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    • 专利摘要:
    APPARATUS, SYSTEM AND METHOD FOR EMULSIFYING OIL AND WATER. The present invention relates to a device, a system and a method for emulsifying oil and water, such as for emulsifying a sizing agent to be used in the treatment of paper or cardboard, introducing a continuous phase under pressure by a nozzle (66) for continuous phase of a Venturi device (50) and in a mixing section. A dispersed phase is optionally introduced under pressure into the mixing section (80) of the Venturi device. The emulsion formed in the mixing section is conveyed through a nozzle (60) to the mixed phase and exit from the Venturi device. The nozzle diameter (60) for the Venturi device mixed phase is more important than the nozzle diameter (66) for the continuous phase with a ratio greater than 1:1 and less than 4:1.
    公开号:BR112012002642B1
    申请号:R112012002642-9
    申请日:2009-08-04
    公开日:2021-05-25
    发明作者:Olivier Maniere
    申请人:Solenis Technologies Cayman, L.P.；
    IPC主号:
    专利说明:

    [0001] The present invention relates to a device, a system and a method for emulsifying oil and water, which are particularly useful in the preparation of aqueous emulsions of sizing agents for internal or surface sizing of paper and cardboard or for the inversion of polymer products into inverse emulsion used in the treatment of paper and cardboard. CONTEXT OF THE INVENTION
    [0002] The additives used in the paper industry for the purpose of making water-resistant penetrants are generally called sizing agents. The two most common synthetic sizing agents are alkyl ketene dimer (AKD) and alkenyl succinic anhydride (ASA).
    [0003] These two agents, ASA and AKD, are hydrophobic materials, not soluble in water. These materials can be added to the liquid paste, before the sheet is formed, which is called internal bonding, or they can be applied to the surface of the formed coil, which is called surface bonding. For both applications, to be effective, the sizing agent must be distributed in the aqueous system. For this reason, these non-water-soluble additives are generally added in the form of aqueous oil-in-water emulsions.
    [0004] The aqueous emulsions of the sizing agents can be offered to the paper mill in this form, or be prepared on site. Indeed, it is more advantageous for certain synthetic sizing agents reacting with cellulose to emulsify them on site. ASA, for example, is emulsified on site due to the instability of the anhydride functionality after emulsification with water.
    [0005] Currently, two classes of on-site emulsification technologies are used in industry: (1) the high-shear technology, and (2) the low-shear technology.
    [0006] After emulsification with high shear, the ASA (or another sizing agent) and a synthetic polymer, starch, or a protective colloid are passed through a pump with a high shear turbine or ho device. - milling, with or without the addition of surface agents. The limitations of this approach lie in the need to have resorted to "heavy, expensive, and relatively complex equipment capable of exerting high homogenization pressures and/or shear, as well as strict procedures regarding temperatures, emulsifying ratios, etc., in order to produce a stable emulsion suitable for the specific glue." (US Patent No. 4,040,900).
    [0007] In order to prevent these limitations regarding emulsification with high shear, approaches based on emulsification with low shear have been proposed, starting with Mazzarella (US Patent No. 4,040,900) in 1977 who disclosed blends of ASA with 3 -20 parts by weight of a surface active additive (surface agent) which "can easily emulsify with water in the absence of high shear forces and in a normal pressure condition simply by shaking and passing through a mixer tap or a regular vacuum cleaner". Unfortunately, such low-shear emulsification can lead to foaming problems and poor sizing effectiveness due to the increased surface agent level causes surface agent to build up in the system (CE Farley and RB Wasser, "Sizing with Alkenyl Succinic Anhydride", Chapter 3 in The Sizing of Paper, 2nd Edition, WF Reynolds, Ed. Tappi Press, 1989, pp.51-62).
    [0008] More recently, Pawlowska et al, (WO2006/096216) disclose "an improved method for wet end paper sizing which utilizes simpler and less costly low shear equipment for ASA emulsification". . disclose a method of sizing, comprising the fact of "forming, in the absence of high shear forces, an aqueous sizing emulsion comprising a component of alkenyl succinic anhydride" which is subsequently diluted with the aid of a cationic component The main difference between Pawlowska and Mazzarella lies in the post-dilution of the emulsion with a cationic component in order to improve retention.The examples demonstrate sustainably that low-shear ASA emulsions are post-diluted with the aid of a cationic starch are less effective sizing agents than high-shear ASA emulsions, but the simplicity of the emulsification process of high-shear ASA emulsions is held to This low offers the paper manufacturer "operating and cost advantages".
    [0009] Other patents disclose the use of modified starches (eg US Patent 6,210,475) or polymer (eg US 6,444,024 B1) in order to improve the performance of emulsification systems with low shear, to -davia, none of these patents solve the basic behavior and performance issues that characterize the low-shear system.
    [0010] In the literature, there is a tendency to have qualitative definitions of conditions with "low shear" in relation to conditions with "high shear". Typically, a list of equipment that suits or does not suit the descriptor is used. Systems with "high shear" are: "present in Waring mixers, pumps with turbines, or other agitators with very high speeds, etc", and "are found in homogenising equipment with pistons or other types" (Mazzarella). Systems with "low shear" consist of: "simply agitation, passing through a mixer tap or a vacuum or through the usual agitation present in a paste preparation system" (Mazzarella) or shear conditions "created by a device selected from the group consisting of centrifugal pumps, static in-line mixers, peristaltic pumps, and their combinations" (Pawlowska). But these definitions get mixed up in lists of commercial emulsification equipment that support industrial units with low and high pressure, such as the "Cytec low pressure turbine emulsifiers from Cytec Industries, Inc, the Nalco high pressure emulsifier systems, and the venturi emulsifiers and the National Starch turbines", which suggests that turbine pumps fall into the low-shear category. In addition, Waring mixers are used to produce high and low energy ASA emulsions (Chen and Woodward, Tappi J. Aug 1986, pg 95) by varying the electrical voltage. Thus, systems with "low shear" and "high shear" cannot be defined solely by the type of equipment.
    [0011] In the "Principles of ASA Sizing" (CE Farley, 1987 Tappi Sizing Short Course, p 89) there is a more quantitative definition of "high shear" and low shear emulsification systems: "emulsification with shear Elevated operation is designed with a turbine pump with precise tolerances. The work done by the pump is such that the pressure differential between the pump inlet and outlet is approximately 0.83 to 0.97 MPa (120 to 140 psi) (8.3 to 9.7 bar). ASA and starch are mixed at or near the turbine pump inlet level. "In low-shear emulsification, ASA, starch as well as a surface agent are mixed, then passed through through a series of venturis. The typical starch:ASA:Surface agent ratio is approximately 2.5 : 1: 0.05. A potential drawback of this method is the higher level of surface agent used, which can lead to what is termed "detachment" and poor ASA effectiveness, as well as foaming problems.” Thus, the distinction it makes. Farley between high shear and low shear is that high shear systems have a pressure differential on the order of 0.83 to 0.97 MPa (120 to 140 psi) (8.3 to 9.7 bar).
    [0012] Similarly, Denowski et al. (US 2008 / 0277084) defines low shear as the ability to pump a liquid through a pump with a back pressure of 0.34 MPa (50 psi) (3.4 bar) or less, while high shear is defined as the need to have a back pressure of 1.03 to 2.07 MPa (150 to 300 psi) (10.3 to 20.7 bar) to pump a liquid.
