timing belts and timing belt manufacturing methods

专利摘要:
TOOTHED BELT. A toothed belt is provided that has a satisfactory durability, even under conditions of high temperature and high load or within an oil or water environment. The toothed belt 10 comprises a belt body 13 including a rubber part of the tooth 11 and a rubber part of support 12. A surface of the rubber part of the tooth 11 is covered with a face fabric 20. The face fabric 20 it undergoes RFL treatment, and has an outer surface 21 covered with a hardened material from a first epoxy resin. The softening point of the hardened material of the first epoxy resin is, for example, 110 ° or higher. The epoxy equivalent of the first epoxy resin is preferably from 100 to 1500 g / eq. Alternatively, the face fabric 20 is subjected to treatment by impregnation with a treatment agent including a second epoxy resin, a hardener to harden the second epoxy resin, and a rubber component.
公开号:BR112013021734B1
申请号:R112013021734-0
申请日:2012-02-16
公开日:2021-03-09
发明作者:Keiji Sakamoto；Shinji Uchigashima；Masanao Sakamoto
申请人:The Gates Corporation；
IPC主号:

专利说明:

Technical Field
[001] The present invention relates to a toothed belt, and in particular to a toothed belt used under high temperature and high load conditions or in an environment with oil or water. Background of the Invention
[002] Conventionally, toothed belts are used for power transmission in internal combustion engines and the like. To improve the resistance of a toothed belt to wear, a face fabric is adhered to a tooth surface of the belt. The face fabric is subjected to an impregnation treatment with a treatment agent, such as RFL or rubber adhesive.
[003] Recently, toothed belts have been used with increasing frequency under conditions of high temperature and high load. That is, the use of more compact or similar engine compartments requires that the timing belts are miniaturized and functional in higher temperature environments. In addition, toothed belts are finding wider applications, and in some cases can be used in the presence of oil.
[004] When a toothed belt is used in a high-temperature, high-load environment, however, a face tissue treatment agent, such as RFL, can wear out quickly. For this reason, cracks and other defects are more likely to occur in the face tissue, and the life span of the toothed belt may be reduced. Furthermore, since the tissue treatment agent described above does not have sufficient oil resistance, the toothed belt tends to have a reduced life span when used in the presence of an oil environment.
[005] Patent Document 1 discloses that a face fabric is subjected to treatment with RFL, and then further subjected to the impregnation treatment with rubber adhesive, to which is added an epoxy or similar compound.
[006] In addition, there have been a number of widely known technologies for improving the durability of a belt by preventing the degradation of a face fabric by treating it with RFL or rubber adhesive. However, when the belt is operated in the presence of oil or water, or under high temperature conditions, treatment agents, such as RFL and rubber adhesive, are prone to degradation and are not able to sufficiently protect the face fabric. - you. For this reason, the treatment agent applied to the face fabric wears off quickly, and the pulleys come into direct contact with the fiber material of the face fabric. As a result, cracks and the like occur in the face fabric, and the durability of the belt is greatly compromised.
[007] For example, a scheme is also known in which the tensile strength of a face tissue is enhanced by adding an aromatic epoxy resin to an RFL treatment liquid, as disclosed in Patent Document 2. Patent Document 1: Publication of Patent Application JP No 2004324832 Patent Document 2: Publication of Patent Application JP No 2001220008 Summary of the Invention Technical problems
[008] However, the epoxy compound in Patent Document 1 is used to improve the adhesion between the face fabric and the belt body, but not to form a coating on a face fabric surface. For this reason, the epoxy compound in Patent Document 1 does not improve wear resistance or oil resistance.
[009] In addition, a fluorine rubber is used as the rubber of the belt body to improve oil resistance in some cases. However, a fluorine rubber may swell, depending on what type of oil is present. For this reason, the oil resistance obtained by the simple use of a fluorine rubber for the belt body is insufficient in some cases.
[010] Furthermore, an RFL-based treatment liquid is not capable of sufficiently improving water resistance, heat resistance, oil resistance, among other attributes of face fabric, even when an epoxy resin is also used. added to the treatment liquid, and is not able to sufficiently improve the durability of a belt used under conditions of high temperature and high load or in an oil or water environment.
[011] The present invention was designed in view of the problems described above, and an objective of the present invention is to improve the wear resistance and the oil and water resistance of a face fabric, and to provide a toothed belt that has a satisfactory life. even when used under high temperature and high load conditions or in an oil or water environment. Solution to Technical Problems
[012] A toothed belt according to the first aspect of the present invention comprises a belt body which includes a tooth part and a tooth bottom part alternately provided on a surface side thereof along the longitudinal direction, and a fabric face that is provided on a surface of the belt body and has an outer surface covered with a hardened material of a first epoxy resin.
[013] The softening point of the hardened material of the first epoxy resin is preferably 110 ° or higher. The epoxy equivalent of the first epoxy resin is preferably 150 to 1500 g / eq. In addition, the hardened material of the first epoxy resin is preferably applied to the face fabric that is subjected to treatment with RFL.
[014] The first epoxy resin is hardened by a first hardener, and the first hardener includes, for example, at least one hardener selected from the group consisting of amine based hardener, acid anhydride based hardener, base hardener of novolac phenol, imidazole-based hardener, and diciandiamide-based hardener. The first hardener is preferably an imidazole-based hardener.
[015] The first epoxy resin preferably includes at least one epoxy resin selected from the group consisting of bisphenol A epoxy resin, bisphenol F epoxy resin, novolac epoxy resin, biphenyl epoxy resin, phenoxy epoxy resin, and long chain aliphatic epoxy resin.
[016] A method of manufacturing a toothed belt according to the first aspect of the present invention comprises coating a surface of a face fabric with a first epoxy resin solution including a first epoxy resin, integrating the rubber arranged on the other side of surface of the face fabric coated to the face fabric and harden the first epoxy resin coating the face fabric by vulcanization.
[017] A toothed belt according to the second aspect of the present invention comprises: a belt body that includes a tooth part and a tooth bottom part alternately provided on a surface side thereof along longitudinal directions and a fabric face that is applied to cover said first belt body surface, the face fabric being treated with a treatment agent composition including a second epoxy resin, a second hardener to harden the second epoxy resin, and a rubber component .
[018] The second epoxy resin includes, for example, at least one epoxy resin selected from the group consisting of aliphatic epoxy resin, novolac epoxy resin, bisphenol A epoxy resin, bisphenol F epoxy resin, biphenyl epoxy resin , and phenoxy-type epoxy resin. In these epoxy resins, the epoxy resin preferably includes at least one epoxy resin selected from the group consisting of aliphatic epoxy resin and novolac type epoxy resin. In addition, the second hardener is preferably an imidazole based hardener.
[019] The rubber component is preferably latex, and the face fabric is preferably subjected to an impregnation treatment with a mixture obtained by diluting the treatment agent composition with water. In addition, the rubber component is preferably nitrile rubber (NBR), hydrogenated nitrile rubber (HNBR) or hydrogenated carboxylic nitrile rubber (HXNBR). Furthermore, the weight ratio of the second epoxy resin to the rubber component (for example, latex) is, for example, from 1: 9 to 9: 1.
[020] The part of the belt body to be adhered to the face fabric is preferably molded by vulcanizing a rubber composition including rubber, resorcinol and a melamine compound. In addition, the rubber of the belt body part to be adhered to the face fabric most preferably includes HNBR or HXNBR.
[021] The outer surface of the face fabric treated with the treatment agent composition including the second epoxy resin, the second hardener to harden the second epoxy resin and the rubber component can be additionally coated with a hardened material from a third resin epoxy.
[022] A method of making a toothed belt according to the second aspect of the present invention is a method of making a toothed belt comprising a belt body including a tooth part and a tooth bottom part alternately provided on one side surface thereof along the longitudinal direction, and a face fabric applied to cover said first surface of the belt body; The method comprising treating the face fabric with a treatment agent composition including a second epoxy resin, a second hardener for hardening the second epoxy resin and a rubber component, and superimposing a non-vulcanized rubber sheet on the face fabric. treated followed by vulcanization molding in order to obtain the toothed belt. Advantageous Effects of the Invention
[023] According to the first aspect of the present invention, the resistance of the face fabric to wear and oil is improved, since the surface of the face fabric is covered with the first epoxy resin. Therefore, the toothed belt has satisfactory durability even when used under conditions of high temperature and high load or in the presence of an oil environment.
[024] In addition, according to the second aspect of the present invention, water resistance, heat resistance, oil resistance, among other aspects of the belt are improved thanks to the modification of the treatment of the face fabric of the toothed belt. Therefore, the toothed belt has satisfactory durability, even when the belt is used under conditions of high temperature and high load or in an oil or water environment. Brief Description of Drawings
[025] Fig. 1 is a cross-sectional view of a toothed belt according to an embodiment of the first aspect of the present invention.
[026] Fig. 2 is a cross-sectional view illustrating a method of manufacturing a toothed belt according to the embodiment of the first aspect of the present invention.
[027] Fig. 3 is a cross-sectional view of a toothed belt according to an embodiment of the second aspect of the present invention.
[028] Fig. 4 is a cross-sectional view, illustrating a method of manufacturing a toothed belt according to the embodiment of the first second of the present invention.
[029] Fig. 5 is a graph illustrating the kinetic friction coefficients for the belts of Examples 1 and 2 and Comparative Example 1.
[030] Fig. 6 is a schematic diagram showing an arrangement in a drive test.
[031] Fig. 7 is a graph that illustrates the durability in units of time obtained from the drive test for the belts of Examples 1 and 2 and Comparative Example 1.
[032] Fig. 8 is a schematic diagram illustrating a ServoPulser test machine.
