PROCESS FOR THE THERMAL PREPARATION OF AN AUXILIARY MATERIAL AND SMALL LAQUADING UNIT TO WORK

专利摘要:
PROCESS FOR THERMAL PREPARATION OF AN AUXILIARY MATERIAL AND PREPARATION UNIT. To create a process for the thermal preparation of an auxiliary material, which can be introduced into a stream of crude gas for cleaning the stream of crude gas charged with an organic pollutant and which, together with the organic pollutant, forms a system stable compound of pollutant and auxiliary material, a process that can be carried out in a simple and resource saving manner, it is proposed that the process includes the following steps: conducting the system formed by pollutant and auxiliary material and a carrier gas stream heated in normal conditions for a thermal preparation device; chemical conversion of at least part of the organic pollutant to generate a prepared auxiliary material; separating the prepared auxiliary material from the auxiliary material loaded with an organic pollutant, by means of transport by means of gas flow and removal of the prepared auxiliary material from the thermal preparation device.
公开号:BR112014010239B1
申请号:R112014010239-2
申请日:2012-10-31
公开日:2020-11-24
发明作者:Sebastian Holler；Cord Kirschke
申请人:Dlirr Systems Ag；
IPC主号:

专利说明:

[001] The present invention relates to a process for the thermal preparation of an auxiliary material, which can be introduced into a stream of crude gas for cleaning the stream of crude gas charged with an organic pollutant and which, together with the organic pollutant, it forms a stable system composed of pollutant and auxiliary material.
[002] Auxiliary material loaded with pollutant can be prepared, for example, in a wet chemical process.
[003] The present invention aims to provide a process for the thermal preparation of an auxiliary material, which can be carried out in a simple and resource-saving manner.
[004] This objective is achieved, according to the invention, through a process for the thermal preparation of an auxiliary material, in which the auxiliary material can be introduced into a stream of crude gas for cleaning the stream of charged crude gas with an organic pollutant, and the auxiliary material, together with the organic pollutant, forms a stable system composed of pollutant and auxiliary material. According to the invention, the process includes:
[005] - conduction of the system formed by pollutant and auxiliary material and a carrier gas stream heated in relation to normal conditions for a thermal preparation device;
[006] - chemical conversion of at least part of the organic pollutant to generate a prepared auxiliary material;
[007] - separation of the auxiliary material prepared from the auxiliary material loaded with an organic pollutant, through transport by means of gas flow;
[008] - removal of prepared auxiliary material from the thermal preparation device.
[009] In an embodiment of the invention it is envisaged that as an auxiliary material a filtering auxiliary material should be chosen, which is used for cleaning a stream of crude gas charged as a pollutant in the form of lacquer overspray, the material being filter aid with lacquer overspray forms a stable system, under normal conditions, formed by filter aid material loaded with lacquer overspray, which can be sedimented in a filtering device.
[0010] It may be conducive for the preparation device to contain or cover a basic material with a turbulent layer. Preferably, the basic material of turbulent layer has a chemical composition that corresponds to the chemical composition of a material used as auxiliary material.
[0011] The auxiliary material loaded with pollutant can be easily prepared especially through turbulence in common with a basic material of turbulent layer.
[0012] The term "normal conditions" means, in particular, a temperature between approximately 20 ° C and approximately 30 ° C.
[0013] The carrier gas stream may include air, for example, or be made up of air. In addition, it may be envisaged that the carrier gas stream will include nitrogen or one or more other inert gases or be made up of nitrogen or one or more other inert gases. Especially to support the thermal preparation, the carrier gas stream may include a reactive gas or gaseous mixture and / or an inert gas or gaseous mixture or may consist of them.
[0014] As an auxiliary material, it can be used, in particular, any means that is able to absorb a fraction of the pollutant liquid.
[0015] The auxiliary material is preferably a material in the form of particles and / or in the form of powder.
[0016] As auxiliary materials can be considered, in particular, for example, lime, stone flour, especially stone lime flour, aluminum silicate, silicon oxide, powdered lacquer or similar.
[0017] Alternatively or completely to this, as an auxiliary material for the absorption and / or joining of the pollutant, particles with a hollow space structure and with a large internal surface in relation to its external dimensions can also be used, such as, for example , natural and / or synthetic zeolites or other hollow bodies, for example in the form of spheres, polymers, glass or aluminum silicate and / or natural or synthetically generated fibers.
[0018] Zeolites are, in particular, aluminum silicates, which have the general sum formula Mn + x / n [(Alθ2) x '(Siθ2) y] ■ z H2O (Mn +: metal cations; x / n: stoichiometric factor, which results from the charge of cations and that of aluminate anions (= "module")). For example, calcium, magnesium, calcium-magnesium, sodium and / or potassium zeolites can be used. Preferably, mixtures of two or more of these types of zeolites are used.
[0019] Alternatively or in addition to this, as an auxiliary material for the absorption and / or joining of the pollutant, particles that react chemically with the pollutant, such as, for example, particles chemically reactive with groups of amine, epoxy, carboxyl, hydroxyl or isocyanate, chemically reactive aluminum oxide particles further treated with octylsilane or monomers, oligomers or solid or liquid polymers, silanes, silanols or siloxanes.
[0020] The auxiliary material preferably consists of a series of particles of auxiliary material, which have, in particular, an average diameter in the range of approximately 10 pm to approximately 100 pm.
[0021] The auxiliary material is, in particular, a fluidizable material and in the form of particles, which, for example, is also called "Precoat" material in the form of filter aid material.
[0022] The filter aid material serves, in particular, to be deposited as a blocking layer on the surface of a filter element, to prevent that surface from sticking due to adherent particles of lacquer overspray. Through a periodic cleaning of the filter element, a system formed by pollutant and auxiliary material, especially lacquer overspray and filter aid material, is able to go from the filter element to a collecting container.
[0023] An auxiliary material loaded with pollutant can be, in particular, a mixture or a system formed of particles of pollutant and particles of auxiliary material. For example, the mixture can cover conglomerates and / or agglomerates of particles of pollutant and particles of material help.
[0024] Pollutant particles are, in particular, lacquer droplets.
[0025] Particles of auxiliary material are, in particular, granules of stone flour.
[0026] The auxiliary material that can be used to clean the raw gas stream charged with pollutant preferably has a particle size distribution that allows at least a large part of the particles of the auxiliary material to be pulled out of the stream of crude gas and / or be collected.
[0027] It can be predicted that a basic material with a turbulent layer corresponds chemically, essentially, to the auxiliary material, especially the auxiliary material to be prepared.
[0028] By a material that chemically corresponds, essentially, to the auxiliary material, it is understood, especially, a material that presents, essentially, the same chemical composition as the auxiliary material.Particularly, a material that chemically corresponds, essentially, to the auxiliary material is formed by the same substance as the auxiliary material.
[0029] Alternatively or in addition to this, it may be envisaged that the basic material of turbulent layer includes an auxiliary material that is chemically different from the auxiliary material to be prepared. In this case, it may be advantageous that the basic material of turbulent layer has a chemical composition that, eventually, after the execution of a process of grinding the basic material of turbulent layer, makes it possible to use the basic material of turbulent layer as auxiliary material.
[0030] In particular, it can be provided that the basic material of turbulent layer is compatible with the auxiliary material to be prepared, in such a way that a mixture of auxiliary material to be prepared and basic material of turbulent layer, eventually crushed, can be used. for cleaning a raw gas stream charged with pollutant.
[0031] As a basic material of turbulent layer, any material in the form of particles can preferably be used. This can be, in particular, an inorganic and / or fluidizable material. It can be present as a pure substance, such as lime stone flour or as a mixture of different substances, such as a mixture of lime stone flour and zeolites.
[0032] Through a turbulence of the auxiliary material loaded with pollutant and / or a basic material of turbulent layer, preferably a turbulent layer is generated, especially a turbulent layer that forms bubbles and / or circulating.
[0033] The preparation device is designed, particularly, as a turbulent layer oven.
[0034] A filtering device is preferably a regenerable filtering device.
[0035] A regenerable filtering device means a separation device for separating impurities from a gas stream conducted through a sterilization device, especially for the separation of pollutants, particularly lacquer overspray, from a stream of raw gas containing pollutant, filtering device in which impurities separated by sedimentation are removed, without the need to replace filter elements of the filtering device.
[0036] A regenerable filtering device is also particularly understood as a filtering device that has one or more dry filter elements and / or dry sedimentation devices, in which a cleaning of a gas stream occurs, essentially, without adding a liquid to the filter elements. Regardless of this, subsequent or previous cleaning steps can be envisaged, also by using (under normal conditions) solvents or liquid detergents.
[0037] In the case of a regenerable filtering device it can be provided that the filtering device includes at least one filter element, which, during the filtering operation, is provided with a blocking layer and / or a layer of protection, which includes auxiliary filtering material, especially lime stone flour.
[0038] In this way, during the filtration operation of the filtering device, it can be prevented that the filter element is affected by impurities from the gas stream conducted to the filtering device. By cleaning the blocking layer, respectively of the protective layer, of the filter element of the filtering device, it is possible to carry out a particularly simple regeneration of the filter element, which can be used again by applying a layer fresh blocking layer, respectively a fresh protective layer.
[0039] As a lacquer, powder lacquer or fluid lacquer is especially considered.
[0040] The concept of "fluid lacquer" - unlike the concept of "powder lacquer" - refers, in this case, to a lacquer with a fluidizable consistency, from fluid to pasty (for example, in the case of a PVC plastisol) . The concept of "fluid lacquer" covers, in particular, the concepts of "liquid lacquer" and "wet lacquer".
[0041] In the case of using fluid lacquer, the lacquer overspray from the lacquering device is, therefore, a lacquer overspray; if wet lacquer is used, it is a wet lacquer overspray.
[0042] It can be advantageous when the average particle size distribution of the basic turbulent layer material is greater than the average particle size distribution of the auxiliary material that can be used for cleaning the crude gas stream and / or is greater than the average particle size distribution of the auxiliary material loaded with pollutant, especially the system formed by pollutant and auxiliary material.
[0043] The average particle size distribution is that particle size that is not reached by 50% of the existing particles, while the remaining 50% of the existing particles are larger than this particle size.
[0044] In particular, it can be predicted that the average particle size distribution of the basic turbulent layer material will be at least approximately double, especially triple, for example ten times, the average particle size distribution of the auxiliary material that can be used to clean the crude gas stream and / or the average particle size distribution of the auxiliary material loaded with pollutant.
[0045] Furthermore, it can be predicted that the average particle size distribution of the basic turbulent layer material will comprise a maximum of approximately one hundred times, especially a maximum of approximately fifty times, especially a maximum of approximately thirty times, of the average of particle size distribution of the auxiliary material that can be used to clean the crude gas stream and / or the average particle size distribution of the auxiliary material loaded with pollutant.
[0046] In a configuration of the invention it is provided that the auxiliary material loaded with pollutant is heated in the preparation device, in such a way that the agglomerates of pollutant and auxiliary material are broken.
[0047] It may be advantageous that the auxiliary material loaded with pollutant is heated in the preparation device, in such a way that the pollutant is converted at least partially, while particles of the auxiliary material remain unchanged.
[0048] Particularly, in this case it can be predicted that particles of the auxiliary material will remain chemically unchanged.
[0049] In this case, a particle is understood to mean both a solid body particle, especially in the case of an auxiliary filter material, and also a drop, especially in the case of lacquer overspray.
