functional radiative cooling coating material and its application

专利摘要:
The present disclosure provides a functional coating material for radiative cooling and application thereof. The radiative cooling functional coating material can be configured to manufacture a radiative cooling functional layer. The functional radiative cooling layer can be configured to reflect ultraviolet light and / or visible light and / or near infrared light in sunlight and emit heat through an atmospheric window in the form of infrared radiation. The radiative cooling functional coating material may include a granular charge and a radiative cooling functional resin, and the granular charge may be distributed in the radiative cooling functional resin.
公开号:BR102020005870A2
申请号:R102020005870-3
申请日:2020-03-24
公开日:2021-01-19
发明作者:Shaoyu Xu；Rongbing WAN；Minghui Wang
申请人:Ningbo Radi-Cool Advanced Energy Technologies Co., Ltd.；Ningbo Ruiling Advanced Energy Materials Institute Co., Ltd.；
IPC主号:

专利说明:

[0001] [001] This application claims all the benefits arising from Patent Application No. CN 201910607455.2, filed on July 5, 2019, with the National Administration of National Intellectual Property of China, the content of which is incorporated into this document as a reference. TECHNICAL FIELD
[0002] [002] The present disclosure refers to the technical field of materials science and, in particular, to a functional coating material of radiative cooling and application thereof. BACKGROUND
[0003] [003] The sun is a huge source of radiation. When sunlight hits the earth, part of the radioactive energy is absorbed by the atmosphere and part of the radioactive energy is reflected back into the universe. Because objects on Earth can absorb radioactive energy, the surface temperature of objects on Earth can be higher than the air temperature above the Earth's surface. Objects that require cooling increase energy consumption and greenhouse gas emissions. With reference to Figure 1, the electromagnetic spectrum of solar radiation can be divided into three zones, ultraviolet light, visible light and near infrared light, whose reasons are, respectively, 6.6%, 44.7% and 48, 7%.
[0004] [004] In radiative cooling, space is considered a source of cold and the Earth and objects on Earth are considered as sources of heat to establish a channel of heat transfer by radiation. Heat can be radiated through the atmospheric window in a specific wave range of the electromagnetic spectrum without consuming energy, so that heat can be transferred directly into space through the atmospheric window to obtain cooling.
[0005] [005] In reference to Figure 2, the atmospheric window refers to electromagnetic waves that are less reflected, absorbed, dispersed and highly transmitted when they penetrate through the atmosphere. The atmospheric window is commonly electromagnetic waves in the range of 0.3 μm to 1.155 μm, 1.4 μm to 1.9 μm, 2 μm to 2.5 μm, 3.5 μm to 5 μm, 7 μm to 14 μm , etc., and has high transmittance. The medium infrared lights emitted by objects on the Earth's surface can transfer heat to outer space through these atmospheric windows in these bands.
[0006] [006] An ideal material for radioactive cooling should have optical properties of a high emissivity in the atmospheric window waveband and a very low emissivity (ie, low absorptivity) beyond the atmospheric window bands. In general, natural materials are unlikely to have such optical properties, while materials treated by some material engineering techniques may have selective optical properties for the atmospheric window, such as a high emissivity in the atmospheric window waveband and a low absorptivity beyond bands of the atmospheric window thus obtaining effective radiative cooling.
[0007] [007] In general, an energy-saving coating can reflect sunlight in bands of visible waves and near infrared by adding a charge, which results in a cooling effect. However, the cooling effect is limited, the mechanical strength is low and the weather resistance is insufficient, which leads to no practical value. SUMMARY
[0008] [008] The present disclosure provides a functional radiative cooling coating material. A radiative cooling coating layer based on the functional radiative cooling coating material has a high reflectivity in the entire solar emission energy spectrum and a high emissivity in the atmospheric window wave range (in a range of 7 μm to 14 μm ). The present disclosure also provides corresponding application methods based on the radiative cooling functional coating material and composite materials based on the radiative cooling coating layer.
[0009] [009] The present disclosure provides a functional radiative cooling coating material to manufacture a functional radiative cooling layer configured to reflect ultraviolet light and / or visible light and / or near infrared light in sunlight and emit heat through a window. atmospheric in a form of infrared radiation. The radiative cooling functional coating material may include a granular charge and a radiative cooling functional resin, and the granular charge may be distributed in the radiative cooling functional resin.
[0010] [010] In one embodiment, the granular load can be shaped like a rod, a sphere or an ellipsoid, and when the granular load is rod-shaped or ellipsoid-shaped, a ratio between a length of the granular load and a granular charge diameter can be in a range from 1: 1 to 10: 1. The length of the granular load can be a longer distance between two end points of the granular load. The diameter of the granular load can be a longer distance in a direction perpendicular to the length of the granular load.
[0011] [011] In one embodiment, the granular charge can be arranged in an orderly manner in the radiative cooling functional resin, and the ordered arrangement means that the granular charge is distributed uniformly and directionally in the functional radiative cooling resin.
[0012] [012] In one embodiment, the granular charge can include a first granular charge and / or a second granular charge, and the first granular charge can have a diameter in the range of 0.5 μm to 40 μm. The functional radiative cooling layer that includes the first granular charge can be configured to reflect visible light and nearby infrared light and emit heat through the atmospheric window in the form of infrared radiation.
[0013] [013] The second granular charge can have a diameter in the range of 0.01 μm to 40 μm. And the functional radiative cooling layer, which includes the second granular charge, can be configured to reflect ultraviolet light and visible light and emit heat in the form of infrared radiation through the atmospheric window. A granular charge diameter can be a medium volume diameter of the granular charge in the present disclosure.
[0014] [014] In one embodiment, the first granular charge and the second granular charge can be aluminum silicate, pearl powder, silicon dioxide, calcium carbonate, aluminum oxide, zinc oxide, zirconium oxide, cerium oxide, respectively. , lanthanum oxide, rhodium dioxide, barium sulfate, talcum powder, titanium dioxide, zinc sulfide, ceramic powder, magnesium oxide, ceramic microspheres, glass microspheres or a combination thereof.
[0015] [015] In one embodiment, the first granular filler can be aluminum silicate, pearl powder, silicon dioxide, calcium carbonate, barium sulfate, talcum powder, titanium dioxide, zinc sulfide, ceramic powder, microspheres of ceramic, glass microspheres or a combination thereof.
[0016] [016] In one embodiment, the second granular charge can be aluminum oxide, zinc oxide, zirconium oxide, cerium oxide, lanthanum oxide, rhodium dioxide, magnesium oxide or a combination thereof.
[0017] [017] In one embodiment, the functional radiative cooling resin can be epoxy resin, polyester, polyurethane, acrylic resin, silicone resin or a combination thereof.
[0018] [018] In one embodiment, the radiative cooling functional coating material may additionally include a directional agent configured to control an orientation of the granular load.
[0019] [019] In one embodiment, the directional agent may be aquosobutyl cellulose acetic acid, ethylene-vinyl acetate copolymer wax emulsion, polyethylene wax, polyamide wax or a combination thereof.
[0020] [020] In one embodiment, the functional radiative cooling coating material may additionally include a pigment.
[0021] [021] In one embodiment, the pigment can be a fluorescent dye.
[0022] [022] The present disclosure may additionally provide a method of applying the radiative cooling functional coating material, which comprises coating the radiative cooling functional coating material on a substrate or main body surface to obtain a functional layer of radiative cooling, in which the functional radiative cooling layer is configured to reflect and / or emit heat to the outside.
[0023] [023] In one embodiment, the substrate can be one made of metal, plastic, rubber, concrete, cement, asphalt, paper, textile, wood, ceramic tile, glass and organic synthetic material.
[0024] [024] In one embodiment, the main body may be one of a building, a photovoltaic module, a system comprising the photovoltaic module, an automobile, an outdoor product, agricultural, livestock and aquaculture greenhouses, aerospace equipment, a device cold chain transport, an external enclosure, textile industry, external communication equipment, industrial equipment, a utility equipment, a cooling water system, an energy system and energy saving equipment.
[0025] [025] The present disclosure may additionally provide a selective radiative cooling coating layer that includes the radiative cooling functional layer manufactured from the radiative cooling functional coating material.
[0026] [026] In one embodiment, the radiative cooling functional layer may include a first radiative cooling functional layer and a second radiative cooling functional layer, the first radiative cooling functional layer may include the radiative cooling functional resin and a first charge granular distributed in the radiative cooling functional resin, and the second radiative cooling functional layer may include the radiative cooling functional resin and a second granular charge distributed in the radiative cooling functional resin.
[0027] [027] In one embodiment, the first functional layer of radiative cooling can have a thickness of 30 μm to 300 μm, and the second functional layer of radiative cooling can have a thickness of 10 μm to 60 μm.
[0028] [028] In one embodiment, the functional radiative cooling layer may include a first surface and a second surface away from the first surface, the selective radiative cooling coating layer additionally including a weather resistant resin layer located on the first surface of the layer functional radiative cooling and / or a first layer of resin located on the second surface of the functional radiative cooling layer.
[0029] [029] In one embodiment, the weather-resistant resin layer can have a transmittance that is greater than or equal to 80%, and a weather-resistant resin layer material can include fluorine-containing resin, epoxy resin, polyester, polyurethane, acrylic resin, silicon resin or a combination thereof.
[0030] [030] A material of the first resin layer may include an epoxy resin and / or an acrylic resin.
[0031] [031] In one embodiment, the weather-resistant resin layer can be 10 μm to 50 μm thick and the first resin layer can be 10 μm to 50 μm thick.
[0032] [032] In one embodiment, a weight ratio between the granular load and the functional radiative cooling layer can be in the range of 1:10 to 6: 1.
[0033] [033] In one embodiment, the functional radiative cooling layer may have a solar energy reflectivity that is greater than or equal to 80% and an atmospheric window emissivity that is greater than or equal to 80%, and is capable of providing a power radiative cooling greater than or equal to 100 W / m2 at room temperature.
[0034] [034] The present disclosure additionally discloses a composite material that includes the selective radiative cooling coating layer that additionally includes a substrate, and the selective radiative cooling coating layer can be arranged on the substrate.
[0035] [035] In one embodiment, the substrate can be one made of metal, plastic, rubber, concrete, cement, asphalt, paper, textile, wood, ceramic tile, glass or organic synthetic material.
[0036] (1) A camada de revestimento de resfriamento radiativo seletivo da presente revelação tem uma refletividade de energia solar (em uma faixa de 300 nm a 2.500 nm) que é maior ou igual a 80% e uma emissividade de janela atmosférica que é maior ou igual a 80%, e é capaz de fornecer uma potência de resfriamento radiativo maior ou igual a 100 W/m2 à temperatura ambiente. (2) A camada de revestimento de resfriamento radiativo seletivo da presente revelação tem uma resistência mecânica alta, boa resistência às intempéries e grande valor prático. [036] As can be seen in the technical proposals above, the modalities of the present disclosure have the following advantages: (1) The selective radiative cooling coating layer of the present disclosure has a solar energy reflectivity (in a range of 300 nm to 2,500 nm) that is greater than or equal to 80% and an atmospheric window emissivity that is greater than or equal to 80%, and is capable of providing radiative cooling power greater than or equal to 100 W / m2 at room temperature. (2) The selective radiative cooling coating layer of the present disclosure has a high mechanical strength, good weather resistance and great practical value.
[0037] [037] Figure 1 is a spectrum of solar radiation energy, where in the spectrum of solar radiation energy per minute, the ratios of ultraviolet light, visible light and near infrared light are respectively 6.6%, 44.7% and 48.7%.
[0038] [038] Figure 2 is a spectrum of atmospheric transmittance, in which the atmospheric window refers to electromagnetic waves that are less reflected, absorbed, dispersed and highly transmitted when they penetrate through the atmosphere.