[033] Fig. 9 is a graph that illustrates the results of a ServoPulser test performed in Example 1 and Comparative Example 1.
[034] Fig. 10 is a graph that illustrates the stress-strain curves of the belts in Example 1 and Comparative Example 1.
[035] Fig. 11 is a graph that illustrates the results of a drive test carried out in Examples 3 and 4 and in Comparative Examples 2 and 3.
[036] Fig. 12 is a graph that illustrates the results of a drive test for water resistance carried out in Example 3 and Comparative Example 3.
[037] Fig. 13 is a graph illustrating the results of a drive test for oil resistance carried out in Example 3 and Comparative Examples 2 and 3.
[038] Fig. 14 is a graph that illustrates the results of an adhesion test in cases where an aliphatic epoxy resin has been used.
[039] Fig. 15 is a graph illustrating the results of an adhesion test in cases where a novolac-type epoxy resin has been used. List of Reference Numbers 10 timing belt 13 belt body 20 face fabric 21 outer surface Description of Achievements
[040] Hereinafter, an embodiment of the first aspect of the present invention is described with reference to the drawings. <Achievement>
[041] Fig. 1 shows a toothed belt of the embodiment of the first aspect of the present invention. The toothed belt 10 is formed with an endless shape, and is used, for example, being wrapped around the driving pulleys and moved (not shown) in an internal combustion engine or the like. The timing belt 10 is a synchronizing belt that transmits a torque (driving force) from a driving pulley to a pulley driven by synchronous force transmission.
[042] The toothed belt 10 includes a belt body 13 and a cord 14. The belt body 13 is formed of a rubber part of the tooth 11 provided on a surface side and a supporting rubber part 12 provided on the other side of the surface; the rubber part of the tooth 11 and the rubber part of support 12 are integrated with each other. The cord 14 is wrapped in a spiral shape and embedded in a border between the rubber part of the tooth 11 and the supporting rubber part 12, while extending in the longitudinal direction of the belt.
[043] In the rubber part of tooth 11, a tooth part 15 and a lower part of tooth 16 are alternately formed on the surface side of the belt body 13 along the longitudinal direction of the belt. The rubber part of tooth 11 includes a rubber part of core 17 and a rubber part of the surface of tooth 18. The rubber part of core 17, which occupies a large proportion of tooth part 15, is laminated to the part of support rubber 12, and is formed along the contour of tooth part 15. The rubber part of the surface of tooth 18 is thin and is laminated to the rubber part of core 17. A face fabric 20 covering the rubber part of tooth 11 is adhered to a surface of the rubber portion of the surface of tooth 18 (i.e., a surface of the belt body 13).
[044] A short fiber (not shown) made of a nylon fiber, an aramid fiber or the like is loaded on the rubber part of the core 17, while the short fiber is not loaded on the rubber part of the tooth surface 18 or in the support rubber part 12. For this reason, the modulus of the rubber part of the core 17 is larger than that of the rubber part of the tooth surface 18 and the support rubber part 12.
[045] A hydrogenated nitrile rubber (HNBR), a nitrile rubber (NBR), a chloroprene rubber (CR), an ethylene-propylene-diene rubber (EPDM), a fluorine rubber, a mixture thereof, or similar , is used as a rubber component of each of the support rubber part 12, the core rubber part 17 and the rubber part of the tooth surface 18, which make up the belt body 13. From the point of view of thermal resistance, durability, and others, HNBR is preferable. The same rubber component or different rubber components can be used for rubber parts 12, 17 and 18.
[046] In this embodiment, the face fabric 20 is subjected to treatment with RFL (resorcinol-formaldehyde-latex), and has an external surface facing the outside 211 (that is, the surface on the side that did not adhere to the body of belt 13) covered with a hardened material from a first epoxy resin.
[047] Although not particularly limited to this, the face fabric 20 is a textile fabric including first threads (for example, weft threads) extending along the longitudinal direction of the belt and second threads (for example, warp) extending along the width of the belt; the first wires and the second wires are intertwined. In face fabric 20, for example, the first threads are made up of elastic threads, and the second threads are made up of non-elastic threads. Thus, the face fabric 20 is elastic in the longitudinal direction of the belt.
[048] RFL treatment of face 20 fabric is carried out by impregnation treatment in which face 20 fabric is immersed in an RFL treatment liquid, and then heat dried. The RFL treatment liquid includes latex and a resorcinol-formaldehyde condensate, which are diluted, for example, with water or the like. As for latex, a latex from any of the rubber components described above is used, and preferably HNBR latex is used. In addition, the amount of adhesion (solid component) of the RFL applied to the face 20 fabric is about 40 to 80 g / m2.
[049] In this embodiment, the coating of the hardened material of the first epoxy resin is formed as follows. Specifically, a first epoxy resin solution obtained by diluting the first epoxy resin and a first hardener with a solvent or the like is coated on a surface of the face fabric 20 subjected to the RFL treatment. Then, the first epoxy resin is heat hardened during the vulcanization of the rubber, which is described later. The solvent included in the first epoxy resin solution coated on the face 20 fabric is preferably evaporated before vulcanization by natural drying or the like.
[050] Examples of the first epoxy resin include bisphenol A epoxy resin, bisphenol F epoxy resin, novolac type epoxy resin, biphenyl type epoxy resin, phenoxy type epoxy resin, long chain aliphatic epoxy resin, among others. One of these first epoxy resins alone or a combination of two or more of them can be used. In these epoxy resins, the bisphenol A epoxy resin or the novolac type epoxy resin is preferable as the first epoxy resin.
[051] The first epoxy resin is preferably of the so-called solid type with a melting point greater than the normal temperature (25oC). The use of a solid type results in good handling ability of the first epoxy resin solution, as the first unhardened epoxy resin solution coating the face fabric 20 tends to be less sticky after the solvent has evaporated. However, the melting point of the first epoxy resin is preferably lower than the heating temperature during vulcanization to be described later, as the first epoxy resin is difficult to harden if it is not melted.
[052] In addition, in order to obtain satisfactory thermal resistance of the hardened material of the first epoxy resin, the epoxy equivalent of the first epoxy resin according to JIS K 7236 is preferably relatively low, and, for example, preferably 100 at 1500 g / eq, and more preferably, from 150 to 1000 g / eq.
[053] The first epoxy resin is hardened by the first hardener. Examples of the first hardener include amine based hardener, acid anhydride based hardener, novolac phenol based hardener, imidazole based hardener, diciandiamide based hardener, among others. One of these first hardeners alone or a combination of two or more of them can be used.
[054] In these hardeners, the imidazole-based hardener, which is a catalytic hardener, is preferable as the first hardener. The imidazole-based hardener, which is a catalytic hardener, polymerizes the first epoxy resin by the direct catalytic reaction of the epoxy rings. Therefore, the hardness of the hardened material can be easily increased, and thus, the frictional coefficient of the outer surface 21 of the face fabric 20 can be reduced easily. In addition, the amount of imidazole-based hardener added may be small. This small amount results in good handling capacity of the first epoxy resin solution, as the first unhardened epoxy resin solution coating the face 20 fabric tends to be less sticky after the solvent has evaporated.
[055] Although not particularly limited, the hardened material of the first epoxy resin preferably has a relatively high softening point in order to obtain satisfactory wear resistance of the face fabric 20 maintaining a high hardness even at an elevated temperature, and, thus, providing a satisfactory friction coefficient to the tooth surface. Specifically, the softening point is preferably 110 ° C or higher. Note that the softening point is measured using a thermomechanical analyzer “TMA / SS120U” (manufactured by SII NanoTechnology Inc.), under the following conditions: measuring temperature range: 30oC to 350oC; load: 100 mN; and temperature rise: 5 ° C / minute.
[056] If the hardened material of the first epoxy resin is too thick, cracks or the like can occur, which can cause cracks in the tooth. For this reason, the amount of adhesion (solid component) of the first epoxy resin solution (i.e., the hardened material of the first epoxy resin) to the face fabric 20 is preferably relatively small, and is, for example, from about 10 to 50 g / m2. The adhesion amount is preferably less than 1/2 of the adhesion amount (solid component) of the RFL. In addition, the face fabric 20 is generally a textile fabric, and has an uneven surface due to the texture of the weave. The amount of adhesion is preferably such that the irregularity is left on the surface (the outer surface 21), even after the surface is covered with the hardened material. If the outer surface 21 covered with the hardened material of the first epoxy resin contains an irregularity that originated from the irregular texture of the weave, there is a high likelihood that noise generation will be prevented, especially when the belt is used in a state where the belt (the face fabric 20) is not in contact with the oil.
[057] Next, a method of manufacturing a toothed belt 10 of this embodiment is described based on Fig. 2. The face fabric 20, which is subjected to the RFL treatment and has a surface 21 '(the outer surface 21) coated with the first epoxy resin solution as described above, it is first preformed by a conventionally known method in a corrugated form with an alternating tooth part 23 and a tooth part 24.
[058] Subsequently, a rubber sheet of the tooth surface 18 'and a rubber sheet of the core 17' are adhered under pressure, in that order, to the other surface 22 'of the face fabric 20 having the corrugated shape. Thus, a face fabric provided with rubber 28 is obtained. At this point, the rubber blade of the tooth surface 18 'and the rubber blade of the core 17' are pressed against the face fabric 20. Therefore, the blade of rubber on the surface of tooth 18 'and the rubber blade of core 17' adhered under pressure are relatively thick on the tooth part 23 and relatively thin on the lower part of tooth 24.
[059] Next, the rubber-faced face fabric 28 is wrapped around a toothed mold 30. The toothed mold 30 has a cylindrical shape, and has an outer peripheral surface on which recessed parts 31 and raised parts 32 are alternately provided along the circumferential direction. Each tooth part 23 of the rubber-provided face fabric 28 is arranged within the corresponding recessed part 31. Note that, in general, each tooth part 23 of the rubber-provided face fabric 28 has a shape that does not exactly fit the recessed part 31, so that there is a space between the tooth part 23 and the recessed part 31.
