• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    POLYETHYLENE-GRAPHEN TEREFTALATE NANOCOMPOSITES. The present invention relates to a nanocomposite material comprising polyethylene terephthalate (PET) as a base polymer and a nanoparticle that increases the strength of the base polymer.
    公开号:BR112013028400B1
    申请号:R112013028400-5
    申请日:2012-05-03
    公开日:2020-11-24
    发明作者:Jay Clarke Hanan
    申请人:The Board Of Regents For Oklahoma State University；
    IPC主号:
    专利说明:

    CROSS REFERENCE TO RELATED ORDER
    [001] This application claims the benefit of U.S. Provisional Application No. 61 / 482,048 filed on May 3, 2011, hereby incorporated by reference in its entirety for all purposes. FIELD OF THE INVENTION
    [002] This disclosure relates to polymers in general and, more specifically, to the strengthening of polymers through the introduction of nanomaterials. BACKGROUND OF THE INVENTION
    [003] Polymers have become an ever-present component of modern life. Products that can be produced from metals and other heavy materials that use laborious and / or energy-intensive processes can now be less expensive, faster and with less energy input. Automotive, medical and information technology and healthcare treatments are just a small sample of the industries that make ubiquitous use of polymers.
    [004] The production of a device from a polymer generally results in an item that is lighter than an equivalent item produced from a structural metal or other material. However, with a decrease in weight, a decrease in resistance usually follows. The decrease in strength may be a decrease in the ability to withstand torsion, cutting, compression, pressure, or other force without warping, breaking or deformation to an unacceptable degree.
    [005] What is needed is a system and method for dealing with the above, and related issues. SUMMARY OF THE INVENTION
    [006] The invention of the present disclosure, in one aspect, comprises a nanocomposite material. The material contains a base polymer that includes polyethylene terephthalate (PET), and a nanoparticle that increases the strength of the base polymer. The nanoparticle can comprise graphene nanoplatelets that can be prepared by exfoliation. Graphene nano-platelets can have an average diameter of 5 micrometers. They can comprise about two weight percent of the nanocomposite material. In other embodiments, graphene nanoplatches may comprise about five, ten or fifteen percent by weight of the nanocomposite material. In another embodiment, the weight percentage can vary from about two to about fifteen.
    [007] The invention of the present disclosure, in another aspect, comprises a method for the production of a nanocomposite material. The method includes providing polyethylene terephthalate (PET) as a base polymer, and providing a nanoparticulate substance. The method also includes the composition of the base polymer with the nanoparticulate material to form a standard blend product, and injection molding of the standard blend product. The nanoparticulate substance can comprise graphene. Graphene can be prepared through exfoliation.
    [008] In one embodiment, the nanoparticulate substance can comprise about two weight percent of the nanoparticle substance material in the standard mixing product. In other modalities the weight percentage can be around five, ten or fifteen. In some modalities it can vary from about two percent to about fifteen percent. BRIEF DESCRIPTION OF THE DRAWINGS
    [009] Figure 1: SEM micrographs of the powder sample xGnP (a) 1000 x; (b) 11000 x.
    [010] Figure 2: Samples tested in the stress of PET (At) and PET- Nanocomposites 15% xGnP (B).
    [011] Figure 3: SEM micrographs of (a) PET, PET- Nanocomposite xGnP (b) 2% by weight, (c) 5% by weight, (d) 10% by weight with micro-gaps, (e) 10% by weight in 5k x and (f) 15% by weight of samples.
    [012] Figure 4: TEM micrographs showing the dispersion of the nano-platelets in PET-nanocomposite xGnP 15%; bright field images (a) 10k x, (b) 20k x and (c) dark field image @ 60k x.
    [013] Figure 5: Comparison of the XRD patterns of xGnP powder with the control of PET and nanocomposite.
    [014] Figure 6: Comparison of the stress-strain curves of PET and PET-xGnP nanocomposites.
    [015] Figure 7: Young module of PET nanocomposites compared to control PET.
    [016] Figure 8: PET-graphene nanocomposite module of prognoses in comparison with experimental results. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
    [017] Base polymers can have several inherent characteristics in relation to their appearance, color, solidity, strength, and any number of other measurable properties. In some cases, a base polymer is mixed with a predetermined amount of a material that will alter the properties of the base polymer. The material added to the base polymer is referred to as a standard mixture and the process of adding the standard mixture to the base polymer in such a way as to change its properties can be referred to as a standard mixing process.
    [018] Polymers can also be prepared in a standard mixing process where further processing will create a final product. For example, a polymer or nanocomposite polymer, as described below, can be prepared into standard mixing granules that are later molded into a final product (for example, through injection molding or other suitable processes).