[0050] Particularly in the case of agglomerates formed by pollutant and particles of auxiliary material, drying and / or chemical transformation of the pollutant is preferably carried out. In this way, the pollutant, especially the lacquer overspray particles, can be totally transformed, such as, for example, burnt, or lose at least one adhesion property that may have existed previously, such that the agglomerates formed by pollutant and material auxiliary decompose into particles of the auxiliary material, possibly with pollutant residues.
[0051] Especially if lime stone flour is used as an auxiliary material, it can be provided that the auxiliary material loaded with pollutant is heated in the preparation device to a maximum of approximately 550 ° C, for example to a maximum of approximately 500 ° C, to prevent an undesirable chemical transformation of lime stone flour, especially calcium carbonate.
[0052] Preferably, the preparation device is operated in such a way that a turbulent layer is formed that forms bubbles and / or that is circulating.
[0053] For example, a receptacle for the turbulent layer can be predicted to have a cross section that expands upward against the direction of the force of gravity, making it possible to form a so-called "Freeboard".
[0054] It may be conducive for the preparation device to be operated in such a way that a gradient is formed in the particle size distribution of the auxiliary material, especially a mixture composed of auxiliary material loaded with pollutant and / or basic layer material turbulent, with the average particle size distribution of the auxiliary material, particularly the mixture, increasing downwards in the direction of the gravity force.
[0055] Small particles of the auxiliary material, especially those without pollutant impurities, as well as, preferably, abrasion residues from the basic material of turbulent layer, preferably accumulate in a higher region - in relation to the direction of the gravity - of the auxiliary material, especially the mixture formed by the auxiliary material loaded with pollutant and the basic material of turbulent layer.
[0056] In a configuration of the invention, it is provided that the auxiliary material loaded with pollutant is supplied to the turbulent layer in a lower region - in relation to the direction of the force of gravity - of a turbulent layer generated through a turbulence in the thermal preparation device . In this way, it becomes possible to enable a particularly long residence time of the auxiliary material loaded with pollutant in the mixture formed by auxiliary material loaded with pollutant and / or by basic material of turbulent layer.
[0057] Particles of the system formed by pollutant and auxiliary material, particles of the prepared auxiliary material and / or particles of a basic material of turbulent layer, which, preferably, accumulate in a superior region - in relation to the direction of the gravity force - from a turbulent layer generated by the turbulence or which are removed from the turbulent layer, are preferably removed from the preparation device.
[0058] In that case, it can be specially provided that the particles are removed from the preparation device by means of a drain from the preparation device.
[0059] Preferably, the removed particles can be used as an auxiliary material for cleaning the raw gas stream.
[0060] It may be advantageous that, for the turbulence of auxiliary material, the carrier gas stream is conducted against the direction of the force of gravity, from bottom to top, through the auxiliary material.
[0061] It can be predicted that for the turbulence of the auxiliary material, the carrier gas stream is conducted, against the direction of the force of gravity, from the bottom upwards, through the auxiliary material, and the carrier gas stream is conducted at a sedimentation device and / or a combustion device before and / or after traversing the auxiliary material. In this way, an undesirable leakage of potentially polluting substances from the preparation device can be avoided.
[0062] A sedimentation device can be, in particular, a filtering device, such as, for example, a hot gas filter or a cyclone.
[0063] The carrier gas stream, preferably conducted through the auxiliary material for the turbulence of the auxiliary material, can be heated especially by means of a heating device. When traveling through the auxiliary material, this can heat up the auxiliary material.
[0064] It may be advantageous for the combustion device to include a further thermal combustion device. In this way, after the auxiliary material has been traversed, higher temperatures can be obtained than during the route through the auxiliary material, in order to be able to burn as completely as possible, especially organic vapors and other gaseous substances possibly harmful to health.
[0065] It may be advantageous that particles of the auxiliary material and / or particles of a basic material of turbulent layer, are removed, through the carrier gas stream, from a turbulent layer generated through a turbulence and are separated by sedimentation to be removed from the preparation device in a sedimentation device.
[0066] For this, the sedimentation device can be arranged separately spatially, for example laterally displaced, from a receptacle to the turbulent layer. In this way, it is reduced particularly effectively or completely prevents a material sedimented in the sedimentation device from returning to the receptacle of the preparation device, in which the turbulent layer is formed.
[0067] The particles of the auxiliary material loaded with pollutant and / or the particles of a basic material with turbulent layer, which are preferably removed from the preparation device, can be used especially for cleaning the raw gas stream. Thus, this auxiliary material is an auxiliary material already prepared.
[0068] Furthermore, it can be predicted that for the turbulence of the auxiliary material, the carrier gas stream is conducted against the direction of the force of gravity, from the bottom upwards, through the auxiliary material, being that, before and / or after After passing through the auxiliary material, the carrier gas stream is conducted to a heat exchanger and / or a drying device for drying the workpieces. In this way, the heat in the carrier gas stream can continue to be used efficiently.
[0069] The carrier gas stream is particularly useful for the generation and / or conservation of a turbulent layer.
[0070] It can be provided that the carrier gas stream removed is conducted, in particular, to a drying device for drying vehicle bodies. Alternatively or in addition to this, it can be provided that the heat contained in the carrier gas stream is transmitted, through a heat exchanger, to other gas streams or other fluid streams. For example, it can be provided that the heat contained in the removed carrier gas stream is transmitted, via a heat exchanger, to the supply air to a drying device for drying workpieces, especially vehicle bodies.
[0071] In addition, the carrier gas stream can come from a drying device for drying workpieces and / or being heated before being conveyed to the preparation device by means of a heat exchanger and a flow of fluid from the drying device.
[0072] In a configuration of the invention, a control device is provided for the control and / or regulation of the devices and units, as well as the components of the devices and units. In particular, a preparation unit can be controlled and / or regulated by means of at least one control device according to the process according to the invention.
[0073] The present invention also relates to a preparation unit for the thermal preparation of an auxiliary material, which can be introduced into a stream of crude gas for cleaning the stream of crude gas charged with an organic pollutant and which, together with the organic pollutant, forms a stable system formed by pollutant and auxiliary material.
[0074] In this regard, the invention sets itself the objective of providing a preparation unit, through which it is possible to prepare auxiliary material in a simple and resource-saving manner.
[0075] This objective is achieved in a preparation unit for the thermal preparation of an auxiliary material, due to the fact that the preparation unit covers:
[0076] - a thermal preparation device for the chemical conversion of at least part of the organic pollutant, for the generation of a prepared auxiliary material;
[0077] - a feeding device for conducting the system formed by pollutant and auxiliary material and a carrier gas stream, heated in relation to normal conditions, for the thermal preparation device;
[0078] - a separation device for separating the auxiliary material prepared from the auxiliary material loaded with an organic pollutant, through transport by means of gas flow;
[0079] - a removal device for removing prepared auxiliary material from the preparation device.
[0080] The preparation unit according to the invention preferably has some or more of the characteristics and / or advantages described in connection with the process according to the invention for the thermal preparation of an auxiliary material.
[0081] In particular, it can be predicted that, by means of the feeding device, an auxiliary material loaded with pollutant in a lower region - in relation to the direction of the gravity force - of a turbulent layer generated through turbulence in the thermal preparation device can be driven into the turbulent layer. For this purpose, the auxiliary material loaded with pollutant can be guided to a lower region - in relation to the direction of the force of gravity - of a receptacle of the preparation device for receiving the auxiliary material and / or a basic layer material turbulent.
[0082] The preparation device is specially configured as a turbulent layer oven.
[0083] In particular, it can be provided that the preparation device includes a receptacle that includes a gas-permeable bottom. In this way, the material admitted to the receptacle, especially a basic material with a turbulent layer and / or an auxiliary material loaded with pollutant, can be subjected to a gas stream, traversed by it and placed in turbulence in a particularly simple way by gas, especially gas carrier.
[0084] Furthermore, it can be provided that the preparation unit includes a heating device, by means of which it is possible to heat the receptacle, the gas-permeable bottom and / or the gas supplied, that is, the carrier gas stream .
[0085] It may be propitious that by means of the removal device, particles of the auxiliary material, particularly the auxiliary material loaded with pollutant, and / or particles of a basic material of turbulent layer, in an upper region - in relation to the direction of the force gravity - from a turbulent layer generated through turbulence, they can be removed. For this, a spillway can be specially provided.
[0086] It may be suitable for the preparation unit to include a sedimentation device and / or a combustion device, to which the carrier gas stream can be conducted, which especially for the turbulence of a basic material of turbulent layer and / or a pollutant-loaded auxiliary material can be conducted through the basic turbulent layer material and / or the pollutant-loaded auxiliary material.
[0087] The preparation unit according to the invention is particularly suitable for use in a sterilization unit.
[0088] The present invention also relates to a sterilization unit for sterilizing workpieces.
[0089] In this regard, the invention sets itself the objective of providing a sterilization unit, which can be operated in a particularly simple or resource-saving manner.
[0090] This objective is achieved, according to the invention, due to the fact that the sterilization unit for sterilizing workpieces, especially vehicle bodies, includes:
[0091] - a ligation device, by means of which the work pieces can be lacquered with lacquer;
[0092] - a filtering device for cleaning a stream of crude gas, charged with lacquer overspray and generated in the sterilization device, by conducting auxiliary filter material for the crude gas stream and separation by sedimentation from the overspray of lacquer together with the filtering aid material in a filter element of the filtering device;
[0093] - a preparation unit, according to the invention, with the organic pollutant being lacquer overspray and the auxiliary material being filtering auxiliary material.
[0094] Due to the use of a preparation unit according to the invention, the sterilization unit according to the invention can be operated in a particularly simple and resource-saving manner.
[0095] Preferably, the ligation unit also includes a mixing device, by means of which a fresh auxiliary material and a prepared auxiliary material can be conducted together and can be mixed. The mixed auxiliary material can preferably be fed to the filtering device of the sterilization unit.
[0096] Furthermore, it can be provided that the sterilization unit includes at least one measuring device for the measurement and / or for the determination of a fraction of pollutant in the auxiliary material loaded with pollutant, that is, of a loading degree auxiliary material with pollutant.
[0097] In addition, the process according to the invention, the preparation unit according to the invention and / or the sterilization unit according to the invention can have one or more of the characteristics and / or advantages described below.
[0098] A particle abrasion of a basic material with a turbulent layer preferably serves to dilute the auxiliary material to be prepared, especially residual substances that may be left in the auxiliary material, especially aluminum flakes of metallic lacquers.
[0099] Especially if lime stone flour is used as an auxiliary material, it can be predicted that the temperature of the basic material of turbulent layer and / or the auxiliary material in the preparation device will be selected in such a way that neither the lime stone burn and neither calcination occurs. In particular, it can be expected that the process will be operated at a temperature level between combustion and calcination of lime stone flour.
[00100] It can also be foreseen that the preparation device is operated in the case of very high temperatures, in which the basic material of turbulent layer and / or the auxiliary material are chemically transformed. The materials thus formed can then be used, especially in other places.