[0039] [039] Figure 3a is an enlarged microscopic view of a first rod-shaped granular charge in one embodiment of the present disclosure, in which a ratio between a length of the first rod-shaped granular charge and a diameter of the first granular charge in rod shape is about 5: 1 and a medium volume diameter of the first rod-shaped granular charge is about 9.8 μm. The length of the granular load can be a longer distance between two end points of the granular load. The diameter of the granular load can be a longer distance in a direction perpendicular to the length of the granular load.
[0040] [040] Figure 3b is an enlarged microscopic view of a second rod-shaped granular charge in another embodiment of the present disclosure, in which a ratio between a length of the second rod-shaped granular charge and a diameter of the second granular charge in shank shape is about 4: 1 and a medium volume diameter of the second shank shaped granular charge is about 4.6 μm. The length of the granular load can be a longer distance between two end points of the granular load. The diameter of the granular load can be a longer distance in a direction perpendicular to the length of the granular load.
[0041] [041] Figure 3c is an enlarged microscopic view of a third rod-shaped granular charge in another embodiment of the present disclosure, in which a ratio between a length of the third rod-shaped granular charge and a diameter of the third granular charge in rod shape is about 3: 1 and a medium volume diameter of the third rod-shaped granular charge is about 1.6 μm. The length of the granular load can be a longer distance between two end points of the granular load. The diameter of the granular load can be a longer distance in a direction perpendicular to the length of the granular load.
[0042] [042] Figure 4a is a cross-sectional view of a first layer of selective radiative cooling coating in one embodiment of the present disclosure, with the first layer of selective radiative cooling coating including four layers from the bottom up which are, respectively, a first layer of resin 1, a first functional layer of radiative cooling 2, a second functional layer of radiative cooling 3 and a layer of weather-resistant resin 4, and a first granular charge 21 and a second granular charge 31 are in an orderly disposition.
[0043] [043] Figure 4b is a cross-sectional view of a second layer of selective radiative cooling coating in another embodiment of the present disclosure, the second layer of selective radiative cooling coating that includes four layers from the bottom up is different from of the structure shown in Figure 4a by the fact that the positions of the first functional radiative cooling layer 2 and the second functional radiative cooling layers 3 are exchanged.
[0044] [044] Figure 4c is a cross-sectional view of a third layer of selective radiative cooling coating in another embodiment of the present disclosure, the third layer of selective radiative cooling coating that includes three layers from the bottom up is different from the structure shown in Figure 4a by the fact that the first radioactive cooling functional layer 2 and the second radioactive cooling functional layer 3 are combined in one layer.
[0045] [045] Figure 4d is a cross-sectional view of a fourth layer of selective radiative cooling in another embodiment of the present disclosure, the fourth layer of selective radiative cooling that includes three layers from the bottom up is different from the structure shown in Figure 4a due to the fact that a layer of weather-resistant resin layer is omitted.
[0046] [046] Figure 4e is a cross-sectional view of a fifth layer of selective radiative cooling coating in another embodiment of the present disclosure, the fifth layer of selective radiative cooling coating that includes two layers from the bottom up is different from the structure shown in Figure 4a by the fact that the first layer of resin 1 and the layer of weather-resistant resin 4 are omitted.
[0047] [047] Figure 5a is a relational plot between a thickness of the first functional layer of radiative cooling and reflectivity in the wavelength range from 400 nm to 760 nm and 760 nm at 2,500 nm. The reflectivity of the first functional layer of radiative cooling 2 was related to its thickness, and the thicker the thickness, the greater the reflectivity. When the thickness was greater than or equal to 130 μm, the reflectivity increased slowly and substantially reached saturation.
[0048] [048] Figure 5b is a relational plot between a thickness of the second functional layer of radiative cooling and reflectivity in the wave range from 300 nm to 400 nm, 400 nm to 760 nm. The reflectivity of the second functional layer of radiative cooling 3 was related to its thickness, and the thicker the thickness, the greater the reflectivity. When the thickness was greater than or equal to 30 μm, the reflectivity increased slowly and reached substantially saturation.
[0049] [049] Figure 6a is a relational graph of the thickness of the first functional layer of radiative cooling and the emissivity in the wave range from 1 μm to 25 μm. The emissivity of the first functional radiative cooling layer 2 in the 7 μm to 14 μm wave range was related to the thickness of the first functional radiative cooling layer 2. The thicker the thickness, the greater the emissivity, and when the thickness was greater or equal to 100 μm, the emissivity increased slowly and reached substantially saturation.
[0050] [050] Figure 6b is a relational plot of the thickness of the second functional layer of radiative cooling and the emissivity in the range of 1 μm to 25 μm. The emissivity of the second functional radiative cooling layer 3 in the 7 μm to 14 μm wave range was related to the thickness of the first radiative cooling functional layer. The thicker the thickness, the greater the emissivity, and when the thickness was greater than or equal to 15 μm, the emissivity increased slowly and reached substantially saturation.
[0051] [051] Figure 7a is a diagram of the distribution of temperature test points for demonstration house A and demonstration house B, both with a length, width and height of 5 m, 4 m and 3 m, respectively.
[0052] [052] Figure 7b is a temperature graph of different test points on the surface of demonstration house A and in the external environment.
[0053] [053] Figure 7c is a temperature graph at different points in the longitudinal direction of demonstration house A.
[0054] [054] Figure 7d is a temperature graph of different test points on the surface of demo house B and the external environment.
[0055] [055] Figure 7e is a temperature graph at different points in the longitudinal direction of demonstration house B.
[0056] [056] Figure 8a is a schematic diagram of positions of temperature test points in the centers of water tanks C and D, each with a length, width and height of 800 mm, 800 mm, 80 mm, respectively.
[0057] [057] Figure 8b is a temperature graph of the temperature test points of water tanks C and D.
[0058] [058] Figure 9a is a schematic diagram of the temperature test points in tent E and tent F.
[0059] [059] Figure 9b is a graph showing the temperature difference of the temperature test points in tents E and F.
[0060] [060] Figure 10a is a schematic diagram of the temperature test points on helmets G and H.
[0061] [061] Figure 10b is a graph showing the temperature of the temperature test points on helmets G and H.
[0062] [062] Figure 11 is a graph showing the temperature of the front and rear temperature test points of impermeable rolled material I and J. DETAILED DESCRIPTION
[0063] [063] The technical proposals for the modalities of the present disclosure will be described clearly and completely below in combination with drawings. It is evident that the modalities described are only part and not all of the modalities of the present disclosure. All other modalities obtained by a person skilled in the art based on the modalities of the present disclosure without any creative efforts are within the scope of the present disclosure.
[0064] [064] The terms "first", "second", "third" and the like in the specification and claims of the present disclosure and in the drawings mentioned above are used to distinguish different objects, and are not intended to describe a specific order. In addition, the terms "comprises", "includes" and any variants thereof are intended to cover a non-exclusive inclusion.
[0065] [065] One embodiment of the present disclosure provides a functional radiative cooling coating material to manufacture a functional radiative cooling layer. The functional radiative cooling layer is configured to reflect ultraviolet light and / or visible light and / or near infrared light in sunlight and emit heat through an atmospheric window in the form of infrared radiation. The radiative cooling functional coating material may include a granular charge and a radiative cooling functional resin, and the granular charge may be distributed in the radiative cooling functional resin.
[0066] [066] The granular charge can be shaped like a rod, an oidecuboid, a cube, a sphere, an ellipsoid, a polyhedron, an axis, a plate or an irregular shape. In addition, the granular charge may have a selectable shape so that the granular charge has an enhanced resonance surface plasmon absorption over a wave range of the atmospheric window. In order to further improve a reflection of sunlight (in a wave range of 0.3 μm to 2.5 μm) of the functional radiative cooling layer and an emissivity of the atmospheric window (in a wave range of 7 μm at 14 μm), the granular load may preferably be rod-shaped, spherical or ellipsoidal. When the granular load is rod-shaped or ellipsoidal, a ratio between a length of the granular load and a diameter of the granular load can be in the range of 1: 1 to 10: 1. The length of the granular load can be a longer distance between two end points of the granular load. The diameter of the granular load can be a longer distance in a direction perpendicular to the length of the granular load.
[0067] [067] The rod-shaped granular charge may have better absorption of enhanced resonance surface plasmon from the atmospheric window with the 7 μm to 14 μm waveband, reflecting and dispersing sunlight multiple times. Thus, the functional radiative cooling layer that includes the rod-shaped granular charge can have a reflectivity superior to sunlight (in the 0.3 μm to 2.5 μm wave range), and effectively convert heat into infrared light in the 7 μm to 14 μm wave range with higher emissivity. The granular load is preferably rod-shaped as shown in Figure 3a to Figure 3c.
[0068] [068] Figure 3a to Figure 3c respectively show three types of granular rod shaped loads that have different ratios between length and diameter and average volume diameters. Referring to Figure 3a, the ratio between the length and the diameter of the granular rod loads is 5: 1 and the medium volume diameter is 9.8 μm. Referring to Figure 3b, the ratio between the length and the diameter of the granular rod loads is 4: 1 and the medium volume diameter is 4.6 μm. With reference to Figure 3c, the ratio between the length and the diameter of the granular rod loads is 3: 1 and the medium volume diameter is 1.6 μm. With reference to Figure 3a to Figure 3c, the effects of reflection and radiation in the sunlight of the three charges in the form of granular rods vary with the ratio between the length and the diameter and the diameter of the medium volume.
[0069] [069] Whereas, when manufacturing the radiative cooling functional layer by the radiative cooling functional coating material, a thickness of the radiative cooling functional layer is affected by a particle size of the rod-shaped granular charge and the ratio between the length and diameter of the rod-shaped granular charge can be selected preferably so that the granular charge can have the best absorption of enhanced resonance surface plasmon from the atmospheric window with a wave range of 7 μm to 14 μm, the ratio between the length and diameter of the rod-shaped granular load is preferably in a range of 3: 1 to 8: 1, more preferably, in a range of 4: 1 to 6: 1.
[0070] [070] The granular filler can be aluminum silicate, silicon dioxide, aluminum oxide, zinc oxide, zirconium oxide, cerium oxide, lanthanum oxide, rhodium dioxide, barium sulfate, zinc sulfide, oxide magnesium or a combination thereof. The granular filler can be pearl powder, calcium carbonate powder, talcum powder, titanium dioxide powder, ceramic powder, ceramic microspheres, glass microspheres or a combination thereof.
[0071] [071] Alternatively, the granular charge may include a first granular charge and / or a second granular charge. That is, when the radiative cooling functional coating material includes a radiative cooling functional resin and a first granular filler distributed in the radiative cooling functional resin, it can be considered as a first radiative cooling functional coating material. When the radiative cooling functional coating material includes a radiative cooling functional resin and a second granular charge distributed in the radiative cooling functional resin, it can be considered as a second radiative cooling functional coating material. The first radiative cooling functional coating material and the second radiative cooling functional coating material can be used at the same time. In use, the radiative cooling functional resin in the first radiative cooling functional coating material may be the same or different from that of the second radiative cooling functional coating material.
[0072] [072] Optionally, the first granular charge can be a material that has a high reflectivity (such as more than or equal to 80%) of visible light and near infrared, and an infrared emissivity of the atmospheric window (in the range of 7 μm to 14 μm wave) which is greater than 80%. The first granular filler can be aluminum silicate, pearl powder, silicon dioxide, calcium carbonate powder, barium sulfate, talcum powder, titanium dioxide, zinc sulfide, ceramic powder, ceramic microspheres, glass microspheres or a combination of them. The particle diameter of the first granular charge can be in the range of 0.5 μm to 40 μm. Preferably, the particle diameter of the first granular charge can be in the range of 1 μm to 20 μm, and more preferably, in the range of 2 μm to 6 μm.
