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    • 专利摘要:
    Annealed Cold Rolled Steel Sheet and Process for Manufacturing an Annealed Cold Rolled Steel Sheet The present invention is concerned with the manufacture of steel sheets having high mechanical strength, uniform elongation and v-folding greater than 90 °. . The cold rolled and annealed steel sheet has a mechanical strength of 1000 mpa or greater, with a uniform elongation greater than or equal to 12%, the composition of which is, by weight, 0,15% <c <0 , 25%, 1.8% <mn <3.0%, 1.2% <si <2%, al <0.10%, 0% <cr <0.50%, 0% <cu <1% , 0% <ni <1%, s <0.005%, p <0.020%, nb <0.015%, ti <0.020%, v <0.015%, co <1%, n <0.008%, b <0.001%; where mn + ni + cu <3%, with the remainder of the composition consisting of iron and unavoidable impurities resulting from the preparation, and the microstructure consisting of 5 to 20% polygonal ferrite in superficial proportions, 10 to 15% residual austenite, 5 to 15% martensite, the remainder consists of slat-shaped bainite and comprises, among the slats, carbides such that the number n of inter-slat carbides over 0.1 micrometer per surface unit is less than or equal to 50000 / mm2.
    公开号:BR112013028841B1
    申请号:R112013028841-8
    申请日:2012-05-03
    公开日:2019-03-19
    发明作者:Sébastien Allain；Arnaud Hennion；Jan Mahieu；Mickaël Denis Crouvizier；Thierry Mastrorillo
    申请人:ArcelorMittal Investigación y Desarrollo, S.L.；
    IPC主号:
    专利说明:

    “COLD AND RECOVERED STEEL SHEET PLATE AND PROCESS OF MANUFACTURING A COLD LAMINATED STEEL SHEET” Field of the Invention [001] The present invention deals with the manufacture of steel plates known as “multiphase”, which simultaneously present a resistance mechanical and a deformation capacity that allows cold forming operations. The present invention deals more precisely with steels that have a mechanical resistance greater than 1000 MPa, a uniform elongation, greater than 12%, a V-foldability greater than 90 °. Motor land vehicles (automobiles, combine harvesters, trailers, semi-trailers ...) constitute, in particular, a field of application for these steel plates, with potential applications in structural parts, reinforcement elements and even in the manufacture of resistant parts abrasion.
    Background to the Invention [002] The strong demand for reducing greenhouse gas emissions, coupled with the growing safety requirements in automobiles and fuel prices have led motor vehicle builders to increasingly use steels with resistance improved mechanics in the body in order to reduce the thickness of the parts and, therefore, the weight of the vehicles, while maintaining the mechanical resistance performances of the structures. In this perspective, steels that combine high strength with sufficient plasticity for forming without the appearance of cracks are becoming increasingly important. Several families of steels that offer different levels of mechanical strength have been proposed over time and in succession.
    [003] Steels have been proposed that comprise microalloy elements whose hardening is obtained simultaneously by reducing the
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    2/25 grain size and fine precipitations. The development of increasingly harder steels followed, then, the growth of steels known as “Dual Phase” in which the presence of martensite within a ductile ferritic matrix allows to obtain a mechanical resistance greater than 400 MPa associated with a good tendency to cold forming.
    [004] In order to achieve characteristics of mechanical strength, ductility and plasticity even more advantageous for the automotive industry, for example, “TRIP” steels for “Transformation Induced Plasticity” were developed. These steels have a complex structure comprising: a ductile structure, ferrite, as well as martensite, which is a hard structure that contributes to high mechanical characteristics and residual austenite that contributes at the same time to strength and ductility thanks to the TRIP effect .
    [005] This TRIP effect designates a mechanism according to which, under further deformation, for example, during a uniaxial stress, the residual austenite of a TRIP steel plate or disk progressively changes into martensite, which translates into a significant consolidation, thus slowing the appearance of cracks. However, steels known as TRIP have mechanical strengths below 1000 Mpa because their polygonal ferrite content, which is a low strength and very ductile structure, is greater than a quarter of the total surface ratio.
    [006] In order to meet this demand for steels with mechanical strength greater than 1000 MPa, it is therefore necessary to reduce the fraction of structure with low mechanical strength and replace it with a more hardening phase. However, it is known that in the field of carbon steels, an increase in mechanical strength is generally accompanied by a loss of ductility. In addition, manufacturers of land-based motor vehicles specify increasingly complex parts that require steels that
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    3/25 allow to reach a foldability greater than or equal to 90 ° without the appearance of cracks.
    [007] The contents of the chemical elements indicated below are in mass percentage.
    [008] The relevant state of the art includes relative W02007077933, which describes a microstructure composed of bainite, martensite and residual austenite. The chemical composition of the claimed sheet comprises 0.10-0.60% C, 1.0-3.0% Si, 1-3.5% Mn, up to 0.15% P, up to 0.02% S, up to 1, 5% Al, and 0.003 to 2% Cr, the rest being iron and impurities. The microstructure within the scope of this patent is obtained during annealing by maintenance after primary cooling under the point of initiation of martensitic transformation Ms. The result is a microstructure comprising a mixture of tempered and / or partitioned martensite. The main claimed advantage is an improvement in resistance to hydrogen damage. The presence of martensite, which is a hardener component in a softer bainitic matrix, makes it impossible to achieve the ductility and foldability expected within the scope of the present invention.
