• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
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    • 专利摘要:
    ATOMIZATION DEVICE, USE OF THE ATOMIZATION DEVICE, PROCESS FOR MICRONIZING A FLUID, AND USE OF DROPS. The invention relates to a new atomization device with improved droplet formation. Small droplets are formed with increased micronized volume through them, in which high volumes of air are fed into a liquid sprayed from a liquid nozzle (2). High volume ratios result in the main free path between droplets being transported in order to minimize collisions and to prevent droplet aggregation.
    公开号:BR112014000654B1
    申请号:R112014000654-7
    申请日:2012-07-09
    公开日:2020-12-22
    发明作者:George Saunders；Ryan Kittredge
    申请人:Omya International Ag；
    IPC主号:
    专利说明:

    Field of the Invention
    [01] The present invention relates to a fluid atomizer comprising a liquid nozzle, said liquid nozzle being circled by a converging air head with an air transition cone and a connected atomizer nozzle tip downstream of the converging air head, optionally comprising a mixing chamber, the nozzle orifice connected to the optional mixing chamber, positioned downstream of said mixing chamber.
    [02] Liquids as well as dispersions containing solid particles such as slurries of mineral matter are sprayed or atomized into fine droplets in order to increase the specific droplet surface, which can lead to improved chemical or engineering processes. Thus reactions or reaction parameters can depend considerably on the droplet size.
    [03] The present invention, therefore, provides an improved atomization device and atomization of liquids or slurries containing solid particles, dispersions or emulsions in micronized droplets. Within the context of the present invention, an atomizer is a device which converts a stream of liquids as described herein before into a fine spray. In addition, the present invention also relates to the use of such an atomization device and micronized droplets. Such use can be, for example, in the field of agriculture where products related to harvest need to be finely dispersed over seeds and / or plants, in painting and / or coating, in combustion processes for improved removal of contaminants produced during said process of combustion, in spray drying of slurries containing solid particles or dispersions, or in fire fighting. The present invention also further relates to slurries, dispersion or emulsions to be sprayed with the atomization device of the present invention. Knowledge of the Invention and Related Technique
    [04] In the field of agriculture, harvesting and plant protection as well as fertilization it is sometimes necessary to provide a profitable harvest. Fertilizers and crop protectors need to be distributed with high efficiency in order to be cost-effective. This can be achieved by the present invention, since the atomization device provides highly efficient atomization or dispersion of the fluid. Within the context of the present invention, the fluid encompasses any liquid material, dispersions, suspensions and emulsions.
    [05] In the fire fighting field, one method of extinguishing a fire is to use water. The first way that water extinguishes a fire is by cooling, which removes heat from the fire. This is possible through the ability of water to absorb large amounts of heat by converting water to water vapor. The second way to extinguish a fire with water is by asphyxiating the fire. When the water is heated to its boiling point, it is converted to water vapor. When this conversion occurs, it dilutes the oxygen in the air with water vapor, thus removing one of the elements that a fire requires to burn. This can also be achieved with foam. It is therefore of great importance to have the fire extinguishing medium being dispersed in as small droplets as possible to provide a large surface area for the cooling and extinguishing effect.
    [06] In the field of combustion processes, known from, for example, coal-based energy plants, which use energy coolers to produce electricity around the world; coal, previously referred to as mine coal or marine coal, a fossil fuel extracted from the ground by underground or surface mining is burned in private furnaces. Depending on the type of coal (anthracite, bituminous, sub-bituminous or lignite) and whose abundance varies within geographic regions, the sulfur content on such coals varies significantly and in an increasing manner in the order mentioned above. Thus lignite is a type of coal with a sulfur content of up to 10% by weight of coal and sometimes even more. The problem of sulfur content becomes evident, as during the process of combustion of coal, in addition to the formation of carbon dioxide (CO2), sulfur is transformed into sulfur dioxide (SO2), which takes into account the largest source of SO2 caused by humans, a polluting gas that contributes to the production of acid rain and causes significant health problems. Other contaminants, such as nitrogen oxides (NOx), hydrochloric acid and heavy metals such as mercury, arsenic, lead, selenium and cadmium are dangerous compounds which are additionally produced and / or accumulated during such combustion processes.
    [07] Combustion processes, however, are not restricted to power plants only. There are only other technologies that use high temperature processes in bottles, such as the paper industry, the steel industry, the waste incineration industry, or mineral material producers, to name just a few.
    [08] For many decades, environmental concerns, but the environmental regulations involved, have led to solid improvements in these high temperature process technologies. Particularly, pollutants, toxic residues, and fine particles were targets to be captured and thus eliminated from the exhaustion of combustion and / or heating processes to reduce their release into the atmosphere and to reduce corrosion within such systems. One way to reduce the carbon dioxide being released into the atmosphere was to increase the efficiency of coal burning or improved reaction processes. However, it is not possible to prevent the formation of such pollutants and therefore there is still a demand in processes which allow the capture of such pollutants and to remove them from the exhaust to provide exhaust which are almost free of such contaminants. Such processes are known to the person skilled in the art.
    [09] In order to comply with all environmental regulations and satisfy the limitations that affect the release of pollutants into the atmosphere, the combustion products formed in the industrial combustion processes are passed through flue gas desulfurization systems (FGD) . The flue gas treatment to capture SO2 is usually carried out in wet lime or limestone scrubbers, in which the lime or limestone slurries are contacted with the flue gas before the flue gas is discharged into the atmosphere. The effectiveness of such washers is quite satisfactory in capturing the 1% to 2% of the sulfur present in the fuel, however, they need important investments.
    [10] A different method uses the injection of a lime or limestone slurry in the high temperature region of the reflector, a technology known as LIMB (Multi-stage burner for limestone injection). This technology, however, is not able to capture more than 60% to 65% of the SO2 formed.
    [11] An additional method is the oven adsorbent injection (FSI) method in which lime and limestone are injected as a slurry in the oven with a sulfur capture effectiveness of 10%> to 60%> . Another suitable adsorbent is dolomite, which, however, does not exceed the effectiveness mentioned above.
    [12] In order to finely spray liquids or slurries containing solid particles or dispersions in the form of fine droplets, application US 2010/0163647 which refers to a two-fluid nozzle allows a wide spray jet opening angle to be obtained with fine droplet atomization. The formation of large droplets at the nozzle edge is prevented by an annular release atomization at the nozzle edge by branching secondary air directly from the annular chamber surrounding the mixing chamber. The pressure gas that leaves the annular release at high speed ensures that a liquid film on the wall of the nozzle orifice of the divergent section is removed to a very thin lamella, which is then broken into small droplets. Part of the pressure gas is thus diverted to the mixing chamber and part of it to the edge of the nozzle orifice.