    [019] In some embodiments of the present disclosure, the nanoscale particles are mixed or combined with a polymer in the standard mixing granules which can then be injection molded into final products. The nanoscale material within the polymer of the standard mixture will only interact to change the properties of the base polymer on a nanoscale, which provides some benefit over the major reinforcement mechanisms. Based on Griffith's fracture theory and Weibull's analysis, larger particles are stronger and may be more effective at reinforcing the matrix compared to their larger counterparts. Likewise, with their increased surface area and high aspect ratios, lower volumes of smaller reinforcements can provide equivalent reinforcement.
    [020] The selection of nanoparticles can be based on the required properties, interaction with the matrix, processing, cost, and application of the final composite. Various nanoparticles such as organo-clays (MMT), metal nanoparticles (Al and Ag), metal oxides (ZnO, silica), and carbon derivatives (CNT's, fullerenes, graphite oxide, graphene), can be useful in the preparation of polymer nanocomposites. In another embodiment, polyethylene terephthalate (PET) -graphene is used to create polymer nanocomposites. The material is suitable for injection and blow molding, and other processing and manufacturing techniques.
    [021] Graphene (comprising a monolayer of carbon atoms) has excellent mechanics (modulus - 1060 GPa, Strength - 20 GPa) and electrical properties (50 x 10-6 I cm), in comparison with other nanoparticles. Graphene can disperse correctly in base polymers with the help of surface treatments. Exfoliative Graphene Nanoplatelets (xGnP) are multiple layers of graphene stacked to form platelets.
    [022] Regarding the specific combination of PET with graphene (for example, as in certain modalities of this description), PET is a widely used polymer, but so far it has been ignored in laboratory studies that partly recognize the fact that it is relatively viscous and has a relatively high melting point. In addition, the PET constituent units have a polarity that can result in the dissolution of certain polar nanostructures when the products are mixed. It should be noted that graphene is a polar substance, which means that it can be expected to dissolve or lose its structural integrity in the presence of PET. However, as disclosed herein, graphene can and maintains sufficient integrity to favorably alter the physical characteristics of PET.
    [023] In one embodiment, graphene nanocomposites exfoliated by PET are prepared using injection molding through a standard mixing process, where the graphene nanoplatters are combined with PET to form standard mixing granules. These experimental results were compared with the theoretical performances using Halpin-Tsai and Hui-Shia models.
    [024] Continuous fiber composites are often evaluated based on a simplified empirical formula, referred to as the "Mixture Rule". In the case of nano reinforcements, the "Mixture Rule" underestimates or overestimates the final properties. This is due to its low volume fractions and often greater property disparity between the matrix and the reinforcement.
    [025] For nanocomposites, the special interaction between na-noplelets and the matrix is important in determining their elastic behavior. High aspect ratios of the nano-platelets combined with complex mechanisms at the matrix reinforcement interface complicate the estimation of the nanocomposite property. Therefore, the traditional micromechanical models were modified to estimate the mechanical properties in relation to the nanoparticles. Experience 1 Materials
    [026] In one demonstration, commercially available 0.80 dl / g (I.V.) polyethylene terephthalate called oZpetTM (GG-3180 FGH, from Leading Synthetics, Australia) was used. The exfoliative graphene nanoplatters, grade xGnP®-M-5 (99.5% carbon) with an average diameter of 5 µm, as shown in Figure 1, were obtained as a dry powder from XG Sciences, Inc. (East Lansing, Ml). The graphene nanoplatforms (xGnP) and the received PET resin were combined in standard PET-xGnP mixing granules from Ovation Polymers (Medina, OH) using their ExTima ™ technology.
    [027] Graphene nanoplots are hydrophobic in nature; the effective dispersion of graphene results from the interaction of functional oxygen and hydroxyl groups (formed due to exposure of carbon in the natural state during platelet fracture) on its surface with polar PET groups [19], The standard mixing granules obtained from the above process they were used as raw material for the injection molding process. PET control samples and PET-xGnP nanocomposite tension bars of increasing weight fractions (2%, 5%, 10% and 15%) were injection molded at temperatures 250 ° C to 260 ° C, following the type specifications - I of ASTM D 638 (hereby incorporated by reference). Characterization Techniques
    [028] The produced nanocomposite tension bars (shown in Figure 2) were tested using a universal material tester (Instron 5582 model). The tests followed the ASTM D 638 standard at a crosshead speed of 5 mm / min. A non-contact Laser Extensometer (Electronic Research Instrument, Model LE - 05) was used to record the free offset of the machine length. The laser extensometer records the displacement of reflections from self-reflective adhesives placed at the length of the standard measurement.
    [029] Three composites of each type were tested together with pure PET specimens for comparison. The laser displacement and crosshead load were recorded simultaneously over a 100 ms time interval.
    [030] The dispersion of graphene nanoplatforms was observed using electron microscopy (SEM, TEM) and X-ray diffraction. SEM micrographs of xGnP powder and PET fracture surfaces, and graphene nanocomposites exfoliated with PET were obtained using a Hitachi S-4800.