    [009] The state of the art also includes patent GB 2 452 231 which describes the manufacture of sheets with a strength greater than 980 MPa with a satisfactory strength limit and a satisfactory tendency to expand the hole and spot welding. The chemical composition of the plate comprises 0.12-0.25% C, 1.0-3.0% Si, 1.5-5% Mn, up to 0.15% P, up to 0.02% S up to 0.4% of Al, the rest being iron and impurities. In addition, the ratio of the Si content weight to that of C, Si / C is included in the range 7-14. The microstructure of the sheet comprises at least 50% of bainitic ferrite, at least 3% of residual austenite in slats, and of austenite in solid form, whose average size is less than or equal to 10 micrometers, and this austenite in solid form is present at
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    4/25 amount of 1% up to half the austenite content in slats. This patent does not provide any information about the foldability of the produced sheet and mentions the absence of carbides in the bainite.
    Description of the Invention [010] The purpose of the present invention is to solve the aforementioned problems. It aims to provide a cold rolled steel that has a mechanical strength greater than 1000 MPa, together with a uniform elongation greater than 12%. The present invention also aims to provide steel with a tendency to conform such that an angle of 90 ° is reached during a V-fold without the appearance of cracks.
    [011] The present invention advantageously also aims to provide a steel whose composition does not contain expensive micro-alloy elements, such as titanium, niobium, or vanadium. In this way, the manufacturing cost is reduced and the thermo-mechanical manufacturing schemes are simplified.
    [012] For this purpose, the object of the present invention is a cold-rolled and annealed steel sheet with mechanical strength greater than or equal to 1000 MPa, with uniform elongation greater than or equal to 12%, the composition of which comprises the contents being expressed in weight,
    0.15% <C <0.25%
    1.8% <Mn <3.0%
    1.2% <Si <2%
    Al <0.10%
    0% <Cr <0.50%
    0% <Cu <1%
    0% <Ni <1%
    S <0.005%
    P <0.020%
    Nb <0.015%
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    5/25
    ΊΊ <0.020%
    V <0.015%
    Co <1%
    N <0.008%
    B <0.001% and it should be clear that Mn + Ni + Cu <3%, the rest of the composition being made up of iron and unavoidable impurities, which result from the elaboration, with the microstructure being constituted, in superficial proportions, of 5 to 20% of polygonal ferrite, from 10 to 15% residual austenite, from 5 to 15% martensite, and the remainder is made of slat-shaped bainite and which comprises such carbides such that the number N of the inter-slat carbides size greater than 0.1 micrometer per unit area is less than or equal to 50,000 / mm 2 .
    [013] The plate, according to the present invention, can, in addition, have the following characteristics, taken alone or in combination:
    - the composition comprises, with the content expressed by weight,
    - 0.18% <C <0.22%
    - the composition comprises, with the content expressed by weight
    - 2% <Mn <2.6%
    - the composition comprises, with the content expressed by weight
    -1.4% <Si <1.8%
    - the composition comprises, with the content expressed by weight
    - 0% <Cr <0.35% [014] - The V-angle at which the crack will appear is greater than or equal to 90 °.
    [015] - the steel sheet also comprises a coating
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    6/25 zinc or zinc alloy.
    [016] The present invention also has as its object a process of manufacturing a cold-rolled steel sheet, annealed, with a resistance greater than or equal to 1000 MPa and with an elongation greater than or equal to 12% comprising the steps, according to which :
    - a steel of composition according to the present invention is obtained, and
    - said steel is cast in the form of a semi-product, and
    - said semi-product is brought to a temperature T reC h above 1150 ° C to obtain a reheated semi-product, after
    - said reheated semi-product is hot rolled, and the hot rolling end temperature Tn is greater than or equal to 850 ° C to obtain a hot rolled sheet, and
    - said sheet is hot-coiled at a temperature Tbob between 540 and 590 ° C to obtain a hot-rolled sheet, and
    - said coiled hot-rolled sheet is cooled to room temperature,
    - an annealing of said base of said hot-rolled coiled sheet is carried out in such a way that the mechanical resistance is less than or equal to 1000 MPa at any point of said hot-rolled coiled sheet, and
    - said annealed hot-rolled sheet is coiled and pickled in order to obtain a hot-rolled sheet suitable for cold rolling, and
    - said hot-rolled sheet suitable for cold rolling is laminated with a reduction rate between 30 and 80% in order to obtain a cold-rolled sheet, and,
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    7/25
    - said cold-rolled sheet is annealed, heating it at a speed Vc comprised between 2 and 6 ° C per second to a temperature Ti comprised between Ac3-15 ° C and Ac3-45 ° C, for a time ti superior or equal to 50 seconds, then
    - said cold-rolled sheet is cooled by subjecting it to a first cooling stage, at a cooling speed between 50 and 1500 ° C / s; and then to a second cooling step such that the end cooling temperature Tfr of said second step is comprised between a temperature Tfri equal to Ms20 ° C and a temperature Tfr2 equal to Ms + 40 ° C, and
    - said cold-rolled sheet is kept in the temperature range comprised between Tw and Tra for a time t2 comprised between 100 and 1000 seconds, and,
    - said cold-rolled sheet is cooled at a speed Vr2 between 3 and 25 ° C per second to room temperature, in order to obtain a cold-rolled and annealed sheet.
    [017] The process according to the present invention may, in addition, have the following characteristics, taken alone or in combination:
    - the temperature Tn is greater than or equal to 900 ° C,
    - the basic annealing comprises a maintenance whose temperature Tm and time tm are such that:
    2.29 x Tm (° C) + 18.6 x tm (h)> 1238, the maintenance temperature Tm being more than 410 ° C,
    - the temperature T1 is between 790 ° C and 820 ° C,
    - a cold-rolled sheet annealed according to the present invention is obtained which is coated with zinc or zinc alloy,
    - a cold-rolled sheet annealed in accordance with the
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    8/25 the present invention, which is annealed at a maintenance temperature Tbase comprised between 150 ° C and 200 ° C for a maintenance time tbase comprised between 10h and 48h.
