![]() sustainable method for treatment and maintenance of artificial water bodies, suitable for low densit
专利摘要:
SUSTAINABLE METHOD AND SYSTEM FOR TREATING BODIES OF WATER AFFECTED BY BACTERIA AND MICROALGALS AT LOW COST. A system for treatment and maintenance of water bodies for low density recreational use is disclosed. A system of the present invention generally includes containment means, coordination means, chemical application means, non-intrusive mobile suction means, and filtering means. The coordination means can receive information about the parameters of controlled water quality, and can opportunely activate the processes necessary to adjust the parameters of water quality within the respective limits. The disclosed system filters only a small fraction of the total volume of water, up to 200 times less per day than the flow filtered by conventional pool filtration systems. The disclosed methods and the system also use less chemicals than conventional pool water treatment systems. The system of the present invention can be used to treat recreational water bodies and provide sustainable methods for producing water that meets the requirements of the Environmental Protection Agency (EPA) for recreational waters, to bathe with full body contact. . 公开号:BR112013024625B1 申请号:R112013024625-1 申请日:2011-09-12 公开日:2020-11-17 发明作者:Fernando Fischmann T 申请人:Crystal Lagoons (Curacao) B.V; IPC主号:
专利说明:
[001] This application was filed on September 12, 2011, as an application for a PCT International Patent in the name of Crystal Lagoons Corporation LLC, a US national corporation, applicant for the designation of all countries except the USA, and Fernando Fischmann T., a citizen of Chile, and claims priority for US Provisional Application No. serial number 61 / 469,548, filed on March 30, 2011, and US Utility Order no. serial number 13 / 136,458, filed on August 1, 2011, and whose orders are hereby incorporated by reference. FIELD OF THE INVENTION [002] The present invention relates to a sustainable method and system for treating and maintaining water bodies at low cost for low density recreational use. Typically, the density of use is up to 0.05 bathers per cubic meter of water volume. Unlike conventional pool filtration systems in which the entire volume of water is filtered up to 6 times a day, the methods and systems described here filter only a small fraction of the total volume of water, up to 200 times less per day than the flow filtered by conventional pool filtration systems. The methods and systems described here also use less chemicals, up to 100 times less than conventional pool water treatment systems. The methods and systems of the present invention can be used to treat recreational water bodies affected by bacteria and microalgae and to provide sustainable methods for the production of water that complies with the bacteriological and physicochemical requirements of recreation water, as established by Government Regulatory Agencies, such as the Environmental Protection Agency (EPA), for baths with full body contact. BACKGROUND [003] Several recreational water bodies are likely to be affected by bacteria and microalgae proliferation. In cases where water quality is of great importance, such as swimming pools, adequate high quality water for swimming is achieved by adding large amounts of chemical agents. In swimming pools, for example, chemical agents are added to the pool water in order to maintain at least a permanent concentration of 1.5 ppm of chlorine agents in the water. This concentration is necessary due to the strict regulations for swimming pools regarding the physico-chemical and bacteriological properties of water, which is achieved by maintaining a permanent oxidation-reduction potential (ORP) in water of at least 650 mV, on a base to be continued. [004] Many countries around the world have regulations on recreational waters and there are generally two types of regulations on the recreational use of such bodies of water. The first type of regulation is directed to swimming pools, which essentially requires the maintenance of a high permanent chlorine buffer, in order to avoid water contamination when new bathers enter the pool. The chlorine buffer neutralizes contaminants and kills microorganisms brought into the pool water by bathers, thus maintaining a high quality of water suitable for recreational purposes. [005] The second type of regulation is applicable to lakes and the sea, and is referred to as the criteria for bathing with full body contact for recreational waters. This regulation is based on the dilution power with water. When new bathers insert a body of water, the contaminants are diluted so that the contaminants do not reach a concentration in the body of water, which causes significant effects. Therefore, in a large body of water such as a lake or sea, a disinfectant buffer is not necessary due to the high dilution power of the large volume of water. [006] There is a global trend towards more sustainable and environmentally conscious systems in all aspects of life that can coexist with the environment leaving the smallest footprint behind. However, when it comes to the treatment of recreational water bodies, to date there has been no significant progress towards environmentally responsible methods and systems. Usual treatments for the proliferation of bacteria and microalgae in swimming pools require large amounts of chemicals and energy, which do not meet current sustainable needs. [007] In order to comply with the first regulation, a chlorine buffer in swimming pools must be maintained on a continuous basis to neutralize contaminants brought into the pool by new bathers. The maintenance of a permanent chlorine buffer in the traditional treatment of swimming pools is related to the maintenance of an ORP level of at least 650 mV on a continuous basis. Once the demand for disinfectant chlorine has been satisfied, the concentration of free chlorine in the remaining water, that is, the residual chlorine acts as a buffer in order to provide disinfection when the new organic matter or microorganisms enter the body of water, for example, when new bathers enter the water. The amount of chemicals used to permanently maintain an ORP level of at least 650 mV is very high, significantly increases the pool's operating costs, involves the use of chemicals in quantities that are not favorable to the environment and can generate by-products of undesirable disinfection (DBP's), such as chloramines. [008] In addition, a pool typically configured requires the filtering of its entire water volume in general from 1 to 6 times a day. This is achieved using a traditionally configured centralized filtering unit. Thus, the traditional swimming pool filtration system consumes large amounts of energy, and also imposes high demands in terms of installation, operation and maintenance costs. [009] In short, traditional swimming pools rely on large amounts of chemicals to maintain a chlorine buffer, in order to neutralize the contamination that enters the water body and a centralized filtration system that filters the entire volume of water in general 1 to 6 times a day. Thus, traditional pool technology has high operating and maintenance costs, due to the high concentrations of disinfection that have to be maintained continuously and the centralized filtration system required. There is a great need for a sustainable, low-energy method and system to treat and maintain large volumes of water for recreational purposes, using a small amount of chemicals. Pools [0010] The consumption of nutrients in water by aerobic microorganisms results in a high demand for oxygen. This, in turn, reduces the levels of oxygen dissolved in the water, and thus allows the development of anaerobic microorganisms. The further development of anaerobic microorganisms produces the accumulation of organic compounds. This chain of events produces an accumulation of nutrients in the water, which can serve as a breeding ground for particular microorganisms. Among the microorganisms developed under these conditions, bacteria and microalgae are the most relevant in recreational water bodies. [0011] Turbidity in recreational water bodies is produced mainly by microalgae present in the water. These microorganisms grow in the water with a certain concentration of nutrients. Depending on the availability of a light source and the concentration of nutrients, algal blooms can occur in a process called eutrophication in which algae fill the entire volume of water, transforming the entire body of water into a huge source of biomass and increasing the turbidity of the water. Different regulations indicate that values of up to 50 nephelometric turbidity units (NTU) would be safe for human health. In British Columbia, for example, the water turbidity determined by the Environmental Protection Division of the Ministry of the Environment for recreational water bodies, establishes a maximum limit of 50 NTU (Section 2 (e) of the Environmental Management Act, 1981, British Columbia, Canada), while the South Australian government considers a maximum value of 25 NTU. When the dissolved nutrients necessary for the maintenance of microalgae are consumed, the microalgae die and are deposited in the lower part of the water body. The available organic matter present in the layer deposited at the bottom of the water body can again serve as a basis for the development of anaerobic microorganisms in the water, which, in general, constitutes a threat to human health. In artificial water organs, water quality deteriorates progressively as a result of microalgae and the growth of bacteria. In typical methods or processes for the treatment of swimming pool water with a high density of bathers, large amounts of disinfectant agents, such as chlorine, together with the filtration of the entire volume of water are used to control the proliferation of bacteria and microalgae. For example, if chlorine is used, it reacts with organic matter, as well as with reducing agents such as hydrogen sulfide, iron ions, manganese ions and nitrite ions. The chlorine consumed in these reactions is defined as the demand for chlorine. To satisfy the chlorine demand, permanent ORP levels of at least 650 mV must be maintained in the water. [0012] The reaction of chlorine with organic compounds present in water can form various toxic by-products or disinfection by-products (DBP). For example, the reaction of chlorine with ammonia can produce chloramines as undesirable by-products. The additional reaction of chlorine or chloramines with organic matter can produce trihalomethanes, which have been implicated as potential carcinogens. Also, depending on the disinfection method, new DBPs have been identified, such as iodinated trihalomethanes, haloacetonitriles, halonitromethanes, haloacetaldehydes, and nitrosamines. In addition, bathers' exposure to organic matter and chlorine has been suggested to contribute to respiratory problems, including asthma, and several other health problems. [0013] The use of chemical agents also represents an environmental problem related to the accumulation and disposal of these chemicals and DBPs in the environment. Therefore, reducing the use of such chemicals and the resulting DBPs would be beneficial. [0014] In addition to the high cost and environmental and health issues associated with chemical treatment, conventional filtration systems have high capital and energy consumption costs. Traditional treatments of standard sized pools require the filtration of the entire volume of water, usually from 1 to 6 times a day using a traditionally configured centralized filtration unit. This type of system imposes a high demand on the supply of energy, as well as high capital costs associated with the filtration system, such as pipes, pumps, filters and equipment, among others. State of the art [0015] US patent 5,143,623 describes a method of removing nutrients, in which the descending particles are collected during the descent of the water body, by a structure having funnel-shaped collectors and the structure can be the size of 1 acre (4046 square meters). Said structure has to remain in place for an extended period of time of at least "few hours" in order to receive the descending particles