abrasive article, method of abrasion of a workpiece and method of preparing a ceramic shaped abrasiv

专利摘要:
abrasive particles made of ceramic, methods of preparing them and abrasive articles containing them. these are ceramic-shaped abrasive particles that have four main sides joined by six common edges. each of the four main sides comes into contact with three others on the four main sides. the six common edges have substantially equal lengths. methods of preparing a shaped ceramic particle are presented. the shaped abrasive ceramic particles are useful for abrasion of a workpiece surface. an abrasive article includes the shaped ceramic abrasive particles retained in a binder.
公开号:BR112012027030B1
申请号:R112012027030
申请日:2011-04-20
公开日:2020-05-19
发明作者:Givot Maiken；G Schwabel Mark；B Adefris Negus
申请人:3M Innovative Properties Co；
IPC主号:

专利说明:

“ABRASIVE ARTICLE, ABRASION METHOD OF A WORK PIECE AND METHOD OF PREPARING A CERAMIC CONFORMED ABRASIVE PARTICLE”
Technical Field
[001] The present description refers to bonded abrasive articles.
Background
[002] Bonded abrasive articles have abrasive particles bonded to each other via a bonding means. Bonded abrasives include, for example, stones, sharpening stones, grinding wheels and cutting wheels. The bonding medium is typically an organic resin, but it can also be an inorganic material such as ceramic or glass (i.e., glassy bonds).
summary
[003] In one aspect, the present description features a plurality of ceramic shaped abrasive particles, wherein the ceramic shaped abrasive particles have four main sides joined by six common edges, where each of the four main sides comes into contact with three others on the four main sides and the six common edges having substantially equal lengths.
[004] In some embodiments, the ceramic shaped abrasive particles adapt to an abrasive of nominal grade specified in the industry. In some embodiments, at least one of the four main sides is substantially flat. In some embodiments, at least one of the four main sides is concave. In some embodiments, the ceramic shaped abrasive particles comprise alpha alumina. In some embodiments, all four of the main sides are concave. In some embodiments, at least one of the four main sides is convex. In some embodiments, the shaped abrasive particles of ceramic are not shaped like truncated pyramids. In some embodiments, the ceramic shaped abrasive particles have tetrahedral symmetry. In some embodiments, abrasive particles
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2/39 shaped ceramics are substantially shaped like regular tetrahedrons. In some embodiments, the shaped ceramic abrasive particles comprise sol-gel derived alumina. In some embodiments, the shaped ceramic abrasive particles have a coating of inorganic particles thereon.
[005] Abrasive particles shaped from ceramic according to the present description are useful; for example, in the manufacture of abrasive articles and for rubbing a workpiece.
[006] Accordingly, in another aspect, the present description presents a method of abrasion of a workpiece, the method which comprises: contacting by means of friction with at least a portion of the abrasive particles formed from ceramic of a abrasive article, in accordance with the present description, with a workpiece surface; and moving at least one workpiece or abrasive article to abrasion at least a portion of the workpiece surface.
[007] In yet another aspect, the present description features an abrasive article which comprises abrasive particles shaped from ceramic, in accordance with the present description, retained in a binder.
[008] In some embodiments, the binder comprises an organic binder. In some embodiments, the abrasive article comprises a bonded abrasive article. In some embodiments, the binder comprises a phenolic resin. In some embodiments, the binder comprises an inorganic binder. In some embodiments, the binder comprises a glassy binder.
[009] In some embodiments, the abrasive article comprises a bonded abrasive wheel. In some embodiments, the connected abrasive wheel comprises a grinding wheel (including, for example, a central depression grinding wheel) or a cutting wheel. In some embodiments, the abrasive article additionally comprises reinforcement material disposed on main surfaces opposite the connected abrasive wheel. In some embodiments, the abrasive article additionally comprises
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3/39 reinforcement placed only on main surfaces of the connected abrasive wheel. In some embodiments, the abrasive article further comprises crushed abrasive particles (for example, according to an abrasive of nominal grade specified in the industry).
[0010] In yet another embodiment, the present description presents a method of preparing an abrasive particle, the method which comprises:
introducing a dispersion of ceramic precursor into a mold cavity, in which the cavity has three concave walls that meet at a common vertex;
drying the ceramic precursor dispersion and removing it from the cavity to provide a ceramic shaped abrasive particle precursor;
calcining the ceramic shaped abrasive particle precursor; and sintering the calcined ceramic shaped abrasive particle precursor to provide the ceramic shaped abrasive particle, wherein the ceramic shaped abrasive particle has four main sides joined by six common edges, where each of the four main sides comes into contact with three others on the four main sides, where at least three of the four main sides are substantially flat, and where the six common edges are of substantially equal length.
[0011] Advantageously, ceramic shaped abrasive particles, according to the present description, have a high degree of symmetry that reduces the possibility of the abrasive particles being oriented along a given direction (for example, as a result of the manufacturing technique ) which can lead to erratic and / or degraded abrasion.
[0012] For use in the present invention:
The term "substantially equal lengths" in reference to the common edges means that the common edges have lengths within +/- 20 percent of a nominal length;
The term "regular tetrahedron" refers to a tetrahedron that has four equal faces; and
The term “substantially conformed” in reference to a regular tetrahedron
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4/39 means that it has the shape of a regular tetrahedron, except for minor defects (for example, as may occur during manufacture).
[0013] The aforementioned modalities can be implemented in any combination of them, unless such combination is clearly erroneous in view of the teachings of the present description.
[0014] Features and advantages of this description will be understood by considering the detailed description, as well as the attached claims. The Figures and the detailed description which follow more particularly exemplify the illustrative modalities.
Brief Description of Drawings
Figure 1 is a perspective view of an exemplary linked abrasive wheel 100 according to an embodiment of the present description;
Figure 2 is a cross-sectional side view of the exemplary linked abrasive wheel 100 shown in Figure 1 taken along line 2-2;
Figure 3A is a schematic perspective view of an exemplary ceramic shaped abrasive particle 20a;
Figure 3B is a schematic perspective view of an exemplary ceramic shaped abrasive particle 20b;
Figure 3C is a schematic perspective view of an abrasive particle shaped from exemplary ceramic 20c;
Figure 3D is a schematic perspective view of an abrasive particle shaped from exemplary ceramic 20d; and
Figure 3E is a schematic perspective view of an abrasive particle shaped from exemplary ceramic 20e.
[0015] While the Figures identified above demonstrate several modalities of this description, other modalities are also contemplated, as noted in the discussion. In all cases, this description presents the description
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5/39 of representation and not as a way of limitation. It should be understood that numerous other modifications and modalities, which are included in the character and scope of the principles of the description, can be developed by those skilled in the art. Figures may not be drawn to scale. Similar reference numbers can be used in all figures to denote similar parts.
Detailed Description
[0016] Referring now to Figures 1 and 2, the exemplary bonded abrasive wheel 100 according to one embodiment of the present description has a central hole 112 used to secure the bonded abrasive wheel 100 to, for example, an energy driven tool . The bonded abrasive wheel 100 includes shaped ceramic abrasive particles 20, conventionally crushed and sized abrasive particles 30, and binder material 25. The first optional chisel 115 and the optional second chisel 116 are arranged on opposite main surfaces of the bonded abrasive wheel 100.
[0017] The shaped ceramic abrasive particles have four main sides joined by six common edges, where each of the main sides comes into contact with three of the main sides, and where the six common edges have substantially equal lengths. Several modalities that have characteristic formats are covered by the aforementioned description.
[0018] In an exemplary embodiment, shown in Figure 3A, the shaped abrasive particles of ceramic are shaped like regular tetrahedrons. Referring now to Figure 3A, the shaped ceramic abrasive particle 20A has four main sides (81a, 82a 83a, 84a) joined by six common edges (91a, 92a, 93a, 94a, 95a, 96a). Each of the main sides comes into contact with the other three of the main sides at their common edges. For example, the main side 81a comes in contact with the main side 82a at the common edge 95a, the main side 81a comes in contact with the main side 84a at the common edge 91a, and the main side 81a comes in contact with the main side 83a on the common edge 94a. Although a regular tetrahedron (ie, which has six equal edges and four
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6/39 faces) is shown in Figure 3A, it will be recognized that other formats are also permissible. For example, shaped abrasive ceramic particles can be shaped like irregular (i.e., non-regular) tetrahedrons, subject to the restriction that six common edges have substantially equal lengths (defined earlier in this document).
[0019] For example, in another exemplary embodiment, shown in Figure 3B, the shaped abrasive ceramic particles are shaped like quadrilateral particles. Referring now to Figure 3B, the shaped ceramic abrasive particle 20B has four main sides (81b, 82b, 83b, 84b) joined by six common edges (91b, 92b, 93b, 94b). Each of the main sides is concave and comes in contact with the other three main sides at respective common edges. For example, the main side 81b contacts the main side 82b on the common edge 95b, the main side 81b contacts the main side 84b on the common edge 91b, and the main side 81b contacts the main side 83b on the common edge 94b. Although a particle with tetrahedral symmetry (that is, four rotational axes of triple symmetry and six reflective planes of symmetry) is shown in Figure 3B, it will be recognized that other shapes are equally permissible. For example, shaped ceramic abrasive particles may have one, two or three concave faces with the rest being flat, subject to the restriction that six common edges have substantially equal lengths.