    [018] The present invention also relates to the use of a cold-rolled and annealed sheet, or a coated sheet, according to the present invention, or manufactured by a process according to the present invention for the manufacture of parts for land motor vehicles.
    Brief Description of the Drawings [019] Other features and advantages of the present invention will appear throughout the description below, given as an example and made with reference to the attached figures, in which:
    - figure 1 shows the dimensions of the tensile specimen used to obtain the mechanical properties,
    figure 2 shows an example of a microstructure of a steel sheet according to the present invention,
    figure 3 shows an example of a microstructure of a steel sheet that does not correspond to the present invention.
    Description of Realizations of the Invention [020] In the figures mentioned above, FP indicates polygonal ferrite, B indicates bainite, MA indicates the islands of martensite and austenite.
    [021] Research carried out within the scope of the present invention could show the interest of the presence of polygonal ferrite, which is characterized by a displacement density lower than that of bainitic ferrite. Polygonal ferrite is, in effect, formed during intercritical annealing and makes it possible to achieve greater than 90 ° bending during V-bending as well as uniform elongation above 12%.
    [022] The influence of the presence of polygonal ferrite that forms under the point Ac3, in the intercritical field (ferrite + austenite) during
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    9/25 annealing maintenance was studied. The presence of this ferrite in a bainitic matrix that comprises residual austenite, and also inevitably martensite, could make it possible, due to the difference in hardness between these different compounds, that the plasticity would be reduced. Surprisingly, the presence of polygonal ferrite between 5 and 20% proved to be a factor in improving the foldability of the sheet of the present invention, which allowed it to be above 90 ° in V-fold angle without the appearance of crack.
    [023] Likewise, it could be demonstrated that the absence of this polygonal ferrite, also impaired the ductility measured by the uniform elongation criterion.
    [024] Regarding the chemical composition of steel, carbon has an important role in the formation of the microstructure and in the mechanical properties in terms of ductility and resistance via the effect called TRIP that it will produce with the residual austenite. From the mostly austenitic structure formed at high temperature during maintenance at temperature ΊΊ, a cooling is carried out, followed by a maintenance during which a bainitic transformation occurs. During this occurrence, bainite is initially formed inside a matrix still mostly austenitic. The carbon, which has a markedly lower solubility in ferrite compared to that in austenite, is discarded in said austenite and partially precipitates as very fine carbides. The fineness of the carbides may be such that the number N of said inter-slat carbides of a size greater than 0.1 micrometer per unit area is less than or equal to 50,000 / mm 2 .
    [025] Thanks to certain alloying elements present in the compositions according to the present invention, in particular Silicon, the precipitation of carbides, in particular cementite, intervenes in a
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    10/25 limited. Thus, austenite, not yet transformed, progressively enriches itself with carbon practically without a precipitation of non-fine carbides intervening at the austenite-bainite interface. This enrichment is such that the austenite is stabilized, that is, that the martensitic transformation from that austenite is limited to the desired proportions of 5 to 15% during cooling and this, up to room temperature. Thus, a controlled amount of martensite appears, contributing to increased mechanical strength in a controlled manner.
    [026] According to the present invention, the carbon content, by weight, is between 0.15 and 0.25%. If the carbon content of the present invention is below 0.15% by weight, the mechanical strength becomes insufficient and the stability of the residual austenite is insufficient. Above 0.25%, weldability becomes increasingly reduced, so low tenacity microstructures are formed in the Thermally Affected Zone (ZAT) or in the molten zone, in the case of autogenous welding; however, the TRIP effect would be improved above 0.25% carbon.
    [027] According to a preferred mode, the carbon content is comprised between 0.18 and 0.22%. Within this range, weldability is satisfactory, the stabilization of austenite is optimized and the martensite fraction is in the range desired by the present invention.
    [028] Manganese is a hardener with a solid replacement solution; it stabilizes austenite and lowers the temperature of transformation Ac3. Manganese therefore contributes to an increase in mechanical strength. According to the present invention, a minimum content of 1.8% by weight is necessary in order to obtain the desired mechanical properties. However, above 3.0%, its gamma-like character leads to the formation of a very marked banded structure that can impair the forming properties of the automotive structure part.
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    11/25 coatability will be reduced. Preferably, a range of manganese content comprised between 2% and 2.6%; thus a satisfactory mechanical strength is combined without increasing the risk of forming structures in bands harmful to conformation or increasing the temperability in the welded alloys, which would impair the welding ability of the plate of the present invention.
    [029] The stabilization of residual austenite was made possible by the addition of silicon, which considerably slows down the precipitation of carbides during the annealing cycle and more particularly during bainitic transformation. This is due to the fact that the solubility of Silicon in cementite is very weak and that this element increases the activity of carbon in austenite. All cementite formation will therefore be preceded by a Si rejection step at the interface. The carbon enrichment of austenite therefore leads to its stabilization at room temperature on the annealed steel sheet. Then, the application of an external pressure, of conformation, for example, will lead to the transformation of this austenite into martensite. This transformation also results in improved damage resistance. With regard to the properties desired by the present invention, an addition of silicon in an amount greater than 2% will appreciably promote ferrite, and the desired mechanical strength would not be achieved and, in addition, very adherent oxides would form which would lead surface failures; the minimum content must also be fixed at 1.2% by weight to obtain the stabilizing effect on austenite. Preferably, the silicon content will be between 1.4 and 1.8% in order to optimize the aforementioned effects.