and, furthermore, comprises a surface equal to the surface of the structure that contains the water body. The structure disclosed in US patent No. 5,143,623 is invasive since it does not allow normal development of water activities and does not allow cleaning of the bottom of the structure, therefore, it cannot provide the desired color properties. In addition, the method does not include the use of disinfectants or a filtration system. [0016] Another document W02009114206 describes a method for removing algae from eutrophic water using a settling tank and different dosages of coagulants. This method requires the construction of at least one settling tank and, preferably, at least 2 settling tanks and the amount of cationic coagulants used is greater than 150 ppm. W02009114206 requires the construction of more than one tank for its method to work properly, which requires more land and has higher costs. The method disclosed by W02009114206 does not disclose the coordinated operation of the system and applies high amounts of coagulants in a way that is not environmentally friendly. [0017] FR2785898 describes a pool water purification system, comprising filtration, sterilization and pH control. The amount of chemical agents and the energy supplied to the traditionally configured centralized filtration system and the ionization process are similar to the amounts and filtration used for standard pool technology. FR2785898 uses a large amount of chemicals to maintain a constant concentration of chemicals in the water. The method in FR2785898 also comprises filtration over the entire volume of water, therefore requiring large amounts of energy and the need for expensive filtration equipment. [0018] US patent 7,820,055 is directed to obtaining large bodies of water for recreational use, and describes a process for installing and maintaining large volumes or bodies of water for recreational purposes, such as artificial lakes and ponds, with excellent coloration, high transparency and clarity similar to those of swimming pools or tropical seas at low cost, especially for bodies of water larger than 15,000 m3. US 7,820,055 defines structural characteristics, such as skimmers for oil removal, water collection systems, construction details, types and colors of coatings, circulation systems and additive injection, requirements for water supply, pH measurement, addition of salts, use of flocculants, changing fresh water rates, additives and oxidation processes, and a suction vehicle powered by a boat. US 7,820,055 describes an open water circulation system, but does not employ filtration or a coordinated method that applies a water temperature dependent algorithm to maintain water quality according to your actual needs. [0019] W02010 / 074770A1 describes an efficient filtering process to maintain recreational and ornamental water bodies. W02010 / 074770A1 requires the application of ultrasound waves to the water, and the application of flocculants. W02010 / 074770A1 does not disclose means of coordination that coordinate the operation of the method and, therefore, imposes high energy demands. SUMMARY [0020] This summary is provided to introduce a selection of concepts in a simplified way, which are further described later in the detailed description. This summary is not intended to identify the necessary or essential resources of the subject in question. Nor is this summary intended to be used to limit the scope of the claimed matter. [0021] The present invention provides a sustainable method and system in the treatment and maintenance of large bodies of water for low bathers density for recreational use. The density of bathers in the body of water is up to 0.05 bathers or less per cubic meter, which is about 10 times less than the density considered in the design of traditional pools. By decreasing the density of bathers, it is possible to use the dilution power of water to maintain the high quality of water suitable for full contact baths without the need to maintain a permanent chlorine buffer, such as in a conventional pool. Thus, the present methods and system of the invention break the size barrier of conventional pools and provide ecological pools of very large dimensions, similar to the lakes of high clarity, which have high water quality associated with conventional pools. These ecological pools are not economically viable using conventional pool filtration technologies. [0022] The methods and systems described here eliminate the chlorine buffer used in conventional pool filtration systems. The amount of chemicals used, therefore, is very low compared to conventional pool water treatment systems. Unlike current pool water treatments, the methods and systems of the invention do not require that ORP levels be maintained permanently. In the methods and systems described here, ORP levels of at least 500 mV are maintained for a period of time determined by an algorithm that depends on the temperature of the water body. Thus, the present invention provides methods and a system capable of adjusting the amount and dosage of chemicals in response to environmental factors, such as water temperature, reducing the amount of chemicals by up to 100 times, compared to traditional treatments of pools. [0023] In addition, the methods and systems described here comprise a low-cost filtering medium, which allows filtering only a small fraction of the total volume of water, up to 200 times less than for conventional pools. Since a traditional centralized filtration unit is not employed, energy consumption and equipment costs can be up to 50 times lower in the present invention than in traditionally configured pool filtration systems. [0024] Thus, the present invention can offer several advantages over traditional pool filtration technology. The present invention employs an algorithm that adjusts the dosage and application of disinfectants to the water body, in order to maintain an ORP level at least 500 mV for a period of time that depends on the water temperature, allowing a reduction in the amount of water of chemicals used by at least an order of magnitude compared to traditional pool filtration systems. The advantages associated with decreasing the amount of chemicals include reduced operating costs and a reduction in the production of DBPs, which can be harmful to the environment and bathers. In addition, the use of a low-cost filtration system that filters a small fraction of the total water volume reduces installation costs, operating costs, and energy use compared to conventional pool filtration systems. [0025] The present invention addresses several environmental problems that arise in water treatment processes affected by bacteria and microalgae. The inventor of the new technology disclosed here, Mr. Fernando Fischmann, has developed many new advances in water treatment technology that are being rapidly adopted worldwide. In a short period of time, the technologies of the invention related to crystalline recreational lagoons have been incorporated into more than 180 projects worldwide. The inventor and his advances in water treatment technology have been the subject of more than 2,000 articles, as can be seen at http://press.crystal-lagoons.com/. The inventor has also received important international awards for innovation and entrepreneurship related to these advances in water treatment technology and has been the subject of interviews with leading media outlets, including CNN, BBC, FUJI, and Bloomberg business week (Bloomberg's Businessweek ). [0026] Both the previous summary and the following detailed description are examples and are explanatory only. Therefore, the previous summary and the following detailed description should not be considered as restrictive. In addition, characteristics or variations may be provided in addition to those set forth herein. For example, certain modalities can be directed to different combinations of characteristics and subcombination described in the detailed description. BRIEF DESCRIPTION OF THE FIGURES [0027] The accompanying drawings, which are incorporated and form part of this description, illustrate various embodiments of the present invention. In the drawings: [0028] Figure 1 is a process flow diagram illustrating a water treatment system in an embodiment of the invention. [0029] Figure 2 shows a top view of a containment structure in an embodiment of the invention. DETAILED DESCRIPTION OF THE INVENTION [0030] The following detailed description refers to the attached drawings. Although the modalities of the invention can be described, modifications, adaptations, and other implementations are possible. For example, substitutions, additions or modifications can be made to the elements illustrated in the drawings, and the methods described here can be modified by substitution, reordering, or adding stages to the disclosed methods. Consequently, the following detailed description does not limit the scope of the invention. Although systems and methods are described in terms of "understanding" of various devices or steps, systems and methods can also "consist essentially of" or "consist of" various devices or steps, unless otherwise stated. Definitions [0031] In light of this disclosure, the following terms or phrases must be understood with the meanings described below: [0032] The term "swimming pool regulations", as used here, means regulations directed to swimming pools that require the maintenance of a permanent chlorine buffer in order to avoid water contamination when new bathers enter the pool. The chlorine buffer neutralizes contaminants and kills microorganisms brought into the pool water by bathers, thus maintaining a high quality of water suitable for recreational purposes. These types of regulations are generally established by a government agency or agency. [0033] The term "chlorine buffer", as used here, means the concentration of residual chlorine in a pool or any other body of water required by pool regulations. The amount of active chlorine acts as a buffer mechanism when new microorganisms or organic matter enters the water, thereby neutralizing organic matter and killing microorganisms in such a way that organic matter can no longer be used as a nutrient for other microorganisms to consume. The chlorine buffer can relate to the ORP levels in the water, which will be controlled in accordance with the present invention. It should be understood that another disinfectant can be used instead of chlorine, such as bromine, in order to maintain the necessary levels of disinfectant. [0034] The term "traditionally configured centralized filtration system" as used herein should be understood to mean a centralized filtering unit or system with a capacity for filtering the entire volume of water in the pool, usually 1 6 times a day to comply with pool regulations. The water sent to the centralized filtration system is collected from different sources, such as drains, skimmers, or by overflow, among others. [0035] The terms "container" or "containment means" are used generically here to describe any large artificial water body, encompassing terminology such as artificial ponds, artificial lakes, artificial tanks, swimming pools and the like, which are large. [0036] The term "non-invasive cleaning system", as used here, includes a suction medium that does not interfere with the normal development of recreational activities in the water. Generally, the suction means are able to travel along the bottom surface of the containment means and the sedimented suction material. For example, a boat that pulls a suction car is a non-intrusive system, given that the permanence of this system is temporary in an area of the water body. A self-propelled suction car would also be non-intrusive. However, a system that requires fixed installations or fixed pipes would be intrusive to the normal development of water sports and other activities. [0037] The term "means of coordination" is used here generically to describe an automated system that is capable of receiving information, processing it and making a decision accordingly. In a preferred embodiment of the invention, this can be done by one person, but more preferably with a computer connected to the sensors. [0038] The term "means of applying chemicals" is used