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    • 专利摘要:
    high-strength hot-dip galvanized steel sheet. this refers to a sheet of high-strength hot-dip galvanized steel that includes a sheet of steel that comprises major components and contains at least 40% by volume of the sum of bainite and martensite, 8-60% by volume of retained austenite and less than 40% by volume of ferrite, with the remainder comprising an incidental structure. the hot-dip galvanized steel sheet has, at its interface, an intermetallic compound (average thickness of 0.1-2 [mu] m and crystal grain diameter of 0.01-1 [mu] m) consisting of fe, al , zn and incidental impurities. after the deposit layer formed by hot-dip galvanizing has been removed, the surface of the base steel sheet has an arithmetic mean of roughness ra of 0.1-2.0 [mu] gives me a roughness curve in which the contour elements have an average rsm length of 5-300 [mu] m. in this way, a sheet of high-strength hot-dip galvanized steel is provided which includes a sheet of high-strength steel as the base and which has excellent plasticity that can inhibit cracking or rupture.
    公开号:BR112014007514B1
    申请号:R112014007514-0
    申请日:2012-09-28
    公开日:2020-09-15
    发明作者:Koichi Sato；Shintaro Yamanaka；Soshi Fujita
    申请人:Nippon Steel Corporation；
    IPC主号:
    专利说明:

    TECHNICAL FIELD
    [001] The present invention relates to a high-strength hot-dip galvanized steel sheet. More specifically, the present invention relates to a high-strength hot-dip galvanized steel sheet, which can easily achieve high strength (for example, a tensile strength of 980 MPa or higher), which has excellent plasticity and which can be used properly as a member of the auto field, the home appliance field, the building material field and the like. BACKGROUND OF THE TECHNIQUE
    [002] Until now, a hot-dip galvanized steel sheet has been used mainly in the automobile field. However, in the case of a hot-dip galvanized steel sheet that uses, as the substrate, a high-strength steel sheet (for example, a tensile strength of 980 MPa or higher), a crack can easily occur particularly in the underlying steel plate during a rigorous processing of the same as in a flexion and a concentration of stress on that part can cause a fracture in many cases.
    [003] From this point of view, for example, Patent Document 1 proposed to reduce the amount of Si enrichment on the surface of a steel sheet before immersing it in a deposition bath, to a certain value or less, by control of an annealing atmosphere. However, it has been difficult to control such an annealing atmosphere.
    [004] In addition, Patent Document 2 describes a high-strength steel sheet in which Si + AI satisfies 0.7% or higher and where as the steel sheet structure, the area ratio of the total amount of lower bainite and total martensite for the complete structure of the steel plate is from 10 to 90%, the amount of austenite retained (or residual) is from 5 to 50% and the proportion of the area of bainite ferrite in the upper bainite for the complete steel plate structure is 5% or higher. Patent Document 3 describes a hot-dip galvanized alloy steel sheet that has a microstructure that contains, in terms of area ratio, from 20 to 75% ferrite and from 5 to 25% retained austenite, in which the average ferrite crystal grain size is 10 pm or less. Patent Document 4 describes a hot-dip galvanized alloy steel sheet that has formed on the surface of the same, starting on the side of the steel sheet, an r phase, a mixed layer of T1 and δ1 phase and a δ1 or a δ1 phase and a Ç phase, where the average thickness of phase r is 1.5 pm or less, an average thickness of the mixed layer of phase T1 and phase δ1 is less than twice the average thickness of phase Tea average aspect ratio (ratio of the long side to the short side under observation in the cross section) of H crystal is 2 or higher.
    [005] In addition, Patent Document 5 describes a hot-dip galvanized alloy steel sheet in which the hot-dip galvanized alloy layer has a chemical composition containing, in mass%, Fe: from 10 to 15% and Al: from 0.20 to 0.45, with the remainder being Zn and impurities and the adhesion resistance at the interface between the steel sheet and the hot-dip galvanized alloy layer is 20 MPa or higher. Patent Document 6 describes a hot-dip galvanized alloy steel sheet with excellent impact and adhesion resistance, which has a coating weight of 20 to 100 g / m2 on one surface or on both surfaces, where the average content of Fe of the deposition layer is from 8 to 16% and the thickness of phase r in the deposition layer is from 0.2 to 1.5 pm. Patent Document 7 describes a hot-dip galvanized steel sheet that has a galvanized film in which a layer of Fe-AI based alloy, a layer of Fe-Zn based alloy and a layer of zinc are present in this order starting from the side of the base steel plate, where the Al content in the Fe-AI based alloy layer is from 10 to 300 mg / m2 and the thickness of the Fe-Zn based alloy layer is 1 / 2 or less of the thickness of the galvanized film. Patent Document 8 describes a hot-dip galvanized steel sheet in alloy, in which the number of ferro-zinc alloy crystals in contact with the film / base iron deposition interface is 5.5 or higher per 1 pm of the interface.
    [006] However, in relation to a high-strength steel sheet that has a high strength (for example, a tensile strength of 980 MPa or higher), a hot-dip galvanized steel sheet that exhibits enough effect. RELATED TECHNIQUE PATENT DOCUMENTS [Patent Document 1] JP-A (Unexamined Japanese Patent Publication; KOKAI) No. 4-211887 [Patent Document 2] Jp_AN ° 2010-65273 [Patent Document 3] jp.A No 2011-17046 [Patent Document 4] jp.A No IQ-306360 [Patent Document 5] jp.A No 2006-97102 [Patent Document 6] jp_A No 5.93402 [Patent Document 7] jp_A No 2006-307302 [Patent Document 8] jp_A N0 2000-144362 SUMMARY OF THE INVENTION PROBLEM TO BE SOLVED BY THE INVENTION
    [007] An objective of the present invention is to provide a hot-dip galvanized steel sheet comprising, as the substrate, a high-strength steel sheet that has a high strength (for example, a tensile strength of 980 MPa or higher ), which is a high-strength hot-dip galvanized steel sheet that is capable of effectively suppressing a crack or fracture and is excellent in plasticity. MEANS TO SOLVE THE PROBLEM
    [008] As a result of prudent study, the present inventors found that an intermetallic compound composed mainly of Fe, Al and Zn is deposited at a thickness in a predetermined range on an interface between the hot-dip galvanized layer and an underlying steel plate and in addition, the contents of Ra and RSm on the surface of the steel sheet after the removal of the hot-dip galvanized layer are controlled to decrease a predetermined range, the plasticity of which can be improved, while suppressing a crack or fracture of the steel plate during rigorous processing.