    [030] The chromium content must be limited to 0.5%; this element makes it possible to control the formation of pro-eutectoid ferrite on cooling during annealing from said temperature Ti; this ferrite, in quantity
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    High 12/25 decreases the mechanical strength required for certain parts desired by the present invention. This element allows to harden and refine the bainitic microstructure. Preferably, the chromium content will be less than 0.35% for cost reasons and to avoid hardening too hard.
    [031] Nickel and copper have effects substantially similar to that of manganese for the present invention, but have different weights with regard to their stabilizing power for austenite. That is why the combination of these three elements in the chemical composition of the present invention must respect the following relationship: Mn + Ni + Cu <3%.
    [032] In amounts greater than 1%, nickel, which is a potent austenite stabilizer, will promote a very pronounced stabilization of the latter; transformation by mechanical request will be more difficult to obtain and the effect on ductility will be less. Above 1%, the cost of adding this alloying element is also excessive.
    [033] In an amount greater than 1%, copper, which is also a stabilizer of austenite, will promote a very pronounced stabilization of the latter; transformation by mechanical request will be more difficult to obtain and the effect on ductility will be less. Above 1%, the cost of adding this alloying element is also excessive and can cause defects in hot forging.
    [034] The aluminum content is limited to 0.10% by weight; this element is a powerful alpha that favors the formation of ferrite. A high aluminum content would increase the Ac3 point and thus make the industrial process costly in terms of energy input for annealing.
    [035] It is also worth remembering that high levels of aluminum increase the erosion of refractories and the risk of obstruction of the nozzles during steel casting upstream of the rolling mill. In addition, aluminum secretes negatively and can lead to macrosegregations. In excessive quantity,
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    13/25 aluminum reduces hot ductility and increases the risk of defects in continuous casting. Without strict control of the casting conditions, defects of the micro and macrosegregation type cause, in fine, a central segregation on the annealed steel sheet. This central band will be harder than its surrounding matrix and will damage the plasticity of the material.
    [036] Above a sulfur content of 0.005%, ductility is reduced due to the excessive presence of sulfides such as MnS (manganese sulfides) which decrease the tendency to deformation.
    [037] Phosphorus is an element that hardens in solid solution, but that considerably decreases spot weldability and hot ductility, particularly due to its tendency to segregate to grain junctions or its tendency to co-segregate with manganese. For these reasons, its content should be limited to 0.020% in order to obtain a good tendency to spot welding.
    [038] Molybdenum is limited to the values of impurities, although it can play an effective role in temperability and delay the appearance of bainite. However, its addition exceeds the cost of adding alloying elements excessively and its use is therefore limited for economic reasons.
    [039] Boron acts strongly on the hardness of steel. It limits the activity of carbon, and limits the diffusional phase transformations (ferritic or bainitic transformation during cooling), thus leading to the formation of hardening phases, such as martensite. This effect is not desirable in the present invention, since what is desired is to promote bainitic transformation in order to stabilize austenite and avoid the formation of a very strong surface ratio of martensite. Thus, the boron content is limited to 0.001%.
    [040] Micro-alloy elements such as niobium, titanium and
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    14/25 vanadium are respectively limited to the maximum levels of 0.015%, 0.020% and 0.015%, as these elements have the particularity of forming precipitates that harden with carbon and / or nitrogen which also tend to reduce the ductility of the product. In addition, they delay recrystallization during annealing and therefore thin the microstructure, which also hardens the material and degrades its ductility.
    [041] Steel can also comprise cobalt in levels less than or equal to 1%, as this hardening element allows to increase the carbon content in the residual austenite. However, its use is limited in the present invention for reasons of cost.
    [042] The rest of the composition consists of iron and unavoidable impurities that result from elaboration.
    [043] According to the present invention, the steel microstructure is made up, in surface proportions, of 5 to 20% polygonal ferrite, 10 to 15% residual austenite, 5 to 15% martensite, and the remainder it consists of bainite in the form of slats and which comprises, between said slats, carbides such as the number N of inter-slat carbides with a size greater than 0.1 micrometer per unit area is less than or equal to 50000 / mm 2 . This majority bainitic structure provides good resistance to damage. Residual austenite confers strength and ductility, polygonal ferrite which also causes ductility and martensite which increases the mechanical strength of the sheet. Polygonal ferrite is distinguished from bainitic ferrite in that it comprises a significantly lower displacement density, as well as a carbon content in solid solution that is also lower than that of bainitic ferrite.
    [044] Less than 10% residual austenite does not significantly increase uniform elongation. Thus, the uniform elongation of 12% will not be achieved. Above 15%, it would be
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    15/25 high carbon content is required to sufficiently stabilize and this would impair steel weldability. Preferably, the carbon content of the residual austenite is greater than 0.8%, in order to obtain a sufficiently stable residual austenite at room temperature.
    [045] The presence of martensite between 5% and 15% allows to achieve the desired mechanical strength within the scope of the present invention, however, above 15%, the martensitic fraction in surface percentage would cause the plate to lose its ductility in the direction of uniform elongation and foldability.
    [046] Above 5%, the desired mechanical strength is not achieved. Preferably, a martensite content greater than 10% will be desirable to obtain a certain safety margin in relation to mechanical strength.
    [047] Polygonal ferrite allows, within the scope of the present invention, to improve ductility both through uniform elongation and through V-folding to reach the 90 ° targeted at an internal angle. The ferrite content is between 5 and 20%. Ideally, it will be between 12 and 20% to ensure better ductility and a safety margin over uniform stretching.
    [048] Finally, bainite, expelling carbon towards residual austenite during its formation, enriches the latter and thus allows it to stabilize it, being at the same time the plate matrix of the present invention.