    [031] The PET control and the nanocomposite with the lowest graphene content were Au / Pt coated using a Balzers Union MED 010 coating. The thin sections (70 nm thickness) used for transmission imaging were subjected to microtomes using the Reichert-Jung Ultracut E microtome. The transmission micrographs were collected using a JEOL JEM-2100 Microscope, with an operating voltage of 200 kV. The X-ray diffraction patterns were collected in reflection, on a Bruker D8 Discovery diffractometer, using Cu Ka radiation (À = 1.54054 A). XRD scans of the xGnP powder next to the PET samples were collected at 40 kV and 40 mA with an exposure time of 120 sec. Results Scanning Electron Microscopy
    [032] SEM micrographs of the dry xGnP powder shown in Figure 1 (b) show a cluster of platelets, with each platelet comprised of numerous layers of graphene stacked together. These platelets were 5 to 10 µm in average diameter and several nanometers (5 to 20 nm) thick.
    [033] The micrographs (Figure 3 (b), (c), (d), (e) and (f)) of the failure surfaces of the PET-graphene nanocomposite showed that the graphene nanoplets remained intact and were dispersed in the PET matrix, without signs of agglomeration. The micrographs clarify that the failure of the nanocomposite under stress was due to the junction of fragile micro-fractures. The presence of micro-gaps and the beginning of fractures from these gaps can be observed from SEM micrographs of nanocomposite samples with 5% and 10% by weight of graphene nanoplate. SEM micrographs show that the nano-platelets were protruding out of the fracture surfaces. They appear to be deformed and mixed with the matrix. Transmission electronic microscopy
    [034] The performance of nanocomposites depends on the dispersion of the nanoparticles. TEM micrographs were collected from thin sections of 70 nm to obtain a better understanding of the dispersion of nanoplelets. The transmission micrographs shown in Figure 4 revealed that the graphene nanoplets remained intact as platelets and were dispersed in the polymer matrix, the individual dispersion of the graphene sheets (complete exfoliation) was not observed. The micrographs were collected in both bright and dark field modes. Since the nanoplatforms consist of several individual graphene sheets, the 70 nm thick sections used may contain layers of polymer and graphene platelets, so the dark field mode was advantageous. Graphene is more conductive than the polymeric matrix, so in the transmission image formation, this difference provides contrast. X-Ray Diffraction
    [035] The XRD patterns collected from the dry xGnP powder, the PET control and the PET-xGnP nanocomposite are shown in Figure 5. The diffraction pattern for the graphene nanoplatelets shows the characteristic maximum points of graphene-2H at 26.6 ° (d = 3.35 A) and 54.7 ° (d = 1.68 A) 20. Slight enlargement of the maximum point at 26.6 ° 20 indicates the presence of platelets with different dimensions. A broad maximum amorphous point in the PET control sample was observed at around 19.2 ° 20. This confirms that the control sample has an amorphous microstructure. As shown in Figure 5, the intensity of the maximum graphene point at 26.6 ° 20 increased with the weight fraction of the nano-platelets. No change in the peak was observed. This, together with TEM micrographs, confirms that the nano-platelets were not substantially exfoliated [20]. In addition, the diffraction pattern confirms that the PET matrix was amorphous as expected, at least within 0.2 mm of the surface. Mechanical Behavior
    [036] The stress-strain curves for the control of PET and nanocomposite were plotted as shown in Figure 6, based on the data collected from the stress tests. The addition of graphene nanoplets increased the performance (modulus) over pure PET by up to 300% and follows an exponential trend as shown in Figure 7. Although the essentially linear behavior has been observed, a protrusion in the stress / stress curve for the nanocomposite at 15%, it suggests an additional strengthening mechanism for this composite over the other smaller volume fraction. This may be due to a reinforcement-reinforcement interaction.
    [037] In order to understand the effectiveness of graphene nanoplatforms as reinforcement, micromechanical models such as the Halpin-Tsai and Hui-Shia models were used to determine the theoretical elastic mechanical performance of this PET-graphene nanocomposite. Micromechanical models estimate properties based on assumptions, such as perfect reinforcements, homogeneous dispersion, or consistent orientation of the reinforcements. An ideal process for the superior performance of the graphene nanocomposite is to have the graphene sheets free of defects (monolayers) in the required length well dispersed in the matrix and oriented along the direction of maximum load.