here generically to describe a system that allows the application or dispersion of chemicals in water [0039] The term "mobile suction means" is used here generically to describe a suction device, which is able to travel between the bottom surface of the sedimentation material's containment and suction means. [0040] The term "propulsion means" is used here generically to describe a propulsion device that allows to provide movement, either by pushing or pulling another device. [0041] The term "filtration means" is used here generically to describe a filtration system that can include a filter, strainer, separator, and the like. [0042] As used here, the term "small fraction" corresponding to the volume of filtered water means a flow up to 200 times less than the flow of filtrate in a traditionally configured pool filtration system. Modes for Carrying Out the Invention [0043] Traditional pool filtration methods and systems rely on the use of a chlorine buffer to neutralize contaminants and kill microorganisms that enter the body of water. These methods and systems require the application of chemicals in large quantities to maintain a permanent buffer regardless of actual water requirements. In addition, these methods and systems, in general, require a traditionally configured centralized filtration system that filters the entire volume of water, usually from 1 to 6 times a day. Thus, traditional pool technology uses a large amount of chemicals and has high capital costs and operating costs associated with the centralized filtration system. [0044] The present invention relates to a low-cost sustainable method and system for treating and maintaining bodies of water affected by bacteria and microalgae for low density recreational use. The density of use is up to 0.05 bathers per cubic meter. Unlike conventional pool filtration systems where the total volume of water is filtered one or more times a day, the methods and system of the present invention filter only a small fraction of the total volume of water, up to 200 times less per day, compared to conventional filtration systems, providing treated water that complies with bacteriological and physicochemical regulations for recreational waters in contact with the entire body. [0045] The sustainable method for treating water can be performed at low cost compared to traditional water treatment systems, due to the fact that the present invention uses less chemicals and consumes less energy than traditional treatment systems the pool water. The methods and system of the invention do not require that ORP levels of at least 650 mV be maintained permanently as in conventional pool water treatment systems. In contrast to conventional filtration systems, the methods and systems described here apply an algorithm that maintains ORP levels of at least 500 mV for a given period of time depending on the water temperature. Thus, the systems and methods of the invention provide a considerable reduction in the amount of chemicals compared to conventional pool water treatments, up to 100 times less, which decreases operating and maintenance costs. [0046] Furthermore, the methods and systems of the invention filter only a small fraction of the total volume of water, up to 200 times less per day, compared to conventional pools that require a generally centralized filtering unit that filters the entire volume of water from 1 to 6 times a day. The filtering means of the methods and system of the invention comprise a smaller filter medium compared to the centralized filtering unit which operates for shorter periods of time, resulting in energy consumption and equipment costs greater than 50 times less than in traditional swimming pool systems. [0047] A system of the present invention generally includes at least one medium containing at least one of the coordination means, at least one of the chemical application means, at least one mobile and at least one filtering medium. Figure 1 illustrates an embodiment of a system of the invention. The system includes containment means (12). The size of the containment means is not particularly limited, however, in many embodiments the containment means can have a volume of at least 15,000 m3, or, alternatively, at least 50,000 m3. It is contemplated that the containers or containment means can have a volume of 1 million m3, 50 million m3, 500 million m3, or more. [0048] The containment medium (12) has a lower part to be able to receive bacteria, algae, suspended solids, metals and other particles that are deposited from the water. In one embodiment, the containment means (12) includes a receiving means (2) for receiving particles or sedimented materials from the water to be treated. A receiving means (2) is attached to the bottom of the containment means (12) and is preferably constructed of a non-porous material capable of being cleaned. The lower part of the containment medium (12) is generally covered with non-porous material, allowing non-intrusive mobile suction means (3) to travel through the entire lower surface of the containment means (12) and suction of sedimented particles produced by any of the processes disclosed herein. Non-porous materials can be membranes, geomembranes, geotextile membranes, plastic liners, concrete, coated concrete, or combinations thereof. In a preferred embodiment of the invention, the lower part of the containment means (12) is covered with plastic liners. The containment means (12) can include an inlet line (13) for supplying water to the containment means (12). The inlet line (13) allows the filling medium (12) to be filled again due to evaporation and other water losses. [0049] The system includes at least one means of coordination (1) that can control the necessary processes depending on the needs of the system (for example, water quality). Such processes may include the activation (9) of a non-intrusive mobile suction medium (3). The coordination means (1) can receive information (8) in relation to the water quality parameters that are controlled and can opportunely activate the necessary processes to adjust the referred quality parameters within the respective limits. The information (8) received by means of coordination (1) can be obtained through visual inspection, empirical methods, algorithms based on experience, by electronic detectors, or combinations thereof. The coordination means (1) can comprise one or more people, electronic devices, or any other means capable of receiving information, processing that information, and activating other processes, and that includes their combinations. An example of a means of coordination is a computing device, such as a personal computer. The coordination means (1) can also include sensors used to receive information (8) in relation to water quality parameters. [0050] The processes are opportunely activated by means of coordination (1), in order to adjust the controlled parameters within their limits. The processes are activated according to the needs of the system, which allows the filtration of a small fraction of the total volume of water per day, thus replacing conventional pool filtration systems that filter the entire volume of water up to 6 times a day. The processes correspond to the timely activation (9) of the mobile suction means (3), which will simultaneously activate the filtering means (7) in order to filter the suction flow through the mobile suction means, filtering only a small fraction of the total water volume, up to 200 times less than conventional swimming pool filtration systems. [0051] The chemical application medium (6) applies or distributes chemicals in the water. Means for applying chemicals (6) include, but are not limited to, injectors, sprayers, manual application, weight dispensers, tubes, and combinations thereof. [0052] The non-intrusive mobile suction means (3) move along the bottom of the containment means (12), sucking water containing sedimented particles and materials produced by any of the processes described here. A propulsion means (4) is coupled to the mobile suction means (3) with a coupling means (5) allowing the mobile suction means (3) to travel through the bottom of the containment means (12). The coupling means (5) can be flexible or rigid. Examples of coupling means include, but are not limited to, ropes, wires, lines, cables, strips, rods, bars, rods, shafts, and combinations thereof. [0053] The mobile suction means must not be intrusive or alter the normal development of recreational activities in the water, such as swimming or the development of water sports. Preferably, the suction means remain temporary over a part of the water body. Thus, a system that requires fixed installations or fixed pipes would be intrusive to the normal development of water sports and other activities. The mobile suction medium travels through the bottom of the containment means, completely suctioning the water flow with the sedimented particles, and allowing to see the background color. The propulsion means (4) drive the mobile suction means (3) by means of a system such as a rail system, a cable system, a self-propelled system, a manual propulsion system, a robotic system, a system guided from a distance, a boat with an engine or a flotation device with an engine, or combinations thereof. In a preferred embodiment of the invention, the propulsion means is a boat with an engine. [0054] The water sucked by the mobile suction means (3) is sent to a filter medium (7). The filtration medium (7) receives the flow of suctioned water through the mobile suction medium (3) and filters the suctioned water containing the particles and sedimented materials, thus eliminating the need to filter the entire volume of water (for example , just filtering a small fraction). The filter medium (7) includes, but is not limited to, cartridge filters, sand filters, ultrafilters, nanofilters and combinations thereof. The suctioned water can be sent to the filtering means (7) by a collection line (10) connected to the mobile suction means (3). The collection line (10) can be selected from flexible tubes, rigid tubes, pipes of any material, and their combinations. The system may include a return line (11) from the filter means (7) back to the containment means (12) to return the filtered water. [0055] Figure 2 shows a top view of a system of the invention. The containment means (12) can include a supply piping system (13) that allows replacement of the containment means (12) due to evaporation or other water loss from the containment means (12). The containment means (12) can also include injectors (14) arranged along the perimeter of the containment means (12) for the application or distribution of chemicals in the water. The containment means (12) can also include skimmers (15) for removing oils and particles from the surface. [0056] In one embodiment, a system of the invention includes the following elements: at least one inlet line (13) for supplying water to at least one containment means (12); - at least one containment means (12) comprising a receiving means (2) for the sedimented particles produced by methods of the method, that is, fixed to the bottom of said containment means; - at least one means of coordination (1), where the means of coordination timely activates the processes necessary to adjust the parameters within their limits; - at least one chemical application medium (6), which allows the addition of disinfectant agents to the water; - at least one non-intrusive mobile suction means (3), which moves through the bottom of said at least one containment means that sucks the water flow containing the sedimented particles produced by methods of the method; - at least one of the propulsion means (4) which provides movement for said at least one non-intrusive mobile suction means so that it can move through said lower part of at least one containment means; - at least one coupling means (5), for connecting said at least one propulsion means and said at least one suction means; - at least one filter medium (7), which filters the water flow containing the sedimented particles; - at least one pick-up line (10), coupled between said at least one mobile suction means and said at least one filtering means, and - at least one return line (11) from said at least a filtering