    [009] Thus, the present invention relates to a hot-dip galvanized steel sheet of high strength, which has excellent plasticity. The present invention can include, for example, the following modalities. [1] A hot-dip galvanized steel sheet, which is a steel sheet comprising, in% by weight, C: from 0.10 to 0.4%, Si: from 0.01 to 0.5%, Mn : from 1.0 to 3.0%, O: 0.006% or less, P: 0.04% or less, S: 0.01% or less, Al: from 0.1 to 3.0% and N: 0.01% or less, with the rest being Fe and unavoidable impurities,
    [0010] in which the steel plate structure also comprises, in terms of volume fraction, 40% or more of the total content of bainite and martensite, from 8 to 60% of retained austenite and less than 40% of ferrite , with the rest being an unavoidable structure and hot dip galvanizing is applied to the surface of the steel sheet and the hot galvanized steel sheet has a layer of an intermetallic compound composed of Fe, Al, Zn and unavoidable impurities at the interface between the hot-dip galvanized sheet steel layer and the underlying steel sheet, the average thickness of the intermetallic compound is 0.1 to 2 pm or less and the crystal grain size of the intermetallic compound is 0.01 or higher up to 1 pm or less and the arithmetic mean of the roughness Ra of the underlying surface of the steel sheet after removal of the hot-dip galvanized layer is 0.1 or higher up to 2.0 pm or less and the average length RSm of the element of the contour curve in the roughness curve is 5 or higher up to 3 00 pm or less. [2] Hot-dip galvanized steel sheet according to [1], where the steel sheet also comprises one element or two or more elements of, in mass%, Cr: from 0.05 to 1.0% , Ni: from 0.05 to 1.0%, Cu: from 0.05 to 1.0%, Nb: from 0.005 to 0.3%, Ti: from 0.005 to 0.3%, V: from 0.005 to 0.5%, B: from 0.0001 to 0.01%, Ca: from 0.0005 to 0.04%, Mg: from 0.0005 to 0.04%, La: from 0.0005 to 0, 04%, Ce: from 0.0005 to 0.04% and Y: from 0.0005 to 0.04%. [3] A process for the production of a hot-dip galvanized steel sheet, comprising: heating a steel material comprising, in% by mass, C: from 0.10 to 0.4%, Si: from 0, 01 to 0.5%, Mn: from 1.0 to 3.0%, O: 0.006% or less, P: 0.04% or less, S: 0.01% or less, Al: from 0.1 to 3 , 0% and
    [0011] N: 0.01% or less, with the remainder being Fe and unavoidable impurities, at 1,100 to 1,300 ° C and then subjecting the steel sheet to a hot rolling treatment at a rolling laminating temperature for finishing temperature Ar3 or higher;
    [0012] stretching (taking up) a hot rolled steel sheet at a stretching temperature of 700 ° C or less and then cold rolling the steel sheet;
    [0013] annealing of cold rolled steel sheet at a maximum heating temperature of 750 to 900 ° C;
    [0014] cooling of the annealed steel sheet to a dip bath temperature at a cooling rate of 3 to 200 ° C / second in the range 500 to 750 ° C and then keeping the steel sheet at 350 to 500 ° C for 10 to 1,000 seconds;
    [0015] performing a deposition treatment by immersing the steel sheet in a hot dip galvanizing bath that has a concentration of Al WAI and a concentration of Fe WFΘ that satisfies, in mass%, the following relationship expressions (1) and (2), at a temperature of the steel plate in the range of, immersed in a deposition bath, from from the temperature of 40 ° C lower than the temperature of the hot dip galvanizing bath to a temperature of 50 ° C higher than the temperature of the hot dip galvanizing bath, in a nitrogen atmosphere that has a nitrogen content of 95% by mass or higher, where the logarithm value log (PH2o / PH2) of the ratio between the partial pressure of hydrogen PH2 and the partial pressure of water vapor PH2O is from -5 to -2: 0.01 <WFΘ <0.05 (1) 0.07 <(WAi-WFe) <0.30 (2)
    [0016] on the cylinder surface of the final position in cold rolling, the arithmetic mean of the roughness Ra is 0.1 or higher up to 8.0 pm or less and the average length RSm of the contour curve element on the roughness is 5 or higher up to 1,200 pm or less,
    [0017] where Ar3 = 901-325xC + 33xSi- 92x (Mn + Ni / 2 + Cr / 2 + Cu / 2 + Mo / 2), where C, Si, Mn, Ni, Cr, Cu and Mo indicate the contents (% by mass) of the respective components and 0 when the component is not contained.
    [0018] [4] The process for the production of high-strength hot-dip galvanized steel sheet according to [3], where on the surface of a cylinder in a stage before the final position in cold rolling, the arithmetic mean of the Ra roughness is 0.1 or higher up to 8.0 pm or less and the average length RSm of the contour curve element in the roughness curve is 5 or higher up to 1,200 pim or less. EFFECT OF THE INVENTION
    [0019] The present invention can provide a hot-dip galvanized steel sheet that has excellent plasticity. The production of the high-strength hot-dip galvanized steel sheet according to the present invention can be relatively easy and can be carried out in a stable manner. Therefore, the hot-dip galvanized steel sheet of high strength can be used in the best way particularly as a steel sheet for automobiles in recent years, with the intention of achieving weight reduction. As a result, its industrial value can be remarkably high. BRIEF DESCRIPTION OF THE DRAWINGS
    [0020] [Fig. 1] Fig. 1 is a graph showing a relationship between the thickness and the particle size of an intermetallic compound and plasticity. In the figure, graphical comparisons of A, B, C and D represent the results of the assessment that refer to the plasticity described last; all of A, B and C have Examples where plasticity passes and D presents Comparative Examples where plasticity fails.
    [0021] [Fig. 2] Fig. 1 is a graph showing a relationship between the underlying steel sheet roughness and plasticity. In the figure, graphical comparisons of A, B, C and D represent the results of the assessment that refer to the plasticity described last; all of A, B and C have Examples where plasticity passes and D presents Comparative Examples where plasticity fails. MODES FOR CARRYING OUT THE INVENTION
    [0022] Hereinafter, the present invention is described in sequence.