    [038] Gong et al. [16] determined a required length for graphene platelets (> 30 mm) to be effective as a reinforcement. The mechanical properties of graphene platelets such as stiffness and decreased Poisson's ratio with an increase in the number comprising layers, as noted by Georgantzinos et al. [22] with molecular simulations. They estimated that the stiffness of platelets comprising five layers decreased by 15% compared to a single layer of graphene, and they also observed that the properties of graphene differ based on its orientation. The graphene platelet module (flake) was reported as TPA 0.795 [23], Table 1: Properties of Graphene and PET used for theoretical predictions

    [039] In the present work, graphene platelets with a wide range of length (or diameter of the platelets present in the out-of-plane direction) and thickness were observed from TEM micrographs. The variation in particle size from the largest dry graphene powder (5 pm) to the smallest (300 nm), the size observed in TEM images (Figure 4), may be due to shear during the combining process and molding. Table 1 shows the average platelet size with minimum and maximum values. These platelet properties were then used to determine the performance range of the nanocomposites, based on the micromechanical models (error bars shown in Figure 8). The predicted modules of the nanocomposite from the micromechanical models were plotted against the experimental results, shown in Figure 8. The module estimated using the Halpin-Tsai model is superior compared to the experimental value. The Halpin-Tsai model estimates the composite module with platelets being aligned along the load direction. However, the platelets were not generally aligned in the direction of the load. In addition, the extremely high stiffness of the reinforcement compared to the matrix (> 250x) makes exact predictions difficult using the Halpin-Tsai model [22]. The Hui-Shia model shows the best agreement. The Hui-Shia model estimates the elasticity modulus of the platelet-loaded nanocomposite in both parallel (axes 1 and 2) and perpendicular (along axis 3) directions as shown in Figure 8. This model is valid for a wide range of relationships stiffness in relation to the Halpin-Tsai model [22],
    [040] In addition, the stress transfer between the matrix for reinforcement in composites is critical in controlling its mechanical behavior. For example, graphene nanocomposites in the PMMA matrix, the stress transfer between the matrix and the graphene platelets and the blades of the raphe no-g raphe were shown to be dominated by van der Waals forces weekly, reducing mechanical performance potential. However, micromechanical models do not consider these changes in voltage transfer behavior. This results in a deviation from the experimental values.
    [041] The current experimental module proved to be reasonable according to theoretical predictions. That is, despite the wide range in the geometry of the tag (see table). The best case was the Hui-Shia model with the module parallel to the nameplate (direction - 3). This suggests reasonable effectiveness of the reinforcement. With the reinforcement randomly distributed, the behavior between the two Hui-Shia predictions of parallel and perpendicular can be expected. Further investigation into the randomness of the platelet distribution is needed for further evaluation. Even more rigid intensification of the module can be expected if the platelets have a higher aspect ratio since the predicted module is sensitive to the aspect ratio. This is a reasonable goal with continuous improvement in the production of additives and their processing with the matrix. Clearly, nanoscale reinforcement is a benefit for enhancing mechanical properties.
    [042] In addition, from X-ray diffraction, the addition of graphene platelets has no impact on the final crystallization of PET. Economies of scale can improve the cost of any of these additives. More understanding of the effect that nano-plates have on the injection molding process can help to further improve composite properties. For example, many different types of threads are available for injection molding and need to be explored for their advantages in mixing and dispersing additives. Test Conclusions
    [043] The present disclosure demonstrates that graphene nanoplatelets are effective in obtaining improved strength characteristics (such as the modulus of elasticity) for Polyethylene Terephthalate, or PET. Injection molding of standard pellet mix granules is a successful method for the preparation of PET-exfoliated graphene nanocomposites (xGnP) from fractions by weight of 2 to 15%. The comparison with the simple mechanical models suggests its superior performance. The stiffness may not only be dependent on the reinforcement stiffness, but also on its aspect ratio and the dominant mechanism for the transfer of interfacial tension between the matrix and the reinforcement. There is also an indication that the reinforcement-reinforcement interaction plays an important role when the volume fraction exceeds 10%. References [1] T. Kuila, S. Bhadra, D. Yao, NH Kim, S. Bose, and JH Lee, "Recent advances in graphene based polymer composites," Progress in Polymer Science, vol. In Press, Corrected Proof. [2] H. Fukushima, "Graphite Nanoreinforcements in Polymer Nanocomposites," in Chemical Engineering and Materials Science, vol. Doctor of Philosophy, 2003, p. 311. [3] X. Jiang and L. T. Drzal, "Multifunctional high density polyethylene nanocomposites produced by incorporation of exfoliated graphite nanoplatelets 1: Morphology and mechanical properties," Polymer Composites, vol. 31, pp. 1091-1098. [4] F. Hussain, M. Hojjati, M. Okamoto, and R. E. Gorga, "Review article: Polymer-matrix Nanocomposites, Processing, Manufacturing, and Application: An Overview," Journal of Composite Materials, vol. 40, pp. 1511-1575, September 1, 2006 2006. [5] D. R. Paul and L. M. Robeson, "Polymer nanotechnology: Nanocomposites," Polymer, vol. 49, pp. 3187-3204, 2008. [6] H. C. Schniepp, J.