [0134] [00134] With the foaming aerosol product of the present invention, if the discharge mechanism that constitutes the double-structure container includes a mixing space for mixing the first concentrated liquid composition discharged from the first filling space of liquid concentrate and the second concentrated liquid composition discharged from the second liquid concentrate filling space, more specifically, if the actuator is formed with a mixing space as shown in FIG. 2 and FIG. 5, for example, the product can deliver a foamy discharge. Therefore, the same can be applied in a given place easily since there is no need to mix the first concentrated liquid composition and the second concentrated liquid composition.
    [0135] [00135] If the foaming aerosol product of the present invention has such a double structure container as shown in FIG. 3 and FIG. 6, for example, which includes a discharge mechanism that has an actuator that discharges the first concentrated liquid composition discharged from the first liquid concentrate filling space and the second concentrated liquid composition discharged from the second liquid filling space. liquid concentrate from separate discharge ports, it is necessary to mix the first and second concentrated liquid compositions at the application site to form a foam. On the other hand, it can be enjoyable to watch as the foam develops or changes its shape.
    [0136] [00136] The foaming aerosol product of the present invention can be used, for example, for the human body and for a variety of other purposes. As the foam is formed by carbon dioxide gas, which is expected to induce an increase in blood flow, the aerosol product can preferably be used particularly for the human body.
    [0137] [00137] More specifically, the aerosol product can be used to dispense hair styling agent, hair wax, hair treatment, hair coloring agent, shampoo, conditioner, hair growth agent, massage agent, facial soap, cleanser , shaving agent, makeup base, skin protector, moisturizer, whitening agent, sun protection agent, hair remover, hand soap, body soap and so on. Examples
    [0138] [00138] Although the examples of the present invention are hereinafter described, the present invention should not be limited by those examples. Examples 1 to 12 and Comparative Example 1 (Preparation of the first concentrated liquid composition)
    [0139] [00139] First, a cream base "Emacol HD2146" (manufactured by San-Ei Kagaku Co., Ltd.) was heated to a temperature range of 80 to 85 ° C to obtain an oil solution (oil phase). Meanwhile, purified water, polyoxyethylene lauryl ether "BL-9EX" (manufactured by Nikko Chemicals Co., Ltd.) as a surfactant, and other materials from the first concentrated liquid composition, as required, were mixed and heated to a range of 80 to 85 ° C to obtain an aqueous solution (water phase).
    [0140] [00140] Next, an emulsion was prepared by slowly adding the aqueous solution thus obtained (water phase) to the oil solution thus obtained (oil phase) which was being stirred at a stirring speed (rotation) of 600 rpm with the use of a propellant stirrer. After the emulsion obtained in this way is cooled to 30 ° C or below, a first concentrated liquid composition that has the composition shown in Table 1 and Table 2 was prepared by adding an organic acid and stirring at a stirring speed of 600 rpm .
    [0141] [00141] It is observed that the cream base "Emacol HD2146" (manufactured by San-Ei Kagaku Co., Ltd.) contains cetyl alcohol (60% by mass), isopropyl palmitate (8% by mass), cetyl sulfate sodium (7% by mass), beeswax (5% by mass), ceteth-6 (5% by mass), ceteth-30 (5% by mass), ceteth-40 (5% by mass) and water ( 5% by mass). (Preparation of the second concentrated liquid composition)
    [0142] [00142] First, a cream base "Emacol HD2146" (manufactured by San-Ei Kagaku Co., Ltd.) was heated to a temperature range of 80 to 85 ° C to obtain an oil solution (oil phase). Meanwhile, purified water, polyoxyethylene lauryl ether "BL - 9EX" (manufactured by Nikko Chemicals Co., Ltd.) as a surfactant, and other materials of the second concentrated liquid composition, as required, were mixed and heated to a strip from 80 to 85 ° C to obtain an aqueous solution (water phase).