    [13] US 2007/0194146 provides a nozzle capable of multiple atomization steps for a nozzle capable of multiple atomization steps of a liquid, where the liquid is atomized in a first direction and subsequent later atomization of the same liquid in a second direction it is made to form a counterflow nozzle. Suitably, the liquid to be dispersed is atomized in at least two separate stages.
    [14] US 5,004,504 refers to the preparation of red transparent iron oxide by spray drying. A filter cake is broken into small droplets by a two-fluid nozzle, said nozzle comprising a central cylindrical conduit and an annular conduit surrounding the cylindrical conduit. The process fluid, which as an aqueous mass of yellow transparent iron oxide, is passed through the central conduit while an atomizing fluid supplied through the surrounding annular conduit is forced under pressure through the annular conduit. No or little pressure is required to transport the yellow clear iron oxide aqueous mass through the central conduit.
    [15] Atomization of the obviously thick aqueous mass of transparent yellow iron oxide is achieved as a result of using a high pressure atomizing fluid such as compressed air or superheated steam at pressures from about 0.55 MPa up to about 0.68 MPa or even higher.
    [16] Thus the prior art related to an atomization process provides different nozzle geometries manufactured for use in different applications, each seeking to have the best efficiency. Summary and Description of the Invention
    [17] The present invention provides a new single-stage atomization device with improved droplet formation, i.e. less droplet formation with increased micronized volume through it, and thus increased process or reaction efficiency, in which said micronized droplets they are applicable, for example, in an oven adsorbent injection method, in spray drying, or other applications mentioned above.
    [18] Such methods of furnace adsorbent injection comprise methods of injecting dry powder or water-based slurry injection of adsorbent material. The general principle of such a coal burning energy referrer is that air and powdered coal are placed in the furnace and burned in which both a secondary water circuit is heated to turn the water into steam to energize the generator turbine, and the hot air from the combustion process is used downstream of the firing portion to heat a secondary water circuit for steam production. The steam is then used to drive the generator's turbine and then cooled down to re-introduce it into the water circuit which serves to produce steam.
    [19] In both cases, the hot exhaust needs to be treated with an adsorbent to capture the toxic waste. This can be achieved by positioning the atomizer of the present invention above the lit burner of the coal burning unit in such a way that the atomizer nozzle tip is not in direct contact with the combustion flame. The furnace is generally a tall, vertical lit cylinder. The height to diameter ratio is selected in such a way that it allows gas speeds of 10 to 15 feet per second and residence times of 1 to 4 seconds, depending on the ignition rate. The outlet gas temperature of the project oven is in the range of 800 ° C to 1100 ° C. The oven described is for illustrative purposes only and should not be construed as limiting the present invention. The skilled person will readily recognize that another furnace with a different lighting chamber configuration can also be equipped with the atomizer of the present invention.
    [20] The injection of adsorbent material through the atomizer nozzle tip into the oven can be performed as an injection in the flow direction or an injection in the opposite direction to the flow. Within the context of the present invention, injection in the direction of flow means that the adsorbent material is injected or sprayed in the same direction as the exhaust gas from the ignition firing unit, while injection in the opposite direction to the flow means that the adsorbent is injected or sprayed against the direction of the exhaust gas flow from the ignition firing unit.
    [21] It will be within the expert's understanding that the injection of adsorbent material is possible at any stage or position downstream of the flaring process, depending on the construction of the energy cooler unit and before the exhaust gas is released into the atmosphere. . Some energy suppliers provide the water circuits for the production of steam in or immediately after the firing unit, or additionally downstream of the oven, where temperatures are still convenient for the production of steam. Private energy providers also use the downstream exhaust gas temperature to exploit the residual heat to preheat condensed water - after the generator turbine - in the water circuit for new steam production. In this way, exhaust gases are additionally cooled before being released into the atmosphere. Description of Drawings
    [22] FIG. 1 illustrates a cross-sectional view of an atomizer embodiment of the present invention.
    [23] FIG. 2 illustrates a cross-sectional view of an atomizer embodiment of the present invention, in which the position of the liquid nozzle 2 can be adjusted in relation to the converging air transition cone A.
    [24] FIG. 3 illustrates a cross-sectional view of an atomizer embodiment of the present invention, in which the housing has parts that slide over one another to adjust the position of the converging air transition cone A in relation to the liquid nozzle 2.
    [25] FIG. 4 illustrates a cross-sectional view of an atomizer embodiment of the present invention.
    [26] FIG. 4a illustrates a cross-sectional view of the tip of the nozzle 1 of FIG. 4.
    [27] FIG. 5 illustrates a cross-sectional view of an atomizer embodiment of the present invention, with a detailed view of the converging air transition cone A, having different diameter ratios.
    [28] FIG. 6 illustrates a cross-sectional view of an atomizer embodiment of the present invention, with a detailed view of the converging air transition cone A, having different cone angles.
    [29] FIG. 7 illustrates a cross-sectional view of different modalities of the atomizer nozzle tip.
    [30] FIG. 8 illustrates a perspective view of an embodiment of the atomizer of the present invention according to FIG. 4, without the nozzle comprising the converging air transition cone A.
    [31] FIG. 9 illustrates a possible embodiment of a diffuser plate.
    [32] FIG. 10 illustrates a perspective view of an embodiment of an atomizer nozzle tip according to FIG. 4a of the present invention.
    [33] FIG. 11 illustrates a perspective view and end view of spacer plates such as S1, S2 according to FIG. 4 and the arrangement of the holes in the diffuser plate in a flat APC air cover according to FIG. 8.
    [34] FIG. 12 illustrates a cross-sectional view of an alternative atomizer configuration of the present invention.
    [35] FIG. 13 illustrates a cross-sectional view of an alternative atomizer configuration of the present invention, where H and M are two separate entities connected via an ICD interconnect device.
    [36] FIG. 14 illustrates cross-sectional views and perspectives of a round to square TE transition element.
    [37] FIG. 15 illustrates a cross-sectional view of an alternative atomizer configuration of the present invention with inch dimension indications and an inch to mm conversion table.