-L. Li, M. J. McAllister, H. Sai, M. Herrera-Alonso, D. H. Adamson, R. K. Prud'homme, R. Car, D. A. Saville, and I.A. Aksay, "Functionalized Single Graphene Sheets Derived from Splitting Graphite Oxide," The Journal of Physical Chemistry B, vol. 110, pp. 8535-8539, 2006. [7] B. Jang and A. Zhamu, "Processing of nanographene platelets (NGPs) and NGP nanocomposites: a review," Journal of Materials Science, vol. 43, pp. 5092-5101, 2008. [8] K. Wakabayashi, C. Pierre, DA Dikin, RS Ruoff, T. Ramanathan, LC Brinson, and JM Torkelson, "Polymer-Graphite Nanocomposites: Effective Dispersion and Major Property Enhancement via Solid -State Shear Pulverization, "Macromolecules, vol. 41, pp. 1905-1908, 2008. [9] I. H. Kim and Y. G. Jeong, "Polylactide / exfoliated graphite nanocomposites with enhanced thermal stability, mechanical modulus, and electrical conductivity," Journal of Polymer Science Part B: Polymer Physics, vol. 48, pp. 850-858, 2010. [10] F. M. Uhl, Q. Yao, H. Nakajima, E. Manias, and C. A. Wilkie, "Expandable graphite / polyamide-6 nanocomposites," Polymer Degradation and Stability, vol. 89, pp. 70-84, 2005. [11] M. A. Rafiee, J. Rafiee, Z. Wang, H. Song, Z.-Z. Yu, and N. Koratkar, "Enhanced Mechanical Properties of Nanocomposites at Low Graphene Content," ACS Nano, vol. 3, pp. 3884-3890, 2009. [12] K. Kalaitzidou, H. Fukushima, and L. T. Drzal, "A new compounding method for exfoliated graphite-polypropylene nanocomposites with enhanced flexural properties and lower percolation threshold," Composites Science and Technology, vol. 67, pp. 2045-2051, 2007. [13] D. G. Miloaga, H. A. A. Hosein, M. Misra, and L. T. Drzal, "Crystallization of poly (3-hydroxybutyrate) by exfoliated graphite nano-platelets," Journal of Applied Polymer Science, vol. 106, pp. 2548-2558, 2007. [14] A. S. Patole, S. P. Patole, H. Kang, J.-B. Yoo, T.-H. Kim, and J.-H. Ahn, "A facile approach to the fabrication of graphene / polystyrene nanocomposite by in situ microemulsion polymerization," Journal of Colloid and Interface Science, vol. 350, pp. 530-537, 2010. [15] Y. C. Li and G. H. Chen, "HDPE / expanded graphite nanocomposites prepared via masterbatch process," Polymer Engineering & Science, vol. 47, pp. 882-888, 2007. [16] H. Hu, L. Onyebueke, and A. Abatan, "Characterizing and Modeling Mechanical Properties of nanocomposites - Review and Evaluation," Journal of Minerals & Materials Characterization & Engineering, vol. 9, p. 45, 2010. [17] P. A. Beale, "Global Polyester Raw Materials Dynamics," in The Packaging Conference, Las Vegas, 2011. [18] J.-H. Chang, S. J. Kim, Y. L. Joo, and S. Im, "Poly (ethyleneterephthalate) nanocomposites by in situ interlayer polymerization: the thermo-mechanical properties and morphology of the hybrid fibers," Polymer, vol. 45, pp. 919-926, 2004. [19] A. A. K, U. S. Agarwal, and R. Joseph, "Carbon nanotubes-reinforced PET nanocomposite by melt-compounding," Journal of Applied Polymer Science, vol. 104, pp. 3090-3095, 2007. [20] H.-B. Zhang, W.-G. Zheng, Q. Yan, Y. Yang, J.-W. Wang, Z.-H. Lu, G.-Y. Ji, and Z.-Z. Yu, "Electrically conductive polyethylene terephthalate / graphene nanocomposites prepared by melt compound-ing," Polymer, vol. 51, pp. 1191-1196, 2010. [21] A. B. Morgan and J. W. Gilman, "Characterization of polymer-layered silicate (clay) nanocomposites by transmission electron microscopy and X-ray diffraction: A comparative study," Journal of Applied Polymer Science, vol. 87, pp. 1329-1338, 2003. [22] C. Y. Hui and D. Shia, "Simple formulae for the effectivemoduli of unidirectional aligned composites," Polymer Engineering & Science, vol. 38, pp. 774-782, 1998. [23] O. L. Blakslee, D. G. Proctor, E. J. Seldin, G. B. Spence, and T. Weng, "Elastic Constants of Compression-Annealed Pyrolytic Graphite," Journal of Applied Physics, vol. 41, pp. 3373-3382, 1970. [24] C. Y. Hui and D. Shia, "Simple formulae for the effective moduli of unidirectional aligned composites," Polymer Engineering & Science, vol. 38, pp. 774-782, 1998. [25] D. Shia, C. Y. Hui, S. D. Burnside, and E. P. Giannelis, "An interface model for the prediction of Young's modulus of layered silicate-elastomer nanocomposites," Polymer Composites, vol. 19, pp. 608-617, 1998. [26] H. Hua, L. Onyebueke, and A. Abatan, "Characterizing and Modeling Mechanical Properties of Nanocomposites-Review and Evaluation," Journal of Minerals & Materials Characterization & Engineering, vol. 9, pp. 275-319, 2010. [27] J. C. H. Affdl and J. L. Kardos, "The Halpin-Tsai equations: A review," Polymer Engineering & Science, vol. 16, pp. 344-352, 1976.