    [0023] First, the reasons for limiting the components are described. In this connection, "%" means% by mass. Ç:
    [0024] C can be an element capable of increasing the strength of a steel plate. However, if its content is less than 0.1%, it can be difficult to satisfy both the tensile strength of 980 MPa or higher and practicality. On the other hand, if the content exceeds 0.40%, the welding capacity on site can hardly be guaranteed. For this reason, the content is adjusted to be from 0.1 to 0.40% or less. The C content can preferably be from 0.12 to 0.3, more preferably from 0.13 to 0.28% Si:
    [0025] Si can be a reinforcing element and can be effective in increasing the strength of a steel sheet. In addition, this element can suppress cementite precipitation and, in turn, contribute to the stabilization of retained austenite and therefore, its addition may be indispensable. If its content is less than 0.01%, the effect of increased strength may be small. On the other hand, if the content exceeds 0.5%, practicality can be reduced. For this reason, the Si content is adjusted to be from 0.01 to 0.5%. The Si content can preferably be from 0.05 to 0.45%, more preferably from 0.15 to 0.42%. Mn:
    [0026] Mn can be a reinforcing element and can be effective in increasing the strength of a steel sheet. However, if its content is less than 1.0%, the tensile strength of 980 MPa or higher can be difficult to obtain. On the other hand, if the content is high, co-segregation with P or S can be promoted to involve a significant deterioration in practicality and therefore an upper limit of 3.0% is specified. For this reason, the Mn content is adjusted to be from 1.0 to 3.0%. The Mn content can preferably be from 2.0 to 2.7%, more preferably from 2.03 to 2.6%. THE:
    [0027] O can form an oxide and deteriorate elongation, flexibility and orifice expansion capacity and therefore the added amount of this element needs to be kept low. Among others, an oxide often exists as an inclusion and when the oxide is present in the perforated face or on the cut surface, a notch gap or a coarse undulation on the end face may be formed to invite the concentration of effort during the orifice expression or rigorous processing and serves as a source of crack formation, giving rise to a significant deterioration in orifice expandability or flexibility. If the O content exceeds 0.006%, the trend described above can be conspicuous and therefore the O content is specified at an upper limit of 0.006% or less. That is, O is limited as an impurity up to 0.006% or less. The O content may preferably be 0.004% or less, more preferably 0.003% or less. On the other hand, an O content of less than 0.0001% can be economically disadvantageous because of the involvement of an excessive rise in cost and therefore, this value can be substantially the lower limit. P:
    [0028] The P can tend to be segregated in the center in the thickness of a steel plate and cause the rupture of a welded part. If its content exceeds 0.04%, a significant break in the welded part can occur and plasticity is also reduced. Therefore, an appropriate content range of 0.04% or less is specified. That is, P is limited as an impurity to 0.04% or less. The P content can preferably be 0.03% or less, more preferably 0.025% or less. The lower limit of P may not be particularly specified, but a content less than 0.0001% can be economically disadvantageous and therefore this value can preferably be adjusted as the lower limit. S:
    [0029] S can adversely affect weldability and manufacturing feasibility during casting and hot rolling. For this reason, the upper limit of its content is adjusted to 0.01% or less. That is, S is limited as an impurity to 0.01% or less. The S content can preferably be 0.006% or less, more preferably 0.005% or less. The lower limit of the S content may not be particularly specified, but a content less than 0.0001% can be economically disadvantageous and therefore, this value can preferably be adjusted as the lower limit. In addition, since S can be linked to Mn to form coarse MnS and deteriorate plasticity such as orifice flexibility or expandability, the content of this element needed to be adjusted as low as possible. Al:
    [0030] Al can promote the formation of ferrite to improve ductility and therefore can be added. This element can also be used as a deoxidizing agent. If its content is less than 0.1%, the effect of the element may be insufficient. On the other hand, its excessive addition can lead to an increase in the number of coarse inclusions based on Al and give rise to the deterioration of the expansion capacity of the orifice or to cause a surface failure. For this reason, the upper limit of the Al content is adjusted to be 3.0%. The Al content can preferably be from 0.2 to 1.5%, more preferably from 0.3 to 1.0%. N:
    [0031] N can form a coarse nitride to deteriorate the orifice's flexibility or expandability and therefore the added amount of it needs to be kept low. If the N content exceeds 0.01%, the above trend may be conspicuous and therefore the N content range is adjusted to 0.01% or less. The N content can preferably be 0.007% or less, more preferably 0.005% or less. From the point of view of reducing the formation of an orifice for insufflation during welding, the content of can be lower. Although the effects according to the present invention can be achieved without specifying the lower limit particularly, an N content of less than 0.0005% can involve a large increase in the production cost and therefore this value can be substantially the lower limit . Cr:
    [0032] Cr can be a reinforcement element and at the same time, it can be important to improve the attenuation capacity. However, if their content is less than 0.05%, these effects may not be achieved and therefore, a lower limit of 0.05% is specified. On the contrary, the fact that it contains this element in excess of 1.0% can adversely affect the manufacturing capacity during production and hot rolling and therefore an upper limit of 1.0% is specified. The Cr content can preferably be 0.6% or less, more preferably 0.5% or less. Ni:
    [0033] Ni can be a reinforcing element and at the same time, it can be important in improving the extinguishing capacity. In addition, this element can improve the wettability of the molten metal or promote a reaction and therefore can be added. However, if their content is less than 0.05%, these effects may not be achieved and therefore, a lower limit of 0.05% is specified. On the contrary, the fact that it contains this element in excess of 1.0% can adversely affect the manufacturing capacity during production and hot rolling and therefore an upper limit of 1.0% is specified. The Ni content can preferably be 0.7% or less, more preferably 0.6% or less. Ass:
    [0034] Cu can be a reinforcing element and at the same time, it can be important to improve the extinguishing capacity. In addition, this element can improve the wetting ability of molten metal or promote a reaction and therefore can be added. However, if their content is less than 0.05%, these effects may not be achieved and therefore, a lower limit of 0.05% is specified. On the contrary, the fact that it contains this element in excess of 1.0% can adversely affect the manufacturing capacity during production and hot rolling and therefore an upper limit of 1.0% is specified. The Cu content may preferably be 0.6% or less, more preferably 0.5% or less. Nb:
    [0035] Nb can be a reinforcing element and can contribute to increase the resistance of the steel sheet by reinforcing precipitation, reinforcing the fine grain by suppressing the growth of a ferrite crystal grain and reinforcing the displacement by suppressing the recrystallization. If the amount added is less than 0.005%, these effects cannot be achieved and therefore a lower limit of 0.005% is specified. If this element is contained in excess of 0.3%, the amount of precipitated carbonitride can be increased to deteriorate plasticity and therefore an upper limit of 0.3% is specified. The Nb content can preferably be 0.25% or less, more preferably 0.20% or less. You:
    [0036] Ti can be a reinforcing element and can contribute to increase the strength of the steel sheet by reinforcing precipitation, reinforcing the fine grain by suppressing the growth of a ferrite crystal grain and strengthening the displacement by suppressing recrystallization . If the amount added is less than 0.005%, these effects may not be achieved and therefore a lower limit of 0.005% is specified. If this element is contained in excess of 0.3%, the amount of precipitated carbonitride can be increased to deteriorate plasticity and, therefore, an upper limit of 0.3% is specified. The Ti content can preferably be 0.25% or less, more preferably 0.20% or less. V:
    [0037] OV can be a reinforcing element and can contribute to increase the strength of the steel sheet by reinforcing precipitation, reinforcing the fine grain by increasing the suppression of a ferrite crystal grain and strengthening the displacement by suppressing the recrystallization. dog. If the amount added is less than 0.005%, these effects may not be achieved and therefore a lower limit of 0.005% is specified. If this element is contained in excess of 0.5%, the amount of precipitated carbonitride can be increased to deteriorate plasticity and therefore an upper limit of 0.5% is specified. The V content may preferably be 0.45% or less, more preferably 0.3% or less.