[00101] It can be foreseen that zeolites will be used as auxiliary material and / or as basic material of turbulent layer. Preferably, zeolites are chemically transformed only minimally at higher temperatures.
[00102] The use of inorganic materials, such as, for example, quartz (SiO2) as basic material of turbulent layer and / or as auxiliary material, allows the use of very high temperatures, such as, for example, up to 1000 ° C. In this way, it is possible, in particular, to burn organic materials from the auxiliary material. Preferably, therefore, further thermal combustion is not necessary. In a modified example, sands are used, possibly as mixtures, including quartz sand, as a basic material with a turbulent layer and / or as an auxiliary material.
[00103] It can be predicted that, by means of a further thermal combustion, substances (TNV) are burned that are contained, especially, in the gas stream, especially the carrier gas stream, which is conducted through the basic material of turbulent layer and / or auxiliary material loaded with pollutant.
[00104] A further thermal combustion device can be, for example, a separate thermal combustion device and allocated to the preparation unit or a later thermal combustion device already existing in a sterilization unit.
[00105] A further thermal combustion device is preferably arranged after a sedimentation device, especially after a hot gas filter, of the preparation unit.
[00106] It may be conducive for the further thermal combustion device to be designed as a torch. In this way, it is possible to totally burn inorganic components, insufficiently incinerated, of the gas stream conducted through the basic material of turbulent layer and / or the auxiliary material loaded with pollutant, converting them into carbon dioxide.
[00107] The use of a separate thermal combustion device later for the preparation unit can facilitate the integration of the preparation unit with a sterilization unit, since the location of the preparation unit is, therefore, essentially independent of a subsequent thermal combustion device of the sterilization unit.
[00108] Preferably, combustion is an exothermic process, in such a way that it is possible to take advantage of the heat it gives off to heat, particularly pre-heat, another processing air, especially a gas stream. In this way, it is preferably possible to reduce the required heating power of the thermal preparation device.
[00109] As a heating device for heating the gas stream conducted through the basic material of turbulent layer and / or the auxiliary material charged with pollutant, an electric heating device is preferably used.
[00110] Alternatively or in addition to this, the gas stream can be heated by means of air leaving a drying device for drying workpieces, especially vehicle bodies. In that case, it can be specially provided that a portion of the air leaving the drying device is forked, and is then conducted through the preparation device, especially the basic material of turbulent layer and / or auxiliary material loaded with pollutant, and eventually, being then led to a further thermal combustion device. In this way, the volumetric total air flow conducted to the subsequent thermal combustion device preferably remains at least approximately unchanged, and this also results in the configuration and size of the further thermal combustion device.
[00111] It may be conducive for air coming out of a drying device to be subjected to solvents. When the outlet air is introduced in the form of a gas stream in the basic material with a turbulent layer and / or in the auxiliary material loaded with pollutant, it is then possible to use the solvent already contained in the gas stream for heating the gas stream, so that less additional energy is needed for heating.
[00112] It may be conducive for several process air streams (gas streams) to be introduced into the preparation device, especially through a regulating valve. Especially when using differently heated process air currents, it is possible to adjust the temperature of the gas flow conducted to the preparation device with a regulating valve.
[00113] In particular, it can be predicted that a subcurrent of air in the gas stream is overheated, such as, for example, having a temperature of 700 ° C, in order to compensate for endothermic processes.
[00114] In addition, it may be anticipated that a subcurrent of air will consist of another gas, such as, for example, nitrogen, oxygen or carbon dioxide, or include another gas at a higher concentration to, through reactions of that gas , influence the combustion and / or transformation of the pollutant in the preparation device.
[00115] It can be provided that two streams of process air are introduced into the preparation device, such that each stream of process air can be introduced into the preparation device through the burner, that is, with process temperature, or without burner, that is, at room temperature. If one of the processing air currents is an outlet air from a drying device, then, because of this, it will be possible to react very flexibly to possible changes of state (changes of operational state) of the sterilization unit. For example, a rapid heating of the preparation device, especially of the basic material of turbulent layer and / or of the auxiliary material loaded with pollutant, can occur through the exhaust air of a drying device when the exhaust air already has a level predetermined temperature. In addition, in this way, the preparation device can also be operated safely without the operation of a drying device. Solvents from the outlet air can be burned in a combustion chamber of the preparation device, especially in the region of the basic material of turbulent layer and / or the auxiliary material loaded with pollutant. In this way, it is preferably possible to compensate for different concentrations of lacquer (degrees of loading) in the auxiliary material loaded with pollutant. In addition, the preparation device can be cooled by means of air whose temperature is at room temperature.
[00116] It can be foreseen that an underflow of air that is introduced in the preparation device, especially through the basic material of turbulence layer and / or the auxiliary material loaded with pollutant, is the exit air of the preparation device that presents, especially, a temperature approximately above 400 ° C. This subcurrent of air may include all of the outlet air from the preparation device or any part thereof.
[00117] It can also be provided that subcurrents of air are conducted to the preparation device, in locations other than the preparation device, especially to the basic material of turbulent layer and / or with auxiliary material loaded with pollutant. For example, it can be envisaged that an underflow of air will be conducted directly through a bottom of a receptacle for the basic material of turbulent layer and / or for the auxiliary material loaded with pollutant, especially through a bed of turbulence, particularly to improve the formation of a turbulent layer.
[00118] It can be predicted that, especially through special nozzle geometries, through the addition of processing air, turbulences will be generated in the so-called Freeboard, which favor or hinder the removal of particles from the turbulent layer, that is, the The residence time of the particles in the preparation device can be reduced, respectively, it can be extended.
[00119] It may be appropriate to introduce process air at different points in the preparation device. In this way, it is possible to generate, in particular, a "stoichiometric layer" in the preparation device, that is, at different points in the preparation device, different concentrations of oxygen predominate. In this sense, for example, excess oxygen can facilitate stoichiometric mode, the combustion of pollutants. Particularly to facilitate combustion reactions that occur incompletely at preferred material temperatures of approximately 550 ° C maximum. Particularly in this case, it is possible to favor individual combustion processes that occur in particles present in suspension.
[00120] The processing air for the thermal preparation device, that is, especially the air (carrier gas stream) conducted through the base material of the turbulent layer and the auxiliary material loaded with pollutant, can be preheated through a heat exchanger. air heat. In particular, heat-emitting process air currents are considered, in particular, the air currents from a subsequent thermal combustion device.
[00121] Since the combustion of organic materials to form carbon dioxide is an exothermic process, then, eventually after the high operating phase (starting process) of the preparation unit, a cooling must occur. As cooling air can for example, air from the house. For this purpose, the heat exchanger of a subsequent thermal combustion device can be bypassed, for example, by means of a bypass.
[00122] When the exothermic reaction in the preparation device is very strong, then another cooling in the preparation device may be necessary. For this purpose, the amount of air used for the turbulence of the auxiliary material loaded with pollutant and / or the basic material of the turbulent layer can be increased. Preferably, care should be taken that the auxiliary material loaded with pollutant does not leave the turbulent layer.
[00123] Alternatively or in addition to this, it is possible to reduce or completely interrupt the supply of auxiliary material loaded with pollutant to the thermal preparation device, especially for the basic material of turbulent layer. If, alternatively or in addition, the amount of air supplied to the preparation device is so low that there is a lack of stoichiometric oxygen, then pyrolysis can be carried out in such a way that tar, soot and / or ash can form.
[00124] Preferably, the preparation device includes a control or regulation device, by means of which it is possible to control and / or regulate the temperature of the gas stream supplied to the preparation device, the mass stream of the gas stream supplied to the preparation device and also the supplied quantity of auxiliary material loaded with pollutant.
[00125] Adjustment can be carried out, for example, depending on an oxygen content in the preparation device that is detected by means of a measuring device. In this sense, through the control device it is possible to strangle or completely interrupt the supply of auxiliary material loaded with pollutant, when the oxygen concentration in the preparation device is very small, such as, for example, equal to or less than approximately 5% . For this purpose, the supply device, such as a conveyor propeller, for example, can be controlled, for example, by means of a frequency converter, which can be strangled depending on a signal from an oxygen sensor of the measuring device. , especially until the carrier has stopped. In this way, it is possible to ensure that pollutants from the pollutant-laden auxiliary material can be incinerated completely, in essence, before another pollutant-laden auxiliary material is supplied.
[00126] In a configuration of the invention it can be provided, for example, that a flow guide (air guide), for example a tube, is arranged in the middle, centralized, in an intake device for the admission of the basic material of turbulent layer and / or pollutant-loaded auxiliary material, in which, preferably, a turbulent layer can be generated by turbulence. There, the gas stream preferably runs in the direction of the gravity force, from top to bottom, and will already be preheated by the prevailing temperatures. With this, the pipes extend, at least partially, preferably for the most part, or even totally, within the preparation device.
[00127] It may be advantageous for the preparation device to include a receptacle, the bottom of which is designed as a nozzle bottom. In particular, it can be provided that a nozzle bottom is designed as a bell-shaped bottom. If nozzle bottoms are used, a small loss of pressure is introduced in the introduction of the gas stream to generate the turbulence of the auxiliary material loaded with pollutant and / or the basic material of the turbulent layer.
[00128] Alternatively, it can be provided that a bottom of the preparation device receptacle includes a fluidization device, such as, for example, a sintered ceramic or sintered metal fluidization device. In this way, the gas stream can be introduced particularly evenly over the entire bottom area. With this, it is constructively possible, in a particularly simple way, to effectively bring the auxiliary material loaded with pollutant into turbulence, especially with the basic material of turbulent layer.
[00129] Preferably, other substances with organic fractions can be burned in the preparation device. For example, a film application in the booth, which is soiled with lacquer after being removed from a sterilizing device designed as a sterilization booth, can be crushed, especially shredded, and can be supplied, as an additional stream of solid substances, to the material basic turbulent layer and / or the auxiliary material loaded with pollutant. In this way, it is possible to increase the combustion rate of the material to be prepared.
[00130] Preferably, the preparation unit is designed in such a way that, even when several streams of substances, material streams and / or gas streams are foreseen, thermal preparation of auxiliary material loaded with pollutant is always possible, even that only by using a gas stream and auxiliary material loaded with pollutant, to be prepared.
[00131] In a configuration of the invention, it can be provided that the preparation device includes a hot gas filter, through which the gas flow is conducted. The preparation device is fed with auxiliary material loaded with pollutant, preferably continuously, by means of the feeding device, such as, for example, a conveyor propeller, a material that, for this, for example, is inserted just above a bottom. of a receptacle of the preparation device. By introducing material into the preparation device, the filling level in the preparation device increases. Particles of auxiliary material and / or abrasion of basic turbulent material, which accumulate at the upper end - in relation to the direction of the gravity force - of the turbulent layer generated, for example, by turbulence, can be removed from the preparation, for example, by means of a dump. Preferably, the auxiliary material prepared and thus removed is then cooled.