    [044] Thus, the present invention is well adapted to achieve the objectives and achieve the purposes and advantages mentioned above, as well as those inherent to them. Although currently preferred modalities have been described for the purposes of this disclosure, numerous changes and modifications will be evident to those of practical skill in the art. Such changes and modifications are included within the spirit of this invention as defined by the claims.
    权利要求:
    Claims (6)
    [0001]
    1. Nanocomposite material, characterized by the fact that it comprises: a base polymer including polyethylene terephthalate (PET); and a nanoparticle that increases the strength of the base polymer, wherein the nanoparticle comprises exfoliated graphene nanoplatforms, the nanoplatforms comprising from 10% to 15% by weight of the nanocomposite material.
    [0002]
    2. Material according to claim 1, characterized by the fact that the nano-platelets comprise 10% by weight of the nanocomposite material.
    [0003]
    3. Material according to claim 1 or 2, characterized by the fact that the nano-platelets comprise 15% by weight of the nanocomposite material.
    [0004]
    4. Production method of a nanocomposite material, characterized by the fact that it comprises: supplying polyethylene terephthalate (PET) as a base polymer; providing a nanoparticulate substance, wherein the step of providing the nanoparticle substance comprises providing exfoliated graphene nanoplatforms, the nanoplatforms comprising from 10% to 15% by weight of the nanocomposite material, as defined in claim 1; compose the base polymer with the nanoparticulate material to form the standard mixing product; and injection mold the standard mixing product.
    [0005]
    Method according to claim 4, characterized in that providing a nanoparticulate substance further comprises providing 10% by weight of the nanoparticle substance material in the standard mixing product.
    [0006]
    Method according to claim 4, characterized in that providing a nanoparticulate substance further comprises providing about 15% by weight of the nanoparticle substance material in the standard mixing product.
    类似技术:
    公开号 | 公开日 | 专利标题
    BR112013028400B1|2020-11-24|POLYETHYLENE-GRAPHEN TEREFTALATE NANOCOMPOND MATERIAL AND ITS PRODUCTION METHOD
    Ngo et al.2016|Thermal conductivity of transparent and flexible polymers containing fillers: A literature review
    Bandla et al.2012|Microstructure and elastic tensile behavior of polyethylene terephthalate-exfoliated graphene nanocomposites
    Kausar et al.2017|Aerospace application of polymer nanocomposite with carbon nanotube, graphite, graphene oxide, and nanoclay
    Alig et al.2012|Establishment, morphology and properties of carbon nanotube networks in polymer melts
    Kasgoz et al.2014|Effect of different types of carbon fillers on mechanical and rheological properties of cyclic olefin copolymer | composites
    Faridirad et al.2017|Polyamide/carbon nanoparticles nanocomposites: a review
    Aoyama et al.2014|AFM probing of polymer/nanofiller interfacial adhesion and its correlation with bulk mechanical properties in a poly | nanocomposite
    Shabafrooz et al.2018|Graphene/polyethylene terephthalate nanocomposites with enhanced mechanical and thermal properties
    Ngo et al.2016|A review on enhancing thermal conductivity of transparent and flexible polymer composites
    Yeh et al.2020|Fabrication of polystyrene/carbon nanocomposites with superior mechanical properties
    Asadi et al.2018|Process-Structure-Property Relationship in Polymer Nanocomposites
    Saralch et al.2019|Response surface methodology based analysis of the impact of nanoclay addition on the wear resistance of polypropylene
    Desai et al.2013|Graphite-based nanocomposites to enhance mechanical properties
    Zicāns et al.2015|Modeling and experimental investigations of elastic and creep properties of thermoplastic polymer nanocomposites
    Koilraj et al.2015|Hybrid Nanocomposites–A Review
    Hanan2004|STANDARD PATENT