    [38] FIG. 16 compares the performance of prior art spray systems with the spray system of the present invention. Detailed description of the Invention
    [39] The micronisation of droplets from a slurry of mineral matter can be achieved by an atomization device as shown in FIG. 1, which represents an embodiment of the present invention and in which 1 is the atomizer nozzle tip, 2 is a commercially available liquid nozzle, 3 is a converging air head, with an air transition cone A, surrounding circulate the liquid nozzle 2 which is connected through a central lance tube 4 with an optional mixing chamber 5, said optional mixing chamber 5 is fed by an inlet 6. Said inlet 6 can be equipped with an inlet fluid 7 and / or an air inlet 8. An air inlet 9 to supply a gas or gas mixture such as nitrogen, air, steam or water vapor is connected to the converging air head 3. This design allows for the introduction large volume of low pressure gas as a concurrent ring around the nozzle. The position of the nozzle 2 is adjustable in such a way that the nozzle 2 can be moved into or out of the air transition cone A - in fact any mechanism that allows the nozzle to be adjusted inside the air transition cone A to achieve optimal mixing conditions of the fluid droplets with the primary air to adjust or change the air velocity at the mixing point, that is the point where the accelerated air comes into contact with the sprayed liquid that escapes from the nozzle orifice until sonic speed is beneficial (FIG. 2).
    [40] Low pressure gas or low pressure air within the context of the present invention means that a gas or air, in general a fluid, which is supplied under a pressure between 0.0005 MPa and below 0.5 MPa , such as 0.4 MPa or 0.3 MPa or 0.25 MPa or 0.2 MPa or 0.15 MPa.
    [41] Adjustment of the appropriate nozzle position within the converging air head can be achieved by various means, such as moving the central lance that carries the nozzle forward or backward within the converging air head as shown in FIG. 2, providing an overlapping housing with moving parts, where one part comprises the converging air head, and the other part comprises the central lance carrying the nozzle, the two parts sliding in relation to each other as shown in FIG. 3.
    [42] In an additional embodiment the adjustment of the position of the liquid nozzle 2 within the converging airhead cone A is shown in FIG. 4. Here one or more spacer plates S1, S2 (FIG. 11), can be positioned between the tip of the nozzle 1 (FIG. 10) that carry the converging airhead cone A and the housing 3 (FIG. 8) , while the housing 3 carrying the lance 4 with the nozzle mounted 2 is reversibly or irreversibly connected with the tip of the nozzle 1 by any means known to the expert, for example, by glue, screws, pipe clamps, screws of ring sleeve or other fastening means. It is within the skill of the art that any means or arrangements that allow positioning of the nozzle 2 within the converging airhead cone A are within the concept of the present invention. Inlet 9 provides a gas supply or gas mixture such as air, steam, water vapor, which allows the introduction of a large volume of air, gas or steam that is directed as a concurrent ring of air, gas or steam around the nozzle 2.
    [43] FIG. 4a refers to a nozzle tip embodiment, in which the converging air transition cone A is comprised at the nozzle tip. P refers to the length of the pipe, which is a stainless steel pipe x 60.96 cm (24 inches) long, NPT threaded at the end of the opposite flange, where NPT refers to the United States National Pipe Thread (in Portuguese, United States national pipe thread). There are some thread sizes of NPT used such as 3.175 mm, 6.35 mm, 9.525 mm, 12.70 mm, 19.05 mm, 25.40 mm, 31.75 mm, 38.10 mm, 50.80 mm - corresponding to 1/8, ^, 3/8, ^,%, 1, m, 1 ^ and 2 inches. La refers to the length of the converging air transition cone A made of a thick stainless steel alloy of 3.175 mm (1/8 inch) 304 also known as "18/8" steel which indicates the minimum content of Chromium (Cr) and Nickel (Ni) to be present. Da refers to the inner diameter of the tube which is equivalent to the diameter Q1 in FIG. 5, ed refers to the internal diameter of the large end of the converging air transition cone A which is equivalent to Q2 in FIG. 5. The cone angle is determined by the side walls of the converging air transition cone A. The tip geometries in the present inventions can be selected from but are not limited to the values as found in table 1.
    The nozzle tip mounting flange (NTMF) has a dimension of 12.7 mm x 190.50 mm (1/2 inch x 7.5 inches) comprising 4 standard 152.4 mm (6 inch) screws drilled for aligning the flange screws.
    [44] As can be seen from Figures 1 to 3 or 4, the converging airhead cone A can be an integral part of the housing or the tip of the nozzle. When the converging air head cone A is part of the nozzle tip, it will be easily seen that such a configured device provides a very easy and flexible adaptation of the atomization conditions and thus adapts to various applications and conditions of use.
    [45] The liquid nozzle is a commercially available nozzle capable of creating a hollow or full cone spray at cone angles from 20 to 80 degrees. Such nozzles, such as 1 / 4M-8, 1 / 4M-4, Spiral Jet 7® or Flomax 0X15®, just to mention a few, are known from suppliers such as Spraying Systems Co®.
    [46] The liquid nozzle is used to inject a spray of droplets into a high-shear zone at the inlet of the tip of the nozzle 1. Said shear zone is the zone where the spray of the liquid from the nozzle comes into contact with the air from the converging air head A. The position of the shear zone thus depends on the relative position of the nozzle within the converging air head cone A.
    [47] Droplets from the liquid nozzle 2 entering the high shear zone are introduced into the secondary air at the tip of the nozzle supplied by the converging low pressure air head 3 fed with a large volume of low pressure air through of an air inlet 8. The volume ratio of secondary air from the converging airhead to the liquid sprayed from the liquid nozzle 2 is maintained at a ratio of from 100: 1 to about 4000: 1. Ratios larger ones such as 5000: 1; 6000: 1; 7000: 1, or 8000: 1 and even greater ratios are within the scope of the present invention. High volume ratios result in an average free path between droplets being transported in order to minimize collisions and to prevent droplet aggregation. It is within the expert's understanding that a suitable ratio is also from about 200: 1 or 300: 1 or 400: 1 or 500: 1 or 600: 1 or 700: 1 or 800: 1 or 900: 1 or 1000 : 1 about the reasons already mentioned, including 2000: 1 or 3000: 1 or 4000: 1. The expert will also recognize that these values are not of a limiting character, since any ratio from 100: 1 to 8000: 1 and even greater reasons can be chosen according to the particular needs.
    [48] The angle of approach, which is the angle of attack of the air stream towards the stream of atomized fluid from the nozzle can be varied from and including 0 degrees up to and including 90 degrees by varying the angles of the cone of converging air transition A, see FIG. 5. The exemplified approach angle shown in FIG 5. is 45 degrees.
    [49] When the angle of the converging air transition cone is 180 degrees, which within the context of the present invention means, at a right angle to the air pressure head, 0 degree, meaning within the context of the present invention, in line, or parallel to the air pressure head housing.