[0020] For example, in another exemplary embodiment shown in Figure 3C, the shaped abrasive particles of ceramic are shaped like quadrilateral particles. Referring now to Figure 3C, the shaped ceramic abrasive particle 20C has four main sides (81c, 82c, 83c, 84c) joined by six common edges (91c, 92c, 93c, 94c). Each of the main sides is convex and comes in contact with the other three main sides at respective common edges. For example, the main side 81c contacts the main side 82c on the common edge 95c, the main side 81c contacts the main side 84c on the common edge 91c, and the main side 81c comes into contact with
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7/39 contact with the main side 83c on the common edge 94c. Although a particle with tetrahedral symmetry is shown in Figure 3C, it will be recognized that other shapes are equally permissible. For example, shaped ceramic abrasive particles can have one, two or three convex faces with the rest being flat or concave, subject to the restriction that six common edges have substantially equal lengths.
[0021] In another exemplary embodiment, shown in Figure 3D, the shaped abrasive particles of ceramic are shaped like particles with eight sides, which have four main sides and four smaller sides. Referring now to Figure 3D, the shaped 20D ceramic abrasive particle has four main sides (81d, 82d 83d, 84d) joined by six common edges (91d, 92d, 93d, 94d). Each of the main sides is hexagonal and comes in contact with the other three main sides at respective common edges. For example, the main side 81d contacts the main side 82d on the common edge 95d, the main side 81d contacts the main side 84d on the common edge 91d, and the main side 81d contacts the main side 83d on the common edge 94d. Although a particle with tetrahedral symmetry is shown in Figure 3D, it will be recognized that other shapes are equally permissible. For example, shaped ceramic abrasive particles can have one, two or three convex faces with the rest being flat, subject to the restriction that six common edges have substantially equal lengths.
[0022] Naturally, real deviations from the world of representations idealized in Figures 3A-3D will often be present. Such ceramic shaped abrasive particles are naturally included. Referring now to Figure 3E, the shaped ceramic abrasive particle 20E has four main sides (81e, 82e 83e, 84e) joined by six common edges (91e, 92e, 93e, 94e). Each of the main sides comes into contact with the other three of the main sides at their common edges. For example, the main side 81e comes in contact with the main side 82e at the common edge 95e, the main side 81e comes in contact with the main side 84e at the common edge 91e, and the main side 81e comes in contact with the main side 83e on the common edge 94e.
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[0023] Shaped ceramic abrasive particles may have a combination of the above shaped elements (for example, convex sides, concave sides, irregular sides and flat sides). Similarly, combinations of shaped ceramic abrasive particles having different shapes and or sizes can be used.
[0024] In some embodiments, shaped ceramic abrasive particles can be produced, according to a multi-step process. The process can be carried out using any ceramic precursor dispersion material.
[0025] Briefly, the method comprises the steps of making a seeded or non-seeded ceramic precursor dispersion that can be converted into the corresponding ceramic (for example, a sol-gel bohemite that can be converted to alpha alumina); loading one or more mold cavities which have the desired external shape of the abrasive particle shaped with a dispersion of ceramic precursor, drying the dispersion of ceramic precursor to form abrasive particles shaped from ceramic precursor; removing the shaped abrasive particles of ceramic precursor from the mold cavities; calcining the shaped abrasive particles of ceramic precursor to form shaped abrasive particles of calcined ceramic precursor, and then sintering the shaped abrasive particles of calcined ceramic precursor to form shaped abrasive ceramic particles. The process will now be described in more detail in the context of shaped ceramic abrasive particles containing alpha-alumina.
[0026] The first stage of the process involves a seeded or non-seeded dispersion of a ceramic precursor that can be converted into ceramic. The ceramic precursor dispersion often comprises a liquid that is a volatile component. In one embodiment, the volatile component is water. The abrasive dispersion must comprise a sufficient amount of liquid so that the viscosity of the abrasive dispersion is sufficiently low, allowing to fill the mold cavities and replicate the mold surfaces, but not so much liquid as to cause the subsequent removal of the liquid from the mold.
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9/39 mold cavity, making it prohibitively expensive. In one embodiment, the dispersion of ceramic precursor comprises from 2 percent to 90 percent, by weight, of particles that can be converted into ceramic, such as aluminum oxide monohydrate (bohemian) particles, and at least 10 percent, by weight, or 50 percent to 70 percent, or 50 percent to 60 percent, by weight, of a volatile component such as water. On the other hand, the dispersion of ceramic precursor in some embodiments, contains 30 percent to 50 percent, or 40 percent to 50 percent, by weight, of solids.
[0027] Useful examples for dispersion of ceramic precursor include zirconium oxide sol, vanadium oxide sol, cerium oxide sol, aluminum oxide sol and combinations thereof. Useful aluminum oxide dispersions include, for example, bohemian dispersions and other aluminum oxide hydrate dispersions. Bohemite can be prepared by known techniques or it can be commercially obtained. Examples of bohemian available for sale include products bearing the trade names "DISPERAL", and "DISPAL", both available from Sasol North America, Inc. or "HIQ40" available from BASF Corporation. These aluminum oxide monohydrates are relatively pure, that is, they include relatively few hydrate phases, if any, other than monohydrates, and have a high surface area.
[0028] The physical properties of the resulting ceramic shaped abrasive particles will, in general, depend on the type of material used in the dispersion of ceramic precursor. For use in the present invention, a "gel" is a three-dimensional network of solids dispersed in a liquid.
[0029] The ceramic precursor dispersion may contain a modifying additive or precursor of a modifying additive. The modifying additive can work to improve some desirable properties of the abrasive particles or to increase the effectiveness of the subsequent sintering step. Modification additives or modification additive precursors can be in the form of soluble salts, typically water-soluble salts. They typically consist of a metal-containing compound and can be a precursor to oxide
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10/39 magnesium, zinc, iron, silicon, cobalt, nickel, zirconium, hafnium, chromium, yttrium, praseodymium, samarium, ytterbium, neodymium, lanthanum, gadolinium, cerium, dysprosium, erbium, titanium and mixtures thereof. The particular concentrations of these additives that may be present in the dispersion of ceramic precursor can be varied based on skill in the art.
[0030] Typically, the introduction of a modifying additive or precursor to a modifying additive will induce the dispersion of ceramic precursor to gel. The dispersion of ceramic precursor can also be induced into gel by applying heat over a period of time to reduce the liquid content in the dispersion through evaporation. The ceramic precursor dispersion may also contain a nucleating agent. Nucleating agents suitable for this description include fine particles of alpha alumina, ferric alpha oxide or its precursor, titanium and titanate oxides, chromium oxides or any other material that will nuclear the transformation. The amount of nucleating agent, if used, must be sufficient to effect the transformation of alpha alumina. The nucleation of such alpha alumina precursor dispersions is disclosed in U.S. Patent No. 4,744,802 (Schwabel).
[0031] The peptizing agent can be added to the ceramic precursor dispersion to produce a more stable hydrosol or colloidal ceramic precursor dispersion. Suitable peptizing agents are monoprotic acids or acid compounds such as acetic acid, hydrochloric acid, formic acid and nitric acid. Multiprotic acids can also be used, but they can quickly gel the dispersion of ceramic precursor, making it difficult to handle or introduce additional components to it. Some commercial bohemian sources contain an acidic titration (such as absorbed formic acid or nitric acid) that will assist in the formation of a stable ceramic precursor dispersion.
[0032] The dispersion of ceramic precursor can be formed by any suitable means; for example, in the case of an alumina precursor sol-gel, by simply mixing aluminum oxide monohydrate with water containing a peptizing agent or forming an aluminum oxide monohydrate slurry to which the
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11/39 peptizing agent is added.
[0033] Foam eliminators or other suitable chemicals can be added to reduce the tendency to bubble or enter air under mixing. Additional chemicals such as wetting agents, alcohols or binding agents can be added if desired.
[0034] The second step of the process involves providing a mold that has at least one mold cavity and preferably a plurality of cavities formed on at least one main mold surface. In some embodiments, the mold is formed as a production tool, which can be, for example, a mat, a blade, a continuous mat, a coating cylinder such as a gravure cylinder, a sleeve mounted on a coating cylinder or a dye. In one embodiment, the production tool comprises polymeric material. Examples of suitable polymeric materials include thermoplastics such as polyesters, polycarbonates, poly (sulfone ether), poly (methyl methacrylate), polyurethanes, polyvinyl chloride, polyolefin, polystyrene, polypropylene, polyethylene or combinations thereof, or heat-cured materials. In one embodiment, all printing is made of a polymeric or thermoplastic material. In another embodiment, the surfaces of the stamping in contact with the dispersion of ceramic precursor during washing, such as the surfaces of the plurality of cavities, comprise polymeric or thermoplastic materials and other portions of stamping can be produced from other materials. A suitable polymeric coating can be applied to a metallic stamping to change its surface tension properties as an example.