[060] Subsequently, the cord 14 is wrapped in a spiral around the rubber sheet of the core 17 ', and a supporting rubber sheet 12' is additionally wrapped around the cord 14. Then, the toothed mold 30 is housed in a vulcanization chamber (not shown). Note that the support rubber sheet 12 ', the core rubber sheet 17', and the tooth surface rubber sheet 18 'are non-vulcanized rubber sheets to be converted into the support rubber part 12 in the the rubber part of the core 17 and the rubber part of the tooth surface 18, respectively, after vulcanization and molding.
[061] In the vulcanization chamber, the face fabric provided with preformed rubber 28, and the like, which are wrapped around the toothed mold 30 are heated with steam, for example, and are pressurized from the outside to the inside with a vulcanization bag or the like provided in the vulcanization chamber. As a result of pressurization and heating, the spaces within the recessed parts 31 are completely eliminated, and the face fabric 20, the rubber sheets 12, 17 'and 18' and the cord 14 are integrated with each other by vulcanizing the sheets rubber 12 ', 17' and 18 ', and the like. Thus, a belt plate is obtained. In addition, as a result of this heating, the first epoxy resin coated on the surface 21 'of the face fabric 20 is hardened by the first hardener, and a coating of a hardened material from the first epoxy resin is formed. The belt plate is removed from the toothed mold 30, subjected to grinding or the like, as appropriate, and then cut into a piece with a predetermined width. Thus, a toothed belt 10 (see Fig. 1) is formed.
[062] As described above, in the embodiment of the first aspect of the present invention, the outer surface 21 of the face fabric 20 is covered with the hardened material of the first epoxy resin. Therefore, the outer surface 21 has a favorable friction coefficient even under high temperature conditions, and the resistance of the face fabric 20 to wear in a high temperature environment can be improved. Furthermore, the coating of the conato fabric 20 with the hardened material of the first epoxy resin improves the resistance of the face fabric 20 and reduces the internal heat generation due to the deformation of the tooth part 15. Therefore, it is possible to obtain a satisfactory belt life, and in particular, a satisfactory belt life under high load and high temperature conditions.
[063] Furthermore, since the outer surface 21 is covered with the hardened material of the first epoxy resin, the belt's resistance to oil is also improved, so that a satisfactory service life of the belt 10 can also be obtained when belt 10 is used in applications involving the presence of oil. Furthermore, since the hardened material of the first epoxy resin is not applied to the surface side facing the interior of the face fabric 20 to be adhered to the belt body 13, the adhesion between the belt body 13 and the fabric face 20 is not affected by the hardened material of the first epoxy resin.
[064] Note that, in this embodiment, the face fabric 20 may be subjected to the rubber adhesive impregnation treatment instead of the RFL treatment. However, face fabric 20 is preferably subjected to treatment with RFL, in consideration of adhesion with the first epoxy resin.
[065] In addition, the first epoxy resin solution is coated on the conato fabric 20 before the face fabric 20 is preformed in a corrugated form. As an alternative, the first epoxy resin solution can be coated after preforming (for example, the rubber sheets are adhered under pressure to the face fabric).
[066] Furthermore, the structure of the toothed belt is not limited to that of Fig. 1. For example, the rubber part of the tooth surface 18 can be eliminated, or an adhesive or similar rubber part in which the cord 14 it is embedded can be provided between the rubber part of the core 17 and the rubber part of support 12. Furthermore, the face fabric 20 does not necessarily need to be preformed. However, after the face fabric 20 is preformed, the elongated portion of the face fabric is reduced during vulcanization and molding. Therefore, the hardened material of the first epoxy resin can be applied evenly to the face fabric 20 more easily. <Implementation of the Second Aspect of the Invention>
[067] In the following, a toothed belt of an embodiment of the second aspect of the present invention is described based on Figs. 3 and 4.
[068] The same parts as in the embodiment of the first aspect of the present invention are indicated by the same reference numbers.
[069] Fig. 3 shows a toothed belt of the embodiment of the second aspect of the present invention. The toothed belt 10 is formed with an endless shape, and is used, for example, being wrapped around the driving pulleys and moved (not shown) in an internal combustion engine or the like. The toothed belt 10 is a synchronizing belt that transmits torque (driving force) from a driving pulley to a pulley driven by synchronous force transmission.
[070] The toothed belt 10 includes a belt body 13 and a cord 14. The belt body 13 is formed of a rubber portion of the tooth 11 provided on one surface side and a support rubber 12 provided on the other side of surface; the rubber part of the tooth 11 and the support rubber 12 are integrated with each other. The cord 14 is wrapped in a spiral shape and embedded in a border between the rubber part of the tooth 11 and the support rubber 12, while extending in the longitudinal direction of the belt.
[071] In the rubber part of tooth 11, a tooth part 15 and a lower part of tooth 16 are alternately formed on the surface side of the belt body 13 along the longitudinal direction of the belt. The rubber part of tooth 11 includes a rubber part of core 17 and a rubber part of the surface of tooth 18. The rubber part of core 17, which occupies a large proportion of tooth part 15, is laminated to the rubber of support 12 and has a shape that corresponds to the shape of the tooth part 15. The rubber part of the tooth surface 18, which is thin, is laminated on the rubber part of the core 17 and arranged on a surface of the rubber part of the tooth 11. A face fabric 20 covering the rubber part of tooth 11 is adhered to a surface of the rubber part of the surface of tooth 18 (i.e., a surface of the belt body 13).
[072] A short fiber 25, which is made of a nylon fiber, a modified nylon fiber obtained by modifying nylon, an aramid fiber, or the like, and which has a fiber length of about 0.5 to 10.0 mm, is loaded on the rubber part of the core 17; the short fiber is not loaded on the rubber part of the surface of tooth 18 or on the support rubber 12. For this reason, the modulus of the rubber part of the core 17 is larger than that of the rubber part of the surface of tooth 18 and support rubber 12. Note that a short aramid fiber is preferably loaded on the rubber part of the core 17 to further improve the strength of the rubber part of tooth 11.
[073] In the rubber part of the core 17, the short fiber 25 is oriented substantially in the direction of thickness of the belt in a central region of the tooth part 15. As the short fiber 25 approaches the surface of the tooth a From the center region, the short fiber 25 is oriented with an inclination from the direction of the thickness so as to extend along the surface of the tooth. The short fiber 25 is oriented substantially along the longitudinal direction of the belt close to an upper part of the tooth part 15 and close to the lower part of tooth 16.
[074] The rubber part of the surface of tooth 18 is obtained by vulcanizing and molding a rubber composition including rubber and various additives. The rubber composition includes hydrogenated nitrile rubber (HNBR) as the main component of rubber, and can include other rubber components, such as hydrogenated carboxylic nitrile rubber (HXNBR) and nitrile rubber (NBR).
[075] The rubber composition used to mold the rubber portion of the tooth 18 surface may include an unsaturated α carboxylate, metallic e-ethylene as the matrix in addition to the rubbers described above. The unsaturated α, e-ethylenic metal carboxylate is included, for example, in an amount of about 0.2 to 0.4 with respect to the matrix (the total weight of the rubber and α, β-ethylenic metal unsaturated carboxylate).
[076] α, e-ethylenic unsaturated carboxylate is formed by ionic bonding of α, e-ethylenic unsaturated carboxylic acid with a metal. For example, a monocarboxylic acid, such as acrylic acid or methacrylic acid, or a dicarboxylic acid, such as maleic acid, fumaric acid, itaconic acid or citraconic acid, is used as the unsaturated α, e-ethylenic carboxylic acid. Preferably, methacrylic acid is used. For example, zinc, magnesium, calcium, barium, titanium, chromium, iron, cobalt, nickel, aluminum, tin, lead or the like is used as the metal, and zinc is preferably used. Thus, for example, zinc dimethylacrylate is used as the metal salt.
[077] The rubber composition used to mold the rubber portion of the tooth surface 18 preferably additionally includes resorcinol and a melamine compound as internal adhesive agents. In this embodiment, these compounds are incorporated into the rubber portion of the tooth 18 surface. Therefore, from heating during vulcanization, or the like, the melamine and resorcinol compound are polymerized and a mesh structure is constructed. As a result, the resistance to breakage, among other attributes, of the surface of the rubber part of tooth 11, is improved. Furthermore, this improves the adhesion resistance of the rubber part of the tooth surface 18 to the face tissue 20, which has been subjected to the impregnation treatment with an epoxy-rubber treatment agent composition to be described later.
[078] The melamine compound is, for example, a melamine compound of which at least part of the amino groups is methoxylated. Specific examples of the melamine compound used include hexamethoxymethylolmelamine compounds, such as hexamethoxymethylolmelamine, condensed partial oligomers thereof, and mixtures thereof. The melamine compound preferably has a viscosity at 25oC (according to DIN19268) of about 3000 to 8000 mPa-s.
[079] Resorcinol is incorporated in an amount of 0.3 to 8 parts by weight, preferably 0.5 to 4.5 parts by weight, and more preferably 1.5 to 3.0 parts by weight, in relation to 100 parts by weight of the rubber composition matrix. In addition, the incorporated parts (weight) of the melamine compound are preferably smaller than those of resorcinol, and the melamine compound is incorporated in an amount of 0.2 to 5 parts by weight, preferably 0.3 to 2, 7 parts by weight, and more preferably 0.9 to 1.8 parts by weight, relative to 100 parts by weight of the rubber composition matrix. If the incorporated amount of any of the melamine and resorcinol compound exceeds the range described above, the resistance to laceration, resistance to rupture, among other attributes, tend to be unsatisfactory. On the other hand, if the incorporated amount is less than the range described above, the adhesion resistance is difficult to improve.
[080] The rubber composition used to mold the rubber portion of the tooth surface 18 preferably includes silica. Like silica, silica is used in the form of fine particles, powder or the like.
[081] In this embodiment, the water contained in the silica causes the melamine compound to formalize, resorcinol is polymerized with formaldehyde, and the melamine compound is also polymerized. As a result, satisfactory adhesive strength and tear strength are achieved, among other attributes, as described above. The silica is in an amount of 5 to 50 parts by weight, and preferably 20 to 40 parts by weight, relative to 100 parts by weight of the rubber composition matrix.