    [50] The ratio of the diameter of the nozzle tip to the diameter of the air pressure head is in the range of 1: 1 to 1: 10, where between the air transition cone A is present. Said air transition cone A having the small diameter Q1 equal to the diameter of the nozzle tip and the large diameter Q2 equal to the diameter of the air pressure head. The converging air transition cone A can thus have an opening angle of from 180 degrees, up to 0 degrees. In an additional embodiment, the ratio of the diameter of the nozzle tip to the air pressure head is kept constant within the range of Q1: Q2 = 1: 1 -1: 7, for example, 1: 4 and the angle of the cone. Air transition is kept constant, for example, at a 45 degree angle (see FIG. 6), or the angle can be varied as described here earlier. It is within the expert's understanding that the Q1: Q2 ratio can be achieved in both ways, that is, by varying the diameter of Q1 and / or Q2. Thus a ratio of Q1: Q2 = 1: 1 is achieved with the same diameters as Q1 and Q2, but with diameters of different sizes, as explained in the following non-limiting examples. Q1 = Q2 = 4 cm, or 5 cm or 10 cm the diameters having different values, but having the same ratio, 1: 1.
    [51] The nozzle tip having a length to diameter ratio of from about 50: 1 to about 0.5: 1, preferably from about 20: 1 to about 1: 1, more preferably from about 15: 1 to about 5: 1. The nozzle tip can also be folded into an angular offset, the angular offset sometimes also referred to as angular folding that is between and including 180 degrees up to about and including 90 degrees. The fold may be present either at the tip end of the nozzle or be in some way between the edges of the tip of the nozzle. The skilled person will be able to think in various ways of such nozzle tips, some examples are shown in FIG. 7. However, the exemplary modalities are not of a limiting character, but are illustrative examples instead.
    [52] A preferred embodiment has a nozzle tip to diameter ratio of 10: 1, a nozzle tip diameter to air pressure head diameter of 1: 5, where the The air has an opening angle of 75 degrees.
    [53] Diffusion plates (DP) and vanes can serve as air regulators and can be incorporated in the airhead housing 3 to minimize turbulence and to ensure an even distribution of air flow around the spray of liquid emanating from of the liquid nozzle 2. Such diffusion plates can be integrated in a so-called flat air cover (APC), which can be made in a removable part or a fixed element of the housing. FIG. 8 shows at least one diffuser plate (DP) that is present between the converging airhead cone and the air inlet (9, I). In a particular embodiment, the diffuser plate can also be present between the mounting devices MD1 and MD2, and thus can serve both as a diffuser plate and as a spacer. The presence of a DP diffuser plate, however, is not mandatory and is therefore optional. Additionally, FIG. 8 shows that the T-shaped housing T is connected to the air plane AP through the flat air cover APC comprising a diffuser plate DP. The geometry and values of the housing of FIG. 8 will now be further described from but are not limited to these values. T is a welded fitting of 76.20 mm (3 inches) Tee ASTM A403, schedule 40. BF refers to a 101.6 mm (4 inch) diameter x 6.35 mm (1/4) flange inch) thick. L refers to a 9.252 mm (3/8 inch) slurry tube made of a 304 stainless steel tube with a length of 381.00 mm (15 inches) and threaded NPT at the end, to allow mounting of a liquid nozzle N and a slurry delivery device. I refers to a 76.20 mm (3 inch) coupling half-screw, 150 lb. NTMF refers to a nozzle tip mounting flange with a thickness of 12.7 mm x diameter of 190.50 mm (1/2 inch x 7.5 inches), comprising 4 fixing holes FH, arranged in a circle of 152.4 mm (6 inch) diameter for screw alignment to secure a nozzle tip type as shown in FIG. 10. Thus the NTMF of FIG. 10 is synonymous with MD1. The NTMF counterpart of FIG. 10 being the NTMF of FIG. 8, synonymous with MD2.
    [54] SF refers to a 9.252 mm (3/8 inch) 150 lb. screw fitting, whereby AP is a 76.20 mm (3 inch) air plane, schedule 40, made of steel 304 stainless steel with a length of 152.4 mm (6 inches). The APC flat air cover with the DP diffuser plate, made of 304 stainless steel, with a diameter of 101.6 mm (4 inches) and thickness of 6.35 mm (1/4 inch), comprises 5 holes with 2 , 54 mm in diameter and a central hole for L. The unique parts described here are reversibly or irreversibly interconnected with each other, such means of connection being known to the skilled person. As a non-limiting example, welding or bonding represent such means of connection.
    [55] The atomization of the liquid, ie the reduction of the droplet size occurs in the shear zone, the zone where the air from the inlet 9 imposes on the spraying of the liquid emanating from the nozzle 2 due to the high shear forces in the shear zone while spraying liquid and air are accelerated to near sonic speed. Diffuser plates which allow to provide a homogeneous air flow can be of different geometries. FIG. 9 provides an exemplary diffuser plate, which should be considered as a non-limiting project.
    [56] The fluid mixing chamber 5, which may or may not be present, is used to produce a homogeneous mixture of solid matter slurry, high pressure air and optionally additional diluents. The mixing chamber comprising a mixing device selected from an energized high shear mixing device or a static one, in fact any mixing device suitable to provide a suitable material for atomization. High pressure air can be introduced into the solid slurry prior to the fluid mixing chamber 5 via the high pressure inlet 7 to the solid slurry inlet 5 or as an alternative embodiment; high pressure air can be introduced through a high pressure inlet into the mixing chamber itself. To further adjust the slurry of solid matter before spraying through the liquid nozzle 2, a diluent inlet 8 may be present in the slurry inlet 6 or the mixing chamber 5. When the mixing chamber is not present, the slurry inlet 6 is feeding the liquid nozzle through the center throw tube 4.
    [57] Within the context of the present invention, high pressure air means that a gas or air, in general a fluid, is supplied under a pressure of between 0.5 MPa and more, such as 0.55 MPa, or 0 , 6 MPa up to 1 MPa or 1.2 MPa or 1.5 MPa. Even higher pressure being applicable if necessary.
    [58] FIG. 12 provides an additional modality, in which the inlet (L, 6) to feed the slurry to the liquid nozzle is made through the air inlet (I, 9). Said arrangement, being freely applicable to the other modalities of the present invention.