[0035] A polymeric or thermoplastic production tool can be replicated from a metal master tool. The master tool will have a pattern opposite to that desired for the production tool. The master tool can be produced in the same way as the production tool. In one embodiment, the master tool is made of metal, for example, nickel and is turned by diamond. In one embodiment, the master tool is at least partially formed using stereolithography. THE
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12/39 polymeric laminar material can be heated together with the master tool such that the polymeric material is embossed with the standard master tool by pressing both. A polymeric or thermoplastic material can also be extruded or molded on the master tool and then pressed. The thermoplastic material is cooled to solidify and produce the production tool. If a thermoplastic production tool is used, then care must be taken not to generate excessive heat that could distort the thermoplastic production tool, limiting its life. More information regarding the design and manufacture of production stamping or master tools can be found in U.S. Patent No. 5,152,917 (Pieper et al.); 5,435,816 (Spurgeon et al.); 5,672,097 (Hoopman et al.); 5,946,991 (Hoopman et al.); 5,975,987 (Hoopman et al.); and 6,129,540 (Hoopman et al.).
[0036] Access to the cavities can be from an opening on the top surface or on the bottom surface of the mold. In some cases, the cavities can extend over a whole thickness of the mold. Alternatively, the cavities can extend only a portion of the mold thickness. In one embodiment, the top surface is substantially parallel to the bottom surface of the mold, with the cavities having a substantially uniform depth. At least one side of the mold, that is, the side on which the cavities are formed, can remain exposed to the surrounding atmosphere during the step in which the volatile component is removed.
[0037] The cavities have a specified three-dimensional shape to produce the shaped abrasive particles of ceramic. The depth dimension is equal to the perpendicular distance from the top surface to the lowest point on the bottom surface. The depth of a given cavity can be uniform or can vary over its length and / or width. The cavities of a given mold can be of the same or different shapes.
[0038] The third step of the process involves loading the cavities in the mold with the dispersion of ceramic precursor (for example, by a conventional technique). In some
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13/39 embodiments, a knife cylinder coating application device or vacuum crack matrix coating application device may be used. A mold release can be used to assist in removing particles from the mold, if desired. Typical mold release agents include oils such as peanut oil or mineral oil, fish oil, silicones, polytetrafluoro ethylene, zinc stearate and graphite. In general, the mold release agent such as peanut oil, in a liquid, such as water or alcohol, is applied to the surfaces of the production stamping in contact with the ceramic precursor dispersion in such a way that between about 0.6 mg / cm ² (0.1 mg / inch ² ) to about 20 mg / cm ² (3.0 mg / inch ² ), or between about 0.6 mg / cm ² (0.1 mg / inch ² ) about 30 mg / cm ² (5.0 mg / inch ² ) of the mold release agent is present per unit area of the mold when a mold release is desired. In some embodiments, the top surface of the mold is coated with the ceramic precursor dispersion. The ceramic precursor dispersion can be pumped over the top surface.
[0039] Subsequently, a scraper or leveling bar can be used to force the dispersion of the ceramic precursor completely into the mold cavity. The remaining portion of the ceramic precursor dispersion that does not enter the cavity can be removed from the top surface of the mold and recycled. In some embodiments, a small portion of the ceramic precursor dispersion may remain on the top surface, and in other embodiments, the top surface is substantially free of dispersion. The pressure applied by the scraper or leveling bar is typically less than 0.6 MPa (100 psi), less than 0.3 MPa (50 psi), or even less than 60 kPa (10 psi (60 kPa). In some embodiments, no exposed surface of the ceramic precursor dispersion extends substantially beyond the top surface.
[0040] In these modalities, where it is desired to have the exposed surfaces of the cavities, result in flat faces of the shaped ceramic abrasive particles, it may be desirable to fill the cavities (for example, with the use of a set of microbocals) and slowly dry the ceramic precursor dispersion.
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[0041] The fourth step of the process involves removing the volatile component to dry the dispersion. Desirably, the volatile component is removed by rapid evaporation rates. In some embodiments, the removal of the volatile component through evaporation occurs at temperatures above the boiling point of the volatile component. An upper limit for the drying temperature often depends on the material from which the mold is made. For the polypropylene matrix, the temperature must be lower than the melting point of the plastic. In one embodiment, for a water dispersion of between about 40 to 50 percent solids and a polypropylene mold, drying temperatures can be between about 90 ° C to about 165 ° C, or between about 105 ° C to about 150 ° C, or between about 105 ° C to about 120 ° C. Higher temperatures can lead to improved production speeds, but it can also lead to degradation of the polypropylene matrix, limiting its useful life as a mold.
[0042] During drying, the dispersion of ceramic precursor shrinks, often causing the cavity walls to retract. For example, if the cavities have flat walls, then the resulting ceramic shaped abrasive particles may tend to have at least three main concave sides. It has been found that by preparing the walls of the concave cavity (so that the volume of the cavity is increased) it is possible to obtain shaped abrasive ceramic particles that have at least three substantially flat main sides. The degree of concavity required, in general, depends on the solids content of the ceramic precursor dispersion.
[0043] The fifth step of the process involves removing shaped abrasive particles of ceramic precursor resulting from the mold cavities. Abrasive particles formed from ceramic precursor can be removed from the cavities using the following processes, alone or in combination in the mold: gravity, vibration, ultrasonic vibration, vacuum, or pressurized air to remove particles from the mold cavities.
[0044] Shaped abrasive particles of ceramic precursor can be
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15/39 additionally dried out of the mold. If the dispersion of the ceramic precursor is dried to the desired level in the mold, this additional drying step will not be necessary. However, in some cases, it may be more economical to employ this additional drying step in order to minimize the time that the ceramic precursor dispersion remains in the mold. Typically, the abrasive particles formed from ceramic precursor will be dried for 10 to 480 minutes, or 120 to 400 minutes, at a temperature of 50 ° C to 160 ° C, or 120 ° C to 150 ° C.
[0045] The sixth stage of the process involves the calcination of abrasive particles formed from ceramic precursor. During calcination, essentially all the volatile material is removed and the various components that are present in the ceramic precursor dispersion are transformed into metal oxides. Abrasive particles formed from ceramic precursor are, in general, heated to a temperature of 400 ° C to 800 ° C, and kept within this temperature range until free water and more than 90 weight percent of any material bound volatile are removed. In an additional step, it may be desirable to introduce the modifying additive through an impregnation process. A water-soluble salt can be introduced by impregnating the pores of the abrasive particles formed from calcined ceramic precursor. Then, the shaped abrasive particles of ceramic precursor are again preheated. This option is further described in U.S. Patent No. 5,164,348 (Wood).
[0046] The seventh stage of the process involves the sintering of the abrasive particles formed from calcined ceramic precursor to form ceramic particles. Before sintering, the calcined ceramic precursor shaped abrasive particles are not completely densified and therefore do not contain the desired hardness content to be used as ceramic shaped abrasive particles. Sintering takes place by heating the abrasive particles formed from precursor calcined ceramics to a temperature from 1000 ° C to 1650 ° C. The time period in which the abrasive particles formed from calcined ceramic precursor must be exposed to the sintering temperature to achieve this level of conversion depends on several
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16/39 factors, but usually, from five seconds to 48 hours is typical.
[0047] In another mode, the duration for the sintering stage is in the range of one minute to 90 minutes. After sintering, the shaped ceramic abrasive particles can have a Vickers hardness of 10 GPa (gigaPascal), 16 GPa, 18 GPa, 20 GPa or greater.
[0048] Other steps can be used to modify the described process, such as, for example, quickly heating the material from the calcination temperature to the sintering temperature, centrifuging the ceramic precursor dispersion to remove sediment and / or residues. In addition, the process can be modified by combining two or more process steps, if desired. The conventional process steps that can be used to modify the process of that description are more fully described in U.S. Patent No. 4,314,827 (Leitheiser).
[0049] Shaped ceramic abrasive particles composed of alpha alumina crystallites, magnesium alumina spinel, and a rare earth hexagonal aluminate can be prepared using the sol-gel precursor alpha alumina particles according to the methods described , for example, in US patent No. 5,213,591 (Celikkaya et al.) and published patent application US No. European Patent Nos. 2009/0165394 A1 (Culler et al.) And 2009/0169816 A1 (Erickson et al.). Abrasive alpha alumina grains may contain zirconia as disclosed in U.S. Patent No. 5,551,963 (Larmie). Alternatively, the abrasive grains of alpha alumina may have a microstructure or additives as disclosed in U.S. Patent No. 6,277,161 (Castro). More information related to methods for making shaped ceramic abrasive particles is presented in U.S. co-pending published patent application No. No. 2009/0165394 Al (Culler et al.).
[0050] The ceramic shaped abrasive particles used in the present description can typically be made using tools (i.e. molds) cut using diamond stamping, which provides a more defining characteristic
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17/39 high than other manufacturing alternatives, such as stamping or punching. Typically, the cavities on the tool surface have flat faces that meet along sharp edges, and form the sides of a regular tetrahedron. The resulting ceramic shaped abrasive particles have a respective nominal standard shape that corresponds to the shape of cavities on the tool surface (for example, random variations) of the nominal standard shape can occur during manufacture, and the ceramic shaped abrasive particles that exhibit such Variations are included in the definition of shaped ceramic abrasive particles as used in this document.