[0073] [073] The second granular charge can be a material that has a high reflectivity (such as more than or equal to 80%) of ultraviolet light and visible light, and an infrared emissivity of the atmospheric window (in the wavelength of 7 μm to 14 μm) which is greater than 80%. The second granular charge can be aluminum oxide, zinc oxide, zirconium oxide, cerium oxide, lanthanum oxide, rhodium dioxide, magnesium oxide or a combination thereof. The particle diameter of the second granular charge can be in the range of 0.01 μm to 40 μm. Preferably, the particle diameter of the first granular charge can be in the range of 0.1 μm to 10 μm, and more preferably, in the range of 0.6 μm to 5 μm.
[0074] [074] Alternatively, when the granular charge in the radiative cooling functional coating material includes the first granular charge and the second granular charge, or when the first radiative cooling functional coating and the second radiative cooling functional coating are used simultaneously, the particle diameter of the first granular charge can be greater than the particle diameter of the second granular charge, and the ratio of the length to the diameter of the first granular charge is greater than the ratio of the length to the diameter of the second granular charge . Granular loads with different particle diameters and different length-to-diameter ratios can have different functions. Granular charge with a large particle diameter and a large ratio of length to diameter can better reflect visible light and near infrared light. The granular charge with a small particle diameter and a small ratio between length and diameter can better reflect ultraviolet light and visible light. The granular charge with the large particle diameter and the large ratio between length and diameter can emit infrared light in the wave range of 7 μm to 14 μm, while the granular charge with the small particle diameter and the large ratio between the length and diameter can additionally enhance an emission of infrared light from the functional radiative cooling layer in the 7 μm to 14 μm wave range.
[0075] [075] It can be understood that, when the granular load in the functional radiative cooling coating is of only one type, but has different particle diameters and ratios between length and diameter, according to the action of the large particle size and of the aforementioned small particle size particle size, the larger particle size charge may act more like a first charge and the smaller particle size charge may act more like a second charge.
[0076] [076] Alternatively, the granular charge can be arranged ordered in the functional radiative cooling resin. The ordered arrangement means that the granular load is distributed evenly and directionally in the functional radiative cooling resin and even in the functional radiative cooling layer. When the granular charge is directionally distributed in the functional layer of radiative cooling, an angle between a longer diameter of the granular charge and a surface of the functional layer of radiative cooling can be in a range of 0 degrees to 45 degrees, preferably in a range from 0 degrees to 30 degrees. Granular charges can be arranged in an orderly manner, so that the granular charge can be evenly distributed in the functional radiative cooling resin and the functional radiative cooling layer can have the enhanced resonance surface plasmon absorption in the atmospheric window with the band from 7 μm to 14 μm and the reflection of sunlight at a certain controlled angle, thereby the reflectivity of ultraviolet light, visible light and near infrared light and the emissivity of infrared light in the 7 wavelength range. μm to 14 μm of the functional radiative cooling layer can be improved.
[0077] [077] An orientation of the granular load can be controlled by an additive such as a directional agent added to the functional radiative cooling coating, such as aqueous acetic acid-butyl cellulose (CMCAB), ethylene-vinyl acetate copolymer wax emulsion (EVA), polyethylene wax and polyamide wax. The directional agent can align the granular load by adjusting a volatilization rate or an anchoring effect.
[0078] [078] The functional radiative cooling resin can be epoxy resin, polyester, urethane resin, acrylic resin, silicon resin or a combination thereof. The functional radiative cooling resin can have a low solar absorptivity and a higher selective emissivity. The functional radiative cooling resin can be combined with the granular charge distributed in it to improve the properties of reflecting sunlight (in a wave range from 300 nm to 2,500 nm) and emit the infrared lights of the atmospheric window in the range of wave from 7 μm to 14 μm. In addition, the radiative cooling functional resin can also improve the mechanical strength of the radiative cooling functional layer and its weather resistance.
[0079] [079] Alternatively, the radioactive cooling functional coating material in the present disclosure can be a liquid that is aqueous or oily.
[0080] [080] In some embodiments, the radiative cooling functional coating material of the present disclosure may additionally include a pigment configured to adjust the color of the radiative cooling functional coating material. The pigment can be a common colored paste, an infrared reflective pigment, a fluorescent dye or a combination thereof.
[0081] [081] In a preferred embodiment, the fluorescent dye can be added as the pigment to the radiative cooling functional coating material. The fluorescent dye may not substantially affect the reflective property of the radiative cooling functional coating material and the radiative cooling functional coating material can perform optimally.
[0082] [082] Adding pigments of different colors, the functional radiative cooling coating material can be red, orange, yellow, green, cyan, blue, lilac, gray, brown and the like. The purpose of manufacturing the functional radiative cooling coating material in different colors is to meet the color requirements in different applications.
[0083] [083] The present disclosure additionally provides a method of applying the radiative cooling functional coating material which includes coating the radiative cooling functional coating material on a substrate or main body surface to obtain a radiative cooling functional layer. . The functional layer of radiative cooling can reflect and / or emit heat to the outside.
[0084] [084] The substrate can be a metal, plastic, rubber, concrete, cement, asphalt, paper, textile, wood, ceramic tile, glass and organic synthetic material. The main body is one of a building, a photovoltaic module, a system that includes the photovoltaic module, an automobile, an outdoor product, agriculture, livestock, and aquaculture greenhouses, aerospace equipment, a cold chain transport device, an external enclosure, textile industry, external communication equipment, industrial equipment, utility equipment, a cooling water system, a power system (for example, air conditioning system, cooling system or heating system), and energy-saving equipment.
[0085] [085] The building can include an industrial building, a commercial building, a residential building, a public building and so on.
[0086] [086] Industrial equipment may include an external power distribution cabinet and the like.
[0087] [087] Utility equipment may include a street lamp and a heat sink device, a bathroom's roof and wall surfaces, a stadium pavement and the like.
[0088] [088] Optionally, a method of coating the radiative cooling functional coating material in the present disclosure can include painting, roller coating, spraying and the like. When the radioactive cooling functional coating material includes the first radioactive cooling functional coating material and the second radioactive cooling functional coating material, one layer can be prepared and dried first and then another layer can be prepared on the same.
[0089] [089] Optionally, a method for making the radiative cooling functional coating material may include: preparing raw materials such as resin, granular filler, and the additive and / or solvent; pre-dispersing raw materials at high speed, crushing and dispersing raw materials; then, evenly stir; filter and test; and finally packaging, to obtain the functional radiative cooling coating material.
[0090] [090] The present disclosure can also provide a selective radiative cooling coating layer that includes the radiative cooling functional layer manufactured by the radiative cooling functional coating material.
[0091] [091] Optionally, in the functional radiative cooling layer, a weight ratio between the granular load to the radiative cooling functional resin can be in the range of 1:10 to 6: 1. The weight ratio between the granular charge and the radiative cooling functional resin is the mass ratio between the granular charge and the solid resin in the radiative cooling functional coating material. If a weight ratio between the granular load and the radioactive cooling functional resin is reduced, the mechanical strength and weathering of the radioactive cooling functional coating material can be improved. Considering the possible improvement in reflectivity and emissivity and the cost, the weight ratio between the granular load and the radiative cooling functional resin can be preferably in a range of 1: 5 to 3: 1, and more preferably, in a range of 1: 3 to 3: 1.
[0092] [092] In some embodiments, the radiative cooling functional layer may include two or more layers, for example, including a first radiative cooling functional layer made of a first radiative cooling functional coating material and a second functional radiative cooling layer made of a second functional radiative cooling coating material. The first functional layer of radiative cooling may have the property of reflecting visible light and near infrared light and emitting heat by the infrared radiation from the atmospheric window. The second functional layer of radiative cooling can have the property of reflecting ultraviolet light and visible light and emit heat in the form of infrared radiation through the atmospheric window.
[0093] [093] Optionally, the reflectivity of visible and infrared light near the first functional layer of radiative cooling can be greater than or equal to 80%, and the emissivity in the wave range of 7 μm to 14 μm of the first functional layer of radiative cooling can be be greater than or equal to 80%. The visible and ultraviolet reflectivity of the second functional layer of radiative cooling can be greater than or equal to 80%, and the emissivity in the wave range of 7 μm to 14 μm of the second functional layer of radiative cooling can be greater than or equal to 80%. In addition, the reflectivity of visible and infrared light close to the first functional layer of radiative cooling can be greater than or equal to 90%, and the emissivity in the wavelength of 7 μm to 14 μm of the first functional layer of radiative cooling can be greater or equal to 90%; the visible and ultraviolet reflectivity of the second functional layer of radiative cooling can be greater than or equal to 90%, and the emissivity of waves in the range of 7 μm to 14 μm of the second functional layer of radiative cooling can be greater than or equal to 90%.
[0094] [094] In another embodiment, the functional radiative cooling layer can also be a layer and not be divided into two layers. The functional layer of radiative cooling can include the first granular charge and the second granular charge. That is, the first functional layer of radiative cooling and the second functional layer of radiative cooling can be combined in one layer.
[0095] [095] Optionally, the infrared emissivity (in the 7 μm to 14 μm wave range) of the radiative cooling functional layer can be greater than or equal to 80%, and the heat reflectivity (in the 300 nm wave range at 2,500 nm) of the functional radiative cooling layer can be greater than or equal to 80%. In addition, the infrared emissivity (in the 7 μm to 14 μm wave range) of the functional radiative cooling layer can be greater than or equal to 90%, and the heat reflectivity (in the 300 nm to 2500 nm wave range) ) of the functional radiative cooling layer can be greater than or equal to 90%.
[0096] [096] In some other embodiments, the selective radiative cooling coating layer may additionally include a weather resistant resin layer and / or a first resin layer. The functional radiative cooling layer can include a first surface and a second surface away from the first surface. The weather-resistant resin layer can be arranged on the first surface of the radiative cooling functional layer to protect the radiative cooling functional layer. The first layer of resin can be disposed on the second surface of the functional radiative cooling layer to contact a substrate or a main body, so that the selective radiative cooling coating layer can be disposed on the substrate or the main body.
[0097] [097] In order to obtain great weather resistance and stain resistance, the weather resistant resin layer material can be a fluorine-containing resin that includes a fluorocarbon resin (FEVE), a polyvinylidene fluoride (PVDF) resin or an ethylene-tetrafluorocarbon. Ethylene copolymer resin (ETFE), fluorinated ethylene-propylene copolymer resin (FEP), fluorine-containing acrylic resin, fluorine-containing polyester, fluorine-containing epoxy, fluorine-containing polyurethane, fluorine-containing silicone resin and so on. Alternatively, the material of the weather resistant resin layer may be other common weather resistant resins, such as epoxy resin, polyester, polyurethane resin, acrylic resin, silicone resin and so on. In addition, the transmittance of the weather-resistant resin layer 4 in a wave range from 300 nm to 2,500 nm must be greater than or equal to 80%, so that the reflectivity of the functional radiative cooling layer in sunlight is not affected .
[0098] [098] The first layer of resin can play roles in improving adhesion and anti-corrosion, and the material of the first layer of resin can be selected according to the type of the substrate, and can be an epoxy resin, an acrylic resin or a combination of the same.