    [59] It is within the expert's understanding that the system components do not need to be provided in a single set. In an additional preferred embodiment (FIG. 13) the in-line fluid mixing chamber or static mixing chamber 5 comprising the slurry feed inlet 6, the high pressure air inlet 7 and the dilution inlet 8 may be in a separate device or housing M connected via at least one ICD interconnect device, such as a tube, hose or tubing to atomization head H, comprising atomizer nozzle tip 1, liquid nozzle 2, the converging airhead housing 3, with the air transition cone A, circling the liquid nozzle 2 which is connected to a central lance tube 4. Inlet 9 provides a gas supply or a gas mixture such as air, steam, water vapor, which allows the introduction of a large volume of air (low pressure), gas or steam which is directed as a concurrent ring of air, gas or steam around the liquid nozzle 2. The center throw tube 4 being supplied through the ICD interconnect device with a suitable product to be atomized which is supplied from the device comprising the mixing chamber 5.9a in FIG. 13 provides an alternative design for the entrance. The H device can be additionally mounted in a flight to allow the particular positioning of the atomizer in the specific application, both automated and manually, for example, in agricultural applications, spray painting, fire fighting or other applications mentioned here above, where a positioning atomizer is desired or necessary. It will be within the expert's understanding that device H can be used in both ways, in combination with device M or without. With regard to the ICD interconnection device, the expert is well aware of the problem encountered by such means. However, the expert knows which material, dimensions, (ie, diameter and wall thickness) and what type of connection means, such as couplings, fixing devices or clamp collars, are suitable for reversibly or irreversibly connecting the H and M devices together.
    [60] The nozzle tip of atomizer 1 provides a directed atomized droplet cloud that can have a particular shape and density according to the nozzle tip size, shape, geometry and applied air pressure. Said air pressure is comprised between 0.002 to 4.0 MPa, preferably between 0.004 to 0.3 MPa, more preferably between 0.01 MPa to 0.25 MPa, even more preferably between 0.05 MPa to 0.2 MPa , even more preferably between 0.08 and 0.2 MPa. The design allows the use of the type of device that provides low to high pressure air from standard rotary lobe blowers, or fans, even compressors. The device that provides low pressure air is preferred as it results in lower capital, operating and maintenance costs.
    [61] In addition to this, the geometry of the atomized droplet cloud can be altered by mounting a transition plate or TE element at the tip end of the nozzle 1. Such a transition element is shown in FIG. 14. Such transition elements make it possible to transform the cone-shaped atomized fluid into wave or flat atomized fluid. Such conformation allows for customized applications, in which the atomized fluid is needed instead in a wavy form rather than in a cone form.
    [62] Transition elements can be from many different projects. The objective is to achieve a desired pattern, for example, a rectangular tapered spray pattern without adversely affecting the droplet size distribution. This can be achieved by incorporating a slight reduction 5 in the cross-sectional area in relation to the nozzle tip. The area reduction is in the range of from about 0% to 25%, preferably from about 0% to 20%), more preferably from about 0%> to about 10%>, depending the properties of the particulate and / or gas stream. Transition elements with other geometries can be mounted on the nozzle tip according to particular needs and uses. Tables 2 provide different geometries of the transition elements that should be considered as non-limiting projects.

    [63] The HC coupling half is a 150 lb coupling half. adapted to the tube size. The coupling half is continuously welded to the transition plate in an airtight manner. Other means of fixation or assembly that provide an airtight connection are known to the skilled person and are thus included here. The internal junction centered on the coupling must be smoothed to minimize turbulence. The corners of the transition plates are preferably rounded and free of burrs. The dimensional tolerances for the transition outlet (rectangular end) are within regular tolerances such as ± 0.1 mm. It is within the concept of the present invention that the transition element is a versatile element and can be made for different pipe sizes, ie different nozzle tip diameters such as ^,%, 1, 1 ^, 1 ^ inch, corresponding at the diameters of 12.70 mm, 19.05 mm, 25.40 mm, 31.75 mm, or 38.10 mm. It is within the discretion of the expert to choose other diameters which are above or below these values as well, and as a consequence of the selection of the different diameter size, the other dimensions of the transition plate necessary to be adapted appropriately, which is within the competence the expert.
    [64] FIG. 15 shows a schematic drawing of a modality with an indication of suitable dimensions in inches. The dimensions, however, should not be considered as binders. Appropriately, dimensions can be scaled up or down according to needs.
    [65] Solid matter comprising suitable slurries being dispersed by the atomizer of the present invention are well known to the skilled person and comprise mineral material such as alkaline earth carbonates, alkaline earth hydroxides, alkaline earth oxides, or ash. Alkaline earth carbonates, for example, comprise natural soil calcium carbonate (GCC) such as marble, lime or limestone, synthetic calcium carbonate such as precipitated calcium carbonates (PCC) such as argonitic PCC, characteristic PCC and / or PCC calcitic, especially prismatic, rhombohedral or scalenohedral PCC, or surface-modified calcium carbonates and similar fillers containing calcium carbonates such as dolomite or fillers based on mixed carbonate; various materials such as talc or the like; mica, titanium dioxide clay, bentonite, magnesite, white satin, sepiolite, huntite, diatomite, silicates; and mixtures thereof, but is not limited.
    [66] Another solid matter comprising slurries can be chosen according to the desired application of the atomizer, as well as liquids and dispersions and emulsions are suitable for use with the atomizer of the present invention according to its specific use.
    [67] In general, the slurry of mineral material with a high solids content comprises at least one mineral material in an aqueous suspension with a solids content from about 30% by weight to 80% by weight, preferably from about 72% by weight to about 79% by weight, more preferably from about 74% by weight to about 78% by weight based on the total weight of the suspension. Fluid pastes with a high solids content are preferred as they allow dispersion of larger quantities of solid materials, whereby fluid pastes with a low solids content of 5% by weight up to about 30% by weight are not excluded from use with the atomizer of the present invention.
    [68] The aqueous suspension may additionally comprise at least one dispersing agent in total amounts from about 0.01% by weight to about 2% by weight, preferably from about 0.04% by weight to about 1.5% by weight, more preferably from about 0.1% by weight to about 1% by weight, even more preferable from about 0.3% by weight to about 0.6 % by weight based on the dry weight of the mineral material.
    [69] Dispersing agents, which can be used are selected from the group comprising homopolymers or copolymers of polycarboxylic acids such as acrylic or methacrylic acids or maleic acids; and / or its salts, for example, partially or acid salts completely neutralized with sodium, lithium, potassium, ammonium, calcium, magnesium, strontium, and / or aluminum or mixtures thereof, preferably sodium, calcium and magnesium, or derivatives of such acids such as esters based on, for example, acrylic acids, methacrylic acid, maleic acid, fumaric acid, itaconic acid, for example acrylamide or acrylic esters such as methyl methacrylate or mixtures thereof; alkali polyphosphates; or mixtures thereof.