    [0013] There is still a need, on the market, to have a simpler and cheaper ASA emulsification equipment, which does not pose problems with the paper machine behavior (foam, deposits) and/or efficiency of mediocre sizing due to high surface agent loading or poor emulsion quality. SUMMARY OF THE INVENTION
    [0014] It has been found that it is possible to prepare emulsions of sizing agents (such as ASA) stable and of good quality in water, with good paper machine performance and good sizing efficiency, by feeding water through a device venturi with a relatively high pressure and introducing the bonding agent at the level of the venturi inlet. This system is simpler, more reliable, more energy efficient and less expensive than traditional high-shear systems used today, and offers better quality emulsions using less important surface agent levels than low-shear systems. , consuming little energy, available today. In addition, this system can be used for the on-site emulsification of other papermaking additives, or the inversion of inverse emulsion polymer products.
    [0015] In a first aspect, an oil-in-water or water-in-oil emulsification system comprises a venturi device. A continuous phase is introduced under pressure into the venturi device and through a continuous face nozzle having a first diameter into a mixing section. A dispersed phase is introduced into the mixing section of the venturi device in order to form an emulsion of the dispersed phase into the continuous phase. The emulsion is carried through a nozzle to mixed phase having a second diameter and to an outlet of the venturi device. The nozzle diameter for mixed phase is larger than the nozzle diameter for continuous phase with a ratio greater than 1:1 and less than 4:1.
    [0016] Preferably, the continuous phase comprises water, which is introduced at a pressure of approximately 1 MPa (10 bar) to approximately 5 MPa (50 bar), and the flow velocity is in the range of 10 to 100 m /s approximately. Preferably, the dispersed phase comprises one or more sizing agent. The emulsion can be evacuated into a discharge chamber, into which optional additives can be mixed there. The emulsion can be stored for later use, or diluted with water or another aqueous solution, before being added to the wet end, or to a size press or bed machine for a paper or cardboard manufacturing system. Alternatively, the emulsion can be added directly to the wet end, or to a size press or bed press for a paper or cardboard manufacturing system.
    [0017] The dispersed phase may contain a cellulose-reactive paper sizing component or a mixture of these components or a non-cellulose-reactive paper sizing component or a mixture of these components. Exemplary cellulose-reactive paper sizing components include alkenyl succinic anhydride (ASA), ketene dimers and multimers such as alkyl ketene dimer (AKD), organic epoxides containing approximately 12 to 22 carbon atoms, acyl halides, acyl halides containing approximately 12 to 22 carbon atoms, fatty acid anhydrides from fatty acids containing approximately 12 to 22 carbon atoms, or organic isocyanates containing approximately 12 to 22 carbon atoms carbon.
    [0018] The dispersed phase can be introduced only by suction at the level of the suction inlet of the venturi device, or possibly pumped with the aid of a pump in the mixing section. Preferably, the dispersed phase is filtered before its introduction into the mixing section.
    [0019] Alternatively, the continuous phase can be water and the dispersed phase because it is an inverse emulsion polymer commonly used in papermaking. In that case, an oil-in-water emulsion containing a polymer in the aqueous phase can be introduced into the venturi device through the suction inlet. The presence of a large volume of dilution water and mixing in the mixing section that breaks the emulsion will "activate" the polymer, producing a dilute polymer-based mixture containing oil droplets. An example of an inverse emulsion polymer commonly used in papermaking is a retention and drainage aiding agent, such as the retention and drainage assistance agents PERFORM SP7200 or PERFORM PC8179 (Ashland Inc., Covington, KY) .
    [0020] In a second aspect, a method of emulsifying a sizing agent to be used for the treatment of paper or cardboard comprises the following steps. A continuous phase is introduced under reduced pressure into a venturi device and at the level of a continuous phase nozzle that has a first dimer that directs this continuous phase into a mixing section of the device. A dispersed phase is introduced into the mixing section of the venturi device in order to form an emulsion of the dispersed phase into the continuous phase. The emulsion is passed through a nozzle for mixed phase having a second diameter d2 which is larger than the diameter of the nozzle for continuous phase d1 with a ratio greater than 1:1 and less than 4:1. Preferably, the continuous phase is introduced at a pressure of approximately 1 MPa (10 bar) to approximately 5 MPa (50 bar) and with a flow velocity at the nozzle for continuous phase ranging from approximately 10 to approximately 100 m/s.
    [0021] In the method, the dispersed phase may contain a paper sizing component that reacts to cellulose or a mixture of these components or a paper sizing component that reacts to cellulose exemplary include alkenyl succinic anhydride (ASA), the dimers and ketene multimers, organic epoxides containing approximately 12 to 22 carbon atoms, acyl halides containing approximately 12 to 22 carbon atoms, fatty acid anhydrides from fatty acids containing approximately 12 to 22 carbon atoms, and organic isocyanates containing of approximately 12 to 22 carbon atoms.
    [0022] In the method, the dispersed phase can be introduced solely by suction at the level of the suction inlet of the venturi device or, eventually, pumped with the aid of a pump in the mixing section. Preferably, the dispersed phase is filtered before its introduction into the mixing section.
    [0023] The resulting emulsion of sizing agent has an average particle diameter of less than approximately 2 microns, preferably between 0.5 and 1.5 microns, and most preferably less than approximately 1 micron, such that measures using a light scattering technique over a proof emulsion for approximately one to approximately ten minutes after the emulsion leaves the venturi device. The emulsion is added either to a wet end or to a size press or bed press for a paper or board making system. If the continuous phase is water, the emulsion is preferably post-diluted with water in order to produce a solid element content in the range of approximately 1 to approximately 5% by weight. Subsequently, the emulsion having undergone post-dilution is preferably mixed with an aqueous solution of a synthetic or natural cationic polymer before being added to the wet end, the size press or the bed-former.
    [0024] In another aspect, a venturi device has a nozzle for continuous phase that has a first diameter that carries a first liquid under pressure to a mixing section, as well as an inlet for directing a second liquid to the mixing section, the in order to form an emulsion there. The venturi device further has a nozzle for mixed phase having a second diameter through which the emulsion is directed to an outlet of the venturi device. The nozzle diameter for mixed phase is larger than the nozzle diameter for continuous phase with a ratio greater than 1:1 and less than 4:1. Preferably, the mixing section is conical and tapered to a wider diameter at the level at which the inlet joins the mixing section to a narrower diameter at the level at which the nozzle for mixed phase joins the mixing section. Preferably, the venturi device comprises a discharge diffuser in fluid communication with the nozzle for mixed phase and at the level of the outlet of the venturi device. BRIEF DESCRIPTION OF THE DRAWINGS
    [0025] Other objectives, advantages and particularities, as well as possible applications of the present invention are disclosed in the following description of the embodiments with reference to the attached drawings, in which: Figure 1 represents a schematic diagram of an exemplary system for emulsification oil and water, according to the invention; figure 2 represents an exit side projection view of a venturi device according to the invention; Figure 3 is a sectional view of the venturi device taken along line 3-3 of Figure 2; and Figure 4 is an exploded sectional view of the venturi device, showing the continuous phase nozzle and the mixed phase nozzle of the venturi device of Figure 3. DETAILED DESCRIPTION OF THE INVENTION
    [0026] In this application, an "emulsion" is a mixture of particles from one liquid into a second liquid. Two common types of emulsions are oil-in-water and water-in-oil emulsions. By "oil" is generally meant a liquid that is insoluble or barely soluble in water. For oil-in-water type emulsions, water is the "continuous phase" and oil is the discontinuous phase. For water-in-oil type emulsions, it is the reverse. In this case, the liquid that forms the continuous phase of the final emulsion is called "continuous phase" and the other liquid that forms the discontinuous phase of the final emulsion is called "dispersed phase". In the case of an oil-in-water type emulsion, water is the continuous phase and oil is the dispersed phase.