    [049] Figure 2 shows an example of a microstructure of a steel plate, according to the present invention, seen under a scanning electron microscope. Residual austenite occupies, here, a surface fraction equal to 15%, it appears in white, in the form of islands or films. The martensite is present in the form of islands in association with the residual austenite, the group commonly called MA islands is revealed with a
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    16/25 granular appearance due to the bites of the chemical attack of the reagent (Nital). The martensite has a surface content, here, equal to 11%. Polygonal ferrite appears with a concave relief. Here, bainite is in the form of the lamellar constituent indicated by the black arrows in figure 2.
    [050] Within certain islands, the local carbon content and, therefore, the local temperability may vary. Residual austenite is then locally associated with martensite within that same island which is designated by the term “M-A” islands, associating martensite and residual austenite.
    [051] The number of carbides larger than 0.1 micrometer in the microstructure is limited. It has been shown that N, the number of inter-slat carbides with a size greater than 0.1 micrometer per unit area, should preferably be less than 50,000 / mm 2 to limit damage in the event of a subsequent request, such as , during hole expansion or V-bend tests. In addition, the excessive presence of coarse carbides can give rise to an early onset of rupture during further forming.
    [052] The plate, according to the present invention, can be manufactured by any appropriate process. For example, the process according to the present invention can be used, which can comprise the steps that will be described.
    [053] A composition steel according to the present invention is obtained first. Then, a semi-product is cast from this steel. This casting can be carried out in ingots or without interruption in the form of plates.
    [054] The melted semi-products can then be brought to a Trech temperature above 1150 ° C to obtain a re-heated semi-product in order to reach at any point a temperature favorable to the high deformations that the steel will undergo during rolling. This interval
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    17/25 temperature allows to be in the austenitic field. However, if the temperature T reC h is above 1275 ° C, the austenitic grains grow undesirably and will cause a more coarse final structure.
    [055] Of course, it is also possible to laminate hot directly after casting without reheating the plate.
    [056] The semi-product is, therefore, hot rolled in a temperature range in which the steel structure is totally austenitic: if the end temperature of rolling mill TA is lower than the starting temperature of the transformation of austenite into ferrite to cooling Ar3 , the ferrite grains are cold rolled by rolling and the ductility is considerably reduced.
    [057] The laminated product is then hot rolled at a temperature Tbob between 540 and 590 ° C. This temperature range allows to obtain a complete bainitic transformation during the quasi-isothermal maintenance associated with winding followed by a slow cooling. A winding temperature above 590 ° C leads to the formation of unwanted oxides. When the winding temperature is excessively low, the product's hardness is increased, which increases the effort required during subsequent cold rolling.
    [058] Next, the hot rolled product is pickled, if necessary, according to a process known per se.
    [059] An annealing known as the base of the coiled sheet can be carried out below in such a way that the maintenance temperature Tm is above 410 ° C and that Tm and the maintenance time tm are such as:
    2.29 x Tm (° C) + 18.6 x tm (h)> 1238 [060] This heat treatment allows to obtain a mechanical resistance of less than 1000 MPa in any point of the hot-rolled sheet, and the difference of hardness between the center of the plate and the
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    18/25 edges are thus minimized. This considerably facilitates the next cold rolling step by softening the formed structure.
    [061] A cold rolling with a reduction rate comprised, preferably, between 30 and 80% is carried out below.
    [062] The cold rolled product is then heated, preferably inside a continuous annealing installation, at an average heating speed V c comprised between 2 and 6 ° C per second. In relation to the annealing temperature T1 below, this heating speed range allows to obtain a fraction of non-recrystallized ferrite strictly below 5%.
    [063] Heating is carried out to an annealing temperature Ti between the temperature Ac3-15 ° C, and Ac3-45 ° C, that is, in a particular temperature range of the intercritical domain in order to obtain a structure not exempt of polygonal ferrite formed in the intercritical. To determine the value of Ac3, for example, a dilatometric method known per se can be used.
    [064] When Ti is less than (Ac3-45 ° C), the structure can comprise a significant fraction of ferrite and the mechanical characteristics desired by the present invention are not obtained. Conversely, if Ti is above Ac3-15 ° C and there is no ferrite formation during cooling following maintenance at Τι, uniform elongation and foldability (V-bend test) are outside the scope of the present invention, that is, 12% uniform elongation and 90 ° in V-fold without cracking. In addition, when the temperature ΊΊ approaches the critical point Ac3, this presents a risk, therefore: industrial conditions may fluctuate slightly during production. Thus, at the end of Ti maintenance, the microstructure can be either entirely austenitic or partially ferritic, with a very small fraction of ferrite that
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    19/25 would be less than 5%. This generates unstable mechanical properties for the sheet produced at the end of the process, which would be detrimental to the final shaping of frame parts for land motor vehicles.
    [065] An annealing temperature Ti according to the present invention allows to obtain an amount of intercritical austenite sufficient to subsequently form, during cooling, bainite in an amount such that the residual austenite will be sufficiently stabilized and the desired mechanical characteristics will be achieved.
    [066] A minimum maintenance time ti, greater than or equal to 50s at temperature Ti allows the dissolution of previously formed carbides, and above all, a sufficient transformation into austenite. A maintenance time in excess of 500s is hardly compatible with the productivity requirements of continuous annealing installations, in particular the roll speed of the coil. The maintenance time ti is, therefore, between 50 and 500s.
    [067] At the end of the annealing maintenance, the plate is cooled until it reaches a temperature preferably between 370 and 430 ° C, the ideal temperature being between Ms-20 ° C and Ms + 40 ° C, where the cooling speed Vref must be fast enough to prevent the formation of perlite. Therefore, the first cooling step is such that the cooling speed Vri is between 50 and 1500 ° C per second.