    [0038] The addition of B in an amount of 0.0001% or higher can be effective in reinforcing a grain limit or increasing the strength of the steel material, however if the amount added exceeds 0.01%, not only the effect can be saturated but also the manufacturing capacity during hot rolling can be reduced and therefore an upper limit of 0.01% is specified.
    [0039] One element or two or more elements selected from Ca, Mg and REM can be added in a total amount of 0.0005 up to 0.04%. Ca, Mg and REM can be an element used for deoxidation and it may be preferable to contain one element or two or more elements thereof in a total amount of 0.0005% or higher. In this case, REM is Metal Terra Rara. However, if the total content of Ca, Mg and REM exceeds 0.04%, the degradation of feasibility formation can be caused. For this reason, its total content is adjusted to be from 0.0005 to 0.04%.
    [0040] Incidentally, in the present invention, REM can be added in the form of Mischmetal in many cases and it may be a case in which a combination of elements in the lantanoid series besides La and Ce is contained. Even when such elements in the lantanoid series other than La and Ce are contained as unavoidable impurities, the effects according to the present invention can be provoked. In this connection, the effects according to the present invention can also be provoked even when metallic La and Ce are added.
    [0041] The structure of the steel material can be described below.
    [0042] In the steel sheet according to the present invention, the total content of bainite and martensite needed to be 40% or higher. Bainite and martensite may be necessary to ensure elongation and strength. The lower limit of its total percentage content is established up to 40%, because if the volume fraction of the total content is less than 40%, its effect is weak.
    [0043] The steel sheet according to the present invention must contain, in terms of volume fraction, from 8 to 60% of retained austenite. Because it contains retained austenite, an increase in resistance and an improvement in ductility can be achieved at the same time. If the volume fraction is less than 8%, the above effect can hardly be achieved and therefore a lower limit of 8% or higher is specified. An upper limit of 60% or less is specified, because its volume fraction exceeds 60%, the volume fraction of bainite or martensite can be less than 40% and sufficient elongation and strength cannot be guaranteed. The volume fraction of retained austenite (y) can preferably be from 9 to 40%, more preferably from 10 to 30%.
    [0044] The ferrite content needs to be less than 40%. Ferrite can improve ductility, but if the content is 40% or higher, strength cannot be guaranteed. Like the form of ferrite, ferrite can be incorporated without being polygonal ferrite.
    [0045] Furthermore, the inevitable structure of the remainder as used in the present invention indicates a pearlite structure.
    [0046] Regarding the microstructure phases described above, ferrite, martensite, bainite, austenite, pearlite and the remaining structure, identification, observation of existing position and measurement of the area proportion can be performed using a NITAL reagent (nitric acid and alcohol) and a reagent published in JP-A N °. 59-219473 for the attack of the steel plate in the cross section of the rolling direction or in the cross section in the direction perpendicular to the rolling direction and making a quantitative determination by observation through an optical microscope 1,000 times and scanning electron microscopes and transmission time from 1,000 to 100,000 times. After observing 20 or more fields for each, the proportion of the area of each structure can be determined by a method of counting points or by image analysis.
    [0047] The constitution of the hot-dip galvanized layer can be described below.
    [0048] In the hot-dip galvanized steel sheet of the present invention, an intermetallic compound composed of Fe, Al, Zn and unavoidable impurities is present in an average thickness of 0.1 to 2 pm at the interface between the hot-dip galvanized layer and a underlying steel plate. In addition, the crystal grain size of the intermetallic compound is from 0.01 to 1 pm, the arithmetic mean of the roughness Ra of the underlying surface of the steel sheet after removal of the hot-dip galvanized layer is from 0.1 to 2.0 pm and the average length RSm of the contour curve element in the roughness curve is from 5 to 300 pm.
    [0049] The intermetallic compound composed of Fe, Al, Zn and unavoidable impurities may be necessary to suppress a fracture of the underlying steel sheet. The reason for this may not necessarily be clear, but according to the knowledge of the present inventors, it can be assumed that the intermetallic compound cracks in a finely dispersed manner during bending work and thus produces an effect of preventing concentration of stress on the cracked part of the underlying steel plate.
    [0050] As shown in Fig. 1, if the thickness of the intermetallic compound is less than 0.1 pm, the effect of the compound may be weak, whereas if the thickness exceeds 2 pm, the intermetallic compound itself may not be finely cracked and a local crack can be generated, making it impossible to relieve stress concentration. For this reason, the thickness of the intermetallic compound is from 0.1 to 2 pm. The thickness can preferably be from 0.2 to 1.5 pm, more preferably from 0.4 to 1 pm.
    [0051] Furthermore, as noted similarly by Fig. 1, the average crystal grain size of the intermetallic compound needs to be from 0.01 to 1 pm. If the average size of the crystal grain exceeds 1 pm, the intermetallic compound may not form a fine crack, but it may form a local cleavage and stress concentration in that part can easily occur. The grain size can be preferably smaller, but if the grain size is less than 0.01 pm, not only the effect of the compound can be saturated but also the production load to guarantee a thickness of 0.1 pm or higher can be increased. For this reason, the average crystal grain size of the intermetallic compound is from 0.01 to 1 pm. The average crystal grain size may preferably be from 0.01 to 0.8 pm, more preferably from 0.01 to 0.5 pm.
    [0052] The process for measuring the thickness of the intermetallic compound can include several methods and include, for example, "Microscopic Cross-Sectional Test Method" (JIS H 8501). This can be a method in which the cross section of the sample is encrusted, polished and then, if desired, etched with a caustic substance and the polished surface is analyzed by an optical microscope, a scanning electron microscope (SEM), a micro analyzer electron beam (EPMA) or similar to determine thickness.
    [0053] In the present invention, the sample was embedded in Technovit 4002 (produced by Maruto Instrument Co., Ltda), polished with polishing papers (JIS R 6001) # 240, # 320, # 400, # 600, # 800 and # 1000 in this order and a part of the corresponding polished face and the deposition layer until the depth of 5 pm of the underlying steel sheet is observed with EPMA using a linear analysis along a direction perpendicular to the interface between the de -position and the underlying steel plate, to thereby determine the thickness.
    [0054] Under this association, the thickness of the intermetallic compound as used in this case can mean a value obtained by determining the thickness of the intermetallic compound in a deposition layer to 10 arbitrary parts spaced from each other by 1 mm or more and calculating the average of the determined thicknesses of the intermetallic compound. The composition and structure of the intermetallic compound may be different from that of the Ç (FeZnn) phase, the δi (FeZm) phase, the Ti phase (FesZn2i) and the r phase (FesZnw) which are Fe, Zn and Fe alloy phase -Zn. Therefore, the intermetallic compound can be identified by analysis using EPMA, an X-ray diffraction method (XRD), a transmission electron microscope (TEM) or similar.