    [0027] A schematic of a system 10 for emulsification of oil and water is shown in figure 1. The system 10 will be described, reporting the emulsification of a sizing agent such as the alkyl ketene dimer (AKD) or alkenyl succinic anhydride (ASA), in water. However, it must be understood that the system can be used to emulsify other materials, and the choice of continuous and dispersed phases is for illustrative purposes and is not intended to limit the invention.
    [0028] Referring to Figure 1, a supply of a "continuous phase", such as water without being limited thereto in this embodiment, from a storage tank or feed tank 12, is supplied to a pump 22 via a line 14 and a filter 16 through a control valve 18 and a flow meter 20. The water flow, which may, as a variant, call "continuous phase" with regard to this embodiment, is controlled to a specific evaluation, using a regulation circuit with the flow meter 20 and the control valve 18. Other means of regulation of the flow are considerable, as the technician knows. The pump 22 can be of any type, including a multi-stage centrifugal pump or a regenerative pump, which can provide a supply pressure of approximately 3 MPa (30 bar), or supply pressures in the range of approximately 1 to 5 MPa (10 to 50 bar), more preferably from approximately 1.8 to 3.5 MPa (18 to 35 bar). Pressure gauges 40b, 40a and 40c are provided for the purpose of controlling, respectively, the pressures of the continuous phase, the dispersed phase and the emulsion. The continuous phase is sent to a first input 48 (refer to figure 3) of a venturi device 50.
    [0029] A "dispersed phase", such as a liquid sizing agent, without however being limited thereto in this embodiment, is supplied (or pumped with the aid of an optional pump 38) from a reservoir storage or supply reservoir 32 via a line 34 and a filter 36 which passes through a flow meter 39 and a back pressure regulator 42 with a suction inlet 52 (refer to figure 3) of the venturi device 50.
    [0030] The optional pump 38 can be of any type that can provide an active feed principle, up to approximately *0.5 MPa (5 bar), preferably approximately 0.3 MPa (3 bar), e.g. flow of the sizing agent, which can also be called "dispersed phase", in this embodiment can be controlled with the aid of the pump 38 or with the aid of a control circuit. It is also considerable to provide alternative controls in order to regulate the ratio of the continuous phase to the dispersed phase fed with the venturi device 50. Considering that the continuous phase fed with the venturi device 50 produces a vacuum at the level of the suction inlet 52 of the phase dispersed phase, there is no need for pump 38 to supply the dispersed phase to the venturi device 50. However, by using the pump 38 to supply the dispersed phase to the venturi device 50, a more sustained supply pressure and better control are achieved. of the emulsion formation process.
    [0031] The continuous and dispersed phases are mixed in the venturi device 50 and are evacuated to a chamber 70. The diameter of the chamber 70 should be sufficient to reduce the velocity of the emulsified product from the venturi device 50. Additives can be mixed into the emulsified product in chamber 70 or downstream of chamber 70.
    [0032] The mixed phase or emulsified product can be directed to the paper machine or to a storage tank 76 or delivery container (not shown), via a pressure control valve 74. If the continuous phase is water, the The emulsion will preferably be powders diluted with water to produce a solids content in the range of approximately 1 to approximately 5% by weight. Thereafter, the post-dilution emulsion is preferably mixed with an aqueous solution of a natural or synthetic cationic polymer, before being added to the wet end by the size press or applicator of a machine for manufacturing paper or cardboard.
    [0033] An embodiment of a venturi device 50 for emulsifying oil and water is shown in figures 2 to 4. Figure 3 is a longitudinal section of the venturi device 50. The venturi device 50 has a first inlet 48, into which the continuous phase, such as water, is introduced. The continuous phase circles through the venturi device 50 in the direction of arrow 54. The flow velocity of the continuous phase increases from the first inlet 48 to a channel 56 of smaller diameter, then into a conical section 58, before entering a nozzle with smaller diameter or nozzle 66 for continuous phase. The shape and dimensions of the continuous phase flow channel can be varied.
    The venturi device 50 has an aspiration inlet 52 through which the dispersed phase, such as a sizing agent, but not limited thereto, enters the venturi device 50 in the direction of arrow 62. Vacuum is produced at the level of the suction inlet 52 by continuous phase flow through nozzle 66 for continuous phase.
    [0035] The continuous phase (eg water) and the dispersed phase (eg a sizing agent) are mixed in a globally conical chamber 80 and enter through nozzle 60 for mixed phase. In the invention, the nozzle diameter d2 for mixed phase is greater than the nozzle diameter d1 for the continuous phase at a ratio greater than 1:1 and less than 4:1. In one embodiment of the invention, referring to Figure 4, the nozzle for mixed phase has a diameter d2 which is twice the diameter d1 of the nozzle 66 for continuous phase. The continuous phase and the dispersed phase mix thanks to the turbulence reigning inside the conical mixing chamber 80 between the nozzle 66 for the continuous phase and the nozzle 60 for the mixed phase, to form the emulsion or mixed phase. The emulsion leaves the nozzle 60 for mixed phase through a discharge diffuser 82 and leaves the venturi device in the direction of arrow 84. The emulsion thus formed is evacuated into chamber 70 (refer to Figure 1).
    [0036] In the invention, emulsions are formed by feeding the continuous phase of an emulsion via the nozzle 66 to the continuous phase at high pressure. Flow from continuous phase via nozzle 66 to continuous phase creates a low pressure region at the level of inlet 52 for dispersed phase in venturi device 50. The continuous and dispersed phases are mixed in a globally conical mixing chamber 80 within the device. venturi 50 and fed into a nozzle 60 for the mixed phase which has a diameter d2 larger than the diameter d1 of the nozzle 66 for continuous phase. The two distinct dimensions d2 and d1 of the diameters create two layers of jets at high velocity. The emulsified product from the venturi device 50 is evacuated into a chamber 70 where the pressure and fluid velocity are reduced. In chamber 70 or downstream from it, additional agents can be added to the emulsion in order to improve its performance, or the emulsion can be diluted with water and/or with an aqueous solution based on cationic polymer or other modifications of the emulsion are considerable. Figure 1 further shows an optional reservoir 76 in which the emulsion can be deposited.
    [0037] A representative venturi device 50 has the following dimensions. Referring to Figure 4, the nozzle 60 for the mixed phase has a cell diameter d2 of approximately 1.2 mm and the nozzle 66 for the continuous phase has a circular diameter d1 of approximately 0.7 mm. In an alternative device, nozzle 60 for mixed phase has a circular diameter d2 of approximately 1.8 mm and nozzle 66 for continuous phase has a circular diameter d1 of approximately 1 mm. Referring to Figure 3, representative venturi device 50 has an overall length of approximately 90 mm. The first inlet 48 is formed with an approximately 12.7 mm (1/2 inch) regulated female circular opening to receive a supply tube or fitting (not shown) for introducing continuous phase into the first inlet 48. The first inlet 48 has a length of approximately 20 mm, and the channel 56 with the smallest diameter 56 is a length of approximately 35 mm, the distal end forming a tapered narrowing to direct liquid from the continuous phase to the nozzle 66 for the continuous phase. Nozzle 66 for continuous phase has a length of approximately 4 mm. The mixed phase nozzle 60 has a length of approximately 15 mm.