means for said at least one containment means; [0057] The method of the invention uses less chemicals and consumes less energy than traditional methods of treating swimming pools and therefore can be performed at low cost compared to traditional methods of treatment. In one aspect, the present method uses significantly less chemicals, because an algorithm is applied that allows the maintenance of an ORP of at least 500 mV for a certain period of time, depending on the water temperature. Thus, there is a considerable reduction in the amount of chemicals, up to 100 times less than traditional pool water treatment systems, which reduces operating and maintenance costs. [0058] In another aspect, the methods of the invention filter only a small fraction of the total volume of water within a given period of time compared to conventional pool filtration systems that filter a much larger volume of water in the same period of time. In one embodiment, the small fraction of the total volume of water is up to 200 times less than the flow processed in traditionally configured centralized filtration systems, which filter the entire volume of water up to 6 times a day. The filtering medium in the method and system of the invention operates in short periods of time, due to orders received from the coordination means. Thus, the filtration medium in the method and system of the present invention has a very low capacity and up to 50 times less capital costs and energy consumption compared to the centralized filtration unit used in conventional pool filtration systems. [0059] In one embodiment, the method includes the following stages: a. Collect water with a concentration of total dissolved solids (TDS) of up to 50,000 ppm; B. Storing said water in at least one containment means (12), wherein said containment means has a base capable of being carefully cleaned by a non-intrusive mobile suction means; ç. Limit the density of bathers to be up to 0.05 bathers per cubic meter of water volume contained in said containment. d. Within 7-day periods, for water temperatures of up to 45 degrees Celsius, maintain said water ORP of at least 500 mV for a minimum period of 1 hour for each degree Celsius of water temperature, by adding agents water disinfection; and. Activate the following processes through a coordination means (1), where the processes purify water and eliminate suspended solids only by filtering a small fraction of the total volume of water: i. Succeed the flow of water containing the sedimented particles produced by the previous processes, with non-intrusive mobile suction means (3) to prevent the thickness of the sedimented material from exceeding an average of 3 mm; ii. Filter the suction flow through the mobile suction medium, with at least one filter medium (7); and iii. Return the filtered water to the said at least one containment medium, thus avoiding the filtration of the total volume of water, just filtering the flow containing the sedimented particles; [0060] The disinfectant agents are applied to the water, by means of chemical application (6), in order to maintain an ORP level of at least 500 mV for a minimum period of time according to the water temperature, within periods of 7 days at a time. Disinfectant agents include, but are not limited to, ozone, biguanide products, algaecides and antibacterial agents, such as copper products, iron salts, alcohols, chlorine and chlorine compounds; peroxides, phenolic compounds; iodophores; quaternary amines (polyquaternary ammonium) in general, such as benzalkonium chloride and S-triazine, peracetic acid, halogen-based compounds; bromine-based compounds, chlorine-based compounds, and combinations thereof. Preferred disinfectants include chlorine-based compounds, ozone, biguanide products, bromine-based compounds, halogen-based compounds, or combinations thereof. [0061] The control of bacteria and microalgae in the body of water is achieved through the application of chemical products that apply disinfectant agents in the body of water. The amount of disinfectant agents used in the present invention is at least an order of magnitude less than the usual amounts required by traditional pool technology. The application of disinfectant agents results in the death of bacteria and other microorganisms, which collect and settle in the water layer along the bottom of the containment means. Unlike traditional pool technology, the disinfectant agents of the present invention are applied without the need to maintain a permanent concentration in the volume of water. The sustainable method applies an algorithm that allows the maintenance of ORP levels only for a certain period of time determined according to the water temperature. If the water temperature is up to 45 degrees Celsius, an ORP level of at least 500 mV is maintained for a minimum period of 1 hour for each degree Celsius of the water temperature. For example, if the water temperature is 25 degrees Celsius, then an ORP level of at least 500 mV is maintained for a minimum period of 25 hours, which can be spread over the period of 7 days. Water having a temperature above 45 degrees Celsius is not suitable for the recreational uses of the present invention, as temperatures may compromise the safety of bathers. [0062] The coordination means (1) can receive information (8) about the water quality parameters within the respective limits. The information received by means of coordination can be obtained by empirical methods. The coordination means (1) is also able to receive information, process the information, and activate the necessary processes according to that information, including their combinations. An example of a means of coordination is a computing device such as a personal computer, connected to sensors that allow the measurement of parameters and the activation of processes according to this information. [0063] The mobile suction medium is designed to perform a thorough cleaning of the surface of the receiving medium in such a way that the color of the surface of the receiving medium is visible, thereby providing the body of water with an attractive color. The coordination means (1) provides information (9) for the mobile suction medium (3) to activate the mobile suction medium. The filter medium (7) is activated simultaneously in order to filter the suction flow through the mobile suction medium (3), filtering only a small fraction of the total volume of water. The filtered water is then returned to the containment means (12) via the return line (11). The mobile suction means (3) is activated (9) through the coordination means (1) to prevent the thickness of the sedimented material from exceeding 3 mm on average. The filtration medium (7) and the mobile suction medium (3) operate only as necessary to maintain water parameters within their limits, for example, only a few hours a day, in contrast to conventional filtration systems that operate continuously on a daily basis. [0064] The water treated by the method of the invention can be supplied by a natural water source, such as an ocean, groundwater, lakes, rivers, treated water, or combinations thereof. The collected water can have a concentration of up to 50,000 ppm of total dissolved solids (TDS). When the TDS concentration is less than or equal to 10,000 ppm, the Langelier saturation index of the water must be less than 3. For the present invention, the Langelier saturation index can be kept below 2 by adjusting the pH, addition of anti-deposits, or a water softening process. When the TDS concentration is greater than 10,000 ppm, the Stiff & Davis Saturation index of the water must be less than 3. For the present invention, the Stiff & Davis saturation index can be maintained up to 2 by adjusting the pH , the addition of anti-deposits, or a water softening process. Antideposites that can be used to keep the Langelier saturation index or the Stiff & Davis saturation index below 2 include, but are not limited to, phosphonate-based compounds, such as phosphonic acid, PBCT (phosphonobutane acid) tricarboxylic), chromates, zinc polyphosphates, nitrites, silicates, organic substances, caustic soda, malic acid-based polymers, sodium polyacrylate, sodium salts of ethylene diamine tetracetic acid, corrosion inhibitors such as benzotriazole, and combinations thereof . EXAMPLES [0065] For the following examples, the terms "a / a / o / a" include plural alternatives (at least one). The information disclosed is illustrative, and other modalities exist and are within the scope of the present invention. Example 1 [0066] The following table summarizes the quantities of chemicals used, energy consumed and associated costs, considering a bathing density of up to 0.05 bathers per cubic meter in A) a system according to the present invention and B) a traditional pool setting. The volume of water in both A) and B) is 90,000 m3. [0067] As illustrated in the table, the cost of operating a swimming pool configured with the system of the present invention will be at least of an order of magnitude lower than a traditional configuration. Example 2 [0068] A body of water of 125,000 m3 was treated with a method and system according to the present invention. The average depth of the water body was 3,125 m. The system includes spaced injectors such as the application of chemical means at the pool border and at the bottom of the structure. The cleaning system is operated in cycles, given the size of the water body. ORP levels were determined as follows: for water temperature up to 45 degrees Celsius, an ORP level of at least 500 mV was maintained for a minimum of 1 hour for each degree Celsius of water temperature. The water temperature was 20 degrees Celsius, so that ORP levels of at least 500 mV were maintained for 20 hours during the week. On the first day of treatment, the application of chemical products injected chlorine from 9:00 am until 7:00 pm to maintain the chlorine concentration of 0.15 ppm, thus completing 10 hours of that day. The same procedure was repeated on the fourth day of treatment from 9:00 am to 7:00 pm, thus completing the 20 hours required for the 7-day treatment cycle. [0069] Before the average thickness of the sedimented material layer exceeded 3 mm, the suction of the sedimented dead microalgae and microorganism debris was initiated by means of a small boat with a propulsion motor means to move a suction device along the bottom of the structure in a zone of the structure. The other zones were activated sequentially, allowing the complete removal of dead microalgae and microorganism debris in a period of 4 hours. [0070] The suction flow was sent to a small cartridge filter, since the volume of the filtrate is a very small percentage (2.5%) of the total volume of water per day. The filter cartridge was located outside the pool, and the filtered water was returned to the pool by a flexible tube. [0071] The energy consumed for 1 week using this configuration was 2,436 kW. In a traditional pool configuration, the energy consumption calculated in one week would have been 124,306 kW. Therefore, the present invention consumes only 2% of the energy and uses an amount of chemical agents up to 100 times lower than an equivalent pool with traditional water treatment technology. [0072] Although certain modalities of the invention have been described, other modalities may exist. In addition, any disclosed method steps or phases can be modified in any way, including reordering steps and / or inserting or deleting steps, without departing from the invention. Although the specification includes a detailed description and associated drawings, the scope of the invention is indicated by the following claims. In addition, although the specification has been described in the language specific to the structural features and / or methodological acts, the claims are not limited to the features or acts described above. Instead, the specific features and acts described above are disclosed as illustrative aspects and modalities of the invention. Several other aspects, modalities, modifications and their equivalents that, after reading the description here, can be suggested to a common person versed in the technique without distancing themselves from the spirit of the invention or the scope of the claimed matter.