[00132] In another embodiment, it can be provided that the preparation device has a receptacle (tubes), in which the thermal preparation takes place and, with this, the auxiliary material and / or the basic material of turbulent layer is strongly heated . In another receptacle (tubes) of the preparation device, in which the prepared auxiliary material from the first receptacle is conducted, for example, by means of a sink, to cool the prepared auxiliary material, it is fluidized with a cold gas stream. . In this case, the cold gas stream absorbs the heat from the prepared auxiliary material, such that the second receptacle can be cooled, in total, to a temperature of approximately 350 ° C, for example. The heated air can then be removed through a filtering device, which is disposed adjacent to the second receptacle or the second receptacle. In that case, the air temperature is preferably above the condensation temperature of the organic substances contained therein. This makes it possible to effectively reduce or completely prevent condensation of organic substances, especially in the filtering device.
[00133] It may be propitious that, through the turbulence of the auxiliary material loaded with pollutant and / or the basic material of turbulent layer in the thermal preparation device, a turbulent layer that forms bubbles is formed. In this way, the discharge of solid substances from the turbulent layer is minimized. Preferably, in this case, an ideal ratio between oxygen in the air and pollutant to be burned is selected.
[00134] Alternatively to this, it can be predicted that, through the turbulence of the auxiliary material loaded with pollutant and / or the basic material of turbulent layer, a turbulent circulating layer will be formed. It may be appropriate for the preparation device to include a receptacle with an expanded cross section ("Freeboard") that extends upwards, against the direction of the force of gravity. In this way, the small particles discharged from the turbulent layer can be delayed based on slowing down the gas flow, so that they can fall back into the turbulent layer.
[00135] In another embodiment of the invention, it can be provided that the prepared auxiliary material is ejected from the preparation device through a filtering device. In particular, the formation of a turbulent circulating layer can be envisaged. For this purpose, the filtering device, especially a hot gas filter, is preferably arranged outside the vertical projection of the receptacle, especially the turbulent layer. In this way, it is effectively reduced or completely avoided that, eventually during cleaning, particles sedimented in the filtering device fall from it back into the turbulent layer. Instead, the fall may occur a container disposed under the filtering device. In this case, preferably, the preparation device is operated in such a way that the particles have a long residence time in the preparation device, in order to guarantee a complete conversion of the organic components of the pollutant.
[00136] In addition, it may be advantageous that the preparation device includes two receptacles (as described above), as well as a filtering device for the discharge of the prepared auxiliary material (as described above).
[00137] Preferably, the preparation device is integrated with a cleaning device for cleaning a stream of crude gas charged with pollutant, especially a filtering device with regenerable filter modules.
[00138] Preferably, the auxiliary material is automatically removed from the filtering device for cleaning the raw gas stream and is led to the preparation device.
[00139] Preferably, a damping device specially provided for automatic or manual operation is provided, in which the auxiliary material loaded with pollutant from the filtering device can be temporarily stored for cleaning the raw gas stream. From the damping device, the auxiliary material loaded with pollutant is conveyed to the preparation device.
[00140] The damping device includes, in particular, a damping container that has a storage volume of, for example, at least approximately one cubic meter, especially approximately 100 cubic meters.
[00141] The supply of auxiliary material loaded with pollutant to the preparation device occurs, preferably, through a cooling fan, which is also called a helical heat exchanger. Cooling of the auxiliary material loaded with pollutant supplied to the preparation device preferably takes place in such a way that the temperature up to the supply to the preparation device is at most approximately 120 ° C, to prevent condensation of tar on the preparation device. food.
[00142] Alternatively, a thick current can be transported, and, preferably, to prevent heat conduction, a transport duct is cooled. If rapid transport occurs, then it is preferable to dispense with cooling the auxiliary material.
[00143] In addition, an irrigation device and / or a vibrating chute may alternatively be provided as the supply device.
[00144] An average particle size of the basic turbulent layer material preferably ranges from approximately 0.1 mm to approximately 10 mm, especially between approximately 0.3 mm to approximately 3 mm.
[00145] The average particle size distribution of fresh and / or prepared auxiliary material is preferably between approximately 10 pm and approximately 50 pm, especially between approximately 15 pm and approximately 30 pm.
[00146] The average particle size distribution of auxiliary material loaded with pollutant is, for example, at approximately 50 pm to approximately 60 pm.
[00147] Other preferred characteristics and / or advantages of the invention are the subject of the description that follows and the drawing presentation of execution examples.
[00148] The drawings show:
[00149] Fig. 1: a schematic vertical cross-section through a ligation unit for the ligation of workpieces;
[00150] Fig. 2: a schematic vertical cross-section through a first execution of a preparation unit for the preparation of auxiliary material;
[00151] Fig. 3: a schematic display corresponding to figure 2, of a second embodiment, in which the outlet air from a preparation device of the preparation unit is used for heating the supply air to the device preparation;
[00152] Fig. 4: a schematic display corresponding to figure 2, of a third embodiment, in which a further thermal combustion device is provided;
[00153] Fig. 5: a schematic display corresponding to figure 2, of a fourth embodiment of a preparation unit, in which several subcurrents of air are provided as a mixed supply airflow for the preparation device;
[00154] Fig. 6: a schematic display corresponding to figure 2, of a fifth form of execution of a preparation unit, in which the supply air is supplied to different points of the preparation device;
[00155] Fig. 7: a schematic display corresponding to figure 2, of a sixth form of execution of a preparation unit, in which an air duct for supply air extends inside the preparation device;
[00156] Fig. 8: a schematic vertical cross-section through a seventh form of execution of a preparation unit, in which a further thermal combustion device is provided, as well as a heat exchanger provided with a bypass for the heating the supply air to the preparation device of the preparation unit;
[00157] Fig. 9: a schematic display corresponding to figure 8, of an eighth form of execution of a preparation unit, which is coupled with a drying device for drying workpieces;
[00158] Fig. 10: a schematic display corresponding to figure 8, of a ninth form of execution of a preparation unit, in which an electrical heating device is provided for heating the supply air to the preparation device of the unit preparation;
[00159] Fig. 11: a schematic display corresponding to figure 8, of a tenth form of execution of a preparation unit, in which a circulating air circuit is provided for the operation of the preparation device of the preparation unit and a drying device for drying workpieces;
[00160] Fig. 12: a schematic display corresponding to figure 8, of an eleventh form of execution of a preparation unit, in which an electric heating device and a heat exchanger are provided;
[00161] Fig. 13: a schematic display corresponding to figure 8, of a twelfth form of execution of a preparation unit, in which a measuring device is provided for determining gas concentrations in the preparation device of the preparation unit preparation;
[00162] Fig. 14: a schematic display of a preparation device for a preparation unit, in which a turbulent layer that forms bubbles is formed;
[00163] Fig. 15: a schematic display of a preparation device for a preparation unit, in which a turbulent circulating layer is formed;
[00164] Fig. 16: a schematic display corresponding to figure 8, of a thirteenth form of execution of a preparation unit, in which a removal of prepared auxiliary material takes place by means of a filtering device;
[00165] Fig. 17: a schematic display of a fourteenth form of execution of a preparation unit, which includes damping devices for intermediate storage of auxiliary material loaded with pollutant and prepared auxiliary material.
[00166] Equally or functionally equivalent elements received the same numbers in all figures.
[00167] A sterilization unit shown in figure 1 and designated as a whole by reference number 100 includes a sterilization device 102 configured as a sterilization booth, in which workpieces 104, such as vehicle bodies, can be lacquered (can be lacquered).
[00168] For this, the workpieces 104 can be guided by means of a workpiece conveying device 108 to an application region 106 of the ligation device 102 and can be removed again from the application region 106.
[00169] The ligation unit 100 also includes a plenum 110 disposed above the ligation device 102, by means of which it is possible to supply air to the application region 106.
[00170] In addition, the sterilization unit 100 includes a filter unit 112 arranged under the sterilization device 102, by means of which it is possible to clean the air conducted through the application region 106, which, due to the application of lacquer on the pieces to work 104, absorbed pollutants configured as lacquer overspray.
[00171] The filtering unit 112 includes several filtering devices 114.
[00172] Each filtering device 114 includes a housing 116 that encloses a raw gas chamber 118 and in which at least one filter element 120 is arranged.
[00173] In addition, the filtering device 114 includes an inlet channel 122, through which a stream of crude gas, which is formed by air impacted by pollutant conducted through the application region 106, can flow into the raw gas 118 from the filter device 114.
[00174] The filtering device 114 is designed as a dry filtering device, that is, a cleaning of the stream of crude gas occurs, essentially, without the addition of a liquid to the filter elements 120. Instead, to the stream of crude gas an auxiliary material can be provided, especially filter aid material, which preferably absorbs a fraction of liquid in the pollutant and, together with the pollutant, can be separated by sedimentation in the filter element 120 in the form of auxiliary material loaded with pollutant. Together with the pollutant, the auxiliary material forms a stable system formed by pollutant and auxiliary material.
[00175] By cleaning the raw gas stream, a pure gas stream is obtained, which leaves the filtering device 114 through a pure gas duct 123.
[00176] The sediment of the pollutant, together with the auxiliary material, forms a blocking layer or a protective layer on the filter element 120, which can be easily removed from the filter element 120.
[00177] Thus, the filtering device 114 is a regenerable filtering device 114, which can be regenerated and used again without a replacement of filter elements 120.
[00178] The auxiliary material loaded with pollutant and removed from the filter element 120 can be received in a collecting container 124 of the filter device 114, which is disposed under the filter element 120.
[00179] After a certain time of operation of the filtering device 114, the auxiliary material is heavily loaded with pollutant, in order to enable a safe cleaning of the raw gas stream and a safe protection of the filter element 120. Therefore, the auxiliary material loaded with pollutant must be regularly prepared and / or replaced with fresh auxiliary material.
[00180] The preparation of the auxiliary material includes the sterilization unit 100 and a thermal preparation unit 126 (see figure 2).
[00181] In the first embodiment, shown in figure 2, of the thermal preparation unit 126, it is provided that the preparation unit 126 includes a preparation device 128, which is specially configured as a turbulent layer oven 130.
[00182] The preparation device 128 includes a receptacle 132 for the admission of basic material of turbulent layer and auxiliary material, especially auxiliary material loaded with pollutant.
[00183] However, in another form of execution it is possible to dispense with the use of basic material with a turbulent layer.
[00184] The use of basic material of turbulent layer can be advantageous when it is intended to prepare an auxiliary material, which, for example, cannot in itself turbulence, due to agglutination forces between the particles of the auxiliary material and / or due to the size of the particles.
[00185] A bottom 134 of receptacle 132 is designed, for example, as a nozzle bottom 136, especially as a bell bottom 138 and makes it possible to feed air through the bottom 134 for the basic material of turbulent layer and for the auxiliary material, especially for the system formed by pollutant and auxiliary material, in receptacle 132.
[00186] Due to the supply air supply through the bottom 134 of the receptacle 132, a turbulent layer 140 formed by basic material of turbulent layer and / or by the system formed by pollutant and auxiliary material in the receptacle 132 can be formed.
[00187] The bell bottom 138 of receptacle 132 includes a series of nozzles 142, which, for example, in the form of bells, are provided with covers 144.
[00188] Through a supply air duct 146 of preparation unit 126 it is possible to supply supply air to receptacle 132 of preparation device 128.
[00189] In addition, the preparation unit 126 includes a heating device 148, especially a burner which serves to heat the supply air.