[0099] [099] Optionally, a thickness of the functional radiative cooling layer can be in a range of 10 μm to 360 μm, 30 μm to 300 μm, 100 μm to 300 μm, or 100 μm to 150 μm. A thickness of the first functional radiative cooling layer can be in the range of 30 μm to 300 μm, 100 μm to 300 μm or 100 μm to 150 μm. A thickness of the second functional radiative cooling layer can be in the range of 10 μm to 60 μm, 15 μm to 60 μm or 15 μm to 30 μm. A thickness of the weather-resistant resin layer can be in the range of 10 μm to 50 μm. A thickness of the first resin layer can be in the range of 10 μm to 50 μm.
[0100] [0100] Referring to Figure 4a to Figure 4e, layers of selective radiative cooling coating with various structures are illustrated and may include all or part of the following layers from bottom to top, respectively.
[0101] [0101] Referring to Figure 4a to Figure 4e, various structures of the selective radiative cooling coating layers of the present disclosure are further described in detail and the granular load may be in the form of a rod. An enlarged microscopic view of the rod-shaped granular charge is shown in Figure 3.
[0102] [0102] Referring to Figure 4a, in some embodiments, the selective radiative cooling coating layer with a first type may include a first resin layer 1, a first radiative cooling functional layer 2, a second radiative cooling functional layer 3 and a layer of weather-resistant resin 4 in order from bottom to top. The first radiative cooling functional layer 2 may include a first radiative cooling functional resin layer 22 and a first granular charge 21 distributed in the first radiative cooling functional resin layer 22. The second radiative cooling functional layer 3 may include a second layer of radiative cooling functional resin 32 and a second granular charge 31 distributed in the second layer of radiative cooling functional resin 32. Both the first granular charge 21 and the second granular charge 31 can be distributed ordered in the first layer of functional cooling resin radiative 22 and the second layer of functional radiative cooling resin 32.
[0103] [0103] In Figure 4a, 100 denotes infrared radiation, 200 denotes solar energy, 210 denotes reflection of visible light and near infrared light, and 220 denotes reflection of ultraviolet light and visible light.
[0104] [0104] With reference to Figure 4b, in some embodiments, the selective radiative cooling coating layer with a second type may include a first resin layer 1, a second functional radiative cooling layer 3, a first functional radiative cooling layer 2 and a layer of weather-resistant resin 4 in order from bottom to top.
[0105] [0105] Unlike the structure shown in Figure 4a, the order of the first functional radiative cooling layer 2 and the second functional radiative cooling layers 3 in Figure 4b is switched.
[0106] [0106] Referring to Figure 4c, in some embodiments, the selective radiative cooling coating layer with a third type may include a first resin layer 1, a functional radiative cooling layer 5, and a weather resistant resin layer 4 in order from bottom to top. The radiative cooling functional layer 5 can include a radiative cooling functional resin layer 52, a first granular charge 21 and a second granular charge 31, and the first granular charge 21 and the second granular charge 31 can be distributed in the resin layer functional radiative cooling 52.
[0107] [0107] Unlike the structure shown in Figure 4a, the first radiative cooling functional layer 2 and the second radiative cooling functional layer 3 are combined in one layer, that is, the radiative cooling functional layer 5 in Figure 4c.
[0108] [0108] Referring to Figure 4d, in some embodiments, the selective radiative cooling coating layer with a fourth type may include a first layer of resin 1, a first functional layer of radiative cooling 2 and a second functional layer of radiative cooling 3 in order from bottom to top.
[0109] [0109] Unlike the structure shown in Figure 4a, the weather-resistant resin layer 4 is omitted in Figure 4d.
[0110] [0110] Referring to Figure 4e, in some embodiments, the selective radiative cooling coating layer with a fifth type may include a first radiative cooling functional layer 2 and a second radiative cooling functional layer 3 in order from bottom to top .
[0111] [0111] Unlike the structure shown in Figure 4a, the weather-resistant resin layer 4 and the first resin layer 1 are omitted in Figure 4e.
[0112] [0112] In addition, the first granular charge 21 and the second granular charge 31 can be randomly distributed in the radiative cooling functional resin. However, the random distribution of the first granular charge 21 and the second granular charge 31 can affect the reflectivity of ultraviolet light and / or visible light and / or near infrared light and emissivity in the 7 μm to 14 μm wave range. functional layer of radiative cooling.
[0113] [0113] It should be noted that the selective radiative cooling coating layers shown in Figures 4a to 4e are just some of the embodiments of the present disclosure in which the weather resistant resin layer and / or the first resin layer can be omitted, the first functional layer of radioactive cooling and the second functional layer of radioactive cooling can be combined in one layer or the first functional layer of radioactive cooling and the second functional layer of radioactive cooling can be inverted. The number of functional layers of radiative cooling is not limited and can be one, two, three, four, five and the like. A type and weight ratio of the granular load, a type and weight ratio of the resin, the thickness of the functional radiative cooling layer and the material and thickness of other layers can be selected as needed. The selective radiative cooling coating layer can be optimized by materials and structure to improve reflectivity and heat emissivity, especially the emissivity in the 7 μm to 14 μm wave range, obtaining an extremely excellent cooling effect.
[0114] [0114] The selective radiative cooling coating layer of the present disclosure has a reflectivity of solar spectral energy that is greater than or equal to 80% and an atmospheric window emissivity that is greater than or equal to 80%, and is capable of providing a radiative cooling power greater than or equal to 100 W / m2 at room temperature. The selective radiative cooling coating layer also has the properties of high mechanical strength and good weather resistance and has practical value. For the radiative cooling power test, see the article “Supplementary Material for Scalable-manufactured randomized glass-polymer hybrid metamaterial for daytime radiative cooling” in the journal “Science” in 2017, and the “silver-coated silicon wafer ”And“ hybrid metamaterial ”can be replaced by the radiative cooling coating material of the present disclosure.
[0115] [0115] The selective radiative cooling coating layer of the present disclosure has many advantages.
[0116] [0116] First, the selective radiative cooling coating layer has a layered structure and each layer has different functions, so that it is convenient for preparation and application.
[0117] [0117] Second, when the radiative cooling functional layer includes the first radiative cooling functional layer and the second radiative cooling functional layer, each of which has selective reflection and emission effects, and can be prepared separately and used selectively.
[0118] [0118] Third, the granular load can be mainly in the form of a rod with a special ratio between length and diameter and arranged in an order in the resin of the functional radiative cooling layer to have better performance.
[0119] [0119] Fourth, the first layer of resin can be configured to increase the adhesion between the functional radiative cooling layer and the substrate.
[0120] [0120] The present disclosure additionally provides a composite material that includes a layer of selective radiative cooling coating. The composite material can include a substrate. The layer of selective radiative cooling coating can be laid on the substrate.
[0121] [0121] The substrate can be one of metal, plastic, rubber, concrete, cement, asphalt, paper, textile, wood, ceramic tile, glass or organic synthetic material.
[0122] [0122] The radiative cooling functional coating material in modalities other than the present disclosure and its application are described above. Experimental data and corresponding engineering applications are also provided below to further describe the performance of the radiative cooling functional coating material and its cooling effect. EXPERIMENT (1) REFLECTIVITY TEST
[0123] [0123] A sample was placed on a photometer, such as a Lambda 950 UV / Vis / NIR Perkin Elmer Spectrometer, and a sample reflectivity can be measured over a wave range from 300 nm to 2500 nm, 300 nm to 400 nm , 400 nm to 760 nm, 760 nm to 2,500 nm in a wavelength range of 5 nm. An average value of the reflectivity of the sample in the wave range of 300 nm to 2,500 nm, 300 nm to 400 nm, 400 nm to 760 nm, and 760 nm to 2,500 nm was taken respectively as the reflectivity of the sample in the solar, ultraviolet, visible and near infrared, which is shown as R, R1, R2 and R3, respectively. (2) EMISSIVITY TEST
[0124] [0124] Infrared emissivity in the 7 to 14 μm wave range was tested with the use of a reflectometer such as a SOC-100 Hemispheric Directional Reflectometer.
[0125] [0125] About the thickness, Figure 5a shows a relationship between the thickness of the first functional layer of radiative cooling and the reflectivity in the wavelength range from 400 nm to 760 nm and 760 nm at 2,500 nm. Figure 5b shows a relationship between the thickness of the second functional layer of radiative cooling and reflectivity in the wave range from 300 nm to 400 nm, 400 nm to 760 nm. Figure 6a shows a relationship between the thickness of the first functional layer of radiative cooling and the emissivity in a wave range from 1 μm to 25 μm. Figure 6b shows a relationship between the thickness of the second functional layer of radiative cooling and the emissivity in the wave range from 1 μm to 25 μm. The results were as follows.
[0126] [0126] The first functional radiative cooling coating material that has an X formula was applied to a galvanized and dried sheet to obtain first functional radiative cooling layers of different thickness, such as about 70 μm, 100 μm, 130 μm, 180 μm, 260 μm, respectively. Formula X was that the first functional radioactive cooling coating material included about 80% weight ratio of acrylic resin, about 19% weight ratio of silicon dioxide and calcium carbonate powder, and about 1 % weight ratio of the directional agent (ethylene-vinyl acetate copolymer wax emulsion). A mass ratio between silicon dioxide and calcium carbonate powder was about 1: 1, silicon dioxide and calcium carbonate powder were rod shaped, the particle diameter of each was about 6 μm , and the ratio between the length and the diameter of each one was about 5: 1. An angle between the surface of the first functional radiative cooling layer and the length of silicon dioxide and calcium carbonate powder was in a range from 0 degrees to 30 degrees. With reference to Figure 5a, it can be concluded that the average reflectivity of the first functional layer of radiative cooling was related to its thickness, and the thicker the thickness, the greater the reflectivity. When the thickness was greater than or equal to 130 μm, the reflectivity increased slowly and substantially reached saturation. According to Figure 6a, the average emissivity of the first functional layer of radiative cooling in the wave range of 7 μm to 14 μm was related to the thickness of the first functional layer of radiative cooling. The thicker the thickness, the greater the emissivity, and when the thickness was greater than or equal to 100 μm, the emissivity increased slowly and reached substantially saturation.
[0127] [0127] A second functional radiative cooling coating material that has a Y formula has been applied to the galvanized sheet that has the second functional radiative cooling layer about 50 μm thick (formula X) and dried to obtain second layers functional radiative cooling of different thickness, such as about 0 μm, 15 μm, 30 μm, 45 μm, respectively. Formula Y was that the second radioactive cooling functional coating material included about 75% weight ratio of polyurethane resin, about 23% weight ratio of aluminum oxide and magnesium oxide, and about 2% weight ratio of directional agent (polyamide wax). A mass ratio between the aluminum oxide and the magnesium oxide was about 1: 1, the aluminum oxide and the magnesium oxide were rod-shaped, the particle size of each was about 3 μm, the ratio between the length and diameter of each was about 6: 1. An angle in a range of 0 degrees to 30 degrees was formed between the surface of the second functional layer of radiative cooling and the length of aluminum oxide and magnesium oxide. According to Figure 5b, it can be concluded that the reflectivity of the second functional layer of radiative cooling was related to its thickness, and the thicker the thickness, the greater the reflectivity. When the thickness was greater than or equal to 30 μm, the reflectivity increased slowly and reached substantially saturation. According to Figure 6b, the emissivity of the second functional layer of radiative cooling in the wave range of 7 μm to 14 μm was related to the thickness of the first functional layer of radiative cooling. The thicker the thickness, the greater the emissivity, and when the thickness was greater than or equal to 15 μm, the emissivity increased slowly and substantially reached saturation.
[0128] [0128] Compared to formula X, the shape of the granular charge may be different. The shapes of the granular load of the samples were rod, ellipsoid, spherical, oidecuboid and cube, respectively. The thickness of the samples from the first functional layer of radiative cooling was 80 μm, and the average reflectivity in the wave range from 400 nm to 2,500 nm and the average emissivity in the wave range from 7 μm to 14 μm of the samples after drying were tested. . The result was that the average reflectivity of the first functional radiative cooling layer in the 400 nm to 2,500 nm wave range and the average emissivity in the 7 μm to 14 μm wave range were related to the shape of the granular load, and in that order of large to small: rod> (ellipsoid and spherical)> (oidecuboid and cube).