[0051] Shaped abrasive ceramic particles can include particles that have various shape characteristics. For example, a ceramic-shaped abrasive particle can have one or more main sides that are convex, flat, concave or another shape, and common edges that are curved or linear. The shaped abrasive ceramic particles may also include particles of different individual shapes, but which have four sides joined by six common edges. Optionally, the main sides can be smooth and / or they can have cavities or protuberances in them; for example to provide additional sharp edges.
[0052] Figures 3A-3E describe several exemplary modalities of shaped abrasive ceramic particles, in accordance with the present description.
[0053] In an exemplary embodiment, the shaped ceramic abrasive particles can be shaped like a regular tetrahedron as shown in Figure 3A. Consequently, the shaped ceramic abrasive particle 20a has four congruent flat main sides 81a, 82a, 83a and 84a joined by six common edges 91a, 92a, 93a, 94a, 95a and 96a.
[0054] In another exemplary embodiment, the shaped abrasive particles of ceramic can be shaped as shown in Figure 3B. Consequently, the shaped ceramic abrasive particle 20b has four concave main sides 81b, 82b, 83b and 84b joined by six common edges 91b, 92b, 93b,
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94b, 95b and 96b.
[0055] In yet another exemplary embodiment, the shaped abrasive particles of ceramic can be shaped as shown in Figure 3C. Consequently, the shaped ceramic abrasive particle 20c has four convex leading sides 81c, 82c, 83c and 84c joined by six common edges 91c, 92c, 93c, 94c, 95c and 96c.
[0056] In yet another exemplary embodiment, the shaped abrasive ceramic particles can be shaped like a truncated tetrahedron in which the vertices are as shown in Figure 3D. Consequently, the shaped ceramic abrasive particle 20d has four flat main sides 81d, 82d, 83d and 84d joined by six common edges 91d, 92d, 93d, 94d, 95d and 96d of substantially equal lengths.
[0057] In yet another exemplary embodiment, the shaped abrasive ceramic particles can be substantially shaped like a truncated tetrahedron, in which one or more vertices and / or common edges are deformed, for example, as a result of manufacturing defects as shown in Figure 3E. Consequently, the shaped abrasive ceramic particle 20e has four main sides 81e, 82e, 83e and 84e joined by six common edges 91e, 92e, 93e, 94e, 95e and 96e of substantially equal lengths.
[0058] Surface coatings on ceramic shaped abrasive particles can be used to improve adhesion between ceramic shaped abrasive particles and a binder material in abrasive articles, or can be used to assist in electrostatic deposition of ceramic shaped abrasive particles . In one embodiment, surface coatings, as described in U.S. Patent No. 5,352,254 (Celikkaya) in an amount of 0.1 to 2 percent coating surface for the shaped abrasive particle weight, can be used. Such surface coatings are described in U.S. Patent No. 5,213,591 (Celikkaya et al.); No. 5,011,508 (Wald et al.); No. 1,910,444 (Nicholson); No. 3,041,156 (Rowse et al.); n ° 5,009,675
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19/39 (Kunz et al.); No. 5,085,671 (Martin et al.); No. 4,997,461 (Markhoff-Matheny et al.); and No. 5,042,991 (Kunz et al.). In addition, the surface coating can prevent welding or adhesion of the shaped abrasive particle. Welding or Adhesion is the term to describe the phenomenon in which metal particles from the workpiece being scraped become welded to the tops of the shaped abrasive ceramic particles. Surface coatings for performing the above functions are known to those skilled in the art.
[0059] Typically, ceramic shaped abrasive particles have a relatively small maximum particle size; for example, less than about 5 mm, 2 mm, 1 mm, 5 micrometers, 200 micrometers, 100 micrometers, 50 micrometers, 20 micrometers or even less than 10 micrometers, although other sizes can be used.
[0060] In some embodiments, the ceramic shaped abrasive particles (and optionally any additional abrasive particles conventionally ground) are sized according to an industry-specified specified grade abrasive. Exemplary classification standards recognized by the abrasives industry include those promulgated by the ANSI (American National Standards Institute), FEPA (Federation of European Producers of Abrasives), and JIS (Japanese Industrial Standard). Such industry-accepted graduation standards include, for example: ANSI 4, ANSI 6, ANSI 8, ANSI 16, ANSI 24, ANSI 30, ANSI 36, ANSI 40, ANSI 50, ANSI 60, ANSI 80, ANSI 100, ANSI 120 , ANSI 150, ANSI 180, ANSI 220, ANSI 240, ANSI 280, ANSI 320, ANSI 360, ANSI 400, and ANSI 600; FEPA P8, FEPA P12, FEPA P16, FEPA P24, FEPA P30, FEPA P36, FEPA P40, FEPA P50, FEPA P60, FEPA P80, FEPA P100, FEPA P120, FEPA P150, FEPA P180, FEPA P220, FEPA P320, FEPA P400 , FEPA P500, FEPA P600, FEPA P800, FEPA P1000, and FEPA P1200; and JIS 8, JIS 12, JIS 16, JIS 24, JIS 36, JIS 46, JIS 54, JIS 60, JIS 80, JIS 100, JIS 150, JIS 180, JIS 220, JIS 240, JIS 280, JIS 320, JIS 360, JIS 400, JIS 400, JIS 600, JIS 800, JIS 1000, JIS 1500, JIS 2500, JIS 4000, JIS 6000, JIS 8000, and JIS 10,000. More typically,
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20/39 ceramic shaped abrasive particles are independently dimensioned according to the classification standards for ANSI 60 and 80 or FEPA P60 and P80.
[0061] The term “rated, specified, industry-recognized abrasives” also includes selected, specified, industry-recognized grade abrasives. For example, the selected, specified, nominal grade may use US standard test sieves, according to ASTM E-11-09 “Standard Specification for Wire Cloth and Sieves for Testing Purposes”. The ASTM E-11-09 standard prescribes the requirements for the design and construction of test sieves using a woven wire cloth medium mounted on a structure for the classification of materials, according to a designated particle size. A typical designation can be represented as -18 + 20, which means that shaped ceramic abrasive particles pass through an ASTM E-11-09 test sieve that meets the standard specifications for the number 18 sieve and are retained in a test sieve that meets the specifications of the ASTM E-11-09 standard for the number 20 sieve. In one embodiment, the shaped ceramic abrasive particles have a particle size of at least 90 percent so that most particles pass through a screen test screen 18 and can be retained in a screen test screen 20, 25, 30, 35, 40, 45 or 50. In various embodiments, the shaped abrasive particles of ceramic can have a selected degree nominal comprising: -18 + 20, -20 / + 25, -25 + 30, -30 + 35, -35 + 40, 5 40 + 45, -45 + 50, -50 + 60, -60 + 70, -70 / + 80, -80 + 100, -100 + 120, -120 + 140, -140 + 170, -170 + 200, 200 + 230, -230 + 270, -270 + 325, -325 + 400, -400 + 450, -450 + 500, or -500 + 635.
[0062] Bonded abrasive articles (e.g., grinding wheel, cutting wheels, sharpening wheels and sharpening stones) according to the present description are typically made by a molding process. During molding, a precursor binder material, organic liquid, inorganic powder or organic powder, is mixed with the abrasive particles. In some cases, a liquid medium (resin or a solvent) is first applied to the abrasive particles to moisten their outer surface, and then the moistened particles are mixed with a powdered medium. Bonded abrasive articles,
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21/39 according to the present description, can be made by compression modeling, injection modeling, transfer modeling or the like. Molding can be completed by hot or cold compression or in any manner known to those skilled in the art.
[0063] The binder material typically comprises a glassy inorganic material (for example, as in the case of vitrified abrasive wheels), metal, or an organic resin (for example, as in the case of resin-bonded abrasive wheels).
[0064] Glassy inorganic binders can be produced from a mixture of different metal oxides. Examples of such glassy metal oxide binders include silica, alumina, limestone, iron oxide, titanium oxide, magnesia, sodium oxide, potassium oxide, lithium oxide, manganese oxide, boron oxide, phosphorus oxide, and the like . Examples of specific vitreous binders based on weight include, for example, 47.61 percent SiO2, 16.65 percent ALO3, 0.38 percent Fe2 O3, 0.35 percent TiO2, 1.58 percent CaO, 0.10 percent MgO, 9.63 percent Na2O, 2.86 percent K2O, 1.77 percent U2O, 19.03 percent B2O3, 0.02 percent MnO2 and 0.22 percent P2O5; and 63 percent SiO2, 12 percent ALO3, 1.2 percent CaO, 6.3 percent Na2O, 7.5 percent K2O and 10 percent B2O3. Still other examples of vitreous binders based on a molar ratio include 3.77 percent SiO2, 0.58 percent ALO3, 0.01 percent Fe2O3, 0.03 percent TiO2, 0.21 percent CaO, 0.25 percent MgO, 0.47 percent Na2O and 0.07 percent K2O. During the manufacture of a vitreous bonded abrasive article, the vitreous binder, in a powder form, can be mixed with a temporary binder, typically an organic binder. Vitrified binders can also be formed from a frit, for example anywhere from about one to 100 percent frit, but in general, 20 to 100 percent frit. Some examples of common materials used in frit binders include feldspar, borax, quartz, soda ash, zinc oxide, bleaching agent, antimony trioxide, carbon dioxide
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22/39 titanium, sodium silicofluoride, flint, cryolite, boric acid and combinations thereof. These materials are usually mixed together as powders, heated to melt into the mixture, and then the molten mixture is cooled. The cooled mixture is crushed and selected until it becomes a very fine powder to then be used as a frit binder. The temperature at which these fry connections are matured depends on their chemistry, but can be in the range of about 600 ° C to about 1800 ° C.
[0065] Examples of metal binders include tin, copper, aluminum, nickel and combinations thereof.
[0066] Organic binder materials are typically included in an amount of 5 to 30 percent, more typically 10 to 25, and more typically 15 to 24 percent, by weight, based on the total weight of the bonded abrasive article. Phenolic resin is the most commonly used organic binder material, and can be used in powder or liquid form. Although phenolic resins are widely used, it is within the scope of this description to use other organic binder materials including, for example, epoxy resins, urea-formaldehyde resins, rubbers, gum, and acrylic binders. Organic bonding materials can also be modified with other bonding materials to optimize or change their properties.
