• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    FIBER PREFORM, E, COMPOSITE COMPONENT The invention relates to a fiber preform to produce composite fiber structures, the wall of which comprises at least a first zone made of bundles of reinforcing fibers having a first resin composition and at least a second zone made of at least one fiber strip comprising at least one filament of reinforcement wire directed unidirectionally, having a second resin composition, wherein the bundles of reinforcement fibers in at least one first zone are oriented in different spatial directions when viewed in a direction parallel to the thickness extension, where each bundle of reinforcement fibers comprises reinforcement fiber filaments arranged parallel to each other, has a length in the range of 3 to 50 mm, and contains the first resin composition at a concentration in the range of 1 to 10% by weight relative to the weight of the fiber, where the wall of the fiber preform has a proportion of fibers of reinforcement of more than 35% in vol, and in which at least a second zone forms a discrete region when viewed in a direction perpendicular to the thickness extension of the (...).
    公开号:BR112013011577B1
    申请号:R112013011577-7
    申请日:2011-11-11
    公开日:2020-12-08
    发明作者:Bernd Wohlmann；Markus Schneider；Andreas Wöginger；Frank Oberwahrenbrock
    申请人:Teijin Carbon Europe Gmbh；
    IPC主号:
    专利说明:

    [1] The present invention relates to a fiber preform for producing composite fiber structures or composite components, the wall of which is made of reinforcing fibers, as well as a composite component made from this type of fiber preform.
    [2] Components made from fiber composite materials are increasingly used, especially in the sectors of the space industry, yet also, for example, in the machine-building industry. Fiber composites often offer the advantage of less weight and / or greater strength over metals. Thus, an essential aspect is the inexpensive production of this type of resilient and still lightweight composite components at the same time. In view of resilience, that is, stiffness and strength, the percentage volume of the reinforcement fibers and especially also the direction of the reinforcement fibers have a determining effect on composite components.
    [3] A commonly used manufacturing method is currently based on so-called prepreg technology. In this case, reinforcement fibers, such as glass fibers or carbon fibers, are arranged, for example, parallel to each other, embedded in a resin matrix, and processed to form sheet-like semi-finished products. These sheets are cut according to the component outline and laminated to a tool by machine or by hand layer by layer, taking into account the orientation of the reinforcement fibers, as required by the component load. Subsequently, the matrix is cured under pressure and temperature in an autoclave. This type of manufacturing process is, however, very complex and expensive for many components.
    [4] In another method, so-called fiber preforms are produced from reinforcing fibers. Essentially, these are semi-finished textile products in the shape of two- or three-dimensional figures made of reinforcement fibers, in which, in other steps to produce the composite fiber component, an appropriate matrix material is introduced through infusion or injection. , also by applying vacuum. Subsequently, the matrix material is cured at, in general, elevated temperatures and pressures to form the finished component. The known methods for infusion or injection of the matrix material in this case are the so-called liquid molding method (LM), or methods related to it, such as resin transfer molding (RTM), resin transfer molding, assisted by vacuum, (VARTM), resin film infusion (RFI), liquid resin infusion (LRI), or flexible resin infusion tooling (RIFT). The fiber material used to produce the fiber preforms may also already be impregnated, for example, with small amounts of a curable plastic material, that is, a binder material, in order to improve the fixation of the reinforcement fibers in the fiber preform . Pre-impregnated yarns of this type are described, for example, in WO 2005/095080.
    [5] In order to produce such fiber preforms, WO 98/22644 has already suggested dispersing short cut reinforcement fibers together with a binding material on an air-permeable canvas, adapted to the shape of the desired fiber preform and maintaining said fibers on the screen by applying vacuum until sufficient preform stability has been achieved after cooling the bonding material. Through this procedure, the reinforcement fibers are arranged in random isotropic arrangements and directions. In fact, this is advantageous if the load directions on the component cannot be predicted in advance; however, it has the simultaneous disadvantage that, due to the isotropic orientation, only a fraction of the fibers are located in the load direction. Adaptation to the special loading directions on the component is therefore not possible when using this method. Reinforcements in the component wall can, at most, be made through, for example, locally increased wall thicknesses, however, they are associated with an increase in component weight. In addition, according to the examples in WO 98/22644, only proportions of fiber volume in the range up to approximately 15% by vol are obtained, and therefore, due to the low proportions of fiber volume, only comparatively low strengths component, related to thickness. Usually, fiber proportions of a maximum of 30% by vol are obtained for components of this type having random reinforcement fiber orientation.