    [0055] In the present invention, the species of each alloy phase was identified by TEM analysis (the same analysis as those described, for example, in Hong, MN and Saka, H., Proc. 4th Intern. Conf. On Zn and Zn Alloy Coated Steel Sheet, Galvatech '98. P. 248, 1998 and Kato, T., Hong, MH, Nunome, K., Sasaki, K., Kuroda, K. and Saka, H., Thin Solid Films , 319, 132, 1998). For details of the MET analysis method, these publications can be cited, if desired.
    [0056] The crystal grain size of the intermetallic compound can be measured by several methods, however in the present invention, the crystal grain size can be measured by the following method. First, a sample can be produced by immersing the steel sheet of the present invention in steaming nitric acid to dissolve and remove the hot-dip galvanized layer. The length of time that the steel sheet is immersed can vary depending on the thickness of the deposition layer, but a bubble can be generated by a corrosion reaction of the deposition layer during dissolution and the bubble can stop the occurrence when finished dissolution. Therefore, immersion can be interrupted by the disappearance of the bubble. As the intermetallic compound can be difficult to dissolve in fuming nitric acid, the crystal grain size of the remaining intermetallic compound can be measured by observing the sample surface after dissolving and removing the deposition layer by SEM 50,000 times. However, the size of the crystal grain of the intermetallic compound as used in this case can mean an average value of diameters obtained by determining the diameter of a crystal grain (when the crystal grain is a polygonal grain, the diameter of a circle assuming a minimum circle including the crystal grain) over 10 arbitrary crystal grains of intermetallic compound in the visual field of SEM observation).
    [0057] In addition, the surface of the underlying steel plate after removing the hot-dip galvanized layer needs to have a certain degree of roughness. The reason for this may be because when the surface of the underlying steel sheet is almost smooth, the anchor effect of the intermetallic compound to a surface of the underlying steel sheet may be insufficient and the intermetallic compound can be easily separated during work , failing to offer any effect on preventing the fracture of the underlying steel sheet. This effect can be exerted when, as shown in Fig. 2, the arithmetic mean of the roughness Ra of the underlying steel sheet surface is 0.1 pm or greater. On the other hand, if Ra exceeds 2 p.m, the lack of uniformity can inversely produce a part on which the effort is concentrated, as a result, a fracture can easily occur. For this reason, Ra is from 0.1 to 2.0 pm. Ra can preferably be from 0.2 to 1.0 pm.
    [0058] In the present invention, the average length RSm of the contour curve element in the roughness curve needs to be in a certain range. As shown in Fig. 2, if RSm exceeds 300 py, the surface may become almost smooth and the anchor effect may be insufficient. RSm can be preferably less, but if it is less than 5 pm, the effect of it can be saturated and only an unnecessary increase in production cost can be involved. For this reason, RSm is from 5 to 300 pm. RSm can preferably be from 10 to 200 pm.
    [0059] Incidentally, Ra and RSm as used in this case can mean an arithmetic mean of the roughness and the average length of the roughness curve element, respectively, which are defined in JIS B 0601.
    [0060] In their measurements, the deposition layer can be removed by treating the hot-dip galvanized steel sheet with a hydrochloric acid containing an inhibitor to expose the underlying steel sheet surface and the roughness of the steel sheet surface. can then be measured. For example, in the present invention, the hot-dip galvanized steel sheet was immersed in a solution prepared by adding 0.02% IBIT 700A (produced by Asahi Chemical Co., Ltda) as an inhibitor to a 5% aqueous solution of hydrochloric acid, to which the underlying steel plate surface was exposed.
    [0061] The length of time the steel sheet is immersed can vary depending on the thickness of the deposition layer, but a bubble can be generated by a corrosion reaction of the deposition layer during dissolution and the bubble can stop the occurrence when dissolution is complete. Therefore, immersion can be interrupted by the disappearance of the bubble. As the surface of the underlying steel sheet can be difficult to dissolve due to the action of the inhibitor, a sample with the surface of the underlying steel sheet that is exposed can be obtained by the method above. Subsequently, the surface was measured to determine Ra and RSm by Handy Surf E-40A (manufactured by Tokyo Seimitsu Co., Ltd.) under the conditions of an evaluation length of 4 mm and a drilling value of 0.8 mm.
    [0062] The production process of high-strength hot-dip galvanized steel sheet with excellent plasticity according to the present invention can be described below. In the present invention, the production process prior to hot rolling may not be particularly limited. Namely, several types of secondary refining can be carried out subsequent to melting in a blast furnace, in an electric oven or the like and after that, casting can be carried out by normal continuous casting, by casting by an ingot method, casting of thin plate or by other methods. In the case of continuous casting, the steel can once be cooled to a low temperature, heated again and then hot rolled or the molten plate can be hot rolled continuously. Scrap scrap can be used for the raw material.
    [0063] The effects according to the present invention can be caused without specifying particularly the heating temperature of the hot-rolled plate. However, an excessively high heating temperature may not be economically preferred and therefore, the upper limit of the heating temperature may preferably be less than 1,300 ° C. In addition, if the heating temperature is excessively low, the finishing laminating temperature can hardly be controlled until the Ar3 temperature or higher and therefore, the lower temperature limit can preferably be 1,100 ° C.
    [0064] If the finishing lamination temperature enters the two-phase region of austenite + ferrite, the structural non-uniformity in the steel plate can be increased to deteriorate the plasticity after annealing. For this reason, the finishing laminating temperature can preferably be the temperature of Ar3 or higher. Incidentally, the temperature of Ar3 can be calculated according to the following formula:
    [0065] Ar3 = 901-325xC + 33xSi-92x (Mn + Ni / 2 + Cr / 2 + Cu / 2 + Mo / 2)
    [0066] Cooling after lamination may not be particularly specified and the effects according to the present invention can be obtained even when a cooling pattern is employed to achieve the respective control combination purposes.
    [0067] The stretching temperature must be 700 ° C or less. If the stretching temperature exceeds 700 ° C, not only a coarse ferrite or pearlite structure can be allowed to exist in the hot-rolled structure, but also the non-uniformity of the structure after annealing tends to become large, leading to an increase anisotropy of the final product material. In the present invention, it may be preferable to improve the resistance-ductility balance by making the structure thin after annealing. In addition, a stretching temperature that exceeds 700 ° C may not be preferred, because the thickness of an oxide formed on the surface of the steel sheet can be increased excessively and, in turn, the stripping effect may be weak . Although the effects according to the present invention can be brought about without specifying the lower limit particularly, stretching at a temperature no more than the ambient temperature can be technically difficult and therefore this temperature can be substantially the lower limit. Incidentally, in hot rolling, the finishing lamination can be carried out continuously by gathering the raw rolled sheets. In addition, the raw rolled sheet can be stretched once.
    [0068] The steel sheet after hot rolling can usually be subjected to the removal of scale on the surface by a pickling treatment. Stripping can be carried out once or stripping can be carried out in a large number of parts.