权利要求:
Claims (11) [0001] 1. Sustainable method to treat and maintain a body of artificial water suitable for low density recreational use, affected by bacteria and microalgae at low cost by filtering the small fraction of the total volume of the body of water, the method characterized by comprising: a. Collect water with a concentration of total dissolved solids (TDS) of up to 50,000 ppm; B. Storing said water in at least one containment means (12), wherein said containment means (12) has a lower part capable of being carefully cleaned by a non-intrusive mobile suction means (3); ç. Limit bathers' density to up to 0.05 bathers per cubic meter in said water contained in said containment medium (12); d. During an interval of 7 days, treat said water in said containment medium (12) for a total time of treatment of an oxidation-reduction potential (ORP) within the interval by periodically adding disinfectants to said water to establish a ORP of at least 500 mV, in which said total ORP treatment is dependent on the temperature of said water being treated and comprises an approximate period of 1 hour for each degree Celsius (° C) of water temperature up to a maximum temperature of 45 ° C; and. Activate the following processes through a coordination means (1) to purify said water and eliminate solids from said water by filtering only a small fraction of the total volume of said water in said containment medium (12), in which the said coordination means (1) receives information about the water quality parameters controlled by said coordination means (1) and activates processes i, ii, and iii to adjust said parameters within their limits: i. Sucking a portion of said water containing the sedimented particles with a mobile suction medium (3) to prevent the thickness of the sedimented material from exceeding an average of 3 mm; ii. Filter the suctioned water portion through the mobile suction medium (3); and iii. Return the filtered water to the said containment medium (12). [0002] 2. Method, according to claim 1, characterized by the fact that the total ORP treatment time is discontinued during the 7-day interval. [0003] 3. Method, according to claim 1, characterized by the fact that: a. if the water collected in stage a) has a total dissolved solids concentration less than or equal to 10,000 ppm, the Langelier saturation index must be less than 3; or b. if the water collected in stage a) has a total dissolved solids concentration greater than 10,000 ppm, the Stiff & Davis saturation index should be less than 3. [0004] 4. Method according to claim 3, characterized by the fact that the Langelier saturation index is kept below 2 by a process selected from pH adjustment, the addition of antideposites, or a water softening process . [0005] 5. Method according to claim 3, characterized by the fact that the Stiff & Davis saturation index is kept below 2 by a process selected from pH adjustment, the addition of antideposites, or a process of softening the Water. [0006] 6. Method according to claim 5, characterized by the fact that antideposites comprise compounds based on phosphonate, phosphonic acid, PBTC (phosphonobutane-tricarboxylic acid), chromates, zinc polyphosphates, nitrites, silicates, organic substances, soda caustic, malic acid-based polymers, sodium polyacrylate, sodium salts of ethylene diamine tetracetic acid, benzotriazole, or a combination thereof. [0007] 7. Method, according to claim 1, characterized by the fact that disinfectant agents are selected from chlorine and chlorine compounds; ozone; biguanide products; halogen-based compounds; bromine-based compounds, or a combination thereof. [0008] 8. Method according to claim 1, characterized by the fact that the mobile suction medium (3) travels through the bottom of the containment means (12) and sucks up the portion of water containing the sedimented particles. [0009] 9. Method, according to claim 1, characterized by the fact that said water is treated within the range to establish the ORP of at least 500 mV for a total treatment time during the interval that depends on the temperature of said water being treated without the need to maintain a permanent concentration of disinfectant agents in the total volume of said water. [0010] 10. Method, according to claim 1, characterized by the fact that said containment means comprises a volume of at least 15,000 m3. [0011] 11. Method according to claim 1, characterized by the fact that the total ORP treatment time is discontinued during the 7-day interval.
类似技术:
公开号 | 公开日 | 专利标题 BR112013024625B1|2020-11-17|sustainable method for treatment and maintenance of artificial water bodies, suitable for low density recreational uses, affected by bacteria and microalgae at low cost AU2016202093B2|2018-01-25|Method and system for treating water used for industrial purposes OA16594A|2015-11-20|Sustainable method and system for treating water bodies affected by bacteria and microalgae at low lost.
同族专利:
公开号 | 公开日 RS55785B1|2017-07-31| EA201391167A1|2014-03-31| CY1118779T1|2017-07-12| EA033884B9|2020-01-22| EA201790138A1|2017-04-28| EP3153474B1|2018-12-26| EP2675759A1|2013-12-25| JO3293B1|2018-09-16| NZ714579A|2017-05-26| CA2830178A1|2012-10-04| AU2016202416A1|2016-05-12| UY33990A|2012-09-28| KR20130135325A|2013-12-10| ES2717823T3|2019-06-25| AP2013007114A0|2013-09-30| CN102730878B|2015-08-12| HRP20190425T1|2019-04-19| HK1175452A1|2013-07-05| CN104944627B|2018-10-19| CR20130465A|2014-02-07| MA35055B1|2014-04-03| ECSP13012908A|2013-11-29| US20120024796A1|2012-02-02| LT2675759T|2017-06-12| PE20140451A1|2014-04-16| CN102730878A|2012-10-17| CN104944627A|2015-09-30| PL2675759T3|2017-09-29| CA2830178C|2015-03-17| US20130213866A1|2013-08-22| US8465651B2|2013-06-18| JP2014514146A|2014-06-19| HUE041803T2|2019-05-28| ES2621005T3|2017-06-30| PL3153474T3|2019-07-31| MX2013011152A|2013-12-02| HUE032217T2|2017-09-28| AU2016202416B2|2018-03-08| ZA201306553B|2013-11-27| BR112013024625A2|2018-02-27| SI3153474T1|2019-04-30| RS20120135A1|2013-10-31| RS57051B1|2018-05-31| SK288595B6|2018-09-03| US9062471B2|2015-06-23| JP5859636B2|2016-02-10| MX344899B|2017-01-09| EP2675759A4|2014-03-12| RS58403B1|2019-04-30| NZ614043A|2015-12-24| EA033884B1|2019-12-05| AR107968A2|2018-07-04| DK2675759T3|2017-04-10| LT3153474T|2019-05-10| PT3153474T|2019-04-02| KR101579068B1|2015-12-21| NI201100186A|2012-11-06| DOP2011000322A|2012-01-31| SG194011A1|2013-11-29| HRP20170473T1|2017-06-16| CL2013002603A1|2013-12-13| IL228459D0|2013-12-31| JO3211B1|2018-03-08| AR085679A1|2013-10-23| EP2675759B1|2016-12-28| AP3745A|2016-07-31| ME02686B|2017-06-20| CO6852054A2|2014-01-30| SI2675759T1|2017-07-31| EA028219B1|2017-10-31| DK3153474T3|2019-04-08| WO2012134527A1|2012-10-04| AU2011363517A1|2013-05-02| EP3153474A1|2017-04-12| CU24169B1|2016-03-31| UA114069C2|2017-04-25| IL228459A|2016-10-31| SK1132011A3|2012-10-02| SG10201609932QA|2017-01-27| GEP201606515B|2016-07-25| PT2675759T|2017-04-04| MY160689A|2017-03-15|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题 US2923954A|1960-02-09|babcock | US2071520A|1935-06-21|1937-02-23|Harrison Joseph Duke|Sports lagoon and ocean terminal| US2141811A|1937-03-20|1938-12-27|Roy B Everson|Swimming pool cleaner| US2314767A|1942-03-18|1943-03-23|Burrell Technical Supply Compa|Adjustable rubber valve| US2646889A|1950-02-15|1953-07-28|Dulak August|Swimming pool cleaning device| US3317925A|1963-05-15|1967-05-09|Robert M Vance|Swimming pool construction| US3247053A|1964-03-02|1966-04-19|Commercial Solvents Corp|Inhibiting the growth of algae in water with nu- alkylamine| US3361150A|1965-01-06|1968-01-02|Universal Interloc Inc|Water conditioning control system| US3419916A|1966-10-03|1969-01-07|Martin M. Schankler|Liner type pool construction| GB1171664A|1967-02-21|1969-11-26|Dorr Oliver Inc|Treatment of polluted streams in place| US3406416A|1967-05-05|1968-10-22|Rainbow Plastics|Wheel for swimming pool vacuum cleaner head| US3412862A|1967-09-07|1968-11-26|Merle P. Chaplin|Method and apparatus for cleaning areas overlain by a water body| US3540274A|1968-02-26|1970-11-17|Medallion Pool Corp|Pool liner| US3660957A|1968-12-10|1972-05-09|Martin M Schankler|Prefabricated