    [6] In US 2010/0126652 A1 and US 2009/0229761 A1, a method and device, respectively, for producing fiber preforms are described, whereby it is possible to satisfy the demand for a fiber direction appropriate to the load in the component. In this case, a so-called TFP method (“tailored fiber placement method”) is used, in which fiber strands or filaments are placed along any number of paths adapted to the distribution of forces that affect the finished component and fixed using fastening threads, in which sewing and knitting machines controlled by computer numerical control are used for this. US 2009/0229760 A1 describes an application device for fiber filaments, suitable for such a TFP method. Using these TFP methods, improved utilization of the mechanical strength of the reinforcement fibers and increased adaptation of the component cross sections to the respective local loads on the component are possible. However, these methods, in particular in the production of fiber preforms with complex three-dimensional structures, are complex and cost-intensive.
    [7] As an alternative for fixing fiber filaments using a textile method, such as using sewing and knitting methods, fiber filaments can also be attached using a thermally activated material binder, by example, by means of a thermoplastic, as described in DE 10 2007 012 608 B4.
    [8] Another possibility for the production of fiber preforms is the use of so-called multiaxial non-wrinkle fabrics. Multiaxial non-wrinkle fabrics are understood to be structures made from a plurality of superimposed fiber layers, wherein the fiber layers comprise sheets of reinforcement threads arranged parallel to each other. The superimposed fiber layers can be connected and secured together through a plurality of sewing and knitting threads arranged side by side and running parallel to each other and forming stitches, so that multiaxial non-wrinkle fabrics are stabilized in this way. The fiber layers are superimposed so that the reinforcing fibers of the layers are directed parallel to each other or alternately in a crossed manner (for example, -45 °; 0 °, + 45 °).
    [9] Multiaxial non-wrinkle fabrics of this type are placed without matrix material in a mold and, for example, for forming, are adapted to their contours using increased temperature. Subsequently, the matrix material required for the production of the composite component is introduced into the mold and fiber preform via infusion or injection, whereby, after curing the matrix material, the composite component is obtained. Multiaxial non-wrinkle fabrics and the use of them to produce fiber preforms are described, for example, in EP 0 361 796 B1, EP 1 352 118 B1, or WO 98/10128.
    [10] Multiaxial non-wrinkle fabrics are, however, expensive to produce, and are generally produced in standard widths, which rarely match the dimensions of the posterior component. This results in an insignificant amount of waste or refuse. In addition, especially for components with complex contours and particularly for components with small radii of curvature, they can only be used to a limited extent, as multiaxial non-wrinkle fabrics cannot be draped in any way. In addition, it has been observed that sewing or knitting yarns can often lead to a reduction in the impact strength of the resulting composite. Finally, the subsequent infusion or injection of the matrix material can also be slowed over liquid molding or related methods.
    [11] To avoid seams and cross filaments, US 2008/0085650 A1 suggests the use of reinforcement material structures having a layered construction, said reinforcement material structures comprising a layer of continuous reinforcement fibers directed in parallel as well as a layer made from, for example, a non-woven fabric, a woven fabric, or from short cut fibers, wherein the layers are connected to each other through an adhesive or through adhesive points. These materials are also initially available in standard widths, which have to be cut to match the component's geometry. In this way, high costs occur due to additional steps, for example, cutting, draping, and connection, as well as an average waste of up to 30% of the output material.
    [12] It is the aim of the present invention to provide a fiber preform that can find use in a plurality of component contours, in which in particular an improved adaptation to the respective local loads on the component is possible, and which can be produced from cheap way.
    [13] The goal is achieved by a fiber preform to produce composite fiber structures, the wall of which is made of reinforcing fibers, - where the wall has a first surface, a second surface is located opposite the first surface and a thickness extending between the surfaces, and is limited by edges, - the wall comprising at least a first zone made of bundles of reinforcing fibers having a first resin composition and at least a second zone made of at least one tape fiber comprising at least one filament of reinforcement wire directed unidirectionally, having a second resin composition, - wherein the bundles of reinforcement fibers in at least one first zone are oriented in different spatial directions from one another when viewed in a direction parallel to the thickness extension, - where each bundle of reinforcement fibers comprises reinforcement fiber filaments directed parallel to each other, has a length in the range of 3 to 50 mm, and contains the first resin composition in a concentration in the range of 1 to 10% by weight relative to the weight of the fiber, - where the wall of the fiber preform has a proportion of fibers reinforcement greater than 35% by vol, and - where the at least a second zone forms a discrete region when viewed in a direction perpendicular to the length of the wall thickness and at least one fiber strip ends with at least one end of it inside the wall.