[00190] In the first embodiment of the preparation unit 126, shown in figure 2, the supply air to be heated by means of the heating device 148 and to be conducted to the receptacle 132 of the preparation device 128 is ambient air from preparation unit 126 environment, especially room air.
[00191] Through the outlet air duct 150 of the preparation unit 126, the gas stream, especially the carrier gas stream, which can be conducted as supply air via the supply air duct 146 to the receptacle 132 of the preparation device 128 and which can be guided through the basic material of turbulent layer and the auxiliary material loaded with pollutant, can be removed from the receptacle 132 of the preparation device 128.
[00192] The preparation unit 126 includes a sedimentation device 152, such as, for example, a filtering device 154. With this, it is possible to prevent undesirable impurities from the outlet air, that is, from the gas stream conducted through the turbulent layer 140, are emitted into the environment of preparation unit 126.
[00193] Furthermore, by means of the sedimentation device 152, especially by means of the filtering device 154, it is possible to remove auxiliary material already prepared from the receptacle 132 of the preparation device 128 (on this, see figure 16).
[00194] With this, the sedimentation device 152 can also serve as a removal device 156 for the removal of already prepared auxiliary material from the preparation device 128. In particular, the sedimentation device 152 is part of a separation device 157 for the separation of auxiliary material already prepared from auxiliary material loaded with pollutant.
[00195] Preparation unit 126 further includes a feeding device 158, by means of which it is possible to supply pollutant-loaded auxiliary material to receptacle 132 of preparation device 128. In particular, the pollutant-loaded auxiliary material can be guided to receptacle 132 in a lower region 161 - in relation to a direction of the force of gravity 160 - thereof.
[00196] The first embodiment of preparation unit 126 described above works as follows.
[00197] Through the supply air duct 146, air is drawn from the environment of the preparation unit 126 and it is supplied as supply air to the receptacle 132 of the preparation device 128.
[00198] In this case, the supply air is heated by means of the heating device 148 above the temperature under normal conditions (about 20 ° C to 30 ° C), especially to a temperature of approximately 550 ° C.
[00199] The supply air is conducted as a gas stream, especially a carrier gas stream, through the bottom 134 of the receptacle 132, turbulences the basic material of turbulent layer disposed in the receptacle 132 and heats the basic material of turbulent layer. In this way, a hot turbulent layer 140 is formed in the receptacle 132 of the preparation device 128.
[00200] By means of the feeding device 158 the base material of turbulent layer is supplied with auxiliary material loaded with pollutant, such as, for example, from the filtering devices 114 of the filtering unit 112 of the sterilization unit 100.
[00201] The auxiliary material loaded with pollutant is then heated and prepared in the preparation device 128.
[00202] With this, the preparation device 128 is a thermal preparation device 128.
[00203] With this, the preparation unit 126 is a thermal preparation unit 126.
[00204] Due to the heating of the auxiliary material loaded with pollutant, the pollutant is transformed chemically, at least partially, especially burned or, at least it reduces the stickiness of the pollutant, in such a way that the agglomerates formed by particles of pollutant and particles of auxiliary material. In that case, preferably, particles of auxiliary material remain chemically unchanged.
[00205] Especially, due to the heating of the auxiliary material loaded with pollutant, an organic component of the pollutant is evaporated, preferably burned, and is removed from the system formed by pollutant and auxiliary material.
[00206] The particles of auxiliary material free of pollutants accumulate, due to the smaller mass and / or the smaller size, in an upper region 162 - in relation to the direction of the force of gravity 160 - of the turbulent layer 140 and there they can be dragged by the current gas stream and, finally, can be sedimented in the sedimentation device 152. By means of the removal device 156, these particles, in the form of prepared auxiliary material, are removed from the preparation device 128 and can be reused in the filtering unit 112, especially in the filtering devices 114 of the filtering unit 112, for cleaning a stream of crude gas.
[00207] In this case, as an auxiliary material, lime stone flour is especially considered.
[00208] Preferably, the basic material of turbulent layer is also lime stone flour, although it preferably presents particles as larger particle diameters. For example, the particles of the basic turbulent layer material are, on average, at least approximately 10 times, for example approximately 50 times, as large as the particles of the auxiliary material.
[00209] During the operation of the preparation unit 126, the basic material of turbulent layer is crushed more and more through abrasion, in such a way that particles of the basic material of turbulent layer are formed that have a size similar to the particles of the material help. Since, preferably, the base material of turbulent layer has a chemical composition that corresponds to the chemical composition of a material that can be used as auxiliary material, then also the particles of basic material of turbulent layer can be removed from the preparation device 128 by means of the removal device 156 and can be used as auxiliary material prepared in the filter unit 112 for cleaning a stream of crude gas.
[00210] A second embodiment, shown in figure 3, of a thermal preparation unit 126 differs from the first embodiment shown in figure 2, basically, in that the outlet air conducted through the sedimentation device 152 is expelled into the environment without recovery. Instead, a heat exchanger 164 is provided, whereby the heat contained in the outlet air from the preparation device 128 can be transferred at least partially to the supply air to be supplied to the preparation device 128. In this way it is preferably possible to reduce a fuel requirement of the heating device 148.
[00211] Moreover, the second form of execution of a preparation unit 126, shown in figure 3, coincides with the first form of execution shown in figure 2 in terms of construction and function, in such a way that it will be taken as a reference to previous description of this.
[00212] A third embodiment of a thermal preparation unit 126 shown in figure 4 differs from the first embodiment shown in figure 2, basically, in that as supply air for preparation device 128 is used outlet air from a drying device (yet to be described) for drying workpieces 104, especially vehicle bodies.
[00213] Furthermore, in the embodiment of preparation unit 126 shown in figure 4, a combustion device 166 is provided, especially a further thermal combustion device 168.
[00214] In this case, the exhaust air from the drying device is conducted partially to the preparation device 128 and partially directly to the further thermal combustion device 168.
[00215] In the third embodiment of the preparation unit 126 shown in figure 4, the outlet air from the preparation device 128 is also conveyed to the further thermal combustion device 168 through the outlet air duct 150, after traversing the sedimentation device 152.
[00216] Due to the use of outlet air from the drying device in the form of supply air to the preparation device 128, it is possible to reduce the fuel requirement of the heating device 148. On the one hand, this is due to the fact that the exhaust air from the drying device already has a high temperature. On the other hand, the outlet air from the drying device contains solvents, most of which are combustible, which, when burned in the preparation device 128, also contribute to raising the temperature, avoiding additional heating through the device heating element 148.
[00217] The subsequent thermal combustion device 168 serves for the elimination of all organic and other substances possibly dangerous to the health of the air leaving the drying device and the air leaving the preparation device 128. Especially, through the further thermal combustion device 168, it is possible to employ a very high temperature for the chemical transformation of undesirable substances.
[00218] Alternatively or in addition to the removal of organic substances from the outlet air, especially the outlet air from the preparation device, by means of further thermal combustion, it is possible to employ a condensate separator. In this case, by means of a heat exchanger, the temperature of the air stream is cooled below the dew point of the organic substances to be separated. Condensed substances are collected in a collecting container.
[00219] Furthermore, the third embodiment of the preparation unit 126 shown in figure 4 coincides with the first embodiment shown in figure 2, in such a way that the description of this one made above will be taken as reference.
[00220] A fourth embodiment of a thermal preparation unit 126 shown in figure 5 differs from the third embodiment shown in figure 4, basically, in that the preparation unit 126 includes a valve arrangement 170, for example whereby the supply air for the preparation device 128 can be made available, optionally from different sources, especially the ambient air, such as, for example, the room air, or from the outlet of a drying device.
[00221] In addition, by means of valve arrangement 170, the supplied air can optionally be supplied to the heating device 148 and be heated there or conducted around the heating device 148.
[00222] By means of a control device 172 of the preparation unit 126 it is possible to control and / or regulate the valve arrangement 170 especially in such a way that a temperature in the receptacle 132 of the preparation device 128 is essentially constant.
[00223] To monitor the temperature in the receptacle 132 of the preparation device 128, a measuring device 174 is provided.
[00224] Preferably, the feeding device 158 and the removing device 156 can also be controlled and / or regulated by means of the control device 172.
[00225] Moreover, the fourth form of execution of a preparation unit 126 shown in figure 5 coincides - in terms of construction and function - with the third form of execution shown in figure 4, in such a way that it will be taken as a reference to described above about this.
[00226] A fifth embodiment of a thermal preparation unit 126 shown in figure 6 differs from the first embodiment shown in figure 2, basically, in that the supply air for preparation device 128 is introduced in different points in receptacle 132 of preparation device 128.
[00227] On the one hand, the supply air is introduced through the bottom 134 of the receptacle 132, to enable a turbulence of the basic material of turbulent layer and the auxiliary material loaded with pollutant.
[00228] In addition, at different points above the turbulent layer 140, supply air is introduced, in order to be able to influence in a planned manner a turbulence and / or a removal of prepared and submitted to turbulent auxiliary material.
[00229] Moreover, the fifth form of execution of a preparation unit 126 shown in figure 6 coincides - in terms of construction and function - with the fourth form of execution shown in figure 5, in such a way that it will be taken as a reference to description above about this.
[00230] A sixth embodiment of a thermal preparation unit 126 shown in figure 7 differs from the first embodiment shown in figure 2, basically due to the fact that preparation device 128 includes an air duct 176, which is essentially vertically aligned, being disposed in the middle in receptacle 132 of preparation device 128 and extending essentially the entire length of receptacle 132 of preparation device 128.
[00231] The air duct 176 enables the supply of air to the bottom 134 of the receptacle 132, the air being conducted in the direction of the force of gravity 160, from above through the receptacle 132 of the preparation device 128 and, as a result, it is automatically heated during operation of the preparation device 128.
[00232] In this way it is possible to efficiently use the heat formed and / or existing in the preparation device 128, to minimize the need for additional heating.
[00233] Moreover, the sixth form of execution of a preparation unit 126 shown in figure 7 coincides with the first form of execution shown in figure 2, in such a way that the description made above about it will be taken as reference.
[00234] A seventh embodiment of a thermal preparation unit 126 shown in figure 8 differs from the first embodiment shown in figure 2, basically, in that the preparation unit 126 includes a further thermal combustion device 168 ( see also the third and fourth forms of execution according to figures 4 and 5).
[00235] In that case, the outlet air from the preparation device 128 is conducted to the further thermal combustion device 168 and is heated there intensely.
[00236] Both the heated exhaust air from the subsequent thermal combustion device 168, as well as the supply air to the preparation device 128 are conducted to a heat exchanger 164 to transmit the heat from the heated exhaust air to the air supply to be heated.
[00237] To prevent overheating of the supply air and / or the intake device 128, the heated outlet air can be conducted partially or completely to bypass the heat exchanger 164 by means of a by-pass 178.
[00238] For the adjustment of a fraction of the outlet air conducted through the heat exchanger 164 and a fraction of the outlet air that bypasses the heat exchanger 164 by means of by-pass 178, a valve arrangement 170 is provided in the seventh embodiment of the preparation unit 126 shown in figure 8. The valve arrangement 170 can be controlled, for example, by means of the control device 172 (see, especially, the fourth embodiment according to figure 5).