    The aspiration inlet 52 in the representative venturi device 50 has a circular diameter of approximately 10 mm and a length of approximately 10 mm. Suction inlet 52 is narrowed at the level of a conical distal end that directs the dispersed phase matter into a tubing leading to a conical chamber 80 for mixing the continuous phase and dispersed phase together to form a mixed phase or emulsion. Conical chamber 80 has a proximal circular diameter of approximately 10 mm and narrows towards mouthpiece 60 for mixed phase at the level of its distal end.
    [0039] The discharge diffuser 82, at the level of the distal end of the representative venturi device 50, in accordance with the invention, is formed with an outer part threaded on the outside of approximately 12.7 mm (1/2 inch) which will be connected to a regulated discharge pipe or fitting (not shown) to which mixed phase (emulsion) leaves the venturi device 50. The discharge diffuser has a length of approximately 18 mm, and an outer circular opening with a diameter of approximately 15 mm . An end projection view of the venturi device 50 from the discharge diffuser 82 in Figure 2 shows that the venturi device 50 has an overall hexagonal or six-sided appearance, and its height and width is approximately 36 mm.
    [0040] The representative venturi device 50 is shown in Figure 3 formed from two machined parts, the first part, in which the first inlet 48 leading to the venturi nozzle 66 is formed, and the second part, in which the venturi is formed. suction inlet 52, conical chamber 80, nozzle 60 for mixed phase and diffuser 82. The first part fits with the second part and is threadedly connected through threads 77 formed on the outside of the first part and the inside of the second part part. A sealing ring 78 is provided for the fluid tightness of the first and second part.
    [0041] The continuous phase of the emulsion can be water-based or oil-based. When the continuous phase is water-based, the dispersed phase of the emulsion can be oil-based. When the continuous phase is oil-based, the dispersed phase of the emulsion can be water-based. Examples of continuous water-based phases include, but are not limited to, water, aqueous starch solutions and polymer solutions. Additional ingredients commonly used in sizing agent emulsions, such as biocides, aluminums, cationic resins, surface agents, etc., but not limited to, may be contained in the continuous phase supply. Examples of oil-based dispersed phase include, but are not limited to, ASA, AKD and polymers. Additives such as surface agents can optionally be contained in the oil phase.
    [0042] The supply pressure in continuous phase is approximately between 1 and 5 MPa (10 and 50 bar), preferably between approximately 1.8 and 3.5 MPa (18 bar and 35 bar). The ratio of the dimensions of the nozzle for mixed phase and the nozzle for continuous phase is greater than 1:1 and less than 4:1, preferably between 1.5:1 and 2.5:1. The diameter of the nozzle for continuous phase (eg nozzle 66 in figure 3) is fixed in order to achieve a flow velocity of approximately 10 to 100 m/s, preferably approximately 40 to 60 m/s . the high speed created from the instantaneous creation conditions of emulsions.
    [0043] It is made to vary the ratio of the continuous phase by the dispersed phase, in order to meet the requirements of the emulsion in terms of viscosity, stability and homogeneity. The concentration of the dispersed phase in the continuous phase ranges from approximately 2 to 50% by weight, preferably 4 to 35% by weight. The diameter of the chamber at the evacuation level of the venturi device (eg chamber 70 in figure 1) is approximately 5 to 100 times the diameter of the continuous phase nozzle of the venturi device (eg nozzle 66 in figure 3) , preferably approximately 40 to 80 times the diameter of nozzle 66 for continuous phase. The pressure in the chamber (for example, in chamber 70 of Figure 1) is approximately 0.1 to 0.67 MPa (1 to 6.7 bar), preferably approximately 0.13 to 0.5 MPa (1 .3 to 5 bar). The pressure of the dispersed phase is approximately 0.13 to 0.67 MPa (1.3 to 6.7 bar), preferably approximately 0.3 to 0.43 MPa (3 to 4.3 bar) .
    [0044] For the dispersed phase of the invention, the preferred paper sizing components are selected from the group consisting of cellulose-reactive paper sizing components and non-cellulose-reactive paper sizing components. For the purposes of this invention, glues that react with cellulose are defined as being glues capable of forming the covalent chemical bonds by reaction with cellulose hydroxyl groups, and glues that do not react with cellulose are defined as being glues that do not form these. covalent bonds with cellulose.
    Preferred cellulose-reactive glues for use in the invention include alkenyl succinic anhydrides (ASA), ketene dimers and multimers, organic epoxides containing approximately 12 to 22 carbon atoms, and acyl halides containing of approximately 12 to 22 carbon atoms, fatty acid anhydrides from fatty acids of approximately 12 to 22 carbon atoms and organic isocyanates containing approximately 12 to 22 carbon atoms. It is also possible to consider the use of mixtures of reactive sizing agents.
    [0046] Alkenyl succinic anhydrides (ASA) are composed of unsaturated hydrocarbon chains containing pendant succinic anhydride groups. They are usually made using a two-step method that eats an Alf olefin. The olefin is initially isomerized by randomly moving the double bond from the alpha position. In the second step, the isomerized olefin with maleic anhydride is reacted to reach the final ASA, having the standard formula (1) (see below). Typical olefins used for the reaction as maleic anhydride include alkenyl, cycloalkenyl, and aralkenyl components containing from approximately 8 to approximately 22 carbon atoms. Specific examples are isooctadecenyl succinic anhydride, n-octadecenyl succinic anhydride, n-hexadecenyl succinic anhydride, n-dodecyl succinic anhydride, i-dodecenyl succinic anhydride, n-decenyl succinic anhydride and n-ctenyl succinic anhydride.

    Alkenyl succinic anhydrides are disclosed in US Patent. No. 4,040,900 which is incorporated herein by reference in its entirety and by C.E. Farley et R.B. Wasser in The Siziong of Paper, Second Edition, edited by W.F. Reynolds, Tappi Press, 1989, pages 51-62. Various alkenyl succinic anhydrides are commercially available from Bercen Inc. Denham Springs, LA, The alkenyl succinic anhydrides for use in the invention are preferably liquid at 25°C. Most preferably they are liquid at 20 °C
    [0048] Preferred ketene dimers and multimers are matters of formula (2) (see below), in which n is an integer from 0 to about 20, R and R", which may be identical or different, are alkyl groups or straight chain or branched alkenyls, saturated or not having 6 to 24 carbon atoms, and R' is a straight chain or branched alkenyl group, saturated or not having from about 1 to about 40 carbon atoms.

    [0049] The ketene dimers that will constitute the dispersed phase role in the method of this invention have the structure of formula (2) in which n = ) and the groups R and R", which may be identical or different, are hydrocarbon radicals. Preferably, the R and R" groups are straight or branched chain alkyl or alkenyl groups having 6 to 24 carbon atoms, cycloalkyl groups having at least 6 carbon atoms, aralkyl groups having at least 7 carbon atoms, alkylaryl groups having at least 7 carbon atoms, and mixtures thereof. Preferably, the ketene dimer is selected from the group consisting of (a) octyl, decyl, dodecyl, tetradecyl, hexadecyl, octadecyl, eicosyl, docosyl, tetracosyl, phenyl, benzyl, beta-naphthyl and the cyclohexyl ketene dimers , and (b) ketene dimers prepared from organic acids selected from the group consisting of montanic acid, naphthenic acid, 9,10-decylenic acid, 9,10-dodecylenic acid, palmitoleic acid, oleic acid, of ricinoleic acid, linoleic acid, eleostearic acid, the natural mixtures of fatty acids found in coprah oil, babassu oil, palm kernel oil, palm oil, olive oil, peanut oil, in rapeseed oil, ox bath, lard, whale lard, mixtures of any of the aforementioned acids. More preferably, the ketene dimer is selected from the group consisting of octyl, decyl, dodecyl, tetradecyl, hexadecyl, octadecyl, axisosyl, docosyl, tetracosyl, phenyl, benzyl, β-naphthyl, and cyclohexyl ketenes dimer.