[0067] Useful phenolic resins include novolaca and resolica phenolic resins. Novolac phenolic resins are characterized by being catalyzed by acid and have a ratio between formaldehyde and phenol less than one, typically between 0.5: 1 and 0.8: 1. Resolutions phenolic resins are characterized by being catalyzed by alkali and having a formaldehyde to phenol ratio greater than or equal to one, typically from 1: 1 to 3: 1. Novolac and resolica phenolic resins can be chemically modified (for example, by reaction with epoxy compounds), or they can be unmodified. Exemplary acid catalysts suitable for curing phenolic resins include sulfuric, hydrochloric, phosphoric, oxalic acids and p-toluenesulfonic acids. Alkaline catalysts suitable for curing phenolic resins include sodium hydroxide, barium hydroxide,
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23/39 potassium hydroxide, calcium hydroxide, organic amines, or sodium carbonate.
[0068] Phenolic resins are well known and are easily available from commercial sources. Examples of commercially available novolac resins include DUREZ 1364, a two-stage phenolic powder resin (marketed by Durez Corporation of Addison, TX under the trade name VARCUM (eg 29302), or HEXION resin AD5534 (marketed by Hexion Specialty Chemicals , Inc., Louisville, Kentucky.) Examples of commercially available phenolic resins useful in the practice of this description include those sold by Durez Corporation of Addison, Texas under the trade name VARCUM (e.g. 29217, 29306, 29318, 29338, 29353 ), those marketed by Ashland Chemical Co. of Bartow, Florida under the trade name AEROFENE (for example, AEROFENE 295), and those marketed by Kangnam Chemical Company Ltd. of Seoul, South Korea under the trade name “PHENOLITE” (for example, PHENOLITE TD-2207).
[0069] The curing temperatures of precursors of organic binder material will vary with the chosen material and wheel model. The selection of suitable conditions is within the capacity of an element skilled in the art. Exemplary conditions for a phenolic binder may include an applied pressure of about 21.9 MPa (20 tonnes per 4 inches in diameter (224 kg / cm ² )) at room temperature followed by heating to temperatures up to about 185 ° C for enough time to cure the precursor to organic binder material.
[0070] In some embodiments, bonded abrasive articles include about 10 to 60 weight percent of shaped abrasive ceramic particles; typically 30 to 60 weight percent, and more typically 40 to 60 weight percent, based on the total weight of the binder material and abrasive particles.
[0071] Bonded abrasive articles may further comprise crushed abrasive particles (ie, abrasive particles that do not result from the breaking of the shaped ceramic abrasive particles and correspond to an abrasive specified in
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24/39 industry, nominal, graduated or combinations thereof). Crushed abrasive particles are typically of a finer degree or degrees of size (for example, if a plurality of degrees of sizes are used) than ceramic shaped abrasive particles, although this is not a requirement.
[0072] Useful ground abrasive particles include, for example, ground particles of molten aluminum oxide, brown molten aluminum oxide, heat-treated aluminum oxide, white molten aluminum oxide, ceramic aluminum oxide materials, such as those commercially available under the trade name 'CUBITRON' with the 3M Company of St. Paul, Minnesota, USA), black silicon carbide, green silicon carbide, titanium diboride, boron carbide, tungsten carbide, aluminum oxide nitride, titanium carbide , diamond, cubic boron nitride, garnet, fused alumina zirconia, aluminum oxinitride, abrasive particles derived from sol-gel, iron oxide, chromium, ceria, zirconia, titanium oxide, silicates, tin oxide, silica (as quartz, glass spheres, glass bubbles and glass fibers), silicates (such as talc, clays (eg montmorillonite), feldspar, mica, calcium silicate, calcium metasilicate, aluminosilica sodium silicate), flint and emery. Examples of abrasive particles derived from sol-gel can be found in U.S. Patent No. 4,314,827 (Leitheiser et al.), No. 4,623,364 (Cottringer et al.); No. 4,744,802 (Schwabel), No. 4,770,671 (Monroe et al.); and No. 4,881,951 (Monroe et al.). It is also contemplated that the abrasive particles could comprise abrasive agglomerates such as, for example, those described in U.S. Patent No. 4,652,275 (Bloecher et al.) Or No. 4,799,939 (Bloecher et al.).
[0073] Abrasive particles can, for example, be distributed evenly or non-uniformly across the bonded abrasive article. For example, if the connected abrasive wheel is a grinding wheel or a cutting wheel, the abrasive particles can be concentrated towards the medium (for example, located away from the outer faces of a cutting or grinding wheel), or just on the outer edge, that is, the periphery, of a wheel
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25/39 cutting or shredding. In another variation, first the abrasive particles can be on one side of the wheel and the different abrasive particles on the opposite side. Typically, however, all abrasive particles are evenly distributed in relation to each other, because the manufacture of the wheels is easier and the cutting effect is optimized when the two types of abrasive particles are positioned in close proximity to each other.
[0074] Abrasive articles bonded in accordance with the present description may comprise additional abrasive particles in addition to those mentioned above, provided that the weight range requirements of the other constituents are complied with. Examples include fused aluminum oxide (including fused alumina-zirconia), brown aluminum oxide, blue aluminum oxide, silicon carbide (including green silicon carbide), garnet, diamond, cubic boron nitride, boron carbide, chrome, and combinations thereof.
[0075] The abrasive particles can optionally be treated with one or more coupling agents to improve the adhesion of the abrasive particles to the binder. Abrasive particles can be treated with the coupling agent (s) before being combined with the binder material, or can have their surfaces treated locally by adding a coupling agent to the binder material. Coupling agents are well known to those skilled in the abrasion technique. Examples of coupling agents include organosilane coupling agents (e.g., gamma-aminopropyltriethoxysilane), titanates and zirconates.
[0076] In some embodiments, bonded abrasive articles according to the present description contain additional crushing aid elements such as polytetrafluoro ethylene particles, cryolite, sodium chloride, FeS2 (iron disulfide) or KBF4 ; typically in proportions of 1 to 25 percent by weight, more typically 10 to 20 percent by weight, subject to the weight range requirements of the other constituents being met. Crushing aid elements are added to optimize the cutting characteristics of bonded abrasives (for example, when used dry without coolant), in general, by
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26/39 means of reducing the temperature of the cutting interface. The crushing aid element may be in the form of single particles or an agglomerate of crushing aid particles. Examples of precisely shaped crushing aid particles are taught in U.S. publication application No. 2002/0026752 A1 (Culler et al.).
[0077] The binding material can optionally contain one or more plasticizers, such as, for example, available as SANTICIZER 154 PLASTICIZER from UNIVAR USA, Inc. of Chicago, Illinois, USA.
[0078] Bonded abrasive articles, in accordance with the present description, may contain additional components, such as filler particles, provided that the weight range requirements of the other constituents are complied with. The filler particles can be added to take up space and / or provide porosity. Porosity allows the bonded abrasive article to spill worn or worn abrasive particles to expose new or fresh abrasive particles.
[0079] Bonded abrasive articles according to the present description can have any range of porosity, for example, from about 1 percent to 50 percent, typically from 1 percent to 40 percent, by volume. Examples of fillers include bubbles and microspheres (e.g., glass, ceramic (alumina), clay, polymeric, metal), stopper, natural plaster, marble, limestone, flint, silica, aluminum silicate and combinations thereof.
[0080] Bonded abrasive articles in accordance with the present description can be made according to any suitable method. In a suitable method, the shaped abrasive ceramic particles are coated with a coupling agent before being mixed with a curable resolvable phenolic. The amount of binding agent is, in general, selected in such a way that it is present in an amount of 0.1 to 0.3 part for every 50 to 84 parts of abrasive particles, although quantities outside this range can also be used . The resulting mixture is added with liquid resin, as well as curable novolac phenolic resin and cryolite. The mixture is pressed into a mold (for example, at an applied pressure of 21.9 MPa (20 tons by 4 inches in diameter 224 kg / cm ² )) to
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27/39 room temperature. The molded wheel is then cured by heating to temperatures up to about 185 ° C long enough to cure the curable phenolic resins.
[0081] Abrasive articles bonded according to the present description are useful, for example, as grinding wheels and cutting wheels.
[0082] Milling wheels typically have a thickness of 0.5 cm to 100 cm, more typically 1 cm to 10 cm, and typically have a diameter between about 1 cm and 100 cm, more typically between about 10 cm and 100 cm, although other dimensions can also be used. For example, bonded abrasive articles can be in the form of a wheel cup, usually between 10 and 15 cm in diameter, or it can be in the form of a “snagging” wheel up to 100 cm in diameter, or it can also be in the form of a grinding wheel with central depression up to about 25 cm in diameter. An optional central hole can be used to attach the cutting wheel to an electrically driven tool. If present, the central hole is typically 0.5 cm to 2.5 cm in diameter, although other sizes can be used. The optional central hole can be reinforced; for example, by a metal flange. Alternatively, a mechanical lock can be attached axially to a surface of the cutting wheel. Examples include threaded places.
[0083] Cutting wheels typically have a thickness of 0.80 mm (mm) to 16 mm, more typically 1 mm to 8 mm, and typically have a diameter between 2.5 cm and 100 cm (40 inches), more typically between about 7 cm and 13 cm, although other dimensions can also be used. An optional central hole can be used to attach the cutting wheel to an electrically driven tool. If present, the central hole is typically 0.5 cm to 2.5 cm in diameter, although other sizes can be used. The optional central hole can be reinforced; for example, by a metal flange. Alternatively, a mechanical lock can be attached axially to a surface of the cutting wheel. Examples include rowed columns, rowed nuts, Tinnerman nuts, and bayonet support columns.
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28/39