    [0069] The hot rolled steel sheet after pickling can usually be cold rolled. The proportion of reduction by lamination can preferably be from 40 to 80%. If the proportion of lamination is less than 40%, the shape can hardly be kept flat or the ductility of the final product can become poor. On the other hand, in the case of cold rolling at a reduction ratio in excess of 80%, the cold rolling of the load can be excessively high and cold rolling can become difficult. The effects according to the present invention can be caused without specifying particularly the number of passes through the lamination and the proportion of reduction by lamination of each pass. However, the surface of the steel sheet after cold rolling needs to be in a state where the arithmetic mean of the roughness Ra is from 0.1 to 2.0 pm and the average length RSm of the contour curve element in the roughness curve is from 5 to 300 pm. To create this state, the rolling surface of the final cold rolling position can preferably be worked such that the arithmetic mean of the roughness Ra becomes from 0.1 to 8.0 pm and the average length RSm of the curve element contour in the roughness curve becomes from 5 to 1,200 pm. It may be more preferable that a cylinder in a stage before the final position is also processed so that Ra and RSm are in the same ranges.
    [0070] In the present invention, cold rolled steel sheet can usually be subjected to annealing and deposition in a continuous line for annealing and deposition. Although the effects according to the present invention can be caused without specifying the heating rate particularly when passing through the line, a heating rate of less than 0.5 ° C / s may not be preferred, because productivity can be greatly impaired. On the other hand, a heating rate that exceeds 100 ° C may involve excessive capital investment and may not be economically preferred.
    [0071] In the present invention, the maximum heating temperature (annealing temperature) needs to be from 750 to 900 ° C. If the maximum heating temperature is less than 750 ° C, it can take a long time for the carbide formed during hot rolling to re-enter a solid solution state and a carbide or part of it can remain as a result , a resistance of 980 MPa or higher can hardly be guaranteed. For this reason, the lower limit of the maximum heating temperature can be 750 ° C. On the other hand, heating to an excessively high temperature can not only involve an increase in cost but be economically disadvantageous but can also induce a disturbance such as deterioration of the shape of a plate during the passage of the plate through the line at high temperature or shortened cylinder life. For this reason, the upper limit of the maximum heating temperature can be 900 ° C.
    [0072] The period of heat treatment in this temperature region may not be particularly limited, however, in order to achieve the dissolution of carbide, heat treatment for 10 seconds or more may be preferred. On the other hand, if the heat treatment time period exceeds 600 seconds, an increase in cost may be involved and therefore, such a heat treatment time may not be preferred from an economic point of view. In addition, in the heat treatment, isothermal maintenance can be carried out at a maximum heating temperature and even when the heating gradient is carried out and after reaching the maximum heating temperature, cooling is immediately started, the effects can be caused according to the present invention.
    [0073] After the annealing is completed, the steel plate can usually be cooled to the immersion temperature of the deposition bath. The average cooling rate from the maximum heating temperature to 750 ° C can preferably be from 0.1 to 200 ° C / s. A cooling rate of less than 0.1 ° C / s may not be preferred, as productivity can be greatly impaired. An excessive increase in the cooling rate may involve an increase in the cost of production and, therefore, the upper limit may preferably be 200 ° C / s.
    [0074] In the present invention, the cooling rate in the range of 500 to 750 ° C must be from 3 to 200 ° C / s. If the cooling rate is too low, austenite can be transformed into a perlite structure in the cooling process and the volume fraction of austenite of 8% or higher can be hardly guaranteed. For this reason, the lower limit can be 3 ° C / s or higher. Even if the cooling rate is increased, there may be no problem in terms of steel quality, but an excessive increase in the cooling rate may involve an increase in the cost of production and therefore the upper limit may preferably be 200 ° C / s. The cooling method can be any process for roller cooling, air cooling, water cooling and a combination thereof.
    [0075] Thereafter, in the present invention, the steel sheet can be kept at a temperature of 350 to 500 ° C for 10 to 1,000 seconds to cause the transformation of the bainite and stabilize the retained austenite. The upper limit of the maintenance temperature can be set to 500 ° C, because the transformation of the bainite can occur at a temperature no higher than that. Incidentally, if the steel sheet is kept at a temperature below 350 ° C, the transformation of bainite can take a long time and, in turn, excessively large equipment may be necessary, resulting in low productivity. For this reason, the maintenance temperature must be from 350 to 500 ° C. The lower limit can be adjusted to 10 seconds, because if the retention is less than 10 seconds it may not allow the transformation of the bainite to proceed sufficiently, making it impossible to stabilize the retained austenite and obtain excellent plasticity. On the other hand, if you stay longer than 1,000 seconds you can cause a reduction in productivity and may not be preferred. Incidentally, maintenance may indicate not only isothermal maintenance, but may include cooling or gradual heating in this temperature region.
    [0076] The temperature of the plate during immersion in the deposition bath can preferably be from a temperature of 40 ° C lower than the temperature of the hot dip bath to a temperature of 50 ° C or higher than that temperature of the hot dip galvanizing bath. If the temperature of the dip plate in the bath is less than (the temperature of the hot dip bath-40) ° C, not only and hot extraction in the dip and the entry into the deposit bath can be large, causing partial solidification molten zinc to deteriorate the appearance of the deposition, however the intermetallic compound of Fe, Al and Zn is less likely to be produced as well, which is an essential feature of the present invention. For this reason, the lower limit is adjusted up to (the temperature of the hot dip bath-40) ° C. However, even when the temperature of the plate before immersion is below (the temperature of the hot dip bath-40) ° C, the steel plate can be reheated before immersion in the deposition bath to a temperature of the plate ( the temperature of the hot dip galvanizing bath -40) ° C or higher and then being immersed in the galvanizing bath. On the other hand, if the immersion temperature of the deposition bath exceeds (the temperature of the hot dip bath + 50) ° C, a problem in operation can be caused, together with the increase in the temperature of the deposition bath. A preferred range may have a lower limit of (the temperature of the hot dip bath-20) ° C and an upper limit of (the temperature of the hot dip bath + 30) ° C and a more preferred range can have a lower limit of (the temperature of the hot dip bath-10) ° C and an upper limit of (the temperature of the hot dip bath + 20) ° C.
    [0077] In addition to pure zinc, Al needs to be added to the deposition bath. Due to the addition of Al, an intermetallic compound composed of Fe, Al and Zn can be produced, which is an essential requirement of the present invention. Incidentally, the deposition bath may contain Fe, Al, Mg, Mn, Si, Cr and the like, in addition to pure zinc.