    [70] The mass molecular weight Mw of such products is preferably in the range of from 1000 to 15000 g / mol, more preferably in the range of from 3000 to 7000 g / mol, for example 3500 g / mol, more preferably in the range of from 4000 to 6000 g / mol, for example 5500 g / mol.
    [71] The particles of mineral material in the aqueous slurry have an equivalent spherical diameter of <2 μm, preferably <1 μm, even more preferably <0.5 μm. The equivalent spherical diameter, therefore, ranges from about 0.1 μm to about 1.9 μm. Preferably, from about 0.4 μm to about 0.9 μm.
    [72] The Brookfield viscosity of the mineral matter slurry measured at 23 ° C after 1 minute of stirring by using a Brookfield ™ viscometer of the RVT model at room temperature and a rotation speed of 100 rpm with the appropriate spindle is from 50 to 1000 mPa-s, preferably from 100 to 750 mPas, more preferably from 150 to 600 mPas, more preferably from 200 to 460 mPas, for example, 300 mPas.
    [73] Such mineral slurries are known to the expert and are readily commercially available, such as Hydrocarb 90 ®, Hydrocarb 60 ®, Hydrocarb HG ®, supplied by OMYA, or other commercially available mineral slurries or dispersions. Within the context of the present invention liquid mineral matter must address any type of solid mineral matter as made in a solvent.
    [74] Another material which can be practical to be in a dispersed form and provide increased reactivity or improved processing can also be broken into droplets by the atomizer of the present invention. The skilled person will readily recognize that not only dispersions or slurries are suitable products to be atomized by the present invention, but also simple solutions or liquids, i.e. mixtures of single-phase liquids and substances dissolved in them, such as fertilizers, herbicides, fungicides , or fire extinguishing means can be atomized by the present invention.
    [75] Table 3 shows the influence of the droplet size depending on the type of nozzle, the flow rate of the test fluid sprayed through the liquid nozzle 2, and the air flow rate inside the air pressure head 4 .
    Table 3. Test conditions
    [76] The tests were performed using the following nozzles: - hydraulic nozzles 1 / 4M-8, and 1 / 4M-4; - SpiralJet nozzles were used for conditions of high liquid flow rate. - Flomax X015
    [77] The material used to spray the tests was Hydrocarb 60®, a high-solids calcium carbonate slurry diluted to 28% by weight of solids in water without surfactant (Type A liquid).
    [78] The Flomax X015 nozzle proved to be more efficient than other commercially available nozzle configurations made with the atomization device of the present invention. Smaller drop sizes are achieved at a lower air flow rate, as seen in the test condition (CT) 16.
    [79] In addition to this, the importance of the nozzle tip becomes evident as seen in TC 9, where the slurry is sprayed without a nozzle tip but with a surrounding air flow at a rate of 1.6 m3 / min. Dimensional drop is reduced compared to TC 1 where no airflow was used. TC 1 shows the spraying effect from the nozzle performance itself. TC 10 shows that when no converging transition cone is present, "reduced narrowing" means an abrupt transition from the housing to the tip of the nozzle, droplet size increases again due to inconsistent airflow, promoting droplet collision and thus leading to the largest droplet size.
    [80] Droplet size measurements were taken with a Malvern 2600 particle analyzer. The Malvern analyzer is a laser diffraction instrument that measures the droplet size based on the diffracted light energy caused by droplets passing through the area. analyzer sample.
    [81] The intensity of scattered light is measured using a series of semicircular photodiodes housed in the receiving unit. The Rosin-Rammler distribution function is used to convert the light intensity distribution to a drop size distribution function.
    [82] The test was performed using a 300 mm receiver lens. This lens configuration allows a measurement range of 1.2 and 564 μm, for the Malvern 2600 instrument. All tests were performed at a spray distance of 610 mm.
    [83] A Modular Spraying System from Spraying Systems Co.® Auto Jet® 2250 was used to control liquid pressure and flow rate. The AutoJet® Modular Spray system is a self-contained modular spray system that improves the performance of spray nozzles. Consisting of two basic components, an electrical control panel and a pneumatic control panel, the modular system provides the energy for a completely integrated system.
    [84] In a preferred embodiment, atomization inside the nozzle is aided with dry compressed air. The atomization air was at room temperature (20 ° C) for all tests. In addition, he was stationary and consistent through testing. Compressed air flow rates were measured with a calibrated thermal mass meter manufactured by Endress-Hauser. This meter measures air / nitrogen pressure and temperature at the measurement location to directly determine the mass flow rate. The high precision measuring range (± 1%) of this meter was from 0.0003 m3 / min to about 12.0 m3 / min (which is equal to 0.3 l / min to about 12000 l / min).
    [85] Dv0.5, D32, Dv0.1 and DV0.9 diameters were used to assess the drop size. The drop size terminology is as follows:
    [86] Dv0.5: Average volume diameter (also known as VMD or MVD). A means for expressing the drop size in terms of the volume of liquid sprayed. The VMD is a value where 50% of the total volume (or mass) of sprayed liquid is made up of drops with diameters larger than the average value and 50% smaller than the average value. This diameter is used to compare the change in drop size on average between test conditions.
    [87] D32: Sauter's average diameter (also known as SMD) is a means of expressing the fineness of a spray in terms of the surface area produced by the spray. Sauter's average diameter is the diameter of a drop that has the same volume to surface area ratio as the total volume of all drops to the surface area of all drops.
    [88] Dv0.1: it is a value where 10% of the total volume (or mass) of sprayed liquid is made of drops with diameters less than or equal to this value.
    [89] Dv0.99: it is a value where 99% of the total volume (or mass) of sprayed liquid is made of drops with diameters less than or equal to this value. This value can also be used as DMAX- FIG. 16 shows the performance comparison of a standard 1 / 4M-8 spray system nozzle spraying in open air (TC 1) to that of the same nozzle installed in the atomization device using the same slurry feed (TC 12). An important reduction in droplet size is observed.
    [90] TC 15 shows the performance of the best available Spray Systems technology to produce fine droplets with the Flomax X015 cloud forming nozzle under the same feeding conditions as TC 1. TC 12 clearly shows that the atomization device of this invention provides less droplet size distribution compared to the best available in the prior art.
    [91] The atomizer of the present invention provides micronized droplets with a diameter in the range of about 2 μm to about 12 μm.