    [0143] [00143] Next, an emulsion was prepared by slowly adding the aqueous solution obtained in this way (water phase) to the oil solution obtained in this way (oil phase) which was being stirred at a speed of rotation (rotation) of 600 rpm with the use of a propellant stirrer. After the emulsion thus obtained was cooled to 30 ° C or below, a second concentrated liquid composition having the composition shown in Table 1 and Table 2 was prepared by adding hydrogen carbonate and stirring at a stirring speed of 600 rpm. (Manufacture of aerosol product)
    [0144] [00144] The aerosol product was manufactured as follows: A double structure container having the configuration shown in FIG. 1 and FIG. 2 was prepared, and the first liquid concentrate filling space (first inner bag) of the double-structure container was filled with the first concentrated liquid composition, while the second liquid concentrate filling space (second inner bag) was filled with the second concentrated liquid composition. The propellant fill space was filled with nitrogen gas as a propellant to achieve an internal product pressure of 0.7 MPa at 25 ° C in the double-structure vessel. Comparative example 2
    [0145] [00145] An aerosol product was manufactured for comparative purposes using the same method as in Example 1, except that an emulsion obtained by preparing the first concentrated liquid composition according to Example 1 has filled the first liquid concentrate filling space ( first internal bag) of the double-structure container instead of the first concentrated liquid composition, and an emulsion obtained by preparing the second concentrated liquid composition according to Example 1 has filled the second liquid concentrate filling space (second internal bag ) instead of the second concentrated liquid composition in Example 1. Avaliation test
    [0146] [00146] Aerosol products manufactured in accordance with Examples 1 to 12 and Comparative Examples 1 and 2 were evaluated using the following method in terms of the foaming of the discharge. The results are shown in Table 1 and Table 2. (Foam discharge)
    [0147] [00147] 5 g of the content of each aerosol product was sprayed into a 50 ml glass beaker. After stirring the discharge into the beaker by slowly rotating a glass rod ten times, the volume of the discharge into the beaker was measured. The composition is rated as "A" as having very good foaming, if the volume is not less than 40 ml. The composition is rated "B" as having good foamability, if the volume of the composition is not less than 20 ml and less than 40 ml. The composition is rated as "C" having insufficient foamability, if the volume is less than 20 ml.
    [0148] [00148] In Table 1 and Table 2, "not less than 60 ml" in the cells of the row indicating the measurements of the "discharge foam" in the evaluation tests means that the foam has spilled on the top of the beaker.
    [0149] [00149] In the tables, the "first composition" indicates the first concentrated liquid composition, the "second composition" indicates the second concentrated liquid composition. "Citric acid" is one that is manufactured by Kozakai Pharmaceutical Co., Ltd., "lactic acid" is one that is manufactured by Kanto Chemical Co., Inc., "fumaric acid" is one that is manufactured by Nippon Shokubai Co. , Ltd., "sodium hydrogen carbonate" is one that is manufactured by Kozakai Pharmaceutical Co., Ltd., "polyoxyethylene lauryl ether" is "BL-9EX" (manufactured by Nikko Chemicals Co., Ltd.), "polyoxyethylene alkyl ether (1) "is" ceteth-6 "," polyoxyethylene alkyl ether (2) "is" ceteth-30 "," polyoxyethylene alkyl ether (3) "is" ceteth-40 "," glycerin "is one that is manufactured by Kao Corporation and "1,3-butylene glycol" is one that is manufactured by Kyowa Hakko Chemical Co., Ltd.
    [0150] [00150] As seen from the results shown in Table 1, it was confirmed that the aerosol products of Examples 1 to 12 could readily form a favorable foam.
    [0151] [00151] The aerosol products of Examples 1 to 12 had a first concentrated liquid composition and a second concentrated liquid composition with a viscosity within the range of 10 to 15,000 mPa • s at a temperature of 20 ° C, with viscosities also being within the range of ± 20% of the average viscosities of the first and second concentrated liquid compositions. Thus, it was also confirmed that the mixing ratio of the first and second concentrated liquid compositions (mass of the first concentrated liquid composition: mass of the second concentrated liquid composition) of the discharge was within the range of 0.8: 1.2 to 1.2: 0.8, and that the product exhibited a high foaming ability (discharge foaming).
    [0152] [00152] On the other hand, in the aerosol product of Comparative Example 1 the content ratio of organic acid in the first concentrated liquid composition and that of hydrogen carbonate in the second concentrated liquid composition were both very low. Thus, the aerosol product could not form a good foam because of a low foaming ability (foaming of the discharge) due to an insufficient amount of carbon dioxide gas generated.
    [0153] [00153] The aerosol product of Comparative Example 2 did not form a foam because the two types of concentrated liquid compositions did not contain an organic acid and a hydrogen carbonate, respectively, and the carbon dioxide gas was not generated when the compositions concentrated liquid were mixed.