    [14] By means of the fiber preform according to the invention, a composite fiber structure or a composite component can be produced in a simple manner. In this case, the fiber preform according to the invention can be placed in a mold close to the mesh using common methods, a matrix material is introduced into the mold and thus into the fiber preform, through infusion, infiltration , or injection, and subsequently the composite component is formed by curing the matrix material. The invention therefore also relates to a composite component, the wall of which is made of reinforcing fibers embedded in a polymer matrix, - the wall having a first surface, a second surface being opposite the first surface and a thickness extending between the surfaces, and is limited by edges, - the wall comprising at least a first zone made of bundles of reinforcing fibers and at least a second zone made of at least one fiber strip comprising at least a filament of reinforcement wire directed unidirectionally, - where the bundles of reinforcement fibers in at least one first zone are oriented in different spatial directions from one another when viewed in a direction parallel to the thickness extension, - where each bundle of reinforcement fibers comprises reinforcement fiber filaments directed parallel to each other and has a length in the range of 3 to 50 mm, - where the prefo wall fiber rm has a proportion of reinforcement fibers greater than 35% by vol, and - in which at least a second zone forms a discrete region when viewed in a direction perpendicular to the extent of wall thickness and at least one fiber tape ends with at least one end of it inside the wall.
    [15] The fiber preform or composite component thus has at least one first zone made of reinforcing fiber bundles and at least one second zone made of at least one fiber tape within the wall of the same. In this case, the first zone within the wall can form a continuous region over the entire wall, in which, for example, one or more second zones are embedded. The second zones can thus be arranged within the wall, that is, forming islands when viewed perpendicularly to the extent of the wall thickness. The second zones can, however, in a preferred embodiment, also be arranged in the region of one of the surfaces on the first zone, that is, in this case at least one fiber strip is mounted, for example, on one of the surfaces. However, it is also possible that the second zone extends over the entire wall thickness and is thus laterally limited by the first zones. In each case, at least a second zone forms a discrete region when viewed in a direction perpendicular to the extent of the wall thickness, i.e., at least a second zone does not form a continuous region over the entire wall when viewed in this direction. As previously explained, only at least one first zone can extend over the entire wall as a continuous region. in a preferred embodiment of the fiber preform according to the invention, the at least one first zone within the wall forms, on the entire wall, in a continuous region made of bundles of reinforcing fibers and the wall comprises at least a second discrete zone arranged inside and / or over the continuous region made of bundles of reinforcement fibers.
    [16] In at least one first zone, the bundles of reinforcement fibers are oriented in different spatial directions from one another when viewed in a direction parallel to the thickness extension, that is, the reinforcement fibers are distributed or isotropically oriented in at least one first zone in spatial directions perpendicular to the extent of thickness. Isotropically it is thus understood to mean that, as long as there is an anisotropic orientation of the fibers within the individual reinforcement fiber bundles, the bundles in their entirety do not show any preferred orientation, but are isotropically oriented in the aforementioned spatial directions. In particular with respect to thicker walls or thicker layer thicknesses of the first zones, there may also be an isotropic distribution taking into account the spatial direction extending in the direction of the wall thickness, that is, the fiber preform or the composite component it can have an isotropic structure in all three spatial directions in at least one first zone.
    [17] According to the invention, each bundle of reinforcement fibers comprises filaments of reinforcement fiber directed parallel to each other and has a length in the range of 3 to 50 mm. Preferably, the length is in the range of 10 to 50 mm. In view of the proportions that can be achieved of reinforcement fibers in at least one first zone, in particular to obtain proportions greater than 40% by vol, it is advantageous if the wall of the fiber preform or the composite component according to the invention has a plurality of bundles of reinforcement fiber bundles having different lengths in at least one first zone, so that overall the lengths of the reinforcement fiber bundles have a distribution. For example, bundles of reinforcement fibers having a length of 20, 30, and 50 mm can be or are combined with each other.
    [18] Bundles of reinforcement fibers may comprise common filament yarns having, for example, 500 to 50,000 reinforcement fiber filaments. It is, however, advantageous if each bundle of reinforcement fibers comprises 500 to 24,000 reinforcement fiber filaments. In order to obtain the most homogeneous distribution of the reinforcement fiber bundles in at least one first zone, and to obtain the highest possible fiber proportions, the number of reinforcement fiber filaments in the reinforcement fiber bundles is particularly preferably in the 500 to 6,000 and more particularly preferably 1,000 to 3,000.
    [19] To obtain high proportions of fiber volume in at least one first zone, in particular to obtain reinforcement fiber proportions greater than 40% by vol, it has been proven that it is equally advantageous if the wall has a plurality of bundle groups of reinforcement fibers has different numbers of reinforcement fiber filaments, because this allows the realization of high densities of conditioning of the bundles in at least one first zone. For example, bundles of reinforcement fibers having 3,000, 6,000, and 12,000 reinforcement fiber filaments can be combined.