[00239] For the separation of the prepared auxiliary material from the auxiliary material loaded with pollutant, a separation device 157 can be provided, designed as a drain device 179. Through this drain device 179, which is preferably arranged in the upper region 162 of the turbulent layer 140, the prepared auxiliary material that accumulates in the upper region 162 can be separated from the auxiliary material loaded with pollutant that accumulates especially in the lower region 161.
[00240] Moreover, the seventh form of execution of the preparation unit 126 shown in figure 8 coincides - in terms of construction and function - with the first form of execution shown in figure 2, in such a way that the description will be taken as reference above made on this.
[00241] An eighth embodiment of a thermal preparation unit 126 shown in figure 9 differs from the seventh embodiment shown in figure 8, basically, due to the fact that the air conduction (supply air and outlet air) ) of the preparation device 128, together with the heat exchanger 164, is integrated with the air conduction (supply air and exhaust air) of a drying device 180 for drying workpieces 104, especially vehicle bodies, and a corresponding corresponding thermo-combustion device 168 thereafter.
[00242] In a manner corresponding to the seventh embodiment shown in figure 8, also in the eighth embodiment shown in figure 9, the supply air to the preparation device 128 is heated by means of a heat exchanger 164, to which the exhaust air from the preparation device 128 heated in the further thermal combustion device 168 is conducted.
[00243] Additionally, in the ninth embodiment shown in figure 8, the heat coming from the outlet air of the subsequent thermal combustion device 168 is expected to be transmitted, through another heat exchanger 164, to the supply air to the device drying time 180.
[00244] As well as the outlet air from the preparation device 128, also the outlet air from the drying device 180 is conveyed to the further thermal combustion device 168.
[00245] Moreover, the eighth form of execution of a preparation unit 126 shown in figure 9 coincides - in terms of construction and function - with the seventh form of execution shown in figure 8, in such a way that it will be taken as a reference to description above about this.
[00246] A ninth embodiment of a thermal preparation unit 126 shown in figure 10 differs from the first embodiment shown in figure 2, basically, in that the heating device 148 is designed as an electric heating device 148, especially as an electric heating unit.
[00247] Thereby, the supply air to the preparation device 128 is heated by means of an electric heating device 148.
[00248] The exhaust air from the preparation device 128 is conducted to a further thermal combustion device 168, thus being released from undesirable pollutants and, finally, released into the environment.
[00249] Moreover, the ninth form of execution of a preparation unit 126 shown in figure 10 coincides - in terms of construction and function - coincides with the first form of execution shown in figure 2, in such a way that it will be taken as reference the description made above about this.
[00250] A tenth embodiment of a thermal preparation unit 126 shown in figure 11 differs from the embodiment shown in figure 9, basically, in that the supply air for preparation device 128 is a part of outlet air from drying device 180.
[00251] The remaining part of the exhaust air from the drying device 180 is conveyed to the further thermal combustion device 168.
[00252] Likewise, the outlet air from the preparation device 128 is conveyed to the further thermal combustion device 168.
[00253] Moreover, the tenth form of execution of a preparation unit 126 shown in figure 11 coincides - in terms of construction and function - with the eighth form of execution shown in figure 9, in such a way that it will be taken as a reference to description of this made above.
[00254] An eleventh form of execution of a thermal preparation unit 126 shown in figure 12 differs from the second form of execution shown in figure 3, basically, due to the fact that the heating device 148 is designed as a heating device electric heating 148, especially as an electric heating aggregate.
[00255] In this case, the heating device 148 is, in particular, a backup heater.
[00256] Moreover, the eleventh form of execution of a preparation unit 126 shown in figure 12 coincides - in terms of construction and function - with the second form of execution shown in figure 3, in such a way that it will be taken as a reference the description about this is made above.
[00257] A twelfth embodiment of a thermal preparation unit 126 shown in figure 13 differs from the fourth embodiment shown in figure 5, basically due to the fact that by means of valve arrangement 170 it is possible to supply no only air streams with different temperatures, but also gas streams with different compositions, optionally, separately or mixed, in the form of supply air for the preparation device 128.
[00258] In this case, using the measuring device 174, it is preferably possible to determine a gas concentration, especially an oxygen concentration, in the preparation device128.
[00259] Depending on the gas concentration determined by means of the measuring device 174, it is possible to influence the valve arrangement 170 by means of the control device 172 to optimize the processing parameters in the preparation device 128.
[00260] Moreover, the twelfth form of execution of a preparation unit 126 shown in figure 13 coincides - in terms of construction and function - with the fourth form of execution shown in figure 5, in such a way that it will be taken as a reference the description of this made above.
[00261] In figure 14 a type of operation of a preparation device 128 is shown schematically, in which in the receptacle 132 of the preparation device 128 a turbulent layer is formed which forms bubbles.
[00262] In the case of a turbulent layer of this type that forms bubbles, the basic material of turbulent layer and / or the auxiliary material loaded with pollutant is passed through air. In this process, the individual solid particles, especially particles of auxiliary material and / or abrasion of basic material of turbulent layer are removed from the turbulent layer.
[00263] In figure 15, a type of operation of a preparation device 128 is schematically shown, in which a turbulent layer circulating in the receptacle 132 of the preparation device 128 is generated.
[00264] In the case of a turbulent circulating layer of this type, an entry into intense turbulence of the basic material of turbulent layer and / or auxiliary material loaded with pollutant occurs. Furthermore, in this way a massive removal of particles from the turbulent layer occurs, that is, a large amount of particles of auxiliary material and / or abrasion of basic material from the turbulent layer is removed from the turbulent layer, upwards, against the direction of the gravity force.
[00265] For the optimization of this type of operation of the preparation device 128, the receptacle 132 has a section 182 that expands upwards, against the direction of the gravity force, a section that leads to a delay in the gas flow in the receptacle 132 of the preparation device 128 and allows a return flow of the removed particles to the turbulent layer 140.
[00266] This section 182 that expands upwards is also called "Freeboard".
[00267] A thirteenth embodiment of a thermal preparation unit 126 shown in figure 16 differs from the first embodiment shown in figure 2, basically, in that below the sedimentation device 152, a collecting container 184 is arranged , by means of which it is possible to receive the auxiliary material already prepared that falls from the sedimentation device 152.
[00268] Since both the sedimentation device 152, as well as the collecting container 184 are disposed laterally in relation to the receptacle 132 of the preparation device 128, then, the auxiliary material already prepared and separated is prevented from returning to the turbulent layer 140.
[00269] In the thirteenth embodiment of a preparation unit 126 shown in figure 16, by means of the sedimentation device 152 and the collecting container 184, the prepared auxiliary material can be easily separated and, finally, removed from the preparation device 128 by means of removal device 156.
[00270] A fourteenth embodiment of a thermal preparation unit 126 shown in figure 17 differs from the first embodiment shown in figure 2, basically, in that the preparation unit 126 includes damping devices186, by means of of which auxiliary material loaded with pollutant and / or already prepared can be stored temporarily.
[00271] For this purpose, damping containers 188 of the damping devices 186 are provided.
[00272] A first damping container 188 serves to receive auxiliary material loaded with pollutant from filter unit 112.
[00273] By means of a conveying device 190, such as, for example, a helical conveyor, especially a cooling propeller or a helical heat exchanger, it is possible to conduct the pollutant-loaded auxiliary material from the damping container 188 to material auxiliary loaded with pollutant for preparation device 128.
[00274] Thus, the transport device 190 is a component of the supply device 158.
[00275] By means of the transport device 190, the auxiliary material loaded with pollutant, especially in the lower region 161 of the turbulent layer 140, can be conducted to the basic material of the turbulent layer and, consequently, to the turbulent layer 140 itself.
[00276] By means of another transport device 190, which, for example, is also configured as a helical conveyor, it is possible to carry prepared auxiliary material, which has been removed from the receptacle 132 of the preparation device 128 by means of a sink 192 , for another damping container 188 of another damping device 186.
[00277] Thus, the drain 192 and the other transport device 190 are components of the removal device 156.
[00278] Preparation unit 126 further includes a storage device 194 for storing fresh auxiliary material, a mixing device 196 for mixing prepared auxiliary material and fresh auxiliary material and / or a disposal device 198 for the disposal of auxiliary material too impure, especially auxiliary material too impure with pollutants.
[00279] The storage device 194 includes another damping container 188, in which, for example, it is possible to provisionally store a fresh auxiliary material supplied by means of trucks.
[00280] The mixing device 196 also includes a damping container 188, in which it is possible to provisionally store a mixture of fresh auxiliary material and prepared auxiliary material.
[00281] The fourteenth form of execution of the preparation unit 126 shown in figure 17 works as follows.
[00282] In filter unit 112, a stream of crude gas charged with pollutant is cleaned with the help of auxiliary material.
[00283] The auxiliary material thus loaded with pollutant has to be replaced or prepared after a certain period of use.
[00284] Such a preparation can be carried out using the thermal preparation unit 126.
[00285] For this, the auxiliary material loaded with pollutant is conducted from the filter unit 112 to a damping device 186, especially being temporarily stored in a damping container 188 for auxiliary material loaded with pollutant.
[00286] From there, the auxiliary material loaded with pollutant is transported, by means of the transport device 190, to the receptacle 132 of the preparation device 128.
[00287] Through the continuous supply of auxiliary material loaded with pollutant to the preparation device 128, the level, that is, the filling level, especially the level of the turbulent layer 140, is continuously increased. By means of the drain 192, the prepared auxiliary material which accumulates in the upper region 162 of the turbulent layer 140 is removed from the receptacle 132 of the preparation device 128 and is conveyed, through the other transport device 190, especially a helical heat exchanger, to the damping container 188 for the auxiliary material prepared. In this process, the auxiliary material is cooled to a maximum temperature of approximately 40 ° C, so that it can continue to be stored at room temperature and, eventually, it can be processed. Alternatively to the use of a helical heat exchanger, a heat exchanger of bulk material can be provided, in which a cooling occurs through flow bypassing heat exchanger tubes, or a pneumatic transport with or without heat exchanger integrated in a transportation pipeline.
[00288] From the damping container 188 for prepared auxiliary material and the damping container 188 for fresh auxiliary material, the respective auxiliary material is conveyed to the mixing device 196, especially to the damping container 188 of the mixing device 196. In that In this case, the mixture contains, for example, approximately 70% of prepared auxiliary material and approximately 30% of fresh auxiliary material.
[00289] Finally, the auxiliary material mixed by means of the mixing device 196 is taken to the filter unit 112 for new use.
[00290] The activation of the required gas streams, especially drafts, in the thermal preparation unit 126 preferably takes place by means of at least one fan, which especially overcomes all pressure losses in the preparation unit 126. In this case, for example, pressure losses can be between approximately 20 KPa (200 mbar) and approximately 30 KPa (300 mbar).
[00291] Moreover, the fourteenth form of execution of the preparation unit 126 shown in figure 17 coincides - in terms of construction and function - with the first form of execution shown in figure 2, in such a way that it will be taken as a reference to description of this made above.
[00292] In other embodiments, not shown, of thermal preparation units 126 it can be provided that one or more features of the described embodiments are optionally combined with each other.
[00293] In this sense, for example, it can be provided that the fourteenth embodiment of the thermal preparation unit 126 shown in figure 17 is provided with a further thermal combustion device 168 according to the third embodiment shown in figure 4.
[00294] Since in all forms of execution of thermal preparation units 126, the auxiliary material loaded with pollutant is thermally prepared and the auxiliary material prepared is separated, by means of gas flow, from the auxiliary material still loaded with pollutant, then the preparation of auxiliary material occurs in a particularly simple and resource-saving manner.