    [068] A partial transformation of austenite into ferrite can occur at this stage in the first stage of cooling. It allows, when carbon is expelled towards austenite, to stabilize austenite to promote the TRIP effect, since carbon is poorly soluble in ferrite. The carbon content in the residual austenite will advantageously exceed 0.8% in order to stabilize it in ambient conditions. The objective of the second stage of
    Petition 870180144965, of 10/26/2018, p. 34/45
    20/25 cooling is to avoid the formation of perlite before maintenance in the range of 370 to 430 ° C.
    [069] The maintenance time in the temperature range of 370 ° C to 430 ° C must be greater than 100 seconds, in order to allow the bainitic transformation and, therefore, the stabilization of the austenite by enriching the austenite with carbon. Maintenance time must also be less than 1000s in order to limit the surface proportion of bainitic ferrite. This last restriction also prevents the formation of coarse carbides, larger than 0.1 micrometer with a density greater than 50000 / mm 2 .
    [070] The plate is then cooled at a speed Vr2 between 3 and 25 ° C / s to room temperature. The result is a cold-rolled and annealed steel sheet comprising 5 to 20% polygonal ferrite, 10 to 15% residual austenite and 5 to 15% martensite, and the rest consisting of bainite.
    [071] A basic post-annealing heat treatment is then advantageously carried out so that the cold-rolled and annealed sheet is maintained at a maintenance temperature Tbase comprised between 150 ° C and 200 ° C for a maintenance time as well between 10 am and 48 am in order to improve the elasticity limit and foldability.
    [072] In addition, the inventors found that small variations in the manufacturing parameters under the conditions defined in the process according to the present invention do not result in major changes in the microstructure or mechanical properties, which is an advantage for the stability of the characteristics of the manufactured products.
    [073] The present invention will now be illustrated from the following examples given by way of non-limitation.
    Petition 870180144965, of 10/26/2018, p. 35/45
    21/25
    Examples [074] Two steels were prepared, whose compositions are shown in table 1 below, expressed in percentage by weight.
    ç Mn Sj Al Cr Ass Ni s P N Ac3 Ms THE 0.196 2,195 1.528 0.038 0.245 0.009 0.019 0.002 0.013 0.004 835 392 B 0.19 1.49 1.45 <0.01 0.61 0.5 0.49 0.002 0.016 <0.01 840 403
    Table 1
    Steel Compositions Used, in which the Balance is Made of Iron (% Weight) [075] Steel A has a chemical composition according to the present invention, whereas steel B, because it has a very high Cr content, is a reference that is not in accordance with the present invention.
    [076] The elements that are present in a percentage strictly less than 0.01 are the elements whose content is considered as. In other words, this element was not deliberately added, but its presence is due to the impurities of the other alloy elements.
    [077] Plates that correspond to the above compositions were produced according to the manufacturing conditions set out in table 2.
    [078] A and B steel compositions were subjected to different annealing conditions. The conditions before hot rolling are identical with heating at 1250 ° C, an end rolling temperature of 920 ° C and a winding temperature of 550 ° C. All hot rolled products are then pickled and then cold rolled with a reduction rate between 30 and 80%.
    [079] Table 2 indicates the manufacturing conditions for the sheets annealed after cold rolling with the following names:
    - maintenance temperature: Ti
    - end cooling temperature Tfr
    Petition 870180144965, of 10/26/2018, p. 36/45
    22/25
    - maintenance time at Tfr: ti
    - basic post-annealing treatment: YES or NO.
    [080] The basic post-annealing treatment, if carried out, is carried out for 24 hours with a temperature increase up to 170 ° C and maintained at that temperature for 10 hours and then free cooling.
    [081] Cooling speeds between ΊΊ and Tfr are all between 50 and 1500 ° C / s.
    ID Initial chemical composition Type Final thickness (mm) Ti (° C) Tfr (° C) you (S) Basic post-annealing 11 THE Invention 0.77 805 390 181 YES I2 THE Invention 0.77 802 390 181 YES I3 THE Invention 0.77 807 400 181 YES I4 THE Invention 0.77 813 397 181 YES I5 THE Invention 0.77 816 410 181 YES I6 THE Invention 0.77 812 375 181 YES I7 THE Invention 0.77 810 410 217 YES I8 THE Invention 0.77 809 410 255 YES I9 THE Invention 0.77 807 405 289 YES 110 THE Invention 0.77 807 385 289 YES 111 THE Invention 0.77 810 410 217 NO 112 THE Invention 0.77 809 410 255 NO 113 THE Invention 0.77 807 405 289 NO 114 THE Invention 0.77 807 385 289 NO R1 THE Reference 0.87 836 412 217 YES R2 THE Reference 0.87 836 405 217 YES R3 THE Reference 1.5 846 410 289 YES R4 THE Reference 1.5 846 402 289 YES R5 B Reference 1.5 890 400 300 NO
    Table 2
    Annealing Conditions of Examples and Counterexamples [082] References R1 to R5 in table 2 refer to
    Petition 870180144965, of 10/26/2018, p. 37/45
    23/25 steel manufactured under conditions that are not in accordance with the present invention. The parameters that are not in accordance with the present invention are underlined. It should be noted that the four references R1 to R4, from composition A, are not in accordance with the present invention, because the holding temperature ΊΊ is above Ac3-15 ° C. Ac3 here corresponds to 835 ° C by dilatometric measurement. On the other hand, the reference R5, from composition B which is not in accordance with the present invention, was also annealed above the point of Ac3-15 ° C.
    [083] Examples 11 to 114 are those claimed by the present invention. Table 3 shows the microstructural properties obtained for the analyzed samples in which residual austenite is indicated by yr, polygonal ferrite by a, martensite by M, and bainite by B. These values are indicated in surface percentage.