[082] The rubber composition used to form the rubber portion of the tooth 18 surface additionally includes known additives for rubber, such as a vulcanizing agent, a plasticizer, a lubricant and carbon black. In this embodiment, an organic peroxide-based vulcanizing agent is preferably used as the vulcanizing agent.
[083] The rubber composition used to mold the rubber part of the tooth 18 surface is prepared as follows. First, additives, such as silica for the rubber composition other than the vulcanizing agent, and the internal adhesive agents (resorcinol and the melamine compound) are mixed with the rubber, preferably at a temperature higher than the temperature in the primary mass described below. Subsequently, the internal adhesive agents are added and the mixture is further kneaded (primary mass). In this primary mass, the kneading temperature is preferably 100oC or higher. This kneading at this temperature results in the release of water from the silica into the composition, and facilitates the formaldehyde donation of the melamine compound in the manner described above. In addition, the vulcanizing agent is added to the kneaded primary mixture, and the resulting mixture is kneaded at a temperature less than the vulcanizing temperature of the vulcanizing agent (less than the kneading temperature in the primary dough). Thus, the rubber composition is obtained (secondary mass). The rubber composition is formed into a sheet, and used as the rubber sheet of the 18 'tooth surface (see Fig. 4). However, the rubber kneading method is not limited to this method, and, for example, additives other than the vulcanizing agent can be added, as appropriate, to the primary or secondary mass.
[084] The rubber part of the core 17 is formed of a rubber composition that does not include the resorcinol or melamine compound described above, but carries the short fiber 25. The other components of the rubber part of the core 17 can be the same as of the rubber part of the surface of tooth 18. Furthermore, the rubber component of the rubber part of core 17 is preferably made mainly of JNBR, as in the case of the rubber part of the surface of tooth 18. However, as of As usual, the rubber component of the rubber part of core 17 may include other rubber components, such as HXNBR and NBR.
[085] As for the support rubber 12, the rubber used for the support rubber of a conventionally known toothed belt can be used, and the support rubber 12 preferably does not carry the short fiber. In addition, the rubber used as the support rubber 12 is preferably made mainly of HNBR, as in the case of the rubber part of tooth 11, and can include other rubber components, if necessary.
[086] Although not particularly limited to this, the face fabric 20 is, for example, a textile fabric including first threads (for example, weft threads) extending along the longitudinal direction of the belt and second threads (for example, warp yarns) extending along the width of the belt; the first wires and the second wires are intertwined. In face fabric 20, for example, the first threads are made up of elastic threads, and the second threads are made up of non-elastic threads. Thus, the face fabric 20 is elastic in the longitudinal direction of the belt, and is more easily formed in a corrugated form in the preform. In this embodiment, at least part of the fiber that constitutes the face fabric 20 is preferably an aramid fiber to enhance the strength of the belt surface, and, for example, at least some of the first yarns are preferably an aramid fiber.
[087] The face fabric 20 is subjected to the impregnation treatment with a treatment liquid obtained by diluting an epoxy rubber treatment agent composition with a dilution liquid (a solvent); the epoxy-rubber treatment agent composition includes a second epoxy resin (prepolymer), a second hardener for hardening the second epoxy resin, and a rubber component. The rubber component included in the treatment agent composition is preferably latex. The solvent used to dilute the treatment agent composition is preferably water. However, the dilution solvent can be an organic solvent, such as toluene, MEK (methyl ethyl ketone), or the like, and the treatment liquid can be a liquid obtained by diluting the epoxy-rubber treatment agent composition with an organic solvent, wherein the epoxy-rubber treatment agent composition includes a non-vulcanized rubber polymer, the second epoxy resin and the second hardener. In addition, the epoxy rubber treatment agent composition can include a vulcanizing agent to vulcanize the rubber component included in the composition. When the face tissue is subjected to the impregnation treatment with the treatment liquid including the vulcanizing agent, the rubber component is vulcanized with the vulcanizing agent by heating during the vulcanization of the rubber, which is described later. As a result, the resistance to oil swelling and the thermal resistance of the face tissue are further improved.
[088] The impregnation treatment is carried out, for example, by immersing the textile fabric in the treatment liquid, and then drying the face fabric by heat to evaporate the solvent, such as water. Heating is preferably carried out at a relatively high temperature in a short period in order to gasify the solvent while limiting, as much as possible, the hardening of the second epoxy resin during heat drying. For example, the heating here is carried out at a temperature higher than the heating temperature in the vulcanization to be described later. The second epoxy resin adhered to the face fabric 20 is a thermosetting epoxy resin that is hardened with the hardener by heating during the vulcanization of the rubber, to be described later. Thus, a coating of the hardened material of the second epoxy resin and the rubber component, such as latex, is formed on a surface of the face fabric 20.
[089] Examples of the second epoxy resin included in the epoxy rubber treatment agent composition include bisphenol A epoxy resin, bisphenol F epoxy resin, novolac epoxy resin, biphenyl epoxy resin, phenoxy epoxy resin, aliphatic epoxy resin , among others. One of these second epoxy resins alone or a combination of two or more of them can be used. Note that the second epoxy resin preferably has a number average molecular weight of 300 or more. Here, the average molecular weight in number is a value measured with a gel permeation chromatograph (GPC) and converted to that of polystyrene.
[090] When the solvent for diluting the epoxy-rubber treatment agent composition is water, the second epoxy resin is preferably water-soluble. In this case, the second epoxy resin dissolves in the treatment liquid, so that a favorable handling capacity of the treatment liquid is obtained, which facilitates the formation of a uniform coating. For example, in the second epoxy resins listed above as examples, the aliphatic epoxy resin is generally water-soluble, and generally dissolves in a treatment liquid that includes water as the solvent.
[091] Meanwhile, the aliphatic epoxy resin makes it easier to obtain an appropriate hardness of the hardened material coating, and therefore makes it possible to improve the durability of the belt while improving the adhesion with the tooth rubber. Examples of the aliphatic epoxy resin include polyglycerin-based aliphatic epoxy resins, such as polyglycerol polyglycidyl ethers. Furthermore, the second epoxy resin preferably has three or more functional groups (epoxy groups), so that a mesh structure can be built by hardening with the second hardener.
[092] The weight ratio (weight ratio of the solid component) of the second epoxy resin to the rubber component in the epoxy-rubber treatment agent composition is, for example, from 9: 1 to 1: 9, and preferably 7: 3 to 3: 7 in terms of the second component epoxy-rubber resin. Furthermore, for example, when the second epoxy resin is of the aliphatic type described above, the incorporated weight of the second epoxy resin is preferably not less than the incorporated weight of the rubber component in order to obtain an appropriate hardness of the face fabric 20 and satisfactory adhesion performance. On the other hand, when the second epoxy resin is of the aromatic type, such as the novolac type, the face fabric 20 tends to be rigid with a small amount of the second epoxy resin. Therefore, in order to obtain an appropriate coating hardness and satisfactory adhesion performance of the meso, the incorporated weight of the second epoxy resin is preferably no greater than the incorporated weight of the rubber component.
[093] The second hardener, included in the epoxy rubber treatment agent composition, can be any one, as long as the second epoxy resin can be hardened. For example, an imidazole hardener, which is a catalytic hardener, is preferably used. A catalytic hardener polymerizes the second epoxy resin by direct catalytic reaction of the epoxy rings. In addition, the second hardener is preferably soluble in water, and dissolved in the treatment liquid as in the case of the second epoxy resin.
[094] In addition, although the rubber component included in the epoxy-rubber treatment agent composition is not particularly limited, NBR, HNBR or HXNBR is preferably used as the rubber component in order to improve adhesion with the part of Tooth 18 surface rubber composed of HNBR. In other words, NBR latex, HNBR latex or HXNBR latex are preferably used.
[095] Furthermore, although the vulcanizing agent for vulcanizing the rubber component included in the epoxy-rubber treatment agent composition is not particularly limited, an amine-based vulcanizing agent, a peroxide or vulcanizing agent a sulfur-based vulcanizing agent is preferably used as the vulcanizing agent to improve the resistance to oil swelling and the thermal resistance of the face tissue.
[096] In addition, the amount of adhesion (solid component) of the epoxy rubber treatment agent to the face 20 fabric is, for example, from 5 to 200 g / m2, and preferably from 20 to 100 g / m2. An adhesion amount of less than 5 g / m2 produces unsatisfactory results in terms of improving the performance of the belt with respect to water resistance, thermal resistance and oil resistance. An amount of adhesion that exceeds 200 g / m2 results in excessive stiffness of the face fabric which leads to the formation of cracks in the fabric and deterioration in the bending performance of the cord.
[097] Next, a method of fabricating a toothed belt 10 of this embodiment is described based on Fig. 4. The face fabric 20 subjected to the impregnation treatment with the epoxy rubber treatment agent composition as described above it is first preformed by a method conventionally known in a corrugated form containing an alternating tooth part 23 and an alternate tooth part 24.
[098] Subsequently, a rubber sheet of the tooth surface 18 'and a rubber sheet of the core 17' are adhered under pressure, in that order, to the first surface 22 'of the face fabric 20 having the corrugated shape. Thus, a face fabric provided with rubber 28 is obtained. At this point, the rubber blade of the tooth surface 18 'and the rubber blade of the core 17' are pressed against the face fabric 20. Consequently, the blade rubber of the surface of tooth 18 'and the rubber blade of core 17' adhered under pressure are relatively thick on the part of tooth 23 and relatively thin on the bottom of tooth 24. Note that the short fiber 25 loaded on the rubber blade of the tooth core 17 ', which has been incorporated along the longitudinal direction, is inclined as appropriate during adhesion under pressure, as is apparent in Fig. 2, and is oriented in substantially the same way as the short fiber in the toothed belt 10.