    [20] To obtain high packing densities of the bundles, that is, to obtain high proportions of fiber volume in at least one first zone exceeding 40% by vol, it is still advantageous if the bundles of reinforcement fibers have a cross section that it is as flat as possible perpendicular to the length of the reinforcement fiber filaments in the bundle. Preferably, the bundles of reinforcement fibers are strip-shaped and have a ratio between bundle width and bundle thickness of at least 25. Particularly preferably, the ratio between bundle width and bundle thickness is in the range of 30 to 150 .
    [21] Through the appropriate selection of bundles of reinforcement fibers with respect to the relationship between bundle width and bundle thickness, with respect to length, as well as with respect to the number of reinforcement fiber filaments, especially high packing densities of bundles of reinforcement fibers and thus especially high proportions of fiber volume, can be carried out in at least one first zone. In a more particularly preferred embodiment of the fiber preform or the composite component, the bundles of reinforcement fibers arranged in the region of at least one first zone in the wall of the fiber preform or the composite component have, in addition to a flat cross section, different lengths and different numbers of reinforcement fiber filaments. This leads especially to high proportions of fiber volume in the wall of the preform or component. According to the invention, the wall of the fiber preform or composite component has, through its entire extension, that is, at each point of its extension, a proportion of reinforcing fibers of at least 35% by vol, preferably a proportion reinforcement fibers of at least 40% by vol, and particularly preferably 45% by vol. It is especially advantageous if the proportion of reinforcement fibers is at least 50% by vol, because this leads to optimum mechanical properties in the composite component. The pre-impregnation of the bundles of reinforcement fibers with the first resin composition thus allows a stable, compact placement of these bundles of reinforcement fibers during the production of the fiber preform, whereby the realization of such high volume proportions fiber is supported.
    [22] The proportion of reinforcement fibers in the fiber preform wall can be determined according to DIN EN 2564: 1998. For this purpose, the fiber preform is impregnated, according to usual methods, with an epoxy resin, such as HexFlow RTM 6 (Hexcel), and cured to form a composite material. Test bodies are cut from the cured composite material, from which mass and density are determined according to DIN EN 2564: 1998, as well as, after treatment with concentrated sulfuric acid to separate the matrix resin, the mass of the fibers contained in the test bodies. In accordance with the provisions of DIN EN 2564: 1998, the fiber mass ratio can thus be determined and, resulting from it, the fiber volume ratio or the reinforcement fiber ratio. This method can also be used to determine the fiber volume ratio for the composite components.
    [23] Bundles of reinforcing fibers in the fiber preform have inventively a content of a first resin component in the range of 1 to 10% by weight relative to the proportion of fiber. Hereby, sufficient stability is provided for the fiber bundles, and disintegration into individual filaments or individual groups of filaments is avoided. At the same time, the use of the resin applications according to the invention ensures that the bundles of reinforcement fibers adhere to each other during the formation of the fiber preform and the fiber preform thus obtains sufficient stability for further handling. Such a resin application is often referred to as a binder or as an agglutination. As already explained, the current matrix material still required for the formation of the composite component is introduced at a later stage of the process by infusion or injection in the preform. Preferably, the bundles of reinforcement fibers in the fiber preform contain the first resin composition in a concentration in the range of 2 to 7% by weight relative to the fiber ratio.
    [24] With respect to the first resin composition, this can be a binder material that satisfies the above mentioned objective. In a preferred embodiment of the invention, the first resin composition is a binder material that can be thermally activated, for example, a thermoplastic. However, preferably the binder material is based on epoxy resins, where the binder material can be multi-melted and can be converted to a fixed state by cooling to room temperature. Resin compositions of this type, or reinforcement fibers that have these types of resin compositions, are exposed, for example, in WO 2005/095080. WO 98/22644 also exposes these types of resin compositions suitable as binders.
    [25] At least one fiber strip over or within at least one first zone and thus at least one second zone itself is arranged, for example, in regions of especially high tension in the subsequent component produced from the preform of fiber or composite component according to the invention and is correspondingly oriented in the stress directions that prevail there. The at least one fiber strip is thus preferably arranged in orientation with forces or directed according to the load on the wall of the fiber preform or composite component. Thus, at least one fiber tape or fiber tapes can extend from one side or edge of the fiber preform or composite component wall to the other side or edge of the fiber preform or composite component and so on the entire extent in this region. The edges can thus define the outer perimeter of the fiber preform; however, they can also appear inside the fiber preform through recesses, opening, projections, among others.