权利要求:
Claims (14)
[0001]
1. Process for the thermal preparation of an auxiliary material, which can be introduced into a stream of crude gas for cleaning the stream of crude gas charged with an organic pollutant and which, together with the organic pollutant, forms a stable system composed of pollutant and auxiliary material, including, where an auxiliary filter material is chosen as an auxiliary material, an auxiliary filter material is chosen, which is used to clean a stream of crude gas charged as a pollutant under the form of lacquer overspray, and the auxiliary filter material with the lacquer overspray forms a stable system, under normal conditions, formed by auxiliary filter material loaded with lacquer overspray, which can be sedimented in a filtering device , characterized by the fact that the process comprises: -conduction of the system formed by pollutant and auxiliary material and a carrier gas stream heated in relation to the conditions normal for a thermal preparation device (128); - chemical conversion of at least part of the organic pollutant to generate a prepared auxiliary material; - separation of the auxiliary material prepared from the auxiliary material loaded with an organic pollutant, by means of transport by means of gas flow; -removing the auxiliary material prepared from the thermal preparation device (128), the preparation device (128) being operated in such a way that a gradient is formed in the particle size distribution of the auxiliary material, the average being the distribution particle size increases downwards in the direction of the gravity force (160), with particles of the prepared auxiliary material, which accumulate in a superior region (162), in relation to the direction of the gravity force (160), of a turbulent layer (140) generated through turbulence or which are removed from the turbulent layer (140), are removed from the preparation device (128).
[0002]
2. Process according to claim 1, characterized by the fact that the preparation device contains a basic material of turbulent layer, which has a chemical composition that corresponds to the chemical composition of a material used as auxiliary material.
[0003]
3. Process according to claim 2, characterized by the fact that the average particle size distribution of the basic turbulent layer material is greater than the average particle size distribution of the auxiliary material that can be used for the cleaning of the raw gas stream and / or is greater than the average particle size distribution of the system formed by pollutant and auxiliary material.
[0004]
Process according to any one of claims 1 to 3, characterized in that the auxiliary material loaded with pollutant is heated in the preparation device (128) in such a way that the agglomerates of pollutant and auxiliary material are broken.
[0005]
Process according to any one of claims 1 to 4, characterized in that the auxiliary material loaded with pollutant is heated in the preparation device (128), in such a way that the pollutant is converted at least partially, while particles auxiliary material remain unchanged.
[0006]
Process according to any one of claims 1 to 5, characterized in that the auxiliary material loaded with pollutant is supplied to the turbulent layer (140) in a lower region (161), in relation to the direction of the force of gravity (160 ), a turbulent layer (140) generated by turbulence in the thermal preparation device (128).
[0007]
Process according to any one of claims 1 to 6, characterized in that particles of the system formed by pollutant and auxiliary material, particles of the prepared auxiliary material and / or particles of a basic material of turbulent layer, which accumulate in an upper region (162), in relation to the direction of the gravity force (160), of a turbulent layer (140) generated through a turbulence or that are removed from the turbulent layer (140), are removed from the preparation device (128 ).
[0008]
Process according to any one of claims 1 to 7, characterized by the fact that for the turbulence of the auxiliary material, the carrier gas stream is conducted, against the direction of the force of gravity (160), from bottom to top, through the auxiliary material, the carrier gas stream being conducted to a sedimentation device (152) and / or to a combustion device (166) before traversing the auxiliary material.
[0009]
Process according to any one of claims 1 to 8, characterized in that for the turbulence of the auxiliary material, the carrier gas stream is conducted, against the direction of the force of gravity (160), from the bottom upwards, through the auxiliary material, the carrier gas stream being conducted to a sedimentation device (152) and / or a combustion device (166) after traversing the auxiliary material.
[0010]
Process according to any one of claims 1 to 9, characterized in that particles of the auxiliary material are removed by means of the gas stream carrying a turbulent layer (140) generated through a turbulence in the thermal preparation device (128) and are separated by sedimentation to be removed from the preparation device (128) in a sedimentation device (152).
[0011]
11. Process according to any one of claims 1 to 10, characterized by the fact that for the turbulence of the auxiliary material, the carrier gas stream is conducted against the direction of the force of gravity (160), from bottom to top, through the auxiliary material, and before and / or after traversing the auxiliary material, the carrier gas stream is conducted to a heat exchanger (164) and / or to a drying device (180) for drying the parts working (104).
[0012]
12. Launting unit for workpieces (104), especially vehicle bodies, including: -a sterilizing device (102), through which the workpieces (104) can be lacquered with lacquer; -a filtering device (114) for cleaning a stream of crude gas, charged with lacquer overspray and generated in the sterilization device (102), by conducting auxiliary filter material for the crude gas stream and separation by sedimentation of the lacquer overspray together with the filter aid material in a filter element (120) of the filtering device (114); and -a preparation unit (126) for thermal preparation of the filter aid material, which can be separated from the filtering device characterized by the fact that the preparation unit (126) comprises: -a thermal preparation device (128) for the chemical conversion of at least part of the lacquer overspray, to generate a prepared auxiliary material; -a feeding device (158) for conducting the system formed by lacquer overpray and auxiliary filter material and a carrier gas stream, heated in relation to normal conditions, for the thermal preparation device (128), the thermal preparation device (128) is formed and adjusted for such operation, with a gradient in the particle size distribution being formed, in which the average of the particle size distribution increases downwards in the direction of gravity (160); -a separation device (157) for the separation of the filter aid material prepared from the filter aid material loaded with a lacquer overspray, through transport by means of gas flow; -a removal device (156) for the removal of the prepared auxiliary material out of the preparation device (128), and by means of the removal device (156), particles of the filtering auxiliary material in an upper region (162) with respect to the direction of the gravity force (160), of a turbulent layer (140) generated through a turbulence of the auxiliary material in the thermal preparation device (128), can be removed from the thermal preparation device (128).
[0013]
A sterilization unit according to claim 12, characterized in that the preparation device (128) is formed as a turbulent layer oven (130).
[0014]
The sterilization unit according to claim 12 or 13, characterized in that the preparation unit (126) comprises a sedimentation device (152) and / a combustion device (166), in which the gas stream carrier can be supplied after the flow through the preparation device (128).