[099] Next, the rubber-faced face fabric 28 is wrapped around a toothed mold 30. The toothed mold 30 has a cylindrical shape with an outer peripheral surface on which recessed parts 31 and raised parts 32 are alternately provided to the along the circumferential direction. Each tooth part 23 of the rubber-provided face fabric 28 is arranged within the corresponding recessed part 31. Note that, in general, each tooth part 23 of the rubber-provided face fabric 28 has a shape that does not exactly fit the recessed part 31, so that there is a space between the tooth part 23 and the recessed part 31.
[0100] Subsequently, the cord 14 is wrapped in a spiral around the rubber sheet of the core 17 ', and a supporting rubber sheet 12' is additionally wrapped around the cord 14. Then, the toothed mold 30 is housed in a vulcanization chamber (not shown). Note that the support rubber sheet 12 ', the core rubber sheet 17', and the tooth surface rubber sheet 18 'are non-vulcanized rubber sheets to be converted into the support rubber 12, on the core rubber 17 and the rubber part of the tooth surface 18, respectively, after vulcanization and molding.
[0101] In the vulcanization chamber, the face fabric provided with rubber 28, and the like, which are wrapped around the toothed mold 30 is heated with steam, for example, and pressurized from the outside to the inside with a vulcanization bag or similar provided in the vulcanization chamber. As a result of pressurization and heating, the spaces within the recessed parts 31 are completely eliminated, and the face fabric 20, the rubber sheets 12, 17 'and 18' and the cord 14 are integrated into each other by vulcanizing the sheets rubber 12 ', 17' and 18 ', and the like. Thus, a belt plate is obtained. In addition, as a result of this heating, the second epoxy resin (prepolymer) in the epoxy-rubber treatment agent composition adhered to the face fabric 20 is hardened by the second hardener, and the rubber component therein is preferably vulcanized by vulcanizing agent in the composition. Thus, the face fabric 20 is coated with the hardened material of the second epoxy resin and the vulcanized rubber component. The belt plate is removed from the toothed mold 30, subjected as appropriate to grinding or the like, and then cut into a piece with a predetermined width. Thus, a toothed belt 10 (see Fig. 3) is obtained.
[0102] As described above, in the embodiment of the second aspect of the present invention, the face fabric 20 is covered with the second component epoxy-rubber resin, so the water resistance, the thermal resistance, the oil resistance and the resistance wear of the face fabric are improved. Therefore, the toothed belt has satisfactory durability, even when used under conditions of high temperature and high load or in a water or oil environment. In addition, predetermined internal adhesive agents are incorporated into the rubber part of the tooth surface 18 to which the face fabric 20 is adhered. Therefore, the adhesion resistance of the rubber part of tooth 11 to the face fabric 20 coated with the second epoxy-rubber resin component is further improved, and the durability of the belt can be further improved.
[0103] Note that, in this embodiment, the outer surface 21 of the face fabric 20, that is, the surface opposite the surface adhered to the rubber part of the tooth surface 18, can be additionally coated with a hardened material of a third epoxy resin as illustrated below.
[0104] The coating of the hardened material of the third epoxy resin is formed as follows. Specifically, a third epoxy resin liquid obtained by diluting the third epoxy resin (prepolymer) and a third hardener with a solvent or similar is coated on the outer surface of the face fabric 20. Then, the third epoxy resin is hardened by heat from the vulcanization molding process described above. The solvent included in the third epoxy resin liquid coated on the face fabric 20 is preferably evaporated before vulcanization by natural drying or the like. Note that the third epoxy resin liquid is coated on the face fabric that has already been treated by impregnation with the epoxy-rubber treatment agent composition described above.
[0105] Examples of the third epoxy resin include bisphenol A epoxy resin, bisphenol F epoxy resin, novolac epoxy resin, biphenyl epoxy resin, phenoxy epoxy resin, aliphatic epoxy resin, among others. One of these third epoxy resins alone or a combination of two or more of them can be used. In these epoxy resins, the bisphenol A epoxy resin or the novolac type epoxy resin is preferable as the third epoxy resin.
[0106] The third epoxy resin (prepolymer), preferably, of the so-called solid type with a melting point higher than the normal temperature (25oC). The use of a solid type results in good handling ability of the third epoxy resin liquid, as the third epoxy resin liquid coated on the face material 20 which has not yet hardened tends to be less sticky once the solvent has evaporated. However, the melting point of the third epoxy resin is preferably lower than the heating temperature during vulcanization, as the third epoxy resin is difficult to harden when not melted.
[0107] In addition, to obtain satisfactory thermal resistance of the hardened material of the third epoxy resin, the epoxy equivalent of the third epoxy resin according to JIS K 7236 is preferably from 100 to 7,000 g / eq, and more preferably, from 150 to 5,000 g / eq.
[0108] The third epoxy resin is hardened by a third hardener.
[0109] Examples of the third hardener include amine based hardener, acid anhydride based hardener, novolac phenol based hardener, imidazole based hardener, diciandiamide based hardener, among others. One of these third hardeners, or a combination of two or more of the same, can be used.
[0110] In these hardeners, the imidazole-based hardener, which is a catalytic hardener, is preferable as the third hardener. The imidazole-based hardener, which is a catalytic hardener, polymerizes the epoxy resin by the direct catalytic reaction of the epoxy rings. Therefore, the hardness of the hardened material can be easily increased, and thus, the frictional coefficient of the outer surface 21 of the face fabric 20 can be reduced easily. In addition, the amount of imidazole-based hardener added may be small. This small amount results in good handling ability of the third epoxy resin liquid, as the third epoxy resin liquid coated on the face material 20 which has not yet hardened tends to be less sticky once the solvent has evaporated.
[0111] Although not particularly limited, the hardened material of the third epoxy resin preferably has a relatively high softening point, in order to obtain satisfactory wear resistance of the face fabric 20 maintaining a high hardness even at an elevated temperature, and , thus, providing a satisfactory friction coefficient to the tooth surface. Specifically, the softening point is preferably 110 ° C or higher. Note that the softening point is measured using a thermomechanical analyzer “TMA / SS120U” (manufactured by SII NanoTechnology Inc.), under the following conditions: measuring temperature range: 30oC to 350oC; load: 100 mN; and temperature rise: 5 ° C / minute.
[0112] If the hardened material of the third epoxy resin is too thick, cracks or the like can occur, which can cause cracks in the tooth. For this reason, the amount of adhesion (solid component) of the third epoxy resin liquid (i.e., the hardened material of the third epoxy resin) to the face fabric 20 is preferably relatively small, and is, for example, from about 10 to 50 g / m2. In addition, the face fabric 20 is generally a textile fabric, and has an uneven surface due to the texture of the weave. The amount of adhesion is preferably such that an irregularity is left on the surface (the outer surface 21), even after the surface is covered with the hardened material. If the outer surface 21 covered with the hardened material of the third epoxy resin contains an irregularity that originated from the irregular texture of the weave, there is a high probability that the noise generated during the operation can be prevented, especially when the belt is used in a state in which the belt (the face fabric 20) is not in contact with the oil.
[0113] As described above, the outer surface 21 of the face fabric 20 is covered with the hardened material of the third epoxy resin in this embodiment. In this case, the outer surface 21 has a favorable friction coefficient even under high temperature conditions, and the resistance of the face fabric 20 to wear in a high temperature environment can be improved. Furthermore, the coating of the hardened material of the third epoxy resin improves the resistance of the face fabric 20 and reduces the internal heat generated by the deformation of the tooth part 15. Therefore, it is possible to further improve the durability of the belt, particularly in a high temperature and high load environment.
[0114] Furthermore, since the outer surface 21 is covered with the hardened material of the third epoxy resin, the belt's resistance to oil is also improved, so that the durability of the belt 10 can be further improved when the belt 10 is operated in the presence of oil. Furthermore, since the hardened material of the third epoxy resin is not applied to the inner surface side of the face fabric 20 to be adhered to the belt body 13, the adhesion between the belt body 13 and the face fabric 20 it is not reduced by the hardened material of the third epoxy resin. On the other hand, the third epoxy resin liquid is applied to the face fabric 20 subjected to the impregnation treatment with the epoxy-rubber treatment agent composition. Therefore, the adhesion of the coating of the hardened material of the third epoxy resin to the face fabric 20 tends to be satisfactory.
[0115] Furthermore, the toothed belt structure 10 in this embodiment is not limited to that of Fig. 3. For example, a short fiber can also be loaded onto the rubber part of the tooth surface 18, or the short fiber does not necessarily need be loaded onto the rubber part of the core 17.
[0116] Furthermore, the rubber part of the surface of the tooth 18 can be eliminated, and the rubber of the tooth can be formed only of the rubber part of the core 17. In this case, however, it is preferable that the internal adhesive agents described above (resorcinol and the melamine compound) are incorporated into the rubber part of core 17. As usual, the two internal adhesive agents described above do not necessarily need to be incorporated into the rubber part of the tooth surface 18 or the rubber part of core 17 adhered to the face tissue.
[0117] Furthermore, an adhesive rubber part or the like in which the cord 14 is embedded can be provided between the rubber part of the core 17 and the support rubber 12. Furthermore, the face fabric 20 does not necessarily need be preformed.
[0118] Note that, in the embodiment described above, the rubber constituting each of the rubber part of the core 17, the rubber part of the tooth surface 18 and the supporting rubber 12 may include rubber components, such as EPDM ( ethylene-propylene-diene copolymer), in addition to the HNBR, NBR and HXNBR described above, or may include a rubber component other than HNBR as the main component. EXAMPLES
[0119] Hereinafter, specific examples of the first and second aspects of the present invention are described below. However, the first and second aspects of the present invention are not limited to the examples illustrated below.
[0120] First, examples of the embodiment of the first aspect of the present invention are illustrated. [Example 1]