    [26] The fiber preform according to the invention is distinguished itself by the fact that it can be flexibly adapted to local loads in the component to be produced from the fiber preform. Accordingly, the fiber preform has, in one embodiment, at least one fiber strip that ends with at least one end of it within the wall, and said fiber strip thus does not extend from an edge of the preform fiber to another edge. The fiber tape or a plurality of fiber tapes thus extends only over parts of the respective expansion or extension of the wall towards a fiber tape, or of these fiber tapes, thus forming regions in the shape of an island or in the shape of a peninsula. . The ends of the fiber tape thus correspond to the ends of at least one filament of reinforcement wire directed unidirectionally, forming this fiber tape. For example, it is also possible, in the case where a fiber preform or composite component has a projection to form a trim, these fiber tapes are applied as reinforcement only in the projection region. Fiber tapes or at least one fiber tape can thus also be applied or extended in a curved path.
    [27] Preferably, the at least one fiber strip is at least 7 cm long and especially preferably at least 10 cm long. At shorter lengths, the transmission of force to the fiber tapes in a component is insufficient. In addition, the handling of shorter fiber strips, in particular in automated placement, as described, for example, in DE 10 2007 012 608 B4, is difficult. The at least one fiber tape is preferably preferably at least 20 cm long. As previously explained, an upper limit on the length of fiber tape results from component geometry in individual cases.
    [28] The at least one fiber strip may comprise, for example, a single multifilament reinforcement yarn that is spread and laid flat, that is, a single reinforcement yarn filament. Preferably, however, the at least one fiber strip comprises a plurality of reinforcement yarn filaments arranged side by side and parallel to each other.
    [29] In an embodiment of the fiber preform according to the invention or of the composite component, the at least a second zone can thus comprise an individual fiber strip, which can also comprise a plurality of multifilament reinforcement yarns applied one after the other. others and each other. Preferably, however, the at least a second zone comprises a plurality of fiber strips arranged in layers on top of each other, where the number of layers as well as their width results from the respective loads on the subsequent component.
    [30] As explained, due to the specific construction of the fiber preform according to the invention, the construction appropriate to the load of the fiber preform as well as the components produced therefrom is possible in a simple way. This is achieved here by the fact that the at least one fiber strip is preferably arranged on the wall of the fiber preform or composite component in orientation with the forces, or directed in a manner appropriate to the load. In one embodiment, therefore, the wall of the fiber preform or composite component comprises at least two fiber tapes and the orientation of the at least one filament of reinforcement wire directed unidirectionally from at least one fiber tape is different from the orientation at least one filament of reinforcement wire directed unidirectionally from another fiber tape. In one embodiment, within the second zone, fiber strips that are arranged in layers on top of each other, or the reinforcement yarn filaments directed unidirectionally, within and forming the said fiber strips, can thus have different orientations. In another embodiment, in the case of a plurality of second zones on and / or on the wall of the fiber preform or composite component, fiber tapes of different second zones, or the filament of reinforcement yarn directed unidirectionally, from different second zones inside, and conforming to, fiber tapes, can have different orientations. The reinforcement wire filaments, differently oriented, can form, for example, an angle α in the range of 5 ° to 175 °, and preferably 20 ° to 160 °, with each other. This of course also comprises modalities in which fiber strips within a second zone and those from different second zones have different orientations between them.
    [31] In another preferred embodiment, at least one filament of reinforcement yarn directed unidirectionally from at least one fiber ribbon, or at least one fiber ribbon, in relation to its longitudinal extension, is not directed parallel to any of the edges fiber preform or composite component.
    [32] According to the invention, the filaments of reinforcement yarn directed unidirectionally, or to at least one fiber tape have a second resin composition. Hereby, secure placement and securing of at least one fiber tape is permitted and stabilization of the fiber preform is achieved. Depending on the application, the fiber tape can be a so-called unidirectional prepreg, where the unidirectionally oriented reinforcement fibers are already impregnated with matrix resin and the concentration of the matrix resin in the prepreg already substantially corresponds to the concentration in the component, that is, in the range of approximately 25 to 45% by weight. Preferably, however, the at least one fiber strip of the fiber preform according to the invention has the second resin composition in a concentration of 1 to 10% by weight relative to the proportion of fiber. The second resin composition then functions as a binding material. In concentrations of this type, good handling and good fixing, previously mentioned, are guaranteed, on the one hand. On the other hand, the at least one fiber tape has sufficient stability and there is good infiltration with the matrix resin during the subsequent component processing.