[0129] [0129] Compared to formula Y, the shape of the granular charge may be different. The shape of the granular load of the samples were rod, ellipsoid, spherical, oidecuboid and cube, respectively. The second functional radiative cooling coating material was applied to the galvanized sheet which has the first functional radiative cooling layer with a thickness of about 150 μm (formula X) and dried to obtain samples of the second functional radiative cooling layers. The thickness of the samples was about 30 μm, and the average reflectivity in the wave range from 300 nm to 760 nm and the average emissivity in the 7 μm to 14 μm wave range after drying were tested. The result was that the average reflectivity of the second functional layer of radiative cooling in the wave range from 300 nm to 760 nm and the average emissivity in the wave range from 7 μm to 14 μm were related to the shape of the granular load, and in that order of large to small: rod> (ellipsoid and spherical)> (oidecuboid and cube).
[0130] [0130] Compared with formula X, the ratio between the length and the diameter of the granular charge may be different. The ratio between the length and the diameter of the granular load of the samples was about 3: 1, 4: 1, 6: 1, 8: 1, 9: 1, respectively. The thickness of the layers was 100 μm, and the average reflectivity in the wave range from 400 nm to 2,500 nm and the average emissivity in the wave range from 7 μm to 14 μm of the samples after drying were tested. The result was that the average reflectivity of the first functional layer of radiative cooling in the 400 nm to 2500 nm wave range and the average emissivity in the 7 μm to 14 μm wave range were related to the ratio between the length and the diameter of the load. granular, and in that order from large to small: (4: 1 and 6: 1)> (8: 1 and 3: 1)> 9: 1.
[0131] [0131] Compared with the formula Y, the ratio between the length and the diameter of the granular charge may be different. The ratio between the length and the diameter of the granular load of the samples was about 3: 1, 4: 1, 6: 1, 8: 1, 9: 1, respectively. The second functional radiative cooling coating material was applied to the galvanized sheet which has the first functional radiative cooling layer with a thickness of about 150 μm (formula X) and dried to obtain samples of the second functional radiative cooling layers. The thickness of the samples was 30 μm, and the average reflectivity in the wave range from 300 nm to 760 nm and the average emissivity in the wave range from 7 μm to 14 μm of the samples after drying were tested. The result was that the average reflectivity of the second functional layer of radiative cooling in the wave range from 300 nm to 760 nm and the average emissivity in the wave range from 7 μm to 14 μm were related to the ratio between the length and the diameter of the load. granular, and in that order from large to small: (4: 1 and 6: 1)> (8: 1 and 3: 1)> 9: 1.
[0132] [0132] Compared to formula X, the medium volume diameter of the granular charge may be different. The medium volume diameter of the samples was about 0.5 μm, 1 μm, 2 μm, 6 μm, 20 μm, 40 μm and 43 μm, respectively. The thickness of the samples from the first functional layer of radiative cooling was 120 μm, and the average reflectivity in the wave range from 400 nm to 2,500 nm and the average emissivity in the wave range from 7 μm to 14 μm of the samples after drying were tested. . The result was that the average reflectivity of the first functional radiative cooling layer in the 400 nm to 2,500 nm wave range and the average emissivity in the 7 μm to 14 μm wave range were related to the medium volume particle diameter of the granular charge , and in that order from large to small: (2 μm and 6 μm)> (1 μm and 20 μm)> (0.5 μm and 40 μm)> 43 μm.
[0133] [0133] Compared with formula Y, the medium volume diameter of the granular charge was different. The particle diameters of the samples were 0.5 μm, 1 μm, 2 μm, 6 μm, 20 μm, 40 μm and 43 μm, respectively. The second functional radiative cooling coating material was applied to the galvanized sheet which has the first functional radiative cooling layer with a thickness of 150 µm (formula X) and dried to obtain samples of the second functional radiative cooling layers. The thickness of the samples was 30 μm, and the average reflectivity in the wave range from 300 nm to 760 nm and the average emissivity in the wave range from 7 μm to 14 μm of the samples after drying were tested. The result was that the average reflectivity of the second functional layer of radioactive cooling in the 300 nm to 760 nm wave range and the average emissivity in the 7 μm to 14 μm wave range were related to the medium volume particle diameter of the granular charge , and in that order from large to small: (2 μm and 6 μm)> (1 μm and 20 μm)> (0.5 μm and 40 μm)> 43 μm.
[0134] [0134] Compared to formula X, the directional alignment of the granular load may be different. The angle between the surface of the first functional layer of radiative cooling and the length of the samples' silicon dioxide and calcium carbonate powder was in a range of 0 degrees to 45 degrees, in a range of 0 degrees to 30 degrees and disposition disorderly, respectively. The thickness of the samples from the first functional layer of radiative cooling was 120 μm, and the average reflectivity in the wave range from 400 nm to 2,500 nm and the average emissivity in the wave range from 7 μm to 14 μm of the samples after drying were tested. . The result was that the average reflectivity of the first functional radiative cooling layer in the 400 nm to 2,500 nm wave range and the average emissivity in the 7 μm to 14 μm wave range were related to the directional alignment of the granular load, and in that order from large to small: in the range of 0 degrees to 30 degrees> in the range of 0 degrees to 45 degrees> disorderly disposition.
[0135] [0135] Unlike formula Y, the angle between the surface of the first functional layer of radiative cooling and the length of silicon dioxide and calcium carbonate powder can be in a range of 0 degrees to 45 degrees, in a range of 0 degree to 30 degrees and disorderly disposition. The second functional radiative cooling coating material was applied to the galvanized sheet which has the first functional radiative cooling layer with a thickness of 150 µm (formula X) and dried to obtain samples of the second functional radiative cooling layers. The thickness of the samples was about 30 μm, and the average reflectivity in the wave range from 300 nm to 760 nm and the average emissivity in the 7 μm to 14 μm wave range after drying were tested. The result was that the average reflectivity of the second functional layer of radiative cooling in the 300 nm to 760 nm wave range and the average emissivity in the 7 μm to 14 μm wave range were related to the directional alignment of the granular load, and in that order from large to small: in the range of 0 degrees to 30 degrees> in the range of 0 degrees to 45 degrees> disorderly disposition.
[0136] [0136] Compared to formula X, the material of the granular fillers may be different. The material of the granular fillers can be pearl powder, silicon dioxide, aluminum oxide and magnesium oxide. The thickness of the samples from the first functional layer of radiative cooling was 80 μm, and the average reflectivity in the wave range from 400 nm to 2,500 nm and the average emissivity in the wave range from 7 μm to 14 μm of the samples after drying were tested. . The result was that the average reflectivity of the first functional layer of radiative cooling in the 400 nm to 2,500 nm wave range and the average emissivity in the 7 μm to 14 μm wave range were related to the granular charge material, and in that order of large to small: (pearl powder and silicon dioxide)> (aluminum oxide and magnesium oxide).
[0137] [0137] Compared to formula Y, the material of the granular charges may be different. The material of the granular fillers was silicon dioxide and calcium carbonate powder with a weight ratio of about 1: 1, magnesium oxide and aluminum oxide, respectively. The second functional radiative cooling coating material was applied to the galvanized sheet which has the first functional radiative cooling layer with a thickness of about 150 μm (formula X) and dried to obtain samples of the second functional radiative cooling layers. The thickness of the samples was about 40 μm, and the average reflectivity in the wave range from 300 nm to 760 nm and the average emissivity in the wave range from 7 μm to 14 μm of the samples after drying were tested. The result was that the average reflectivity of the second functional layer of radiative cooling in the wave range from 300 nm to 760 nm and the average emissivity in the wave range from 7 μm to 14 μm were related to the material of the granular charge, and in that order of large to small: (magnesium oxide and aluminum oxide)> silicon dioxide and calcium carbonate powder with a weight ratio of about 1: 1.
[0138] [0138] Compared to formula X, the material of the resins was different. The material of the resins was epoxy resin, polyester, polyurethane resin, acrylic resin, silicone resin and fluorine resin, respectively. The thickness of the samples from the first functional layer of radiative cooling was about 80 μm, and the average reflectivity in the wave range from 400 nm to 2,500 nm and the average emissivity in the wave range from 7 μm to 14 μm of the samples after drying have been tested. The result was that the average reflectivity of the first functional layer of radiative cooling in the 400 nm to 2,500 nm wave range and the average emissivity in the 7 μm to 14 μm wave range were related to the resin material, and in that order of great for small: (epoxy resin, polyester, polyurethane resin, acrylic resin and silicone resin)> fluorine resin.
[0139] [0139] Compared to formula Y, the material of the resins was different. The material of the resins was epoxy resin, polyester, polyurethane resin, acrylic resin, silicone resin and fluorine resin, respectively. The second functional radiative cooling coating material was applied to the galvanized sheet which has the first functional radiative cooling layer with a thickness of about 150 μm (formula X) and dried to obtain samples of the second functional radiative cooling layers. The thickness of the samples was about 40 μm, and the average reflectivity in the wave range from 300 nm to 760 nm and the average emissivity in the wave range from 7 μm to 14 μm of the samples after drying were tested. The result was that the average reflectivity of the second functional layer of radiative cooling in the wave range from 300 nm to 760 nm and the average emissivity in the wave range from 7 μm to 14 μm were related to the resin material, and in that order of great for small: (epoxy resin, polyester, polyurethane resin, acrylic resin and silicone resin)> fluorine resin.
[0140] [0140] Compared to formula X, the weight ratio between the granular charge and the resin may be different. The weight ratios between the granular load and the resin of the samples were about 10:89, 25:74, 50:49, 60:39, respectively. The thickness of the samples from the first functional layer of radiative cooling was about 80 μm, and the average reflectivity in the wave range from 400 nm to 2,500 nm and the average emissivity in the wave range from 7 μm to 14 μm of the samples after drying have been tested. The result was that the average reflectivity of the first functional radiative cooling layer in the 400 nm to 2,500 nm wave range and the average emissivity in the 7 μm to 14 μm wave range were related to the weight ratio between the granular load and the resin, and in that order from big to small: 25:74> 10:89> 50:49> 60:39.
[0141] [0141] Compared with formula Y, the weight ratio between the granular charge and the resin may be different. The weight ratios between the granular load and the resin of the samples were about 10:89, 25:74, 50:49, 60:39, respectively. The second functional radiative cooling coating material was applied to the galvanized sheet which has the first functional radiative cooling layer with a thickness of about 150 μm (formula X) and dried to obtain samples of the second functional radiative cooling layers. The thickness of the samples was about 40 μm, and the average reflectivity in the wave range from 300 nm to 760 nm and the average emissivity in the wave range from 7 μm to 14 μm of the samples after drying were tested. The result was that the average reflectivity of the second functional layer of radiative cooling in the wave range from 300 nm to 760 nm and the average emissivity in the wave range from 7 μm to 14 μm were related to the weight ratio between the granular load and the resin, and in that order from big to small: 25:74> 10:89> 50:49> 60:39. (3) WEATHER RESISTANCE TEST
[0142] [0142] (1) Sample preparation for xenon lamp testing: layers of selective radiative cooling coating were formed by coating the functional radiative cooling coating material on a 150 mm * 70 mm * 4 mm non-fiber cement board asbestos and included the first layer of resin (acrylic resin), the first functional layer of radiative cooling (which has formula X), the second functional layer of radiative cooling (which has formula Y) and the layer of weather-resistant resin , in order from bottom to top. The first layer of resin, the first functional layer of radioactive cooling and the second functional layer of radioactive cooling of the sample were the same. The sample's weather-resistant resin layer was supplied separately as a fluorocarbon resin (FEVE), a polyvinylidene fluoride resin (PVDF), an ethylene-tetrafluoroethylene (ETFE) copolymer resin and a fluorine-containing silicone resin. After coating the wire rods with the size of about 120 μm and about 80 μm at one time and curing for about 168 hours for each layer, sample 1, sample 2, sample 3 and sample were obtained 4. TESTING EQUIPMENT IS XENON LAMP TESTER.