    Doğanay2016|Production and characterization of polylactide/silver nanowire nanocomposite films
    Hu et al.2012|Tribological behavior of polyamide 66-based binary and ternary nanocomposites
    Bandla2015|Injection Molded Poly |-Graphene Nanocomposites
    Yang2007|Characterization, Modeling and Prediction of the Creep Resistance of Polymer Nanocomposites
    Patel2005|Synthesis and characterization of polymer nanocomposites
    EMEK2013|A study on thermophysical properties of graphite filled polymer nanocomposites
    Jakubowicz2005|Nano-clays in polymer compositestiny particles with huge potential
    同族专利:
    公开号 | 公开日
    EP2705091A2|2014-03-12|
    JP6113148B2|2017-04-12|
    US9636855B2|2017-05-02|
    EP2705091B1|2018-04-25|
    US10808098B2|2020-10-20|
    CA2835112A1|2012-11-08|
    US10087302B2|2018-10-02|
    KR20190110630A|2019-09-30|
    BR112013028400A2|2017-01-24|
    JP2014513186A|2014-05-29|
    EP2705091B8|2018-08-15|
    KR20140034802A|2014-03-20|
    MX359481B|2018-09-28|
    AU2012250670A1|2013-12-19|
    US20170218166A1|2017-08-03|
    CO6811879A2|2013-12-16|
    KR101851708B1|2018-04-24|
    KR102195567B1|2020-12-28|
    IL229216A|2017-01-31|
    AU2012250670C1|2016-07-21|
    KR102025305B1|2019-09-25|
    CN103814080B|2016-12-07|
    WO2012151433A2|2012-11-08|
    EP2705091A4|2014-10-29|
    WO2012151433A3|2013-01-17|
    CN103814080A|2014-05-21|
    KR20180043400A|2018-04-27|
    EP3372644A1|2018-09-12|
    CA2835112C|2020-05-05|
    ES2673289T3|2018-06-21|
    US20190010304A1|2019-01-10|
    AU2012250670B2|2016-03-17|
    MX2013012880A|2014-07-30|
    RU2013153379A|2015-06-10|
    US20140080962A1|2014-03-20|
    IL229216D0|2014-01-30|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    US20070216067A1|2000-01-21|2007-09-20|Cyclics Corporation|Macrocyclic polyester oligomers as carriers and/or flow modifier additives for thermoplastics|
    US8501858B2|2002-09-12|2013-08-06|Board Of Trustees Of Michigan State University|Expanded graphite and products produced therefrom|
    US7745528B2|2006-10-06|2010-06-29|The Trustees Of Princeton University|Functional graphene-rubber nanocomposites|
    US20080315453A1|2007-06-22|2008-12-25|Michael Joseph Molitor|Process for the production of polyester nanocomposites|
    US9546092B2|2008-02-05|2017-01-17|The Trustees Of Princeton University|Functionalized graphene sheets having high carbon to oxygen ratios|
    WO2009112573A2|2008-03-13|2009-09-17|Basf Se|Method and dispersion for applying a metal layer to a substrate and metallizable thermoplastic molding compound|
    US9080122B2|2009-01-06|2015-07-14|Board Of Trustees Of Michigan State University|Nanoparticle graphite-based minimum quantity lubrication method and composition|
    EP2449003A1|2009-06-29|2012-05-09|E. I. du Pont de Nemours and Company|Process for the production of polyester nanocomposites and shaped articles made thereof|
    JP5296622B2|2009-07-08|2013-09-25|帝人株式会社|Molded product comprising conductive resin composition|
    KR20110012338A|2009-07-30|2011-02-09|현대자동차주식회사|Method for emission controlling of diesel particulate filter|
    WO2011028924A2|2009-09-02|2011-03-10|University Of Washington|Porous thermoplastic foams as heat transfer materials|
    WO2011074125A1|2009-12-18|2011-06-23|国立大学法人 北海道大学|Graphene oxide sheet, article containing grapheme-containing substance produced by reducing the graphene oxide sheet, and process for production of the graphene oxide sheet|
    KR101093056B1|2010-05-07|2011-12-13|금오공과대학교 산학협력단|Polytrimethylene terephthalate/Graphene Composites with Enhanced Mechanical Property and Electrical Conductivity and Method for Preparing the Same|
    ES2673289T3|2011-05-03|2018-06-21|The Board Of Regents For Oklahoma State University|Nanomaterials composed of poly -grafen|
    US9803100B2|2013-04-30|2017-10-31|Kimberly-Clark Worldwide, Inc.|Non-fluorinated water-based superhydrophobic surfaces|
    CN113150505A|2015-03-17|2021-07-23|尼亚加拉装瓶有限责任公司|Graphene reinforced polyethylene terephthalate|