swimming pool construction| US3641594A|1969-12-18|1972-02-15|Leisign Engineering Co Inc|Gutter and water supply system for swimming pools| US3695434A|1970-08-28|1972-10-03|George R Whitten Jr|Purification| US3748810A|1971-03-24|1973-07-31|Mattingly Inc|Method of swimming pool manufacture| DE2141460A1|1971-08-19|1973-02-22|Dynamit Nobel Ag|Plastic coating for swimming pools - plasticised pvc sheeting tautly fixed by use of metal strips fixed onto the edge of| US3788982A|1972-01-18|1974-01-29|F Zsoldos|Color control of water that is recirculated| US3844760A|1972-02-29|1974-10-29|Monsanto Co|Composition for and method of treating water| HU165521B|1972-07-03|1974-09-28| US4119535A|1973-04-16|1978-10-10|White Eugene B|Method of sanitizing a volume of water in conjunction with chlorine| FR2269317B2|1973-12-26|1977-03-11|Chandler Michael| DE2505846A1|1974-02-15|1975-08-21|Vmw Ranshofen Berndorf Ag|CLADDING MADE OF PROFILED SHEETS, IN PARTICULAR SHEET METALS FOR SPATIAL CURVED SURFACES| US4176058A|1974-10-24|1979-11-27|Grobler Jacobus J|Method means for de-silting water| US3950809A|1974-11-08|1976-04-20|Rudolf Emil Schatzmann|Combination sweeper and vacuum cleaner for swimming pools| US4090266A|1975-12-19|1978-05-23|Price John W|Swimming pool construction| US4519914A|1975-06-30|1985-05-28|Kenji Etani|Method for treating swimming pool water| US4880547A|1975-06-30|1989-11-14|Kenji Etani|Methods for water treatment| GB1494005A|1976-04-30|1977-12-07|Intchim Ltd|Swimming pools| US4055491A|1976-06-02|1977-10-25|Porath Furedi Asher|Apparatus and method for removing fine particles from a liquid medium by ultrasonic waves| US4100641A|1976-06-24|1978-07-18|Pansini Andrew L|Swimming pool cleaners| US4063419A|1976-11-12|1977-12-20|Garrett Donald E|Energy production from solar ponds| US4117683A|1977-01-24|1978-10-03|Rasmussen Ross H|System and method for cooling hot water from industrial plant cooling use| US4129904A|1977-11-14|1978-12-19|Pansini Andrew L|Swimming pool cleaner| IL55402D0|1978-08-21|1978-10-31|Melamed A|Method and means for cooling of heat generating industrial operations| CH638272A5|1978-12-27|1983-09-15|Sommer Schenk Ag|UNDERWATER CLEANING DEVICE.| US4263759A|1979-03-15|1981-04-28|Bradley Enterprises, Inc.|Swimming pool construction and method of making the same| US4227361A|1979-03-16|1980-10-14|Bradley Enterprises, Inc.|Method of constructing a swimming pool| US4254525A|1979-07-12|1981-03-10|Aladdin Equipment Company|Submerged surface vacuum cleaner| EP0041516B1|1979-12-03|1984-09-19|DURACK, Michael James|Liquid retaining structures| US4306967A|1980-04-14|1981-12-22|Trautwein Bill B|Cooling tower basin water treating apparatus| JPS5912287B2|1980-07-12|1984-03-22|Akira Ito| US4338697A|1980-08-14|1982-07-13|Caleb Broadwater|Simplified pool cleaning apparatus| US4343696A|1981-02-03|1982-08-10|Hung Pai Yen|System for removing sludge from dam reservoir| US4402101A|1981-08-07|1983-09-06|Zyl Robert M Van|Power pool cleaner| US4548371A|1982-06-11|1985-10-22|Ultralight Flight, Inc.|Ultralight aircraft| US4464215A|1982-07-28|1984-08-07|W. R. Grace & Co.|Process of applying a unitary construction barrier| US4572767A|1982-09-28|1986-02-25|Mccord James W|Vapor generating and recovery apparatus| IT1206485B|1983-04-06|1989-04-27|Mario Scheichenbauer|METHOD FOR THE CONSTRUCTION OF SWIMMING POOLS REALIZED WITH CASSERI APERDERE.| JPS59222294A|1983-05-30|1984-12-13|Nippon Kankyo Seibi:Kk|Purification of lake water or river water using contact material| US4652378A|1984-08-15|1987-03-24|Solmat Systems, Ltd.|Method of and apparatus for reduction of turbidity in a body of fluid| JPH0473612B2|1984-11-26|1992-11-24| US4581075A|1985-03-15|1986-04-08|Maxi-Sweep, Inc.|Self-propelled water borne pool cleaner| US4640784A|1985-07-29|1987-02-03|Cant Investments Pty. Limited|Method and apparatus for cleaning swimming pools| US4692956A|1985-12-31|1987-09-15|Kassis Amin I|Pool vacuum| US4752740A|1986-05-19|1988-06-21|Steininger Jacques M|Electronic water chemistry analysis device with linear bargraph readouts| US5028321A|1986-07-23|1991-07-02|Damon K. Stone|Method and apparatus for water circulation, cleaning, and filtration in a swimming pool| US5107872A|1986-08-15|1992-04-28|Meincke Jonathan E|Cleaning system for swimming pools and the like| ES2001429A6|1986-09-18|1988-05-16|Crystalclear Co S A|Treating water to destroy pathogens| US4768532A|1987-01-23|1988-09-06|Jandy Industries|Underwater pool cleaner| US4767511A|1987-03-18|1988-08-30|Aragon Pedro J|Chlorination and pH control system| AT389235B|1987-05-19|1989-11-10|Stuckart Wolfgang|METHOD FOR CLEANING LIQUIDS BY MEANS OF ULTRASOUND AND DEVICES FOR CARRYING OUT THIS METHOD| US4863365A|1987-07-27|1989-09-05|Pipe Liners, Inc.|Method and apparatus for deforming reformable tubular pipe liners| US4948296A|1987-12-18|1990-08-14|Huntina Pty. Ltd.|Swimming pool construction| US4835810A|1988-01-06|1989-06-06|Rainbow Lifegard Products, Inc.|Wheeled pool vacuum head with vacuum enhancing seal| US4849024A|1988-01-07|1989-07-18|Liberty Pool Products S.A.|Pool cleaner| US4776053A|1988-02-01|1988-10-11|Kiraly J George|Swimming pool vacuum cleaner hydrofoil| US4952398A|1988-03-17|1990-08-28|Jean Tapin|Biocidal composition with copper algicide| JPH0444752Y2|1988-06-04|1992-10-21| IT1217945B|1988-06-28|1990-03-30|Egatechnics Srl|AUTOMATIC SELF-PROPELLED CLEANER FOR SWIMMING POOLS| ZA885179B|1988-07-18|1989-04-26|Graham Mervyn Elliott|Swimming pool skimmer| DE3844374A1|1988-12-30|1990-07-05|Wahnbachtalsperrenverband|Method for removing motile microorganisms from water| US4931187A|1989-02-07|1990-06-05|Klenzoid, Inc.|Cooling tower system| US4909266A|1989-03-10|1990-03-20|Frank Massa|Ultrasonic cleaning system| DK0429631T3|1989-06-16|1993-08-30|Univ Houston|Biocidal Methods and Compositions for Recycling Water Systems| GB2243151A|1990-04-20|1991-10-23|Lu Wen Pin|Device for aerating and dispersing chemicals in lakes etc.| US5039427A|1990-06-19|1991-08-13|General Chemical Corporation|Method of treating lake water with aluminum hydroxide sulfate| FR2665209A1|1990-07-25|1992-01-31|Chandler Michael|HYDRAULIC BROOM DEVICE FOR POOL POOL AND THE LIKE.| JPH076180B2|1990-09-03|1995-01-30|鹿島建設株式会社|Seawater purification facility using tidal range| US5293659A|1990-09-21|1994-03-15|Rief Dieter J|Automatic swimming pool cleaner| US5106229A|1990-10-09|1992-04-21|Blackwell William A|In ground, rigid pools/structures; located in expansive clay soil| FR2668527B1|1990-10-29|1992-12-31|Negri Jean Daniel|WATER BASIN STRUCTURE, AND METHOD FOR THE PRODUCTION THEREOF.| ES2086444T3|1990-10-31|1996-07-01|3S Systemtechn Ag|SELF-PROPELLED CLEANING DEVICE, IN PARTICULAR FOR POOLS.| US5174231A|1990-12-17|1992-12-29|American Colloid Company|Water-barrier of water-swellable clay sandwiched between interconnected layers of flexible fabric needled together using a lubricant| US5108514A|1991-02-08|1992-04-28|Kisner Kim T|In-situ method for cleaning swimming pools without draining the water| US5143623A|1991-06-17|1992-09-01|Kroll Brian L|Nutrient and particle removal: method and apparatus for treatment of existing lakes, ponds and water bodies| JP3026643B2|1991-07-16|2000-03-27|三洋電機株式会社|Air supply and exhaust system| FR2685374B1|1991-12-24|1994-03-25|Pierre Nicoloff|SELF-CONTAINED VACUUM ROBOT FOR POOLS.| US5268092A|1992-02-03|1993-12-07|H.E.R.C., Inc.|Two water control system using oxidation reduction potential sensing| JPH05220466A|1992-02-13|1993-08-31|Hideaki Sakai|Method and apparatus for automatic adding and stirring and method for using apparatus for automatic adding and stirring and method for cleaning water in pond, lake or river by means of apparatus for automatic adding and stirring and apparatus for cleaning water of pond, lake or river by means of automatic adding and stirring| JPH05261395A|1992-03-17|1993-10-12|Hitachi Kiden Kogyo Ltd|Clarifying device for water area| JP2977663B2|1992-04-14|1999-11-15|サンデン株式会社|Underwater vacuum cleaner| US5422014A|1993-03-18|1995-06-06|Allen; Ross R.|Automatic chemical monitor and control system| US5337434A|1993-04-12|1994-08-16|Aqua Products, Inc.|Directional control means for robotic swimming pool cleaners| US5398361A|1994-03-21|1995-03-21|Cason; Kurt N.