    [33] The proportion of reinforcement fibers in at least one fiber strip of at least a second zone of the fiber preform should be less than 70% by vol, so that, in the finished component, after infiltration with matrix resin , a substantially complete embedding of the reinforcement fibers in the matrix resin is guaranteed. On the other hand, the proportion of fibers must be as high as possible so that a reinforcement effect as high as possible is achieved in the given volume. Not least, but also under consideration of practical handling capacity, the volume proportions of reinforcement fibers in at least one fiber strip of the fiber preform or composite component have been shown to be appropriate in the range of 40 to 65% vol and preferably in the range of 50 to 65 vol%.
    [34] With respect to the second resin composition, it can, like the first resin composition, be a binder material that can be thermally activated, for example, a thermoplastic. A binder material based on epoxy resins is also preferred, in which the binder material can be multi-melted and can be converted to a fixed state by cooling to room temperature. Also, with respect to the second resin composition or with respect to the fiber tapes having such resin compositions, the exposed yarn and resin compositions, for example, in WO 2005/095080, can be considered. Preferably, the first resin composition and the second resin composition are chemically similar and especially preferably identical. Resin compositions or suitable binder materials are also described, for example, in the already mentioned WO 98/22644.
    [35] With respect to the reinforcement fibers or reinforcement fiber yarns used in the fiber preform according to the invention or in the composite component according to the invention, said fibers or yarns can be those based on carbon, glass, aramid, ceramic, boron, steel or based on synthetic polymers, such as polyamide, polyhydroxy ether, polyethylene, in particular UHMW polyethylene, or polyester, or a combination of these materials, for example, in the form of mixed yarns (co-woven yarns) . In a preferred embodiment, the reinforcement fibers of the reinforcement fiber bundles and / or the reinforcement yarn filaments of the at least one fiber tape are carbon fibers. In this case, the carbon fibers can be those that are obtained from tar, polyacrylonitrile or viscose pre-products.
    [36] The combination of bundles of reinforcing fibers, isotropically rigid, and strands of fiber or reinforcing wire filaments oriented in force, allows for a cheap production of fiber preforms, which can be simultaneously adapted to the loads specific components in the subsequent component. Thus, the first zones can be inexpensively shaped with bundles of reinforcement fibers, for example, through so-called fiber spraying processes, in which reinforcement fiber threads applied with the first resin composition are fed to a head cutting, cut into correspondingly measured bundles having the desired length, and finally sprayed on a tool adapted to the final contours of the fiber preform. Alternatively, a filling made of corresponding bundles of reinforcement fibers can also be deposited on the tool. In both cases, the positioning of the bundles of reinforcement fibers can be supported by applying vacuum to the tool, which is perforated in this case.
    [37] At the same time, or also, for example, subsequently, in regions where there will be a high load on the subsequent component, fiber tapes can be applied, oriented in the direction of the loads, in which, for this purpose, the well-known methods of prior art can be used, as an application method set out in WO 2007/101578 using a flame spray method to deposit the second resin composition during application, or the method set out in DE 10 2007 012 608 B4, in which the fiber strips or reinforcement fiber filaments, which are provided with a binder material that can be thermally activated, for example, with a thermoplastic, thus a second resin composition, are positioned by means of an automated application device on a horizontal head. Methods of this type are also known as "fiber laying methods".
    [38] Thus, in contrast to the prior art fiber preforms, fiber preforms having, in principle, any possible flat or two-dimensional surface geometry, or preferably having a three-dimensional surface geometry that differs from the flat surface geometry, can be produced by means of the present invention. The preform according to the invention and also the composite component according to the invention can have different wall thicknesses over the extension of the wall of the same or also projections, opening, etc. A preferred fiber preform, therefore, has in particular different wall thicknesses in the region of at least one first zone.
    [39] Hereby, the fiber preform according to the invention or the composite component according to the invention can be available in a plurality of different modalities. By flexibly controlling the first and second zones in relation to each other, a simple adaptation to the loads on the component can be achieved. Thus, according to loading locations, an adaptation can be made by increasing the wall thickness through additional proportions of first zones, that is, by adding reinforcement bundles. Likewise, reinforcement is possible in specific regions through second zones having fiber strips oriented in the direction of loading. Hereby, depending on the specific component or depending on the specific fiber preform, the proportion of first zones having bundles of reinforcement fibers can surpass the proportion of second zones having fiber tapes made of reinforcement yarn filaments, or vice versa . The key to determining the modality in this case are the loads predetermined in the final component as well as the goals to be achieved with respect to, for example, wall thicknesses, weight, volume, etc. and not lastly in relation to the component's manufacturing costs.