    AU2016232854B2|2015-03-17|2020-07-02|Sudheer BANDLA|Graphene reinforced polyethylene terephthalate|
    WO2017007568A1|2015-07-08|2017-01-12|Niagara Bottling, Llc|Graphene reinforced polyethylene terephthalate|ES2673289T3|2011-05-03|2018-06-21|The Board Of Regents For Oklahoma State University|Nanomaterials composed of poly-grafen|
    WO2014144139A1|2013-03-15|2014-09-18|Xolve, Inc.|Polymer-graphene nanocomposites|
    CN103224694A|2013-04-18|2013-07-31|苏州旭光聚合物有限公司|Conductive PBT composite material|
    US10432061B2|2013-07-19|2019-10-01|Gkn Hybrid Power Limited|Flywheel assembly|
    GB2517524B|2013-07-19|2017-04-05|Gkn Hybrid Power Ltd|Flywheel control scheme|
    PT107398B|2014-01-12|2018-06-26|Octavio Adolfo Romao Viana|ETHYLENE AND POLYPHENEETALATE FILTER AND / OR GRAFFEN OXIDE|
    CN113150505A|2015-03-17|2021-07-23|尼亚加拉装瓶有限责任公司|Graphene reinforced polyethylene terephthalate|
    AU2016232854B2|2015-03-17|2020-07-02|Sudheer BANDLA|Graphene reinforced polyethylene terephthalate|
    JP6742580B2|2015-07-08|2020-08-19|ナイアガラ・ボトリング・リミテツド・ライアビリテイー・カンパニー|Graphene reinforced polyethylene terephthalate|
    WO2017007568A1|2015-07-08|2017-01-12|Niagara Bottling, Llc|Graphene reinforced polyethylene terephthalate|
    EP3319935A4|2015-07-08|2019-03-13|Niagara Bottling, LLC|Graphene reinforced polyethylene terephthalate|
    US10689501B2|2015-10-27|2020-06-23|Jinan Shengquan Group Share Holding Co., Ltd.|Composite polyester material, composite polyester fiber, processes for preparing the same and uses thereof|
    CN105525381B|2015-10-27|2018-03-06|济南圣泉集团股份有限公司|A kind of composite polyester fiber containing graphene, preparation method and use|
    CN105504700B|2015-10-27|2017-12-19|济南圣泉集团股份有限公司|A kind of composite polyester material containing graphene, preparation method and purposes|
    KR101960619B1|2015-10-27|2019-07-15|지난 셩취엔 그룹 쉐어 홀딩 코., 엘티디.|Composite polyurethane foam comprising graphene, preparation method and use thereof|
    CN105506771B|2015-10-27|2017-12-05|济南圣泉集团股份有限公司|A kind of composite polyester fiber, preparation method and use|
    CN105504696B|2015-10-27|2017-12-15|济南圣泉集团股份有限公司|A kind of composite polyester material, preparation method and purposes|
    CN105603568B|2016-01-21|2018-05-01|济南圣泉集团股份有限公司|A kind of modified hollow cotton and preparation method thereof|
    CN105525384B|2016-01-22|2019-05-10|济南圣泉集团股份有限公司|A kind of purposes of modified hollow cotton|
    CN107383395A|2017-04-24|2017-11-24|劳富文|The graphene color masterbatch preparation method of PET material|
    KR102284847B1|2017-06-26|2021-08-03|항저우 고우시 테크놀로지 컴퍼니 리미티드|Graphene composite material and its manufacturing method|
    EP3446725A1|2017-08-22|2019-02-27|Cook Medical Technologies LLC|Medical balloons with nanoplatelet composite materials and method of making the same|
    KR101974046B1|2017-11-15|2019-08-23|울산과학기술원|Method of manufacturing nylon prepreg having carbon nano material|
    CA3099526A1|2018-05-09|2019-11-14|Niagara Bottling, Llc|Poly-graphene nanocomposites from improved dispersion|
    PT110802A|2018-06-24|2019-12-24|Octavio Adolfo Romao Viana|PROCESS FOR OBTAINING A BIOPLASTIC FILM AND GRAPHEN OXIDE AND / OR GRAPHENE.|
    WO2021035202A1|2019-08-22|2021-02-25|Xg Sciences, Inc.|Graphene reinforced hybrid composites|
    WO2021222760A1|2020-04-30|2021-11-04|Pepsico, Inc.|Light-weight hot-fill container and methods for making the same|
    法律状态:
    2018-04-03| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|
    2020-03-31| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|
    2020-08-11| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|
    2020-11-24| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 03/05/2012, OBSERVADAS AS CONDICOES LEGAIS. |
    2022-03-03| B21F| Lapse acc. art. 78, item iv - on non-payment of the annual fees in time|Free format text: REFERENTE A 10A ANUIDADE. |
    优先权:
    申请号 | 申请日 | 专利标题
    US201161482048P| true| 2011-05-03|2011-05-03|
    US61/482,048|2011-05-03|
    PCT/US2012/036376|WO2012151433A2|2011-05-03|2012-05-03|Polyethylene terephthalate-graphene nanocomposites|
    [返回顶部]