|Vacuum cleaner for submerged non-parallel surfaces| IL109394A|1994-04-22|1997-03-18|Maytronics Ltd|Swimming pool cleaning, navigational control system and method| JPH07310311A|1994-05-17|1995-11-28|Shimizu Corp|Artificial lagoon| US5454129A|1994-09-01|1995-10-03|Kell; Richard T.|Self-powered pool vacuum with remote controlled capabilities| US5616239A|1995-03-10|1997-04-01|Wendell; Kenneth|Swimming pool control system having central processing unit and remote communication| DE19515428C2|1995-04-26|1997-03-13|L V H T Lehr Und Versuchsgesel|Process for the treatment of various industrial waters in leisure pools| NZ333404A|1996-06-26|2000-06-23|Jordan M Laby|Automatic swimming pool cleaning system using an apparatus powered from the pressure side of a pump| FR2740493B1|1995-10-27|1998-01-09|Armater|BASIN OR POOL STRUCTURE WITHOUT VERTICAL WALL| US5782480A|1995-12-20|1998-07-21|Phillips; Reuben|Wheeled amphibious vehicle| US5802631A|1996-07-01|1998-09-08|Friedman; Jerome|Pool liner installation method and apparatus| US6657546B2|1996-10-04|2003-12-02|Pablo F. Navarro|Integrated water treatment control system with probe failure detection| JPH10169226A|1996-12-11|1998-06-23|Nippon Filcon Co Ltd|Pool water circulating and filtering method, and circulating and filtering type pool| CN2292798Y|1997-02-15|1998-09-30|赵昌银|Water circulation treatment and underwater dirt collecting device for swimming pool| JP3970971B2|1997-02-26|2007-09-05|大和工業株式会社|Pool facility remote monitoring system| FR2760483A1|1997-03-10|1998-09-11|Philippe Billaud|ELECTRONIC APPARATUS FOR AUTOMATIC FILTRATION MANAGEMENT BASED ON TEMPERATURE PARAMETERS, FILTRATION TIME| DE19814705A1|1997-04-02|1998-10-08|Hellebrekers Install Tech Bv|Process and assembly treats continual flow of swimming pool water with agent| US5842243A|1997-04-24|1998-12-01|Aqua Products Inc.|Manually propelled pool cleaner| EP1007184A4|1997-05-15|2004-07-21|Orange County Water Distr|Method and system for cleaning a water basin floor| KR200162956Y1|1997-06-11|1999-12-15|강동석|The screen washing devise of a waste water treatment apparatus| JP3267904B2|1997-08-20|2002-03-25|株式会社マリン技研|Water purification system| DE29716994U1|1997-09-23|1997-11-13|Teichform Gmbh|Artificial garden pond| JP3641930B2|1998-03-19|2005-04-27|株式会社日立製作所|Sterilization treatment method and sterilization treatment apparatus| US6846452B2|1998-07-17|2005-01-25|Ashland Inc.|Scale inhibitor for an aqueous system| IL125592A|1998-07-30|2004-06-01|Argad Eyal Water Treat Technol|Water treatment| FR2785898B1|1998-11-17|2000-12-22|Jacques Giroguy|PROCESS AND INSTALLATION FOR SANITATION OF BASIN WATERS SUCH AS POOL WATERS| US6317901B1|1998-11-30|2001-11-20|Noel Leon Corpuel|Fresh or salt water pool| CN1256250A|1998-12-09|2000-06-14|中国科学院生态环境研究中心|Water purifying process including micro flocculation of inorganic high-molecular flocculant and direct deep-bed filtration| DE19860568B4|1998-12-22|2005-08-04|Menschel, Claudia, Dr.rer.nat.|Process and plant for the remediation of surface waters| US6149819A|1999-03-02|2000-11-21|United States Filter Corporation|Air and water purification using continuous breakpoint halogenation and peroxygenation| US6409926B1|1999-03-02|2002-06-25|United States Filter Corporation|Air and water purification using continuous breakpoint halogenation and peroxygenation| US6419840B1|1999-03-30|2002-07-16|Jonathan E Meincke|Cleaning system for swimming pools and the like| US6539573B1|1999-04-05|2003-04-01|Michael A. Caccavella|JetNet| US6231268B1|1999-04-19|2001-05-15|Limnetics Corporation|Apparatus and method for treatment of large water bodies by directed circulation| US6303038B1|1999-06-01|2001-10-16|Albemarle Corporation|Solid mixtures of dialkylhydantoins and bromide ion sources for water sanitization| JP2001003586A|1999-06-23|2001-01-09|N Tec Kk|Algae generation preventive device for pool with elevating floor| JP2001009452A|1999-06-30|2001-01-16|Nkk Corp|Treatment equipment for swimming pool water and treatment by the equipment| US6277288B1|1999-07-12|2001-08-21|Joseph Gargas|Combined ozonation and electrolytic chlorination water purification method| TW482186U|1999-11-23|2002-04-01|Sheng-Yi Liu|Breeded-cycle water treat equipment| US6280639B1|2000-06-20|2001-08-28|Pedro G. Ortiz|Method and apparatus for automatic cleaning of a swimming pool| US20030228195A1|2000-08-21|2003-12-11|Masaru Mizutani|Pool using deep-sea water and its surrounding facilities| JP4463405B2|2000-09-20|2010-05-19|東亜ディーケーケー株式会社|Sensor for redox current measuring device and redox current measuring device| FR2818681B1|2000-12-21|2003-04-04|Zodiac Pool Care Europe|SIDE TRANSMISSION CASSETTE FOR SELF-PROPELLED ROLLING DEVICE UNDERWATER SURFACE CLEANER| US6620315B2|2001-02-09|2003-09-16|United States Filter Corporation|System for optimized control of multiple oxidizer feedstreams| JP4427202B2|2001-03-27|2010-03-03|有限会社アトラス|Pool water purification treatment method| JP3723091B2|2001-04-10|2005-12-07|三菱重工業株式会社|Water purification equipment| CN2467601Y|2001-04-16|2001-12-26|王泽蓉|Stable pressure storing water drinking water and domestic water qualities separating multifunction supply water tank| AT452260T|2001-07-03|2010-01-15|Pentair Pool Products Inc|CHAIR FOR AN AUTOMATIC SWIMMING POOL CLEANER| FI116305B|2001-07-27|2005-10-31|Antti Happonen|Methods and devices for utilizing water energy| GB0118749D0|2001-08-01|2001-09-26|Procter & Gamble|Water treatment compositions| US6644030B2|2001-09-10|2003-11-11|Usgen New England, Inc.|Cooling systems and methods of cooling| JP4183415B2|2001-12-27|2008-11-19|和重 田沼|Water purification equipment| JP2003200173A|2002-01-09|2003-07-15|Tadashi Inoue|Water cleaning material of water tank such as cooling tower containing inorganic antibacterial agent or the like and water cleaning method| DE10201089A1|2002-01-14|2003-07-31|P & W Invest Vermoegensverwalt|Process for the disinfection and cleaning of water-bearing systems, in particular in swimming and bathing pool systems, and device for carrying it out| CN2541443Y|2002-03-19|2003-03-26|沈忠文|Swimming pool water circulating and purifying appts.| ES2290417T3|2002-04-25|2008-02-16|Astral Pool España, S.A.|EQUIPMENT FOR THE TREATMENT OF POOL WATER.| US7189314B1|2002-09-06|2007-03-13|Sensicore, Inc.|Method and apparatus for quantitative analysis| US7094353B2|2002-11-04|2006-08-22|Arch Chemicals, Inc.|Method of water treatment| FR2847286A1|2002-11-14|2004-05-21|Marie Jeanne George|POOL TILE PROFILE| JP4188125B2|2003-03-05|2008-11-26|Tdk株式会社|Magnetic recording medium manufacturing method and manufacturing apparatus| CN1256250C|2003-03-06|2006-05-17|郭风华|Two-way driven machine horse and its matched farm tools| US7022223B2|2003-05-13|2006-04-04|Tesomas Holdings Llc|Methods and systems for removing floating solid waste from the surface of a watercourse| AU2003902540A0|2003-05-23|2003-06-05|Watertech Services International Pty Ltd|A swimming pool cleaning and sanitising system| US6896799B2|2003-06-16|2005-05-24|Garabet Nemer Ohanian|Fish aquarium| US20050016906A1|2003-06-27|2005-01-27|Doug Gettman|Mobile field electrical supply, water purification system, wash system, water collection, reclamation, and telecommunication apparatus| CA2532079C|2003-07-11|2010-02-09|Pda Security Solutions, Inc.|Remote monitoring system for water supply network| DE10334521A1|2003-07-29|2005-02-24|P & W Invest Vermögensverwaltungsgesellschaft mbH|Flocculant, process for its preparation and its use| CN2635653Y|2003-07-29|2004-08-25|刘正义|Scale-removing water-purifying circulation device for swimming pool| US7118307B2|2003-09-24|2006-10-10|Eea Inc.|Cooling water intake system| US20050207939A1|2003-12-05|2005-09-22|Christopher Roussi|Water-quality assessment system| US20060169322A1|2003-12-12|2006-08-03|Torkelson John E|Concealed automatic pool vacuum systems| US7252843B2|2003-12-16|2007-08-07|Moore David J|Composition for cleaning contained bodies of water| JP4729263B2|2004-04-02|2011-07-20|イーエス・テクノロジー株式会社|Water quality management method| US20070181498A1|2004-05-10|2007-08-09|Povl Kaas|Method and a system for purifying water from a basin, in particular a swimming pool| JP3964415B2|2004-09-01|2007-08-22|▲隆▼ 桝井|Water quality improvement method| US8007653B2|2004-09-15|2011-08-30|Aquatron, Inc.