    ID Type yr α M B 11 Invention 15 14 11 60 I2 Invention 15 20 15 60 I4 Invention 14 19 13 54 I5 Invention 10 13 14 63 I6 Invention 14 14 14 58 R1 Reference 15 0 22 63 R5 Reference 14 0 19 67
    Table 3
    Surface Proportions of Constituents (Invention and Reference) [084] The mechanical properties are measured below, using an ISO 20x80 specimen with the dimensions in Table 4 illustrated by Figure 1. The uniaxial tractions that allow to obtain these properties Mechanics were applied in the direction parallel to that of cold rolling.
    Type B Lo Lc R T Lt Outline dimension ISO 20x80 20 80 100 20 30 260 260 x 32
    Petition 870180144965, of 10/26/2018, p. 38/45
    24/25
    Table 4
    Dimensions of the Tensile Specimens, Expressed in mm [085] All the plates according to the present invention have a slat-shaped bainite with inter-slat carbides such that the N number of these carbides larger than 0.1 micrometer per unit area is less than or equal to 50000 / mm 2 .
    [086] During the V-fold test, the appearance of crack in the material is manifested by a 5% drop in the force applied by the machine during the sheet bending. The test is then interrupted at this stage and the internal angle is measured after the elastic return, its difference with 180 ° gives the complementary angle that must be greater than 90 ° within the scope of the present invention.
    [087] The mechanical tensile properties obtained are shown in table 5 below with the following abbreviations:
    - the yield strength: Re
    - mechanical resistance: Rm
    - uniform stretching: Al. Unif.
    - V-folding with the complementary angle (°) from which the crack appears: V bend.
    - Ne: Not rated
    ID Re (Mpa) Rm (Mpa) Al. Unif. (%) V bend (°) 11 627 1073 13.6 115.5 I2 628 1072 13.6 111.0 I3 633 1073 13.4 111.8 I4 682 1110 12.8 107.3 I5 708 1129 12.6 104.0 I6 706 1111 12.3 99.3 I7 621 1099 13.7 111.0 I8 735 1136 12.1 100.0 I9 632 1127 13.2 108.0 110 639 1122 13.4 105.0
    Petition 870180144965, of 10/26/2018, p. 39/45
    25/25
    ID Re (Mpa) Rm (Mpa) Al. Unif. (%) V bend (°) 111 531 1099 13.7 100.0 112 543 1138 13.2 90.0 113 637 1151 12.7 96.0 114 566 1142 13.2 97.0 R1 900 1208 92 86.0 R2 881 1186 9.4 Huh R3 912 1270 82 60.6 R4 913 1233 82 Huh R5 1020 1395 52 87.0
    Table 5
    Mechanical properties of the References of the Invention [088] It should be noted that the five references R1 to R5 show uniform elongations as well as V-fold values that are not in accordance with the objectives of the present invention.
    [089] The present invention makes it possible to provide a steel sheet suitable for depositing a zinc coating, in particular by the usual electroplating processes.
    [090] It makes it possible to make available a steel that has a good tendency to weld by means of usual assembly processes such as, for example, and without limitation, spot resistance welding.
    [091] The steel plates according to the present invention can be used advantageously for the manufacture of structural parts, reinforcement elements, security elements, anti-abrasive elements or transmission discs for applications in land motor vehicles.
    权利要求:
    Claims (12)
    [1]
    1/4
    Claims
    1. COLD AND RECOVERED STEEL SHEET PLATE, characterized by the fact that it has a mechanical strength greater than or equal to 1000 MPa, with uniform elongation greater than or equal to 12% and a bending angle in V from which a crack appears. is greater than or equal to 90 °, whose composition comprises, and the levels are expressed
    in weight, 0.15% <C <0.25% 1.8% <Mn <3.0%1.2% <Si <2%Al <0.10%0% <Cr <0.50%0% <Cu <1%0% <Ni <1%S <0.005%P <0.020%Nb <0.015%Ti <0.020% V <0.015%Co <1%N <0.008%B <0.001%
    where Mn + Ni + Cu <3%, the rest of the composition being made up of iron and inevitable impurities that result from the elaboration, and the microstructure is made up, in superficial proportions, of 5 to 20% of polygonal ferrite, from 10 to 15% residual austenite, from 5 to 15% martensite, the remainder is made of slat-shaped bainite and comprises, between the slats, carbides such that the N number of the carbides
    Petition 870180144965, of 10/26/2018, p. 41/45
    [2]
    2/4 interlaths larger than 0.1 micrometer per unit area is less than or equal to 50000 / mm 2 .
    2. STEEL SHEET, according to claim 1, characterized by the fact that the composition comprises, being the content expressed in weight,
    0.18% <C <0.22%
    [3]
    3. STEEL SHEET, according to claim 1 or 2, characterized by the fact that the composition comprises, being the content expressed in weight,
    2% <Mn <2.6%
    [4]
    4. STEEL SHEET according to any one of claims 1 to 3, characterized by the fact that the composition comprises, the content being expressed in weight,
    1.4% <Si <1.8%
    [5]
    5. STEEL SHEET according to any one of claims 1 to 4, characterized by the fact that the composition comprises, the content being expressed in weight,
    0% <Cr <0.35%
    [6]
    6. STEEL SHEET according to any one of claims 1 to 5, characterized in that it further comprises a zinc or zinc alloy coating.