    [40] The invention will now be described in more detail by means of the following figures, in which the figures should not have a limiting character. In simplified schematic representation: Figure 1 shows a top view of a fiber preform according to the invention in the form of a curved hub segment. Figure 2 shows a cross section through the fiber preform segment shown in figure 1 along line A - A. Figure 1 schematically shows a fiber preform 1 in the shape of a curved hub segment having a first surface 2 and a second surface 3 and a thickness extending between the surfaces. From a top view of the first surface 2, the first zones 4 made of bundles of reinforcement fibers 5 can be recognized, said bundles being, on average, isotropically oriented in different directions. The bundles of reinforcement fibers 5 are constructed of reinforcement filaments 6, cut short, running parallel to each other, in which the number of reinforcement fiber filaments in the bundle can be in the range of 500 to 50,000. The bundles of reinforcement fibers 5 are provided with a first resin composition, whereby good adhesion of the bundles of reinforcement fibers to each other is obtained and the fiber preform obtains sufficient stability for further manipulation.
    [41] In the present example, the fiber preform 1 has two second zones 7a, 7b on its first surface 2 in the form of fiber tapes comprising filaments of reinforcement yarn 8a, 8b, directed unidirectionally. In the example shown, the second zone 7a extends over surface 2 from one edge to the opposite edge, while the second zone 7b extends only over a segment of the surface and ends within the wall. The reinforcement wire filaments 8a, 8b of the second zones 7a, 7b are oriented in different directions and are not directed parallel to any of the edges of the fiber preform.
    [42] Figure 2 shows a cross section through the fiber preform segment schematically represented in Figure 1. Therefore, the same parts are provided with the same reference numbers. The fiber preform 1 is present as a curved segment having a first surface 2 and a second surface 3, between which the thickness of the fiber preform wall extends. The wall is constructed of a first zone 4 and second zones 7a, 7b, 9, 10, in which in the representation of the cross section it is clear that the first zone 4 forms, on the entire wall, a continuous region made of bundles of fibers of reinforcement 5 and said zone can be designated as a continuous phase. In contrast, the second zones 7a, 7b, 9, 10 are embedded as discrete regions in the first zone 4. In figure 2, in addition to zones 7a, 7b shown in figure 1 on the first surface 2, two additional second zones 9, 10 are shown on the inner wall, which zones are completely surrounded by the first zone 4. The second zones 7a, 7b, 9, 10 are constructed from the reinforcement wire filaments 8, 8a, 8b which are arranged on top of each other in several layers.
    [43] The fiber preform shown in figures 1 and 2 has a relatively large thickness. Therefore, in this example, the bundles of reinforcement fibers 5 are also oriented substantially isotropically over the wall cross section in the cross section view.
    权利要求:
    Claims (17)
    [0001]
    1. Fiber preform to produce composite fiber structures, characterized by the fact that the wall is made of reinforcing fibers, in which the wall has a first surface, a second surface is located opposite the first surface and a thickness extending between the surfaces, and is limited by edges, where the wall comprises at least a first zone made of bundles of reinforcing fibers having a first resin composition and at least a second zone made of at least one fiber strip comprising at least a filament of reinforcement wire directed unidirectionally, having a second resin composition, in which the bundles of reinforcement fibers in at least one first zone are oriented in different spatial directions from one another when viewed in a direction parallel to the extension of thickness, where each bundle of reinforcement fibers comprises reinforcement fiber filaments directed parallel to each other, has a length in the range of 3 to 50 mm, and contains the first resin composition in a concentration in the range of 1 to 10% by weight relative to the weight of the fiber, where the wall of the fiber preform has a higher proportion of reinforcing fibers at 35% by vol, and in which at least a second zone forms a discrete region when viewed in a direction perpendicular to the extent of wall thickness and at least one fiber strip ends with at least one end thereof within the wall.
    [0002]
    2. Fiber preform according to claim 1, characterized in that the wall thereof comprises at least two strands of fiber and the orientation of at least one filament of reinforcement yarn directed unidirectionally from at least one fiber strand is different from the orientation of at least one filament of reinforcement yarn directed unidirectionally from another fiber tape.
    [0003]
    Fiber preform according to claim 1 or 2, characterized in that the at least one filament of reinforcement wire directed unidirectionally from at least one fiber strip is not directed parallel to any of the edges.
    [0004]
    Fiber preform according to any one of claims 1 to 3, characterized in that the reinforcing fibers of the reinforcement fiber bundles and / or the reinforcement yarn filaments of the at least one fiber tape are fibers of carbon.
    [0005]
    Fiber preform according to any one of claims 1 to 4, characterized in that the at least one first zone within the wall forms a continuous region formed from bundles of reinforcement fibers and the wall comprises at least one second discrete zone arranged in and / or over the continuous region made of bundles of reinforcement fibers.