    [0078] The atmosphere at the time of immersion of the steel sheet in the deposition bath is a nitrogen atmosphere that has a nitrogen content of 95% by volume or greater, in which the value of the logarithm log (PH2o / PH2) of pressure partial hydrogen PH2 for a partial water vapor pressure PH2O is from -5 to -2. If the log value (PH2o / PH2) is less than -5, it cannot be economically preferred and in addition, the reactivity on the steel plate surface or on the deposition bath surface can be increased to allow massive formation of a fragile Fe-Zn alloy layer and adhesion by deposition during work can be poor. On the other hand, if the value of the log (PH2o / PH2) exceeds -2, an oxide of Zn may be formed on the surface of the deposition bath and inhibit the formation of the intermetallic compound composed of Fe, Al and Zn may be insufficient and as a result, not only can deposition not be obtained within the scope of the present invention, but also deposition may not adhere to the steel sheet, giving rise to a lack of coating. If the nitrogen content is less than 95% by volume, the proportion of water vapor and hydrogen in the atmosphere can be increased, which may not be preferred in view of the advantage and safety. An increase in the proportion of hydrogen in the atmosphere may cause the steel plate to become brittle and reduce ductility and may not be preferable. The atmosphere at the time of immersing the steel sheet in the deposition bath as used in this case can mean an atmosphere in the oven of at least 10 seconds or more before immersion in the deposition bath, based on the time the steel sheet it is immersed in the deposition bath and can mean the entire atmosphere in the maximum period of time from annealing to immersion in the deposition bath in a continuous annealing and deposition line.
    [0079] To control the properties of the deposition layer, the hot dip galvanizing bath is a deposition bath that has a concentration of Al WAI and a concentration of Fe WFe that satisfies, in mass%, the following relationship expressions (1 ) and (2): 0.01 <WFe <0.05 (1) 0.07 <(WAi-WFe) <0.30 (2)
    [0080] If WFe is less than 0.01, a brittle Zn-Fe alloy layer can be thickened at the interface between the deposition layer and the steel plate and deposition adhesion during work can be weak . If WFe exceeds 0.05, a thick layer of an intermetallic compound composed of Fe, Al and Zn can be formed and a crack is likely to be produced in the intermetallic compound itself and in addition, top slag of Fe2Ah may be formed in the bath deposition in order to cause an indentation mark or an uncoated part, and the appearance after deposition is deteriorated.
    [0081] The reason (WAi-WFe) is adjusted to be 0.07 or higher to 0.30 or less is because if (WAi-WFe) is less than 0.07, an alloy layer of Brittle Zn-Fe can be thickened at the interface between the deposition layer and the steel plate and deposition adhesion during work can be weak. On the other hand, if (WAi-WFe) exceeds 0.30, a thick layer of an intermetallic compound composed of Fe, Al and Zn can be formed and a crack is likely to be produced in the intermetallic compound itself.
    [0082] The material of the hot-dip galvanized steel sheet of high strength excellent in plasticity according to the present invention can, in principle, be produced through steps of obtaining normal refining iron, obtaining steel, casting, cold rolling hot and cold rolling, but the effects according to the present invention can be obtained even with a material produced partially or entirely by omitting these steps, as long as the conditions according to the present invention can be satisfied. EXAMPLES
    [0083] Hereinafter, the present invention is described in more detail.
    [0084] A plate that has the components shown in Table 1 was heated to 1,200 ° C, cooled with water in a water cooling zone and then stretched to the temperature shown in Table 2. The thickness of the hot-rolled plate was adjusted to stay in the range of 2 to 4.5 mm.
    [0085] The hot-rolled sheet was treated with acid and then cold-rolled to have a sheet thickness of 1.2 mm after cold rolling, with a cold-rolled sheet being obtained. Table 2 below shows Ra and RSm of the surface of a cylinder in the final position and on the surface of a cylinder, which was just before the final position, to be used in this operation.
    [0086] Thereafter, the cold rolled sheet was subjected to a heat treatment and a hot dip galvanizing treatment under the conditions shown in Table 2 in a continuous hot dip galvanizing line and the steel sheet was cooled at a rate cooling temperature shown in Table 2 from the annealing temperature to a temperature of 500 to 750 ° C, then maintained at a temperature of 350 to 500 ° C for 5 to 300 seconds, immersed in a controlled galvanizing bath at predetermined conditions and subsequently cooled to room temperature. Finally, the steel obtained was skin lamination, with a reduction ratio of 0.4%. During this time, the deposition weight was adjusted to approximately 45 g / m2 on both surfaces. Table 1 Chemical Components (% by mass)
    The underline represents that the value is outside the scope of the present invention, Table 2-1 Table 2

    The letter underlined in bold represents outside the scope of the present invention.

    The letter underlined in bold represents outside the scope of the present invention.

    The letter underlined in bold represents outside the scope of the present invention.

    The letter underlined in bold represents outside the scope of the present invention. F: Ferrite, B: bainite, y. austenite, M: martensite, P: pearlite. Table 2-2

    The letter underlined in bold represents outside the scope of the present invention.

    The letter underlined in bold represents outside the scope of the present invention.

    The letter underlined in bold represents outside the scope of the present invention.

    The letter underlined in bold represents outside the scope of the present invention. F: Ferrite, B: bainite, y: austenite, M: martensite, P: pearlite.
    [0087] In the tensile test, a specimen JIS No. 5 was sampled in the directions perpendicular and parallel to the lamination direction of the 1.2 mm thick plate and evaluated for tensile properties. From the elongation value obtained, the difference (ΔEI) was calculated between the elongation (L-E1) when a tensile test was performed in the direction parallel to the rolling direction and the elongation (C-E1) when the tensile test was performed in the direction perpendicular to the lamination direction. In each sample, the tensile test was performed on 5 plates and by determining the average of the values, the tensile strength (TS) was calculated starting from the average value. Incidentally, in relation to a steel plate that has a large anisotropy of the material, the elongation value tended to vary.
    [0088] As for plasticity, it was observed a steel sheet cut in 40x100 mm to an arbitrary position in an arbitrary direction was flexed at 120 ° (bending radius R = 3 mm), a region of 200 pm x 200 pm in the surface of the convex side of the flexed part by a scanning electron microscope with 10 parts that differ from each other and the evaluation was made according to the following criteria by counting, of the 10 portions, the number of portions in which a crack was observed. "A", "B" and "C" were Example and "D" was Comparative Example. A: The crack in the 0 portion (passes) B: The crack in the 1 to 2 portions (passes) C: The crack in the 3 to 5 portions (passes) D: The crack in the 6 to 10 portions (failure) INDUSTRIAL APPLICABILITY
    [0089] According to the present invention, a high-strength hot-dip galvanized steel sheet with excellent plasticity can be provided. The production of high-strength hot-dip galvanized steel sheet can be relatively easy and can be carried out in a stable manner. Therefore, the high-strength hot-dip galvanized steel sheet according to the present invention can be particularly good as a steel sheet for automobiles aimed at reducing weight in recent years and its industrial value can be remarkably high.