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法律状态:
2017-08-08| B25D| Requested change of name of applicant approved|Owner name: DUERR SYSTEMS AG (DE) |

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2018-03-27| B15K| Others concerning applications: alteration of classification|Ipc: B01D 53/44 (2006.01), B01D 37/02 (2006.01), B01D 4 |

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2018-04-03| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|

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2018-05-15| B15K| Others concerning applications: alteration of classification|Ipc: B05B 14/40 (2018.01), B05B 14/43 (2018.01), B05B 1 |

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2020-03-24| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|

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2020-10-06| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|

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2020-10-20| B09W| Correction of the decision to grant [chapter 9.1.4 patent gazette]|Free format text: RETIFICACAO DO DEFERIMENTO NOTIFICADO NA RPI 2596 DE 06/10/2020. |

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2020-11-24| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 31/10/2012, OBSERVADAS AS CONDICOES LEGAIS. |

优先权:

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申请号 | 申请日 | 专利标题

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DE202011107555.2|2011-11-02|

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DE202011107555U|DE202011107555U1|2011-07-27|2011-11-02|filter system|

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EPPCT/EP2012/058167|2012-05-03|

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PCT/EP2012/058167|WO2013013848A1|2011-07-27|2012-05-03|Filter facility and method for operating a filter facility|

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DE102012219692.7|2012-10-26|

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DE102012110243A|DE102012110243A1|2011-11-02|2012-10-26|Filter system for use in paint shop for coating workpieces such as vehicle body, has processing device that is provided for processing paint overspray and filter aid material|

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DE102012110243.0|2012-10-26|

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DE102012219692A|DE102012219692A1|2011-11-02|2012-10-26|Filter system for use in paint shop for coating workpieces such as vehicle body, has processing device that is provided for processing paint overspray and filter aid material|

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PCT/EP2012/071627|WO2013064575A1|2011-11-02|2012-10-31|Method for the thermal preparation of an auxiliary material and preparation unit|

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