[0143] [0143] Test conditions: temperature of the blackboard was 55 ± 2 degrees centigrade, humidity was about 70% RH, rain was about 18 min / 2 h, power was about 550 W / m2, and time of being placed was about 1,000 h. Appearance, powderiness and discoloration before and after aging were observed, and the change in mean reflectivity (in the 300 nm to 2500 nm wave range) before and after aging ΔR (reflectivity before aging less reflectivity after aging) and change at medium emissivity (in the 7 μm to 14 μm wave range) ΔE (emissivity before aging less emissivity after aging) were tested.
[0144] [0144] The results of the Xenon Lamp Test were that sample 1, sample 2, sample 3, sample 4 had no obvious change in appearance, powderiness and discoloration before and after aging, the ΔR reflectivity changes of all samples were below 2%, and the ΔE emissivity changes for all samples were below 2%. (2) TEMPERATURE RESISTANCE TEST
[0145] [0145] Sample preparation: the first functional radiative cooling coating material (which includes about 79% acrylic resin, about 20% aluminum silicate and about 1% polyethylene wax as the directional agent, in that the aluminum silicate was rod-shaped, had an approximate 4: 1 ratio between length and diameter, and the particle diameter was about 2 μm) was applied to a non-asbestos fiber cement board with a size approximately 150 mm * 70 mm * 4 mm. After coating the 120 μm and 80 μm wire rods at one time and curing for 168 hours, respectively, sample 5 was obtained.
[0146] [0146] The second functional radiative cooling coating material (which includes about 70% silicone resin, about 27% aluminum oxide and about 3% aqueous acetic acid-butyl cellulose as the directional agent, in that aluminum oxide was rod-shaped, had an approximate 6: 1 ratio between length and diameter, and the particle diameter was about 0.6 μm) was applied to a non-asbestos fiber cement board with a approximate size of 150 mm * 70 mm * 4 mm. After coating the wire rods with the size of about 120 μm and about 80 μm at once and cure for about 168 hours, sample 6 was obtained.
[0147] [0147] The weather resistant resin (fluorinated ethylenepropylene copolymer resin (FEP)) was applied to a non-asbestos fiber cement board with an approximate size of 150 mm * 70 mm * 4 mm. After coating the wire rods with the size of about 120 μm and about 80 μm at one time and curing for about 168 hours, sample 7 was obtained.
[0148] [0148] Test procedure: the samples were placed in water and soaked for 18 hours and then removed. The water stains on the surface of the samples were dried and placed in a refrigerator and placed at minus 20 degrees centigrade for about 3 hours. Then the samples were taken and placed in an oven at about 50 degrees Fahrenheit for about 3 hours. The processing was then carried out in 5 cycles to observe the change in the surface of the samples. If at least 2 of the 3 samples in each test had no changes, that is, there was no powder, cracks, bubbles, flaking, obvious discoloration, and other phenomena of film degradation, the result of the sample test was “without abnormality”.
[0149] [0149] The results of the temperature resistance performance test were normal for sample 5, sample 6, sample 7, that is, there was no powder, cracks, bubbles, flaking, obvious discoloration and other phenomena of film degradation . (3) WATER RESISTANCE TEST
[0150] [0150] The water resistance properties of sample 5, sample 6 and sample 7 were tested.
[0151] [0151] Test procedure: after immersion in water for 96 hours, it was observed in the samples if the surface had bubble phenomena, dust drop, obvious discoloration and the like.
[0152] [0152] The results of the water resistance test were that the surface of sample 5, sample 6 and sample 7 had no bubbles, dust drop, obvious discoloration and the like. (4) STAIN RESISTANCE TEST: THE SPOT RESISTANCE PROPERTIES OF SAMPLE 1, SAMPLE 2, SAMPLE 3 AND SAMPLE 4 WERE TESTED.
[0153] [0153] The test equipment was the Coating Stain Resistance Tester.
[0154] [0154] Pollution source configuration: a standard suspension of ash and water with a mass ratio of 1: 1 was used.
[0155] [0155] Test procedure: first, the reflectivity of the sample in the upper, middle and lower positions was tested. The average reflectivity value was obtained and denoted as P. 0.7 ± 0.1 g of pollution source was brushed in each sample. The samples were dried in an oven at about 60 degrees centigrade for about 30 minutes, removed and placed for about 2 h. After rinsing with a coating stain resistance tester for about 1 min, the samples were placed for about 24 h. After repeating the above process, the reflectivity of the samples was tested in the upper, middle and lower positions, and the average value was obtained and denoted as Q.
[0156] [0156] Resistance to coating stains was calculated by the reflectivity reduction rate (X) as follows: X = | PQ | / P * 100%, and the result was an arithmetic average of three samples, and two effective values have been maintained. The average relative error of the three samples must be less than or equal to 15%.
[0157] [0157] The result of the stain resistance test was that the reflectivity reduction rates (X) of all among sample 1, sample 2, sample 3 and sample 4 were 3% or less than 3%. (5) MECHANICAL PROPERTIES: (1) MEMBERSHIP TEST
[0158] [0158] The adhesion of sample 5, sample 6 and sample 7 was tested.
[0159] [0159] Adhesion test: according to the provisions of GB / T 9286-1998, the samples were cut, respectively, three lines by an edge cutter in the parallel and vertical directions along the long edge of the sample, each interval was 3 mm and the number of grids was 4. The tape rupture test was performed.
[0160] [0160] The results were evaluated at six levels of 0, 1, 2, 3, 4 and 5. Level 0 means that the cutting edge was completely smooth and there was no separation. Level 1 meant that there was a small peeling coating at the intersection of the incision, but the cross-sectional area significantly affected was not more than 5%. Level 2 meant that, at the intersection of the incision and / or along the edge of the incision, the cross-sectional area affected by the peeling coating was significantly greater than 5% and not significantly greater than 15%. Level 3 meant that part or all of the coating was peeled along the cutting edge with large fragments and / or part or all of the peeling in different parts of the grid, the affected cross-sectional area was significantly greater than 15% and not significantly higher than 35%. Level 4 meant that the coating was peeled along the cutting edge and / or some or all of the squares appeared to peel, the affected cross-sectional area was significantly greater than 35% and not significantly greater than 65%. Level 5 meant that the degree of removal exceeded 4 levels.
[0161] [0161] The result of the adhesion test was that the degrees of peeling of the entire surface of sample 5, sample 6 and sample 7 were lower than level 2. (2) Bending resistance test
[0162] [0162] The test equipment was the Cylindrical Flexion Tester.
[0163] [0163] Sample preparation: the first functional radiative cooling coating material (including about 75% acrylic resin, about 25% aluminum silicate, where the aluminum silicate was rod-shaped, was right approximately 4: 1 between length and diameter, and the particle diameter was 6 μm) was applied to a tinplate with an approximate size of 150 mm * 70 mm * 0.25 mm. After coating the wire rods with a size of about 120 μm and about 80 μm at one time and curing for about 168 hours, sample 8 was obtained. A second functional radiative cooling coating material (including a alumina-containing silicone resin, where the shape of the alumina is a rod, the length-to-diameter ratio was 6: 1, and the particle diameter was 5 μm) was applied to a tinplate of a size approximately 150 mm * 70 mm * 0.25 mm. After coating the wire rods with a size of about 120 μm and about 80 μm at one time and curing for 168 hours, respectively, the sample was obtained 9.
[0164] [0164] A weather-resistant resin (fluorinated ethylenepropylene copolymer resin (FEP)) was applied to a tinplate approximately 150 mm * 70 mm * 0.25 mm in size. After coating the wire rods with the size of about 120 μm and about 80 μm at one time and curing for about 168 hours, respectively, sample 10 was obtained.
[0165] [0165] Test procedure: the flexibility of the sample was tested using a cylindrical bending tester. If there were no ridges or cracks visible on the sample surface or if the size of the ridges and cracks was less than 2 mm, the sample was considered acceptable.
[0166] [0166] The flexural strength property of sample 8, sample 9 and sample 10 was tested.
[0167] [0167] The result of the flexural strength test was that the surfaces of sample 8, sample 9 and sample 10 showed no visible ridge or crack. (3) ABRASION RESISTANCE TEST
[0168] [0168] The test equipment was the Wash Tester.
[0169] [0169] Sample preparation: a first functional radiative cooling coating material (including about 90% acrylic resin and about 10% aluminum silicate, where the aluminum silicate was rod shaped, the ratio between length and diameter was about 4: 1, and the particle diameter was about 4 μm) was applied on PVC plastic sheet with an approximate size of 432 mm * 165 mm * 0.25 mm. After scraping through a wet film prep machine with a size of about 200 μm once and curing for about 7 days, sample 11 was obtained. A second functional radiative cooling coating material (including about 85 % silicone resin and about 15% aluminum oxide, where the aluminum oxide was rod-shaped, the length-to-diameter ratio was about 6: 1, and the particle diameter was about 3 μm) was applied on PVC plastic sheet with an approximate size of 432 mm * 165 mm * 0.25 mm. After scraping through a wet film preparation machine with a size of about 200 μm once and curing for about 7 days, sample 12 was obtained.
[0170] [0170] A weather resistant resin (fluorinated ethylene propylene copolymer resin (FEP)) was applied to a plastic sheet approximately 432 mm * 165 mm * 0.25 mm in size. After scraping through a wet film preparation machine with a size of about 200 μm once and curing for about 7 days, sample 13 was obtained.
[0171] [0171] Test procedure: the sample was rubbed with an aqueous solution of about 2.5 g / l of sodium dodecylbenzene sulfonate, the brush moved at a frequency of alternating movements of 37 ± 2 cycles per minute and distance of a reciprocating stroke was about 300 mm * 2. The brush moved in the central area of about 100 mm at a constant speed. When the number of alternating brush movements was up to 10,000, the sample was removed and it was observed whether the sample surface was damaged.
[0172] [0172] The abrasion resistance property of sample 11, sample 12 and sample 13 was tested.
[0173] [0173] The result of the abrasion resistance test was that the surfaces of sample 11, sample 12 and sample 13 were not damaged. [ENGINEERING APPLICATION]
[0174] [0174] The selective radiative cooling coating layers of the present disclosure can be applied in a variety of different fields and applied to buildings, storage devices, textiles, helmets and waterproof rolled material serve as examples in the following description . CASE 1: DEMONSTRATION HOUSE
[0175] [0175] In order to explain the cooling and cooling effect of the selective radiative cooling coating layer, the selective radiative cooling coating layer was applied to the building as an example in the following description.
[0176] [0176] A demonstration house was produced from stainless steel material and had a length, width and height of about 5 m, about 4 m and about 3 m, respectively. A layer of selective radiative cooling coating was formed on the outside of the roof and on four walls. The selective radiative cooling coating layer included a first resin layer (acrylic resin) with a thickness of about 20 μm, a first functional radiative cooling layer (formula X) with a thickness of about 100 μm, a second layer functional radiative cooling (formula Y) with a thickness of about 15 μm, and a layer of weather resistant resin (polyvinylidene fluoride resin) with a thickness of about 20 μm from the bottom up. The selective radiative cooling coating layer had a reflectivity of 91% in a wave range of 0.3 μm to 2.5 μm and an emissivity of about 94% in a wave range of 7 μm to 14 μm. The outdoor demonstration house with the selective radiative cooling coating layer was defined as demonstration house A, which was measured on a lawn at No. 88, Dongfeng Road, Fenghua District, Ningbo City on August 22, 2018 with the use of a thermocouple with a data logger. Record temperature changes within 24 hours of a total of 9 test points on the surface and inside demonstration house A.
[0177] [0177] Another demonstration house of the same size, material, structure and shape was placed in the same environment as demonstration house A, except that there was no layer of selective radiative cooling coating on the outside of the roof and on the four walls. The demonstration house without selective radioactive cooling coating layer was defined as demonstration house B. The thermocouple with data logger was used to measure and record temperature changes in the same period of time as in exhibition room A, for a total of nine test points on the surface and inside demonstration house B. The test point distributions for demonstration house A and demonstration house B were the same, as shown in Figure 7a.
[0178] [0178] In Figure 7a, A1, A6, A7, A8 and A9 were respectively in the central position of the outer surface of the roof of demonstration house A, in the central position of the external surface of the east side wall, in the central position of the external surface of the west side wall, in the central position of the external surface of the south side wall and in the central position of the external surface of the north side wall. A2, A3, A4, and A5 were test points for air temperature on the same vertical line perpendicular to the ground in demonstration house A, with different heights from the ground. The external ambient temperature was also tested.