[0084] Optionally, the abrasive articles bonded according to the present description may additionally comprise a talagra that reinforces the bonded abrasive article; for example, arranged on one or two main surfaces of the bonded abrasive article or arranged within the bonded abrasive article. Examples of dowels include a woven or knitted cloth. The fibers in the talagarça can be made of glass fibers (for example, plastic with fiberglass reinforcement), organic fibers, such as polyamide, polyester or polyimide. In some cases, it may be desirable to include textile reinforcing fibers within the bonding medium, so that the fibers are evenly dispersed throughout the bonded abrasive article.
[0085] Abrasive articles bonded according to the present description are useful, for example, for abrasion of a workpiece. For example, they can be turned into shredding or cutting wheels that have good shredding characteristics while maintaining a relatively low operating temperature that can prevent thermal damage to the machining part.
[0086] The attached abrasive grinding wheels can be used in any right angle grinding tool, such as those available from Ingersoll-Rand, Sioux, Milwaukee, USA and Cooper Power Tools of Lexington, South Carolina, USA . The tool can be electrically or pneumatically driven, usually at speeds of around 1000 to 50000 RPM.
[0087] During use, the bonded abrasive wheel can be used dry or wet. During wet grinding, the connected abrasive wheel is used in conjunction with water, oil-based lubricants or water-based lubricants. Alloyed abrasive wheels according to the present description can be particularly useful in various workpiece materials such as, for example, carbon steel bar or blade and more exotic metals (for example, stainless steel or titanium), or on softer ferrous metals (for example, mild steel, low alloy blades, or cast irons).
[0088] The objectives and advantages of this description are further illustrated
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29/39 by the following non-limiting examples, but the specific materials and their proportions mentioned in these examples, as well as the other conditions and details, should not be understood as unduly limiting this description.
Examples
[0089] Except where otherwise specified, all parts, percentages, ratios, etc. in the examples and the rest of the specification are by weight. In the tables in the Examples, “NA” means not applicable.
Materials used in the examples
Table 1
ABBREVIATION DESCRIPTION SAPn Abrasive particles conformed as described in Table 2 AP1 Ceramic alumina abrasive particles with modified surface, grade 36, obtained as CUBITRON 324AV available from 3M, St. Paul, Minnesota, USA AP2 Abrasive aluminum oxide particles, ANSI grade 60 CX, obtained from Washington Mills Electro Minerals, Niagara Falls, New York, USA. AP3 Ceramic alumina abrasive particles derived from sol-gel, grade 80, obtained as CUBITRON 321 available from 3M, St. Paul, Minnesota, USA AP4 Abrasive particles of ceramic alumina derived from sol-gel, grade 50, obtained as CUBITRON 324AV available from 3M, St. Paul, Minnesota, USA CRY Synthetic cryolite (Na3AlF6), obtained as RTN CRYOLITE fromTR International Trading Co. of Houston, Texas, USA PR1 A one-stage liquid phenolic resin, obtained as VARCUM 29353 from Durez Corp. from Addison, Texas, USA PR2 The two-stage phenolic powder resin, obtained as VARCUM 29302 from Durez Corp. SM 10 cm (4-inch) diameter fiberglass discs, obtained as 3321 from Industrial Polymers & Chemicals of Shrewsbury, Massachusetts, USA
Description of Molds Used for the Manufacture of Abrasive Shaped Ceramic Particles SAP1-SAP3
[0090] The molds used to manufacture the SAP1 - SAP3 particles were generated by a rapid prototyping device known as a PERFACTORY SXGA + W / ERM MINI MULTI LENS stereolithography device produced by envisionTEC GmbH in Gladbeck, Germany. The envisionTEC machine was configured with
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30/39 a projector lens that has a focus distance of 60 mm. The resin used to build these molds was envisionTEC R5. For SAP1, the regular tetrahedral cavities had an edge length of 3 mm. For SAP3, the regular tetrahedral cavities had an edge length of 2 mm. For SAP2, the regular tetrahedron had an edge length of 3 mm with lateral faces with a central bulge of 0.14 mm for each lateral cavity (that is, in each of the three cavity walls and resulting in a concavity in the corresponding face of the abrasive particle.).
Description of Molds Used for the Manufacture of Abrasive Shaped Ceramic Particles SAP4-SAP5
[0091] The molds used to manufacture the SAP4 particles were a matrix of regular tetrahedral cavities with openings in the shape of an equilateral triangle in closed packaging (side length (step) = 0.9429 mm). Each regular tetrahedral cavity has a depth of 0.8171 mm and a pull angle of 77.5 degrees. The deposit area between the openings was 0.0508 mm apart.
[0092] The mold used to manufacture the SAP5 particles was a matrix of regular tetrahedral cavities with openings in the shape of an equilateral triangle in closed packaging (side length (step) = 1.5918 mm). Each regular tetrahedral cavity has a depth of 1.3571 mm and a pull angle of 77.5 degrees. The deposit area between the openings was 0.1016 mm apart.
The Description of the Molds Used to Manufacture Comparative Abrasive Ceramic Particles SAPA - SAPC:
[0093] The mold has triangular cavities shaped in a closed package with equal length on all three sides (that is, the cavity has the shape of a truncated triangular pyramid). The lateral length of the mold cavities used to manufacture SAPA and SAPB was 2.79 mm (110 mils). For SAPA and SAPB, the mold was manufactured so that the mold cavities had parallel ridges rising from the bottom surfaces of the cavities that intersected with one side of the triangle at an angle
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31/39 of 90 degrees. The parallel ridges were spaced 0.277 mm (10.9 mils) from each other, and the cross-section of the ridges was a triangular shape that has a height of 0.0127 mm (0.5 mils) and an angle of 45 degrees between the sides of each crest at the tip. For SAPA, the depth of the side wall was 0.91 mm (36 mils). For SAPB, the mold was manufactured in such a way that the cavities had parallel ridges projecting on the bottom surfaces of the mold cavities that intersected with a side of the triangle at a 90 degree angle. The parallel ridges were spaced 0.10 mm (3.9 mils) apart, and the cross section of the ridges was a triangular shape that has a height of 0.0032 mm (0.126 mil) and an angle of 45 degrees between the sides of each crest at the tip. For SAPB, the lateral wall depth was 0.46 mm (18 mils).
[0094] SAPC: The lateral length of the mold cavities used for the manufacture of SAPC was 1.66 mm (65 mils). The lateral wall depth was 0.80 mm (31 mils). The mold cavities had parallel ridges rising from the bottom that intersected with one side of the triangle at a 90 degree angle. The ridges were spaced 0.150 mm (5.9 mils) from each other, and the cross section of the ridges was a triangle shape that had a height of 0.0127 mm (0.5 mil) and an angle of 30 degrees between the sides of each crest at the tip.
[0095] For SAPA - SAPC the angle of the slope (that is, the dihedral angle formed between the base of the mold cavities and each of the side walls) was 98 degrees.
Curvature Radius Measurement Technique
[0096] The radius of curvature for all samples was determined according to the following method: The ceramic shaped abrasive particles have a radius of curvature along the side edges that connect to the base and top of the shaped abrasive particles. ceramic of 50 micrometers or less. The radius of curvature was measured from a polished cross section taken between the top and bottom surfaces, for example, using a CLEMEX VISION PE image analysis program available from Clemex Technologies, Inc. of Longueuil, Quebec, Canada, connected via an inverted light microscope or other software / analysis equipment
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32/39 images suitable. The radius of curvature for each point of the shaped abrasive particle was determined by defining three points at the tip of each point when viewed in cross section (for example, at 100X magnification). The first point was placed at the beginning of the tip curve where there is a transition from the straight edge to the beginning of a curve, the second point was located at the tip apex and the third point at the transition from the curved tip to a straight edge. The image analysis software then draws an arc defined by three points (beginning, middle and end of the curve) and calculates a radius of curvature. The radius of curvature of at least 30 apexes is measured and averaged to determine the average radius of the tip.
Particle Length Measurement Technique
[0097] The dimensions of the final particles were measured using a commercially available "AM413ZT DINO-LITE PRO" digital microscope, obtained from www.BigC.com of Torrance, California, USA. Five particles from each batch were laid out flat, and an image was taken at 100x magnification. The lengths of all three sides of each particle were measured using the software built into the computer of the digital camera. The average of these 15 length measurements was calculated, as well as the standard deviation.
Particle Thickness Measurement Technique for Abrasive Particles SAP1
- SAP5
[0098] The particle thickness was calculated from the measurement of the particle length according to the geometric properties of a regular tetrahedron.
Particle Thickness Measurement Technique for SAPA Abrasive Particles
- SAPC
[0099] The dimensions of the final abrasive particles were measured using a digital microscope "AM413ZT DINO-LITE PRO" available for sale, available from www.BigC.com in Torrance, California, USA. The average particle thickness was determined by assembling five particles of each type of side (the flat sides being perpendicular to the table surface) and capturing images of the sides of
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33/39 particle at 100x magnification. The particle thickness of the center and close to each edge was measured for each side, using the cursor of the software provided. The particles were then rotated 120 degrees perpendicular to the table surface, and three height measurements were taken from the second and third sides, respectively. Thus, 9 measurements of particle thickness were taken from each sample, a total of 45 measurements for 5 particles. The mean and standard deviation were calculated.
Crush Test (Full Cut, 10 cycles)
[00100] The sample wheels for testing were mounted on a reciprocating shredding machine. The pre-weighed test workpieces were 400 mm x 50 mm x 7 mm 1018 steel coupons and were assembled to engage with the grinding wheel at an angle of 15 degrees to the horizontal top surface of the workpiece. job. The workpiece was fixedly mounted on the 400 mm x 7 mm side. The milling machine was activated to turn the milling wheel at 6000 RPM. The rotary grinding wheel was installed against the test workpiece at a force of 58 N while traversing the long dimension of the workpiece at a rate of 15.24 cm / s (6 inches per second). Test cycles were 1.0 minutes. The test workpieces were weighed after 1 °, 5 ° and 10 ° cycles. After 10 one-minute milling cycles, the total weight of the removed workpiece was determined and reported as Total Cut, 10 cycles.