    [0050] Alkylketene dimers have been used commercially for many years and are prepared by dimerization of alkylketenes obtained from straight chain saturated fatty acid chlorides; those that are most widely used are obtained from palmitic and/or stearic acid. Pure alkylketene dimer is available from Ashland Hercules Water Technologies, Ashland Inc, Wilmington, Del. as a sizing agent under the name AQUAPEL 364.
    [0051] Preferred ketene multimers to be used as the dispersed phase in the method of this invention have the formula (2) in which n is an integer equal to at least 1, R and R", which may be identical or different, are alkyl groups or straight chain or branched alkenyls, saturated or not having 6 to 24 carbon atoms, preferably 10 to 20 carbon atoms, and even more preferably 14 to 16 carbon atoms, and R' is an alkylene group of straight or branched chain, saturated or not, having from 2 to 40 carbon atoms, preferably from 4 to 8 carbon atoms or from 28 to 40 carbon atoms.
    Preferred ketene multimers are described in European Patent Application Publication No. 0 629 741 A1 and in US patents. Nos. 5,685,815 and 5,846,663, both being incorporated into the case by reference in their entirety.
    Among the preferred ketene dimers and multimers to be used as the dispersed phase in the invention are those that are not in solid form at 25 °C (solid matter not substantially crystalline, semi-crystalline or waxy; i.e., which they run off by heating without heat of fusion). Ketene dimers and multimers that are not in the solid state at 25°C are disclosed in US Patent Nos. 5,685,815, 5,846,663, 5,725,731, 5,766,417 and 5,879,814, each of which is incorporated in the case by reference in its entirety. Ketene dimers that are not solid state at 25°C are supplied by Ashland Hercules Water Technologies, Wilmington, Del., as sizing agents under the names PRE-QUEL and PRECIS.
    [0054] Other preferred cellulose reactive glues to be used in dispersed phase form in the invention are mixtures of ketene dimers or multimers with alkenyl succinic anhydrides as described in the US patent. No. 5,766,417, which is incorporated into the case by reference in its entirety.
    The adhesives which do not react with cellulose in the form of the dispersed phase in the invention preferably include hydrophobic materials which flow freely at temperatures below 95°C, preferably below 70°C, wax, rosin , esterified, hydrocarbon resins or terpenes, and polymer sizing agents.
    [0056] Also, sizing emulsions of this invention may conveniently contain at least one surface agent in order to facilitate their emulsification in water, such matters are well known in the art. The surface agent component facilitates emulsification of the sizing agent with a water component when emulsifying. Generally, surface agents are anionic or non-ionic or they can be cationic and can have a wide range of HLB values.
    [0057] Suitable surface agents include, but are not limited to, phosphate ethoxylates which may contain hydrocarbon alkyl, aryl, aralkyl, or alkenyl substituents, sulfonated products, such as those obtained, sulfonating fatty alcohols or aromatic fatty alcohols, ethoxylated alkyl phenols such as nonyl phenoxy polyethoxy ethanols, octyl phenoxy polyethoxy ethanols, polyethylene glycols such as PEG 400 monooleate and PEG 600 dilaurate, ethoxylated phosphate esters, sulfo dialkyl succinates, such as sodium dioctyl sulfosuccinate, alkyl polyoxy alkylene or alkyl aryl polyoxy alkylene esters or the corresponding mono or diesters, and trialkyl amines and their acids and quaternary salts as well as amine hydrates, such as oleyl dimethyl amine and stearyl dimethyl amine.
    [0058] Preferred surface agents are those that emulsify the sizing agent to achieve the average droplet diameter of the emulsion or smaller particle size. Such emulsions may have an average droplet diameter or particle size of approximately 2 microns or less, preferably between 0.5 and 1.5 microns, and more preferably about 1 micron or less. Droplet size can be conveniently measured by any well-known particle size measurement technique, for example, the microscopic, classical or quasi-elastic light scattering, sedimentation, disk centrifugation, electrozone detection methods, chromatographic and fractionation of runoff in a field at sedimentation equilibrium. Conveniently, droplet sizes can be estimated by a light scattering method using an instrument such as the HORIBA LA-300 Particle Size Analyzer.
    [0059] Of course, the amount of surface agent can vary depending on the specific surface agent, or the mixture of surface agents used, as the person skilled in the art is well aware. The amount of surface agent present in a sizing composition of the invention should not exceed the minimum to have an average particle size of approximately 2 microns or less, preferably between 0.5 and 1.5 microns and more preferably of about 1 micron or less resulting emulsion. Higher amounts can lead to particle size degradation and machine behavior problems that are a consequence of a poor quality emulsion. From the order of 0.01% to approximately 10% surface agent by weight, based on the total weight of sizing agent, may be used. Preferably, the quality of surface agent present in a sizing composition ranges from approximately 0.1% to approximately 5% by weight. More preferably, the amount of surface agent present in a sizing composition is less than approximately 1.0% by weight. Commercially available blends comprising at least one sizing agent and at least one surface agent, such as the PREQUEL 20F or PREQUEL 90F sizing agents supplied by Ashland Inc., Wilmington, Del., can be conveniently used for forming of the sizing emulsions of the invention.
    [0060] With reference to oil-in-water emulsions, such as sizing agent emulsions, the continuous phase can be water or an aqueous solution of a natural or synthetic polymer. Water is preferred. If the continuous phase is water, post-dilution of the emulsion with water to obtain a desired solids content, followed by further dilution with an aqueous solution based on natural or synthetic polymer is recommended. Cationic polymers that can be used to form oil-in-water emulsions of sizing agents include any water-soluble nitrogen-containing cationic polymer that imparts a positive surface charge to the particles in the dispersed phase of the emulsion. Typically, these cationic polymers are quaternary ammonium compounds; ethylene unsaturated amine homopolymers or copolymers; the resinous reaction products of epihalohydrins and polyaminopolyamides; alkylenepolyamines; poly(dialyl amines), bisamino propyl piperazine, dicyandiamide (or cyanamide)-polyalkylene polyamine condensates, dicyandiamide (or cyanamide)-formaldehyde condensates, and dicyandiamide (or cyanamide)-bis-amino propyl piperazine condensates; and cationic starches. Cationic starches are water-soluble starches containing amino groups, quaternary ammonium or other cationic groups in sufficient quantity so that the starch as a whole has a pronounced affinity for cellulose. Cationic indium is preferred. Non-cationic polymers can also be used.
    [0061] The use of cationic polymers in sizing compositions is globally described in US Patent Nos. 4,240,935, 4,243,481, 4,279,794, 4,295,931, 4,317,756, 4,522,686, all issued in Dumas, in US Patent No. 2,961,366 issued Weisgerber and US Patent No. 5,853,542 (released in Bottorff). Atmospheric polymers despite those disclosed in U.S. Patent No. 7,270,727 (Varnell), may also be used. The entire contents of each of these patents are incorporated in the case by reference.
    [0062] The minimum amount of cationic polymer used must be sufficient so that the dispersion becomes cationic. The amount used will vary as a function of water solubility and the cationic strength of the particular polymer employed, as well as other variables such as water quality.