[0179] [0179] In Figure 7a, B1, B6, B7, B8 and B9 were respectively in the central position of the external surface of the roof of the demonstration house B, in the central position of the external surface of the east side wall, in the central position of the external surface of the west side wall, in the central position of the external surface of the south side wall and in the central position of the external surface of the north side wall. B2, B3, B4, and B5 were test points for air temperature on the same vertical line perpendicular to the ground in demonstration house B, with different heights from the ground. The external ambient temperature was also tested.
[0180] [0180] With reference to Figure 7b, the temperature graph of different test points on the surface of demonstration house A and in the external environment was shown. It can be seen from Figure 7b that the temperature of the external surface of demonstration house A with the selective radiative cooling coating layer (which includes the roof and the northeast and southwest directions) was lower than that of the external environment by about 6.1 degrees centigrade.
[0181] [0181] Referring to Figure 7c, the temperature at different points in the longitudinal direction of demonstration house A with the selective radiative cooling coating layer was lower than that of the external environment in 24 hours. Compared to the outside, the temperature dropped about 5.5 degrees Fahrenheit. As the sun increased, the closer the position was to the roof, the lower the temperature. This indicated that the selective radiative cooling coating layer had an obvious passive radiative cooling effect.
[0182] [0182] Referring to Figure 7d, the temperature on the outer surface of demonstration house B (including the roof and south, east, north and west directions) without the selective radiative cooling coating layer is higher than that of the external environment by about 21 degrees centigrade. As can be seen from Figures 7b and 7d, the temperature of the demonstration house A with the selective radiative cooling coating layer was lower than that of the demonstration house B without the selective radiative cooling coating layer by about 24 degrees centigrade.
[0183] [0183] As can be seen from Figure 7e, demonstration room B without the selective radiative cooling coating had a large temperature difference at different points in the longitudinal direction. As the sun increased, the closer the position was to the roof, the higher the temperature. Temperature stratification was more obvious. CASE 2: WATER TANK
[0184] [0184] In order to illustrate the cooling and cooling effect of the selective radiative cooling coating layer, the selective radiative cooling coating layer was applied to the storage device as an example in the following description. EXAMPLE 1:
[0185] [0185] A water tank was produced from plastic material and had a length, width and height of about 800 mm, about 800 mm and about 80 mm, respectively. The water tank received the selective radiative cooling coating layer on the top surface of the water tank. The selective radiative cooling coating layer included a base layer with a thickness of about 30 μm, a resin layer (epoxy resin), a first functional radiative cooling layer (formula X) with a thickness of about 120 μm , a second functional radiative cooling layer (formula Y) with a thickness of about 20 μm and a layer of weather-resistant resin (carbon resin with fluorine) with a thickness of about 30 μm from the bottom up. The reflectivity of the selective radiative cooling coating layer was about 91% in a wave range from 0.3 μm to 2.5 μm, and the emissivity was about 96% in a wave range from 7 μm to 14 μm. The water tank with the selective radiative cooling coating layer was defined as the water tank C. A temperature test point C1 was defined in the center of the water tank C. COMPARATIVE EXAMPLE 1
[0186] [0186] The water tank of the same material and size as the water tank C and not treated in any way on the upper surface has been defined as the water tank D. A temperature test point D1 has been defined in the center of the water tank. water D in the same position as the temperature test point C1. The positions of the temperature test points C1 and D1 were respectively at the water centers in the water tanks C and D as shown in Figure 8a. From 20 to 21 August 2018, the temperature changes of temperature test points C1 and D1 in the water tank were tested on the lawn at No. 88 Dongfeng Road, Fenghua District, Ningbo City. The test results were shown in FIG. 8b.
[0187] [0187] Referring to Figure 8b, first, the temperature of the water temperature test point C1 in the water tank C of the selective radiative cooling coating layer was lower than that of the external environment in 24 hours. Compared to the outside environment, the temperature dropped about 5.3 degrees Fahrenheit at one extreme. This indicated that the selective radiative cooling coating layer had an obvious passive radiative cooling effect. Second, the temperature of the temperature test point C1 of the water tank C with the selective radiative cooling coating layer was lower than that of the temperature measurement point D1 of the water tank D without the radiant cooling coating layer. selective in 24 h, by about 14.4 degrees centigrade at one end. This indicated that the selective radiative cooling coating layer had an obvious passive radiative cooling effect. CASE 3: TENT
[0188] [0188] In order to illustrate the cooling and cooling effect of the selective radiative cooling coating layer, the selective radiative cooling coating layer was applied to the textile as an example in the following description.
[0189] [0189] A selective radioactive cooling coating layer was formed on the surface of tent E, and the selective radioactive cooling coating layer included a first layer of resin with a thickness of about 40 μm (which includes acrylic resin and epoxy resin. with a mass ratio of 1: 1), a first functional radiative cooling layer (formula X) with a thickness of about 130 μm, a second functional radiative cooling layer (formula Y) with a thickness of about 30 μm , a layer of weather resistant resin (ethylene-tetrafluoroethylene copolymer resin) with a thickness of about 40 μm from the bottom up. The reflectivity of the selective radiative cooling coating layer was about 92% in a wave range of 0.3 μm to 2.5 μm, and the emissivity was about 97% in a wave range of 7 μm at 14 μm. COMPARATIVE EXAMPLE 1
[0190] [0190] Another F tent of the same size, material and style as tent E has not been treated on the surface. On April 26, 2019, temperature changes at different locations inside tent E and tent F were tested on the lawn at No. 88 Dongfeng Road, Fenghua District, Ningbo City. The temperature change outside was measured. As shown in Figure 9a, it is a schematic diagram of the temperature test points in tent E and tent F.
[0191] [0191] Among them, E1 / F1, E2 / F2, E3 / F3 were the three temperature test points in the vertical line of the E and F tents and on the ground, and E1 / F1 are the temperature test points in the tent surface E / F. E2 / F2 is the temperature test point that is about 2 cm from the top of the E / F tent, and E3 / F3 is the temperature test point of the inner center of the E / F tents.
[0192] [0192] Figure 9b is a graph showing the temperature difference of the temperature test points in tents E and F.
[0193] [0193] Referring to Figure 9b, first, the temperature in tent E with the selective radiative cooling coating layer is lower than that in tent F without the selective radiative cooling coating layer by about 10 degrees centigrade to 17 degrees centigrade. Second, the selective radiative cooling coating placed on the tent had an obvious passive cooling effect, which can reduce the tent's internal temperature and improve the comfort of the tent. CASE 4: HELMET
[0194] [0194] When a layer of selective radiative cooling coating is applied to the hat / helmet field, the temperature inside the cap / helmet can be greatly reduced and the comfort of the cap / helmet can be increased in the sun.
[0195] [0195] To illustrate the effect of the selective radiative cooling coating, the following is exemplified. EXAMPLE 1:
[0196] [0196] A layer of selective radiative cooling coating was laid on the outer surface of the helmet. The selective radiative cooling coating layer included a first resin layer with a thickness of about 50 μm (including an acrylic resin and an epoxy resin with a mass ratio between 2: 1), a first functional radiative cooling layer ( formula X) with a thickness of about 150 μm, a second functional radiative cooling layer (formula Y) with a thickness of about 50 μm, and a layer of weather resistant resin (ethylene copolymer resin and fluorinated propylene) with a thickness of about 50 μm from the bottom up. The selectivity of the selective radiative cooling coating layer was about 92% in a wave range from 0.3 μm to 2.5 μm, and the emissivity was about 97% in a wave range from 7 μm to 14 μm. The helmet with a selective radiative cooling coating layer was defined as G, a temperature test point in the upper position inside the helmet was defined as G1. COMPARATIVE EXAMPLE 1
[0197] [0197] Another helmet of the same type as helmet G was not treated on the outer surface and was defined as H. A temperature test point in the same upper position inside helmet H as in helmet G was defined as H1. A schematic diagram of the temperature test points on helmets G and H, as shown in Figure 10a. From April 16, 2019 to April 18, 2019, the temperature changes of the upper temperature test points H1 and G1 on the helmet were tested on the top of building No. 88, Dongfeng Road, Fenghua District, Ningbo City. The test results were shown in FIG. 10b.
[0198] [0198] It can be seen from Figure 10b that the temperature difference between the normal helmet (helmet H) and the cooling helmet (helmet G) was tested, and the test point was the upper position on the helmet. The maximum temperature difference at 11 am can reach 13.5 degrees centigrade. Second, the cooling effect was proportional to the intensity of solar radiation. The higher the irradiation intensity, the better the cooling effect. Third, the selective radiative cooling coating layer had an obvious passive cooling effect on the helmet's surface, which can reduce the helmet's internal temperature and improve the helmet's comfort. CASE 5: WATERPROOF WRAPPED MATERIAL
[0199] [0199] The application of the selective radiative cooling coating layer to the field of impermeable rolled material can solve the problem of excessive temperature of the flat roof or of the inclined roof, reduce the temperature of the roof floor, reduce the consumption of cooling energy and save energy and environmental protection while guaranteeing waterproofing.
[0200] [0200] To illustrate the cooling effect of the selective radiative cooling coating layer, the following is exemplified. EXAMPLE 1:
[0201] [0201] The selective radiative cooling coating layer was placed on the outer surface of the impermeable rolled material facing directly into the air. The selective radiative cooling coating layer includes a first resin layer (including acrylic resin) with a thickness of about 50 μm, a first functional radiative cooling layer (formula X) with a thickness of about 200 μm, a second functional radiative cooling layer (formulation Y) with a thickness of about 60 μm, a layer of weather resistant resin (ethylene-tetrafluoroethylene copolymer resin) with a thickness of 10 μm from the bottom up. The reflectivity of the selective radiative cooling coating layer was about 92% in a wave range of 0.3 μm to 2.5 μm, and the emissivity was about 97% in a wave range of 7 μm at 14 μm. The impermeable rolled material with the selective radiative cooling coating layer was defined as I, in which a temperature test point I1 was defined on the front side and a temperature test point I2 was defined on the rear side. COMPARATIVE EXAMPLE 1
[0202] [0202] Another waterproof rolled material (from the same batch of products) was not treated on the outer surface and was defined as J, in which a temperature test point J1 was defined on the front side and a temperature test point J2 was defined on the back side.
[0203] [0203] On May 23, 2019, the temperature of the front and rear temperature test points of the impermeable rolled materials I and J was tested within 24 hours on top of building No. 88, Dongfeng Road, Fenghua District, Ningbo City. The graph showing the temperature of the front and rear temperature test points of impermeable rolled material I and J was shown in Figure 11.
[0204] [0204] Referring to Figure 11, first, the temperature of the front and rear surfaces of the impermeable rolled material I with the selective radiative cooling coating layer on the front side was significantly lower than that of the front and rear surfaces of the impermeable rolled material J without the selective radiative cooling coating layer, and the maximum temperature difference can reach 40 degrees centigrade. Second, the temperature difference between the impermeable rolled material I and J can reach the maximum at noon, indicating that the selective radiative cooling coating layer had the best radiative cooling effect at midday. Third, the temperature difference between the lower surface of the impermeable rolled material I and J was greater than that of the upper surface, due to the testing of the upper surface being affected by heat transfer by atmospheric convection. Fourth, the selective radiative cooling coating layer can effectively reduce the surface temperature of the impermeable rolled material for a long time, thereby reducing the overall roof temperature.
[0205] [0205] In the above modalities, the descriptions of the various modalities are different, and the parts that are not described in detail in a particular modality, can be referred to the related descriptions of other modalities.
[0206] [0206] The above modalities are used only to explain the technical solutions of the present disclosure and are not limited to them. People versed in the technique must understand that they can still modify the technical solutions described in the modalities above, or some technical characteristics are replaced in an equivalent way; and these modifications or substitutions do not deviate from the essence of the corresponding technical solutions of the spirit and scope of the technical solutions of the modalities of the present revelation.