|Method and appartus for operation of pool cleaner with integral chlorine generator| EP1853523B1|2004-12-30|2012-07-18|Dewatering Filtration Technology Services Pty Ltd|Method for ground water and wastewater treatment| ITPD20050028A1|2005-02-08|2006-08-09|Vittorio Pareti|POOL CLEANING MACHINE| JP2006289230A|2005-04-08|2006-10-26|Yamatake Corp|Water treatment apparatus and water treatment method| WO2006110928A1|2005-04-14|2006-10-19|Man Fui Tak|Swimming pool cleaning system| US7832959B1|2005-04-18|2010-11-16|Bean Stuyvesant, L.L.C.|Method of restoration of a highly saline lake| ITPD20050261A1|2005-09-09|2007-03-10|Alessandro Milani|PROCEDURE FOR THE CONSTRUCTION OF UNDERGROUND POOLS, FOUNTAINS AND ARTIFICIAL LAKES IN GENERAL| US7754073B2|2005-11-22|2010-07-13|Ultra Aquatic Technology Pty Ltd|Method and apparatus for collecting and/or removing sludge| US20070181510A1|2006-02-03|2007-08-09|Harvey Michael S|Algaecidal compositions for water treatment and method of use thereof| EP2004556B1|2006-04-10|2015-09-16|Medora Environmental, Inc.|Water circulation system for ponds, lakes, municipal tanks, and other bodies of water| US7437248B2|2006-07-03|2008-10-14|Zakaria Sihalla|Water quality sampling system| AR060106A1|2006-11-21|2008-05-28|Crystal Lagoons Corp Llc|PROCESS OF OBTAINING LARGE WATER BODIES OVER 15,000 M3 FOR RECREATIONAL USE WITH COLORING, TRANSPARENCY AND CLEANING FEATURES SIMILAR TO THE TROPICAL POOLS OR SEA TROPICAL SEA AT LOW COST| US7699994B2|2007-08-02|2010-04-20|Ecosphere Technologies, Inc.|Enhanced water treatment for reclamation of waste fluids and increased efficiency treatment of potable waters| US8721898B2|2007-08-02|2014-05-13|Ecosphere Technologies, Inc.|Reactor tank| JP5132282B2|2007-12-03|2013-01-30|アズビル株式会社|Water management device and water management method| WO2009114206A2|2008-03-14|2009-09-17|Franklin Bailey Green|Method to remove algae from eutrophic water| CL2008003900A1|2008-12-24|2009-03-13|Crystal Lagoons Curacao Bv|Water filtration process of a pond, without filtering the entire water, which comprises a) emitting ultrasonic waves in the pond; b) add a flocculant; c) suction the floccules with a vacuum cleaner towards an effluent collection line; d) filter said effluent and return the filtered flow to the pond.| US8153010B2|2009-01-12|2012-04-10|American Air Liquide, Inc.|Method to inhibit scale formation in cooling circuits using carbon dioxide| JP5208061B2|2009-06-29|2013-06-12|株式会社日立製作所|Flocculant injection control system| US8312768B2|2009-07-10|2012-11-20|Centro De Investigaciones Submarinas S.L.|Autonomous and remote-controlled multi-parametric buoy for multi-depth water sampling, monitoring, data collection, transmission, and analysis| US8211296B2|2010-04-09|2012-07-03|Nch Ecoservices, Llc|Portable water treatment system and apparatus| DE102010019510B4|2010-05-06|2018-03-29|Brain Brandenburg Innovation Gmbh|Process for introducing chemical additives into waters|AR060106A1|2006-11-21|2008-05-28|Crystal Lagoons Corp Llc|PROCESS OF OBTAINING LARGE WATER BODIES OVER 15,000 M3 FOR RECREATIONAL USE WITH COLORING, TRANSPARENCY AND CLEANING FEATURES SIMILAR TO THE TROPICAL POOLS OR SEA TROPICAL SEA AT LOW COST| JO3415B1|2011-03-30|2019-10-20|Crystal Lagoons Tech Inc|System for treating water used for industrial purposes| FR2982893B1|2011-11-21|2015-05-22|Aldebaran Robotics|BASIN MONITORING SYSTEM AND METHOD OF MONITORING| CA2855564C|2012-12-19|2019-01-15|Crystal LagoonsB.V.|Localized disinfection system for large water bodies| CN103880128B|2012-12-19|2016-08-17|水晶池有限公司|Localization decontamination system for great water body| US9920498B2|2013-11-05|2018-03-20|Crystal LagoonsB.V.|Floating lake system and methods of treating water within a floating lake| JOP20190185A1|2013-12-12|2017-06-16|Crystal Lagoons Tech Inc|System for maintaining water quality in large water bodies| ME03478B|2014-11-12|2020-01-20|Crystal Lagoons Curacao Bv|Suctioning device for large artificial water bodies| BR112017013072A2|2014-12-19|2018-02-20|Coca Cola Co|on-demand system to extract and purify well water| KR101570120B1|2015-04-01|2015-11-19|주식회사 현진기업|Removing system of green tide using ultrasonic wave| CN106367351B|2015-07-23|2021-07-09|中国石油化工股份有限公司|Microalgae collecting method and application thereof| WO2017189997A1|2016-04-29|2017-11-02|Peroxychem Llc|Wastewater treatment method| JOP20190012A1|2018-02-01|2019-08-01|Crystal Lagoons Tech Inc|A publicly accessible urban beach entertainment complex for bringing the beach life to the cities including a surf feature with a centerpiece man-made tropical-style lagoon and method for providing efficient utilization of limited use land in urban location| JOP20190011A1|2018-02-01|2019-07-02|Crystal Lagoons Tech Inc|A publicly accessible urban beach entertainment complex for bringing the beach life to the cities with a centerpiece man-made tropical-style lagoon and method for providing efficient utilization of limited use land in urban location| US11015333B2|2018-02-01|2021-05-25|Crystal Lagoons Technologies, Inc.|Publicly accessible urban beach entertainment complex including a surf feature with a centerpiece man-made tropical-style lagoon and method for providing efficient utilization of limited use land| US11270400B2|2018-02-01|2022-03-08|Crystal Lagoons Technologies, Inc.|Publicly accessible urban beach entertainment complex with a centerpiece man-made tropical-style lagoon and method for providing efficient utilization of limited use land| US11132663B2|2018-02-01|2021-09-28|Crystal Lagoons Technologies, Inc.|Publicly accessible urban beach entertainment complex including a surf feature with a centerpiece man-made tropical-style lagoon and method for providing efficient utilization of limited use land| US11186981B2|2018-02-01|2021-11-30|Crystal Lagoons Technologies, Inc.|Publicly accessible urban beach entertainment complex with a centerpiece man-made tropical-style lagoon and method for providing efficient utilization of limited use land| US11123645B2|2018-02-01|2021-09-21|Crystal Lagoons Technologies, Inc.|Publicly accessible urban beach entertainment complex with a centerpiece man-made tropical-style lagoon and method for providing efficient utilization of limited use land| US10597316B2|2018-06-13|2020-03-24|Dt Engenharia De Empreendimentos Ltda|System for implementation or de-pollution and revitalization of artificial or natural lakes| US11098495B2|2018-12-26|2021-08-24|Crystal Lagoons Technologies, Inc.|Urban transformation and construction method for creating a public access tropical style swimming lagoon with beaches within vacant or abandoned sites| US10724260B2|2018-12-26|2020-07-28|Crystal Lagoons Technologies, Inc.|Construction method for creating a restricted access swimming lagoon with beaches at a retail site| CN111104860B|2019-11-19|2022-02-15|浙江工业大学|Unmanned aerial vehicle water quality chromaticity monitoring method based on machine vision|
法律状态:
2019-07-02| B06T| Formal requirements before examination [chapter 6.20 patent gazette]| 2020-02-04| B06A| Patent application procedure suspended [chapter 6.1 patent gazette]| 2020-05-26| B09A| Decision: intention to grant [chapter 9.1 patent gazette]| 2020-11-17| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 12/09/2011, OBSERVADAS AS CONDICOES LEGAIS. |
优先权:
[返回顶部]
申请号 | 申请日 | 专利标题 US201161469548P| true| 2011-03-30|2011-03-30| US61/469,548|2011-03-30| US13/136,458|2011-08-01| US13/136,458|US8465651B2|2011-03-30|2011-08-01|Sustainable method and system for treating water bodies affected by bacteria and microalgae at low cost| PCT/US2011/051244|WO2012134527A1|2011-03-30|2011-09-12|Sustainable method and system for treating water bodies affected by bacteria and microalgae at low cost| 相关专利
Sulfonates, polymers, resist compositions and patterning process
Washing machine
Washing machine
Device for fixture finishing and tension adjusting of membrane
Structure for Equipping Band in a Plane Cathode Ray Tube
Process for preparation of 7 alpha-carboxyl 9, 11-epoxy steroids and intermediates useful therein an
国家/地区
|