    [0063] The amount of natural or synthetic polymer can be expressed as a percentage of the weight of the glue that reacts with the cellulose used. Preferably, the amount of polymer is from approximately 0.1% to approximately 400% by weight relative to the weight of the glue which reacts with the cellulose, more preferably from approximately 2 to approximately 100% by weight relative to the weight of the cellulose. cellulose-reactive size, and most preferably from approximately 10 to approximately 30% by weight relative to the weight of the cellulose-reactive size. This amount will depend on the requirements of a specific paper production application.
    [0064] The temperature of the aqueous solution used for the dilution station is generally less than approximately 50 °C, but may be higher, depending on the application. The pH of the aqueous solution varies depending on the application. The pH can be in the range of 4 to 8 approximately. Post-dilution is generally performed under low shear conditions, for example, under the shear conditions created by a device such as a centrifugal pump, a static in-line mixer, a peristaltic pump, a rod stirrer, or combinations of such devices.
    [0065] The sizing agent emulsions prepared by this invention can be used in the context of internal sizing of paper or cardboard where the sizing emulsions are added to the liquid paste at the level of the wet end of the paper making process, or to surface sizing of paper or cardboard in which the sizing dispersions are applied at the level of the size press or the applicator. This invention can also be used in one or both parts of a two part bonding system. For example, one part can be mixed internally with the wood pulp and a second part applied at the size press level, a common practice in papermaking.
    [0066] The amount of sizing agent added to the paste or applied in the form of surface glue ranges from approximately 0.005 to 5% by weight, based on the siccity of the paste, i.e., the fibers and optional fillers, and, preferably from 0.01 to 1% by weight, where the dosage depends mainly on the quality of the pulp or paper to be glued, the sizing compound used and the level of sizing desired.
    [0067] The chemical elements conventionally added to the pulp, when producing paper or cardboard, such as treatment aid agents (e.g. retention aid agents, drainage aid agents, water control additives contaminants, etc.) or other functional additives (e.g., wet or dry strength enhancing additives, dyes, optical brightening agents, etc.) may be used in combination with the sizing agents of this invention.
    [0068] The invention has been described in the case with reference to a dispersed phase which may contain a sizing agent. As a variant, the venturi device 50 of this invention can also be used for preparing the inverse emulsion polymers commonly used in the papermaking process. Inverse emulsion polymers are prepared and stabilized using surface active agents, more commonly called surface agents. The surface agents used will allow the emulsification of the water-soluble monomer in the oil phase, prior to polymerization, and provide stability to the resulting emulsion polymer. Stability that includes resistance to sedimentation, minor changes in viscosity over time and premature inversion, without forgetting the need to have a stable emulsion during the polymerization process, requires a robust set of emulsion stabilization .
    [0069] The inversion of the emulsion refers to the process before use, in which the phases are inverted and the polymer is released from the discontinuous phase. A large volume of aqueous solution is added in order to create a continuous aqueous (water) phase, in which coalescence of the previously dispersed aqueous phase reaches the polymer dispersion in the solution, making the solution viscous. Surface agents, called "disaggregating surface agents", are added to the emulsion to favor inversion, in order to disturb the original emulsion's stabilization system, when the relatively large volume of water is combined, having resorted to a certain level of stirring or shearing, with the water-in-oil emulsion. It is the joint action of these three factors, the considerable volume of the dispersed phase, the shear forces, and the surface disaggregating agent(s), which results in the inversion, or phase inversion, of the emulsion. Furthermore, the polymer can presently interact with other matters with aqueous phases. The relatively small amount of oil (20 - 40% by weight of the original emulsion) is dispersed in the aqueous phase, where, due to the addition of the large volume of aqueous solution, the oil is a minor component.
    [0070] The polymer is inverted in an aqueous solution so that the resulting concentration of active polymer is typically in the range of approximately 0.1% to approximately 1.5% by weight. The concentration used depends on a number of factors, including, but not limited to, water temperature and chemistry, solution viscosity, delivery rate, and equipment dimensions and flow rates.
    [0071] It is possible to invert the emulsion polymer in an aqueous solution, directing converging flows of water and pure emulsion to the desired concentrations through the venturi device 50. In this inversion, the continuous phase is water, which is introduced by the first inlet 48 of the venturi device 50, and the dispersed phase is the polymer-based emulsion or crude emulsion, which is introduced through the suction inlet 52 of the venturi device 50. The pressure of the continuous phase can be in the range of approximately 1 to 4 MPa (10 to 40 bar), preferably from approximately 1.5 to 2.5 MPa (15 to 25 bar), and the flow rate of the continuous phase can be approximately 10 to 50 m/s, preferably from approximately 25 to 35 m/s. The resulting mixture then undergoes a mixing step, in a static mixer or a mechanical pump, in which the mixing action improves the inversion process. Typically, the aqueous solution is then transferred into a reservoir, where it is mixed until it becomes homogeneous. In a continuous system, the transfer step to a reservoir is eliminated.
    [0072] Typically, the added dilution water is added to the invert polymer solution just prior to introduction into the process to aid dispersion of the polymer. EXAMPLES Example 1
    [0073] 150 l/h were fed as continuous phase into a first input of a venturi device as shown in figures 2-4. The water supply pressure is 3 MPa (30 bar). The nozzle diameter for continuous phase (eg nozzle diameter 66 in figure 3) is 1 mm. A dispersed phase based on PREQUEL 20F sizing agent (an ASA) was supplied under vacuum to the suction inlet of the venturi device at 15 kg/h. The nozzle diameter for mixed phase (eg the nozzle diameter 60 in figure 3) is 2 mm. Venturi velocity is 53 m/s at the nozzle for continuous phase. The median particle size of the emulsion is 0.67 microns. Example 2
    [0074] 170 l/h of water were fed as continuous phase into a first inlet of a venturi device as shown in figures 2-4. The water supply pressure is 3 MPa (30 bar). The nozzle diameter for continuous phase (eg nozzle diameter 66 in figure 3) is 1 mm. A dispersed phase based on PREQUEL 20 F sizing agent (an ASA) was supplied under vacuum to the suction inlet of the venturi device at 27 kg/h. The nozzle diameter for mixed phase (eg nozzle diameter 60 in figure 3) is 2 mm. Venturi velocity is 60 m/s at the nozzle for continuous phase. The median particle size of the emulsion is 0.67 microns. Example 3
    [0075] 80 l/h of water was fed as a continuous phase into a first inlet of a venturi device as shown in figures 2-4. The water supply pressure is 3.1 MPa (31 bar) (page 23 line9). The nozzle diameter for continuous phase (eg nozzle diameter 66 in figure 3) is 0.8 mm. A dispersed phase based on PREQUEL 20F sizing agent (an ASA) was supplied under vacuum to the suction inlet of the venturi device at 8 kg/h. The nozzle diameter for mixed phase (eg nozzle diameter 60 in figure 3) is 1.6 mm. Venturi velocity is 44 m/s at the nozzle for continuous phase. The median particle size of the emulsion is 0.82 microns. Example 4 (comparative example)