Cutting Test
[00101] The cutting wheels in the example were tested on a Maternini cutting test machine, model PTA 100/230, from Davide Maternini SPA in Malnate, Italy) equipped with a 230V and 105 mm (4 inch) Bosch shredder model GWS 6-100 (nominal 10,000 rpm). The cutting test machine was used in the following parameters: test program 100-SS-R, cutting current: 3.5A, Factor kp = 15, Factor kd = 30. The workpieces were 16 mm solid stainless steel wheels. Both the average cutting time and the number of cuts were recorded until the cutting wheels reached a diameter of 90 mm.
Preparation of Shaped Ceramic Abrasive Particles with REO dope
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34/39 (SAP1-SAP5 and SAPA -SAPC)
[00102] A sample of bohemian sol-gel was produced using the following recipe: aluminum oxide powder monohydrate (1600 parts) available as DISPERAL from Sasol North America, Inc., was dispersed by high shear mixing of a solution containing water (2400 parts) and 70 percent aqueous nitric acid (72 parts) for 11 minutes. The resulting sol-gel was aged for at least 1 hour before coating. The sol-gel was forced into the production of stamping that has triangular shaped mold cavities of the dimensions reported above.
[00103] The sol-gel was introduced into the cavities with the help of a spatula, so that all openings in the production stamping were completely filled. A mold release agent, 1 percent peanut oil in methanol was used to coat the production stamping with about 0.08 mg / cm ² (0.5 mg / in ² ) of peanut oil applied to the stamping of production. Excess methanol was removed by placing production stamping blades in an air convection oven for 5 minutes at 45 ° C. The production stamping coated with sol-gel was placed in an air convection oven at 45 ° C for at least 45 minutes for drying. The abrasive particles formed from ceramic precursor were removed from the production stamping, passing them through an ultrasonic horn. The abrasive particles formed from ceramic precursor were calcined at approximately 650 ° C. The shaped abrasive particles of calcined ceramic precursor were impregnated with an alternative rare earth oxide (REO) solution comprising 1.4 percent MgO, 1.7 percent Y2O3, 5.7 percent La2O3 and 0, 07 percent CoO. In 70 grams of the REO solution, 1.4 grams of HYDRAL COAT 5 powder available from Almatis of Pittsburg, Pennsylvania, USA (approximately 0.5 microns of average particle size) are dispersed by stirring in an open beaker. About 100 grams of abrasive particles formed from calcined ceramic precursor are then impregnated with 71.4 grams of the dispersion of the HYDRAL COAT 5 powder in REO solution. The abrasive particles formed from calcined and impregnated ceramic precursor were,
Petition 870200039889, of 03/26/2020, p. 43/53
35/39 then, calcined again at 650 ° C before sintering to the final hardness content at approximately 1400 ° C. Both calcination and sintering were performed using rotary tube ovens. The resulting composition was an alumina composition containing 1 weight percent MgO, 1.2 weight percent Y2O3, 4 weight percent La2O3 and 0.05 weight percent, CoO, with traces of TO2, SO2, and CaO. The resulting abrasive particle dimensions are reported in Table 2 (below).
Table 2
PARTICLE FORMAT APPROXIMATE PLOT SIZE AVERAGE PARTICLE LENGTH, mm, (standard deviation) AVERAGE PARTICLE THICKNESS, mm, (standard deviation) AVERAGE ASPECT OF AVERAGE PARTICLE, length / thickness AVERAGE RADIUS OF CURVATURE OF SIDE EDGES OF ABRASIVE PARTICLE, micrometers, (standard deviation) MOLD CAVITY DIMENSIONS SAP1 regular equilateral tetrahedron 18 1.2 (0.044) 1.06 (0.04) 1.13 38 (23) regular tetrahedron with 3 mm edge SAP2 regular equilateral tetrahedron with concave faces 18 1.39 (0.116) 1.06 (0.12) 1.13 25.98(18.59) regular tetrahedron with concave faces, 3 mm edge SAP3 regular equilateral tetrahedron 20 0.897 (0.0381) 0.78 (0.04) 1.15 41.62(17.65) regular tetrahedron with 2 mm edge SAP4 regular equilateral tetrahedron 30 0.474 (0.0201) 0.410(0.02) 1.15 17.07(2.84) regular tetrahedron with 0.99 mm edge SAP5 regular equilateral tetrahedron 25 0.794(0.0337) 0.687(0.03) 1.15 18.31(5.80) regular tetrahedron with 1.67 mm edge SAPA regular truncated triangular pyramid 18 1,383(0.063) 0.31 (0.08) 4.5 13.71(9.1477) 2.79 mm long x 0.91 mm deep, 98 ° slope angle SAPB triangular pyramid 18 1.447 (0.044) 0.164(0.033) 8.8 22.74(13.29) 2.79 mm in length
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36/39
regular truncatedx 0.46 mm in depth, 98 ° slope angle SAPC regular truncated triangular pyramid 20 0.765 (0.064) 0.258 (0.058) 3 8.01(3.8513) 1.72 mm long x 0.02 mm deep, 98 ° slope angle
Examples 1-3 E Comparative Examples A-C
[00104] The grinding wheels of examples 1-3 and comparative examples A-C were built to demonstrate the effects of incorporating particles of various geometries into 105 mm (4-inch) grinding wheels.
[00105] In Example 1, the radially constructed stratified reinforced wheels having an inner radial (80% of the wheel radius, which comprises a conventional bonded abrasive composition) and a circumferential band (20% of the wheel) of the test composition. This circumferential band (e.g. "tire") of the composition of the invention or comparative was 1.0 cm thick along the perimeter of each wheel.
[00106] The 80% interior composition of Example 1 was manufactured by combining, based on the weight of the final grinding wheel, 44 parts of AP1, 3.8 parts of AP2 and 2.48 parts of AP3. 4.4 parts of PR1 was added with stirring followed by 13.88 parts of PR2 and 12 parts of CRY. The 20% outer (circumferential) band was manufactured by combining 5.5 parts of SAP1, 5.5 parts of AP1, 0.95 part of AP2 and 0.62 part of AP3. 1.1 part of PR1 was added with stirring, followed by 3.47 parts of PR2 and 3 parts of CRY. The radially stratified mixture was sandwiched between layers of SM in a 105 mm diameter matrix and pressed in a single cavity press at a pressure of 22.6 MPa (20 tons / 12.27 inches ² (230 kg / cm ² ) ). The grinding wheels were then placed between metal plates, separated by sheets coated with TEFLON and placed in a curing oven. After a curing cycle of about 40 hours (Segment 1: set point of 78.8 ° C (174 ° F), increase over
Petition 870200039889, of 03/26/2020, p. 45/53
37/39 minutes, soak for 7 hours; Segment 2: setpoint 107 ° C (225 ° F), increase over 4 hours and 20 minutes, soak for 3 hours; Segment 3: set point 185 ° C (365 ° F), increase over 3 hours and 15 minutes, soak for 18 hours; Segment 4: setpoint 26.6 ° C (80 ° F), decrease over 4 hours and 27 minutes, soak for 5 minutes), a 22.2 mm (7/8 inch) center hole was drilled using a diamond drill and the grinding wheel was precisely fitted to 98 mm in diameter.
[00107] Examples 2-3 and comparative examples A-C were done in the same way as Example 1 with the exception that the compositions were adjusted as shown in Table 3.
Comparative example D
[00108] Comparative example D was a wheel made in the same way as in Example 1, with the exception that the composition was uniform throughout as shown in Table 3, below. The grinding wheel of Comparative Example D contained only crushed abrasive particles.
Table 3
EXAMPLE PART ABRASIVE CULAS, parts, by weight, (pbw) PR1, pbw PR2, pbw CRYpbw CUTTOTA L, 10 cycles, gram s SAP1 SAP2 SAP3 SAP A SAP B SAP C AP1 AP2 AP3 1 Outdoor 5.55.5 0.95 0.62 1.1 3.47 3 415.49 Interior 44 3.8 2.48 4.4 13.88 12 ND 2 Outdoor5.5 5.5 0.95 0.62 1.1 3.47 3 487.59 Interior 44 3.8 2.48 4.4 13.88 12 ND 3 Outdoor 5.5 5.5 0.95 0.62 1.1 3.47 3 437.59 Interior 44 3.8 2.48 4.4 13.88 12 ND Comparative example A Outdoor 5.5 5.5 0.95 0.62 1.1 3.47 3 261.34 Interior 44 3.8 2.48 4.4 13.88 12 ND Example comparative B Outdoor 5.55.5 0.95 0.62 1.1 3.47 3 173.48 Interior 44 3.8 2.48 4.4 13.88 12 ND Example Outdoor5.5 5.5 0.95 0.62 1.1 3.47 3 325.33
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38/39
EXAMPLE PART ABRASIVE CULAS, parts, by weight, (pbw) PR1, pbw PR2, pbw CRYpbw CUTTOTA L, 10 cycles, gram s SAP1 SAP2 SAP3 SAP A SAP B SAP C AP1 AP2 AP3 Active Comparison C Interior 44 3.8 2.48 4.4 13.88 12 ND Example Active Comparison D 55 4.76 3.14 5.5 17.25 15.1 168.3
Examples 4-5 and Comparative Example E
[00109] The cutting wheels of Examples 4-5 and Comparative Example E were built to demonstrate the effects of particles incorporating various geometries on 105 mm (4-inch) cutting wheels.
[00110] For Example 4, 5.5 parts of AP1, 5.5 parts of SAP4, 0.95 part of AP2 and 0.62 part of AP3 were mixed with 1.1 part of PR1. Meanwhile, 3.47 parts of PR2, 3.0 parts of CRY were mixed. The dry powder mixture was slowly added to the wet mixture of resin and abrasive particles. A 105 mm (4 inch) diameter (SM) fiberglass swab obtained as 3321 & from Industrial Polymers Chemicals of Shrewsbury, Massachusetts, USA was placed in a mold of a hydraulic press machine. A mixture of 20 g mineral / resin was placed in a mold of a hydraulic press machine, on top of the talaguça. A second talaguça was placed on top of the mixture composition and pressed into a single cavity mold at a pressure of 22.6 MPa (20 tons / 12.27 inches ² (230 kg / cm ² )). The cutting wheels were then placed between metal plates, separated by sheets coated with TEFLON, and placed in a curing oven. After a curing cycle of about 40 hours (Segment 1: setpoint 78.8 ° C (174 ° F), rise over 4 minutes, soak for 7 hours; Segment 2: setpoint 107 ° C ( 225 ° F), increase over 4 hours and 20 minutes, soak for 3 hours, Segment 3: setpoint 185 ° C (365 ° F), increase over 3 hours and 15 minutes, soak for 18 hours; Segment 4: set point 26.6 ° C (80 ° F), increase over 4 hours 27 minutes, soak for 5 minutes), the dimensions of the final cutting wheels were 104.03 - 104.76 mm x -1.34-1.63 mm x 9.5 mm.
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39/39
[00111] The cutting wheels were tested according to the cutting test. The results are reported in Table 4.
[00112] Example 5 and Comparative Example E were prepared in the same way as Example 4, except that the composition changes as shown in Table 4.
[00113] The comparative test results are shown in Table 4 (below) for average time per cut and number of cuts achieved before the wheel is consumed. Table 4
EXAMPLE ABRASIVE PARTICLES, pbw PR1, pbw PR2, pbw CRY, pbw CUTTING TIME, seconds NUMBER OF CUTS AP1 AP2 AP3 AP4 SAP4 SAP5 4 5.5 0.95 0.625.51.1 3.47 3.0 9.8 21 5 5.5 0.95 0.62 5.5 1.1 3.47 3.0 8.77 31 Comparative Example E 5.5 0.95 0.62 5.5 1.1 3.47 3.0 9.16 12.5
[00114] All patents and publications presented here are incorporated herein, by reference, in their entirety. All examples given in this document are to be considered as non-limiting, except where indicated otherwise. Various modifications and alterations to this disclosure can be made by those skilled in the art without departing from the scope and spirit of this disclosure, and it should be understood that this disclosure should not be unduly limited to the illustrative modalities presented here.