[0121] First, a textile fabric in which the warp yarns and weft yarns are interwoven into a 2/2 twill was prepared as the face fabric. The warp yarns were non-elastic yarns composed of 110-dtex nylon filament yarns. The weft yarns were elastic yarns composed of composite yarns in which intermediate yarns made of 220-dtex para-aramid fiber yarns (product name: Technora) were wrapped around core yarns made of elastic urethane yarns. 470-dtex, and cover yarns made of 110-dtex nylon fiber were additionally wrapped in the intermediate yarns. In a step described later, the warp yarns were extended along the belt width direction, and the weft yarns were extended along the longitudinal direction of the belt.
[0122] The RFL treatment was carried out by immersing the face tissue in an RFL treatment liquid (RF / latex (weight ratio) = 1/6, latex component: HNBR latex), and then drying the face tissue ( at a temperature of 160 ° C for 5 minutes). The amount of adhesion (solid component) of RFL to the face tissue was 80 g / m2.
[0123] Next, an epoxy resin liquid was prepared by adding 3 parts by weight of an imidazole-based hardener to 100 parts by weight of a novolac-type epoxy resin (epoxy equivalent: 210 g / eq) which were diluted with 500 parts by weight of MEK (methyl ethyl ketone). The epoxy resin liquid was applied by air spray coating on a surface of the face fabric subjected to the RFL treatment, so that an adhesion amount (solid component) of 20 g / m2 was achieved. Then, the face tissue was left to rest at normal temperature (25oC) so that the MEK could evaporate.
[0124] Subsequently, sheets of non-vulcanized rubber formed from HNBR that did not carry a short fiber were prepared as the rubber sheet of the tooth surface and the rubber sheet of support. In addition, a non-vulcanized rubber made of HNBR carrying 4 parts by weight of a short aramid fiber in relation to 100 parts by weight of the rubber component was prepared as the core rubber sheet. Then, the face tissue was preformed into a corrugated form, and the rubber sheet of the tooth surface and the rubber sheet of the core were adhered under pressure, in that order, to the other surface of the face tissue, which is the surface without the liquid epoxy resin coating. Thus, a preformed face fabric provided with rubber was obtained.
[0125] Next, the preformed face fabric provided with rubber, a cord made of a glass cord and the supporting rubber blade were wrapped around a toothed mold. Then, these materials were molded by vulcanization in a vulcanization chamber at a temperature of 150o under a predetermined pressure for 20 minutes. Thus, a RU toothed belt plate was obtained. In example 1, the hardened epoxy resin material covering the first surface (the outer surface) of the face fabric had a softening point of 150oC. [Example 2]
[0126] Example 2 was conducted in the same manner as Example 1, except that the epoxy resin liquid used was an epoxy resin liquid obtained by adding 3 parts by weight of an imidazole hardener to 100 parts of weight of a bisphenol A epoxy resin (epoxy equivalent: 900 g / eq) which was diluted with 500 parts by weight of a MEK solvent. In example 2, the hardened epoxy resin material covering the first surface (the outer surface) of the face fabric had a softening point of 100oC. [Comparative Example 1]
[0127] Comparative Example 1 was performed in the same way as Example 1, except that an epoxy resin liquid was not coated on the face fabric. [Frictional Coefficient of the Belt Tooth Surface]
[0128] A part corresponding to a single tooth was cut from the belt having a width of 19 mm in each of Examples 1 and 2 and Comparative Example 1. The single tooth part was arranged in a stainless steel friction material of such that the upper part of the tooth was in contact with the friction material. Then, the kinetic friction coefficient was measured by moving the friction material 30 mm in the longitudinal direction of the belt at a speed of 10 mm / second with a load of 500 g being applied to the single tooth part of the belt. The kinetic friction coefficient was measured with a friction coefficient measuring device [type HEIDON: 14FW (manufactured by Shinto Scientific Co., Ltd.)] at an ambient temperature of 25 ° C (normal state) at an ambient temperature of 25 ° C ° C (normal state) and an ambient temperature of 120 ° C (warm state). Fig. 5 shows the measurement results. [Trigger Test]
[0129] Fig. 6 is an example of a transmission system arrangement used in an internal combustion engine. Toothed belts with a width of 16 mm obtained from the belt plates of Examples 1 and 2 and Comparative Example 1 were subjected to a durability test using this transmission system. The transmission system 40 contained a toothed driving pulley 41 which was connected to a crankshaft and which had 20 teeth and a diameter of 600 mm, toothed driven pulleys 42 and 43 which were connected to axles, and each of which it had 40 teeth and a diameter of 121 mm, and a flat tensioning pulley 44 with a diameter of 80 mm. The toothed belt 10 was wrapped around the pulleys 41 to 43. In a state where tension was applied to the toothed belt 10 from the outer peripheral side by the tensioner pulley 44 on the slack side of the belt, the toothed belt 10 was operated at 4000 rpm under a load per single tooth of 8.4 N / mm. The test was carried out at an ambient temperature of 120oC, and the operating time elapsed until the belt failed was measured as the durability time. Fig. 7 shows the measurement results. [Test using ServoPulser]
[0130] Example 1 and Comparative Example 1 were also evaluated for durability based on a test using a ServoPulser. The test was performed with the ServoPulser 74 test machine illustrated in Fig. The ServoPulser 74 testing machine included a metal fixture 75 having an irregular shape corresponding to the tooth shape of the toothed belt, and a claw 77. For the evaluation test, a toothed belt containing 10 teeth and a width of 20 mm was obtained of each of the belt plates to be used as a test piece 76. Test piece 76 was arranged to extend in the vertical direction. An upper end of the test piece 76 was fixed in place and a single tooth 76a at the lower end of the test piece 76 was engaged with the corresponding shape of the metal fixture 75. Then, the metal fixture 75 and the lower end of the fixture test 76 were interposed together and fixed with claw 7 on the left and right side.
[0131] A sine wave load periodically varying from 0 to a predetermined load was applied in a downward direction until claw 77 interposing the metal fixture 75 and the test piece 76. The frequency of the sine wave was 1 Hz. In this test , which was carried out at an ambient temperature of 120oC, the number of cycles of the sine wave was counted until the rupture of the single tooth 76a. Fig. 9 shows the test results, in which the horizontal axis represents the number of cycles of the load applied before the rupture of the single tooth 76a and the breaking time, and the vertical axis represents predetermined loads. [Loss of Hysteresis]
[0132] As for Example 1 and Comparative Example 1, a sine wave load periodically varying from 0 to 13 N / mm was applied at an ambient temperature of 120oC for 1 hour (3600 cycles), in the same way as in the test using the ServoPulser. Then, the stress and strain in a single cycle were measured. Fig. 10 shows stress-strain curves illustrating the loss of hysteresis in this measurement.
[0133] As is apparent from the results described above, the friction coefficient of Comparative Example 1 was a relatively low and satisfactory value at normal temperature. However, the coefficient of friction increased under the high temperature condition, and was not maintained at a satisfactory value. In contrast, it is conceivable that the wear resistance of each of Examples 1 and 2 was improved compared to that of Comparative Example 1 because the friction coefficient of each of Examples 1 and 2 was relatively low, not only at normal temperature , but also under the condition of high temperature. In addition, the hysteresis loss of Example 1 in the high temperature environment was less than that of Comparative Example 1, and it can be understood that the generation of heat, and similar effects, due to tooth deformation, were reduced. Furthermore, it is apparent from the test results using the ServoPulser and the durability test, that the belts in each of Examples 1 and 2 had high durability in the high temperature and high load environment. [Blade Immersion Test]
[0134] A sheet of material hardened from the epoxy resin liquid of Example 1 (hardened at .150oC for 20 minutes) was immersed in oil (IRM903) of 140oC for 72 hours according to JIS K 6258. The percentage of change of volume of the hardened material was + 0.3%. Note that an HNBR rubber and a fluorine rubber were subjected to the same test for comparison. As a result, their percentages of volume change were + 8% and + 1%, respectively. It can be understood that the hardened material of the epoxy resin of example 1 was resistant to oil swelling, and had satisfactory oil resistance.
[0135] Below are examples corresponding to the embodiment of the second aspect of the present invention. [Example 3]
[0136] First, a textile fabric in which the warp yarns and weft yarns are interwoven in a 2/2 twill was prepared as the face fabric. The warp yarns were non-elastic yarns composed of 110-dtex nylon filament yarns. The weft yarns were elastic yarns composed of composite yarns in which intermediate yarns made of 220-dtex para-aramid fiber yarns (product name: Technora) were wrapped around core yarns made of elastic yarns of 470-dtex urethane, and cover yarns made of 110-dtex nylon fibers were additionally involved in the intermediate yarns. In a step described later, the warp yarns were extended along the belt width direction, and the weft yarns were extended along the longitudinal direction of the belt.
[0137] In addition, a solution of an epoxy rubber treatment agent composition was prepared as follows. Specifically, 70 parts by weight (in terms of solid component) of a polyglycerol polyglycidyl ether (product name: DENACOL EX-521, manufactured by Nagase ChemteX Corporation) as an epoxy resin, 3.5 parts by weight (in terms of component solid) of 2-ethyl-4-methylimidazole as a hardener, and 30 parts by weight (in terms of solid component) of NBR latex were mixed together, and the mixture was diluted with water so that a solid component concentration of 14% by weight was achieved. The face tissue was immersed in this solution, and then dried at 180oC for 5 minutes, so that the epoxy rubber treatment agent composition was adhered to the face tissue. The amount of adhesion (solid component) of the epoxy rubber treatment agent composition to the face fabric was 40 g / m2.
[0138] Next, a slide made of a rubber composition containing the composition shown in Table 1 was prepared as the rubber slide of the tooth surface. In addition, a non-vulcanized rubber formed from HNBR carrying 12 parts by weight of a short aramid fiber in relation to a fiber length of 1 mm in relation to 100 parts by weight of the rubber component was prepared as the rubber sheet from the core. Then, the face tissue subjected to treatment by impregnation with the epoxy rubber treatment agent composition as described above was preformed in a corrugated form. After that, the rubber sheet on the tooth surface and the rubber sheet on the core were adhered under pressure, in that order, to a surface of the face tissue. Thus, a preformed face fabric provided with rubber was obtained.
* 1 each numerical value is expressed in parts by weight. * 2 HNBR with a 96% hydrogenation percentage was used. * 3 An oligomer that had a viscosity at 25oC (according to DIN 19268) of 5500 mPa-s, and that was a partial condensate of hexamethoxymethylmolamine was used as the melamine compound.