    [0076] 180 l/h of water was fed as continuous phase into a first inlet of a venturi device as shown in figures 2-4. The water supply pressure is 3.2 MPa (32 bar). The nozzle diameter for continuous phase (eg nozzle diameter 66 in figure 3) is 1 mm. A dispersed phase based on PREQUEL 20F sizing agent (an ASA) was supplied under vacuum to the suction inlet of the venturi device at 15 kg/h. The nozzle diameter for mixed phase (eg nozzle diameter 60 in figure 3) is 1 mm (same diameter for continuous phase and mixed phase nozzle). Venturi velocity is 63 m/s at the mixed phase nozzle. The emulsion almost immediately dispersed into separate phases: water and ASA drops. It was impossible to measure the particle size distribution. Example 5
    [0077] 160 l/h of water was fed as continuous phase into a first inlet of a venturi device as shown in figures 2-4. The water supply pressure is 3 MPa (30 bar). The nozzle diameter for continuous phase (eg nozzle diameter 66 in figure 3) is 1 mm. A dispersed phase based on PREQUEL 90F sizing agent (an AnKD supplied by Ashland Hercules Water Technologies, Wilmington, Del.) was supplied under vacuum to the suction inlet of the venturi device at 30 kg/h. The nozzle diameter for mixed phase (eg nozzle diameter 60 in figure 3) is 2 mm. Venturi velocity is 57 m/s at the nozzle for continuous phase. The emulsion was found to be stable with a median particle size of 0.8 microns. Example 6
    [0078] 90 l/h of water was fed as a continuous phase into a first inlet of a venturi device as shown in figures 2-4. The water supply pressure is 3 MPa (30 bar). The nozzle diameter for continuous phase (for example, the nozzle diameter 66 in figure 5) is 0.8 mm. A dispersed phase based on PREQUEL 20F sizing agent (an ASA) was supplied under vacuum to the suction inlet of the venturi device at 30 kg/h. The nozzle diameter for mixed phase (for example, the nozzle diameter 60 in figure 3) is 2.4 mm. Venturi speed is 50 m/s at the nozzle for continuous phase. The emulsion was found to be stable with a median particle size of 1.15 microns. Example 7
    [0079] 180 l/h of water was fed as continuous phase into a first inlet of a venturi device as shown in figures 2-4. The water supply pressure is 3 MPa (30 bar). The nozzle diameter for continuous phase (eg nozzle diameter 66 in figure 3) is 1.2 mm. A dispersed phase based on PREQUEL 20F sizing agent (an ASA) was supplied under vacuum to the suction inlet of the venturi device at 30 kg/h. The nozzle diameter for mixed phase (eg nozzle diameter 60 in figure 3) is 1.6 mm. Venturi velocity is 44 m/s at the nozzle for continuous phase. The emulsion was found to be stable with a median particle size of 0.8 microns.
    [0080] While the present invention has been described in connection with particular embodiments thereof, it is clear that various other forms and modifications will be apparent to the artisan. The appended claims and the present invention are to be interpreted comprehensively to encompass all such obvious forms and modifications which fall within the scope of the invention.
    权利要求:
    Claims (14)
    [0001]
    1. A system for emulsifying oil-in-water or water-in-oil comprising: - a Venturi device (50) having a nozzle (66) for continuous phase and an inlet (52) for dispersed phase, - in which the nozzle stops continuous phase has a first diameter (d1) which directs the flow of a continuous phase into a mixing section (80) of the venturi device, and - the dispersed phase inlet introduces a dispersed phase into the mixing section in order to form a dispersed phase and continuous phase emulsion; and - in which said venturi device has a nozzle (60) for mixed phase having a second diameter (d2) whereby the emulsion is led from the mixing section to an outlet of the Venturi device, - said second diameter (d2) of said Venturi device (50) being larger than said first diameter (d1) in a ratio greater than 1:1 and less than 4:1, the system characterized by the fact that it is designed so that the continuous phase - is introduced to a pressure ranging from approximately 1 MPa (10 bar) to approximately 5 MPa (50 bar), and - have a velocity in the range of approximately 10 to 100 m/s through the nozzle for continuous phase.
    [0002]
    2. System according to claim 1, characterized in that it additionally comprises a pump (22) for pumping the continuous phase inside the Venturi device (50).
    [0003]
    3. System according to any one of claims 1 or 2, characterized in that the continuous phase comprises water or an aqueous starch solution or a polymer-based solution.
    [0004]
    4. System, according to any one of claims 1 to 3, characterized in that the dispersed phase comprises one or more inverse emulsions.
    [0005]
    5. System according to any one of claims 1 to 3, characterized in that the dispersed phase comprises one or more paper sizing compounds that do not react with cellulose or paper sizing compounds reacting with cellulose, such as alkenyl succinic anhydride (ASA), alkyl ketene dimer (AKD), ketene dimers, ketene multimers, organic epoxides containing approximately 12 to 22 carbon atoms, acyl halides containing approximately 12 to 22 carbon atoms, fatty acid anhydrides from fatty acids containing approximately 12 to 22 carbon atoms, or organic isocyanates containing approximately 12 to 22 carbon atoms.
    [0006]
    6. Method for emulsifying a sizing agent to be used in the treatment of paper or cardboard comprising the fact of: - introducing under pressure into a Venturi device (50) a continuous phase containing water, said Venturi device having a nozzle (66) for continuous phase of a first diameter (d1) that directs said continuous phase in a mixing section (80); - introducing into the mixing section (80) of the Venturi device a dispersed phase containing at least one sizing agent, in order to form an emulsion of the dispersed phase and the continuous phase; - leading the emulsion through a nozzle (60) to mixed phase of a second diameter (d2) in said Venturi device; - said diameter (d2) of the nozzle for the mixed phase of said venturi device being greater than said diameter (d1) of the nozzle for continuous phase with a ratio greater than 1:1 and less than 4:1, characterized by the fact that that the continuous phase - is introduced at a pressure ranging from approximately 1 MPa (10 bar) to approximately 5 MPa (50 bar), and - has a speed in the range of approximately 10 to 100 m/s through the nozzle to continuous phase.
    [0007]
    7. Method according to claim 6, characterized in that the continuous phase comprises water or an aqueous starch solution or a polymer-based solution.
    [0008]
    8. Method according to any one of claims 6 or 7, characterized in that the dispersed phase comprises paper sizing compounds that do not react with cellulose or paper sizing compounds that do react with cellulose, such as anhydride alkenyl succinic acid (ASA), alkyl ketene dimer (AKD), ketene dimers, ketene multimers, organic epoxides containing approximately 12 to 22 carbon atoms, acyl halides containing approximately 12 to 22 carbon atoms, anhydrides of fatty acids from fatty acids containing approximately 12 to 22 carbon atoms, or organic isocyanates containing approximately 12 to 22 carbon atoms.
    [0009]
    9. Method according to any one of claims 6 to 8, characterized in that the dispersed phase additionally comprises one or more surface agents in a proportion ranging from 0.1% to approximately 5% by weight of the said dispersed phase.
    [0010]
    10. Method according to any one of claims 6 to 9, characterized by the fact that the emulsion has an average particle size below 2 microns.
    [0011]
    11. Method, according to any one of claims 6 to 10, characterized by the fact that the emulsion has a concentration of dispersed phase / continuous phase ranging from 2 to 50 percent by weight.
    [0012]
    12. Method, according to any one of claims 6 to 11, characterized by the fact that it additionally comprises the fact of post-diluting the emulsion and adding the post-diluted emulsion to a wet part or to a press of bonding or layering for a paper or cardboard manufacturing system.