    [7]
    7. PROCESS OF MANUFACTURING A COLD LAMINATED STEEL SHEET, with resistance greater than or equal to 1000 Mpa, with elongation greater than or equal to 12% and a bending angle in V from which a crack appears is greater than or equal at 90 °, characterized by the fact that it comprises the steps of:
    - obtaining a steel having the composition as defined in any one of claims 1 to 5, and
    Petition 870180144965, of 10/26/2018, p. 42/45
    3/4
    - mold steel into a semi-product shape, and
    - bring the semi-product to a Trech temperature above 1150 ° C to obtain a reheated semi-product, and
    - laminating the hot reheated semi-product, with the end temperature of the hot rolling Tfi greater than or equal to 850 ° C to obtain a hot-rolled sheet, and
    - winding the hot plate to a temperature Tbob between 540 and 590 ° C to obtain a hot rolled coil and,
    - cool the hot-rolled coiled sheet to room temperature, and,
    - perform a basic annealing of the hot-rolled laminated sheet in such a way that the mechanical resistance is less than or equal to 1000 MPa at any point of the hot-rolled coiled sheet, and the hot-rolled coiled and annealed sheet is unwound and pickled from in order to obtain a hot-rolled sheet suitable for cold rolling, and
    - laminate the hot-rolled sheet, suitable for cold rolling, with a reduction rate between 30 and 80% in order to obtain a cold-rolled sheet, and,
    - annealing the cold-rolled sheet by heating it at a speed Vc between 2 and 6 ° C per second to a temperature Ti between Ac3-15 ° C and Ac3-45 ° C, for a time ti greater than or equal to 50 seconds, and,
    - cooling the cold-rolled sheet by subjecting it to a first cooling stage at a cooling speed between 50 and 1500 ° C / s and then to a second cooling stage such that the end of cooling temperature Tfr of the second stage is included between a temperature Tmí equal to Ms-20 ° C and a temperature Tra equal to Ms + 40 ° C, and
    Petition 870180144965, of 10/26/2018, p. 43/45
    4/4
    - keep the cold-rolled sheet in the temperature range between Tm and Tfr2 for a time t2 between 100 and 000 seconds, and
    - cool the cold-rolled sheet at a speed Vr2 between 3 and 25 ° C per second to room temperature in order to obtain a cold-rolled and annealed sheet.
    [8]
    8. MANUFACTURING PROCESS, according to claim 7, characterized by the fact that the temperature Tn is greater than or equal to 900 ° C.
    [9]
    9. MANUFACTURING PROCESS, according to any one of claims 7 to 8, characterized by the fact that the base annealing comprises a maintenance in temperature Tm and time tm are such that:
    2.29 x Tm (° C) + 18.6 x tm (h)> 1238, and the maintenance temperature Tm is more than 410 ° C.
    [10]
    10. MANUFACTURING PROCESS, of a sheet according to any of claims 7 to 9, characterized by the fact that the temperature Ti is between 790 ° C and 820 ° C.
    [11]
    11. MANUFACTURING PROCESS, according to any of claims 7 to 10, characterized in that an annealed cold-rolled sheet is obtained and the annealed cold-rolled sheet is coated with Zinc or a Zinc alloy.
    [12]
    12. MANUFACTURING PROCESS, according to any one of claims 7 to 11, characterized by the fact that the annealed cold-rolled sheet and eventually coated an annealed cold-rolled sheet is obtained and the obtained sheet is annealed at a maintenance temperature Tbase comprised between 150 ° C and 200 ° C for a maintenance time Tbase comprised between 10h and 48h.
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    同族专利:
    公开号 | 公开日
    JP2014514459A|2014-06-19|
    BR112013028841A2|2017-01-31|
    MX2013013106A|2014-12-08|
    RU2013154555A|2015-06-20|
    JP5941533B2|2016-06-29|
    CA2835540A1|2012-11-15|
    PL2707514T3|2017-05-31|
    EP2707514B1|2016-11-09|
    KR20140012167A|2014-01-29|
    KR101453240B1|2014-10-22|
    MA35149B1|2014-06-02|
    MX350016B|2017-08-23|
    US9427939B2|2016-08-30|
    US20140170439A1|2014-06-19|
    RU2606361C2|2017-01-10|
    CN103620063B|2015-11-25|
    WO2012153016A1|2012-11-15|
    HUE031852T2|2017-08-28|
    CN103620063A|2014-03-05|
    UA112771C2|2016-10-25|
    ZA201308409B|2014-07-30|
    EP2707514A1|2014-03-19|
    ES2612515T3|2017-05-17|
    CA2835540C|2017-03-14|
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    KR102321292B1|2019-12-18|2021-11-03|주식회사 포스코|High strength steel sheet having excellent workability and method for manufacturing the same|
    KR102321295B1|2019-12-18|2021-11-03|주식회사 포스코|High strength steel sheet having excellent workability and method for manufacturing the same|
    KR102321285B1|2019-12-18|2021-11-03|주식회사 포스코|High strength steel sheet having excellent workability and method for manufacturing the same|
    KR102321297B1|2019-12-18|2021-11-03|주식회사 포스코|High strength steel sheet having excellent workability and method for manufacturing the same|
    法律状态:
    2018-07-31| B07A| Technical examination (opinion): publication of technical examination (opinion) [chapter 7.1 patent gazette]|
    2019-02-05| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|
    2019-03-19| B16A| Patent or certificate of addition of invention granted|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 03/05/2012, OBSERVADAS AS CONDICOES LEGAIS. |
    优先权:
    申请号 | 申请日 | 专利标题
    FRPCT/FR2011000286|2011-05-10|
    FR2011000286|2011-05-10|
    PCT/FR2012/000174|WO2012153016A1|2011-05-10|2012-05-03|Steel sheet with high mechanical strength, ductility and formability properties, production method and use of such sheets|
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