[0139] Next, the preformed face fabric provided with rubber, a cord made of a glass cord, and a support rubber sheet formed from HNBR without any short fiber were wrapped around a toothed mold.
[0140] These materials were then molded by vulcanization in a vulcanization chamber at a temperature of 160oC for 30 minutes. And so, a belt plate was obtained. The belt plate was ground and then cut. Thus, a toothed belt RU with a width of 19.1 mm and 92 teeth was obtained. [Example 4]
[0141] Example 4 was the same as Example 3, except that the other surface of the face fabric, which was the opposite surface of the surface on which the rubber sheets were adhered under pressure, was covered with a material hardened with an epoxy resin . Specifically, in Example 4, a face fabric subjected to the impregnation treatment with the epoxy rubber treatment agent composition was first obtained in the same manner as in Example 3. Subsequently, an epoxy resin liquid, which was obtained diluting 100 parts by weight of a novolac-type epoxy resin (epoxy equivalent: 210 g / eq) with 500 parts by weight of MEK (methyl ethyl ketone) and adding 3 parts by weight of a hardener based on deimidazole , was applied by air spray coating on the other surface of the face fabric in order to achieve an adhesion amount (solid component) of 20 g / m2. Then, the face tissue was left to rest at normal temperature (25oC) so that the MEK could evaporate. Subsequently, a toothed belt was manufactured using the face fabric coated with the epoxy resin liquid in the same manner as in Example 3. [Comparative Example 2]
[0142] Comparative Example 2 was conducted in the same manner as Example 1, except that the face fabric was subjected to treatment by impregnation with rubber adhesive, instead of treatment by impregnation with the composition of epoxy treatment agent. rubber. Note that the rubber adhesive included HNBR as the rubber component, to which phenol resin was added. In addition, the amount of adhesion (solid component) of the rubber adhesive to the face fabric was 50 g / m2. [Comparative Example 3]
[0143] Comparative Example 3 was conducted in the same manner as Example 1, except that the face tissue was subjected to treatment by impregnation with RFL, instead of treatment by impregnation with the epoxy rubber treatment agent composition. Note that the RFL was such that the RF / latex weight ratio was 1/5, and the latex component was NBR latex. The amount of adhesion (solid component) of RFL to the face tissue was 50 g / m2. [Trigger Test]
[0144] A drive test was performed on the toothed belts of Examples 3 and 4 and Comparative Examples 2 and 3 described above using the drive test machine illustrated in Fig. 6. A drive test machine 40 has a pulley of toothed drive 41 having 20 teeth and a diameter of 60 mm, toothed pulleys 42 and 43, each having 40 teeth and a diameter of 121 mm, and a flat tension pulley 44 having a diameter of 80 mm. The toothed belt 10 was wrapped around the pulleys 41 to 43. In a state where tension was applied to the toothed belt 10 from the outer peripheral side with the tensioner pulley 44 on the slack side of the belt, the toothed belt 10 was driven at 4000 rpm under a single tooth load of 9.2 N / mm. The test was carried out in an environment with an ambient temperature of 120oC, and the operating time elapsed until the belt failed was measured as the durability time. Fig. 11 shows the relationship of the durability of each belt, where the value of the belt in Comparative Example 3 was assigned the value of 100. [Drive Test for Water Resistance]
[0145] Each belt was operated for 200 hours in the same way as in the drive test, except that the ambient temperature was changed to 80oC, and water was poured over the belt in a predetermined position at 1 liter / hour. The thickness of the face tissue was measured before and after the test, and an assessment was made using the value obtained by subtracting the thickness of the face tissue after testing the thickness of the face tissue before the test as the amount of wear of the face tissue during operation in a state moistened by water. Fig. 12 shows the wear ratio of the face fabric of each of the belts in Comparative example 3 and Example 3, where the amount of wear of the face fabric of the belt in Comparative Example 3 was assigned the value of 100. Note, however, that this test was not performed in Example 4 and Comparative Example 2. [Drive Test for Oil Resistance]
[0146] Each belt was driven in the same way as in the drive test, except that the ambient temperature was changed to 130oC, the engine oil was poured over the belt in a predetermined position, the load per single tooth was 8 N / mm and the number of revolutions was 5400 rpm. Then, the operating time elapsed until the belt failed was measured. Fig. 13 shows the relation of the operating time of each belt, in which the value of 100 was assigned to the running time of Comparative Example 3. Note, however, that this test was not conducted in Example 4. [Adhesion Resistance]
[0147] Then, adhesion test samples A to H were prepared as follows, and the change in adhesion strength was determined as the relationship between the epoxy resin and the latex in the epoxy-rubber treatment agent composition was changed. [Sample A]
[0148] A face fabric subjected to treatment by impregnation with the same solution as the epoxy rubber treatment agent composition as in Example 3 was prepared. The face fabric was adhered to a 4 mm thick rubber sheet, which was made of a rubber composition having the constitution illustrated in Table I, by vulcanization at 160oC for 20 minutes at a pressure of 40 kfg. Thus, Adhesion Test Sample A was obtained with a width of 25 mm and a length of 120 mm. [Sample B]
[0149] Adhesion Test Sample B was obtained in the same way as Sample A, except that the incorporated amounts of materials were changed in the preparation of the solution of the epoxy rubber treatment agent composition as follows: Polyglycerol polyglycidyl ether it made up 50 parts by weight, 2-ethyl-4-methylimidazole made up 2.5 parts by weight, and the NBR latex made up 50 parts by weight, in terms of solid component. [Sample C]
[0150] Adhesion Test Sample C was obtained in the same way as Sample A, except that the incorporated amounts of materials were changed in the preparation of the solution of the epoxy rubber treatment agent composition as follows: Polyglycerol polyglycidyl ether it made up 30 parts by weight, 2-ethyl-4-methylimidazole made up 1.5 parts by weight, and the NBR latex made up 70 parts by weight, in terms of solid component. [Sample D]
[0151] A solution of a latex-free epoxy treatment agent composition was prepared as follows. Specifically, 100 parts by weight (in terms of solid component) of a polyglycerol polyglycidyl ether (DENACOL EX-521) and 5 parts by weight (in terms of solid component) of 2-ethyl-4-methylimidazole were mixed together and the mixture it was diluted with water so that a solid component concentration of 14% by weight was achieved. Adhesion Test Sample D was obtained in the same way as Sample A, except that the face tissue was subjected to treatment by impregnating with this solution of the latex-free epoxy treatment agent composition, instead of the impregnating treatment with the solution of the epoxy rubber treatment agent composition. [Sample E]
[0152] Adhesion Test Sample E was obtained in the same way as Sample A, except that the solution of the epoxy rubber treatment agent composition was changed to a solution prepared as follows. Specifically, 70 parts by weight (in terms of solid component) of a novolac-type epoxy resin (product name: DENACOL EM-160, manufactured by Nagase ChemteX Corporation) as an epoxy resin, 3.5 parts by weight (in solid component terms) of 2-ethyl-4-methylimidazole as a hardener, and 30 parts by weight (in terms of solid component) of NBR latex were mixed together, and the mixture was diluted with water so that a solid component concentration 14% by weight was achieved. [Sample F]
[0153] Adhesion Test Sample F was obtained in the same way as Sample E, except that the incorporated amounts of materials were changed in the preparation of the epoxy rubber treatment agent composition solution as follows: epoxy resin novolac cresol type made up 50 parts by weight, 2-ethyl-4-methylimidazole made up 2.5 parts by weight, and the NBR latex made up 50 parts by weight, in terms of solid component. [Sample G]
[0154] The Adhesion Test Sample G was obtained in the same way as Sample E, except that the incorporated amounts of materials were changed in the preparation of the solution of the epoxy rubber treatment agent composition as follows: epoxy resin novolac cresol type made up 30 parts by weight, 2-ethyl-4-methylimidazole made up 1.5 parts by weight, and the NBR latex made up 70 parts by weight, in terms of solid component. [Sample H]
[0155] A solution of a latex-free epoxy treatment agent composition was prepared as follows. Specifically, 100 parts by weight (in terms of solid component) of a novolac cresol epoxy resin (DENACOL EM-160) and 5 parts by weight (in terms of solid component) of 2-ethyl-4-methylimidazole were mixed together and the mixture was diluted with water so that a solid component concentration of 14% by weight was achieved. The Adhesion Test Sample H was obtained in the same manner as Sample E, except that the face tissue was subjected to treatment by impregnating with this solution of the latex-free epoxy treatment agent composition, instead of the impregnating treatment with the composition of epoxy rubber treatment agent.
[0156] The peeling resistance between the face fabric and the rubber sheet was measured using each of the Adhesion Test Samples A to H under a normal temperature (23oC) and high temperature (120oC) environment of according to JIS K 6256-1: 2006. Figs. 14 and 15 show the results.
[0157] As shown in Figs. 11 to 13, the belt of Example 3, whose face fabric was treated with the epoxy-rubber treatment agent, achieved better belt life and wear resistance than the belts of Comparative Examples 2 and 3, whose fabrics of face were treated with the rubber adhesive or subjected to treatment with RFL; all under the conditions of high temperature and high load and in the presence of oil and water. Furthermore, it can be understood that further improvements in belt life can be achieved with the use of an epoxy resin coating, such as in Example 4.
[0158] Furthermore, as shown in Figs. 14 and 15, the stripping resistance has not been improved enough for each sample with a hardened coating composed of only a hardened material of an epoxy resin. On the other hand, the resistance to flaking of each sample whose face tissue was covered with epoxy-rubber resin was improved. In particular, the case of the aliphatic type. Samples A and B, in which the weight of the epoxy resin was not less than the weight of the latex, achieved satisfactory resistance to flaking. In addition, in the case of the novolac type, all samples achieved satisfactory peeling resistance.
[0159] Note that it was found that the face tissues of Samples E, F and H were relatively rigid based on texture for their touch. For this reason, degradation in performance, such as lack of durability, can occur in Samples E and F, although peeling resistance is satisfactory. In contrast, the face tissues of Samples A, B and G were not as rigid, and had satisfactory resistance to flaking. Therefore, it is conceivable that the face fabrics of Samples A, B and G are highly likely to improve performance, as well as the durability of the belts.