    [0013]
    13. Method of inverting an inverse emulsion comprising: - introducing under pressure into a Venturi device (50) a continuous phase containing water, said Venturi device having a nozzle (66) for a continuous phase of a first diameter (d1) that direct said continuous phase into a mixing section (80); - introducing into the mixing section (80) of the Venturi device a dispersed phase containing at least one inverse emulsion, in order to form a dispersed phase and continuous phase emulsion; - leading the emulsion through a nozzle (60) to mixed phase of a second diameter (d2) in said Venturi device; - said diameter (d2) of the nozzle for mixed phase of said Venturi device being greater than said diameter (d1) of the nozzle for continuous phase with a ratio greater than 1:1 and less than 4:1 characterized by the fact that the pressure of the continuous phase is in the range of approximately 1 MPa (10 bar) to 4 MPa (40 bar), preferably approximately 1.5 MPa (15 bar) to 2.5 MPa (25 bar), and the continuous phase has a speed of approximately 10 to 50 m/s, preferably approximately 25 to 35 m/s, through the nozzle for continuous phase.
    [0014]
    14. Method according to claim 13, characterized in that the inverse emulsion comprises one or more agents to aid retention and drainage for use in paper or cardboard manufacturing systems.
    类似技术:
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    同族专利:
    公开号 | 公开日
    CA2770942C|2016-11-01|
    ZA201201603B|2013-10-28|
    WO2011015715A1|2011-02-10|
    RU2012108162A|2013-09-10|
    AU2009350832A1|2012-03-08|
    KR20120041242A|2012-04-30|
    BR112012002642A2|2020-12-15|
    MX2012001551A|2012-05-23|
    CA2770942A1|2011-02-10|
    PL2461898T3|2016-01-29|
    AU2009350832B2|2016-06-09|
    CN102639219B|2016-03-09|
    ES2550620T3|2015-11-11|
    EP2461898B1|2015-10-07|
    PT2461898E|2015-11-30|
    RU2538578C2|2015-01-10|
    US20120103546A1|2012-05-03|
    JP2013501164A|2013-01-10|
    JP5740548B2|2015-06-24|
    EP2461898A1|2012-06-13|
    KR101644212B1|2016-07-29|
    CN102639219A|2012-08-15|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    US1540592A|1924-08-25|1925-06-02|Best Robert Bertram|Emulsifying or mixing apparatus|
    GB1205675A|1968-01-05|1970-09-16|Karl Hutter|Device for mixing media, more particularly liquids|
    IT1015665B|1974-07-04|1977-05-20|Snam Progetti|METHOD FOR THE PREPARATION IN WITH TINUE OF WATER OIL EMULSIONS AND EQUIPMENT SUITABLE FOR THE PURPOSE|
    CH620134A5|1978-03-14|1980-11-14|Blaser & Co Ag|
    US4210534A|1979-05-11|1980-07-01|Clevepak Corporation|Multiple stage jet nozzle and aeration system|
    SU1590124A1|1988-04-08|1990-09-07|Институт технической механики АН УССР|Apparatus for producing fine-dispersed system|
    JPH02127594A|1988-11-02|1990-05-16|Hokuetsu Paper Mills Ltd|Sizing of papermaking raw material using substituted succinic anhydride|
    GB8910372D0|1989-05-05|1989-06-21|Framo Dev Ltd|Multiphase process mixing and measuring system|
    EP0616002B1|1992-09-18|1998-03-04|Idemitsu Petrochemical Co., Ltd.|Process for producing polycarbonate powder|
    US5403522A|1993-11-12|1995-04-04|Von Berg; Richard|Apparatus and methods for mixing liquids and flowable treating agents|
    US5595631A|1995-05-17|1997-01-21|National Starch And Chemical Investment Holding Corporation|Method of paper sizing using modified cationic starch|
    AU718417B2|1995-11-14|2000-04-13|Stockhausen Gmbh & Co. Kg|Water additive and method for fire prevention and fire extinguishing|
    DE19703779C2|1997-02-01|2003-06-05|Karlsruhe Forschzent|Method and device for producing a disperse mixture|
    AUPO609997A0|1997-04-09|1997-05-01|Queensland University Of Technology|Mixing apparatus|
    US6004024A|1997-11-14|1999-12-21|Calgon Corporation|Emulsion feed assembly|
    WO1999042545A1|1998-02-19|1999-08-26|Crystallisation & Degumming Sprl|Method for producing microcrystals of vegetable and animal fats|
    US6210475B1|1999-09-03|2001-04-03|Bayer Corporation|Use of hydroxyalkylated starches for improved emulsification of sizing agents|
    KR20020058081A|1999-12-16|2002-07-12|추후보정|Sizing composition|
    US6576049B1|2000-05-18|2003-06-10|Bayer Corporation|Paper sizing compositions and methods|
    US6796704B1|2000-06-06|2004-09-28|W. Gerald Lott|Apparatus and method for mixing components with a venturi arrangement|
    DE602004021861D1|2004-08-06|2009-08-13|Campos Carlos Miguel Moreira|DEVICE FOR MIXING FLUIDS|
    AU2008251478B2|2007-05-09|2012-01-12|Buckman Laboratories International, Inc.|ASA sizing emulsions for paper and paperboard|
    US7784999B1|2009-07-01|2010-08-31|Vortex Systems Ci|Eductor apparatus with lobes for optimizing flow patterns|US8088250B2|2008-11-26|2012-01-03|Nalco Company|Method of increasing filler content in papermaking|
    US8852400B2|2010-11-02|2014-10-07|Ecolab Usa Inc.|Emulsification of alkenyl succinic anhydride with an amine-containing homopolymer or copolymer|
    CN105051288B|2013-03-13|2017-11-07|纳尔科公司|Paper machine performance is improved using aldehyde-functionalized polymer and strengthens the method for applying glue|
    CN102817601B|2012-08-31|2015-04-08|中国石油天然气股份有限公司|Method and device for performing on-line profile control on polymer driving oil field by applying crosslinking agent|
    JP6355906B2|2012-10-05|2018-07-11|花王株式会社|Method for producing emulsion|
    JP6444062B2|2013-06-17|2018-12-26|花王株式会社|Method for producing dispersion|
    ES2681433T3|2013-07-19|2018-09-13|Philip Morris Products S.A.|Hydrophobic paper|
    US9956532B2|2013-11-07|2018-05-01|U.S. Department Of Energy|Apparatus and method for generating swirling flow|
    US9567708B2|2014-01-16|2017-02-14|Ecolab Usa Inc.|Wet end chemicals for dry end strength in paper|
    US9702086B2|2014-10-06|2017-07-11|Ecolab Usa Inc.|Method of increasing paper strength using an amine containing polymer composition|
    US9920482B2|2014-10-06|2018-03-20|Ecolab Usa Inc.|Method of increasing paper strength|
    AU2016248111A1|2015-04-13|2017-11-02|Virginia Tech Intellectual Properties, Inc.|Apparatus for dewatering and demineralization of fine particles|
    CN106917324B|2015-12-25|2019-11-08|艺康美国股份有限公司|A kind of paper-making sizing method and its paper of preparation|
    CN109072558A|2016-05-13|2018-12-21|艺康美国股份有限公司|Thin paper dust is reduced|
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    法律状态:
    2021-01-05| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|
    2021-01-12| B25A| Requested transfer of rights approved|Owner name: SOLENIS TECHNOLOGIES CAYMAN, L.P. (CH) |
    2021-01-19| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|
    2021-03-09| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|
    2021-05-25| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 04/08/2009, OBSERVADAS AS CONDICOES LEGAIS. PATENTE CONCEDIDA CONFORME ADI 5.529/DF |
    优先权:
    申请号 | 申请日 | 专利标题
    PCT/FR2009/000976|WO2011015715A1|2009-08-04|2009-08-04|Apparatus, system and method for emulsifying oil and water|
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