    权利要求:
    Claims (4)
    [0001]
    1. High-strength hot-dip galvanized steel sheet, characterized by the fact that it comprises, in mass%, C: from 0.10 to 0.4%, Si: from 0.01 to 0.5%, Mn : from 1.0 to 3.0%, O: 0.006% or less, P: 0.04% or less, S: 0.01% or less, Al: from 0.1 to 3.0% N: 0 , 01% or less, and optionally one element or two or more elements, in% by mass, Cr: from 0.05 to 1.0%, Ni: from 0.05 to 1.0%, Cu: from 0, 05 to 1.0%, Nb: from 0.005 to 0.3%, Ti: from 0.005 to 0.3%, V: from 0.005 to 0.5%, B: from 0.0001 to 0.01%, Ca : from 0.0005 to 0.04%, Mg: from 0.0005 to 0.04%, La: from 0.0005 to 0.04%, Ce: from 0.0005 to 0.04% and Y: from 0.0005 to 0.04% with the remainder being Fe and unavoidable impurities, where the structure of the steel sheet also comprises, in terms of volume fraction, 40% or more of the total content of bainite and martensite, from 8 to 60% retained austenite and less than 40% ferrite, with the rest being an inevitable structure and hot dip galvanizing is applied to the surface of the steel sheet and the hot dip galvanized steel sheet has a layer of an intermetallic compound composed of Fe, Al, Zn and unavoidable impurities at the interface between the hot dip galvanized layer and the steel sheet underlying, the average thickness of the intermetallic compound is 0.1 to 2 pm or less and the crystal grain size of the intermetallic compound is 0.01 or greater than 1 pm or less and the arithmetic mean of the surface roughness Ra steel sheet underlying layer after removal of the hot-dip galvanized layer is 0.1 or greater than 2.0 pm or less and the average length RSm of the contour curve element in the roughness curve is 5 or greater up to 300 pm or less.
    [0002]
    2. High-strength hot-dip galvanized steel sheet, according to claim 1, characterized by the fact that the steel sheet also comprises one element or two or more elements, in mass%, Cr: from 0.05 to 1.0%, Ni: from 0.05 to 1.0%, Cu: from 0.05 to 1.0%, Nb: from 0.005 to 0.3%, Ti: from 0.005 to 0.3%, V : from 0.005 to 0.5%, B: from 0.0001 to 0.01%, Ca: from 0.0005 to 0.04%, Mg: from 0.0005 to 0.04%, La: from 0, 0005 to 0.04%, Ce: from 0.0005 to 0.04% and Y: from 0.0005 to 0.04%.
    [0003]
    3. Process for the production of a high-strength hot-dip galvanized steel sheet, characterized by the fact that it comprises: the heating of a steel material comprising, in mass%, C: from 0.10 to 0 , 4%, Si: from 0.01 to 0.5%, Mn: from 1.0 to 3.0%, O: 0.006% or less, P: 0.04% or less, S: 0.01% or less, Al: from 0.1 to 3.0% N: 0.01% or less, and optionally one element or two or more elements, in% by mass, Cr: from 0.05 to 1.0%, Ni : from 0.05 to 1.0%, Cu: from 0.05 to 1.0%, Nb: from 0.005 to 0.3%, Ti: from 0.005 to 0.3%, V: from 0.005 to 0, 5%, B: from 0.0001 to 0.01%, Ca: from 0.0005 to 0.04%, Mg: from 0.0005 to 0.04%, La: from 0.0005 to 0.04% , Ce: from 0.0005 to 0.04% and Y: from 0.0005 to 0.04% with the remainder being Fe and unavoidable impurities, at 1,100 to 1,300 ° C and then subjecting the steel plate to a hot rolling treatment at a rolling temperature to finish temperature Ar3 or m more high; stretching the hot rolled steel sheet at a stretching temperature of 700 ° C or less and then cold rolling the steel sheet; annealing of cold rolled steel sheet at a maximum heating temperature of 750 to 900 ° C; cooling of the annealed steel sheet to a dip bath temperature at a cooling rate of 3 to 200 ° C / s in the range 500 to 750 ° C and then keeping the steel sheet at 350 to 500 ° C for 10 to 1,000 seconds; performing a deposition treatment by immersing the steel sheet in a hot dip galvanizing bath that has a concentration of Al WAI and a concentration of Fe WFe that satisfies, in mass%, the following relationship expressions (1) and (2), at a temperature of the steel plate in the range of, immersed in a deposition bath, from a temperature of 40 ° C lower than the temperature of the galvanizing bath to a temperature of 50 ° C higher than the temperature of the hot dip galvanizing bath, in a nitrogen atmosphere that has a nitrogen content of 95% by mass or higher, where the value of the logarithm log (PH2o / PH2) of the proportion between the partial pressure of hydrogen PH2 and the PH2O water vapor partial pressure is from -5 to -2: 0.01 <WFe <0.05 (1) 0.07 <(WAi-WFe) <0.30 (2) on the surface of the cylinder in the final position in cold rolling, the arithmetic mean of the roughness Ra is 0.1 or greater up to 8.0 pm or less and the average length RSm of the contour curve element in the roughness curve is 5 or greater up to 1,200 pm or less, where Ar3 = 901-325xC + 33xSi- 92x (Mn + Ni / 2 + Cr / 2 + Cu / 2 + Mo / 2), where C, Si, Mn, Ni, Cr, Cu and Mo indicate the contents (% by mass) of the respective components and it remains 0 when the component is not contained.
    [0004]
    4. Process for the production of a high-strength hot-dip galvanized steel sheet according to claim 3, characterized by the fact that on the surface of a cylinder in a stage before the position of the final position in cold rolling, the arithmetic mean of the Ra roughness is 0.1 or greater up to 8.0 pm or less and the average length RSm of the contour curve element in the roughness curve is 5 or greater up to 1,200 μm or less.
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    KR101601001B1|2016-03-08|
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    MX2014003664A|2014-04-30|
    PL2762603T3|2019-08-30|
    CA2850094C|2015-10-13|
    EP2762603A4|2015-09-09|
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    法律状态:
    2018-03-27| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|
    2019-08-13| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|
    2019-09-03| B25D| Requested change of name of applicant approved|Owner name: NIPPON STEEL CORPORATION (JP) |
    2020-04-07| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|
    2020-09-15| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 28/09/2012, OBSERVADAS AS CONDICOES LEGAIS. |
    2021-08-10| B21F| Lapse acc. art. 78, item iv - on non-payment of the annual fees in time|Free format text: REFERENTE A 9A ANUIDADE. |
    2021-11-30| B24J| Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)|Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2640 DE 10-08-2021 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |
    优先权:
    申请号 | 申请日 | 专利标题
    JP2011217146|2011-09-30|
    JP2011-217146|2011-09-30|
    PCT/JP2012/075203|WO2013047812A1|2011-09-30|2012-09-28|High-strength hot-dip galvanized steel sheet|
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