权利要求:
Claims (32)
[0001]
1. Toothed belt (10) FEATURED for comprising a belt body (13) which includes a tooth part (15) and a lower tooth part (16) alternately provided on a surface side thereof along the longitudinal direction, and a face fabric (20) which is provided on a surface of the belt body (13) and which has an outer surface (21) covered with a hardened material consisting of a first hardened epoxy resin.
[0002]
2. Toothed belt (10), according to claim 1, CHARACTERIZED by the fact that the softening point of the hardened material of the first epoxy resin is 110oC or higher.
[0003]
3. Toothed belt (10), according to claim 1, CHARACTERIZED by the fact that the epoxy equivalent of the first epoxy resin is from 100 to 1,500 g / eq.
[0004]
4. Toothed belt (10), according to claim 1, CHARACTERIZED by the fact that the hardened material of the first epoxy resin is applied to the face fabric (20) after the face fabric (20) is subjected to treatment with resorcinol -formaldehyde-latex.
[0005]
5. Toothed belt (10), according to claim 1, CHARACTERIZED by the fact that the first epoxy resin is hardened by a first hardener.
[0006]
6. Toothed belt (10), according to claim 5, CHARACTERIZED by the fact that the first hardener includes at least one hardener selected from the group consisting of amine-based hardener, acid-anhydride-based hardener, water-hardener novolac phenol based, imidazole based hardener and diciandiamide based hardener.
[0007]
7. Toothed belt (10), according to claim 6, CHARACTERIZED by the fact that the first hardener is an imidazole based hardener.
[0008]
8. Toothed belt (10), according to claim 1, CHARACTERIZED by the fact that the first epoxy resin includes at least one epoxy resin selected from the group consisting of bisphenol A epoxy resin, bisphenol F epoxy resin, novolac type epoxy resin , biphenyl-type epoxy resin, phenoxy-type epoxy resin, and long-chain aliphatic epoxy resin.
[0009]
9. Toothed belt (10), according to claim 1, CHARACTERIZED by the fact that the first epoxy resin includes at least one epoxy resin selected from the group consisting of epoxy resin type novolac and epoxy resin bisphenol A.
[0010]
10. Toothed belt (10), according to claim 4, CHARACTERIZED by the fact that the dry weight per unit area of the first epoxy resin applied to the face fabric (20) is less than half the dry weight per unit of resorcinol-formaldehyde-latex treatment area.
[0011]
11. Toothed belt (10), according to claim 1, CHARACTERIZED by the fact that said face fabric (20) has irregularities on the external surface (21) due to a weave texture of the face fabric (20), and wherein said dry weight per unit area of the first epoxy resin applied to the face fabric (20) is such that said irregularities remain on the external surface (21).
[0012]
12. Toothed belt (10), according to claim 1, CHARACTERIZED by the fact that the dry weight per unit area of the first epoxy resin applied to the face fabric (20) is in the range of 10 g / m2 to 50 g / m2.
[0013]
13. Toothed belt (10) according to claim 1, CHARACTERIZED by the fact that the hardened material of the first epoxy resin is applied to the face fabric (20) after the face fabric (20) is subjected to a composition treatment agent including a second epoxy resin, a second hardener to harden the second epoxy resin, and a rubber component.
[0014]
14. Toothed belt (10) according to claim 13, CHARACTERIZED by the fact that the rubber component includes nitrile rubber, hydrogenated nitrile rubber, or hydrogenated carboxylic nitrile rubber.
[0015]
15. Toothed belt (10), according to claim 13, CHARACTERIZED by the fact that the weight ratio of the second epoxy resin to the rubber component is from 1: 9 to 9: 1.
[0016]
16. Toothed belt (10), according to claim 13, CHARACTERIZED by the fact that the amount of adhesion (solid component) of the treatment agent composition for the face tissue (20) is from 5 to 200 g / m2 .
[0017]
17. Toothed belt (10), according to claim 13, CHARACTERIZED by the fact that the rubber component is latex.
[0018]
18. Toothed belt (10) according to claim 13, CHARACTERIZED by the fact that the treatment agent composition additionally includes a vulcanizing agent to vulcanize the rubber component.
[0019]
19. Method of manufacturing the toothed belt (10) defined in claim 1, said method CHARACTERIZED by comprising: coating a surface of a face fabric (20) with a first epoxy resin solution consisting of a solvent, a first epoxy resin and a first hardener; evaporate the solvent; integrating rubber arranged on the other surface side of the face fabric coated with the face fabric (20); and hardening the first epoxy resin by coating the face fabric by vulcanization.
[0020]
20. Toothed belt (10) FEATURED for comprising a belt body (13) that includes a tooth part (15) and a lower tooth part (16) alternately provided on a surface side of the same along the longitudinal direction, and a face fabric (20) which is applied to cover a surface of the belt body (13), the face fabric (20) being treated with a treatment agent composition including a second epoxy resin, a second hardener for harden the second epoxy resin, and a rubber component.
[0021]
21. Toothed belt (10) according to claim 20, CHARACTERIZED by the fact that the second epoxy resin includes at least one epoxy resin selected from the group consisting of aliphatic epoxy resin, novolac type epoxy resin, bisphenol A epoxy resin, bisphenol F epoxy resin, biphenyl type epoxy resin and phenoxy type epoxy resin.
[0022]
22. Toothed belt (10), according to claim 21, CHARACTERIZED by the fact that the second epoxy resin includes at least one epoxy resin selected from the group consisting of aliphatic epoxy resin and novolac type epoxy resin.
[0023]
23. Toothed belt (10) according to claim 20, CHARACTERIZED by the fact that the second hardener is an imidazole based hardener.
[0024]
24. Toothed belt (10) according to claim 20, CHARACTERIZED by the fact that the rubber component includes nitrile rubber, hydrogenated nitrile rubber or hydrogenated carboxylic nitrile rubber.
[0025]
25. Toothed belt (10) according to claim 20, CHARACTERIZED by the fact that the weight ratio of the second epoxy resin to the rubber component is from 1: 9 to 9: 1.
[0026]
26. Toothed belt (10) according to claim 20, CHARACTERIZED by the fact that the amount of adhesion (solid component) of the treatment agent composition for the face tissue (20) is from 5 to 200 g / m2 .
[0027]
27. Toothed belt (10), according to claim 20, CHARACTERIZED by the fact that the rubber component is latex.
[0028]
28. Toothed belt (10) according to claim 20, CHARACTERIZED by the fact that the treatment agent composition additionally includes a vulcanizing agent to vulcanize the rubber component.
[0029]
29. Toothed belt (10) according to claim 20, CHARACTERIZED by the fact that the part of the belt body (13) to be adhered to the face fabric (20) is shaped by the vulcanization of a rubber composition including rubber , resorcinol and a melamine compound.
[0030]
30. Toothed belt (10) according to claim 20, CHARACTERIZED by the fact that the rubber of the belt body (13) constituting the part to be adhered to the face fabric (20) includes hydrogenated nitrile rubber or carboxylic nitrile rubber hydrogenated.
[0031]
31. Toothed belt (10) according to claim 20, CHARACTERIZED by the fact that the outer surface (21) of the face fabric (20) treated with the treatment agent composition is additionally covered with a hardened material of a third epoxy resin.
[0032]
32. The toothed belt manufacturing method (10) defined in claim 20, the method being CHARACTERIZED in that it comprises: treating the face fabric (20) with a treatment agent composition including a second epoxy resin, a second hardener to harden the second epoxy resin and a rubber component; and superimpose a sheet of non-vulcanized rubber on the treated face fabric followed by vulcanization molding, in order to obtain the toothed belt (10).

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法律状态:
2018-12-18| B06F| Objections, documents and/or translations needed after an examination request according art. 34 industrial property law|

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2019-10-08| B06U| Preliminary requirement: requests with searches performed by other patent offices: suspension of the patent application procedure|

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2020-07-07| B06A| Notification to applicant to reply to the report for non-patentability or inadequacy of the application according art. 36 industrial patent law|

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2021-01-05| B09A| Decision: intention to grant|

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2021-03-09| B16A| Patent or certificate of addition of invention granted|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 16/02/2012, OBSERVADAS AS CONDICOES LEGAIS. |

优先权:

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申请号 | 申请日 | 专利标题

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JP2011038394A|JP5602056B2|2011-02-24|2011-02-24|Toothed belt|

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JP2011-038394|2011-02-24|

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JP2011264739A|JP5597181B2|2011-12-02|2011-12-02|Toothed belt|

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JP2011-264739|2011-12-02|

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PCT/JP2012/053606|WO2012114967A1|2011-02-24|2012-02-16|Toothed belt|

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