    [92] It is at the user's discretion that commercially available liquid nozzles are used in the atomizing device, since liquid nozzle 2 is interchangeable with any suitable liquid nozzle, and its use in the atomizing device of the present invention will improve outstanding performance. In general, the performance of any nozzle can be improved when said nozzle is installed in an atomizing device of the present invention. Regardless of the size of the nozzle, since the converging airhead cone A, the housing, the nozzle tip or the converging airhead cone A that carries the nozzle tip 1, which is a particular modality, can be constructed in a personalized way to fit the selected nozzle.
    [93] A potential use could be, for example, in adsorbent injection technology, in which a proprietary material is broken into small droplets by the atomizer of the present invention in an industrial heating and energy cooler, in order to remove acid or toxic gas and heavy metals from the flue gas generated during combustion. Such a toxic acid or gas comprises, HCl, SO2, CO, NOx. Example for a heavy metal accumulated in such combustion processes is mercury (Hg).
    [94] The present invention also relates to a process for micronizing a fluid comprising the steps of providing an atomization device of the present invention, providing a fluid for micronizing in which the fluid is provided through the central throw tube (4) at the liquid nozzle (2), and in which a gas is provided through the air inlet (9), said gas being accelerated through the converging air transition cone (A) in a concurrent gas ring, and being connected with the sprayed fluid escaping from the nozzle thus forming droplets which are transported through the atomizer nozzle tip (1).
    [95] Said fluid comprising a liquid or a mixture of liquid, a suspension, a dispersion or an emulsion, and wherein said liquid or mixture of liquid, dispersion of a suspension or emulsion is a fertilizer or a crop protector or plant.
    [96] The present invention further relates to a process for micronizing a fluid, wherein the fluid is a fire-extinguishing agent.
    [97] Still further, the present invention relates to a process, in which the suspension is a suspension of mineral matter, or in which the dispersion is a dispersion of mineral matter.
    [98] The present invention also relates to the use of micronized droplets, in which such droplets are used in fertilization, plant crop protection.
    [99] An additional use of the micronized droplets according to the present invention is the use in fire fighting.
    [100] An additional use of such micronized droplets is in an oven adsorbent injection method, spray drying or fire fighting, in which the fluid is a dispersion or suspension of mineral matter.
    权利要求:
    Claims (35)
    [0001]
    1. Atomization device for obtaining droplets, comprising a nozzle tip (1), a liquid nozzle (2), a housing (3) comprising a converging air head, with an air transition cone (A) surrounding circulating the liquid nozzle (2) which is connected to a central throwing tube (4), said throwing tube being fed through an inlet (6), the housing (3) additionally comprising at least one air inlet (9) to supply a gas as a concurrent ring around the nozzle, characterized by the fact that the position of the liquid nozzle (2) that is connected to the central lance tube (4) is adjustable in such a way that the nozzle ( 2) can be moved into or out of the air transition cone (A).
    [0002]
    Atomization device according to claim 1, characterized by the fact that the nozzle tip (1) and the air transition cone (A) are connected to each other.
    [0003]
    Atomization device according to claim 2, characterized by the fact that the nozzle tip (1) connected with the air transition cone (A) are reversibly connected to the housing (3).
    [0004]
    4. Atomization device according to claim 3, characterized by the fact that the connection with the housing is established by an overlap housing with moving parts, where a part comprises the tip of the nozzle 1 connected to the air transition cone ( A), and the other part comprises the housing with the central throwing tube (4), said throwing tube being fed through an inlet (6), the housing (3) additionally comprising at least one air inlet (9, I) to supply a gas as a concurrent ring around the nozzle, the two parts sliding in relation to each other.
    [0005]
    5. Atomization device according to claim 3, characterized by the fact that the connection with the housing is established through the provision of the nozzle tip (1) connected to the air transition cone (A) in a mounting device ( MD1) as a first part, by providing the housing (3) with a mounting device (MD2) as a second part, and connecting said first part with said second part via the mounting device (MD1) and (MD2 ).
    [0006]
    Atomization device according to claim 5, characterized by the fact that the assembly through the mounting devices can be made by glue, screws, tube clamps, ring sleeve screws or other fixing means.
    [0007]
    Atomization device according to any one of claims 1 to 6, characterized in that the adjustment of the liquid nozzle (2) in relation to the air transition cone A is carried out by means selected from the movement of the tube of central throw (4) that carries the liquid nozzle (2) back and forth, or by positioning one or more spacer plates of the same thickness or of different thicknesses (S1, S2) between the mounting devices (MD1 ) and (MD2), or by combining both.
    [0008]
    Atomization device according to any one of claims 1 to 7, characterized in that a diffuser plate (DP) is present between the converging head cone and at least one air inlet (9, I) .
    [0009]
    Atomization device according to any one of claims 1 to 8, characterized in that the converging airhead cone (A) has an opening angle from 0 ° to 180 °.
    [0010]
    Atomization device according to any one of claims 1 to 9, characterized in that the ratio of the diameters of the nozzle tip (1) and the housing (3) is from 1: 1 to 1:10 , preferably from 1: 1 to 1: 7, more preferably from 1: 1 to 1: 4.
    [0011]
    Atomization device according to any one of claims 1 to 10, characterized in that the nozzle tip has a length to diameter ratio of from about 50: 1 to about 0.5: 1, preferably from about 20: 1 to about 1: 1, more preferably from about 15: 1 to about 5: 1.
    [0012]
    Atomization device according to any one of claims 1 to 11, characterized in that the tip of the nozzle (1) has an angular displacement that is between and including 180 ° to and including 90 °.
    [0013]
    Atomization device according to any one of claims 1 to 12, characterized in that a mixing chamber (5) is present just in front of the central tube (4) carrying the liquid nozzle (2).
    [0014]
    Atomization device according to claim 13, characterized in that the mixing chamber (5) comprises a mixing device selected from a high shear energized mixing device or a static one.
    [0015]
    Atomization device according to either of claims 13 or 14, characterized in that the mixing chamber can be in a separate device or housing (M) connected via at least one interconnection device (ICD) such as a tube, a hose or a pipe to the atomization head (H), comprising the atomizer nozzle tip (1), a liquid nozzle (2), the converging airhead housing (3), with the air transition (A), circling the liquid nozzle (2) which is connected to a central throw tube (4).
    [0016]
    16. Use of the atomization device as defined in any one of claims 1 to 15, characterized in that it is for spraying a fluid, in which the fluid is provided through the central throw tube (4) to the liquid nozzle (2 ), and in which a gas is provided through the air inlet (9), said gas being accelerated through the converging air transition cone (A) in a concurrent gas ring, and being connected with the sprayed fluid that escapes from the nozzle thus forming droplets which are transported through the atomizer nozzle tip (1).