权利要求:
Claims (15)
[0001]
Functional radiative cooling coating material to manufacture a functional radiative cooling layer characterized in that said layer is configured to reflect ultraviolet light, visible light, near infrared light or a combination thereof, in sunlight, and to emit heat through an atmospheric window in the form of infrared radiation, the radiative cooling functional coating material comprises a granular charge and a radiative cooling functional resin, and the granular charge is distributed in the radiative cooling functional resin.
[0002]
Functional radiative cooling coating material according to claim 1, characterized in that the granular load has the shape of a rod, a sphere or an ellipsoid, and when the granular load is rod-shaped or ellipsoid-shaped, a ratio between a length of the granular load and a diameter of the granular load is in the range of 1: 1 to 10: 1.
[0003]
Functional radiative cooling coating material, according to claim 1, characterized in that the granular load is arranged in an orderly manner in the radiative cooling functional resin, the granular load being evenly and directionally distributed in the radiative cooling functional resin. .
[0004]
Functional radiative cooling coating material according to claim 1, characterized in that the granular charge comprises a first granular charge and / or a second granular charge, and the first granular charge has a diameter in a range of 0.5 μm to 40 μm, the functional radiative cooling layer comprising the first granular charge to be configured to reflect visible light and nearby infrared light and emit heat through the atmospheric window in the form of infrared radiation; the second granular charge has a diameter in the range of 0.01 μm to 40 μm, and the functional radiative cooling layer comprising the second granular charge is configured to reflect ultraviolet light and visible light and emit heat through the atmospheric window in the form of infrared radiation; the first granular charge and the second granular charge are respectively aluminum silicate, pearl powder, silicon dioxide, calcium carbonate, aluminum oxide, zinc oxide, zirconium oxide, cerium oxide, lanthanum oxide, rhodium dioxide , barium sulfate, talcum powder, titanium dioxide, zinc sulfide, ceramic powder, magnesium oxide, ceramic microspheres, glass microspheres or a combination thereof.
[0005]
Functional radiative cooling coating material according to claim 4, characterized in that the first granular filler is aluminum silicate, pearl powder, silicon dioxide, calcium carbonate, barium sulfate, talcum powder, titanium dioxide, zinc sulphide, ceramic powder, ceramic microspheres, glass microspheres or a combination thereof, the second granular charge is aluminum oxide, zinc oxide, zirconium oxide, cerium oxide, lanthanum oxide, rhodium dioxide, magnesium oxide or a combination thereof.
[0006]
Functional radiative cooling coating material according to claim 1, characterized in that the functional radiative cooling resin is epoxy resin, polyester, polyurethane, acrylic resin, silicone resin or a combination thereof.
[0007]
Functional radiative cooling coating material according to any one of claims 1 to 6, characterized in that it further comprises a directional agent configured to control an orientation of the granular load; the directional agent is aqueous acetic acid-butyl cellulose, ethylene-vinyl acetate copolymer wax emulsion, polyethylene wax, polyamide wax or a combination thereof.
[0008]
Functional radiative cooling coating material according to any one of claims 1 to 6, characterized in that it additionally comprises a pigment, the pigment being a fluorescent dye.
[0009]
Method of application of the radiative cooling functional coating material, according to claim 1, the application method being characterized by comprising coating the radiative cooling functional coating material on a substrate or main body surface for obtain a functional layer of radiative cooling, in which the functional layer of radiative cooling is configured to reflect and / or emit heat to the outside; the substrate is a metal, plastic, rubber, concrete, cement, asphalt, paper, textile, wood, ceramic tile, glass and organic synthetic material; the main body is one of a building, a photovoltaic module, a system comprising the photovoltaic module, an automobile, an outdoor product, agricultural, livestock and aquaculture greenhouses, aerospace equipment, a cold chain transport device, a external enclosure, textile industry, external communication equipment, industrial equipment, utility equipment, cooling water system, energy system and energy saving equipment.
[0010]
Selective radioactive cooling coating layer, said coating layer being characterized by comprising a functional radioactive cooling layer manufactured by the functional radioactive cooling coating material according to any one of claims 1 to 8.
[0011]
Selective radiative cooling coating layer according to claim 10, said coating layer being characterized by comprising a first functional radiative cooling layer and a second functional radiative cooling layer, the first functional radiative cooling layer comprises the functional radiative cooling resin and a first granular charge distributed in the functional radiative cooling resin, the second functional radiative cooling layer comprises the functional radiative cooling resin and a second granular charge distributed in the functional radiative cooling resin, the first functional layer of radiative cooling has a thickness of 30 μm to 300 μm, and the second functional layer of radiative cooling has a thickness of 10 μm to 60 μm.
[0012]
Selective radiative cooling coating layer according to claim 10, the radiative cooling functional layer being characterized by comprising a first surface and a second surface distant from the first surface, the selective radiative cooling coating layer further comprises a weather resistant resin layer located on the first surface of the radiative cooling functional layer, and / or a first resin layer located on the second surface of the radiative cooling functional layer, the weather resistant resin layer has a transmittance that is greater than or equal to 80%, and a weather resistant resin layer material comprises fluorine-containing resin, epoxy resin, polyester, polyurethane, acrylic resin, silicon resin or a combination of the same, a material of the first resin layer comprises an epoxy resin and / or an acrylic resin, the layer of weather-resistant resin has a thickness of 10 μm to 50 μm, and the first layer of resin has a thickness of 10 μm to 50 μm.
[0013]
Selective radiative cooling coating layer according to claim 10, characterized by a weight ratio between the granular load and the radiative cooling functional resin being in the range of 1:10 to 6: 1.
[0014]
Selective radiative cooling coating layer according to any of claims 10 to 13, characterized in that the functional radiative cooling layer has a solar energy reflectivity that is greater than or equal to 80% and an atmospheric window emissivity that is greater or equal to 80% and is capable of providing radiative cooling power greater than or equal to 100 W / m2 at room temperature.
[0015]
Composite material comprising the selective radiative cooling coating layer according to claim 10, characterized in that said coating layer comprises a substrate and the functional radiative cooling layer is arranged on the substrate, the substrate is metal, plastic, rubber, concrete, cement, asphalt, paper, textile, wood, ceramic tile, glass or organic synthetic material.

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同族专利:

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公开号 | 公开日

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WO2021003777A1|2021-01-14|

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PH12020550103A1|2021-01-25|

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TWI740202B|2021-09-21|

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JP2021528502A|2021-10-21|

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SG11202002783SA|2021-02-25|

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TW202102644A|2021-01-16|

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US10947394B2|2021-03-16|

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AU2020256416B2|2021-11-11|

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AU2020256416A1|2020-11-12|

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CN110896639B|2021-12-14|

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AU2019236674B1|2020-08-20|

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US20210002491A1|2021-01-07|

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CN110317521A|2019-10-11|

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CN110896639A|2020-03-20|

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EP3760678A1|2021-01-06|

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CN113388305A|2021-05-28|2021-09-14|上海交通大学|Radiation refrigeration composite coating with structural color, application and preparation method|

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法律状态:
2021-01-19| B03A| Publication of a patent application or of a certificate of addition of invention [chapter 3.1 patent gazette]|

优先权:

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申请号 | 申请日 | 专利标题

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CN201910607455.2|2019-07-05|

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CN201910607455.2A|CN110317521A|2019-07-05|2019-07-05|Selective radiation refrigeration coating and its composite material and methods for using them|

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