    [0006]
    Fiber preform according to any one of claims 1 to 5, characterized in that each bundle of reinforcement fibers has a length in the range of 10 to 50 mm.
    [0007]
    Fiber preform according to any one of claims 1 to 6, characterized in that the wall has a plurality of groups of bundles of reinforcing fibers having different lengths between them.
    [0008]
    Fiber preform according to any one of claims 1 to 7, characterized in that each bundle of reinforcement fibers has 500 to 24,000 reinforcement fiber filaments.
    [0009]
    Fiber preform according to any one of claims 1 to 8, characterized in that the wall has different groups of reinforcement fiber bundles having different numbers of reinforcement fiber filaments from one another.
    [0010]
    Fiber preform according to any one of claims 1 to 9, characterized in that the wall in at least one first zone has a reinforcement fiber ratio of at least 45% by vol.
    [0011]
    Fiber preform according to any one of claims 1 to 10, characterized in that the bundles of reinforcing fibers contain the first resin composition in a concentration in the range of 2 to 5% by weight in relation to the proportion of fiber.
    [0012]
    Fiber preform according to any one of claims 1 to 11, characterized in that the at least one fiber strip comprises a plurality of reinforcement fiber filaments arranged next to each other.
    [0013]
    Fiber preform according to any one of claims 1 to 12, characterized in that the at least one fiber strip has a length of at least 7 cm.
    [0014]
    Fiber preform according to any one of claims 1 to 13, characterized in that the at least one fiber tape has the second resin composition in a concentration of 1 to 10% by weight in relation to the proportion of fiber .
    [0015]
    Fiber preform according to any one of claims 1 to 14, characterized in that the first resin composition and the second resin composition are identical.
    [0016]
    16. Composite component, characterized by the fact that it can be produced from a fiber preform as defined in any one of claims 1 to 15.
    [0017]
    17. Composite component, characterized by the fact that the wall is made of reinforcement fibers embedded in a polymer matrix, in which the wall has a first surface, a second surface is located opposite the first surface and a thickness extending between the surfaces, and is limited by edges, the wall comprising at least a first zone made of bundles of reinforcement fibers and at least a second zone made of at least one fiber strip comprising at least one filament of reinforcement yarn unidirectionally directed, where the bundles of reinforcement fibers in at least one first zone are oriented in different spatial directions from one another when viewed in a direction parallel to the thickness extension, where each bundle of reinforcement fibers comprises filaments of reinforcement fiber directed parallel to each other and has a length in the range of 3 to 50 mm, where the wall of the composite component has a prop reinforcement fibers greater than 35% by vol, and in which at least a second zone forms a discrete region when viewed in a direction perpendicular to the length of the wall and at least one fiber strip ends with at least one end inside the wall.
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    同族专利:
    公开号 | 公开日
    WO2012072405A1|2012-06-07|
    US8840988B2|2014-09-23|
    KR101945690B1|2019-02-11|
    AU2011335297B2|2014-10-02|
    KR20130121858A|2013-11-06|
    CA2819525A1|2012-06-07|
    JP5808420B2|2015-11-10|
    CN103269845B|2016-04-20|
    ES2617781T3|2017-06-19|
    CA2819525C|2018-10-09|
    US20130244018A1|2013-09-19|
    RU2013129996A|2015-01-10|
    AR084080A1|2013-04-17|
    TW201240789A|2012-10-16|
    EP2646226A1|2013-10-09|
    RU2583017C2|2016-04-27|
    TWI555624B|2016-11-01|
    EP2646226B1|2017-01-11|
    AU2011335297A1|2013-05-02|
    JP2013544310A|2013-12-12|
    BR112013011577A2|2017-10-24|
    CN103269845A|2013-08-28|
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    法律状态:
    2018-04-03| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|
    2019-08-13| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|
    2020-02-27| B25D| Requested change of name of applicant approved|Owner name: TEIJIN CARBON EUROPE GMBH (DE) |
    2020-05-26| B06A| Notification to applicant to reply to the report for non-patentability or inadequacy of the application [chapter 6.1 patent gazette]|
    2020-09-15| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|
    2020-12-08| B16A| Patent or certificate of addition of invention granted|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 11/11/2011, OBSERVADAS AS CONDICOES LEGAIS. |
    优先权:
    申请号 | 申请日 | 专利标题
    EP10193489.1|2010-12-02|
    EP10193489|2010-12-02|
    PCT/EP2011/069939|WO2012072405A1|2010-12-02|2011-11-11|Uni-directional fibre preform having slivers and consisting of reinforcing fibre bundles, and a composite material component|
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