    [0017]
    17. Use according to claim 16, characterized by the fact that the gas provided through the air inlet (9) is fed in volumes from about 0.0003 m3 / min to about 20 m3 / min , preferably from about 0.1 m3 / min to about 12 m3 / min, even more preferably from about 0.2 m3 / min to about 10 m3 / min, and even more preferable from about 0.4 m3 / min to about 6 m3 / min.
    [0018]
    18. Use according to claim 16 or 17, characterized in that the gas provided through the air inlet (9) has a pressure from about 0.001 to 0.6 MPa, preferably from about 0.002 up to about 0.5 MPa, more preferably from about 0.004 to about 0.45 '.
    [0019]
    19. Use according to any of claims 16 to 18, characterized in that the volume ratio of air to fluid provided sprayed from the nozzle is maintained in a ratio of from 100: 1 to about 8000: 1.
    [0020]
    20. Use according to any of claims 16 to 19, characterized in that the fluid provided through the lance tube has a flow rate of from about 0.05 l / min to about 5 l / min. min, preferably from about 0.1 l / min to about 4 l / min, more preferably from about 0.19 l / min to about 2.7 l / min.
    [0021]
    21. Use according to any of claims 16 to 20, characterized in that the gas provided by the inlet is a single gas or a mixture of gas such as air, nitrogen or noble gas, or mixtures thereof, hot steam or steam.
    [0022]
    22. Use according to any of claims 16 to 21, characterized in that the fluid provided through the throw tube is a liquid or a mixture of liquid, a suspension, a dispersion or an emulsion.
    [0023]
    23. Use according to claim 22, characterized by the fact that the suspension is a suspension of mineral matter.
    [0024]
    24. Use according to claim 22, characterized by the fact that the dispersion is a dispersion of mineral matter.
    [0025]
    25. Use according to either of claims 23 or 24, characterized in that the mineral material is selected from alkaline earth carbonates, alkaline earth hydroxides, alkaline earth oxides, or ash.
    [0026]
    26. Use according to claim 25, characterized in that the alkaline earth carbonates comprise natural soil calcium carbonate (GCC) such as marble, lime or limestone, synthetic calcium carbonate such as precipitated calcium carbonates (PCC) such as argonitic PCC, characteristic PCC and / or calcitic PCC, especially prismatic, rhombohedral or scalenohedral PCC or surface-modified calcium carbonates, and any similar fillers containing calcium carbonates such as dolomite or mixed carbonate based fillers; various materials such as talc or the like; mica, titanium dioxide clay, bentonite, magnesite, white satin, sepiolite, huntite, diatomite, silicates; and mixtures thereof.
    [0027]
    27. Process for micronizing a fluid, characterized by the fact that it comprises the steps of - providing an atomization device as defined in any of claims 1 to 15 - providing a fluid for micronizing in which the fluid is provided through the throw tube central (4) to the liquid nozzle (2), and in which a gas is provided through the air inlet (9), said gas being accelerated through the converging air transition cone (A) in a concurrent gas ring , and being connected with the sprayed fluid that escapes from the nozzle thus forming droplets which are transported through the atomizer nozzle tip (1).
    [0028]
    28. Process according to claim 27, characterized in that the fluid comprises a liquid or a mixture of liquid, a suspension, a dispersion or an emulsion.
    [0029]
    29. Process according to claim 28, characterized in that the liquid or liquid mixture is a fertilizer or a crop or plant protector.
    [0030]
    30. Process according to claim 28, characterized in that the fluid is a fire-extinguishing agent.
    [0031]
    31. Process according to claim 28, characterized by the fact that the suspension is a suspension of mineral matter.
    [0032]
    32. Process according to claim 28, characterized by the fact that the dispersion is a dispersion of mineral matter.
    [0033]
    33. Use of the process according to claim 29 characterized by the fact that it is in fertilization or crop or plant protection.
    [0034]
    34. Use of the process according to claim 30 characterized by the fact that it is in fire fighting.
    [0035]
    35. Use of the process according to claim 31 or 32, characterized by the fact that it is in an oven adsorbent injection method, in spray drying, or in fire fighting.
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    同族专利:
    公开号 | 公开日
    PL2731729T3|2017-08-31|
    CL2014000037A1|2014-08-22|
    TWI602617B|2017-10-21|
    CO6852050A2|2014-01-30|
    JP5934790B2|2016-06-15|
    TW201307493A|2013-02-16|
    LT2731729T|2017-05-10|
    RU2558106C1|2015-07-27|
    DK2731729T3|2017-05-08|
    BR112014000654A2|2017-02-14|
    TW201325734A|2013-07-01|
    EP2731729B1|2017-02-01|
    AU2012282573A1|2014-01-16|
    CA2840026C|2017-10-24|
    ES2624312T3|2017-07-13|
    CA2840026A1|2013-01-17|
    EP2554273A1|2013-02-06|
    HUE032183T2|2017-09-28|
    SI2731729T1|2017-05-31|
    JP2016155125A|2016-09-01|
    JP2014527903A|2014-10-23|
    US20190134653A1|2019-05-09|
    US10220398B2|2019-03-05|
    AU2012282573B2|2015-08-13|
    CN103764295A|2014-04-30|
    HRP20170626T1|2017-06-30|
    ZA201400197B|2015-05-27|
    CN103764295B|2017-05-31|
    KR20140035519A|2014-03-21|
    EP2731729A1|2014-05-21|
    US20150013769A1|2015-01-15|
    PT2731729T|2017-05-05|
    WO2013007673A1|2013-01-17|
    RS55857B1|2017-08-31|
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    法律状态:
    2018-12-11| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|
    2020-03-17| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|
    2020-10-06| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|
    2020-10-20| B09W| Correction of the decision to grant [chapter 9.1.4 patent gazette]|Free format text: RETIFICACAO DO DEFERIMENTO NOTIFICADO NA RPI 2596 DE 06/10/2020. |
    2020-12-22| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 09/07/2012, OBSERVADAS AS CONDICOES LEGAIS. |
    优先权:
    申请号 | 申请日 | 专利标题
    US201161506306P| true| 2011-07-11|2011-07-11|
    US61/506,306|2011-07-11|
    EP20110176306|EP2554273A1|2011-08-02|2011-08-02|Atomizing nozzle device and use of the same|
    EP11176306.6|2011-08-02|
    PCT/EP2012/063358|WO2013007673A1|2011-07-11|2012-07-09|Atomizing nozzle device, atomizing process and use|
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