权利要求:
Claims (12)
[1]
1. Abrasive article CHARACTERIZED by the fact that it comprises ceramic shaped abrasive particles retained in a binder, in which the ceramic shaped abrasive particles have four main sides joined by six common edges, where each of the four main sides comes into contact with three others on the four main sides, and where the six common edges have substantially equal lengths, where each of the main sides is concave, and where the abrasive article is an abrasive wheel.
[2]
2. Abrasive article according to claim 1, CHARACTERIZED by the fact that at least one of the four main sides is substantially flat.
[3]
3. Abrasive article according to claim 1 or 2, CHARACTERIZED by the fact that at least one of the four main sides is concave.
[4]
Abrasive article according to any one of claims 1 to 3, CHARACTERIZED by the fact that the shaped abrasive particles of ceramics comprise alumina derived from sol-gel.
[5]
Abrasive article according to any one of claims 1 to 4, CHARACTERIZED by the fact that shaped ceramic abrasive particles comprise alpha alumina.
[6]
Abrasive article according to any one of claims 1 to 5, CHARACTERIZED by the fact that the binder comprises an organic binder.
[7]
Abrasive article according to any one of claims 1 to 6, CHARACTERIZED by the fact that the abrasive article comprises a bonded abrasive article.
[8]
8. Abrasive article according to any one of claims 1 to 7, CHARACTERIZED by the fact that the binder comprises a glassy binder.
[9]
Abrasive article according to any one of claims 1 to 8, CHARACTERIZED by the fact that the abrasive article comprises a connected abrasive wheel.
[10]
10. Method of abrasion of a workpiece, CHARACTERIZED by the fact that
Petition 870200039889, of 03/26/2020, p. 49/53
2/2 comprising:
friction by contacting at least a portion of the ceramic shaped abrasive particles of the abrasive article, as defined in claim 1, with a workpiece surface; and moving at least one of the workpiece or abrasive article to abrasion at least a portion of the workpiece surface.
[11]
11. Method of preparing a ceramic-shaped abrasive particle CHARACTERIZED by the fact that it comprises:
introducing a dispersion of ceramic precursor into a mold cavity, in which the cavity has three concave walls that meet at a common vertex;
drying the ceramic precursor dispersion and removing it from the cavity to provide a ceramic shaped abrasive particle precursor;
calcining the ceramic shaped abrasive particle precursor; and sintering the calcined ceramic shaped abrasive particle precursor to provide the ceramic shaped abrasive particle, wherein the ceramic shaped abrasive particle has four main sides joined by six common edges, where each of the four main sides comes into contact with three others on the four main sides, where at least three of the four main sides are substantially flat, and where the six common edges have substantially equal lengths.
[12]
12. Method according to claim 11, CHARACTERIZED by the fact that the ceramic shaped abrasive particle comprises alpha alumina.

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公开号 | 公开日

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CA2797096C|2018-07-10|

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WO2011139562A2|2011-11-10|

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WO2011139562A3|2012-02-02|

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KR101849797B1|2018-04-17|

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法律状态:
2018-04-10| B06F| Objections, documents and/or translations needed after an examination request according art. 34 industrial property law|

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2019-02-19| B06T| Formal requirements before examination|

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2019-12-31| B06A| Notification to applicant to reply to the report for non-patentability or inadequacy of the application according art. 36 industrial patent law|

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2020-04-07| B09A| Decision: intention to grant|

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2020-05-19| B16A| Patent or certificate of addition of invention granted|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 20/04/2011, OBSERVADAS AS CONDICOES LEGAIS. |

优先权:

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申请号 | 申请日 | 专利标题

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US32848210P| true| 2010-04-27|2010-04-27|

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PCT/US2011/033188|WO2011139562A2|2010-04-27|2011-04-20|Ceramic shaped abrasive particles, methods of making the same, and abrasive articles containing the same|

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