    [0154] [00154] It was also confirmed that the aerosol products of Examples 1 to 12 could still form a favorable foam even after they were stored for a long period of one month under an environment with a temperature of 45 ° C. NUMERICAL REFERENCE LISTING 10 Double structure container 11 Pressure resistant container 12 Aerosol valve 13A First accommodation 13B Second accommodation 14A First pipe 14B Second pipe 15A First internal bag 15B Second inner bag 16A First immersed tube 16B Second immersed tube 21 Actuator 22A First actuator pass 22B Second actuator pass 23 Mixing space 24 Discharge port 31 Actuator 32A First actuator pass 32B Second actuator pass 34A First discharge port 34B Second discharge port 40 Double structure container 41A First pressure-resistant container 41B Second pressure-resistant container 42A First aerosol valve 42B Second aerosol valve 43A First accommodation 43B Second accommodation 44A First pipe 44B Second pipe 45A First internal bag 45B Second inner bag 48 Container retainer 51 Actuator 52A First actuator pass 52B Second actuator pass 53 Mixing space 54 Discharge port 61 Actuator 62A First actuator pass 62B Second actuator pass 64A First discharge port 64B Second discharge port
    权利要求:
    Claims (5)
    [0001]
    Foaming aerosol product characterized by the fact that it comprises a double structure container that has a propellant filling space, two independent liquid concentrate filling spaces and a discharge mechanism to simultaneously discharge the contents that fill the two spaces filling liquid concentrate, where: the propellant filling space in the double-structure container is filled with a propellant composed of a compressed gas; a first concentrated liquid composition containing an organic acid, water, a surfactant, and an upper alcohol fills a first liquid concentrate fill space in the double-structure container, where the upper alcohol is selected from the group consisting of lauryl alcohol , myristyl alcohol, cetyl alcohol, ceto-stearyl alcohol, arachyl alcohol, beenyl alcohol, oleyl alcohol, jojoba alcohol, stearyl alcohol, cholesterol, phytosterol, lanolin alcohol, octyldodecanol, hexildecanol and isostearyl alcohol, and mixtures thereof; and the organic acid being contained in a content ratio of 0.5 to 15.0% by mass per 100% in the first concentrated liquid composition; a second concentrated liquid composition containing a hydrogen carbonate, water, a surfactant, and an upper alcohol fills a second liquid concentrate fill space in the double-structure container, in which the upper alcohol is selected from the group consisting of alcohol lauryl, myristyl alcohol, cetyl alcohol, ceto-stearyl alcohol, aryl alcohol, beenyl alcohol, oleyl alcohol, jojoba alcohol, stearyl alcohol, cholesterol, phytosterol, lanolin alcohol, octyldodecanol, hexildecanol and isostearyl alcohol, and mixtures thereof; and the hydrogen carbonate being contained in a content ratio of 0.5 to 15.0% by mass per 100% in the second concentrated liquid composition; and the first concentrated liquid composition discharged from the first liquid concentrate filling space and the second concentrated liquid composition discharged from the second liquid concentrate filling space are mixed to form a foam.
    [0002]
    Foaming aerosol product according to claim 1, characterized by the fact that a mixing ratio of the first concentrated liquid composition discharged from the first liquid concentrate filling space and the second concentrated liquid composition discharged at from the second liquid concentrate filling space (mass of the first concentrated liquid composition: mass of the second concentrated liquid composition) is 0.8: 1.2 to 1.2: 0.8.
    [0003]
    Foaming aerosol product according to claim 1 or 2, characterized in that the first concentrated liquid composition has a viscosity of 10 to 15,000 mPas at a temperature of 20 ° C, the second concentrated liquid composition has a viscosity of 10 to 15,000 mPa • s at a temperature of 20 ° C, and each of the viscosity of the first concentrated liquid composition and the viscosity of the second concentrated liquid composition is within a range of ± 20% of an average the viscosities of the first concentrated liquid composition and the second concentrated liquid composition.
    [0004]
    Foaming aerosol product according to any one of claims 1 to 3, characterized in that the discharge mechanism includes a mixing space for mixing the first concentrated liquid composition discharged from the first filling space. liquid concentrate and the second concentrated liquid composition discharged from the second liquid concentrate filling space.
    [0005]
    Foaming aerosol product according to any one of claims 1 to 4, characterized in that the foaming aerosol product is intended to be applied to the human body.
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    同族专利:
    公开号 | 公开日
    US20140246515A1|2014-09-04|
    JPWO2014027410A1|2016-07-25|
    KR101608606B1|2016-04-01|
    IN2014CN02674A|2015-07-03|
    US9776787B2|2017-10-03|
    WO2014027410A1|2014-02-20|
    EP2886625B1|2018-06-13|
    EP2886625A4|2016-01-20|
    BR112014010853A2|2017-06-13|
    KR20140082776A|2014-07-02|
    JP5390729B1|2014-01-15|
    EP2886625A1|2015-06-24|
    CN103930513B|2016-06-29|
    CN103930513A|2014-07-16|
    BR112014010853A8|2017-06-20|
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    法律状态:
    2018-03-27| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|
    2019-08-06| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|
    2020-11-10| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|
    2021-01-12| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 16/08/2012, OBSERVADAS AS CONDICOES LEGAIS. |
    优先权:
    申请号 | 申请日 | 专利标题
    PCT/JP2012/070787|WO2014027410A1|2012-08-16|2012-08-16|Foam-forming aerosol product|
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